metal-organic papers Acta Crystallographica Section E Structure Reports Online
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Mg掺杂BaTiO3介电陶瓷中氧空位缺陷的EPR监控第35卷⼀第1期⼀吉⼀林⼀化⼀⼯⼀学⼀院⼀学⼀报Vol.35No.1⼀2018年1⽉JOURNALOFJILININSTITUTEOFCHEMICALTECHNOLOGYJan.⼀2018收稿⽇期:2017 ̄10 ̄23基⾦项⽬:国家⾃然科学基⾦项⽬(21271084)?吉林省科技发展计划项⽬(20121825)?长⽩⼭学者特聘教授⽀持计划(2015047)作者简介:郑永顺(1993 ̄)?男?吉林梅河⼝⼈?吉林化⼯学院研究⽣?主要从事⽆机介电陶瓷材料⽅⾯的研究.?通信作者:路⼤勇?E ̄mail:dylu@jlict.edu.cn⼀⼀⽂章编号:1007 ̄2853(2018)01 ̄0040 ̄04Mg掺杂BaTiO3介电陶瓷中氧空位缺陷的EPR监控郑永顺?路⼤勇?(吉林化⼯学院材料科学与⼯程研究中⼼?吉林吉林132022)摘要:在烧结温度Ts=1400?下?采⽤固相反应法制备(Ba1-xMgx)TiO3(x=0.015)和Ba(Ti1-xMgx)O3(x=0.015)陶瓷.以电⼦顺磁共振(EPR)技术作为关键技术?研究了陶瓷的点缺陷.结果表明:BMT为六⽅和伪⽴⽅钛酸钡结构的混合相?BTM为六⽅和四⽅钙钛矿结构的混合相.在低于-100?的菱⽅相中?探测到与氧空位相关g=1.956的EPR信号?且Ba空位⼆Ti空位和O空位共存.关键词:镁掺杂钛酸钡?X射线衍射?电⼦顺磁共振?点缺陷中图分类号:O614.23⽂献标志码:ADOI:10.16039/j.cnki.cn22-1249.2018.01.010⼀⼀在介电场中?BaTiO3基陶瓷是使⽤最⼴泛的电介质.镁离⼦(Mg2+)具有固定的价态?通常与稀⼟离⼦作为共掺杂剂掺杂在BaTiO3中作为X7R型应⽤于多层陶瓷电容器(MLCC)中[1 ̄6].在1150?的较低的烧结温度(Ts)下?认为Mg2+倾向于靠近晶粒的表⾯.对于Mg掺杂的BaTiO3陶瓷?Mg2+被认为是替代BaTiO3中的Ti位的受体(Mg?Ti)[7 ̄9]?因为6 ̄CNMg2+(0.72?)与Ti4+(0.605?)的离⼦尺⼨相近[10].这⾥采⽤了Kr?ger和Vink提出的缺陷符号[11].离⼦半径作为配位数(CN)的函数在表1中给出[10].然⽽Mg2+在BaTiO3 ̄MgTiO3体系中代替Ba位和Ti位的两性⾏为很少被考虑.根据报道?当Mg2+代替Ti4+位点时?每个Mg2+离⼦(Mg?Ti)被认为伴随着⼀个氧空位(V七O)[7].V七O的存在与Mg掺杂的BaTiO3中的半导体⾏为有关?这归因于由受体掺杂的Mg2+离⼦产⽣的氧空位的迁移率[7]具体请参照参考⽂献[7].在研究者的报道[7]中没有在Mg掺杂的BaTiO3中观察氧空位存在的直接证据.本实验?在烧结温度Ts=1400?下制备了BMT ̄BTM陶瓷.采⽤电⼦顺磁共振(EPR)技术对BMT ̄BTM中的V七O进⾏检测?并提供了低温菱⽅相中存在V七O的证据.在Ts=1400?时?发现了Ti4+与Ti3+的还原以及在六⽅相中与Ti3+(3d1)有关的两种EPR信号.表1⼀离⼦半径作为配位数(CN)的函数离⼦配位数(CN)半径(?)Ba2+121.61Ti4+60.605Ti3+60.67Mg2+121.23Mg2+60.721⼀实验部分1.1⼀试剂与仪器以BaCO3(分析纯?上海帝阳)⼆TiO2(99.9%?上海帝阳)和MgO(基准试剂?国药)粉末为初始原料.采⽤了国内丹东皓圆仪器有限公司的DX ̄2700型X射线衍射仪测定.以CuKα为射线源?扫描范围为20??2θ?85??步宽为0.02??采样时间为3s?管电压⼆管电流分别为40kV和30mA?采⽤步进扫描⽅式进⾏扫描.利⽤美国Accelrys公司的MSModeling软件的Reflex模块并结合Sma4Wine软件?对XRD谱进⾏处理?除去CuKα2散射和衍射背底的贡献?进⾏晶体结构计算.采⽤法国JY公司的532nm激光LabRAMXploRA型拉曼光谱仪在室温下对样品进⾏测量?采⽤德国BrukerCorporationA300 ̄10/12型电⼦顺磁共振仪对BMT和BTM样品进⾏EPR谱测试?选⽤X波段频率为9.84GHz?在-150?温度点进⾏测定?测试范围为500 ̄6500G.g值由hν0=gβH关系计算.1.2⼀实验过程采⽤固相冷压陶瓷技术?按照名义分⼦式(Ba1-xMgx)TiO3(BMT)⼆Ba(Ti1-xMgx)O3(x=0.015)(BTM)进⾏原料配⽐?将混合的原料在玛瑙研钵中研磨1h后以350?/h升⾄1100?预烧5h进⾏脱碳.⽤聚⼄烯醇⽔溶液(PVA)粘合剂?将混合物在200MPa压⼒下加压2min压制成⽚.最后在1400?下空⽓中烧结12h制备碳酸钡陶瓷.2⼀结果与讨论2.1⼀XRD谱图分析图1显⽰的是BMT ̄BTM陶瓷粉末在室温下测量的XRD谱图与模拟的⽴⽅⼆四⽅⼆六⽅钛酸钡XRD谱图的对⽐图.2θ/?图1⼀BMT ̄BTM室温的室温XRD谱图与模拟⽴⽅⼆四⽅⼆六⽅钛酸钡XRD谱图的对⽐图观察图谱发现?BMT在~45?处的峰(图1b)逐渐演变为四⽅晶系BaTiO3(空间群:P4mm)(JCPDS卡号6 ̄526)的(002)/(200)峰与六⽅晶系BaTiO3(JCPDS卡号34 ̄129)(空间群:P63/mmc)的(204)峰(图1(a)所⽰)?即四⽅相和六⽅相共存在BMT中?BTM在~45?处的峰(图1c)逐渐演变为⽴⽅体BaTiO3(空间群:Pm3m)JCPDS卡号31 ̄174)的(200)与六⽅晶系BaTiO3的(204)峰(图1a所⽰)?即⽴⽅相和六⽅相共存在BTM中.2.2⼀RS谱图分析室温下BMT ̄BTM的拉曼光谱如图3(a)所⽰.四⽅BaTiO3具有四种常见的光学模式:A1(TO2)?B1+E(TO+LO)?A1(TO3)和A1(LO3)+E(LO3)?特征峰分别为~260?~305?~520?和~720cm-1.BMT ̄BTM的拉曼散射实验阐明了三个事实:(1)~305cm-1的尖峰通常被认为是四⽅相的证明?并且在⽴⽅BaTiO3相中消失[11 ̄13].因此?310cm-1峰(图3(a)存在?说明BTM中的⽴⽅相是伪⽴⽅.(2)对于BMT与BTM在195cm-1处观察到特征峰?这归因于伪⽴⽅相或四⽅晶相中存在正交变形[14?15].(3)Ba(Ti1 ̄xFex)O3-δ(BTF)陶瓷具有完全六⽅相的结构(a=5.724??c=13.990??V0=397.04?3)(图3所⽰)?主要表现出三个强带?152?208和640cm-1(图3b)?分别对应于E1g?E1g+E2g和A1g声⼦[16].对于BMT?这三个频带较弱?重叠在四⽅声⼦光谱(图3(a))?显⽰六⽅晶相和四⽅晶相共存?⽽对于BTM?这三个频带较明显(图3(a))?显⽰六⽅晶相和伪⽴⽅晶相共存.Ramanshift/cm-1图2⼀(a)在Ts=1400?烧结的BMT ̄BTM和(b)六⽅Ba(Ti0.95Fe0.05)O3(BTF)陶瓷的室温拉曼光谱插图显⽰了BTF的XRD图谱14⼀⼀第1期郑永顺?等:Mg掺杂BaTiO3介电陶瓷中氧空位缺陷的EPR监控⼀⼀⼀2.3⼀EPR谱图分析图3为(a)BMT与(b)BTM在-150?下测得的变温EPR谱图.从图中可以看出在低于-100?的菱⽅相中?探测到与氧空位相关g=1.956的EPR信号[17]?并探测到与Ti空位相关g=2.004的EPR信号[18]?与Ba空位相关g=1.974的EPR信号[20].g=1.934和1.942处的两个Ti3+相关信号与BMT⼆BTM中的六⽅相有关?因为Ti3+相关信号只能在低温下观察到?这是由于通过低温有效地延长了⾃旋 ̄晶格弛豫时间(τ)[19].所以推断出在BMT与BTM中Ba空位⼆Ti空位和O空位共存.H/GH/G图3⼀(a)BMT与(b)BTM在-150?下测得的变温EPR谱图3⼀结⼀⼀论在Ts=1400?的烧结温度下?采⽤固相反应法制备(Ba1-xMgx)TiO3和Ba(Ti1-xMgx)O3(x=0.015)陶瓷.通过XRD测试结果表明BMT为六⽅和伪⽴⽅钛酸钡结构的混合相?BTM为六⽅和四⽅钙钛矿结构的混合相?通过电⼦顺磁共振(EPR)技术测试的结果表明BMT与BTM陶瓷在低于-100?的菱⽅相中?探测到与氧空位相关g=1.956的EPR信号?且Ba空位⼆Ti空位和O空位共存.参考⽂献:[1]⼀H.Kishi.?N.Kohzu.?J.Sugino?etal.Theeffectofrare ̄earth(La?Sm?Dy?HoandEr)andMgonthemicro ̄structureinBaTiO3[J].J.Eur.Ceram.Soc.?1999?19(6 ̄7):1043 ̄1046.[2]⼀J.H.Hwang.?S.K.Chol.?andY.H.Han.Dielectricprop ̄ertiesofBaTiO3codopedwithEr2O3andMgO[J].Jpn.J.Appl.Phys.?2001?40(8):4952 ̄4955.[3]⼀H.Kishi.?Y.Mizuno.?H.Chazono.Base ̄metalelectrode ̄multilayerceramiccapacitors:past?presentandfutureperspectives[J].Jpn.J.Appl.Phys.?2003?42(1):1 ̄15.[4]⼀S.Wang.?S.Zhang.?X.Zhou.?etal.Effectofsinteringatmospheresonthemicrostructureanddielectricprop ̄ertiesofYb/Mgco ̄dopedBaTiO3ceramics[J].Mater.Lett.?2005?59(19):2457 ̄2460.[5]⼀C. ̄Y.Chang.?W. ̄N.Wang.?C. ̄Y.Huang.EffectofMgOandY2O3dopingontheformationofcore ̄shellstructureinBaTiO3ceramics[J].J.Am.Ceram.Soc.?2013?96(8):2570 ̄2576.[6]⼀C. ̄H.Kim.?K. ̄J.Park.?Y. ̄J.Yoon.?etal.RoleofYttiumandmagnesiumintheformationofcore ̄shellstructureofBaTiO3grainsinMLCC[J].J.Eur.Ceram.Soc.?2008?28(6):1213 ̄1219.[7]⼀S.H.Cha.?Y.H.Han.EffectsofMndopingondielectricpropertiesofMg ̄dopedBaTiO3[J].J.Appl.Phys.?2006?100(10):104102.[8]⼀M.Dong.?H.Miao.?G.Tan.?etal.EffectsofMg ̄dopingonthemicrostructureandpropertiesofBaTiO3ceramicspreparedbyhydrothermalmethod[J].J.Elec ̄troceram.?2008?21(1):573 ̄576.[9]⼀S. ̄H.Yoon.?C.A.Randall.?K. ̄H.Hur.Effectsofacceptorconcentrationonthebulkelectricalconductioninacceptor(Mg) ̄dopedBaTiO3[J].J.Appl.Phys.?2010?107(10):103721.[10]R.D.Shannon..Revisedeffectiveionicradiiandsys ̄24⼀⼀吉⼀林⼀化⼀⼯⼀学⼀院⼀学⼀报⼀⼀2018年⼀⼀tematicstudiesofinteratomicdistancesinhalidesandchalcogenides[J].ActaCrystallogr.SectA.?1976?32(5):51 ̄767.[11]D. ̄Y.Lu.?X. ̄Y.Sun.?M.Toda.Anovelhigh ̄kY5Vbariumtitanateceramicsco ̄dopedwithlanthanumandcerium[J].J.Phys.Chem.Solids.?2007?68(4):650 ̄664.[12]M.P.Fontana.?M.Lambert.Lineardisorderandtemper ̄aturedependenceofRamanscatteringinBaTiO3[J].SolidStateCommon.?1972?10(1):1 ̄4.[13]A.M.Quittet.?M.Lambert.TemperaturedependenceoftheRamancrosssectionandlightabsorptionincubicBaTiO3[J].SolidStateCommon.?1973?12(10):1053 ̄1055.[14]T.Nagai.?K.Iijima.?H.J.Hwang.?etal.EffectofMgOdopingonthephasetransformationsofBaTiO3[J].J.Am.Ceram.Soc.?2000?83(1):107 ̄112.[15]C.H.Perry.?D.B.Hall.TemperaturedependenceoftheRamanspectruminBaTiO3[J].Phys.Rev.Lett.?1965?15(17):700 ̄702.[16]H.Yamaguchi.?H.Uwe.?T.Sakudo.?etal.Raman ̄scat ̄teringstudyofthesoftphononmodesinhexagonalbar ̄iumtitanate[J].J.Phys.Soc.Jpn.?1987?56(2):589 ̄595.[17]彭研焱?路⼤勇.Tb在BaTiO3中的⾃补偿模式探索及介电性质[J].吉林化⼯学院学报?2016?33(1):61 ̄64.[18]刘婷婷?路⼤勇.Lu在BaTiO3中⾃的位占据研究[J].吉林化⼯学院学报?2016?33(1):65 ̄68.[19]P.S.Dobal.?A.Dixit.?R.S.Katiyar.?etal.Micro ̄RamanstudyofBa1-xSrxTiO3ceramics[J].J.RamanSpectrosc.?2001?32(2):147 ̄149.EPRMonitoringofOxygen ̄vacancyDefectsinMg ̄dopedBaTio3DielectricCeramicsZHENGYong ̄shun?LUDa ̄yong?(ResearchCenterforMaterialsScienceandEngineering?JilinInstituteofChemicalTechnology?JilinCity132022?China)Abstract:(Ba1-xMgx)TiO3andBa(Ti1-xMgx)O3-x(x=0.015)ceramicswerepreparedbythesolid ̄statereactionmethodatasinteringtemperatureofTs=1400?.Electronparamagneticresonance(EPR)wasemployedasakeytechniquetostudythepointdefectsofceramics.TheresultsshowthatBMTceramicexhibitedthemixedphasesofhexagonalandpseudocubicperovskitestructures?BTMceramicexhibitedthemixedphasesofhexagonalandtetragonalperovskitestructures.AnEPRsignalatg=1.956?whichisassociatedwithoxygen ̄vacancydefects?wasdetectedintherhombohedralphasebelowT=-100?.ThreetypesofpointdefectsofBa?Ti?Ovacanciescouldcoexistinceramics.Keywords:Mg ̄dopedBaTiO3?X ̄raydiffraction?electronparamagneticresonance?pointdefect34⼀⼀第1期郑永顺?等:Mg掺杂BaTiO3介电陶瓷中氧空位缺陷的EPR监控⼀⼀⼀。
