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排水外文翻译

排水外文翻译
排水外文翻译

毕业设计(论文)外文资料翻译

系:建筑工程学院

专业:给水排水工程

姓名:肖梓楠

学号:2012303030237

外文出处:journalhomepage:www.elsevier.

(用外文写)

com/locate/fuel

附件: 1.外文资料翻译译文;2.外文原文。

褐煤火力发电厂排放的自然放射性核素和重金属环境评价

D. Karamanis a,b,*, K. Ioannides b,c, K. Stamoulis c

a Department of Environmental and Natural Resources Management, University of Ioannina, 30100 Agrinio, Greece

b Physics

Department, University of Ioannina, 45110 Ioannina, Greece

c Archaeometry Center, University of Ioannina, 45110 Ioannina, Greece

签订协议

文章历史:

2009年一月获得14

2009年2月接受修订19

2009年2月接受20

2009年3月可用网上13

1.介绍

褐煤是化石燃料的主要来源,是能源生产的主要来源。在希腊,电功率超过要求的60%是产生在褐煤电厂,每年消耗超过6000万吨的褐煤,生产约1300万吨的总灰分[ 1 ]。希腊的主要矿区是褐煤中心的西方马其顿,在四大矿山(南部,主要amyntaion Kardia,褐煤褐煤开采领域)开发经营(总功率4438兆瓦)(图1)。然而,在使用植物燃烧褐煤生产时,除了电能,残留包含有害成分。

发电厂的环境污染在世界各地的影响一般从土地的使用、健康危害和空气、油、特别是水源[ 2 ]。除了主要污染物(微粒,碳,硫和氮氧化物),褐煤燃烧可能产生潜在的有毒微量元素的排放量[ 3,7 ]。此外,褐煤发电厂是主要来源之一,技术增强自然会产生放射性材料(TENORM)[8,9]。

虽然许多已经进行了测量,在关系到全球大气排放上,放射性水平及沉积物的重金属浓度的评价研究对于其他可能排放在周围的环境中的污染物相当少。例如,火山灰和锅炉灰渣除去沉淀要用水冲灰池,其中的元素可以从灰浸出和径流进入水体环境。此外,发电厂使用大量的水供冷却,它使用后,流入附近的河流和湖泊。水是通过蒸发浪费占有一个大百分比(60—70%),而其余的水则返回到盆地[ 10 ]。除了从站的涡轮机散发的热量,冷却水中可能含有无机和有机化合物的浓度必须保

持在环境ACC可以接受的限制。在许多情况下,煤的副产品是暴露于水中的[11,12];煤炭洗选过程中,水抽出的矿区,都面临雨或水喷雾,运输水煤浆和处理灰、定期锅炉管清洗和灰处理都用到水。从这些不同的子过程中,主要微量元素的任何浸出都可能会导致水的摄入量和释放从湿冷电厂的水质量的大幅下降。因此,发电排放的水可能会造成重大的环境污染,影响到周围的地区,除了大气排放,由于这些环境干扰的来源的多样性[ 13 ],其他都没有进行评估。

以上考虑的连续使用排放海域与近年来灌溉水资源减少的事实相结合,目前的工作目的为了确定在排放水中微量金属和放射性同位素的浓度和任何环境影响评价中主要褐煤周边地区的发电计划。此外,本研究的第二个目的是调查溶解行为和微量元素的赋存状态和识别出微量元素从煤灰的提取的可能,在从褐煤在废水浓度升高的发电厂。

D. karamanis等人。燃油88(2009)2046 - 2052 2047

Fig. 1. The lignite center of Western Macedonia in Greece with the major

lignite-fired power plant of ‘‘Agios Dimitrios” [10].

*相应的作者。地址:管理,艾奥尼纳大学,30100 agrinio环境和自然资源部,希腊。电话:+ 30 26410 74102;传真:+ 30 26410 39576。

