Shipping Process of Lithium metal Batteries
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锂电池应用工艺流程化学英文回答:Lithium Battery Applications and Manufacturing Process.Lithium batteries are widely used in electronic devices due to their high energy density, lightweight, and longcycle life. They are commonly found in applications such as: Portable electronics (e.g., smartphones, laptops)。
Electric vehicles.Power tools.Medical devices.Manufacturing Process.The manufacturing process of lithium batteries involvesseveral key steps:1. Materials Preparation: The cathode and anode materials are synthesized using electrochemical or chemical methods.2. Electrode Fabrication: The cathode and anode materials are mixed with a binder and solvent to form a paste, which is then coated onto metal foils.3. Cell Assembly: The electrodes are separated by a porous separator and assembled into a laminated structure.4. Electrolyte Filling: The cell is filled with an electrolyte solution to facilitate ion movement.5. Aging and Formation: The cell undergoes a process of aging and formation to stabilize its performance.Chemistry.Lithium batteries rely on the electrochemical reactionbetween the cathode and anode materials. The cathode typically consists of a lithium metal oxide, while the anode is made of graphite or a lithium-ion-containing compound.During charging, lithium ions are extracted from the cathode and intercalated into the anode. This process creates a difference in electrical potential between the electrodes.During discharging, the lithium ions flow from the anode to the cathode, releasing energy and generating electrical current.Requirements.Specific requirements for lithium battery manufacturing and applications include:Materials Purity: High-purity materials are essential for cell performance and safety.Quality Control: Strict quality control measures ensure consistent battery quality and reliability.Safety Standards: Lithium batteries must meet stringent safety standards to prevent potential hazards such as fire or explosion.中文回答:锂电池应用和工艺流程。
Guidance DocumentTransport of Lithium Metal and Lithium Ion BatteriesRevised 10 August 2009IntroductionThis document is based on the provisions set out in the 2009/2010 Edition of the ICAO Technical Instruction for the Safe Transport of Dangerous Goods by Air and the 50th Edition (2009) of the IATA Dangerous Goods Regulations (DGR).The purpose of this document is to provide guidance for complying with provisions applicable to the transport by air of lithium batteries that take effect from 1 January 2009 as set out in the DGR. Specifically the document provides information on: Ê Definitions;Ê Classification;Ê Exceptions;Ê Special Provisions;ÊPackaging provisions for lithium batteries;Ê Prohibitions;Ê Passenger Provisions;DefinitionsLithium Battery – The term “lithium battery” refers to a family of batteries with different chemistries, comprising many types of cathodes and electrolytes. For the purposes ofthe DGR they are separated into:ÊLithium metal batteries. Are generally primary (non-rechargeable) batteries that have lithium metal or lithium compounds as an anode. Lithium metal batteries aregenerally used to power watches, calculators, cameras, etc.;Example Lithium Metal BatteriesÊLithium-ion batteries (sometimes abbreviated Li-ion batteries). Are a type of secondary (rechargeable) battery commonly used in consumer electronics. Also included within lithium-ion batteries are lithium polymer batteries. Lithium-ionbatteries are generally found in mobile telephones, laptop computers, etc.Example Lithium Ion BatteryTransport as CargoClassificationLithium batteries are classified in Class 9 – Miscellaneous dangerous goods as:Ê UN 3090, Lithium metal batteries; andÊ UN 3480, Lithium ion batteriesor if inside a piece of equipment or packed separately with a piece of equipment as:Ê UN 3091, Lithium metal batteries contained in equipment; orÊ UN 3091, Lithium metal batteries packed with equipment; andÊ UN 3481, Lithium ion batteries contained in equipment; orÊ UN 3481, Lithium ion batteries packed with equipment.In the absence of exceptions, these batteries must be shipped in quantities that comply with the limitations contained in the Regulations (see DGR Table 4.2). Also, they must be contained in specification packaging prescribed by the ICAO Technical Instructions and IATA Dangerous Goods Regulations. A completed package must display a Class 9 hazard label in addition to markings that identify the applicable proper shipping name and UN number. A shipper must document the shipment using a Shipper’s Declaration for Dangerous Goods.ExceptionsSmall lithium metal and lithium ion batteries are excepted from most of the requirements of the ICAO Technical Instructions and IATA DGR provided that they comply with all of the requirements set out in Part 1 of Packing Instructions 965, 966 and 967 for lithium ion batteries and Part 1 of Packing Instructions 968, 969 and 970 for lithium metal batteries in the 50th edition of the IATA DGR.Packages containing lithium batteries, or lithium batteries contained in, or packed with, equipment that meet the provisions of Part 1 of these packing instructions are not required to have a Class 9 hazard label and there is no requirement for a Shipper’sDeclaration for Dangerous Goods for consignments of these batteries. However, in the event of an incident involving these batteries, the incident reporting requirements apply. Note:Only batteries that have successfully passed the test procedures of Part III, Sub-Section 38.3 of the UN Manual of Tests and Criteria qualify under this exception. This is also true for so-called “OEM” or “aftermarket” batteries. Any battery manufacturer or distributor should be able to provide documentation confirming that the batteries have been so tested.Lithium metal and lithium ion batteries larger than those described in Part 1 of the applicable packing instruction must be assigned to Class 9 and consigned as UN 3090 (Lithium metal batteries), UN 3480 (Lithium ion batteries), UN 3091 (Lithium metal batteries contained in equipment or Lithium metal batteries packed with equipment) or UN 3481 (Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment). All applicable requirements contained in the IATA Dangerous Goods Regulations relating to these commodities must be complied with, including the training requirements; a “Shipper’s Declaration for Dangerous Goods” must be issued, and packages must bear the Class 9 hazard label.Special ProvisionsLithium batteries are also subject to a number of specials provisions which may allow for the