无卤素板料的data-sheet S1155 MSDS

危险化学品特性表（自制）危险化学品特性表（自制） (1)（1）丙烯酸 (3)（2）甲酸 (4)（3）氢氟酸 (6)（1）N,N-二甲基甲酰胺 (7)（2）丙烯酸丁酯 (8)（1）萘 (10)（2）乌洛托品 (11)（1）氯酸钠 (13)（1）四氯乙烯 (15)（2）二氯甲烷 (17)3.1.1.1丙酮 (18)3.1.1.2-丁酮 (20)3.1.1.3甲醇 (21)3.1.1.4乙醇 (23)3.1.1.5 环己酮 (24)3.1.1.6异丙醇 (25)3.1.1.7 甲苯 (27)3.1.1.8 1，2-二甲苯 (29)3.1.1.9 乙醚 (30)3.1.1.10 乙酸乙酯 (32)3.1.1.11过氧化氢 (33)3.1.1.12高锰酸钾 (35)3.1.1.13重铬酸钾 (36)3.1.1.14硝酸银 (38)3.1.1.15苯酚 (39)3.1.1.16三氯甲烷 (41)3.1.1.17四氯化碳 (42)3.1.1.18氢氧化铵水溶液 (44)3.1.1.19氢氧化钠 (45)3.1.1.20氢氧化钾 (46)3.1.1.21甲醛 (47)3.1.1.22盐酸 (49)3.1.1.23硝酸 (51)3.1.1.24硫酸 (52)3.1.1.25 乙酸 (54)3.1.1.26三氯乙酸 (56)3.1.1.27氢氟酸 (57)3.1.1.28次氯酸钠 (59)3.1.1.29亚硫酸氢钠 (60)（4）纯苯 (62)（5）1,1-二氯乙烷 (63)（7）正丁醇 (65)（10）二（正）丁醚 (66)（11）丙烯酸正丁酯 (68)（4）冰醋酸 (69)三氯乙醛 (70)硝酸钠 (72)连二亚硫酸钠 (73)石油醚 (74)对二甲苯 (76)氧 (77)⑺乙酸酐 (80)⑻2-丁酮 (81)（1）丙烯酸表3.1-1 丙烯酸简介（2）甲酸表3.1-2甲酸简介（3）氢氟酸表3.1-3氢氟酸简介（1）N,N-二甲基甲酰胺表3.1-4 N,N-二甲基甲酰胺简介（2）丙烯酸丁酯表3.1-5丙烯酸丁酯简介（1）萘表3.1-6萘简介（2）乌洛托品表3.1-7乌洛托品简介（1）氯酸钠表3.1-8氯酸钠简介（2）亚硝酸钠表3.1-9亚硝酸钠简介（1）四氯乙烯表3.1-10四氯乙烯简介（2）二氯甲烷表3.1-11二氯甲烷简介3.1.1.1丙酮3.1.1.2-丁酮3.1.1.3甲醇3.1.1.4乙醇3.1.1.5 环己酮3.1.1.6异丙醇3.1.1.7 甲苯3.1.1.8 1，2-二甲苯3.1.1.9 乙醚3.1.1.10 乙酸乙酯3.1.1.11过氧化氢3.1.1.12高锰酸钾3.1.1.13重铬酸钾3.1.1.14硝酸银3.1.1.15苯酚3.1.1.16三氯甲烷3.1.1.17四氯化碳3.1.1.18氢氧化铵水溶液3.1.1.19氢氧化钠3.1.1.20氢氧化钾3.1.1.21甲醛3.1.1.22盐酸。

Material Safety Data SheetMaterial Name: WROUGHT ALUMINUM PRODUCTS, 1xxx SERIES ALLOYS ID: 663* * * Section 1 - Chemical Product and Company Identification * * *Chemical Formula: MixtureProduct Use: Various fabricated aluminum parts and products.Other Designations: 1xxx Series Alloys, 1xxx Cladding, 1350BS, 1435, 990LR, 995LR, C01A, C49A, C65A, C99A,C01B, C18B, C19B, C27B, C178, C479, C481, C531, C794, C798, CZ60, Clad 1100, KB10, MD56, MD115, MD119, MD230, MD251, MD335, RA91, RA179, W006.Alcoa Inc.Phone: Health and Safety: 1-412-553-4649201 Isabella StreetPittsburgh, PA 15212-5858Emergency Information:USA: Chemtrec: 1-800-424-9300 or 1-703-527-3887 Alcoa: 1-412-553-4001* * * Section 2 - Composition / Information on Ingredients * * *CAS #Component Percent7429-90-5Aluminum>997440-47-3Chromium<0.05 Component InformationAdditional compounds which may be formed during processing are listed in Section 8.* * * Section 3 - Hazards Identification * * *Emergency OverviewSolid. Silvery. Odorless. Non-flammable as supplied. Small chips, fine turnings and dust from processing may be readily ignitable.Explosion/fire hazards may be present when (See Sections 5, 7 and 10 for additional information):= Dust or fines are dispersed in the air.= Chips, dust or fines are in contact with water.= Dust or fines are in contact with certain metal oxides (e.g. rust).= Molten metal is in contact with water/moisture or certain metal oxides.Dust and fume from processing can cause irritation of eyes, skin and upper respiratory tract.Potential Health Effects(If dusts or fumes are generated by processing)EyesCan cause irritation.SkinCan cause irritation.InhalationCan cause irritation of upper respiratory tract and other health effects listed below. Cancer hazard.Health Effects of IngredientsChromium dust Can cause irritation of eyes, skin and respiratory tract. Chromium and trivalent chromiumIARC/NTP: Not classified by IARC.Aluminum dust, fines and fumes Low health risk by inhalation. ACGIH: Listed as nuisance dust (milling,cutting, grinding).Some products are supplied with a lubricant/oil coating or have residual oil from the manufacturing process. OilCan cause irritation of skin. Skin contact (prolonged or repeated): Can cause dermatitis. Mineral oils, untreated or mildly refined Studies with experimental animals by skin