Silica Aerogel-Synthesis and Applications

KH550的水解工艺及其对Si02表面改性的研究第39卷第2期2012正北京化工大学(自然科学版) JournalofBeijingUniversityofChemicalTechnology(NaturalScience)V oI.39.No.22O12KH550的水解工艺及其对SiO2表面改性的研究高正楠江小波郭锴(北京化工大学教育部超重力工程研究中心,北京100029)摘要:用电导率在线测量法和红外光谱法研究了硅烷偶联剂3一氨丙基三乙氧基硅烷(KH550)的水解工艺.采用共沸蒸馏和溶剂置换方式置换出湿凝胶中物理吸附水,并用KH550水解液对SiO 湿凝胶进行了改性.通过红外光谱(FT—IR),邻苯二甲酸二丁酯(DBP)吸油值,粒度分析仪和接触角测定仪等方式对改性效果进行了表征.结果表明,采用KH550对SiO湿凝胶进行改性后,产品的接触角显着提高,吸油值增大70%以上,孑L容为未改性样品的2倍,有机相中的分散性显着提高.同时,对比共沸蒸馏和溶剂置换两种方式,共沸蒸馏得到疏水性更好的超细SiO,,改性后样品的接触角可以达到140.以上.共沸蒸馏过程中,当改性剂KH550用量为超细SiO绝干粉重的17.5%(质量分数)时,改性效果最好.关键词:KH550;超细SiO,;共沸蒸馏;溶剂置换中图分类号:TQ127.2引言超细SiO:作为一种重要的无机化工产品,可应用于橡胶,吸附剂,涂料,化妆品,药物,医学诊断,功能材料等许多领域.但是由于SiO,表面羟基的存在,使其表现亲水性,在有机介质中难以润湿和分散,与有机基体之间结合力差,使复合材料性能降低,限制了产品的实际应用.因此需要对其进行改性,减弱SiO表面的极性,提高粉体与有机分子的相容性和结合力.目前大多数文献报道的有关液相沉淀法制备SiO的改性,都是对已制备粉体的改性.而SiO:湿凝胶在干燥过程中,伴随水分的脱除,凝胶网络结构出现坍塌,很容易造成硬团聚.由此制备的改性产品,分散性较差,在一定程度上影响改性效果..,同时由于对粉体进行了重复处理,也会造成资源的浪费.克服凝胶表面结构坍塌可以采用表面张力较小的溶剂代替湿凝胶网络孔道中的水,避免团聚现象¨.3-氨丙基三乙氧基硅烷(KH550)是一种较好的无机粒子表面改性剂,可用于SiO表面修饰.经KH550改性后的颗粒均取得了较好的效收稿日期:2011一l1—21第一作者:女,1988年生,硕士生通讯联系人E—mail:**************果,粉体与有机分子的相容性提高.本文采用电导率在线测量方法研究了硅烷偶联剂KH550的水解工艺,同时采用溶剂置换和共沸蒸馏置换凝胶孔道中的水分,并使用KH550水解液对产品进行湿法改性.通过对比改性前后样品性能, 分析KH550对SiO的改性效果.1实验部分1.1主要仪器及药品恒温水浴锅,上海树立仪器仪表公司;DZG-403型真空干燥箱,天津天宇技术实业公司;FW一100型高速粉碎机,天津泰斯特仪器有限公司;MP521型pH/电导率仪,上海三信仪表厂.SiO湿凝胶,自制,含水量92%～93%(质量分数),pH7～8;KH550,电导率0.05IxS/cm,国药集团化学试剂有限公司;无水乙醇,电导率2.0itS/ cm,北京化工厂;去离子水,电导率0.4I~S/cm;正己烷,正丁醇,分析纯,北京化工厂.1.2KH550水解实验按照KH550与去离子水体积比为1:1,加入乙醇溶液,配制不同体积分数的KH550水解液,磁力搅拌进行混合,室温条件下进行水解,通过电导率仪在线测量KH550水解过程,讨论水解液,水解浓度对水解状况的影响.1.3超细Sio:改性称取适量硫酸沉淀法制备的SiO:湿凝胶,直接北京化工大学(自然科学版)进行干燥,得到未改性产品.取适量SiO,湿凝胶,采用乙醇置换3次,然后使用正己烷置换,置换后的凝胶加入KH550水解液进行改性,得到的产品洗涤干燥后得到溶剂置换产品;另称取一定量的湿凝胶, 加入正丁醇,搅拌加热蒸馏,脱除滤饼中大部分水,持续加热至体系温度升至正丁醇沸点,此时产品已变成粉末,然后加入KH550水解液进行改性,洗涤, 抽滤,干燥得到共沸改性产品.1.4分析表征用美国Nicolet60一SXB型FT—IR光谱仪进行红外分析;用美国康塔公司QuadrasorbSI型全自动比表面和孔隙度分析仪测定比表面积和孔分布;用英国Malven公司ZETASIZER-3000HS型粒度分析仪, 测定改性前后样品在有机相(乙醇)中的粒度分布;邻苯二甲酸二丁酯(DBP)测定吸油值;德国Kruss公司K100C型全自动表面界面张力仪测定水滴在SiO,粉体压片上的接触角.采用滴定法测定SiO表面羟基数.称取样品2.0g于400mL烧杯中,加入250mL20%的NaC1 溶液,搅拌均匀后,用0.1mol/L的HC1标准液调节试液pH为4,这一步耗用的酸碱量不计.然后用0.1mol/L的NaOH标准液以每S2～3滴速度对上述试液进行滴定,到试液的pH=9,保持5min不变后即为终点.