transport of batteries other than in accordance with the defined conditions or limits,or which require the shipper to take additional precautions when preparing batteries for transport. The special provisions applicable to lithium batteries are set out following. Notwithstanding the general requirement that prior to being transported each type of lithium battery must have successfully passed the UN test requirements, there is provision for prototype lithium batteries that have not yet passed the UN test requirements to be shipped for testing purposes, this testing includes pre-production or product compatibility testing, in accordance with Special Provision A88, as follows:A88 Prototype lithium batteries and cells to be tested that are packed with not more than 24 cells or 12 batteries per packaging that have not been tested to the requirements in sub-section 38.3 of the UN Manual of Tests and Criteria may be transported aboard cargo aircraft, if approved by the appropriate authority of the State of origin and the following requirements are met:(a) the cells and batteries must be transported in an outer packaging that is a metal,plastic or plywood drum or a metal, plastic or wooden box and that meets the criteria for Packing Group I packagings; and(b) each cell and battery must be individually packed in an inner packaging inside anouter packaging and surrounded by cushioning material that is non-combustible, and non-conductive. Cells and batteries must be protected against short-circuiting.For air transport, specific quantity limits apply to the gross weight of each package that contains lithium batteries. The gross weight includes the weight of all of the packaging materials as well as the weight of batteries. The maximum weight for packages consigned for carriage as Cargo Aircraft Only is 35 kg gross. However, there is provision for large batteries that have a weight that exceed the 35 kg packaged weight to be consigned on a cargo aircraft in accordance with Special Provision A99 as follows:A99 Irrespective of the limit specified in Column L of the List of Dangerous Goods (Subsection 4.2), a lithium battery or battery assembly that has successfully passed the tests specified in the UN Manual of Tests and Criteria, Part III, sub-section 38.3 and that meets the requirements of Packing Instruction 965 for lithium ion batteries, and Packing Instruction 968 for lithium metal batteries as prepared for transport may have a mass exceeding 35 kg G, if approved by the appropriate authority of the State of origin. A copy of the document of approval must accompany the consignment.There will be occasion where a manufacturer may wish to have a defective battery returned for analysis. However, where such batteries may pose a safety risk they are prohibited from transport by air as set in Special Provision A154, as follows:A154 Lithium batteries identified by the manufacturer as being defective for safety reasons, or that have been damaged, that have the potential of producing a dangerous evolution of heat, fire or short circuit are forbidden for transport (e.g. those being returned to the manufacturer for safety reasons).One of the major risks associated with the transport of batteries and battery-powered equipment is short-circuit of the battery as a result of the battery terminals coming into contact with other batteries or metal objects. Special Provision A164 require that all batteries and battery-powered equipment must be packed to prevent short circuit an inadvertent operation as follows:A164 Any electrical battery or battery-powered device, equipment of vehicle having the potential of a dangerous evolution of heat must be prepared for transport so as to prevent:(a) a short circuit (e.g. in the case of batteries by the effective insulation of exposedterminals; or in the case of equipment, by disconnection of the battery and protection of exposed terminals); and(b) unintentional activation.ProhibitionsTransport to, from or through the United StatesLithium metal batteries shipped to, from or through the United States are subject toadditional limitations specified in the US national dangerous goods regulations containedin Code of Federal Regulations Title 49 (49 CFR). The basis of these limitations isreflected in State Variation USG-02, which states that:Primary (non-rechargeable) lithium metal batteries and cells, (UN 3090), are forbiddenfor transportation aboard passenger-carrying aircraft. Such batteries transported inaccordance with Part 2 of Packing Instruction 968 must be labelled with the CARGOAIRCRAFT ONLY label. Such batteries transported in accordance with Part 1 of PackingInstruction 968 must be marked “PRIMARY LITHIUM BATTERIES — FORBIDDEN FORTRANSPORT ABOARD PASSENGER AIRCRAFT” or “LITHIUM METAL BATTERIES— FORBIDDEN FOR TRANSPORT ABOARD PASSENGER AIRCRAFT”.Primary (non-rechargeable) lithium metal batteries and cells contained in or packed withequipment (UN 3091) are forbidden for transportation aboard passenger-carrying aircraftunless:1. the equipment and the batteries and cells are transported in accordance withPacking Instruction 969 or 970, as appropriate;2. the package contains no more than the number of lithium metal batteries or cellsnecessary to power the intended piece of equipment;3. the lithium content of each cell, when fully charged, is not more than 5 grams;4. the aggregate lithium content of the anode of each battery, when fully charged, isnot more than 25 grams; and5. the net weight of lithium batteries does not exceed 5 kg (11 lb).Primary (non-rechargeable) lithium metal batteries and cells contained in or packed withequipment (UN 3091) and transported in accordance with Part 2 of Packing Instruction969 or 970 that do not conform to the above provisions are forbidden for transportationaboard passenger-carrying aircraft and must be labelled with the CARGO AIRCRAFTONLY label.Primary (non-rechargeable) lithium metal batteries and cells contained in or packed withequipment (UN 3091) and transported in accordance with Part 1 of Packing Instruction969 or 970 that do not conform to the above provisions are forbidden for transportationaboard passenger-carrying aircraft and must be marked “PRIMARY LITHIUM BATTERIES — FORBIDDEN FOR TRANSPORT ABOARD PASSENGER AIRCRAFT”or “LITHIUM METAL BATTERIES — FORBIDDEN FOR TRANSPORT ABOARDPASSENGER AIRCRAFT”.Passenger ProvisionsTransport within Passenger BaggageCertain restrictions apply to the carriage of lithium metal and lithium ion batteries even when carried by passengers as baggage. Once again, only batteries that have successfully passed the Tests outlined in Part