contact have found skin tumors. IARC/NTP: Listed as "known to be a human carcinogen" by the NTP. Listed as carcinogenic to humans by IARC (Group 1)*.Health Effects Of Additional Compounds Which May Be Formed During ProcessingHexavalent chromium (Chrome VI) Can cause irritation of eyes, skin and respiratory tract. Skin contact: Can cause irritant dermatitis, allergic reactions and skin ulcers. Chronic overexposures: Can cause perforation of the nasal septum, respiratory sensitization, asthma, fluid in the lungs (pulmonary edema), lung damage, kidneydamage, lung cancer, nasal cancer and cancer of the gastrointestinal tract. IARC/NTP: Listed as "known to be a human carcinogen" by the NTP. Listed as carcinogenic to humans by IARC (Group 1)*.Alumina Low health risk by inhalation. ACGIH: Listed as nuisance dust.If the product is heated well above ambient temperatures or machined, oil vapor or mist may be generated. Oilvapor and mist Can cause irritation of respiratory tract. Acute overexposures: Can cause bronchitis, asthma,headache, central nervous system effects (nausea, dizziness and loss of coordination) and drowsiness (narcosis).Welding, plasma arc cutting, and arc spray metalizing can generate ozone. Ozone Can cause irritation of eyes, nose and upper respiratory tract. Acute overexposures: Can cause shortness of breath, tightness of chest,headache, cough, nausea and narrowing of airways. Effects are reversible on cessation of exposure. Acuteoverexposures (high concentrations): Can cause respiratory distress, respiratory tract damage, bleeding and fluid in the lungs (pulmonary edema). Effects can be delayed up to 1-2 hours. Additional information: Studies withexperimental animals by inhalation have found genetic damage, reproductive harm, blood cell damage, lung damage and death.Welding fumes IARC/NTP: Listed as possibly carcinogenic to humans by IARC (Group 2B)*. AdditionalInformation: In one study, occupational asthma was associated with exposures to fumes from aluminum welding.Plasma arc cutting can generate oxides of nitrogen. Oxides of nitrogen (NO and NO2) Can cause irritation ofeyes, skin and respiratory tract. Acute overexposures: Can cause reduced ability of the blood to carry oxygen(methemaglobin). Can cause cough, shortness of breath, fluid in the lungs (pulmonary edema) and death. Effects may be delayed up to 2-3 weeks. Nitrogen dioxide (NO2) Chronic overexposures: Can cause scarring of the lungs (pulmonary fibrosis).*IARC ClassificationsGroup 1: The agent is carcinogenic to humans. There is sufficient evidence that a causal relationship existedbetween exposure to the agent and human cancer.Group 2B: The agent is possibly carcinogenic to humans. Generally includes agents for which there is limitedevidence in the absence of sufficient evidence in experimental animals.Medical Conditions Aggravated By Exposure to the ProductAsthma, chronic lung disease, and skin rashes.* * * Section 4 - First Aid Measures * * *First Aid: EyesFlush eyes with plenty of water or saline for at least 15 minutes. Consult a physician.First Aid: SkinWash skin with soap and water for at least 15 minutes. Consult a physician if irritation persists.First Aid: InhalationRemove to fresh air. If unconscious or severely injured, check for clear airway, breathing and presence of pulse.Perform CPR if there is no pulse or respiration. Consult a physician.* * * Section 5 - Fire Fighting Measures * * *Flammable PropertiesThis product does not present fire or explosion hazards as shipped. Small chips, turnings, dust and fines fromprocessing may be readily ignitable.Fire/ExplosionMay be a potential hazard under the following conditions:= Dust or fines dispersed in the air can be explosive. Even a minor dust cloud can explode violently.