class lecture-solar cell 高分子太阳能电池
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matter 有机太阳能电池有机太阳能电池(Organic solar cell)是一种研究中的太阳能技术,通过有机材料来转化太阳能为电能。
相比传统的硅太阳能电池,有机太阳能电池具有更低的制造成本、更轻薄灵活、更易于制造和处理等优点,因此被认为是未来太阳能技术的发展方向。
本文将介绍有机太阳能电池的工作原理、材料以及应用前景等方面。
有机太阳能电池的工作原理与传统的硅太阳能电池有所不同。
传统的硅太阳能电池是通过半导体材料中的PN结构来将太阳能转化为电能,而有机太阳能电池则利用了有机材料的光电效应来实现能量转换。
有机太阳能电池通常由两个电极、有机半导体材料以及电子传输材料组成。
当有机半导体材料吸收阳光中的光子时,会产生电子-空穴对。
这些电子-空穴对会沿着半导体材料的分子链传输到电极上,从而产生电流。
这种电流可以被集电极收集并用于外部电路。
与硅太阳能电池相比,有机太阳能电池的优势主要体现在其材料的特性上。
有机材料通常是由碳、氢、氧、氮等元素构成的,因此具有较低的制造成本。
此外,有机材料还具有较高的吸光度和较高的光电转化效率,可以更好地吸收阳光中的能量。
有机材料还可以以薄膜形式制备,因此电池可以更轻薄灵活,适应更广泛的应用场景。
然而,有机太阳能电池也存在一些挑战和限制。
首先,有机材料相对不稳定,容易受到环境的影响而发生降解。
其次,有机太阳能电池的光电转化效率相对较低,目前的研究重点是提高其效率。
此外,有机材料的长时间使用稳定性也需要进一步改进。
这些问题都是当前研究的热点和难点。
尽管有机太阳能电池仍然存在一些技术挑战,但其应用前景依然广阔。
有机太阳能电池的轻薄灵活特性使其可以应用于各种场景,例如可穿戴设备、移动充电器、户外设备等。
此外,有机太阳能电池还可以制备成不同形状和颜色的薄膜,可以应用于建筑物的外墙、窗户、屋顶等位置,实现建筑一体化太阳能利用。
此外,有机太阳能电池还可以与其他能量存储设备结合使用,实现太阳能的高效利用。
①Solar cell is also known as "solar cells" or "cell", is a kind of electricity generation by using sunlight directly photoelectric semiconductor wafer.In physics called solar photovoltaic, or pv.太阳能电池也被称为“太阳能电池”或“细胞”,是一种直接利用阳光发电的光电半导体薄片。
在物理学中称为太阳能光伏或pv。
②At the instant of the backlight irradiate, solar cells can produce voltage and current in the case of a loop.The solar cell is the device that through the photoelectric effect or photochemical effect transformed the light energy into electricity directly.Till now, working in the photoelectric effect of film type solar cell is the mainstream.即时的背光照射、太阳能电池能产生电压和电流的循环。
太阳能电池的设备是通过光电效应或者光化学效应直接把光能转化成电能。
直到现在,在光电效应工作的薄膜式太阳能电池为主流。
③The sun light on semiconductor p-n junction, to form a new hole - electron pair, the p-n junction built in under the action of electric field, light born cavitation flow p area, light electrons n area, after processing circuit will generate an electric current.This is how the photoelectric effect solar cell works.太阳光线在半导体pn结,形成新的洞——电子对的pn结内建电场的作用下,光生空穴流p区,光电子n 区域,经过处理电路将产生电流。
高分子材料在太阳能电池中的应用随着全球环境问题的日益突出,清洁能源的需求也越来越迫切。
太阳能作为一种绿色能源,被广泛应用于各个领域,特别是在发电方面。
太阳能电池是太阳能发电的重要组成部分,它是将太阳能转化为电能的装置。
高分子材料作为太阳能电池的主要组件之一,具有重要的应用价值和广阔的发展前景。
一、高分子材料在太阳能电池中的作用高分子材料在太阳能电池中主要作为光伏层的组成材料。
它能够吸收太阳光的能量,将其转化为电信号。
高分子材料也能够作为电极材料,传导电荷信号并输出电流。
另外,高分子材料还具有成本低、易加工等优点,这使得它在太阳能电池中的应用变得更加广泛。
二、高分子材料在不同类型太阳能电池中的应用根据太阳能电池的类型不同,高分子材料的应用也相应地有所不同。
1. 有机太阳能电池有机太阳能电池(organic solar cells,简称OSC)是一种基于高分子材料的新型太阳能电池。
其发展始于上个世纪八十年代初,近年来取得了很大的进展。
高分子材料在有机太阳能电池中主要作为光伏层的组成材料。
有机太阳能电池利用半导体高分子材料的光致发光作用,在光的照射下,高分子材料能够吸收能量,形成电子空穴对,最后通过电极输出电流信号。
有机太阳能电池具有成本低、制造工艺简单、可塑性强等优点,因此被广泛应用。
2. 硅太阳能电池硅太阳能电池是目前最常见的太阳能电池,利用半导体硅的光伏效应将太阳能转化为电能。
高分子材料在硅太阳能电池中主要作为封装材料和透明导电膜的材料。
高分子材料具有优异的防水、防氧化、耐强酸碱等性能,可有效保障硅太阳能电池的长期使用。
3. 热光伏太阳能电池热光伏太阳能电池(thermophotovoltaic solar cells,简称TPV)利用光子能够使电子转移到价带中的特性,将室温热能转化为电能。
高分子材料在热光伏太阳能电池中主要应用于光转换层和波导膜。
高分子材料的浓度受到温度变化较小的影响,因此可以保证太阳能电池的输出稳定。
全新版大学英语听说教程第四册听力原文TEST1PartAConversation 1:W: Have you got a job, Phil?M: Yeah, I do yard work for the people in the neighborhood, cutting grass, raking fallen leaves, planting trees and pulling out weeds, things like that.Q: What does Phil do?Conversation 2:M: The trees on our campus are really beautiful.W: You're right, and they are useful, too. They cut down on our need for air conditioning, don't you think?Q: What does the woman mean?Conversation 3:W: Professor Webster has a class this afternoon from 2:30 to 4. But he won't be able to make it because he's lost his voice.M: Does he want me to try to find somebody else to take his place?Q: What does the man mean?Conversation 4:M: Can you come to the concert with me this weekend, or do you have to prepare for the exams next week?W: Frankly speaking I still have a lot to do for the exams but maybe a break would do me good.Q: What will the woman probably do?Conversation 5:M: Have you heard the weather report for today?W: Yes. It says that the sandstorm is going to be