III, Sub-Section 38.3 of the UN Manual of tests and criteria may be carried.As said before batteries manufactured, distributed or sold by major companies do meet this requirement, however, certain replacement batteries which are not OEM or aftermarket batteries but simply low-cost copies of those – also called “fakes” – may not have undergone the required tests. Untested batteries are consequently excluded from air transport.Users of equipment powered by lithium metal and lithium ion batteries should therefore be vigilant when buying replacement batteries from unknown sources, such as on markets or Internet auction platforms. The differences between genuine and copied battery types may not be visible but could be very dangerous; such untested batteries may have a risk of overheating or causing fires.Because of the risks associated with the carriage of spare batteries these may not be transported within passenger checked baggage. Spare batteries must be in carry-on baggage.These requirements are stipulated by subparagraph 2.3.5.9 of the IATA Dangerous Goods Regulations:2.3.5.9 Consumer electronic devices (watches, calculating machines, cameras, cellular phones, lap-top computers, camcorders, etc.) containing lithium metal or lithium ion cells or batteries when carried by passengers or crew for personal use, which should be carried in carry-on baggage. Spare batteries must be individually protected to prevent short circuits by placement in the original retail packaging or by otherwise insulating terminals, e.g. by taping over exposed terminals or placing each battery in a separate plastic bag or protective pouch, and carried in carry-on baggage only. In addition, each installed or spare battery must not exceed the following quantities:(a) for lithium metal or lithium alloy batteries, a lithium content of not more than 2 g; or(b) for lithium ion batteries, a watt-hour rating of not more than 100 Wh.There is also provision, with the approval of the airline, for larger lithium ion batteries with a watt-hour rating in excess of 100 Wh, but not more than 160 Wh in equipment and no more than two spare lithium ion batteries as set out in subparagraph 2.3.3.2 as follows:2.3.3.2 Lithium ion batteries exceeding a watt-hour rating of 100 Wh but not exceeding 160 Wh may be carried as spare batteries in carry on baggage, or in equipment in either checked or carry on baggage. No more than two individually protected spare batteries per person may be carried.Although the text provided above does not impose a limit on the number of lithium metal and lithium ion batteries being carried as spares within a passenger’s carry-on baggageit must be emphasized that the number of spares must be “reasonable” in the context ofthe equipment used by the passenger and his or her itinerary. Furthermore, these mustbe intended to power consumer electronic devices (including, but not limited to, camerasand professional film equipment, laptop computers, MP3 players, cell phones, PersonalDigital Assistants (PDA’s), pocket calculators etc.Batteries which are carried for the purpose of resale or beyond personal needs areclearly not covered.The regulations imposed on these commodities by the United States competentauthorities (Department of Transportation and FAA) match the ICAO / IATA regulationsaddressed in this document.Frequently Asked QuestionsPart 1 – Questions Related to DefinitionsA. What are the various types of lithium batteries?Lithium batteries fall into two broad classifications; lithium metal batteries and lithium ionbatteries. Lithium metal batteries are generally non-rechargeable and contain metallic lithium. Lithium ion batteries do not contain metallic lithium and are rechargeable.B. What are lithium polymer batteries?A lithium polymer battery is a type of lithium ion battery. Generally, the main difference islithium ion polymer batteries contain a polymer electrolyte.C. What is the difference between a lithium cell and a lithium battery?A lithium cell is a single encased electrochemical unit consisting of one positive and onenegative electrode that exhibits a voltage differential across the two terminals. A lithiumbattery is one or more cells electrically connected. A single cell battery is considered acell and not a battery.Note: Units that are commonly referred to as “battery packs” having the primary function of providing a source of power to another piece of equipment are for the purposes of these Regulations treated as batteries.D. How are component cells connected to form a battery?Cells in batteries may be connected in parallel, in series, or in a combination of the two.When cells are connected in series the voltage of the battery increases but the capacityin ampere-hours (Ah) does not change. By contrast, when cells are connected in parallelthe capacity in ampere-hours of the battery (Ah) increases but the voltage stays the same.E. How do I determine the watt-hour rating for a particular lithium ion battery?The watt-hour (Wh) rating is a measure by which lithium ion batteries are regulated.Lithium ion batteries manufactured after 1 January 2009 are required to be marked with the watt-hour rating.You can also arrive at the number of watt-hours your battery provides if you know the battery’s nominal voltage (V) and capacity in ampere-hours (Ah):Ah x V = WhThis information is often marked on the battery.Note that if only the milli-ampere-hours (mAh) are marked on the battery then divide that number by 1000 to get ampere-hours (Ah) (i.e. 4400 mAh / 1000 = 4.4. Ah).Most lithium ion batteries marketed to consumers are below 100 watt-hours. If you are unsure of the watt-hour rating of your lithium ion battery, contact the manufacturer.F.F. What is a button cell battery?A button cell battery is a round small cell or battery where the overall height is less thanthe diameter.Part 2 – Questions related to Packaging and Transport ProvisionsA. How do I safely package lithium batteries for transport?One of the major risks associated with the transport of batteries and battery-powered equipment is short-circuit of the battery as a result of the battery terminals coming into contact with other batteries, metal objects, or conductive surfaces. Packaged batteries or cells must be separated in a way to prevent short circuits and damage to terminals. They must be packed in a strong outer packaging or be contained in equipment. Sample packaging meeting these requirements is shown below:B. How can batteries be effectively protected against short circuit?Methods to protect against short circuit include, but are not limited to, the following methods:a) Packing