= Chips, dust or fines in contact with water can generate flammable/explosive hydrogen gas. Hydrogen gas could present an explosion hazard in confined or poorly ventilated spaces.= Fines and dust in contact with certain metal oxides (e.g., rust). A thermite reaction, with considerable heatgeneration, can be initiated by a weak ignition source.= Molten metal in contact with water/moisture or other metal oxides (e.g., rust). Moisture entrapped by moltenmetal can be explosive. Contact of molten aluminum with other metal oxides can initiate a thermite reaction. Extinguishing MediaUse Class D extinguishing agents on dusts, fines or molten metal. Use coarse water spray on chips and turnings.DO NOT USE: Halogenated agents on small chips, dusts or fines. Water around molten metal.Fire Fighting Equipment/InstructionsFire fighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing when appropriate.* * * Section 6 - Accidental Release Measures * * *Small/Large SpillIf molten: Contain the flow using dry sand or salt flux as a dam. Do not use shovels or hand tools to halt the flow of molten aluminum. Allow the spill to cool before remelting as scrap.* * * Section 7 - Handling and Storage * * *Handling/StorageProduct should be kept dry. Avoid generating dust. Avoid contact with sharp edges or heated metal. Hot and cold aluminum are not visually different.Requirements for Processes Which Generate Dusts or FumesIf processing of these products includes operations where dust or extremely fine particulate is generated, obtain and follow the safety procedures and equipment guides contained in Aluminum Association Bulletin F-1 and National Fire Protection Association (NFPA) brochures listed in Section 16. Cover and reseal partially empty containers. Use non-sparking handling equipment. Provide grounding and bonding where necessary to prevent accumulation of staticcharges during dust handling and transfer operations. (See Section 15).Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuums and electrostatic precipitators must not be used. Dust collection systems must be dedicated to aluminum dust only and should be clearly labeled as such. Do not co-mingle fines of aluminum with fines of iron, iron oxide (rust) or other metal oxides.Do not allow chips, fines or dust to contact water, particularly in enclosed areas.Avoid all ignition sources. Good housekeeping practices must be maintained.Requirements for Remelting of Scrap Material and/or IngotMolten metal and water can be an explosive combination. The risk is greatest when there is sufficient molten metal to entrap or seal off the water. Water and other forms of contamination on or contained in scrap or remelt ingot are known to have caused explosions in melting operations. While the products may have minimal surface roughness and internal voids, there remains the possibility of moisture contamination or entrapment. If confined, even a fewdrops of water can lead to violent explosions.All tooling and containers which come in contact with molten metal must be preheated or specially coated and rust free. Molds and ladles must be preheated or oiled prior to casting. Any surfaces that may contact molten metal(e.g., concrete) should be specially coated.Drops of molten metal in water (e.g. from plasma arc cutting), while not normally an explosion hazard, can generate enough flammable hydrogen gas to present an explosion hazard. Vigorous circulation of the water and removal of the particles minimize the hazards.During melting operations, the following minimum guidelines should be observed:= Inspect all materials prior to furnace charging and completely remove surface contamination such as water, ice, snow, deposits of grease and oil or other surface contamination resulting from weather exposure, shipment, orstorage.