very bad and we're advised to stay indoors. Q: What is the woman talking about?Part2DialogueW: Hello, University of Sidney. May I help you?M: Yes. I'm looking for information on courses in computer programming.W: Do you want a day or evening course?M: Well, it would have to be an evening course since I work during the day.W: Uh-huh. Have you taken any courses in data processing?M: No.W: Oh, well, data processing is a prerequisite course. You have to take that course before you can take computer programming.M: Oh, I see. Well, when is it given? I hope it's not on Tuesdays.W: There's a class that meets on Monday evenings at seven.M: Just once a week?W: Right. But that's almost three hours -- from seven to nine forty-five p.m.M: Oh. Well, that's all right. I could manage that. How many weeks does the course last?W: Let me see... oh, yes, twelve weeks. You start the first week in September and finish... oh... just before Christmas. December twenty-first.M: And how much is the course?W: That's 300 dollars, and that includes the necessary computer time.M: OK. By the way, is there anything that I should bring with me?W: No. Just your checkbook.M: Thank you so much.W: You're very welcome. Bye.M: Bye.PartCHealth experts have warned for many years that cigarette smoking can lead to heart disease, cancer and other medical problems. But smokers still find it extremely difficult to stop. The American Cancer Society decided to do something to help them kick this bad habit.Every year the group organizes a national non-smoking day in an attempt to get smokers to quit smoking. The organization is asking all smokers to stop smoking at least for 24 hours. They hope this will eventually enable many people to permanently kill the habit.The cancer society officials will give telephone callers advice on how to stop smoking. Smokers also can call a special telephone number to hear recorded messages by doctors.Some businesses will offer their workers candy or chewing gum to help them fight down the crave for smoking. Some companies are offering special gifts and lower prices to people who sign an agreement to stop smoking. And Americans who do not smoke are being asked to help just one person quit smoking during the 24-hour-campaign.PartDPassage 1Office systems are equipment used to create, store, process, or communicate information in a business environment. This information can be manually, electrically, or electronicallyproduced, duplicated, and transmitted.The rapid growth of the service sector of the world economy beginning in the mid-1970s has furnished a new market for sophisticated office automation.Most modern office equipment, including typewriters, dictation equipment, facsimile machines, photocopiers, calculators, and telephone systems as well, contains a microprocessor. With the increasing incorporation of microchips into office equipment, the line between the computer and other equipment has blurred.At the same time, computers, either stand-alone or as part of a network, and specialized software programs are taking over tasks such as facsimile transmission or fax, voice mail, and telecommunications that were once performed by separate pieces of equipment. In fact, the computer has virtually taken the place of typewriters, calculators, and manual accounting techniques and is rapidly taking over graphic design, production scheduling, and engineering design.The use of computers and other modern equipment has enabled links to be established far beyond the walls of a building. Electronic links allow people in a modern office to communicate with workers at home or in satellite offices. This capability has led to a sharp increase in telecommuting. Since the early 1990s workers have worked at least part of the time outside the main office. Managers and professional employees are the major participants in this trend. As