Magnon Bose condensation in symmetry breaking magnetic field
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a r X i v :c o n d -m a t /0607711v 2 [c o n d -m a t .s t r -e l ] 1 S e p 2006Magnon Bose condensation in symmetry breaking magnetic field S.V.Maleyev,V.P.Plakhty,S.V.Grigoriev,A.I.Okorokov and A.V.Syromyatnikov Petersburg Nuclear Physics Institute,Gatchina,Leningrad District 188300,Russia E-mail:maleyev@.spb Abstract.Magnon Bose condensation (BC)in the symmetry breaking magnetic field is a result of unusual form of the Zeeman energy that has terms linear in the spin-wave operators and terms mixing excitations which momenta differ in the wave-vector of the magnetic structure.The following examples are considered:simple easy-plane tetragonal antiferromagnets (AFs),frustrated AF family R 2CuO 4,where R=Pr,Nd etc.,and cubic magnets with the Dzyaloshinskii-Moriya interaction (MnSi etc.).In all cases the BC is important when the magnetic field is comparable with the spin-wave gap.The theory is illustrated by existing experimental results.1.Introduction Magnon Bose condensation (BC)in magnetic field was intensively studied in spin singlet materials (see for example [1]and references therein).In this case magnons condens in the field just above the triplet gap.In this paper we consider magnon BC that appears in the symmetry breaking magnetic field.The theoretical discussion is illustrated by experimental observation of this BC in frustrated antiferromagnet (AF)Pr 2CuO 4and cubic helimagnets MnSi and FeGe.To clarify our idea we begin with consideration of conventional AFs.In textbooks two limiting cases are considered.First,the magnetic field is directed along the sublattices.In this case the system remains stable up to the critical field H C =∆,where ∆is the spin-wave gap.Then the first order transition occurs to the state in which the field is perpendicular to sublattices (spin-floptransition).Second,the field is perpendicular to initial staggered magnetization.The system remains stable but the spins are canted toward the field by the angle determined by sin ϑ=−H/(2SJ 0),where J 0=Jz ;J and z are the exchange interaction and the number of nearest neighbors,respectively.At H +2SJ 0the spin-flip transition occurs to the ferromagnetic state.To the best of our knowledge the first consideration of the symmetry breaking field was performed theoretically in [2]in connection with experimental study of the magnetic structure of the frustrated AF R 2CuO 4,where R=Pr,Nd,Sm and Eu [3,4].In these papers the non-collinear structure was observed using the neutron scattering in the field directed at angle of δ=450to the sublattices.It was found in[2]that in inclinedfield the Zeeman energy has unusual form with terms which are linear in the spin-wave operators and term mixing magnons which momenta differ in the AF vector k0.As a result the BC arises of the spin-waves with momenta equal to zero and±k0.Similar situation exists in cubic helimagnets MnSi etc.[5].If thefield is directed along the helix wave-vector k the plain helix transforms into conical structure and then the ferromagnetic spin state occurs at criticalfield H C.But if H⊥k the magnon condense with momenta zero,±k,±2k etc.This leads to the following observable phenomena:i)a transition to the state with k directed along thefield at H⊥∼H C1=∆√S/2(a l−a+l),l=1,2 and a l(a+l)are Bose operators.As a result the Zeeman energy has unusual formH Z=H a+q+k0a q+iϑN,i.e. these operators has to be considered as classical variables as in the Bogoliubov theory of the BC in dilute Bose gas.Due to thefirst term in(2)we must consider the operatorsa±k0and a+∓kas classical variables too.Minimizing the full Hamiltonian with respectto these variables we obtainE=(∆2sin22ϕ)/(16J0)−S2J0ϑ2−(H H⊥)2/[4J0(∆2(ϕ,H)],(3)where thefirst term is the energy of the square anisotropy.In cuprates with S=1/2ithas quantum origin and arises due to pseudodipolar in-plane interaction[9].The secondterm is the energy of the spin canting in perpendicularfield.The last term is the BCenergy and∆2(ϕ,H)=∆2cos4ϕ+H2⊥−H2 is the spin-wave gap in thefield[2].This contribution becomes important at H∼∆.The spin configuration is determined byd E/dϕ=0and equilibrium condition d2E/dϕ2≥0.This theory was verified by neutrons scattering[10,11].In diagonalfield H (1,1,0)the spin configuration in frustrated Pr2CuO4is governed by Eq.