电子邮件地址:dkaraman@cc.uoi.gr(D. karamanis)。

0016-2361 / $ -见前面的问题2009 Elsevier公司保留所有权利。关键词:10.1016/j.fuel.2009.02.032

2048 D. karamanis等人。燃油88(2009)2046 - 2052

2.材料与方法

2.1.取样和样品制备

这项研究是从一种叫“Agios Dimitrios”的能量植物进行研究(1595兆瓦),NW 希腊(E 2 11 55.400’,22.900’N 40L)(图1)。这种植物,在希腊产量最大,使用Aliakmon的河水,并且在初级处理后将产生的污水排放在vegoritis湖,沉淀后取样[ 14 ]。在2004年10月到2006月5月期间进行测量。这场测量包括温度、电导率、pH值、溶解性总固体(TDS)。地表水样品(3升)以确定重金属的含量、总α、总β和226Ra的活动。样品收集在聚乙烯瓶,送到实验室,通过0.45 1米的过滤器过滤,并酸化到ph值为2的体系。从灌溉领域的沉淀物和土壤样品收集装在塑料袋里并在105LC里干燥。

2.2.分析方法

阿尔法和贝塔活动水残留过滤后的测定与堪培拉2004年气体正比计数器和叙述的方法。以800 V和–B模式在1500 Vβ高原操作α模式(1000者),进行总α和β活动的水样测定液体闪烁计数[ 16 ]。五百毫升的水被蒸发到几毫升,然后转移到20毫升容量的塑料瓶。样品蒸发至干燥,在50液晶和2 M磷酸和Ultima GOLDTM AB鸡尾酒16毫升4毫升加入。三碳水化合物3170tr / SL液体闪烁计数器,在A-B 模式与脉冲衰减鉴频器130设置操作,用于分析。最低检测限(MLD)为0.009和0.015贝可L 1总α和β活动,时间分别为700 min计数时间。通过对MnO2薄膜涂

层和α光谱[ 17 ]吸附溶解的镭同位素的测定。简而言之,聚酰胺片浸泡在2%(w/v)KMnO4溶液在60 LC 2 h.与聚酰胺IDE–MnO2膜钳座沉浸在1升的玻璃烧杯含有典型的容积0.5 L的水样,用预调pH值为7.5。该溶液搅拌2天以上。在手术结束时,样品洗净,用600或900平方毫米的低背景PIPS探测器接近几何参数测量。238U、226Ra,用22% c-spectroscopy HPGe探测器测定沉积物和土壤样品第二百三十二、40K。在测量样品干燥105 LC 24 h,然后均匀通过破碎、筛分为<0.5毫米的分数。每一个山姆人就转移到圆柱形塑料容器的体积为200立方厘米,体重和密封。密封样品存放4周以上才算让226Ra和224Ra和短命衰变产品达到长期平衡。用具体的活动是来自第二百三十四的γ射线的加权平均(63.3 keV和92.8 keV的(4.8%)(5.58%))。确定从185 keVγ线校正的226Ra的贡献后,235U的具体活动。镭-226的具体活动得到从295.2 keV的活动确定的加权平均(19.3%),351.9 keV(37.6%)keV的γ射线从214Pb和609.3 keV的(46.1%)和1764。(15.4%)从5 keV千214Bi。238.6 keVγ射线(4.87%)和(84.5%)212Pb,583.1 keV和911.1 keV的208tl(25.8%)228Ac用于测定—第二百三十二国的具体活动。40K是从1460.8 keV的确定(11%)γ射线。效率刻度是每形成与国际原子能机构的标准参考源虽然iaea-cu-2006-03全球开放水平测试研究放射性核素的测定。

溶解的微量金属元素(V,Cr,Mn,Fe,Ni,Cu,Zn,Pb和Mo)用X射线荧光法测定的优化(XRF)他们的PYR rolidinedithiocarbamat富集法ES(PDC)纤维素过滤器[ 18 ]。水的体积则为0.8至1升混合遗传算法的LG 10,作为内部标准,pH值为3.7。沉淀通过添加新鲜制备铵溶液10毫升氨基甲酸酯金属片(1%)。大力搅拌一小时后,氨基甲酸酯被过滤通过准直的微孔过滤器收集(0.45流明的孔径、直径47毫米、12毫米的有效直径)。过滤器干燥80 LC然后直接计算在艾奥尼纳大学XRF单元ED-XRF光谱仪。光谱仪包括一个80平方毫米的Si(Li)探测器,109CD 环形放射源和标准nim-bin电子。该系统被校准的金属标准和参考样品bcr-715验证。以这种方式,钒,铬,锰,铁,镍,铜,锌,铅和钼的浓度测定。