they no longer have to spend hours traveling from home to office, their work productivity has increased.As technology advances further, new equipment will be invented and introduced into the modern office, which will result in even greater efficiency in office work.Questions:1.What do office systems refer to according to the passage?2. What has furnished a new market for sophisticated office equipment since the mid-19703. How have electronic links benefited professionals and managers?Passage 2When it comes to leisure activities, Americans aren't quite the fun-seekers they've been supposed to be. For one out of five, weekends and vacations are consumed by such drudgeries as house-cleaning, yard-working and cooking; only one-third of them enjoy the luxury of relaxing in the sun, going camping, playing sports, or simply relaxing.These are among the conclusions reached by a recent poll in which more than 1,120 employed Americans were asked how they occupy themselves on days they are not at work. According to the poll, older people, the rich, and the well-educated are most apt to spend their spare time doing the things they 'want to do' rather than those they 'have to'. Overall, high-salaried people were more active then those with lower incomes -- they reported watching less television and were more likely to engage in social and cultural activities. Furthermore, those with college degrees were about twice as likely as those with no more than a high school education to spend time playing sports (42% compared with 23%). On the subject of vacations, the study found that college graduates were more likely than those with only high school degrees to have vacation plans (80% versus 60%). Of those who did intend to take some time off, 46% planned a sightseeing vacation (34% in the UnitedStates, 12% abroad), 34% expected to visit friends or relatives, 22% headed for the beach or lake, and 12% intended to relax at home.People who are divorced, widowed, or separated, the survey concluded, are the least likely of any group to take a vacation -- and the least likely to attach any importance to it.Questions:1. What is the passage mainly about?2. How do most people in the US spend their vacation according to the passage?3. Which of the following adjectives best describes the passage?4. Which of the following can be inferred from the passage?Passage 3A movement to make US hotels smoke-free got a boost on Thursday when Woodfin Suite Hotels, owner of 18 hotels in 11 states, said its six California properties will go smoke-free starting September 1st.The announcement followed a similar move by Howard Johnson International Inc., which said in June that its hotel on Pocahontas Trail in Williamsburg, Va. would become the chain's first smoke-free property. And on August 1, Apple Core Hotels turned its 80-room Comfort Inn Midtown in New York City's Theater District into a no-smoking property.Hotel owners said they hope to make up for any lost business by winning over guests who prefer a smoke-free environment, but most admitted the move is largely experimental and traveler reaction will be closely watched before any major expansion of their programs. Apple Core Chief Operating Officer said his company decided to take the no-smoking plunge for a simple reason: demand."It has nothing to do with public policy," he said. "There's tremendous demand. People are very upset when they've been promised a smoke-free room and they get a smoked-in room instead."The handful of hotel owners who have taken the no-smoking plunge say the move will also help them save money in their housekeeping departments.The process of "de-smoking" a room -- eliminating all the negative effects when a room has been smoked in -- typically costs about $500 per room. Smoking rooms also face higher costs associated with more frequent carpet shampooing, curtain