日前,北京化工大学仲崇立教授团队关于金属-有机框架(Metal-Organic Frameworks, MOF)多级孔道制备的研究发表在《Nature Communication》上,再次体现了中国科学家在这一领域的强大实力。
MOF是一类具有纳米孔道结构的新兴功能材料,在气体储存与分离、催化、药物负载等领域具有很好的应用前景。
MOF材料以微孔为主,这限制了客体在其中的传输过程,是它实际应用的不利因素。
然而,构筑同时具有微孔、介孔乃至大孔的多级孔道结构,可以有效解决这一问题。
仲崇立老师与北京工业大学的李建荣老师合作,在合成MOF的过程中引入金属—有机聚集体(Metal-Organic Assemblies, MOA)作为模板剂,合成MOF后将均匀嵌入在MOF内部的MOA用酸消解,这就在原有的微孔MOF中造出了介孔。
利用这种思路,该课题组成功合成了19种稳定的多级孔道MOF材料,并对它们的大分子传输能力进行了研究。
该课题组使用美国康塔仪器公司的Autosorb-iQ气体吸附分析仪测试了每一种MOF的吸附等温线,由吸附等温线的形状,有力地佐证了介孔结构的成功构建。
他们同时使用康塔仪器数据分析软件的BET、t-plot、BJH、DFT等模型对MOF 材料的总比表面积、微孔比表面积、微孔孔径分布、介孔孔径分布等进行了分析,分析结果证明了该研究的一系列设想。
美国康塔仪器美国康塔仪器(Quantachrome Instruments)被公认为是对样品权威分析的优秀供应商,它可为实验室提供全套装备及完美的粉末技术,及极佳的性能价格比。
康塔公司不仅通过了ISO9001及欧洲CE认证,也取得了美国FDA IQ/OQ认证。
作为开发粉体及多孔材料特性仪器的世界领导者,美国康塔仪器产品涵盖比表面、物理吸附、化学吸附、高压吸附、蒸汽吸附、竞争性气体吸附、真密度、堆密度、开/闭孔率、粒度粒形、Zeta电位、孔隙率、压汞仪、大孔分析、微孔分析、滤器分析等诸多领域。
一种高收率uio-66金属有机框架材料的制备方法及应用(原创实用版3篇)目录(篇1)1.引言2.UIO-66 金属有机框架材料的概述3.制备方法4.应用领域5.结论正文(篇1)【引言】金属有机框架材料 (Metal-Organic Frameworks,简称 MOFs) 是一种具有高比表面积、多孔性、可调结构和化学功能性的晶态材料。
近年来,随着材料科学的发展和应用需求的增加,MOFs 已经成为材料科学领域的研究热点之一。
UIO-66 是一种典型的 MOF 材料,具有良好的性能和应用前景。
本文将介绍一种高收率 UIO-66 金属有机框架材料的制备方法及应用。
【UIO-66 金属有机框架材料的概述】UIO-66 是一种由尿嘧啶和金属离子构筑而成的金属有机框架材料,具有四方对称性、大孔容、高表面积等优点,可应用于催化、吸附、分离、传感等领域。
UIO-66 材料的制备方法对其性能和应用有着重要的影响。
【制备方法】本文介绍的制备方法如下:1.在一定温度下,将尿嘧啶和金属离子 (如 Co2+、Ni2+、Zn2+等) 溶液混合,并加入适量的有机酸 (如乙酸、丙酸等);2.搅拌一段时间后,沉淀出 UIO-66 晶体;3.将晶体分离、洗涤、干燥,得到高收率的 UIO-66 金属有机框架材料。
【应用领域】UIO-66 金属有机框架材料具有广泛的应用领域,包括但不限于以下几个方面:1.催化:UIO-66 材料具有可调结构和化学功能性,可作为催化剂或催化剂载体,应用于各种催化反应;2.吸附:UIO-66 材料具有良好的孔容和表面积,可作为吸附剂,应用于气体吸附、分离和储存等领域;3.分离:UIO-66 材料具有可调结构和化学功能性,可作为分离剂,应用于分离和提纯混合物;4.传感:UIO-66 材料具有良好的传感性能,可应用于各种传感器件的制备。
目录(篇2)一、引言二、UIO-66 金属有机框架材料的概述三、制备方法1.溶胶 - 凝胶法2.水热法3.微波法四、应用领域1.催化剂2.吸附剂3.电化学器件五、总结与展望正文(篇2)【引言】随着科技的发展,新型材料在各领域中的应用越来越广泛,UIO-66 金属有机框架材料(Metal-Organic Frameworks, MOFs)作为一种高收率的新型材料,在催化剂、吸附剂和电化学器件等领域具有广泛的应用前景。
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序号 ISSN 刊名简称分区刊名全称3 年平均IF2011年 IF1 00092665CHEM REV 1 CHEMICAL REVIEWS36.39740.1972 01087673ACTA CRYSTALLOGR A 1ACTACRYSTALLOGRAPHICASECTION A35.4452.0763 03060012CHEM SOC REV 1CHEMICAL SOCIETYREVIEWS25.14428.764 0079670PROG POLYM SCI 1PROGRESS IN POLYMERSCIENCE23.57424.105 00014842ACCOUNTS CHEM RES 1ACCOUNTS OF CHEMICALRESEARCH20.56521.646 1755433NAT CHEM 1 Nature Chemistry19.22620.5247 0002510ALDRICHIM ACTA 1 ALDRICHIMICA ACTA15.52216.0918 0066426XANNU REV PHYS CHEM 1ANNUAL REVIEW OFPHYSICAL CHEMISTRY14.61314.139 01675729SURF SCI REP 1SURFACE SCIENCEREPORTS14.58411.69610 14337851ANGEW CHEM INT EDIT 1ANGEWANDTECHEMIEINTERNATIONALEDITION12.67113.45511 00108545COORDIN CHEM REV 1COORDINATIONCHEMISTRY REVIEWS11.11812.1112 19361327ANNU REV ANAL CHEM 1Annual Review of AnalyticalChemistry9.726 9.04813 13895567J PHOTOCH PHOTOBIOC1JOURNAL OFPHOTOCHEMISTRY ANDPHOTOBIOLOGYCPHOTOCHEMISTRYREVIEWS9.70710.3614 02650568NAT PROD REP 1NATURAL PRODUCTREPORTS9.291 9.79015 1754569 ENERG ENVIRON SCI 1 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SCI收录的A类和B类相关期刊目录(材料和机械)1.材料科学(A类期刊)/SCI前50%序号 期刊名称(简) 期刊名称(全) ISSN号 影响因子学科1 PROG MATER SCI PROGRESS IN MATERIALS SCIENCE 0079‐6425 20.846 材料科学:综合2 NAT MATER NATURE MATERIALS 1476‐1122 19.782 材料科学:综合3 NAT NANOTECHNOL Nature Nanotechnology 1748‐3387 14.917 材料科学:综合4 MAT SCI ENG R MATERIALS SCIENCE & ENGINEERINGR‐REPORTS0927‐796X 14.400 材料科学:综合5 NANO LETT NANO LETTERS 1530‐6984 9.627 材料科学:综合6 ADV MATER ADVANCED MATERIALS 0935‐9648 8.191 材料科学:综合7 ADV FUNCT MATER ADVANCED FUNCTIONAL MATERIALS 1616‐301X 7.496 材料科学:综合8 SMALL SMALL 1613‐6810 6.408 材料科学:综合9 BIOMATERIALS BIOMATERIALS 0142‐9612 6.262 材料科学:生物材料10 MRS BULL MRS BULLETIN 0883‐7694 5.168 材料科学:综合11 CHEM MATER CHEMISTRY OF MATERIALS 0897‐4756 4.993 材料科学:综合12 ANNU REV MATER RES ANNUAL REVIEW OF MATERIALSRESEARCH1531‐7331 4.765 材料科学:综合13 SOFT MATTER Soft Matter 1744‐683X 4.703 材料科学:综合14 INT J PLASTICITY INTERNATIONAL JOURNAL OFPLASTICITY0749‐6419 4.516 材料科学:综合15 J MATER CHEM JOURNAL OF MATERIALS CHEMISTRY 0959‐9428 4.339 材料科学:综合16 CARBON CARBON 0008‐6223 4.260 材料科学:综合17 CRIT REV SOLID STATE CRITICAL REVIEWS IN SOLID STATE ANDMATERIALS SCIENCES1040‐8436 4.152 材料科学:综合18 CRYST GROWTH DES CRYSTAL GROWTH & DESIGN 1528‐7483 4.046 晶体学19 CRYST GROWTH DES CRYSTAL GROWTH & DESIGN 1528‐7483 4.046 材料科学:综合20 ORG ELECTRON ORGANIC ELECTRONICS 1566‐1199 3.879 材料科学:综合21 J APPL CRYSTALLOGR JOURNAL OF APPLIEDCRYSTALLOGRAPHY0021‐8898 3.629 晶体学22 ACTA MATER ACTA MATERIALIA 1359‐6454 3.624 材料科学:综合 22 ACTA MATER ACTA MATERIALIA 1359‐6454 3.624 冶金工程24 J MECH PHYS SOLIDS JOURNAL OF THE MECHANICS ANDPHYSICS OF SOLIDS0022‐5096 3.542 材料科学:综合25 INT MATER REV INTERNATIONAL MATERIALS REVIEWS0950‐6608 3.500 材料科学:综合26 CRYSTENGCOMM CRYSTENGCOMM 1466‐8033 3.468 晶体学27 NANOTECHNOLOGY NANOTECHNOLOGY 0957‐4484 3.310 材料科学:综合28 ACTA BIOMATER Acta Biomaterialia 1742‐7061 3.113 材料科学:生物材料29 DENT MATER DENTAL MATERIALS 0109‐5641 2.990 材料科学:生物材料30 MACROMOL BIOSCI MACROMOLECULAR BIOSCIENCE 1616‐5187 2.831 材料科学:生物材料31 DYES PIGMENTS DYES AND PIGMENTS 0143‐7208 2.796 材料科学:纺织32 CURR NANOSCI Current Nanoscience 1573‐4137 2.793 材料科学:综合33 PLASMONICS Plasmonics 1557‐1955 2.765 材料科学:综合34 ACTA CRYSTALLOGR D ACTA CRYSTALLOGRAPHICA SECTIOND‐BIOLOGICAL CRYSTALLOGRAPHY0907‐4449 2.620 晶体学35 J BIOMED MATER RES A JOURNAL OF BIOMEDICAL MATERIALSRESEARCH PART B‐APPLIEDBIOMATERIALS1549‐3296 2.612 材料科学:生物材料36 J ELECTROCHEM SOC JOURNAL OF THE ELECTROCHEMICALSOCIETY0013‐4651 2.483 材料科学:膜37 SCRIPTA MATER SCRIPTA MATERIALIA 1359‐6462 2.481 材料科学:综合38 SCRIPTA MATER SCRIPTA MATERIALIA 1359‐6462 2.481 冶金工程39 ACTA CRYSTALLOGR A ACTA CRYSTALLOGRAPHICA SECTION A0108‐7673 2.385 晶体学40 J NANOPART RES JOURNAL OF NANOPARTICLERESEARCH1388‐0764 2.338 材料科学:综合41 INTERMETALLICS INTERMETALLICS 0966‐9795 2.219 材料科学:综合42 