防腐涂料

J. Cent. South Univ. (2012) 19: 46−54DOI: 10.1007/s11771−012−0971−zCorrosion resistance of waterborne epoxy coating pigmented bynano-sized aluminium powder on steelLIU Jian-hua(刘建华), ZHAN Zhong-wei(詹中伟), LI Song-mei(李松梅), YU Mei(于美)School of Materials Science and Engineering, Beihang University, Beijing 100191, China© Central South University Press and Springer-Verlag Berlin Heidelberg 2012Abstract: A novel kind of waterborne epoxy coating pigmented by nano-sized aluminium powders on high strength steel was formulated. Several coatings with different pigment volume content (PVC) were prepared. The coating morphology was observed using scanning electron microscopy (SEM), and the electrochemical properties were investigated by electrochemical impedance spectroscopy (EIS). Immersion test and neutral salt spray test were also conducted to investigate the corrosion resistance of the coating. It is demonstrated that the critical pigment volume content (CPVC) value is between 30% and 40%. The coating with PVC of 30% exhibits good corrosion resistance in 3.5% (mass fraction) NaCl solution.Key words: nano-sized aluminium powder; waterborne epoxy coating; corrosion resistance; pigment volume content1 IntroductionOrganic coating is one of the efficient methods to protect metallic substrates from corrosion [1], and the efficiency could be enhanced by adding some kinds of suitable pigments [2]. Some widely used lead-based and hexavalent chromium (VI)-contained pigments, posed environmental concerns, and were proved to be detrimental to human. Therefore, they must be removed from the coating formulation [3]. Moreover, the introduction of strict regulations in the use of volatile organic compounds (VOC) has brought about the development of waterborne coating technologies. Consequently, based on the environmental protection requirements, many novel protective coatings with waterborne binders and non-toxic anticorrosion pigments [4] have been studied extensively.In recent years, waterborne coatings with nano- sized inorganic composites as pigments have been investigated because of their effectiveness in corrosion protection. For example, nano-TiO2 [5−7], nano-SiO2 [6−7], and nano-sized titanium powder [8] were applied to modifying organic coatings.When coatings are formulated, one important characteristic value is pigment volume content (PVC), which strongly affects their properties [9]. Furthermore, there is a critical pigment volume content (CPVC) [10] in many coating formulations containing pigments or dyes. Below the CPVC, the pigment can uniformly distribute in the binder matrix without harming its integrality and compactness. While above the CPVC, the excessive pigment can not be fully packed by the binder, and pores and voids occur in the coating matrix.In our previous studies, the corrosion resistance of many kinds of steel has been extensively investigated [11−14]. Besides, nano-science has also been introduced into our research to exploit valuable areas with novel sharp [15] and properties [16]. In this research, nano- sized aluminium powder was added into waterborne epoxy coatings with different pigment volume contents (PVC) from 10% to 80%. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) were applied to determine the critical pigment volume content (CPVC) independently. The corrosion resistance of the coating with optimum PVC of 30% was investigated by immersion test and neutral salt spray test. In combination with equivalent circuit simulation method, electrochemical impedance spectroscopy was also used to reveal the corrosion behavior of the coating (PVC 30%) during the immersion in 3.5% (mass fraction) NaCl solution.2 Experimental2.1 Samples preparationHigh strength steel panels (30CrMnSi) were used as metallic substrates with a size of 100 mm × 50 mm ×Foundation item: Project(51001007) supported by the National Natural Science Foundation of China; Project(2011ZE51057) supported by the Aero Science Foundation of ChinaReceived date: 2010−10−01; Accepted date: 2011−01−23Corresponding author: LIU Jian-hua, Professor; Tel/Fax: +86−10−82317103; E-mail: liujh@J. Cent. South Univ. (2012) 19: 46−54 47 2 mm. The panels were polished with SiC waterproofabrasive papers up to grit #400, degreased with acetoneand deionized water, then blown dry with clean air. Thepre-treatment operations were performed prior to theapplication of the epoxy coating.The coating procedure was as follows: Thewaterborne epoxy resin (HD-BE314, chemical purity,Beijing Jinhuili Applied Chemical Products Co. Ltd.,China) was mixed with deionized water in a mass ratioof 1:1, then magnetically stirred for about 2 h until auniform, light-yellow solution was obtained. Thealuminium