cleaning and minor repairs for such things as cigarette burns in fabrics, according to hotel managers.Furthermore, smoking rooms often take longer to clean than their no-smoking counterparts because they must be deodorized each day.It is also a benefit to the employees who can clean the rooms much faster. And employees who don't smoke won't get the smell. Even smokers complain when they walk in and get the smell of stale smoke.Despite the benefit of going smoke-free, however, many hotels may be reluctant to completely do away with smoking rooms in the near future. It will be more the personalpreference of the owner doing it, whereas the public company has to be more careful because it limits the demand.Questions:1. What does the passage mainly tell us?2. What do we know about Woodfin Suite Hotels?3. What is the main reason why some owners want to ban smoking in their hotels?TEST2PartAConversation 1:M: I have never heard such a fascinating lecture on solar energy. But you don't seem impressed. Don't you like it, Sally?W: Well, I must admit that I dozed off most of the time. I think it's too difficult for me to understand.Q: How did the woman feel about the lecture?Conversation 2:W: Thank goodness! You've finally arrived. The presentation started ten minutes ago. And I was just beginning to panic.M: Sorry I'm late. The traffic was extremely bad.Q: How did the woman feel when she saw the man?Conversation 3:W: I hear that you work part-time at a supermarket. What do you do there?M: I work in the produce section. I also stock shelves. Sometimes when it really gets busy, I help at the checkout counter.Q: What does the man occasionally do at his supermarket?Conversation 4:M: Mary, I've finally decided about my history paper. I'm going to focus on World War II.W: That's good, but you need to concentrate on one particular area. What about looking at thecourse of events in the Pacific?Q: What does the woman think of the man's topic?Conversation 5:M: To get an MA, you'll need thirty-six credit hours. Fifteen must be from the Education Department and fifteen from the Psychology Department. For the remaining six credit hours you have to write a thesis in about two thousand words.W: Hmm, that seems a lot, but I'm sure I'll manage.Q: What are the two speakers talking about?PartBFast ReadingAt 6:45 p.m. on the evening of Thursday 9th October, Miss Allen was returning from work to her home at 79 Winston Avenue. She had left work at 5:30 p.m. and stopped at the Fox and Goose public house in Market Street for a drink with a colleague. Miss Allen and her colleague had left the pub at 6:30 p.m. and Miss Allen had walked to the No.13 bus stop at the end of Market Street. While awaiting the arrival of the bus, she noticed a group of three youths loitering on the corner. The youths started to approach her, and she started to walk in the opposite direction. The footsteps behind her accelerated and a youth of about 19 years of age stopped her and asked her the time. As Miss Allen stopped and looked at her watch the youth seized her wrist, twisted her arm behind her back and forced her at knifepoint to surrender her handbag and her ring and bracelets. The two accomplices were encouraging their friend at this point. After Miss Allen gave the youth her handbag and her ring and bracelets the three quickly disappeared. Miss Allen was very shaken, but decided to walk to her home, a distance of about three miles, where she would alert the police. She arrived home at 7:40 p.m., only to discover that her flat had been hurriedly burgled. Clearly the muggers had found Miss Allen's keys in her handbag and had arrived before her to ransack her flat. Miss Allen later called the police to report the mugging and the burglary. In her handbag, there were 65 pounds in cash, her credit cards and checkbook and her keys. Two necklaces, several