INTERMETALLICS INTERMETALLICS 0966‐9795 2.219 冶金工程43 MECH MATER MECHANICS OF MATERIALS 0167‐6636 2.211 材料科学:综合44 MICROPOR MESOPORMATMICROPOROUS AND MESOPOROUSMATERIALS1387‐1811 2.210 材料科学:综合45 COMPOS SCI TECHNOL COMPOSITES SCIENCE ANDTECHNOLOGY0266‐3538 2.171 材料科学:复合46 ACTA CRYSTALLOGR B ACTA CRYSTALLOGRAPHICA SECTIONB‐STRUCTURAL SCIENCE0108‐7681 2.163 晶体学47 NANOSCALE RES LETT Nanoscale Research Letters 1931‐7573 2.158 材料科学:综合48 IEEE T NANOTECHNOL IEEE TRANSACTIONS ONNANOTECHNOLOGY1536‐125X 2.110 材料科学:综合49 ELECTROCHEMSOLID STELECTROCHEMICAL AND SOLIDSTATE LETTERS1099‐0062 2.109 材料科学:综合50 COLLOID SURFACE B COLLOIDS AND SURFACESB‐BIOINTERFACES0927‐7765 2.109 材料科学:生物材料51 EUR PHYS J E EUROPEAN PHYSICAL JOURNAL E 1292‐8941 2.025 材料科学:综合52 SOL ENERG MAT SOL C SOLAR ENERGY MATERIALS AND SOLARCELLS0927‐0248 2.002 材料科学:综合53PHOTONICNANOSTRUCTPhotonics andNanostructures‐Fundamentals andApplications1569‐4410 2.000 晶体学54PHOTONICNANOSTRUCTPhotonics andNanostructures‐Fundamentals andApplications1569‐4410 2.000 材料科学:综合55J NANOSCINANOTECHNOJOURNAL OF NANOSCIENCE ANDNANOTECHNOLOGY1533‐4880 1.987 材料科学:综合56 J CRYST GROWTH JOURNAL OF CRYSTAL GROWTH 0022‐0248 1.950 晶体学57 MICROSC MICROANAL MICROSCOPY AND MICROANALYSIS 1431‐9276 1.941 材料科学:综合58 CHEM VAPOR DEPOS CHEMICAL VAPOR DEPOSITION 0948‐1907 1.936 材料科学:膜59 J BIOMED MATER RES B JOURNAL OF BIOMEDICAL MATERIALSRESEARCH PART B‐APPLIEDBIOMATERIALS1552‐4973 1.933 材料科学:生物材料60 J MOL GRAPH MODEL JOURNAL OF MOLECULAR GRAPHICS &MODELLING1093‐3263 1.932 晶体学61 J MICROMECHMICROENGJOURNAL OF MICROMECHANICS ANDMICROENGINEERING0960‐1317 1.930 材料科学:综合62 J BIOACT COMPAT POL JOURNAL OF BIOACTIVE ANDCOMPATIBLE POLYMERS0883‐9115 1.917 材料科学:生物材料63 J MATER RES JOURNAL OF MATERIALS RESEARCH 0884‐2914 1.916 材料科学:综合64 SEMICOND SCI TECH SEMICONDUCTOR SCIENCE ANDTECHNOLOGY0268‐1242 1.899 材料科学:综合65 CORROS SCI CORROSION SCIENCE 0010‐938X 1.895 材料科学:综合66 CORROS SCI CORROSION SCIENCE 0010‐938X 1.895 冶金工程67 MATER CHEM PHYS MATERIALS CHEMISTRY AND PHYSICS 0254‐0584 1.871 材料科学:综合68 J BIOMAT SCI‐POLYM E JOURNAL OF BIOMATERIALSSCIENCE‐POLYMER EDITION0920‐5063 1.862 材料科学:生物材料69 APPL PHYS A‐MATER APPLIED PHYSICS A‐MATERIALSSCIENCE & PROCESSING0947‐8396 1.857 材料科学:综合70 SOFT MATER SOFT MATERIALS 1539‐445X 1.810 材料科学:综合71 J AM CERAM SOC JOURNAL OF THE AMERICAN CERAMICSOCIETY0002‐7820 1.792 材料科学:硅酸盐72 DIAM RELAT MATER DIAMOND AND RELATED MATERIALS 0925‐9635 1.788 材料科学:综合73 SYNTHETIC MET SYNTHETIC METALS 0379‐6779 1.788 材料科学:综合74 POLYHEDRON POLYHEDRON 0277‐5387 1.756 晶体学75 INT J DAMAGE MECH INTERNATIONAL JOURNAL OFDAMAGE MECHANIC1056‐7895 1.750 材料科学:综合76 J MAGN MAGN MATER JOURNAL OF MAGNETISM ANDMAGNETIC MATERIALS0304‐8853 1.704 材料科学:综合77 THIN SOLID FILMS THIN SOLID FILMS 0040‐6090 1.693 材料科学:膜78 THIN SOLID FILMS THIN SOLID FILMS 0040‐6090 1.693 材料科学:综合79 SURF COAT TECH SURFACE & COATINGS TECHNOLOGY 0257‐8972 1.678 材料科学:膜80 CURR OPIN SOLID ST M CURRENT OPINION IN SOLID STATE &MATERIALS SCIENCE1359‐0286 1.677 材料科学:综合81 COMPOS PARTA‐APPL SCOMPOSITES PART A‐APPLIED SCIENCEAND MANUFACTURING1359‐835X 1.662 材料科学:复合82 J BIOMATER APPL JOURNAL OF BIOMATERIALSAPPLICATIONS0885‐3282 1.651 材料科学:生物材料83 J NUCL MATER JOURNAL OF NUCLEAR MATERIALS 0022‐3115 1.643 材料科学:综合84 MATER LETT MATERIALS LETTERS 0167‐577X 1.625 材料科学:综合85 J INTEL MAT SYST STR JOURNAL OF INTELLIGENT MATERIALSYSTEMS AND STRUCTURES1045‐389X 1.610 材料科学:综合86 J MATER SCI‐MATER MJOURNAL OF MATERIALSSCIENCE‐MATERIALS IN MEDICINE0957‐4530 1.581 材料科学:生物材料87 J EUR CERAM SOC JOURNAL OF THE EUROPEAN CERAMICSOCIETY0955‐2219 1.562 材料科学:硅酸盐88 PROG ORG COAT PROGRESS IN ORGANIC COATINGS 0300‐9440 1.540 材料科学:膜89 OPT MATER OPTICAL MATERIALS 0925‐3467 1.519 材料科学:综合90 SMART MATER STRUCT SMART MATERIALS & STRUCTURES 0964‐1726 1.512 材料科学:综合91 MAT SCI ENG C‐BIO S MATERIALS SCIENCE & ENGINEERINGC‐BIOMIMETIC ANDSUPRAMOLECULAR SYSTEMS0928‐4931 1.486 材料科学:综合92 PHILOS MAG PHILOSOPHICAL MAGAZINE 1478‐6435 1.486 材料科学:综合93 PHILOS MAG PHILOSOPHICAL MAGAZINE 1478‐6435 1.486 冶金工程94 MATER RES BULL MATERIALS RESEARCH BULLETIN 0025‐5408 1.484 材料科学:综合95 ADV ENG MATER ADVANCED ENGINEERING MATERIALS1438‐1656 1.463 材料科学:综合96 MAT SCI ENG A‐STRUCTMATERIALS SCIENCE ANDENGINEERING A‐STRUCTURALMATERIALS PROPERTIES MICROST0921‐5093 1.457 材料科学:综合97 J ALLOY COMPD JOURNAL OF ALLOYS ANDCOMPOUNDS0925‐8388 1.455 材料科学:综合98 J ALLOY COMPD JOURNAL OF ALLOYS ANDCOMPOUNDS0925‐8388 1.455 冶金工程99 GOLD BULL GOLD BULLETIN 0017‐1557 1.450 材料科学:综合 100 GOLD BULL GOLD BULLETIN 0017‐1557 1.450 冶金工程101 MET MATER‐INT METALS AND MATERIALSINTERNATIONAL1598‐9623 1.424 材料科学:综合102 MET MATER‐INT METALS AND MATERIALSINTERNATIONAL1598‐9623 1.424 冶金工程103 NANOSC MICROSCTHERMNanoscale and MicroscaleThermophysical Engineering1556‐7265 1.417 材料科学:表征与测试104 APPL SURF SCI APPLIED SURFACE SCIENCE 0169‐4332 1.406 材料科学:膜 105 CELLULOSE CELLULOSE 0969‐0239 1.406 材料科学:纸与木材 106 CELLULOSE CELLULOSE 0969‐0239 1.406 材料科学:纺织 107 WEAR WEAR 0043‐1648 1.395 材料科学:综合 108 GRANUL MATTER GRANULAR MATTER 1434‐7636 1.370 材料科学:综合109 MACROMOL MATERENGMACROMOLECULAR MATERIALS ANDENGINEERING1438‐7492 1.368 材料科学:综合110 INT J APPL CERAM TEC International Journal of AppliedCeramic Technology1546‐542X 1.366 材料科学:硅酸盐111 LIQ CRYST LIQUID CRYSTALS 0267‐8292 1.362 晶体学112 CERAM INT CERAMICS INTERNATIONAL 0272‐8842 1.360 材料科学:硅酸盐 113 POLYM TEST POLYMER TESTING 0142‐9418 1.357 材料科学:表征与测试114 KOVOVE MATER Kovove Materialy Metallic Materials 0023‐432X 1.345 材料科学:综合 115 KOVOVE MATER Kovove Materialy Metallic Materials 0023‐432X 1.345 冶金工程116 Z KRISTALLOGR ZEITSCHRIFT FUR KRISTALLOGRAPHIE 0044‐2968 1.338 晶体学117 MAT SCI ENG B‐SOLIDMATERIALS SCIENCE ANDENGINEERING B‐SOLID STATEMATERIALS FOR ADVANCED TECH0921‐5107 1.330 材料科学:综合118 HYDROMETALLURGY HYDROMETALLURGY 0304‐386X 1.324 冶金工程119 J ELECTRON MATER JOURNAL OF ELECTRONIC MATERIALS0361‐5235 1.320 材料科学:综合120 J NON‐CRYST SOLIDS JOURNAL OF NON‐CRYSTALLINESOLIDS0022‐3093 1.319 材料科学:硅酸盐121 J NON‐CRYST SOLIDS JOURNAL OF NON‐CRYSTALLINESOLIDS0022‐3093 1.319 材料科学:综合122 COMPOS PART B‐ENG COMPOSITES PART B‐ENGINEERING 1359‐8368 1.311 材料科学:复合123 J SOL‐GEL SCI TECHN JOURNAL OF SOL‐GEL SCIENCE ANDTECHNOLOGY0928‐0707 1.300 材料科学:硅酸盐124 CURR APPL PHYS CURRENT APPLIED PHYSICS 1567‐1739 1.291 材料科学:综合125 J VAC SCI TECHNOL AJOURNAL OF VACUUM SCIENCE &TECHNOLOGY A‐VACUUM SURFACESAND FILMS0734‐2101 1.278 材料科学:膜126 METALL MATERTRANS AMETALLURGICAL AND MATERIALSTRANSACTIONS A‐PHYSICALMETALLURGY AND MATERIAL1073‐5623 1.278 材料科学:综合127 METALL MATERTRANS AMETALLURGICAL AND MATERIALSTRANSACTIONS