计算每nmSiO:表面积上的羟基个数n n:(×了V)胁1010(1)I—了J(1)式(1)中:S为样品的比表面积,m/g;V为0.1mol/L NaOH滴定体积,mL.2结果与讨论2.1KH550水解条件的确定采用电导率(y)测定法对硅烷偶联剂水解程度进行检测.由于硅烷偶联剂和去离子水的电导率较低,而水解产物硅醇和醇的电导率相对较高.因此,在KH550水解过程中,伴随硅醇的产生,电导率将逐渐增大,一定时间后水解反应达到平衡时,相应的电导率会稳定在某一值.图1是KH550水解和醇解过程中电导率随时间的变化规律.实验发现KH550在无水乙醇溶液中很快形成均匀透明的溶液.观察电导率随时间变化规律,反应初期电导率有些许升高,随后电导率变化非常小,这表明反应初期KH550与无水乙醇中的水分发生了反应,水分消耗完,电导率基本保持不变.按照水解平衡原理,水解过程产生醇,醇的加入应该会抑制硅烷偶联剂的水解,不利于生成硅醇. 因此可知,醇解过程中乙醇只是起到溶解的作用….同时,观察KH550在水溶液中的水解过程,可以发现,水溶液中KH550水解完全的时间极短, 而且硅醇之间很容易发生缩聚,使改性效果变差. 为增大完全水解的时间,根据反应动力学,可以在体系中加入醇,抑制其水解速度.因此,KH550水解溶剂选择一定配比的水醇混合溶剂.图1KH550水解和醇解过程电导率变化Fig.1ConductivitychangesofKH550during hydrolysisandalcoholysis图2显示了不同体积分数()的KH550水解完全时电导率变化.随着溶液中KH550体积分数的增加,达到的最大电导率先增加后减小.KH550 体积分数较小时,KH550用量的增加使体系中水解产生的硅醇增多,电导率增加;当KH550含量达到一定值时,水解生成的硅醇过多,硅醇缩合生成硅氧烷的几率增大,电导率降低.因此,最佳KH550体积分数应选择在15.75%附近.图2不同体积分数的KH550水解液电导率变化Fig.2Conductivitychangesfordifferent volumefractionsofKH550用傅里叶变换红外光谱仪检测水解前后特征基团的变化,结果如图3所示.第2期高正楠等:KH550的水解工艺及其对SiO:表面改性的研究40003O002o00lo000O'/cm一'1一KH550样品;2--水解0.5h后的KH550浴掖图3KH550和水解0.5h的红外光谱图Fig.3IRSpectraofpristineKH550andKH550afterhydrolysisfor0.5h图3中2974cm～,2887cm～,1457cm～,1378cm～,1079emI1处的谱带为si一0一cHCH基团的特征峰.3400cm和1616cm代表了N—H的伸缩和弯曲振动.水解0.5h后,3400cm处吸收峰变宽,可能是改性剂中N—H的伸缩振动和水解后Si—OH基团的伸缩振动发生重叠,KH550水解过程出现硅羟基.2.2改性前后SiO:粉体表征2.2.1粉体结构样品各官能团可以通过文献上的FT—IR数据得到.图4给出了改性前后样品的红外光谱图.40o03O002o0ol0oO0ocma一未改性样品;b--共沸改性;c一溶剂置换改性图4改性前后样品红外光谱图Fig.4IRspectraofunmodifiedandmodifiedsilica图4中3450cm～,1100cm和950cm处的吸收带分别代表了SiO:表面Si—OH伸缩振动,反对称伸缩振动及弯曲振动.1200～1100cm和467m处的密集带代表si—O—si反对称伸缩振动和弯曲振动.3437ClXl和1630cm附近的吸收峰分别代表水分子(包括表面的吸附水和结构水)的O—H和H一0H的伸缩振动和弯曲振动.经共沸蒸馏和溶剂置换后,采用改性剂KH550对产品进行改性,2850～2950cm区域内出现较弱的光谱带,代表了改性基团一cH的c—H伸缩振动峰.2.2.2粉体性能在相同改性介质中,采用溶剂置换和共沸蒸馏两种方式对湿凝胶进行处理,利用水解后的硅烷偶联剂KH550对样品进行改性,改性后粉体性能如表1.从表1数据可以看出经改性处理后的超细SiO粉体的比表面积比未改性样品有所减小.SiO:是一种具有一定微孑L结构的物质,氮吸附法测定的比表面积包括粒子外表面和内微孔的表面积.由于改性过程中表面改性剂在外表面和孔内部的吸附,造成改性后比表面积的减少.表1KH550不同改性方式样品数据Table1PropertiesofKH550afterdifferentmodification processes通过动态氮气吸附容量法测定3种样品的孔容,结果如表1所示.改性后样品孔容较改性前变大.观察图5共沸改性前后样品孔径分布,未改性样品a(3～10rim)孔径分布范围较窄,平均孔径为6.63nm,相比之下,采用共沸蒸馏改性样品b的孔径分布主要集中在3～50nm之间.这主要是由于共沸蒸馏和溶剂置换两种方式置换出了滤饼中大部分水分,减少了干燥过程中水分蒸发造成的孔道坍塌,使大部分中孔和一些大孔得以保留.a一未改性样品Ib一共沸蒸馏改性样品图5改性前后SiO孔径分布Fig.5Poredistributionsofunmodifiedandmodifiedsilica第2期高正楠等:KH550的水解工艺及其对SiO表面改性的研究?l1? 