pairs of earrings, a camera and a portable CD player were stolen from her flat.PartCFor years almost everyone has believed that people lose some of their mental powers as they age. We have believed that old people have difficulty remembering and they think more slowly. Some even believe that old people have a reduced number of brain cells.Doctors are now saying that the loss of mental powers is not a sign of old age but of diseases. But Warner Shan, an expert on aging, says that some healthy elderly people seem to lose mental powers because they expect to lose some. They accept the idea that old people always lose intelligence, but studies have shown that if a person refuses to accept this idea and remains healthy, active and interested in life, his mental powers will not be affected. In fact, some kinds of intelligence continue to grow.The studies also show that old people who live with their families and have active lives increase in intelligence. People who live alone and withdraw from any kind of social life seem to lose mental ability.PartDPassage 1Lifestyle is the way a person lives; it includes work, leisure time, hobbies, other interests, and personal philosophy. One person's lifestyle may be dominated by work with few social activities. Another's may involve hobbies, recreational activities or personal philosophy. There is little doubt that lifestyles are changing and that these changes will have an impact on the way business operates in the years ahead. Several cases are causing lifestyle changes in some developed countries.First, there is more leisure time than ever before. The workweek is now less than forty hours, as compared with seventy hours a century ago. Some experts believe it will be twenty-five hours or less in a few decades. Several firms have adopted four-day workweeks with more hours per day. Others have cut down on the number of working hours each week. Reduced work schedules mean increased leisure time.Second, families have fewer children than before -- and young couples are postponing childbirth instead of having children early in the marriage. This trend has forced many businesses to modify their competitive strategies. Gerber Products Company used to advertise 'babies are our business -- our only business'. Now Gerber products include infant and toddler clothing, stuffed animals and accessories such as bottles, baby powder and so on. Third, people are better educated and more prosperous now than they were earlier. These advantages bring with them the freedom to question current lifestyles and examine new ones. Inquiries of this nature have sometimes led to personal lifestyle changes. Today's youth, for example, are not only better educated but more independent and individualistic than past generations.The business world is only beginning to realize how people's lifestyles can influence their behavior as employees, consumers and members of society.Questions:1. What does the passage mainly tell us?2. Which of the following can be inferred from the passage?3. What does the speaker say about today's youth?Passage 2Mountain climbers around the world dream about going up Mount Qomolangma. It is the highest mountain in the world. But many people who have climbed the mountain had left waste material that is harming the environment. The pollution is affecting populated areasnear the mountain.A team of Americans is planning the largest clean-up effort ever on Mount Qomolangma. They will make the risky trip up the mountain next month. The team of eight Americans will be guided by more than twenty ethnic Sherpas of Nepal. Their goal is to remove all the trash they see and send most of it back to the United States. They will spend two months moving up the mountain gathering oxygen bottles, fuel containers, batteries, drinks cans, human waste and other trash. They are expected to