A‐PHYSICALMETALLURGY AND MATERIAL1073‐5623 1.278 冶金工程128 SCI TECHNOL ADV MAT SCIENCE AND TECHNOLOGY OFADVANCED MATERIALS1468‐6996 1.270 材料科学:综合129 CMC‐COMPUT MATERCONCMC‐Computers Materials & Continua1546‐2218 1.241 材料科学:综合130 PHYS CHEM MINER PHYSICS AND CHEMISTRY OFMINERALS0342‐1791 1.238 材料科学:综合131 PHYS STATUS SOLIDI APHYSICA STATUS SOLIDIA‐APPLICATIONS AND MATERIALSSCIENCE0031‐8965 1.214 材料科学:综合132 OXID MET OXIDATION OF METALS 0030‐770X 1.212 冶金工程133 J THERM SPRAY TECHN JOURNAL OF THERMAL SPRAYTECHNOLOGY1059‐9630 1.204 材料科学:膜134 MODEL SIMULMATER SCMODELLING AND SIMULATION INMATERIALS SCIENCE ANDENGINEERING0965‐0393 1.158 材料科学:综合135 GEOSYNTH INT GEOSYNTHETICS INTERNATIONAL 1072‐6349 1.157 材料科学:综合136 J INCL PHENOMMACROJOURNAL OF INCLUSION PHENOMENAAND MACROCYCLIC CHEMISTRY0923‐0750 1.153 晶体学137 INT J ADHES ADHES INTERNATIONAL JOURNAL OFADHESION AND ADHESIVES0143‐7496 1.143 材料科学:综合138 COMP MATER SCI COMPUTATIONAL MATERIALS SCIENCE0927‐0256 1.135 材料科学:综合 139 NDT&E INT NDT & E INTERNATIONAL 0963‐8695 1.131 材料科学:表征与测试140 REV ADV MATER SCI REVIEWS ON ADVANCED MATERIALSSCIENCE1606‐5131 1.122 材料科学:综合141 INT J FATIGUE INTERNATIONAL JOURNAL OF FATIGUE0142‐1123 1.117 材料科学:综合 142 COMPOS STRUCT COMPOSITE STRUCTURES 0263‐8223 1.116 材料科学:复合143 INT J REFRACT MET H INTERNATIONAL JOURNAL OFREFRACTORY METALS & HARDMATERIALS0263‐4368 1.105 材料科学:综合144 INT J REFRACT MET H INTERNATIONAL JOURNAL OFREFRACTORY METALS & HARDMATERIALS0263‐4368 1.105 冶金工程145PROG CRYSTGROWTH CHPROGRESS IN CRYSTAL GROWTH ANDCHARACTERIZATION OF MATERIALS0960‐8974 1.091 晶体学146 PROG CRYSTGROWTH CHPROGRESS IN CRYSTAL GROWTH ANDCHARACTERIZATION OF MATERIALS0960‐8974 1.091 材料科学:表征与测试147 J MATER SCI JOURNAL OF MATERIALS SCIENCE 0022‐2461 1.081 材料科学:综合148 JOM‐US JOM‐JOURNAL OF THE MINERALSMETALS & MATERIALS SOCIETY1047‐4838 1.081 材料科学:综合149 JOM‐US JOM‐JOURNAL OF THE MINERALSMETALS & MATERIALS SOCIETY1047‐4838 1.081 冶金工程150 ADV APPL CERAM Advances in Applied Ceramics 1743‐6753 1.074 材料科学:硅酸盐151 J ENG MATER‐T ASME JOURNAL OF ENGINEERING MATERIALSAND TECHNOLOGY‐TRANSACTIONS OFTHE ASME0094‐4289 1.059 材料科学:综合152 POLYM COMPOSITE POLYMER COMPOSITES 0272‐8397 1.058 材料科学:复合153 SCI TECHNOL WELD JOI SCIENCE AND TECHNOLOGY OFWELDING AND JOINING1362‐1718 1.030 材料科学:综合154 SCI TECHNOL WELD JOI SCIENCE AND TECHNOLOGY OFWELDING AND JOINING1362‐1718 1.030 冶金工程155 CEMENT CONCRETERESCEMENT AND CONCRETE RESEARCH 0008‐8846 1.028 材料科学:综合156 MATER DESIGN MATERIALS & DESIGN 0261‐3069 1.028 材料科学:综合 157 MATER TRANS MATERIALS TRANSACTIONS 1345‐9678 1.018 材料科学:综合 158 MATER TRANS MATERIALS TRANSACTIONS 1345‐9678 1.018 冶金工程159 IEEE T ADV PACKAGING IEEE TRANSACTIONS ON ADVANCEDPACKAGING1521‐3323 1.011 材料科学:综合160 J ADHESION JOURNAL OF ADHESION 0021‐8464 1.000 材料科学:综合 161 J POROUS MAT JOURNAL OF POROUS MATERIALS 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TRANSACTIONS ONCOMPONENTS AND PACKAGINGTECHNOLOGIES1521‐3331 0.902 材料科学:综合175 STRUCT CHEM STRUCTURAL CHEMISTRY 1040‐0400 0.888 晶体学176 MECH ADV MATERSTRUCMECHANICS OF ADVANCED MATERIALSAND STRUCTURES1537‐6494 0.883 材料科学:表征与测试177 MECH ADV MATERSTRUCMECHANICS OF ADVANCED MATERIALSAND STRUCTURES1537‐6494 0.883 材料科学:复合178 MECH ADV MATERSTRUCMECHANICS OF ADVANCED MATERIALSAND STRUCTURES1537‐6494 0.883 材料科学:综合179 VACUUM VACUUM 0042‐207X 0.881 材料科学:综合 180 J EXP NANOSCI Journal of Experimental Nanoscience 1745‐8080 0.875 材料科学:综合 181 PHASE TRANSIT PHASE TRANSITIONS 0141‐1594 0.865 晶体学182 ARTIF CELL BLOOD SUB ARTIFICIAL CELLS BLOOD SUBSTITUTESAND IMMOBILIZATIONBIOTECHNOLOGY1073‐1199 0.857 材料科学:生物材料183 Z METALLKD ZEITSCHRIFT FUR METALLKUNDE 0044‐3093 0.857 冶金工程184 J ADHES SCI TECHNOL JOURNAL OF ADHESION SCIENCE ANDTECHNOLOGY0169‐4243 0.852 材料科学:综合185 FIRE MATER FIRE AND MATERIALS 0308‐0501 0.843 材料科学:综合186 CONSTR BUILD MATER CONSTRUCTION AND BUILDINGMATERIALS0950‐0618 0.841 材料科学:综合187 J ENERG 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MICROSCTHERMNanoscale and Microscale ThermophysicalEngineering1556‐72650.538 材料科学:表征与测试42 COMBUST EXPLOSHOCK+COMBUSTION EXPLOSION AND SHOCKWAVES0010‐50820.530 材料科学:综合43 MATER STRUCT MATERIALS AND STRUCTURES 1359‐59970.530 材料科学:综合44 APPL COMPOS MATER APPLIED COMPOSITE MATERIALS 0929‐189X0.520 材料科学:复合45 SENSOR MATER SENSORS AND MATERIALS 0914‐49350.518 材料科学:综合46 NEW DIAM FRONT CTECNEW DIAMOND AND FRONTIER CARBONTECHNOLOGY1344‐99310.517 材料科学:膜47 NEW DIAM FRONT CTECNEW DIAMOND AND FRONTIER CARBONTECHNOLOGY1344‐99310.517 材料科学:综合48 FIRE SAFETY J FIRE SAFETY JOURNAL 0379‐71120.514 材料科学:综合49 ACTA CRYSTALLOGR E ACTA CRYSTALLOGRAPHICA SECTIONE‐STRUCTURE REPORTS ONLINE1600‐53680.508 晶体学50 J AM LEATHER CHEM AS JOURNAL OF THE AMERICAN LEATHERCHEMISTS ASSOCIATION0002‐97260.506 材料科学:纺织51 J ELECTROCERAM JOURNAL OF ELECTROCERAMICS 1385‐34490.503 材料科学: 硅酸盐52 J INORG MATER JOURNAL OF INORGANIC MATERIALS 1000‐324X0.498 材料科学: 硅酸盐53 J SOC INF DISPLAY Journal of the Society for 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METALL SIN ACTA METALLURGICA SINICA 0412‐19610.449 冶金工程68 CORROS ENG SCITECHNCORROSION ENGINEERING SCIENCE ANDTECHNOLOGY1478‐422X0.447 材料科学:综合69 CORROS ENG SCITECHNCORROSION ENGINEERING SCIENCE ANDTECHNOLOGY1478‐422X0.447 冶金工程70 J SANDW STRUCTMATERJOURNAL OF SANDWICH STRUCTURES &MATERIALS1099‐63620.444 材料科学:表征与测试71 J SANDW STRUCTMATERJOURNAL OF SANDWICH STRUCTURES &MATERIALS1099‐63620.444 材料科学:复合72 SURF ENG SURFACE ENGINEERING 0267‐08440.444 材料科学:膜73 INORG MATER+ INORGANIC MATERIALS 0020‐16850.442 材料科学:综合74 ACTA MECH SOLIDA SIN ACTA MECHANICA SOLIDA SINICA 0894‐91660.438 材料科学:综合75 IRONMAK STEELMAK IRONMAKING & STEELMAKING 0301‐92330.438 冶金工程76 PART PART SYST CHAR PARTICLE & PARTICLE SYSTEMSCHARACTERIZATION0934‐08660.437 材料科学:表征与测试77 REV METAL MADRID REVISTA DE METALURGIA 0034‐85700.436 冶金工程78 PLAST RUBBERCOMPOSPLASTICS RUBBER AND COMPOSITES 1465‐80110.431 材料科学:复合79 PHYS CHEM GLASSES‐BPhysics and Chemistry ofGlasses‐European Journal of Glass Scienceand Technology Part B1753‐35620.429 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Technology0955‐62220.404 材料科学:纺织93 FIBRES TEXT EAST EUR FIBRES & TEXTILES IN EASTERN EUROPE 1230‐36660.402 材料科学:纺织94 EXP TECHNIQUES EXPERIMENTAL TECHNIQUES 0732‐88180.400 材料科学:表征与测试95 ADV CEM RES ADVANCES IN CEMENT RESEARCH 0951‐71970.400 材料科学:综合96 MATER CONSTRUCC MATERIALES DE CONSTRUCCION 0465‐27460.393 材料科学:综合97 MATER RES INNOV MATERIALS RESEARCH INNOVATIONS 1432‐89170.388 材料科学:综合98 CORROS REV CORROSION REVIEWS 0334‐60050.387 材料科学:膜99 CORROS REV CORROSION REVIEWS 0334‐60050.387 冶金工程100 RES