但是溶剂置换过程中消耗的有机溶剂量较大,置换时间较长.综合来看,共沸蒸馏改性效果要优于溶剂置换改性.图8KH550不同改性方式沉降体积变化趋势Fig.8SedimentationvolumechangeforKH550 modifiedbydifferentmethodsT口'鲁宕料蚓世图9KH550不同改性方式沉降速率变化趋势Fig.9SedimentationratechangeforKH550 modifiedbydifferentmethods2.4改性剂用量对改性效果的影响图l0研究了采用共沸蒸馏水浴加热65℃,反应2h,改性剂KH550用量对表面羟基数的影响.由图1O可以看出随着改性剂用量的增加,表面羟基数逐渐减少,改性剂KH550用量为17.5%(质量分数)左右时,表面羟基数最小,改性效果较好.随着改性剂用量的继续增大,KH550水解产生硅醇的数量相对较多,硅醇缩合为硅氧烷的几率增大,不利于改性,出现了改性剂用量为23%左右时表面羟基数增大的情况.3结论(1)KH550适宜的水解条件为:采用水/乙醇混合溶剂,KH550水解体积分数为l5.75%.(2)KH550改性SiO后得到了大孔径,疏水性能良好的改性产品,分散性提高.对比不同的改性w(KH550)/%图10共沸KH550不同改性剂用量对表面羟基数的影响Fig.10Effectoftheamountofmodificationagentonthe hydroxylnumberofthesilicaSurface方式,共沸蒸馏改性效果要明显优于溶剂置换改性.采用共沸蒸馏改性,KH550质量分数为17.5%时,改性效果最好.参考文献:[1]NozawaK,GailhanouH,RaisonL,eta1.Smartcontrol ofmonodispersest/~bersilicaparticles:effectofreactant additionrateongrowthprocess[J].Langmuir,2005,21:1516—1523.[2]RahmanlA,JafarzadehM,SipautCS.Synthesisofor- gano?functionalizednanosilicaviaCO??condensationmodifi-? cationusing-aminopropytriethoxysilicane(APTES)[J].CeramicsInternational,2009,35:1883—1888.[3]刘琪,崔海信,顾微,等.硅烷偶联剂KH一570对纳米二氧化硅的表面改性研究[J].纳米科技,2009,6(3):15—18.LiuQ,CuiHX,GuW,eta1.Surfacemodificationof nano—silicabysilaneeouplingagentKH一570[J].Nano—science&Nanotechn01ogy,2009,6(3):15—18.(in Chinese)[4]解小玲,郭睿劫,贾虎生,等.KH一550改性纳米二氧化硅的研究[J].太原理工大学,2008,39(1):26—28.XieXL,GuoRJ,JiaHS,eta1.Studyonnano—scale silicamodificationbyKH?550[J].JournalofTaiyuan UniversityofTechnology,2008,39(1):26—28.(in Chinese)[5]吴海艳,周莉,臧树良.纳米二氧化硅表面改性的研究[J].矿冶,2010,19(4):49-52.WuHY,ZhouL,ZangSL.Surfacemodificationofnano?silica[J].Mining&Metallurgy,2010,19(4):49-52.(inChinese)[6]林金辉,王美平,魏双凤.超细SiO:的化学沉淀法制备及其原位改性[J].硅酸盐通报,2007,26(4):12?北京化工大学(自然科学版)2012在[7][8][9]842—844.LinJH,WangMP,WeiSF.Preparationandin—situ modificationofuhrafineSiO2bychemicalprecipitation method[J].BulletinoftheChineseCeramicSociety, 2007,26(4):842—844.(inChinese)姚明明,姚欣.疏水性二氧化硅气凝胶的常压制备与表征[J].广东化工,2010,37(1):5-8.Y aoMM,YaoX.Preparationandcharacterizationcfhy—drophobicsilicaaerogelatambientpressure[J].Guang dongChemicalIndustry,2010,37(1):5—8.(inChi—nese)WuZJ,XiangH,KimT,eta1.Surfacepropertiesof submicrometersilicaspheresmodifiedwithaminopropyl—triethoxysilaneandphenyltrieth0xysilane[J].Journalof ColloidandInterfaceScience,2006,304:119—124.