= Store materials in dry, heated areas with any cracks or cavities pointed downwards.= Preheat and dry large or heavy items such as ingot adequately before charging into a furnace containing molten metal. This is typically done by use of a drying oven or homogenizing furnace. The drying cycle should bring theinternal metal temperature of the coldest item of the batch to 400°F and then hold at that temperature for 6 hours.* * * Section 8 - Exposure Controls / Personal Protection * * *Engineering ControlsUse with adequate explosion-proof ventilation to meet the limits listed in Section 8.Personal Protective EquipmentRespiratory ProtectionUse NIOSH-approved respiratory protection as specified by an Industrial Hygienist or other qualified professional if concentrations exceed the limits listed in Section 8. Suggested respiratory protection: P95Eye ProtectionWear safety glasses/goggles to avoid eye contact.Skin ProtectionWear impervious gloves to avoid repeated or prolonged skin contact with residual oils and to avoid any skin injury. GeneralPersonnel who handle and work with molten metal should utilize primary protective clothing like face shields, fire resistant tapper's jackets, leggings, spats and similar equipment to prevent burn injuries. In addition to primaryprotection, secondary or day-to-day work clothing that is fire resistant and sheds metal splash is recommended for use with molten metal.Minimize breathing oil vapors and mist. Remove oil contaminated clothing; launder or dry-clean before reuse.Remove oil contaminated shoes and thoroughly clean and dry before reuse. Cleanse skin thoroughly after contact, before breaks and meals, and at the end of the work period. Oil coating is readily removed from skin with waterless hand cleaners followed by a thorough washing with soap and water.Exposure GuidelinesA: General Product InformationAlcoa recommends an Occupational Exposure Limit for Oil Mist of 0.5 mg/m3 TWA.B: Component Exposure LimitsAluminum (7429-90-5)ACGIH10 mg/m3 TWA (metal dust)OSHA15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)Chromium (7440-47-3)ACGIH0.5 mg/m3 TWAOSHA 1 mg/m3 TWAC: Additional Compounds Which May be Formed During ProcessingAlumina (non-fibrous) (1344-28-1)ACGIH as Al: 10 mg/m3 TWA (The value is for total dust containing no asbestos and < 1%crystalline silica)OSHA15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)Chromium (II) compounds (Not Available)OSHA0.5 mg/m3 TWA (as Cr)Chromium (III) compounds (as Cr) (Not Available)ACGIH as Cr: 0.5 mg/m3 TWAChromium (VI) compounds- water soluble (Not Available)ACGIH0.05 mg/m3 TWAChromium (VI) compounds (certain water insoluble forms) (Not Available)ACGIH0.01 mg/m3 TWAChromic acid and chromates (7738-94-5)OSHA and chromates: C 1 mg/10m3Welding fumes (NOC) (Not Available)ACGIH 5 mg/m3 TWAOzone (10028-15-6)ACGIH Heavy work: 0.05 ppm TWA; Moderate work: 0.08 ppm TWA; Light work: 0.1 ppm TWA;heavy, moderate or light work, <= 2Hrs: 0.20 ppmOSHA0.1 ppm TWA; 0.2 mg/m3 TWANitrogen dioxide (10102-44-0)ACGIH 3 ppm TWAACGIH 5 ppm STELOSHA C 5 ppm; C 9 mg/m3Nitric oxide (10102-43-9)ACGIH25 ppm TWAOSHA25 ppm TWA; 30 mg/m3 TWA* * * Section 9 - Physical & Chemical Properties * * *Appearance:SilveryPhysical State:Solid: sheet, plate, wire, rod,bar, extrusion, forgings, etc.Boiling Point:Not applicable Melting Point:Range: generally 1190-1215 ºF(643-657 ºC)Vapor Pressure:Not applicable Vapor Density:Not applicableSolubility Water:None Specific Gravity:See DensitypH Level:Not applicableDensity:Range: generally 2.70-2.71g/cm³ (0.097-0.098 lb/in³)Odor:None Odor Threshold:Not applicableOctanol-Water Coefficient:Not applicable* * * Section 10 - Chemical Stability & Reactivity Information * * *StabilityStable under normal conditions of use, storage, and transportation as shipped.Conditions to AvoidChips, fines, dust and molten metal are considerably more reactive with the following:= Water: Slowly generates flammable/explosive hydrogen gas and heat. Generation rate is greatly increased with smaller particles (e.g., fines and dusts). Molten metal can react violently/explosively with water or moisture,particularly when the water is entrapped.= Heat: Oxidizes at a rate dependent upon temperature and particle size.= Strong oxidizers: Violent reaction with considerable heat generation. Can react explosively with nitrates (e.g., ammonium nitrate and fertilizers containing nitrate) particularly when heated or molten.= Acids and alkalis: Reacts to generate flammable/explosive hydrogen gas. Generation rate is greatly increased with smaller particles (e.g., fines and dusts).= Halogenated compounds: Many halogenated hydrocarbons, including halogenated fire extinguishing agents, can react violently with finely divided aluminum.= Iron oxide (rust) and other metal oxides (e.g., copper and lead oxides): A violent thermite reactiongenerating considerable heat can occur. Reaction with aluminum fines and dusts requires only very weak ignition sources for initiation. Molten aluminum can react violently with iron oxide without external ignition source.= Iron powder and water: An explosive reaction forming hydrogen gas occurs when heated above 1470°F(800°C).* * * Section 11 - Toxicological Information * * *Health Effects of IngredientsA: General Product InformationNo information available for product.B: Component Analysis - LD50/LC50No LD50/LC50's are available for this product's components.CarcinogenicityA: General Product InformationNo information available for product.B: Component CarcinogenicityChromium (7440-47-3)ACGIH A4 - not classifiable as a human carcinogenIARC Monograph 49; 1990* * * Section 12 - Ecological Information * * *EcotoxicityA: General Product InformationNo information available for product.B: Component Analysis - Ecotoxicity - Aquatic ToxicityNo ecotoxicity data was found for this product's components.Environmental FateNo information available for product.* * * Section 13 - Disposal Considerations * * *Disposal InstructionsReuse or recycle material whenever possible. Material may be disposed of at an industrial landfill.US EPA Waste Number & DescriptionsA: General Product InformationRCRA Status: Must be determined at time material is disposed. If material is disposed as waste, it must becharacterized under RCRA according to 40 CFR, Part 261, or state equivalent in the U.S.B: Component Waste NumbersRCRA waste codes other than described under Section A may apply depending on use of product. Refer to 40 CFR 261 or state equivalent in the U.S.