NONDESTRUCTEVALRESEARCH IN NONDESTRUCTIVEEVALUATION0934‐98470.385 材料科学:表征与测试101 TETSU TO HAGANE TETSU TO HAGANE‐JOURNAL OF THEIRON AND STEEL INSTITUTE OF JAPAN0021‐15750.384 冶金工程102 CRYSTALLOGR REP+ CRYSTALLOGRAPHY REPORTS 1063‐77450.380 晶体学103 J FIRE SCI JOURNAL OF FIRE SCIENCES 0734‐90410.377 材料科学:综合 104 INSIGHT INSIGHT 1354‐25750.368 材料科学:表征与测试105 J JPN I MET JOURNAL OF THE JAPAN INSTITUTE OFMETALS0021‐48760.367 冶金工程106 GLASS SCI TECHNOL Glass Science and Technology 0946‐74750.365 材料科学:硅酸盐 107 MATER HIGH TEMP MATERIALS AT HIGH TEMPERATURES 0960‐34090.362 材料科学:综合 108 MATER HIGH TEMP MATERIALS AT HIGH TEMPERATURES 0960‐34090.362 冶金工程109 ANTI‐CORROSMETHOD MANTI‐CORROSION METHODS ANDMATERIALS0003‐55990.361 冶金工程110 COMPUT CONCRETE Computers and Concrete 1598‐81980.351 材料科学:表征与测试111 MECH TIME‐DEPENDMATMECHANICS OF TIME‐DEPENDENTMATERIALS1385‐20000.351 材料科学:表征与测试112 FOREST PROD J FOREST PRODUCTS JOURNAL 0015‐74730.351 材料科学:纸与木材113 HIGH TEMP MAT PR‐ISR HIGH TEMPERATURE MATERIALS ANDPROCESSES0334‐64550.346 材料科学:综合114 STEEL RES INT STEEL RESEARCH INTERNATIONAL 1611‐36830.345 冶金工程115 J UNIV SCI TECHNOL B JOURNAL OF UNIVERSITY OF SCIENCEAND TECHNOLOGY BEIJING1005‐88500.342 材料科学:综合116 J UNIV SCI TECHNOL B JOURNAL OF UNIVERSITY OF SCIENCEAND TECHNOLOGY BEIJING1005‐88500.342 冶金工程117 ARCH MECH ARCHIVES OF MECHANICS 0373‐20290.333 材料科学:表征与测试118 MATER SCI‐POLAND MATERIALS SCIENCE‐POLAND 0137‐13390.332 材料科学:综合 119 ADV COMPOS MATER ADVANCED COMPOSITE MATERIALS 0924‐30460.318 材料科学:复合 120 MAG CONCRETE RES MAGAZINE OF CONCRETE RESEARCH 0024‐98310.317 材料科学:综合121 MATERIALWISS WERKST MATERIALWISSENSCHAFT UNDWERKSTOFFTECHNIK0933‐51370.317 材料科学:综合122 J COAT TECHNOL RES Journal of Coatings Technology andResearch1547‐00910.316 材料科学:膜123 ADV COMPOS LETT ADVANCED COMPOSITES LETTERS 0963‐69350.314 材料科学:复合124 NONDESTRUCTTEST EVANondestructive Testing and Evaluation 1058‐97590.312 材料科学:表征与测试125 J WUHAN UNIVTECHNOLJOURNAL OF WUHAN UNIVERSITY OFTECHNOLOGY‐MATERIALS SCIENCEEDITION1000‐24130.312 材料科学:综合126 GLASS PHYS CHEM+ GLASS PHYSICS AND CHEMISTRY 1087‐65960.301 材料科学:硅酸盐。
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Chromatogr.HRC Journal of High Resolution ChromatographyHung. J. Ind. Chem.Hungarian Journal of Industrial Chemistry Hydrocarbon Process., Int. Ed. Hydrocarbon Processing, International Edition Hyperfine Interact. Hyperfine InteractionsIIEEE Sens. J.IEEE Sensors JournalInd. Diamond Rev.Industrial Diamond ReviewInd. Eng. Chem. Fundam.Industrial and Engineering Chemistry Research FundamentalsInd. Eng. Chem. Res. Industrial and Engineering Chemistry ResearchIndian J. Biochem. Biophys.Indian Journal of Biochemistry and Biophysics Indian J. Chem. Technol.Indian Journal of Chemical TechnologyIndian J. Chem., Sect A Indian Journal of Chemistry Section A: Inorganic, Bio-inorganic, Physical, Theoretical and Analytical ChemistryIndian J. Chem., Sect B Indian Journal of Chemistry Section B: Organic Chemistry including Medicinal ChemistryIndian J. Eng. Mater. Sci.Indian Journal of Engineering and Materials ScienceIndian J. Heterocycl. Chem.Indian Journal of Heterocyclic Chemistry Indian J. Pure Appl. Phys. Indian Journal of Pure and Applied PhysicsIndian J. Technol. Indian Journal of TechnologyIng. Quim. Ingeniera Quimica (Madrid)Infrared Phys. Technol.Infrared Physics and TechnologyInorg. Chem. Inorganic ChemistryInorg. Chem. Commun.Inorganic Chemistry Communications Inorg. Chim. Acta Inorganica Chimica ActaInorg. Mater.Inorganic MaterialsInorg. React. Mech.Inorganic Reaction MechanismsInorg. Synth.Inorganic SynthesesInsect Biochem. Mol. Biol. Insect Biochemisry and Molecular Biology Instrum Sci. Technol.Instrumentation Science and TechnologyInt. Biodeterior. Biodegrad.International Biodeterioration and BiodegradationInt. DATA Ser., Sel. Data Mixtures, Ser. A International DATA Series, Selected Data on Mixtures, Series AInt. J. Adhes. Adhes.International Journal of Adhesion and AdhesivesInt. J. Biochem. International Journal of BiochemistryInt. J. Biochem. Cell Biol.International Journal of Biochemistry and Cell BiologyInt. J. Bio-Chromatogr.International Journal of BiochromatographyInt. J. Biol. Macromol.International Journal of Biological MacromoleculesInt. J. Cast Met. Res.International Journal of Cast Metals Research Int. J. Chem. Kinet. International Journal of Chemical KineticsInt. J. Environ. Anal. Chem. International Journal of Environment Analytical ChemistryInt. J. Fatigue International Journal of FatigueInt. J. Heat Fluid Flow International Journal of heat and fluid flowInt. J. Heat Mass Transfer International Journal of Heat and Mass TransferInt. J. Hydrogen Energy International Journal of Hydrogen Energy Int. J. Immunopharmacol International Journal of Immunopharmacology Int. J. Inorg. Mater.International Journal of Inorganic Materials Int. J. Mass spectrom.International Journal of Mass SpectrometryInt. J. Mass Spectrom. Ion Processes International Journal of Mass Spectrometry and Ion Processes。
SCI收录的A类和B类相关期刊目录(材料和机械)1.材料科学(A类期刊)/SCI前50%序号 期刊名称(简) 期刊名称(全) ISSN号 影响因子学科1 PROG MATER SCI PROGRESS IN MATERIALS SCIENCE 0079‐6425 20.846 材料科学:综合2 NAT MATER NATURE MATERIALS 1476‐1122 19.782 材料科学:综合3 NAT NANOTECHNOL Nature Nanotechnology 1748‐3387 14.917 材料科学:综合4 MAT SCI ENG R MATERIALS SCIENCE & ENGINEERINGR‐REPORTS0927‐796X 14.400 材料科学:综合5 NANO LETT NANO LETTERS 1530‐6984 9.627 材料科学:综合6 ADV MATER ADVANCED MATERIALS 0935‐9648 8.191 材料科学:综合7 ADV FUNCT MATER ADVANCED FUNCTIONAL MATERIALS 1616‐301X 7.496 材料科学:综合8 SMALL SMALL 1613‐6810 6.408 材料科学:综合9 BIOMATERIALS BIOMATERIALS 0142‐9612 6.262 材料科学:生物材料10 MRS BULL MRS BULLETIN 0883‐7694 5.168 材料科学:综合11 CHEM MATER CHEMISTRY OF MATERIALS 0897‐4756 4.993 材料科学:综合12 ANNU REV MATER RES ANNUAL REVIEW OF MATERIALSRESEARCH1531‐7331 4.765 材料科学:综合13 SOFT MATTER Soft Matter 1744‐683X 4.703 材料科学:综合14 INT J PLASTICITY INTERNATIONAL JOURNAL OFPLASTICITY0749‐6419 4.516 材料科学:综合15 J MATER CHEM JOURNAL OF MATERIALS CHEMISTRY 0959‐9428 4.339 材料科学:综合16 CARBON CARBON 0008‐6223 4.260 材料科学:综合17 CRIT REV SOLID STATE CRITICAL REVIEWS IN SOLID STATE ANDMATERIALS SCIENCES1040‐8436 4.152 材料科学:综合18 CRYST GROWTH DES CRYSTAL GROWTH & DESIGN 1528‐7483 4.046 晶体学19 CRYST GROWTH DES CRYSTAL GROWTH & DESIGN 1528‐7483 4.046 材料科学:综合20 ORG ELECTRON ORGANIC ELECTRONICS 1566‐1199 3.879 材料科学:综合21 J APPL CRYSTALLOGR JOURNAL OF APPLIEDCRYSTALLOGRAPHY0021‐8898 3.629 晶体学22 ACTA MATER ACTA MATERIALIA 1359‐6454 3.624 材料科学:综合 22 ACTA MATER ACTA MATERIALIA 1359‐6454 