赵光磊,郭锴,王宝玉,等.超重力硫酸沉淀法白炭黑的连续化生产研究[J].无机盐工业,2009,41(9):34—36.ZhaoGL,GuoK,WangBY,eta1.Studyc11continu- OUSproductionofsilicabyhypergravitysulfuricacidpre—cipitationmethod[J].InorganicChemicalsIndustry,2009,41(9):34—36.(inChinese)[10]潘懋.滴定法测定气相法白炭黑比表面积的讨论[J].[12]化学世界,1993(8):380—383.PanM.Discussionontitrationmethodforsurfacearea determinationoffumedsilica[J].ChemicalWorld,1993(8):380—383.(inChinese)王斌,霍瑞亭.硅烷偶联剂水解工艺的研究[J].济南纺织化纤科技,2008(2):25—27.WangB.HuoRT.Studyonhydrolysisofsilanecouplingagem[J].JinanTextileTechnology,2008(2):25—27.(inChinese)ZhuravlevLT.Thesurfacechemistryofamorphoussili—ca.Zhuravlevmodel[J].ColloidsandSurfacesA:Phys—icochemicalandEngineeringAspects,2000,173:1—4.Studyofthehydrolysisof3-aminopropyltriethoxysilane(KH550) andthesurfacemodifiicationofsilica GAOZhengNanJIANGXiaoBoGUOKai fResearchCenteroftheMinistryofEducationforHighGravityEngineeringandTechnology BeijingUniversityofChemicalTechnology,Beijing100029,China)Abstract:Throughmonitoringthechangeinconductivityduringthehydrolysiscf3一aminopropyltriethoxysilane(KH550)andusingFT—IRspectroscopy,theoptimumconditionsf0rthehydrolysisofKH550wereinvestigated. Wetsilicagelfromwhichthephysisorbedwaterwasremovedbyazeotropicdistillationorrapi dsolventreplacementwastreatedwithKH550.TheproductswerecharacterizedbyFouriertransforminfraredspect roscopy(FT-IR),di—n—butylphthalate(DBP)oilabsorption,laserparticlesizeanalysisandcontactanglemeasureme ntsinorderloin—vestigatetheeffectofmodification.Theresultsshowedthatthecontactanglecfthemodifiedsi licaincreased,and theDBPabsorptionvaluesignificantlyincreasedbymo/ethan70%comparedtotheunmodifi edproducts.Theporevolumewastwicethatoftheunmodifiedsilica.Theamountofproductsintheorganicphaseals oincreasedsignifi—cantly.Theazeotropicdistillationmethodforwetgelmodificationaffordedmorehydrophobi csilicathanlhesolventreplacementmethod.andthecontactanglebetweenmodifiedsilicaandwaterreachedashigh as140..Theoptimal conditionsforsilicamodificationinvolvedamodifiermassfractionof17.5%oftheweightofs ilicaandtheuseofazeotropicdistillation.Keywords:3-aminopropytriethoxysilane;ultrafinesihca;azeotropicdistillation;solventre placement。