powder (analytical purity, median-particle-size (D50) of 60 nm, Nanjing Emperor Nano-Material Co.Ltd., China) was slowly added into a silane couplingagent solution under severe stirring for 10 min, and themolar ratio of silane-to-aluminium was 1:2. After stirring,the aluminium powder solution was ultrasonicallyprocessed for 30 min, and then mixed with the epoxysolution to get different PVC from 10% to 80% withincrement of 10%. The final solution was then stirred forat least 6 h at room temperature, while several additiveswere added, such as defoamer, diapersant, flow agent,which were bought as commercial products and usedwithout any further purification or dilution. Thecomposition of the coating presented in this study isgiven in Table 1.Table 1 Composition of waterborne epoxy coatingBinder Pigments Solvent AdditiveHD-BE314 (two-pack, waterborne) Aluminiumpowder(D50=60 nm)DistilledwaterDefoamer,silane coupling agent,dispersant,flow agent,thickenerThe steel panels were dip coated for two times and then dried in air for 24 h, followed by a 3 h oven-dry at 120 °C. The thickness of the coatings was (20±3) μm after drying, which was measured by a coating thickness gauge MiniTest 610 (Elektro Physik, Germany). The cross-section micrographs of the coating, as well as the related EDS measurements, were also carried out to confirm the thickness.2.2 Testing methodsTo observe the surface and cross-section morphology of the coatings, SEM analyses were performed using a JSM-5800 instrument in secondary electron mode.The electrochemical impedance spectroscopy (EIS) was measured by electrochemical work station (Princeton 2273, USA). The electrochemical testing solution was a 3.5% NaCl aqueous solution open to air, held at room temperature (25 °C ). A three-electrode cell arrangement was used in the experiment by sticking a plastic cylinder on the sample sheet and filling it with the testing solution. The exposed sample surface area was7 cm2. A Pt-plate and a saturated calomel electrode (SCE) were used as counter and reference electrode, respectively. All EIS measurements were performed in a frequency range from 1 MHz to 10 mHz under open circuit potential, with a 10 mV amplitude of the sinusoidal voltage signal.The corrosion resistance was examined using immersion test and neutral salt spray test according to ASTM B117. During the immersion in 3.5% NaCl solution, several EIS measurements were carried out at different time points (0.5, 5, 24, 72, 120, 288, 400, 600,800 h) with the frequency range from 0.1 MHz to 10 mHz. The impedance data were analyzed using ZsimpWin software to extract characteristic parametersof the coatings.To measure the adhesion performance of the coatings, a cutting tool (295/V, Erichen, Germany) was used to make a cross-cut through the coatings till the substrate. The cutting surface was observed and evaluated according to the ASTM D 3359-02.3 Results and discussion3.1 Determination of CPVCThe critical pigment volume content (CPVC) is an important parameter to each coating system containingone kind or more pigments [17−22]. Many experimental methods were reported as reference method of CPVC, such as calculation of oil absorption values, internal stress measurement, hiding power, mercury porosimetry [23] and gas permeation [24]. Among these methods, the SEM observation and EIS measurement were regarded asthe most reproducible methods to distinguish the undercritical from overcritical coatings.The surface morphology of coatings containing nano-sized aluminium powder with pigment volume content (PVC) from 10% to 60% is shown in Fig. 1. The micro-pore structure is observed in the coatings with PVC of more than 40% as shown in Fig. 1(d). For coatings with PVC lower than 30%, the aluminium powders are randomly embedded in the continuously connected matrix of epoxy binder with a relatively flat surface. For coatings with PVC from 30% to 40%, the metallic powders are uniformly distributed in the coating body, and the binder adequately fills the spaces amongthe powder particles and the aggregates, which results in sporadic isolated holes. Therefore, it is demonstrated thatthe optimal CPVC value is between 30% and 40%.Figure 2 shows the micrograph of cross-section ofthe coating with PVC of 30% and related EDS results. The epoxy coating appears darker than the steel substrate, which clearly distinguishes the interface. The coatingJ. Cent. South Univ. (2012) 19: 46−54 48Fig. 1 SEM micrographs of surface of coatings with different PVC: (a) 10%; (b) 30%; (c) 40%; (d) 60%Fig. 2 SEM micrograph (a) and EDS linear scanning of cross-section of coating with PVC of 30%: (b) Fe; (c) C; (d) Altightly adheres to the substrate, without any pores or defects