3.624 冶金工程24 J MECH PHYS SOLIDS JOURNAL OF THE MECHANICS ANDPHYSICS OF SOLIDS0022‐5096 3.542 材料科学:综合25 INT MATER REV INTERNATIONAL MATERIALS REVIEWS0950‐6608 3.500 材料科学:综合26 CRYSTENGCOMM CRYSTENGCOMM 1466‐8033 3.468 晶体学27 NANOTECHNOLOGY NANOTECHNOLOGY 0957‐4484 3.310 材料科学:综合28 ACTA BIOMATER Acta Biomaterialia 1742‐7061 3.113 材料科学:生物材料29 DENT MATER DENTAL MATERIALS 0109‐5641 2.990 材料科学:生物材料30 MACROMOL BIOSCI MACROMOLECULAR BIOSCIENCE 1616‐5187 2.831 材料科学:生物材料31 DYES PIGMENTS DYES AND PIGMENTS 0143‐7208 2.796 材料科学:纺织32 CURR NANOSCI Current Nanoscience 1573‐4137 2.793 材料科学:综合33 PLASMONICS Plasmonics 1557‐1955 2.765 材料科学:综合34 ACTA CRYSTALLOGR D ACTA CRYSTALLOGRAPHICA SECTIOND‐BIOLOGICAL CRYSTALLOGRAPHY0907‐4449 2.620 晶体学35 J BIOMED MATER RES A JOURNAL OF BIOMEDICAL MATERIALSRESEARCH PART B‐APPLIEDBIOMATERIALS1549‐3296 2.612 材料科学:生物材料36 J ELECTROCHEM SOC JOURNAL OF THE ELECTROCHEMICALSOCIETY0013‐4651 2.483 材料科学:膜37 SCRIPTA MATER SCRIPTA MATERIALIA 1359‐6462 2.481 材料科学:综合38 SCRIPTA MATER SCRIPTA MATERIALIA 1359‐6462 2.481 冶金工程39 ACTA CRYSTALLOGR A ACTA CRYSTALLOGRAPHICA SECTION A0108‐7673 2.385 晶体学40 J NANOPART RES JOURNAL OF NANOPARTICLERESEARCH1388‐0764 2.338 材料科学:综合41 INTERMETALLICS INTERMETALLICS 0966‐9795 2.219 材料科学:综合42 INTERMETALLICS INTERMETALLICS 0966‐9795 2.219 冶金工程43 MECH MATER MECHANICS OF MATERIALS 0167‐6636 2.211 材料科学:综合44 MICROPOR MESOPORMATMICROPOROUS AND MESOPOROUSMATERIALS1387‐1811 2.210 材料科学:综合45 COMPOS SCI TECHNOL COMPOSITES SCIENCE ANDTECHNOLOGY0266‐3538 2.171 材料科学:复合46 ACTA CRYSTALLOGR B ACTA CRYSTALLOGRAPHICA SECTIONB‐STRUCTURAL SCIENCE0108‐7681 2.163 晶体学47 NANOSCALE RES LETT Nanoscale Research Letters 1931‐7573 2.158 材料科学:综合48 IEEE T NANOTECHNOL IEEE TRANSACTIONS ONNANOTECHNOLOGY1536‐125X 2.110 材料科学:综合49 ELECTROCHEMSOLID STELECTROCHEMICAL AND SOLIDSTATE LETTERS1099‐0062 2.109 材料科学:综合50 COLLOID SURFACE B COLLOIDS AND SURFACESB‐BIOINTERFACES0927‐7765 2.109 材料科学:生物材料51 EUR PHYS J E EUROPEAN PHYSICAL JOURNAL E 1292‐8941 2.025 材料科学:综合52 SOL ENERG MAT SOL C SOLAR ENERGY MATERIALS AND SOLARCELLS0927‐0248 2.002 材料科学:综合53PHOTONICNANOSTRUCTPhotonics andNanostructures‐Fundamentals andApplications1569‐4410 2.000 晶体学54PHOTONICNANOSTRUCTPhotonics andNanostructures‐Fundamentals andApplications1569‐4410 2.000 材料科学:综合55J NANOSCINANOTECHNOJOURNAL OF NANOSCIENCE ANDNANOTECHNOLOGY1533‐4880 1.987 材料科学:综合56 J CRYST GROWTH JOURNAL OF CRYSTAL GROWTH 0022‐0248 1.950 晶体学57 MICROSC MICROANAL MICROSCOPY AND MICROANALYSIS 1431‐9276 1.941 材料科学:综合58 CHEM VAPOR DEPOS CHEMICAL VAPOR DEPOSITION 0948‐1907 1.936 材料科学:膜59 J BIOMED MATER RES B JOURNAL OF BIOMEDICAL MATERIALSRESEARCH PART B‐APPLIEDBIOMATERIALS1552‐4973 1.933 材料科学:生物材料60 J MOL GRAPH MODEL JOURNAL OF MOLECULAR GRAPHICS &MODELLING1093‐3263 1.932 晶体学61 J MICROMECHMICROENGJOURNAL OF MICROMECHANICS ANDMICROENGINEERING0960‐1317 1.930 材料科学:综合62 J BIOACT COMPAT POL JOURNAL OF BIOACTIVE ANDCOMPATIBLE POLYMERS0883‐9115 1.917 材料科学:生物材料63 J MATER RES JOURNAL OF MATERIALS RESEARCH 0884‐2914 1.916 材料科学:综合64 SEMICOND SCI TECH SEMICONDUCTOR SCIENCE ANDTECHNOLOGY0268‐1242 1.899 材料科学:综合65 CORROS SCI CORROSION SCIENCE 0010‐938X 1.895 材料科学:综合66 CORROS SCI CORROSION SCIENCE 0010‐938X 1.895 冶金工程67 MATER CHEM PHYS MATERIALS CHEMISTRY AND PHYSICS 0254‐0584 1.871 材料科学:综合68 J BIOMAT SCI‐POLYM E JOURNAL OF BIOMATERIALSSCIENCE‐POLYMER EDITION0920‐5063 1.862 材料科学:生物材料69 APPL PHYS A‐MATER APPLIED PHYSICS A‐MATERIALSSCIENCE & PROCESSING0947‐8396 1.857 材料科学:综合70 SOFT MATER SOFT MATERIALS 1539‐445X 1.810 材料科学:综合71 J AM CERAM SOC JOURNAL OF THE AMERICAN CERAMICSOCIETY0002‐7820 1.792 材料科学:硅酸盐72 DIAM RELAT MATER DIAMOND AND RELATED MATERIALS 0925‐9635 1.788 材料科学:综合73 SYNTHETIC MET SYNTHETIC METALS 0379‐6779 1.788 材料科学:综合74 POLYHEDRON POLYHEDRON 0277‐5387 1.756 晶体学75 INT J DAMAGE MECH INTERNATIONAL JOURNAL OFDAMAGE MECHANIC1056‐7895 1.750 材料科学:综合76 J MAGN MAGN MATER JOURNAL OF MAGNETISM ANDMAGNETIC MATERIALS0304‐8853 1.704 材料科学:综合77 THIN SOLID FILMS THIN SOLID FILMS 0040‐6090 1.693 材料科学:膜78 THIN SOLID FILMS THIN SOLID FILMS 0040‐6090 1.693 材料科学:综合79 SURF COAT TECH SURFACE & COATINGS TECHNOLOGY 0257‐8972 1.678 材料科学:膜80 CURR OPIN SOLID ST M CURRENT OPINION IN SOLID STATE &MATERIALS SCIENCE1359‐0286 1.677 材料科学:综合81 COMPOS PARTA‐APPL SCOMPOSITES PART A‐APPLIED SCIENCEAND MANUFACTURING1359‐835X 1.662 材料科学:复合82 J BIOMATER APPL JOURNAL OF BIOMATERIALSAPPLICATIONS0885‐3282 1.651 材料科学:生物材料83 J NUCL MATER JOURNAL OF NUCLEAR MATERIALS 0022‐3115 1.643 材料科学:综合84 MATER LETT MATERIALS LETTERS 0167‐577X 1.625 材料科学:综合85 J INTEL MAT SYST STR JOURNAL OF INTELLIGENT MATERIALSYSTEMS AND STRUCTURES1045‐389X 1.610 材料科学:综合86 J MATER SCI‐MATER MJOURNAL OF MATERIALSSCIENCE‐MATERIALS IN MEDICINE0957‐4530 1.581 材料科学:生物材料87 J EUR CERAM SOC JOURNAL OF THE EUROPEAN CERAMICSOCIETY0955‐2219 1.562 材料科学:硅酸盐88 PROG ORG COAT PROGRESS IN ORGANIC COATINGS 0300‐9440 1.540 材料科学:膜89 OPT MATER OPTICAL MATERIALS 0925‐3467 1.519 材料科学:综合90 SMART MATER STRUCT SMART MATERIALS & STRUCTURES 0964‐1726 1.512 材料科学:综合91 MAT SCI ENG C‐BIO S MATERIALS SCIENCE & ENGINEERINGC‐BIOMIMETIC ANDSUPRAMOLECULAR SYSTEMS0928‐4931 1.486 材料科学:综合92 PHILOS MAG PHILOSOPHICAL MAGAZINE 1478‐6435 1.486 材料科学:综合93 PHILOS MAG PHILOSOPHICAL MAGAZINE 1478‐6435 1.486 冶金工程94 MATER RES BULL MATERIALS RESEARCH BULLETIN 0025‐5408 1.484 材料科学:综合95 ADV ENG MATER ADVANCED ENGINEERING MATERIALS1438‐1656 1.463 材料科学:综合96 MAT SCI ENG A‐STRUCTMATERIALS SCIENCE ANDENGINEERING A‐STRUCTURALMATERIALS PROPERTIES MICROST0921‐5093 1.457 材料科学:综合97 J ALLOY COMPD JOURNAL OF ALLOYS ANDCOMPOUNDS0925‐8388 1.455 材料科学:综合98 J ALLOY COMPD JOURNAL OF ALLOYS ANDCOMPOUNDS0925‐8388 1.455 冶金工程99 GOLD BULL GOLD BULLETIN 0017‐1557 1.450 材料科学:综合 100 GOLD BULL GOLD BULLETIN 0017‐1557 1.450 冶金工程101 MET MATER‐INT METALS AND MATERIALSINTERNATIONAL1598‐9623 1.424 材料科学:综合102 MET MATER‐INT METALS AND MATERIALSINTERNATIONAL1598‐9623 1.424 冶金工程103 NANOSC MICROSCTHERMNanoscale and MicroscaleThermophysical Engineering1556‐7265 1.417 材料科学:表征与测试104 APPL SURF SCI APPLIED SURFACE SCIENCE 0169‐4332 1.406 材料科学:膜 105 CELLULOSE CELLULOSE 0969‐0239 1.406 材料科学:纸与木材 106 CELLULOSE CELLULOSE 0969‐0239 1.406 材料科学:纺织 107 WEAR WEAR 0043‐1648 1.395 材料科学:综合 108 GRANUL MATTER GRANULAR MATTER 1434‐7636 1.370 材料科学:综合109 MACROMOL MATERENGMACROMOLECULAR MATERIALS ANDENGINEERING1438‐7492 1.368 材料科学:综合110 INT J APPL CERAM TEC International Journal of AppliedCeramic Technology1546‐542X 1.366 材料科学:硅酸盐111 LIQ CRYST LIQUID CRYSTALS 0267‐8292 1.362 晶体学112 CERAM INT CERAMICS