each battery or each battery-powered device when practicable, in fullyenclosed inner packagings made of non-conductive material (such as a plastic bag);b) Separating or packing batteries in a manner to prevent contact with otherbatteries, devices or conductive materials (e.g., metal) in the packagings; andc) Ensuring exposed terminals or connectors are protected with non-conductivecaps, non-conductive tape, or by other appropriate means.If not impact resistant, the outer packaging should not be used as the sole means of protecting the battery terminals from damage or short-circuiting. Batteries should be securely cushioned and packed to prevent shifting which could loosen terminal caps or reorient the terminals to produce short circuits.Terminal protection methods include but are not limited to the following:a) Securely attaching covers of sufficient strength to protect the terminals;b) Packaging the battery in a rigid plastic packaging; andc) Constructing the battery with terminals that are recessed or otherwise protectedso that the terminals will not be subjected to damage if the package is dropped.C. What does the new lithium battery handling label look like and when is itrequired?The new lithium battery handling label is required as specified in the additional requirements of Part 1 of packing instructions 965, 966, 967, 968, 969 and 970. The new label is as shown in Figure 7.4.I IATA Dangerous Goods Regulations. The border of the label must have red diagonal hatchings with text and symbols in black on a contrasting background. The lithium battery handling label may be printed directly on the outer packaging provided that there is sufficient contrast between the elements of the lithium battery label and the colour of the packaging material.*Place for “Lithium ion battery” and/or “Lithium metal battery”110 mmD. When is a lithium battery handling label not required?A lithium battery handling label is not required for packages prepared in accordance with Part 2 of Packing Instructions 965-970 (i.e. bearing a Class 9 label) or when a package contains no more than 4 cells or 2 batteries installed in equipment prepared in accordance with Part 1 of Packing Instructions 967 and 970. This applies to UN 3481 Lithium ion batteries contained in equipment (See Part 1 of Packing Instruction 967) and UN3091 Lithium metal batteries contained in equipment (see Part 1 of Packing Instruction 970), except that button cells installed in equipment (including circuit boards) need not be considered. As these packages do not require a lithium battery handling label, the accompanying document mentioned in the “Additional Requirements” of Part 1 of Packing Instructions 967 and 970 is not required.E. Is there a requirement for the Lithium Battery Handing Label to be available inlanguages other than English?English is generally the standard language accepted in international aviation. However, the State of origin where offering the package for shipment may require their official language. Subsection 7.1.3.3 of the IATA DGR specifies that in addition to the languages which may be required by the State of origin, English must be used.F. Part 1 in Packing Instructions 967 and 970 states that "Each packagecontaining more than four cells or more than two batteries installed in equipment must be labelled with a lithium battery handling label." What is the intent of this provision?This provision authorizes packages with equipment containing no more than 2 batteries or 4 cells to be offered for transport without the lithium battery handling label. For example, a package containing a notebook computer may have 1 lithium ion battery and 2 small lithium metal coin cells installed in the product. This single package does not require the lithium battery handling label. The number of cells contained inside the lithium ion battery are NOT counted towards the 4 cell limitation because it is the battery installed in the equipment being presented for transport. In addition, multiple packages each containing no more than 2 batteries or 4 cells may be overpacked and neither the individual packages nor the overpack would require the label.G. I have an MP3 player that contains one single-cell lithium ion battery pack. Do Ihave to label the shipping box that contains each MP3 player? What if I place five MP3 players in a shipping box? Does this require a label?For packages of single MP3 players, no lithium battery label would be required since you can place up to 4 of these single-cell batteries in a box without labelling the outer box. In the case where 5 MP3 players are in a shipping package, a lithium battery label on the outer shipping package would be required.H. Can a single label be used to identify that both lithium metal and lithium ionbatteries are contained inside the package?Yes. A single label identifying both lithium ion and lithium metal batteries may be usedI. What are the requirements for the telephone number on the lithium batteryhandling label?The telephone number should be of a person knowledgeable about the shipment but is not intended to be for the purposes of obtaining immediate emergency response guidance, and is therefore not required to be monitored at all times that the package is in transit. It is acceptable for the number to be monitored during the company’s normal business hours in order to provide product-specific information relative to the shipment. However, it also is acceptable to use an emergency response, 24-hour phone number on the label.J. For the purposes of the lithium battery packing instructions, what is considered the "package"?The package is the complete product of the packing operation that satisfies the requirement of the packing instruction. The package may contain multiple batteries or pieces of equipment provided the limitations set out in the applicable packing instruction are not exceeded. The package must be marked and labelled as required by the packing instruction. A single package may be offered for transport, or one or more packages may then be placed into an overpack for ease of handling or transport purposes. When an overpack is used, the package markings and labels must be duplicated on the overpack unless the markings and labels required on individual packages are visible, or are not required by the packing instruction (i.e. less than 4 cells or 2 batteries when contained in equipment).K. Please explain the documentation requirements for consignments of lithium batteries that are required to have the lithium battery label?Each consignment of packages with lithium batteries that is required to have the