at the interface. The matrix of the coating is compact, indicating that the double dip-coating process does not bring in delamination inside the coating. The thickness of the coating is approximately 20 μm. The EDS linear scanning was conducted to preciselydetermine the interface between the substrate and thecoating. The linear scanning direction is shown as the white arrow in the SEM micrograph in Fig.2. Three elements (Fe, C and Al) were chosen with their EDS results along the arrow listed in Fig. 2. The steep changesof the contents of three elements clearly show the interface labeled with the dash line.To identify the above conclusion about the CPVC value, EIS of the coatings was measured as another independent indicator. Bode diagrams of the coatings containing nano-sized aluminium powder with PVC from 10% to 80% after an immersion time of 3 h in 3.5% NaCl solution are shown in Fig. 3, and those of 120 h are shown in Fig. 4.Fig. 3 Bode diagrams of waterborne epoxy coatings containing nano-sized aluminium powder with different PVC after 3 h immersion in 3.5% NaCl solution: (a) Magnitude plots;(b) Phase plotsAs shown in Fig. 3(a), after 3 h exposure in 3.5% NaCl solution, the Bode magnitude plots of the undercritical coatings with PVC of 10% and 20% showthe same shape, and so do the curves of coatings with PVC from 50% to 80%, which are regarded to be overcritical. The spectra of the coatings with PVC of 30% and 40% have impedance between the above two groups of curves. The lower PVC coatings generally present much higher impedance than those with higherFig. 4 Bode diagrams of waterborne epoxy coatings containing nano-sized aluminium powder with different PVC after 120 h immersion in 3.5% NaCl solution: (a) Magnitude plots;(b) Phase plotsPVC, especially in the low frequency range. However,the Bode phase plots do not support such classification evidently, as shown in Fig. 3(b). All the curves have a capacitance arc in the middle frequency range (10−1−103 Hz). The curves of the coatings with PVC lower than 40% also show a sharp salient in the high frequency range, which are much steeper than those with higher PVC.The Bode magnitude plots of coatings with various PVC immersed for 120 h, as shown in Fig. 4, distinguishthe overcritical from the undercritical coatings much more clearly than that of 3 h immersion. The gaps between the undercritical and the overcritical coatingsare significantly widened, where the curves of coatings with PVC of 30% and 40% lay in the middle. Such classification can also be derived from the Bode phase plots. The Bode phase curves with PVC of 10% and 20% appear to be similar with those after 3 h exposure. The curves with PVC higher than 40% have only one visible capacitance arc, which shift to lower frequency compared with curves in Fig. 3, and become much more flatter in the high frequency range. The curves with PVCof 30% and 40% differ from the others. They feature thesalient in low frequency, which is similar with theovercritical PVC, and the soar in high frequency, which is alike with the undercritical PVC.Summarily, based on the analysis of the SEM images and the EIS curves, the CPVC value of the waterborne epoxy coatings containing nano-sized aluminium powder can be demonstrated between 30% and 40%.3.2 Corrosion resistance of coatings during immersionThe CPVC value can greatly affect the properties of the coatings, and is taken into consideration during the formulation. Generally, the ratio of PVC/CPVC is advised to be between 0.5 and 0.8, in order to get a better comprehensive performance [24]. Therefore, the coatings studied in the following immersion test were prepared with a PVC value of 30%.Figure 5 shows the EIS plots of the coatings with PVC of 30% immersed in 3.5% NaCl solution for different immersion time. From these curves, it is revealed that three successive stages are distinguished during the immersion process. In the first stage of the immersion process (0.5−5 h), there is only one capacitance arc on the Nyquist plot, which implies that the coating exhibits good barrier to prohibit the permeation of the corrosive species such as water, oxygen, and other ions towards the surface of the substrate. The Bode plot also presents a simple shape indicating a time constant in this stage.After 5 h immersion, the capacitance arc on the Nyquist plot changes as a semicircle, and another arc appears at the end of the semicircle, which implies that the reactions of the aluminium powder embedded in the coating have been detected. Moreover, a tiny tail appears at the end of the Nyquist curves, which is probably caused by the electrical conduction of the corrosion products of the aluminium powders, mainly the