remove at least three tons of trash in large bags. Team leader Robert Hoffman is making his fourth trip up the mountain. He says he hopes to return Mount Qomolangma to the condition it was in before the first successful climb fifty years ago. He says he hopes the effort will influence other people to clean up the environment closer to home.Human waste on Mount Qomolangma is a major concern. So the clean-up team will take along with them newly developed equipment to collect and treat human waste. Over the years, the waste particles have polluted the mountain. In the warm season when the ice melts, the polluted water flows to Nepalese villages below. The problem has gotten worse in recent years because climbing Mount Qomolangma has become more popular.Since 1992 the government of Nepal has required climbers to bring down what they take up. But those rules were never fully carried out. And no one has ever been required to bring back their trash from the highest part of the mountain.Mount Qomolangma is part of the Himalayan mountain range. It is on the border between Nepal and Tibet, China. Edmund Hillary of New Zealand and Sherpa Tensing Norgay made the first successful climb in 1953. Since then, more than eight hundred people have successfully climbed the mountain. Some people who reached the top died on their way down. Many other people died before reaching the top, which is almost nine thousand meters high.Questions:1. Which of the following can best serve as the title of the passage?2. Which of the following is true?3. What's the American team's goal in going up Mount Qomolangma?4. What can be concluded from the passage?Passage 3According to popular belief, eccentrics are wealthy people who can afford to indulge their eccentricities on a grand scale. But nowadays eccentrics are just as likely to work at ordinary jobs. One man, for example, works in a bank from 9 to 5, but in his spare time carries a bow and arrow and thinks of his home as a leafy corner of Sherwood Forest. Another eccentric is a social worker but lives in a cave and does long charity walks wearing pajamas. A third spends all his time in bed and a fourth lives only on potatoes.Dr. David Weeks has found that such oddballs often have certain features in common. They are often the only or eldest child raised in strict homes. Many have strange eating or sleepinghabits. And although they are frequently impatient with other people, they are generally not competitive and hate sports. They are poor conversationalists, but are often highly educated and read far more than ordinary people. They are often creative and inventive, especially in the scientific field. Not surprisingly, eccentrics tend to live alone and they are more likely to be men. They outnumber women by two to one.If you're an eccentric, you'll be encouraged by Dr. Weeks' study. Eccentrics are less likely to be mentally ill than more conventional people are. And, in his view, they provide some harmless, welcome relief from ordinary people.Questions:1. Why does the speaker give three examples of eccentrics at the beginning of his talk?2. What can we learn about eccentrics from Dr. Weeks' study?3. What's Dr. Weeks' attitude toward eccentrics?。
General Mechanism in Organic Photovoltaic Cells(1) Photon absoption (ηA )(2) Generation of excitons(3) Exciton diffusion (ηdiff )(4) Hole-electron separation (ηTC )(5) Carrier transport towards the electrode (ηtr )(6) Charge collection at the respectiveelectrode(ηCC )General Scheme for Organic Photovoltaic EffectExamples on Polymer Phtovoltaic DevicesFirst Polymer-Polymerheterojunction PVEnergy conversion efficiency: 2.9 %Science1995Characteristics of Solar CellsAir Mass (AM)-A measure of how much atmosphere sunlight must travel through to reach surface. The intensity is fixed at 100W/cm 2. Open circuit voltage (V oc )Voltage across the