统计分析采用统计软件包SPSS 12进行(SPSS公司,芝加哥,伊利诺斯,Windows 版本。12)。

3.结果与讨论

燃烧过程中,燃烧的灰烬不显著富集所有可燃物的结果,这是将底灰之间(或渣),那落在锅炉和粉煤灰,悬浮于烟气和挥发性元素和化合物蒸气。不燃性的要素包括自然喜欢在褐煤[ 19 ]目前。如果褐煤或飞或底灰混合排放水域悬浮物、放射性升高量应在排放水进行观察研究。事实上,测量和测试活动对微粒残留水过滤后750±400 BQ公斤1和1540±500 BQ公斤1收集总α,分别。这些值是比喻那些观察到Bü柯在燃煤电厂粉煤灰的[ 20 ]。平均总的活动进行了计算,以包括每个值(低于20%)的实验误差的加权平均。在值的误差是标准偏差,而不是加权标准偏差,以说明所观察到的数据传播。此外,总α活性而对称分布的偏度值显示(0.21),从2018凋亡分布平坦(1.61)。最后是预期的时空环境分析由于多种因素在特定参数测定的影响。此外,总活性测定的目的是为了有进一步的详细的同位素分析的必要性籼稻等。由于升高的值进行了观察,一个彻底的同位素分析,进一步进行沉积物和下面的描述。

通过测量总α进行排放海域的放射性总β和226Ra的活动状态。结果列在表1中包括平均浓度与相关的标准偏差和最大值和最小值。水总α测量范围,β和226Ra 活动0.062–0.268 BQ L 1,L 1和0.064–0.268 BQ 0.021–0.062 BQ L 1,分别。测得的样品的平均镭活性被发现48.2±6.2 MBQ L 1是震级高于希腊[ 18 ]与R的河水,典型的226Ra的水平,对于表面水域被污染的粉煤灰库[ 21 mljac和krizman结果]。此外,统计分析显示,总α和226Ra活动与水的温度和电导率的关系。

D. karamanis等人。燃油88(2009)2046 - 2052 2049 Table 1

Physicochemical characteristics, trace elements and radioactivity parameters of the discharge waters of Agios Dimitrios power plant in Greece.

Values-outlet channel Typical values for water streams [28]

or river waters [29],

Range Mean ± SD

European means [30]

and world average [31]

总β活性与水的温度,电导率和TDS自40K在总β活性的主要成分。显著的季节性差异只在总β放射性浓度(f3,8 = 11.6 [ 0.019 ] P = f的方差比和P的概率水平的分析方差)。

由于排放水用于灌溉,通道底部沉积物和土壤样品采集的灌溉领域的活动进行了测量的伽玛能谱。表2给出了铀、镭、钍、钾同位素的测定平均值。活动的238U,

235U 和226Ra 沉积物几乎两倍高于土壤,表明一个放射性浓集在沉积物中的褐煤和/或灰的存在。

Water Temperature (LC)

pH Conductivity (l S cm 1) TDS (mg L 1) V (l g L 1) Cr (l g L 1) Mn (l g L 1) Fe (l g L 1) Ni (l g L 1) Cu (l g L 1) Zn (l g L 1) Mo (l g L 1) Pb (l g L 1) Gross alpha (Bq L 1) Gross beta (Bq L 1) 226Ra (Bq L 1

) 然而,这种增强不到希腊飞灰[22,23]发现污染水平的铀矿山环境或沉积物中的磷酸盐加工厂[ 24 ]下游。

类似于水,增强226Ra 含量也发现沉积物中(表2)但低于10在欧洲产生的灰烬中226Ra 活度浓度平均值EAN 的大陆国家(158±62 Bq/kg ,95%置信)[ 25 ]。水和沉积物之间的分布从226Ra ,KD 表示,发现1108±151毫升每克、在协议对mljac 和krizman [21] 。土壤样品中226Ra 的平均值为26.8±0.8和同意与希腊土壤中发现的平均值[ 26 ]。因此,土地灌溉用水增加溶解镭浓度并未导致在任何增强土壤中的镭。在土壤沉积物的平均40K 和第二百三十二浓度较高,因为土壤富含粘土通常是高钾和钍。

平均同位素238U 和235U 活动率为18.4±4.7沉积物样品和土壤样品中24.3±4.4。因此,在与自然的RA ,这是21.44个0.02 [ ] [ 27 ]中的错误,在良好的协议。 Table 2 Activity of 238U, 235U,