hydroxide and oxide of aluminium. It is generally considered that these precipitations gradually accumulate and block the micro-pores through which the corrosive media reach the interface of the coating and substrate, resulting in a kind of “healing” of the damage site of the coating. The height of the lg|Z|-plateau of Bode magnitude curves at low frequencies, which is generally used as an estimate for the pore resistance of the coating, declines with increasing the exposure time. On the Bode phase plots, the phase angle decreases greatly in the intermediate frequency range, compared with that of initial stage. A salient of the phase angle curves is observed in the low frequency range, and another relatively small one for the high frequency range. Therefore, more than two time constants are detected, which is confirmed in the following equivalent circuit simulation procedure. The EIS curves maintain theFig. 5 EIS plots of waterborne epoxy coatings containing nano- sized aluminium powder with PVC of 30% immersed in 3.5% NaCl solution for different times: (a) Nyquist plots; (b) Bode magnitude plots; (c) Bode phase plotssimilar shape until about 400 h, which implies that in this period the corrosion behaviors of the coatings share the same mechanism.After 400 h immersion, the pore resistance of the coating decreases significantly. On the Nyquist plot, the capacitive arc in the high frequency range shrinks to a small semicircle, while another one at low frequency enlarges relatively. Furthermore, the tiny tail disappears, indicating the destruction of the occluded structures produced by precipitations. A considerable change occursfor the shape of the Bode phase curves. The salient in the low frequency range becomes distinct and shifts to high degrees. The phase plateau at high frequencies, visible for the initial stage and not so visible for the middle stage, has completely disappeared, and the phase angle decreases directly and steeply to a large plateau near 0° which lasts until the middle frequencies. The above facts prove that the corrosive media such as water and ions have penetrated through the coating and reached the metallic substrate. Consequently, the semicircle in the low frequency range in the Nyquist plot is expected to change into an inclined line, which is regarded as a sign of diffusion process of substrate corrosion.Moreover, the equivalent circuit was used to fit the experimental EIS data. As recalled by KEDDAM et al [25], an organic coating with considerable thickness cannot be simplified as an intact capacitor, and the impurities from additives ruin the perfection of the coating for most cases. Therefore, the classical equivalent circuit as shown in Fig. 6(a) cannot fully reflect the coating structure during the whole immersion, except for the initial stage. In this stage, the coating has good barrier property which can be simulated by the circuit in Fig. 6(a) including the solution resistance R el,Fig. 6 Nyquist plots and fitting results using equivalent circuits of coatings immersed for different time: (a), (b) Initial stage (0.5 h);(c), (d) Middle stage (120 h); (e), (f) Final stage (600 h)J. Cent. South Univ. (2012) 19: 46−54 52the coating capacitance C c, the pore resistance of thecoating R p, the double layer capacitance C d and thecharge transfer resistance R ct. To get better simulationresult, the double layer capacitance C dl can be replacedby a constant phase element (CPE) Q dl. Using this circuit,the EIS data of the coating in initial stage are well fitted.Figure 6(b) represents a typical Nyquist plot (0.5 h) andits fitting results. From the fitting results, thecharacteristic parameters of the immersed coating areextracted, as listed in Table 2, together with the goodnessof the fitting. The pore resistance R p generally decreaseswith the immersion time in the initial stage, and so doesthe coating capacitance C c. This can be explained by thewater uptake and penetration of ions. These corrosivemedia break through the coating surface, reach thealuminium powders embedded in the coating, and reactwith them. The reaction products attach to the powder,which results in the increase of the charge transferresistance R ct, and prevents the corrosion to a certainextend.Table 2 Electrochemical parameters of coatings (PVC 30%) fordifferent immersion timeTime/ hC c /(F·cm−2)R p/(Ω·cm2)R ct/(Ω·cm2)Goodnessof fitting0.5 5 24 72 120 288 400 600 800 4.773×10−94.175×10−91.476×10−91.043×10−71.706×10−51.002×10−61.338×10−62.818×10−65.078×10−81.509×1067.317×1054.256×1051.637×1047.508×104575.1208.4108.131.385.933×1066.109×1068.819×1066.427×1052.486×1041.206×1051.317×1043 6382 5631.995×10−42.678×10−42.926×10−42.580×10−42.621×10−41.097×10−32.457×10−42.937×10−44.953×10−4With