lithium battery handling label must be accompanied by a document such as an airway bill or other document that indicates:• The package contains lithium ion cells or batteries;• The package must be handled with care and that a flammability hazard exists if the package is damaged;• Special procedures should be followed in the event the package is damaged, to include inspection and repacking if necessary; and• A telephone number for additional information.This document may be in any form provided it contains all the appropriate information and accompanies the consignment. For example, the document may be provided separately to the carrier or in a pouch attached to the package.L. Does IATA require an MSDS containing the UN test data?No. IATA does not require the use of MSDS and test data is not part of the required documentation requirements when offering lithium batteries for transport.M. Under Packing Instructions 966 and 969, it states that “The maximum number of batteries in each package must be the minimum number required to power the equipment, plus two spares”. If a package contains 4 power tools (each tool contains a lithium ion battery), can 2 extra lithium ion batteries be placed in the package for each piece of equipment for a total of 8 batteries?Yes. The 8 batteries reflect two spares for each of the 4 power tools in the outer package.N. May lithium battery packages be placed in an overpack in accordance with the new IATA Dangerous Goods Regulations?Yes. The overpack may also contain packages of dangerous goods or goods not subject to the Regulations provided there are no packages enclosing different substances which might react dangerously with each other. An overpack must be marked with the word “overpack” and must be labelled with the lithium battery label (Figure 7.4.I), unless the label(s) on the package(s) inside the overpack are visible or not required by the Packing Instruction.In addition, the word “overpack” must be marked on overpacks containing packages transported in accordance with Part 2 of the applicable Packing Instructions (i.e. bearing Class 9 labels).O. Do the quantity limits shown in the IATA packing instructions apply to overpacks containing lithium batteries?The quantity limits shown in packing instructions 965 and 968, refer to the package. Provided each package remains under the limit specified in the packing instruction, the overpack may exceed the specified limits.P. Packing Instructions 966 and 969 Part 1 include a requirement for a 1.2 metre drop test. What portion or portions of the package are subject to this test?The completed package containing batteries as prepared for transport in accordance with the relevant packing instruction must be capable of withstanding the 1.2 m drop test. This could apply to a package solely containing batteries that is packaged in full compliance with the provisions of the packing instruction (to include the 1.2 m drop test capability requirement) and is then overpacked with equipment and offered for transport (see item 2N for additional information related to overpacks). Or, it could apply to a package that includes batteries properly packed in inner packaging and equipment or other non-dangerous goods that are placed in a single outer packaging. The package that includes both the inner packaging containing batteries and the equipment must comply with the packing instruction to include meeting the capability to pass the 1.2 m drop test.。
固态锂电池工艺流程英文回答:Solid-State Lithium Battery Manufacturing Process.1. Raw Material Preparation.The first step in the manufacturing process of solid-state lithium batteries is the preparation of raw materials. This involves obtaining high-purity lithium metal, cathode materials (such as lithium nickel manganese cobalt oxide or lithium iron phosphate), and solid-state electrolytes (such as ceramic or polymer).2. Electrode Fabrication.The next step is to fabricate the electrodes. The cathode and anode materials are mixed with a binder and solvent to form a slurry, which is then cast onto a current collector (usually aluminum or copper). The electrodes arethen dried and pressed to ensure good contact between the active material and the current collector.3. Solid Electrolyte Fabrication.The solid electrolyte is typically synthesized via a chemical reaction. The starting materials are mixed and heated to form a ceramic or polymer composite. The solid electrolyte must be ionically conductive while being electronically insulating.4. Cell Assembly.The electrodes and solid electrolyte are then assembled into a battery cell. The cell is usually constructed in a stack-and-laminate format, with the solid electrolyte sandwiched between the electrodes. The cell is then sealed to prevent moisture and air ingress.5. Formation.Once the cell is assembled, it undergoes a formationprocess. This involves charging and discharging the cell at a controlled rate to stabilize the electrode-electrolyte interface and improve the cell's performance.6. Testing.After formation, the cells are thoroughly tested to ensure they meet the desired specifications. Testing includes electrochemical characterization, safety testing, and environmental testing.中文回答:固态锂电池工艺流程。
锂电池行业翻译资料英文IntroductionThe lithium battery industry is a rapidly growing sector that plays a crucial role in various applications, including electric vehicles, portable electronics, and renewable energy storage systems. To stay updated with the latest advancements and trends in this industry, it is important to access reliable and accurate translation resources in English. This document aims to provide valuable translation materials related to the lithium battery industry. Please note that the translations provided are for reference purposes only and may require further verification.1. Lithium Battery OverviewLithium batteries are rechargeable energy storage devices that use lithium ions to facilitate the flow of charge between electrodes. They are known for their high energy density, longer cycle life, and comparatively higher voltage levels. Lithium batteries are widely used in portable electronic devices, such as smartphones and laptops, due to their lightweight and compact design.2. Lithium Battery TypesThere are several types of lithium batteries, including:2.1 Lithiumion Battery (Liion)Liion batteries are the most common type of lithium batteries used today. They are known for their high energy density, low selfdischarge rates, and long cycle life. Liion batteries are extensively employed in electric vehicles, consumer electronics, and energy storage systems.2.2 Lithium Polymer Battery (LiPo)LiPo batteries are a type of lithium battery that use a solid polymer electrolyte instead of a liquid electrolyte used in Liion batteries. They offer higher energydensity, improved flexibility, and enhanced safety compared to Liion batteries. LiPo batteries are commonly used in smartphones, tablets, and wearable devices.2.3 Lithium Iron Phosphate Battery (LiFePO4)LiFePO4 batteries, also known as lithium iron phosphate batteries, are a type of lithium battery that utilize iron phosphate as the cathode material. They offer improved safety, longer cycle life, and better thermal stability compared to other lithium battery types. LiFePO4 batteries are often used in power tools, electric vehicles, and renewable energy storage systems.3. Lithium Battery Manufacturing ProcessThe production of lithium batteries involves several key steps, including:3.1 Electrode PreparationDuring this process, the electrode materials, such as lithium cobalt oxide (LiCoO2) for the cathode and graphite for the anode, are prepared. These materials are coated onto metal foils and then dried to form the electrode sheets.3.2 Cell AssemblyIn this step, the electrode sheets are assembled with a separator, which prevents the electrodes from coming into contact with each other. The electrodes are then rolled or stacked together and inserted into a metal or plastic casing.3.3 Electrolyte FillingThe casing is filled with a liquid electrolyte that allows the lithium ions to move between the electrodes during charging and discharging. The electrolyte is typically a mixture of lithium salts dissolved in an organic solvent.3.4 Battery SealingTo ensure the integrity and safety of the battery, the casing is sealed to prevent leakage of the electrolyte and protect the internal components from external influences. Various sealing methods, such as heat sealing or ultrasonic welding, are used for this purpose.3.5 Battery Testing and Quality ControlEvery battery undergoes stringent testing to ensure its performance and safety. This includes capacity testing, cycle life testing, and checking for any manufacturing defects. Batteries that pass these tests proceed to the next stage, while defective ones are discarded or undergo further analysis.4. Lithium Battery Safety ConsiderationsWhile lithium batteries offer numerous benefits, it is essential to consider safety precautions due to their inherent risks. Some key safety considerations include:Temperature Control: Lithium batteries should be operated within their recommended temperature ranges to prevent thermal runaway and potential hazards.Overcharge and Overdischarge Protection: Appropriate charging and discharging circuits should be implemented to prevent overcharging or discharging, which could lead to reduced battery life and safety risks.Transportation and Storage: Proper packaging, labeling, and handling procedures must be followed to ensure the safe transportation and storage of lithium batteries. Protection Circuitry: Lithium batteries often incorporate protection circuitry to monitor voltage, temperature, and prevent short circuits or other malfunctions.ConclusionThe translation materials provided in this document offer insights into the lithium battery industry. These resources can serve as valuable references for individuals seeking English translations related to various aspects of this industry, including battery types, manufacturing processes, and safety considerations. It is crucial to verify the accuracy of the translations and supplement them with updated and reliable information from reputable sources.。
Declaration for Lithium Batteries Section II *Note: This version will be used from April 1,2022.W ARNING:Master AWB Number:LITHIUM BATTERIES THAT HAVE BEEN RECALLED BY THE MANUFACTURER FOR SAFETY REASONS MUST NOT BE SHIPPED BY AIR. The lithium cell/battery is of the type proven to meet the requirement of each test in the UN Manual of T ests and Criteria, Part III, subsection 38.3; and with test summary attached or with CERTIFICATE which including information that test summary required attached, and is manufactured under a qualitymanagements program according to 63rdDGR 3.9.2.6(e). The tested package is capable of withstanding a.1.2m drop test in any orientation (exceptPI967 & PI970).Lithium Ion - Maximum of•20 Watt-hours per cell; and•100 Watt-hours per battery Lithium Metal – Maximum of•1 gram of lithium metal content per cell; and•2 grams of aggregate lithium content per battery□ Packed with equipment (ICAO/IATA Packing Instruction 966, Section II) – Cells or batteries contained in a package with associated electronic equipment – with the batteries not installed in the equipment (for batteries, The Watt-hour rating must be marked on the outside case except those manufactured before 1 January 2009)□ Packed with equipment (ICAO/IATA Packing Instruction 969, Section II)– Cells or batteries contained in a package with associated battery-powered equipment – with the batteries not installed in the equipment□ Contained in equipment (ICAO/IATA Packing Instruction 967, SectionII) – Cells or batteries installed in equipment (for batteries, The Watt-hour rating must be marked on the outside case except those manufactured before1 January 2009)□ Contained in equipment (ICAO/IATA Packing Instruction 970, Section II)– Cells or batteries installed in equipmentAdditional Handling Informationl T his package must be handled with care. A flammability hazard exists if the package is damaged.l If this package is damaged in transportation, it must not be loaded until the condition of the contents can be verified. The batteries contained in this package must be inspected for damage and may only be repacked if they are intact and protected against short circuitsl For more information about the batteries contained in this package, please call: __________________________l For PI967/PI970, the total cells or batteries in each package are: Cells (and/or) Batteries;l For PI966/PI969, the number of cells or batteries in each package must not exceed the number for the equipment’s operations plus two spares sets;Package Description (Please insert “√” in brackets according to the actual shipment)l Durably and legibly “Lithium battery mark” has been labeled on each package ( )l“Lithium battery mark” is not necessary(only for PI967/P970)1) packages containing only button cell batteries installed in equipment (including circuit boards) ()2) consignments of two packages or less where each package contains no more than four cells or two batteries installed inequipment ( )l The word “overpack” (at least 12 mm high) has been marked on the outside of the overpack,every overpack must be durably and legibly marked with all applicable marks and labels. (if applicable)()I hereby declare that the contents of this consignment are fully and accurately described above by the proper shipping name, and are classified, packaged, marked and labeled/placarded, and are in all respects in proper condition for transport according to applicable international and national governmental regulations. I declare thatall of the applicable air transport requirements have been /Address of shipperSignature of shipper or his agent:Date:Manufacturer Seal: (optional)Issuing Carrier’s Agent Seal:(effect from 2022-04-01) Edition 2关于锂电池 Section II 空运声明*提醒:本版本自2022年4月1日起使用。