226Ra, 232Th and 40K in channel bottom sediments and the

19.1–31.9 24.6 ± 1.3 8.17–8.39

8.28 ± 0.15 7.50 [30] 706–1194 996 ± 45

446 [30] 572–1111 847 ± 59

0.2–3.4 1.6 ± 0.3

0.71 [29] 0.2–5.2 1.2 ± 0.7

0.4–1.1 [28]; 0.7 [29] 0.6–8.3 2.7 ± 0.9

0.2 [28], 34 [29] 12.4–134.4 68.8 ± 14.5

17 [28], 66 [29] 1.6–7.8 3.5 ± 0.6

0.056–0.17 [28]; 0.8 [29] 1.6–8.7 3.6 ± 0.7

1.48 [29] ; 1.00 [31] 1.0 – 70.2 11.1 ± 7.4

0.1–4.5 [29]; 0.6 [29]; 10 [31] 3.4–54.5 32.4 ± 6.5

0.4 [29] 0.1–2.3 1.0 ± 0.3

0.04–0.75 [28]; 0.2 [31] 0.06–0.27 0.14 ± 0.03

0.06–0.27 0.19 ± 0.03

0.02–0.06 0.048 ± 0.006

Soil 29.2 ± 2.2 1.2 ± 0.2 26.8 ± 0.8 36.8 ± 1.5 492.6 ± 25.8

Sediments 57.1 ± 9.5 3.1 ± 0.6 53.2 ± 2.9 14.6 ± 0.4 99.6 ± 7.2

该238U/226Ra平均活动率为1.07±0.46和1.09±0.09在沉积物和土壤,分别说明所有的放射性核素之间的平衡的存在样品中铀系列的。

为了表示活动由于226Ra,第二百三十二和40K的由一个单一的数量,考虑到与他们相关的辐射危害,常见的镭当量活动(Raeq)W如计算为[ 9 ]:

居住区环境质量?cra-226t1:43cth-232t0:07ck-40e1T

用活度浓度贝可公斤1表示C。该测定值114贝可公斤1土壤低于370贝可公斤1限值。从天然存在的放射性核素的外照射评价,室外空气吸收率由于对地面γ射线在地面1米以上的计算从226Ra、第二百三十二和40K的浓度值,假设其他的放射性核素,如137Cs、90Sr和铀-235衰变系列可以为他们贡献很小的总剂量从BAC 忽视环境的地方。关键组,其中个人剂量进行评估,是对群体成员的代表,表现出最高的影响从曝光到电厂废水。它是由农民,有在各自领域区使用土地灌溉水通道。为了计算从所收集的样品中的剂量率从研究领域,下列关系被使用[ 9 ]

D?0:462crat0:604ctht0:0417cke2T

其中D是NGY 1和CRA,CTH和CK在BQ公斤1活性浓度,假设所有的镭-226衰变产物和第二百三十二是在放射性平衡与他们的后代。值为55±4 NGY 1土壤与估计世界平均外部曝光率从陆地γ辐射57 NGY 1和希腊的平均同意(56 NGY 1)。在土壤中的活动,由于在土壤中的活动,得到的年有效剂量当量计算使用以下关系[ 9 ]。

E?T Q D 10 6 3Te

其中E是mSv Y 1有效剂量当量,Q为0.7 SV GY 1 Y 1的成年人接触环境中能量的伽玛射线值,T是时间一年,即8760是室外占用系数(0.2),且是剂量率。平均年有效剂量当量为0.068±0.005 mSv Y 1,这是在协议的外部世界平均年有效剂量(即0.07毫西弗Y 1)。

2050 karamanis等人D.。燃油88(2009)2046 - 2052

根据镭当量活动结果,空气吸收剂量率,年有效剂量,天然放射性核素从氏排出水环境效应热电厂被认为是可以忽略不计。

在放电水域中溶解的金属浓度的结果在表1,而他们的变化在测量期间如图2所示。每一种金属都会在浓度范围内表现出较大的变化,因为大标准偏差值的反映,

而有些金属比世界平均水平显示更高的值前或在水流附近的燃煤发电厂[ 31 ]。然而,该值仍低于标准和准则的最大浓度连续浓度(CCC)美国环保署水质标准[ 31 ]值。

Fig. 3. ‘‘Box plot” graphic

representation of metals

concentration in the discharge

waters of the coal-fired power plant.