(3)and the intensityof the(1/2,1/2,−1)is given by I∼1+sin2ϕ[2].Neglecting the BC term we getsin2ϕ=−(H/H C)2,where H C=∆.As a result at H→H C we obtain I∼H C−H. But very close to H C the BC term becomes important and we have a crossover to I∼(H C−H)1/2.It is clearly seen infigure2.This crossover was observed in[10,11].3.Frustrated AFsIn frustrated R2CuO4AFs there are two copper spins in unit cell belonging to different CuO2planes(see inset infigure1).From symmetry considerations these spins do not interact in the exchange approximation.The orthogonal spin structure is a result of the interplane pseudodipolar interaction(PDI)[2,3]and the ground state energy is given by∆2E=on T we obtain H C≃7.8T andγC≃5.30that is in stronger disagreement wit the experiment.The experimentally obtained anglesαandγat T=18K andδ=9.50are shown infigure4[12].The transition to the collinear state withα∼−450andγC∼200 was observed.Again the non-BC theory can not explain the experimental data.For example it givesγC≃2.50.Explanation of all these experimental data using the BC theory will be given elsewhere.4.BC in helimagnetsIn helimagnets MnSi etc.Dzyaloshinskii-Moriya interaction(DMI)stabilizes the helical structure and the helix wave-vector has the form k=SD[ˆa׈b]/A,where D is the strength of the DMI,A is the spin-wave stiffness at momenta q≫k,ˆa andˆb are unit orthogonal vectors in the plane of the spin rotation.The classical energy depends on thefield component H along the vector k and the cone angle of the spin rotation is given by sinα=−H/H C,where H C=Ak2is the criticalfield of the transition into ferromagnetic state[5].However at H⊥≪H C rotation of the helix axis toward thefield direction and the second harmonic2k of the spin rotation were observed[6-8].Both phenomena are related to the magnon BC in perpendicularfield[5].The linear and mixing terms appear in the Zeeman energy in much the same way as it was discussed above:H Z=(H a−i H b)2the real form of the BC energy is not so simple.It is determined by nonlinear interactions but consideration of this problem is out of the scope of this paper.As a result the perpendicular susceptibility is proportional to1/(∆2−H2⊥/2)and 2k harmonic appears.The last was observed by neutron scattering[6-8].Intensities of corresponding Bragg satellites have the formI±∼[∆2/(∆2−H2⊥/2)]2[1∓(kP)]δ(q∓2k),(7) where P is the neutron polarization.If H⊥→∆√5.ConclusionsWe discuss a few examples of the magnon BC in symmetry breaking magneticfield.BC appears due to unusual terms in Zeeman energy.Obviously this phenomenon is very general and can be observed in other ordered magnetic systems.Effects related to the BC has to be more pronounced in thefield of order of the sin-wave gap.6.AcknowledgmentsThis work is partly supported by RFBR(Grants03-02-17340,06-02-16702and00-15-96814),Russian state programs”Quantum Macrophysics”,”Strongly Correlated electrons in Semiconductors,Metals,Superconductors and Magnetic Materials””Neutron Research of Solids”,Japan-Russian collaboration05-02-19889-JpPhysics-RFBR and Russian Science Support Foundation(A.V.S.).References1Crisan M,Tifrea I,Bodea D and Grosu I2005Phys.Rev.B721644142Petitgrand D,Maleyev S,Bourges P and Ivaniv A1999Phys.Rev.B5910793D.Petitgrand,Moudden A,Galez P and Boutrouille P1990J.Less-Common Metals164-165768 4ChattpodhayaT,Lynn J,Rosov N,Grigereit T,Barilo S and Zigunov D1994Phys.Rev.B49 99445Maleyev S2006Phys.Rev.B731744026Lebech B,Bernard J and Feltfoft1989J.Phys.:Condens.Matter161057Okorokov A,Grigoriev S,Chetverikov Yu,Maleyev S,Georgii R,B¨o ni P,Lamago D,EckerslebeH and Pranzas P2005Physica B3562598Grigoriev S,Maleyev S,Chetverikov Yu,Georgii R,B¨o ni P,Lamago D,Eckerlebe H and Pranzas P2005Phys.Rev B721344029Yildirim T,Harris A,Aharony A and Entin-Wohlman O1995Phys.Rev.B521023910Plakhty V,Maleyev S,Burlet P,Gavrilov S and Smirnov O1998Phys.Lett.A25020111Ivanov A and Petitgrand D2004J.Mag.Mag Materials272-27622012Plakhty V,Maleyev S,Gavrilov S,Bourdarot F,Pouget S and Barilo S2003Europhys.Lett.61 53413Ivanov A,Bourges P and Petitgrand D1999Physica B259-261879FiguresaFigure 1.Spin configuration in the field.Full and dashed arrows correspond to zero and nonzero field,respectively.Addition spin canting in H ⊥is shown by broken arrows.Inset:spin configuration in neighboring planes of frustrated AF.Figure 2.Log-Log plot of the (1/2,1/2,−1)Bragg intensity in diagonal field,h ∼(H C −H ).Figure3.Thefirst order transition in thefield directed along b axis.Calculated intensities for the spinflop configurations when spins are perpendicular to thefield (white arrows).Figure4.Field dependence of anglesαandγatδ=9.50.)10a H mT =)50b H mT =)150c H mT=Figure 5.Bragg reflections in the field along (1,1,0).a)Four strong spots corresponds to ±(1,1,1)and ±(1,1,−1)reflections.Weak spots are the double Bragg scattering.b)The 2k satellites appear.c)The helix vector is directed along the field.。