To pack To shipTo satisfyPractical guide for preparing parcelsposte.fr/colissimo-entrepriseBEST PRACTICESThe key to a successful shipmentOur state-of-the art technical tools ensurerapidity, reliability and that your parcels are tracked from A to B. Your logistics chain now reaches to yourconsignee’s end address.A WELL-PREPARED PARCEL3Dimensionand weight rules(1) 30 kg in a selection of French Post Offices.A WELL-PREPARED PARCELThe key to a successful shipmentSo that your parcel is machinable and reaches its destination, it must comply with the following conditions.It must :• B e stable so that it does not tip over; don’t hesitate to wedge, stuff and evenly distribute the contents of the parcel.• O pt for regular shapes: make sure you have at least one horizontal surface onto which you can affix the shipping label.• B e prepared using packing solutions that do not stick out i.e. string, handles, flaps, etc.• U se wrapping that is sufficiently resistant and adapted to the content: avoid overly irregular shapes and materials that affectthe legibility of the label such as plastic, cellophane, etc., which are too reflective.• W hen sending tubes, use machinable tubes (triangular or square tubes that ensure parcel stability). Traditional non-machinable tubes are always subject to additional charges.For more information, please read our General Terms & Conditions of Sale.It must to be read by La Poste machines.• P lease comply with the minimum dimensions: L = 16 cm; W = 11 cm• Check legibility:Check the printing quality of your label.All information on the label and in particular the barcode must be completely legible.Print your label without white lines, deletions and lateral offset.Use non-porous paper.• Make sure the label is really flat:Choose the largest surface of the parcel and affix your label on one side only.Make sure you only affix one label to each parcel.If you are sending a tube, make sure you affix the label widthways rather than lengthways.Exceed the maximum weight of 30 kg.Wrap the parcel in paper - even partially.Group parcels using straps, string, etc.Give us unwrapped goods: they will not be accepted.Use overly loose straps and string.F old the label and affix it so that it overlaps an edge or place it above/below wrapping materials or adhesive tape.Use the label as an adhesive (e.g. tape).Under no circumstance should the wrapping conceal any of the label information,even partially.What do not to do What do not to do5A few examplesTHE 9 CATEGORIES OF FORBIDDEN HAZARDOUS GOODS:Dangerous goods are contents wich present a potential danger in their transport of handling (according to Universal Postal Union). They may not be transported by post.Electrically powered apparatus (wheelchairs, lawnmowers, etc.)Wet batteries (corrosive), batteries or lithium batteriesBreathing apparatus Cylinders of compressed air or oxygen Toolboxes May contain explosives (power rivets), aerosols, adhesives, etc.Gas cylinders Compressed gasCosmeticsHairspray, flammable liquids and other dangerous goods Samples for testing May contain dangerous goods Individual meal packs (IMP)Flameless ration heaters (FRH) and self-heating beverages (SHB)Diving equipment Gas cylinders, high intensity diving lamps FireworksExplosive substancesAgricultural supplies Fertilizers, pesticides, herbicides Party supplies Compressed gases, explosive articles Dental supplies Resins or solventsMedical supplies Dangerous chemicals, thermometers, blood pressure instruments Photographic supplies Dangerous chemicals Frozen fruit, vegetablesDry iceFor more information, contact your sales representative.A few examplesTHE FORBIDDEN HAZARDOUS GOODS:9IN THE SPOTLIGHTLithium batteries Lithium batteries are a specialcase for which air and roadtransport is subject to stringentconditions:Only the following batteries, Array in the quantities and with thefeatures listed below, used inone (or more) appliances, areauthorised for road transport*:• A maximum of fourbatteries or two lithium-ionbatteries UN3481(packagingrequirement 967, SectionII) per parcel, batteries notexceeding 20 Wh, batteriesnot exceeding 100 Wh, witha maximum total batteryweight of 5 kg per parcel.• A maximum of fourbatteries or two lithium-metal batteries UN3091(packaging requirement970, Section II) per parcels,batteries not exceeding 1gof lithium, batteries notexceeding 2g of lithium, witha maximum total batteryweight of 5 kg per parcel.* F rance and Europe only. Shipment byair (outside Europe) is not authorised.11Colissimo is here to advise you...IN THE SPOTLIGHTYour contact is at your service to provide additional information and advice about:• T he constraints associated with your line of business and your customers’ special requirements.• T he organisation of equipment in your warehouses, the configuration of your logistics chain, the composition of parcel flows and how they are managed (number of parcels, average weight, type of goods, type of packaging, etc.). This information will be examined by our technical and logistics teams to ensure optimal compatibility with our services.Your sales contact will also look at any logged anomalies and will suggest actions to make improvements.Thanks to this permanent dialogue, Colissimo can deliver your parcels quickly and well by meeting your high standards of quality.L a P o s t e – S A a u c a p i t a l d e 3 800 000 000 e u r o s – 356 000 000 R C S P a r i s - S i èg e s o c i a l : 9 R U E D U C O L O N E L P I E R R E A V I A – 75015 P A R I S -J a n v i e r 2017 - R éa l i s a t i o n : K o o b e e - (1) C o n s u l t a t i o n g r a t u i t e h o r s c o ût d e c o n n e x i o n e t d e c o m m u n i c a t i o n s e l o n l ’o p ér a t e u r c h o i s i .。