正己烷对溶胶-凝胶过程及常压干燥工艺制备SiO 2气凝胶的影响卢斌;张丁日;卢孟磊【摘要】以正硅酸乙酯(TEOS)为硅源，三甲基氯硅烷(TMCS)为表面修饰剂，采用酸碱两步催化溶胶−凝胶法和常压干燥法，通过在凝胶中填充适量正己烷(N-hexane)控制溶胶−凝胶过程，使凝胶孔洞趋于均匀，提高凝胶溶剂置换和表面改性效率，制备高性能SiO2气凝胶，制备工艺周期为30 h。

采用BET，SEM和FT-IR等对样品进行表征。

研究结果表明：正己烷填充量为0.2(TEOS与N-hexane物质的量比为1：0.2)，制备周期最短，制备出的样品具有最大比表面积(972.5 m2/g)、最大孔容(2.9 cm3/g)和最小密度(0.08 g/cm3)，疏水性最佳。

%Silica aerogels were prepared with TEOS as raw material by sol-gel method, surface modification of TMCS and ambient pressure drying within 30 h. Appropriate amount of N-hexane was filled into silica gel to improve efficiency of sol-gel and surface modification process. The structures of samples were characterized by means of BET, SEM and FT-IR etc. The results show that when filler content of N-hexane is 0.2(molar ratio of TEOS to N-hexane is 1:0.2), hydrophobic silica aerogels has low apparent density (0.08 g/cm3), high surface area (972.5 m2/g) and high pore volume (2.9 cm3 /g).【期刊名称】《中南大学学报（自然科学版）》【年(卷),期】2015(000)006【总页数】7页(P2020-2026)【关键词】SiO 2气凝胶;溶胶-凝胶法;常压干燥法;正己烷;胶粒双电层结构【作者】卢斌;张丁日;卢孟磊【作者单位】中南大学材料科学与工程学院，湖南长沙，410083;中南大学材料科学与工程学院，湖南长沙，410083;中南大学材料科学与工程学院，湖南长沙，410083【正文语种】中文【中图分类】O648二氧化硅气凝胶具有极高的比表面积(800~1 500 m2/g)、极大的孔洞率(85%~99%)、极低的热传导率(5 mW/(m·K))和独特的声学性能等，因此，在很多领域发挥重要作用，如用作高性能催化剂、保温涂料、超绝热材料、窗体材料等[1−4]。

SiO2气凝胶骨架增强研究进展李明; 陈跃【期刊名称】《《湖北理工学院学报》》【年(卷),期】2019(035)005【总页数】6页(P59-64)【关键词】SiO2气凝胶; 增强; 纤维; 复合【作者】李明; 陈跃【作者单位】湖北理工学院材料科学与工程学院湖北黄石435003【正文语种】中文【中图分类】TB321SiO2气凝胶(Silica Aerogel)是一种由纳米级基元颗粒构成，具有三维多孔网络骨架的非晶态固体材料[1]。

SiO2气凝胶三维网络骨架由一次粒子和二次粒子构成，其典型结构如图1所示，二次粒子之间以Si-O键相互连接，并以点接触的方式形成“项颈”结构，粒子之间通过连续、无序地延伸构成三维多孔网络骨架主体[2-3]。

SiO2气凝胶骨架间充斥着大量介孔孔隙(2～50 nm)，气孔率高达99.8%，因而具有众多特殊性能，比如低密度(0.03～0.35 g/cm3)、低热导率(常温下0.02～0.09 W/(m·K))、高比表面积(600～1000 m2/g)、低折射率(1.02～1.08)等性质[4-5]。

