O H
C O O H
3
1.
CH 3CH 2COCl
2.NH 3
HCl
COOH
(CH 3)2CHOH
+3.
浓H 2SO 4
NHCH 2CH 3
4.
+
CH 3I
5.
CH Cl
NaCN
LiAlH 4
SH
NaHCO 3
6.
N
+
HCl
7.
8.
N
CH 3
H 3
Cl 2 ,NaOH
PCl 5
CH 3CH 2CHCH 2COOH
CH 3
9.2
KMnO 425
10.
O O
O
+
11.
3
CH
3
O
C
12.CH 3CH 2
O +
HO CH 2CH 2
HO
TsOH
13.
C 2H 5OC COC 2H 5O O
+CH 3COC 2H O
C 2H 5ONa
14.
2
1.
CO O H
O H
2 CH 3CH 2MgBr
NHCH 3
2.CH 3O
CH 3COCl
HNO
33.
24
4.
CH 3CH 2SH
+
NaOH
CHO
5.CH 3O
CH 22
6.
NH 2
NaNO 2, HCl CuBr / HBr
CH CHO
N
+
HNO 3
H 2SO 4 (98%)
7.
N
Na +C 2H 5OH
2
8.
9.
CH 2CHO 2COOH
300℃
KMnO4
CH 3CH 2
②10.Cl 2
12.
Fe + HCl O O O
11.
+
NO 2NaNO 2HCl
CH 2CH 2CH 2CH 2
COOH
COOH 13.
2 CH 3CH 2CH 2CH
O
10% NaOH
5 ℃
14.
COOH
COOH
1.
HOCH 2CH 2CH 2COOH
Na
322.
ClCH 2NaCN
CH 3CH 2OH H 2
SO 4
3.
4.
NH 2
2SO 4
H 2O, OH
N
H
①过量CH 3
I ①过量②湿CH 3I 5.
Ag 2O
Ag 2O
NH 2
3Br 2
NaNO 2, HCl H 3PO 2H 2O
6.
7.
CH 2Br S
H 2N H 2N
+
①②+
NaOH, H 2O
NaOH
8.
N
CH 3
H
+
PCl 5NH 3
Br
2 ,NaO H
9.
2 HI
2 NaCN
NH 2
NaNO 2, HCl
CuCN
3
H 3O +
10.
CH 3CH 2OH
CH Cl
NaCN
LiAlH 4
(CH 3CO)2O
11.
N 2 Cl
SnCl 2 + HCl
12.
O H
C O O H
1.
COCl
2.C 2H 5OH
3
+
NaOH
COOH
+
3.浓H 2SO 4
HOCH 2CH 2OH
N(CH 2CH 3)2
4.
+CH 3I
5.
CH 2Cl
NaCN
NaO H/H 2O
HCl
①②6.
CH 2O 17 H 35
CHO CC 17 H 35
2O CC 17 H 35
O
O O 3 NaO H
+
NH 2
NaNO 2, HCl
CuCN
H 3O +
7.
8.22
HNO 32CH 3I
K 2S
O
+
COOCH 3
3
N H
+
(CH 3CO)2O 150-200℃
9
CH 3COONO 2
10
CH 3
2Pd-BaSO 4
喹啉-硫
11
KMnO4
PCl 3
HOOC COOH
4
Ag 2O
②12
N H
3I 2①②
3I 2①②13
CH 3CH 2CH CH 3
3)3OH
14.