cell in sunlight when no current is flowing.Short circuit voltage (I sc ) Current flows through an solar cell when there is no external resistance.Maximum power point (mpp) The maximum power is produced.Fill Factor (FF)Power conversionefficiency (PCE)mppCurrent ChallengesThe lower photocurrent is due to poor light absorption, generation and transport. The fill factor is due to poor transport and recombination.New device designs: Ordered Bulk HeterojuctionsImproving light harvestingSmall band gap polymer, dye-sensitized materials, light-trapping structures Improving charge transportCarrier mobility (10-2~10-5cm2/VS) is lowControl morphologyProcessing condition, self organization, synthesis of D-A block copolymer, use of porous films as templateAddressing manufacturing issue and improving stabilityBy encapsulating cells and more stable materialsUnderstanding device function and limits to performanceProspects for high-efficiency (>10%)Polymer PV cells–1. New device designs: Ordered Bulk Heterojuctions–Approach:Polymer Semiconductor/acceptor Order Heterojuction Structure–2. The high light-absorbing capabilities:–Conjugated polymer and electron acceptor with lower band gap: 350-900 nm (3.5~1.4eV)–Approach: Low Eg Polymer–3. Higher carrier mobilities:–Approach :高分子mobilities> 0.01 cm2/Vs and Morphology control Chem. Mater.2004, 16, 4533Four device architectures of conjugatedpolymer–based PV cells•Single Layer(a):Low EQE(0.1~1%) due to exciton recombination; low carrier mobility •Bilayers (b) :PA-PPV/TiO 225% EQE, 3.9 % power efficiency (435 nm); PPV/BBL 66%% EQE, 2% power efficiency •Bulk heterojunction (c) (d):–PPV/C60 Derivatives 70% EQE, 3.5% power efficiencyChem. Mater.2004, 16, 4533(a)(b)(c)(d)Bilayer DevicesOrganic Photovoltaic Device ArchitecturesOrganic Photovoltaic Device ArchitecturesBulk Heterojunction DevicesConcept of Polymer/Acceptor Photovoltaic DeviceEnergy levels and harvesting of energy from D/A interface within a PV cellBilayer cell due to complete phase separation : polymer domain size >> exciton diffusion length General rules for preparing efficient polymer-acceptor solar cellsVertical aligned Acceptor: polymer domain size <exciton diffusion lengthHigh balanced electron and hole mobility and large interfacial area of the bulk heterojunction . High extinction coefficient and absorb light from much of solar spectrum. Optimization of energy levels to promote charge separation and transfer. Form interconnected bicontinous solid dipersion and vertically aligned structure with polymer domain size <exciton diffusion lengthAdv. Colloid Interface Sci. 2008, 138, 1Absorption Spectrum of Organic MaterialsPhoton reflux from the sun (AM 1.5)TPTMax. IPCE: P3HT/PC61BM-63% at 540 nm P3/PC71BM-49% at 500nmThe presence of PC71BM can provide more photon current because it can absorb the photon beyond wavelength of 600nmCoplanar chromophoreb-PC61BM; c-PC71BMHigh absorption coefficient in comparison to P3HTKo et al., Macromolecules 2008, 41, 5519The broad absorption feature possibly due to the random copolymer structure of P2 which combine the absorbance of TPT rich and BT rich structuresThe PCBM domains (dark) are around 10nm and homogeneously distributed in the matrix The nanoscale phase separation between electron donor and acceptor allowing large areas of interface for better photogenerated chargesTPTb-PC61BM; c-PC71BMKo et al, J. Am. Chem. Soc. 2008, in pressD-A Conjugated Alternating Polymers:PCBM Solar CellsVoc = 0.76 V Voc = 0.72 V Isc = 3.1 mA/cm2 FF = 0.37 PCE = 1 % Isc = 4.31 mA/cm2FF = 0.49 PCE = 1.6 %Voc = 0.72 V Isc = 4.66 mA/cm2FF = 0.46 PCE = 2.2 %Voc = 0.56 V Isc = 3.6 mA/cm2FF = 0.49 PCE = 0.51 %D-A Conjugated Alternating Polymers:PCBM or C70 Solar CellsVoc = 0.54 V Isc = 1.76 mA/cm2 FF = 0.46 PCE = 0.3 % :PCBM Voc = 0.58 V Isc = 3.4 mA/cm2 FF = 0.35 PCE = 0.7 % :C70 Voc = 0.56 V Isc = 