图1 SiO2气凝胶典型结构图1 SiO2气凝胶的应用领域SiO2气凝胶在保温隔热、催化吸附等领域具有广泛的应用价值。

比如，SiO2气凝胶可作为隔热保护衬板，抵挡宇宙飞船或者航天飞机在穿越大气层时产生的白炽高温，阻隔大型舰艇的蒸发器、锅炉等高温系统向舱内散热，以及用于液化天然气(Liquefied Natural Gas, LNG)工程或其他低温建设项目的防“漏热”处理等。

SiO2气凝胶在日用保温领域也已有一些应用，比如气凝胶保温杯套、气凝胶防寒服、高山靴保暖层。

在催化吸附领域，SiO2气凝胶高比表面积及多孔结构的特点可将其作为吸附剂、催化剂及催化剂载体应用于工业或生物医药行业。

例如，利用SiO2气凝胶作为Fe2O3或TiO2的载体制备工业催化剂[6-7]，作为药物的搭载工具[8]等。

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万方数据万方数据万方数据万方数据万方数据万方数据万方数据万方数据万方数据甲烷干重整研究进展作者：赵健， 周伟， 汪吉辉， 马建新， ZHAO Jian， ZHOU Wei， WA NG Ji-hui， MA Jian-xin作者单位：赵健,汪吉辉,ZHAO Jian,WA NG Ji-hui(华东理工大学资源与环境工程学院,上海200237;同济大学新能源汽车工程中心,上海201804)， 周伟,马建新,ZHOU Wei,MA Jian-xin(同济大学新能源汽车工程中心,上海201804;同济大学汽车学院,上海201804)刊名：天然气化工英文刊名：Natural Gas Chemical Industry年，卷(期)：2011,36(6)1.程金民;黄伟;左志军碳化终温对碳化钼的制备及甲烷二氧化碳重整催化性能的影响[期刊论文]-高等学校化学学报2010(01)2.Hanif A Study on the structure and formation mechanism of molybdenum carbides[外文期刊] 2002(03)3.Nagaoka K;Takanabe K;Aika K I Influence of the reduction temperature on catalytic activity of Co/TiO2 (anatase-type) for high pressure dry reforming of methane[外文期刊] 2003(01)4.Ghorbanzadeh A M;Lotfalipour R;Rezaei S Carbon dioxide reforming of methane at near room temperature in low energy pulsed plasma 20095.Zhang J;H Wang;A K Dalai Development of stable bimetallic catalysts for carbon dioxide reforming of methane [外文期刊] 2007(02)6.史克英;商永臣天然气二氧化碳转化制合成气的研究:Ⅸ.反应机理 1998(01)7.陈文艳环境友好条件下甲烷等离子体重整制氢的研究[学位论文] 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黄冈市人民政府关于颁授黄冈市第十届自然科学优秀学术论文的通报正文：----------------------------------------------------------------------------------------------------------------------------------------------------黄冈市人民政府关于颁授黄冈市第十届自然科学优秀学术论文的通报各县、市、区人民政府，龙感湖管理区、黄冈高新区管委会、黄冈白潭湖片区筹委会、白莲河示范区管委会，市直各单位：近年来，全市广大科技工作者潜心钻研，大胆创新，取得了一批自然科学成果及优秀学术论文。

为进一步营造崇尚科学、尊重知识、尊重人才、鼓励创造的科学文化氛围，鼓励全市科技工作者不断加强学术创新，更好地服务于黄冈市高质量发展，经各县（市、区）科协、市直各有关单位推荐、初评，经黄冈市第十届自然科学优秀学术论文评审委员会评审确定，并经公示无异议，市政府同意颁授万柳撰写的《Nitrogen, sulfur co-doped hierarchically porous carbon from rape pollen as high-performance supercapacitor electrode》、万美南撰写的《Observation of reduced phase transition temperature in N-doped thermochromic film of monoclinic VO2 》、丁秀娟撰写的《超声引导下置入PICC导管异位的原理分析及护理体会》等250 篇论文为黄冈市第十届自然科学优秀学术论文。

希望获奖的同志珍惜荣誉，再接再厉，不断探索奋进，在各自工作领域作出新的更大成绩。

市政府号召全市广大科技工作者要以优秀论文撰写者为榜样，进一步解放思想，紧紧围绕我市经济社会发展中的重大课题，深入研究，克难攻关，锐意进取，勇于创新，为推动黄冈在湖北高质量发展中力争上游作出新的更大贡献。