锂离子电池封装工艺流程英文回答:Lithium-ion Battery Packaging Process Flow.The packaging process of lithium-ion batteries involves several key steps to ensure the safety, reliability, and performance of the battery. Here is a general overview of the process:1. Electrode Preparation:The first step is to prepare the electrodes, which are the positive and negative terminals of the battery. The electrodes are typically made of metal oxides or graphite and are coated with a conductive material to facilitate electron flow.2. Electrode Assembly:The prepared electrodes are then assembled into a stack, with a separator material placed between them to prevent short circuits. The separator is a porous material that allows ions to pass through while blocking the flow of electrons.3. Pouch Formation:The electrode stack is then placed into a pouch made of a flexible, waterproof material. The pouch is sealed to create an airtight environment that protects the battery from external factors.4. Electrolyte Filling:An electrolyte solution is injected into the pouch to facilitate the movement of ions between the electrodes. The electrolyte is typically a mixture of organic solvents and lithium salts.5. Sealing and Inspection:The pouch is then sealed to prevent electrolyte leakage and ensure the integrity of the battery. The battery undergoes rigorous inspections to verify its safety and performance before being shipped to the end-user.中文回答:锂离子电池封装工艺流程。
海水提取锂工业流程The process of extracting lithium from seawater is a complex and challenging task. The rapid growth in demand for lithium as a key component in electric vehicle batteries and electronic devices has fueled interest in developing more efficient methods for extracting lithium from seawater. 海水提取锂的工业流程涉及多个步骤和技术,这是一个复杂而具有挑战性的任务。
One of the main challenges of extracting lithium from seawater is the low concentration of lithium in seawater. The average concentration of lithium in seawater is about parts per million (ppm), making it a difficult and costly process to extract lithium from such a large volume of seawater. 海水中锂的浓度很低,一般在每百万分之之间,因此从如此大量的海水中提取锂是一项困难且昂贵的工作。
The most common method for extracting lithium from seawater is through a process called ion exchange. This process involves passing seawater through a series of ion exchange resins, which selectively absorb the lithium ions from the seawater. However, this method is energy-intensive and requires a large amount of resources, making itexpensive and not very environmentally friendly. 最常见的从海水中提取锂的方法是离子交换。
磷酸铁锂电池组装工艺流程英文回答:The assembly process of lithium iron phosphatebatteries involves several steps. Here is a general outline of the process:1. Electrode Preparation: The first step is to prepare the positive and negative electrodes. The positive electrode is usually made of lithium iron phosphate (LiFePO4) powder mixed with conductive additives and a binder. The negative electrode is typically made of graphite powder mixed with a binder. These electrode materials are coated onto metal foils and then dried.2. Electrolyte Preparation: The electrolyte is acrucial component of the battery. It typically consists of a lithium salt dissolved in a solvent mixture. The electrolyte is prepared by carefully mixing the lithiumsalt with the solvent and ensuring it is well-mixed andfree from impurities.3. Cell Assembly: In this step, the positive and negative electrodes are assembled together with a separator in between. The separator acts as a barrier to prevent direct contact between the electrodes, while allowing the flow of ions. The electrodes and separator are then rolled or stacked together to form a jellyroll-like structure.4. Cell Encapsulation: The jellyroll structure is then placed in a cylindrical or pouch-shaped enclosure. The enclosure is made of a material that is both electrically insulating and chemically stable. This step helps toprotect the cell from external influences and provides structural support.5. Electrolyte Filling: The next step involves filling the cell with the prepared electrolyte. This is done in a controlled environment to ensure the electrolyte is evenly distributed and there are no air bubbles trapped inside. The cell is then sealed to prevent leakage.6. Formation: After the cell is sealed, it undergoes a formation process. This involves applying a series of charge and discharge cycles to the cell to activate the electrochemical reactions and stabilize its performance. This step is essential for achieving optimal battery performance.7. Testing and Quality Control: Once the formation process is complete, the batteries undergo rigorous testing and quality control checks. This includes measuring the capacity, voltage, internal resistance, and other performance parameters to ensure they meet the required specifications.8. Packaging and Distribution: Finally, the batteries are packaged and prepared for distribution. They are typically packaged in boxes or trays and labeled with relevant information such as the battery type, capacity, and safety instructions. The batteries are then shipped to customers or used in various applications.中文回答:磷酸铁锂电池的组装工艺流程包括以下几个步骤:1. 电极制备,首先是准备正负电极。
如何计算锂含量
锂含量计算公式
每0.3克锂金属产生1安培小时的能量
1毫安=1/1000安培
例如:邮寄一个装有6个电池芯的锂金属电池,每个电池芯为2500mAh
锂金属/合金电池
锂金属电池 设备及锂金属电池 装在设备内的锂金属电池
UN3090 P.I.968 Section II 单独邮寄锂金属/合金电池,需要先得到联邦快递危险品管理部门(DG Admin)的批准 联系方式001-9014347233 UN3091 P.I.969 Section II 每个电池的锂含量不得超过2g/电池,或1g/电池芯 完整的IATA锂电池标签 (Appendix 1) 锂电池声明必须注明在运单或单独打印并贴在外包装上 (Appendix 2) 包装要求 (Appendix 3) 无需“危险品声明”(DGD) 没有附加费用 每包裹电池数量最大值为本设备驱动电池+2块备用电池 UN3091
P.I.970
Section II
每个电池的锂含量不得超过
2g/电池,或1g/电池芯
完整的IATA锂电池标
签(单个包裹中电池数
不超过2块,或电池芯
数不超过4块,无需锂
电池标签) (Appendix
1)
当锂电池标签被使用
时,声明必须打印并贴
在外包装上
(Appendix 2)
包装要求
(Appendix 3&4)
无需“危险品声明”
(DGD)
没有附加费用
Ah per cell x 0.3gm x number of cells
2500mAh/1000X0.3X6=4.5g
Appendix 1
Appendix 2
2-1(the document must be affixed to the surface of package)
2-2(the statement must be wrote on the AWB)
Lithium metal batteries not restricted as per PI968 (PI969, PI970)
Appendix 3
Cells and batteries must be packed in strong outer packaging that conforms
to 5.0.2.4, 5.0.2.6.1 and 5.0.2.12.1.
Cells and batteries must be packed in inner packaging that completely
encloses the cell or battery.
Each package must be capable of withstanding a 1.2 m drop test in any
orientation without:
•damage to cells or batteries contained therein;
•shifting of the contents so as to allow battery to battery (or cell to cell) contact;
•release of contents.
(FedEx Express requires that the maximum weight of each package shall be
within 10kg gross)
Appendix 4
(for lithium metal battery contained in equipment装在设备内的锂金属电池)
1. Equipment must be equipped with an effective means of preventing accidental activation;
2. The equipment containing the cells or batteries must be secured against movement within the