2.1 mA/cm2 FF = 0.32 PCE = 0.37 % :C70 :C70 :PCBM Voc = 0.61 V Isc = 2.4 mA/cm2 FF = 0.40 PCE = 0.59 % Voc = 0.78 V Isc = 3 mA/cm2 FF = N/A PCE = 0.9 %D-A Conjugated Alternating Polymers:PCBM Solar CellsVoc = 0.72 V Isc = 3.1 mA/cm2 FF = 0.37 PCE = 1 %Voc = 0.77 V Isc = 3.4 mA/cm2 FF = 0.42 PCE = 0.2 %Voc = 0.56 V Isc = 3.5 mA/cm2 FF = 0.58 PCE = 1.1 %Voc = 0.59 V Isc = 2.6 mA/cm2FF = 0.39 PCE = 0.6 %Voc = 0.61 V Isc = 0.2 mA/cm2FF = 0.24 PCE = 0.02 %If the Eg is too small, it would induce the electron/hole recombination and lower PCE. Also, the HOMO/LUMO energy level matching is also important.Importance of Polymer Morphology on Photovoltaic EfficiencyMorphology determining parameters: The spin casting solvent The composition between polymer and fullerene The solution concentration The controlled phase separation and crystallization induced by thermal annealing The chemical structure of the materialsDesign Rules for Donors in Solar Cell –Towards 10 % PCETo get PCE >10% Bandgap of donor polymer < 1.74 eV & LUMO < -3.92 eVThe importance of HOMO/LUMO level on the Photovoltaic DevicesImportance of donor HOMO and acceptor LUMOThe EA of the PTPQ, PTQ, PPyBT, and PTDA: 2.7~3.0 eV, mismatch with Al→ → poor PV efficiencyDidecyloxyphenylene-Acceptor Alternating Conjugated Polymers (solar cell eff.~0.4%)1.0Absorbance (a.u.)0.8 0.6 0.4 0.2 0.0 300Normalized Absorbance1 2a 2b 2c 2d1.0 0.8 0.6 0.4 0.2 0.0 3003a 3b 3c400500600700800900Wavelength (nm)400500600700800900Wavelenth (nm)Order of Eg : POC10-P < POC10-Q < POC10-Py < POC10-BT < POC10-TP (intramolecular charge transfer), 3b> 2b, 3c>2c: backbone planarity2Current density ( mA/cm )3b 3c 2aλmaxabs, PolymersfilmMobility On/off (cm2V-1s-1) 1.89×10-3 1.41×10-5 1.92×10-4 2.10×10-3 82 36 60421(nm) DP/TP DP/DTTP DP/DTBT0.0 0.2 0.4 0.6 0.80401,678 410, 638 413, 618 381, 549-1-2Voltage (V)DP/DTQ3600Chen and Jenekhe, Macromolecules, 2008Indolocarbazole-Acceptor Alternating Conjugated Polymers (Solar Cell Eff.~1.40%)O B O O N B O + N C12H25 N C12H25 N N N N Br N S Br S nMacromolecules 2009, vol.42, 1897.4K2CO3 (aq)/Toluene Pd(PPh3)4 N OB O39PIC-TP12Current Density ( mA/cm )39IC2C12H25C12H252 0 -2 -4 -6 -8 -10 0.0 0.2 0.4P28IC-TP12/PC61BM P28IC-TPO/PC61BM P28IC-BT/PC61BM P28IC-QO/PC61BM P28IC-QO/PC71BM P39IC-TP12/PC61BMP39IC-QO/PC61BMNO B O N+BrXBr NXn28ICS S N NX=N C12H25N C12H25NNNSNROORROOR0.60.828PIC-TP1228PIC-TPOR = 2-ethylhexyl28PIC-BT28PIC-QOR = 2-ethylhexylVoltage (V)TFT-Pristine polymer polymer P28IC-TP12 P28IC-TPO P28IC-BT P28IC-QO P39IC-TP12 P39IC-QO Mobility (cm2V-1s-1) 4.04x10-4 5.50x10-5 1.93x10-4 1.89x10-4 2.42x10-4 1.66x10-5 On/Off (–) 236 40 30900 46900 1180 50Solar Cell-Polymer/PCBM (1:4) Jsc (mA/cm2) 0.98 0.98 2.11 3.15 (4.46)a 2.45 1.53 Voc (V) 0.49 0.35 0.55 0.66 (0.65)a 0.60 0.67 FF (%) 0.45 0.41 0.42 0.42 (0.48)a 0.45 0.32 PCEb (%) 0.22 0.14 0.49 0.87 (1.40)a 0.66 0.32NewQuinoxaline based Donor-Acceptor Conjugated PolymersFor Optoelectronic Applications Highest Solar Cell PCE :1.76%M1OS * S *ONN*OOC10H21 N N S *OS C10H21OMn=22308 PDI=2.38 HOMO= -5.18 eV LUMO= -3.60 eV Mobility 9.25x10-4 On/off 2.31x104Mn=8590 PDI=1.67 HOMO= -4.91 eV LUMO= -3.03 eV Mobility 4.71x10-5 On/off 4.07x103O OOOM3N S N*N SN S*Mn=4003 PDI=1.26 J. Polym. Sci. Polym. Chem. 2009, Through the collaboration of W. C. Chen and F. C. Chen HOMO= -5.06 eV LUMO= -3.36 eV Mobility 9.25x10-4 On/off 2.3x104Mn=8450 PDI=1.76 HOMO= -5.06 eV LUMO= -3.19 eV Mobility 2.52x10-4 On/off 2.00x104The importance of HOMO/LUMO level on the Photovoltaic DevicesTheoretical PCE ~10% in a single PV cell: Bandgap of donor polymer < 1.74 eV & LUMO < -3.92 eV using PCBMTheoretical PCE up to 15% By Tandem cell Adv. Mater 2008, 20, 579-583Scharber et al., Adv. Mater. 2006, 18, 7894.26.13.4 2.75.15.3 Cs CO Inverted semi-tranparent OPVsJ-V characteristics12 nm ALD HfO2 or 5μm PVDCALD Al2O3AlP3HT:PCBMPEDOT:PSSITO。