由于微量元素发生在褐煤中的

有机物质和无机灰'impurities”

元素释放到环境中的可能性,以

及作为一个有效的褐煤洗米减轻

这种释放途径,是由一个元素的

大小与包含在褐煤[ 32 ]。本研

究的结果表明,所有的研究金属,除钼,无论是沉淀后溶解由于增加的水通道的PH 值或不提取从褐煤/灰最初。由于微量金属大多与铁氧化物和残留硅酸盐材料[ 33 ],最小的金属浸出,可以预期在自然条件下(中性至碱性PH值)由于惯性铁的氧化物和硅酸盐的残余不溶性。

让一个更好的可视化的金属浓度数据的变化范围,平均浓度,以及不同金属的比较,一盒图表示应用于。在图3所示的结果可以在三个集中类别:高(铁,钼),中(铜,锰,镍和锌)和较低的(铬,钒和铅)进行分类浓度。此顺序是相关的两个以上的微量元素在褐煤灰分和水溶性馏分中的元素的灰分。此外,丰富的微量元素锰,铜,镍,氮,铬,钒是相同的顺序在灰(100 - 600),而钼和铅是一个订单较低[ 34 ]。根据水浸实验pentarietal。35、微量元素的水溶性成分分为三类,第一类含1%以上的组分元素为铁,其次包括元素,如铜,镍,锌,锰与水溶性组分的0.01 - 0.8%,而铬和铅的分数是一个顺序(0.001 - 0.01%)。而且,这个顺序遵循河水中微量元素的化学元素丰度[ 29 ]与钼浓度的异常。钼值在自然水域比较高,这可以归因于增加的钼浓度的褐煤灰烬的' ' Dimitrios”电站(级高一阶她比普通土壤)[ 36 ]和提高浸出率从褐煤煤灰[37,38]。

的统计分析显示,铅与铁(皮尔森相关:0.841 [磷= 0.004 ])和铜与锌(皮尔森相关)的高相关性:0.864 [磷= 0.003 ])。观察两无相关性痕量金属的浓度和物理化

学或放射性参数,表明它们的浓度的变化的主要离子的去耦。分层聚类分析(HCA)进一步探讨微量元素成分的关系,放射性物化参数。皮尔森相关系数被用来测量的相似性(或差异)是一类变量和集群。将中位数的方法应用于链接集群。四集群进行区分(图4):第一类主要是由放射性物化法和参数;第二类包括铜、镍、锌、锰第三,铁、Mo、Pb、V、Cr第四。这种聚类同意协会建议在大多数煤或根据分类元素,这组元素根据其首选的主机相。

Fig. 2. Trace metals in the discharge waters of the coal-fired power plant.

D. karamanis等人。燃油88(2009)2046 - 2052 2051

图4。对燃煤电厂排放

的水微量元素成分的

凝聚层次聚类分析。

Fe Mn和Mo是铁和氧

化还原敏感元素。锰

通常替代钙、铁方解

石、铁白云石、或

SID利,但它也可以是有机结合的,或发生在粘土或铁?硫化物[ 32 ]。V和Cr是亲石元素,一般在粘土(特别是伊利石)和不常见的重矿物,如铬铁矿、钛铁矿、磁铁矿、或尖晶石[ 32 ]。他们也都发生在有机碎屑的非晶氧化物和氢氧化物。铜、镍和锌是亲硫元素,已发现肺与希腊灰[ 39 ]。然而,在高pH值的那些排出的水是非

常轻微的变化观察。

4.结论

在一个被确定的值的放射性在一个褐煤燃煤电厂排放的水不能被认为是典型的和可比的,通常观察到的河流和河流。在排放水域的226Ra浓度为至少一个或一个数量级高于天然水体中226Ra在底部沉积物浓度被发现高于F在自然水域沉积物中发现。然而,土壤中的灌溉水增强放射性核素的浓度是相似的原状土和在妈妈没有影像学的重要性耳鼻喉。

此外,一些重金属的检测在水域排放值显示比世界平均背景浓度或水溪附近燃煤功率更高的价值植物。这种贡献途径应考虑在土壤中的浓度升高,通常观察到周围的地区燃煤电厂。

Acknowledgements

This research was co-funded by the European Union in the framework of the program ‘‘Pythagoras I” of the ‘‘Operational Pro-gram for Education and Initial V ocational Training” of the 3rd Com-munity Support Framework of the Hellenic Ministry of Education, funded by 25% from national sources and by 75% from the Euro-pean Social Fund (ESF). The authors thank the Greek Public Power Corporation for providing the information concerning the channel output and the anonymous reviewers for their patient reading of the manuscript and their invaluable comments.

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附件2:外文原文

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