INTERNATIONAL 0272‐8842 1.360 材料科学:硅酸盐 113 POLYM TEST POLYMER TESTING 0142‐9418 1.357 材料科学:表征与测试114 KOVOVE MATER Kovove Materialy Metallic Materials 0023‐432X 1.345 材料科学:综合 115 KOVOVE MATER Kovove Materialy Metallic Materials 0023‐432X 1.345 冶金工程116 Z KRISTALLOGR ZEITSCHRIFT FUR KRISTALLOGRAPHIE 0044‐2968 1.338 晶体学117 MAT SCI ENG B‐SOLIDMATERIALS SCIENCE ANDENGINEERING B‐SOLID STATEMATERIALS FOR ADVANCED TECH0921‐5107 1.330 材料科学:综合118 HYDROMETALLURGY HYDROMETALLURGY 0304‐386X 1.324 冶金工程119 J ELECTRON MATER JOURNAL OF ELECTRONIC MATERIALS0361‐5235 1.320 材料科学:综合120 J NON‐CRYST SOLIDS JOURNAL OF NON‐CRYSTALLINESOLIDS0022‐3093 1.319 材料科学:硅酸盐121 J NON‐CRYST SOLIDS JOURNAL OF NON‐CRYSTALLINESOLIDS0022‐3093 1.319 材料科学:综合122 COMPOS PART B‐ENG COMPOSITES PART B‐ENGINEERING 1359‐8368 1.311 材料科学:复合123 J SOL‐GEL SCI TECHN JOURNAL OF SOL‐GEL SCIENCE ANDTECHNOLOGY0928‐0707 1.300 材料科学:硅酸盐124 CURR APPL PHYS CURRENT APPLIED PHYSICS 1567‐1739 1.291 材料科学:综合125 J VAC SCI TECHNOL AJOURNAL OF VACUUM SCIENCE &TECHNOLOGY A‐VACUUM SURFACESAND FILMS0734‐2101 1.278 材料科学:膜126 METALL MATERTRANS AMETALLURGICAL AND MATERIALSTRANSACTIONS A‐PHYSICALMETALLURGY AND MATERIAL1073‐5623 1.278 材料科学:综合127 METALL MATERTRANS AMETALLURGICAL AND MATERIALSTRANSACTIONS A‐PHYSICALMETALLURGY AND MATERIAL1073‐5623 1.278 冶金工程128 SCI TECHNOL ADV MAT SCIENCE AND TECHNOLOGY OFADVANCED MATERIALS1468‐6996 1.270 材料科学:综合129 CMC‐COMPUT MATERCONCMC‐Computers Materials & Continua1546‐2218 1.241 材料科学:综合130 PHYS CHEM MINER PHYSICS AND CHEMISTRY OFMINERALS0342‐1791 1.238 材料科学:综合131 PHYS STATUS SOLIDI APHYSICA STATUS SOLIDIA‐APPLICATIONS AND MATERIALSSCIENCE0031‐8965 1.214 材料科学:综合132 OXID MET OXIDATION OF METALS 0030‐770X 1.212 冶金工程133 J THERM SPRAY TECHN JOURNAL OF THERMAL SPRAYTECHNOLOGY1059‐9630 1.204 材料科学:膜134 MODEL SIMULMATER SCMODELLING AND SIMULATION INMATERIALS SCIENCE ANDENGINEERING0965‐0393 1.158 材料科学:综合135 GEOSYNTH INT GEOSYNTHETICS INTERNATIONAL 1072‐6349 1.157 材料科学:综合136 J INCL PHENOMMACROJOURNAL OF INCLUSION PHENOMENAAND MACROCYCLIC CHEMISTRY0923‐0750 1.153 晶体学137 INT J ADHES ADHES INTERNATIONAL JOURNAL OFADHESION AND ADHESIVES0143‐7496 1.143 材料科学:综合138 COMP MATER SCI COMPUTATIONAL MATERIALS SCIENCE0927‐0256 1.135 材料科学:综合 139 NDT&E INT NDT & E INTERNATIONAL 0963‐8695 1.131 材料科学:表征与测试140 REV ADV MATER SCI REVIEWS ON ADVANCED MATERIALSSCIENCE1606‐5131 1.122 材料科学:综合141 INT J FATIGUE INTERNATIONAL JOURNAL OF FATIGUE0142‐1123 1.117 材料科学:综合 142 COMPOS STRUCT COMPOSITE STRUCTURES 0263‐8223 1.116 材料科学:复合143 INT J REFRACT MET H INTERNATIONAL JOURNAL OFREFRACTORY METALS & HARDMATERIALS0263‐4368 1.105 材料科学:综合144 INT J REFRACT MET H INTERNATIONAL JOURNAL OFREFRACTORY METALS & HARDMATERIALS0263‐4368 1.105 冶金工程145PROG CRYSTGROWTH CHPROGRESS IN CRYSTAL GROWTH ANDCHARACTERIZATION OF MATERIALS0960‐8974 1.091 晶体学146 PROG CRYSTGROWTH CHPROGRESS IN CRYSTAL GROWTH ANDCHARACTERIZATION OF MATERIALS0960‐8974 1.091 材料科学:表征与测试147 J MATER SCI JOURNAL OF MATERIALS SCIENCE 0022‐2461 1.081 材料科学:综合148 JOM‐US JOM‐JOURNAL OF THE MINERALSMETALS & MATERIALS SOCIETY1047‐4838 1.081 材料科学:综合149 JOM‐US JOM‐JOURNAL OF THE MINERALSMETALS & MATERIALS SOCIETY1047‐4838 1.081 冶金工程150 ADV APPL CERAM Advances in Applied Ceramics 1743‐6753 1.074 材料科学:硅酸盐151 J ENG MATER‐T ASME JOURNAL OF ENGINEERING MATERIALSAND TECHNOLOGY‐TRANSACTIONS OFTHE ASME0094‐4289 1.059 材料科学:综合152 POLYM COMPOSITE POLYMER COMPOSITES 0272‐8397 1.058 材料科学:复合153 SCI TECHNOL WELD JOI SCIENCE AND TECHNOLOGY OFWELDING AND JOINING1362‐1718 1.030 材料科学:综合154 SCI TECHNOL WELD JOI SCIENCE AND TECHNOLOGY OFWELDING AND JOINING1362‐1718 1.030 冶金工程155 CEMENT CONCRETERESCEMENT AND CONCRETE RESEARCH 0008‐8846 1.028 材料科学:综合156 MATER DESIGN MATERIALS & DESIGN 0261‐3069 1.028 材料科学:综合 157 MATER TRANS MATERIALS TRANSACTIONS 1345‐9678 1.018 材料科学:综合 158 MATER TRANS MATERIALS TRANSACTIONS 1345‐9678 1.018 冶金工程159 IEEE T ADV PACKAGING IEEE TRANSACTIONS ON ADVANCEDPACKAGING1521‐3323 1.011 材料科学:综合160 J ADHESION JOURNAL OF ADHESION 0021‐8464 1.000 材料科学:综合 161 J POROUS MAT JOURNAL OF POROUS MATERIALS 1380‐2224 1.000 材料科学:综合162 MINER PROCESSEXTR MMineral Processing and ExtractiveMetallurgy Review0882‐7508 1.000 冶金工程163 J MICRO‐NANOLITHMEMJournal of Micro‐NanolithographyMEMS and MOEMS1537‐1646 0.986 材料科学:综合164 EXP MECH EXPERIMENTAL MECHANICS 0014‐4851 0.985 材料科学:表征与测试165 EXP MECH EXPERIMENTAL MECHANICS 0014‐4851 0.985 材料科学:综合166 J COMPUT THEORNANOSJournal of Computational andTheoretical Nanoscience1546‐1955 0.981 材料科学:综合167 CEMENT CONCRETECOMPCEMENT & CONCRETE COMPOSITES 0958‐9465 0.962 材料科学:复合168 J COMPOS MATER JOURNAL OF COMPOSITE MATERIALS 0021‐9983 0.957 材料科学:复合169 J MATER SCI‐MATER ELJOURNAL OF MATERIALSSCIENCE‐MATERIALS IN ELECTRONICS0957‐4522 0.947 材料科学:综合170 MATER CHARACT MATERIALS CHARACTERIZATION 1044‐5803 0.932 材料科学:表征与测试171 J COMPUT‐AIDEDMATERJOURNAL OF COMPUTER‐AIDEDMATERIALS DESIGN0928‐1045 0.917 材料科学:综合172 MICROSYST TECHNOL MICROSYSTEM TECHNOLOGIES 0946‐7076 0.912 材料科学:综合 173 COMPOS INTERFACE COMPOSITE INTERFACES 0927‐6440 0.911 材料科学:复合174 IEEE T COMPON PACK TIEEE 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metal-organic papersActa Crystallographica Section E Structure Reports OnlineISSN1600-5368Tetramethylammonium tetraaquadichloro-chromium(III)trichloride dihydrateAnnika K.Eriksson,a*Barbara M. Casari a and Vratislav Langer ba Department of Inorganic Chemistry,GoÈteborg University,SE-41296GoÈteborg,Sweden,andb Department of Environmental Inorganic Chemistry,Chalmers University of Technology, SE-41296GoÈteborg,Sweden Correspondence e-mail:anneka@chem.gu.seKey indicatorsSingle-crystal X-ray studyT=173KMean'(Cr±O)=0.003AÊDisorder in main residueR factor=0.053wR factor=0.149Data-to-parameter ratio=18.1For details of how these key indicators were automatically derived from the article,see /e.