the increase of the immersion time, amounts of the corrosive media penetrate into the coating, and the occluded structures produced by precipitations as mentioned before start to influence the corrosion process. The dissimilar structures bring changes to the equivalent circuit. As shown in Fig. 6(c), a parallel combination of impurity structures capacitance C i and resistance R i is incorporated in series with R ct. Figure 6(d) shows the Nyquist plot with immersion time of 120 h and its fitting results. Three capacitive arcs appear and change the shape of the curve greatly. The arc in the high frequency range reflects the property of the unharmed coating, while the features of electrochemical reaction of aluminium powder and blocking effect of the occluded structures correspond to the ones at low frequencies. In this period, sharp decline of R p value is clearly observed, and R ct reaches its peak as shown in Table 2 and Fig. 7,Fig. 7 Evolution of coating capacitance C c, coating resistance R p, and charge transfer resistance R ct with immersion timewhich can be explained by the continual breakage of the coating integrity and the increasingly effective cathodic protection of the aluminium powders. From the facts above, the main corrosion resistance in this period is confirmed to be from the aluminium powder reaction. Studying the evolution of coating capacitance C c, a increscent tendency is observed, which means that water and other corrosive media penetrate much deeper in depth and larger in amount into the coating, and probably reach the metallic substrate under the coating at the end of this stage.Subsequently, the disbonding of the coating to the metallic substrate becomes severe due to the penetration of the corrosive media, gradually the occluded structures are overcome, and micro media-transfer pores generate at places where the coatings are broken down. The corrosion mechanism changes, and its representation in Nyquist plot is that the capacitive arc in the high frequency range shrinks in magnitude significantly, while another one at low frequencies turns to be a semicircle. In the end, the low-frequency arc has a good chance to become an inclined line, which means that the diffusion process has taken the major role of the corrosion mechanism. Therefore, a Warburg impedance W is needed to be added into the equivalent circuit, and the elements of the occluded structures should be deleted, as represented in Fig. 6(e). The Nyquist plot of coating immersed for 600 h is shown in Fig. 6(f) with its well fitted result. During the final stage, the main protective function comes from the blocking effect of the coating itself, which is incapable to well protect the substrate from corrosion. The values of R p and R ct in Table 2 and Fig. 7 decrease sharply, and the coating capacitance C c slowly increases.3.3 Neutral salt spray and adhesion testThe neutral salt spray test was applied to thecoatings with PVC of 30% and 40% to evaluate thecorrosion resistance according to ASTM B117. The test results of the two coatings (PVC 30% and 40%) before and after 800 h neutral salt spray are shown in Fig. 8. The chromatism of the coatings appearing in Fig. 8 is caused by different shooting conditions, and not related to any property change of the coatings. It is clearly observed that the coating with PVC of 30% shows a good corrosion resistance without any visible defects in comparison with the coating of PVC 40%. On the contrary, dark red corrosion products on the surface of the coating with PVC of 40% are found, which indicates that corrosive media have penetrated the coating matrix and reached the substrate. From the results, it is clearly shown that the coating with PVC slightly lower than CPVC (i.e. PVC 30%) exhibits good corrosion resistance during long exposure in aggressive corrosion environment.The cross-cut surfaces of the coatings with PVC of 30% (Fig. 9(a)) and 40% (Fig. 9(b)) after 400 hFig. 8 Appearances of coatings after neutral salt spray test with 5% NaCl solution: PVC 30% coating before (a) and after (b) 800 h salt spray; PVC 40% coating before (c) and after (d) 800 h salt sprayFig.9 Cross-cut surfaces of coatings with PVC of 30% (a) and 40% (b) after immersion in 3.5% NaCl solution for 400 himmersion in 3.5% NaCl solution are shown in Fig.9. The lines are clear, the edges and corners are trenchant, and no sign of flaking is detected, indicating good adhesion performance of the two coatings even after long time immersion.4 Conclusions1) The corrosion resistance of waterborne epoxy coating can be promoted by adding nano-sized aluminium powder as pigment. 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