#2004International Union of Crystallography Printed in Great Britain±all rights reserved The title metal-organic octahedral chromium compound,(C4H12N)2[CrCl2(H2O)4]Cl3Á2H2O,was synthesized accordingto the Palmer method.The chromium complex ion possessesmirror symmetry and has two axial ClÀions and fourequatorial water molecules.The octahedral complex cationand tetramethyl ammonium tetrahedra pack in a`parquet'-style pattern,with ClÀions and water molecules in betweenthe`bricks'.The structure is compared with aquapentachloro-chromate(III)complexes in the literature.CommentIn the last decade,octahedral complexes of chromium(III)have attracted increasing interest after the discovery of theircatalytic properties(Ogura&Yoshida,1987).Ligand-substi-tution reactions are slow in chromium(III)complexes,due totheir considerable kinetic stability.The title compound,(I),was synthesized according to themethod of Palmer(1954).The chromium(III)ion wasexpected to be coordinated by®ve ClÀanions and a watermolecule,as observed in the structures described for the Rband Cs aquapentachlorochromates(III)(Eriksson et al.,2004).However,the product was not stable enough to produce asimilar compound,as it was found to be amorphous andhygroscopic under ambient conditions.We believe that,due tothe hygroscopic effect,the red±violet aquapentachloro-chromate complex slowly turned,by ligand substitution,intothe green complex tetraaquadichlorochromium(III),whichseems to be more prone to crystallize as the title doublesalt.The tetraaquadichlorochromium(III)complex was®rstdescribed by Dance&Freeman(1965),and then by Morosin(1966),as the chromium(III)chloride complex[Cr(H2O)4Cl2]Cl(H2O)2.Another chromium(III)compound,Cs2[Cr(H2O)4Cl2]Cl3,was described by Nyburg et al.(1997)and is more similar to(I).The molecular structure of(I)is shown in Fig.1,andselected bond distances and angles are given in Table1.Thecation possesses mirror symmetry,with two axial ClÀions andfour equatorial water molecules.The three ClÀions each lieReceived27May2004Accepted1June2004Online12June2004on mirror planes.In each ammonium cation the N and two C atoms lie on mirror planes.The axial ClÀion Cl1is linked to one Me via CÐHÁÁÁCl hydrogen bonds.The equatorial water molecules are surrounded by three different ClÀions(Cl3,Cl4 and Cl5)and are linked by OÐHÁÁÁCl hydrogen bonds.The hydrogen-bonding network is rather complex and is summarized in Table2.The octahedral complex cation and tetramethylammonium tetrahedra pack in a parquet-style pattern,with ClÀions and water molecules in between the bricks,as shown in Fig.2. In complex(I),the CrÐCl and CrÐOH2bond distances are ca0.04AÊshorter than the equivalent distances in the aqua-pentachlorochromate(III)complexes(Eriksson et al.,2004). This can be explained by the lower electronegative contribu-tion from the smaller number of ClÀions,which results in tighter covalent bonding of the Cr III ion,and by fewer elec-tronic steric effects of the ClÀions(Fig.3).ExperimentalTetramethylammonium chloride and chromium(VI)oxide were dissolved in deionized water,according to the method of Palmer (1954).The product became amorphous and hygroscopic under ambient conditions and formed no crystals.In an environment with low relative humidity,single crystals of(I)were formed.Crystal data(C4H12N)2[CrCl2(H2O)4]Cl3Á2H2OM r=485.64Orthorhombic,Pnmaa=18.4374(2)AÊb=6.8192(1)AÊc=18.4330(2)AÊV=2317.55(5)AÊ3Z=4D x=1.392Mg mÀ3Mo K radiationCell parameters from8192re¯ections=2.2±27.3"=1.09mmÀ1T=173(2)KFragment of plate,green0.20Â0.08Â0.04mmData collectionSiemens SMART1K CCD area-detector diffractometer3scansAbsorption correction:multi-scan(SADABS;Sheldrick,2002)T min=0.811,T max=0.95827823measured re¯ections2822independent re¯ections2139re¯ections with I>2'(I)R int=0.087max=27.3h=À23323k=À838l=À23323Re®nementRe®nement on F2R[F2>2'(F2)]=0.053wR(F2)=0.149S=1.002822re¯ections156parametersH atoms treated by a mixture ofindependent and constrainedre®nementw=1/['2(F o2)+(0.09P)2+2.33P]where P=(F o2+2F c2)/3(Á/')max=0.001Á&max=0.73e AÊÀ3Á&min=À0.59e AÊÀ3metal-organic papersFigure2The octahedral complex cations and tetramethylammonium tetrahedra packed in a parquet-style pattern,with ClÀions and water molecules in between.Figure1The molecular structure and atom-numbering scheme for(I).Displace-ment ellipsoids are drawn at the50%probability level.Table1Selected geometric parameters(AÊ, ).Cr1ÐO2 1.992(2) Cr1ÐO1 2.008(3)Cr1ÐCl2 2.2889(14) Cr1ÐCl1 2.3133(14)O2iÐCr1ÐO291.17(15) O2iÐCr1ÐO1i89.52(11) O2ÐCr1ÐO1i178.97(11) O2iÐCr1ÐO1178.97(11) O2ÐCr1ÐO189.53(11) O1iÐCr1ÐO189.77(15) O2iÐCr1ÐCl288.81(8) O2ÐCr1ÐCl288.81(8)O1iÐCr1ÐCl291.98(8) O1ÐCr1ÐCl291.97(8) O2iÐCr1ÐCl190.13(8) O2ÐCr1ÐCl190.13(8) O1iÐCr1ÐCl189.10(8) O1ÐCr1ÐCl189.10(8) Cl2ÐCr1ÐCl1178.48(6)Symmetry code:(i)x Y12Ày Y z.Table2Hydrogen-bonding geometry(AÊ, ).DÐHÁÁÁA DÐH HÁÁÁA DÁÁÁA DÐHÁÁÁA O1ÐH1AÁÁÁCl5ii0.85(2) 2.27(3) 3.073(3)159(5)O1ÐH1BÁÁÁCl30.84(2) 2.20(2) 3.027(3)166(5)O2ÐH2AÁÁÁO4iii0.83(2) 1.88(2) 2.709(3)175(5)O2ÐH2BÁÁÁCl4ii0.84(2) 2.23(2) 3.036(3)163(4)O3ÐH3AÁÁÁCl5iv0.86(2) 2.27(2) 3.123(5)178(7)O3ÐH3BÁÁÁCl40.85(2) 2.26(2) 3.115(4)177(6)O4ÐH4AÁÁÁO30.85(2) 1.84(2) 2.679(6)172(7)O4ÐH4BÁÁÁCl3v0.85(2) 2.27(2) 3.112(4)178(6)C12ÐH12CÁÁÁCl5vi0.98 2.82 3.803(3)177C22ÐH22AÁÁÁCl1v0.98 2.74 3.715(2)172 Symmetry codes:(ii)x Y yÀ1Y z;(iii)12 x Y12Ày Y12Àz;(iv)xÀ12Y32Ày Y12Àz;(v) 1Àx Y12 y YÀz;(vi)xÀ1Y y Y z.The water H atoms were located in a difference Fourier map and were re®ned isotropically without any constraints.For the methyl groups,the CÐH distances(0.98AÊ)and CÐCÐH angles(109.5 ) were kept®xed,while the torsion angles were allowed to re®ne,with the starting position based on a threefold averaged circular Fourier synthesis.Some of the methyl groups(C12,C13,C22and C23)are positioned on a mirror plane and,as a result,the methyl H atoms are disordered.A common isotropic displacement parameter was re®ned for the methyl H atoms.Data collection:SMART(Siemens,1995);cell re®nement:SAINT (Siemens,1995);data reduction:SAINT and SADABS(Sheldrick, 2002);program(s)used to solve structure:SHELXTL(Bruker,2001); program(s)used to re®ne structure:SHELXTL;molecular graphics: DIAMOND(Brandenburg,2000);software used to prepare material for publication:SHELXTL.ReferencesBrandenburg,K.(2000).DIAMOND.Version2.1d.Crystal Impact GbR, Bonn,Germany.Bruker(2001).SHELXTL.Version 5.10.Bruker AXS Inc.,Madison, Wisconsin,USA.Dance,I.G.&Freeman,H.C.(1965).Inorg.Chem.4,1555±1561. Eriksson,A.K.,Casari,B.M.&Langer,V.(2004).Acta Cryst.C60,i40±i42. Morosin,B.(1966).Acta Cryst.21,280±284.Nyburg,S.C.,Soptrajanov,B.,Stefov,V.&Petrusevski,V.M.(1997).Inorg. Chem.36,2248±2251.Ogura,K.&Yoshida,I.(1987).Electrochim.Acta,32,1191±1197. Palmer,W.G.(1954).Experimental Inorganic Chemistry.Cambridge University Press.Sheldrick,G.M.(2002).SADABS.Version2.03.University of GoÈttingen, Germany.Siemens(1995).SMART and SAINT.Versions4.0.Siemens Analytical X-ray Instruments Inc.,Madison,Wisconsin,USA.metal-organic papersFigure3A comparison of the aquapentachlorochromate(III)and tetraaquadi-chlorochromium(III)complexes.Displacement ellipsoids are drawn atthe50%probability level.。