* * * Section 14 - Transportation Information * * *Special TransportationPSN #1PSN #2PSN #3PSN #4Notes:(1)Proper Shipping Name:Not RegulatedHazard Class:-UN NA Number:-Packing Group:-RQ:-Other - Tech Name:-Other - Marine Pollutant:-Notes:(1)When "Not regulated," enter the proper freight classification, "MSDS Number," and "Product Name" on theshipping paperwork.Canadian TDG Hazard Class & PIN:Not regulated* * * Section 15 - Regulatory Information * * *US Federal RegulationsA: General Product InformationAll electrical equipment must be suitable for use in hazardous atmospheres involving aluminum powder inaccordance with 29 CFR 1910.307. The National Electrical Code, NFPA 70, contains guidelines for determining the type and design of equipment and installation which will meet this requirement.B: Component AnalysisThis material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).Aluminum (7429-90-5)SARA 313:form R reporting required for 1.0% de minimis concentration (fume or dust only) Chromium (7440-47-3)SARA 313:form R reporting required for 1.0% de minimis concentrationCERCLA:final RQ = 5000 pounds (2270 kg) (no reporting of releases of this hazardous material isrequired if the diameter of the pieces of the solid metal released is equal to or exceeds0.004 inches)SARA 311/312 Physical and Health Hazard Categories:Immediate (acute) Health Hazard:Yes, if particulates/fumes generated during processing.Delayed (chronic) Health Hazard:Yes, if particulates/fumes generated during processing.Fire Hazard:NoSudden Release of Pressure:NoReactive:Yes, if moltenState RegulationsA: General Product InformationPENNSYLVANIA "Special Hazardous Substance": Chromium compounds, hexavalentChemical(s) known to the State of California to cause cancer: Hexavalent chromiumB: Component Analysis - StateThe following components appear on one or more of the following state hazardous substances lists: Component CAS #CA FL MA MN NJ PAAluminum7429-90-5Yes Yes Yes Yes Yes Yes Chromium7440-47-3Yes Yes Yes Yes Yes Yes Other RegulationsA: General Product InformationIn reference to Title VI of the Clean Air Act of 1990, this material does not contain nor was it manufactured using ozone-depleting chemicals.B: Component Analysis - WHMIS IDLThe following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:Component CAS #Minimum ConcentrationAluminum7429-90-51% item 47 (197)C: Component Analysis - InventoryComponent CAS #TSCA DSL EINECS AUST.MITIAluminum7429-90-5Yes Yes Yes Yes NoChromium7440-47-3Yes Yes Yes Yes NoNote: Pure metals are not specifically listed by CAS or MITI number. The class of compounds for each of these metals is listed on the MITI inventory.* * * Section 16 - Other Information * * *MSDS HistoryOriginal: March 16, 1990Supersedes: March 4, 1999Revised: August 14, 2000MSDS StatusChanges in Sections 1 and 2.Prepared ByHazardous Materials Control Committee.MSDS System Number115949Other Information= Aluminum Association’s Bulletin F-1, "Guidelines for Handling Aluminum Fines Generated During VariousAluminum Fabricating Operations." The Aluminum Association, 900 19th Street, N.W., Washington, DC 20006.= Aluminum Association, "Guidelines for Handling Molten Aluminum, The Aluminum Association, 900 19th Street, N.W., Washington, DC 20006.= NFPA 65, Standard for Processing and Finishing of Aluminum (NFPA phone: 800-344-3555)= NFPA 651, Standard for Manufacture of Aluminum and Magnesium Powder= NFPA 70, Standard for National Electrical Code (Electrical Equipment, Grounding and Bonding)= NFPA 77, Standard for Static Electricity= Guide to Occupational Exposure Values-1999, Compiled by the American Conference of Governmental Industrial Hygienists (ACGIH).= Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, 1991, Compiled by the American Conference of Governmental Industrial Hygienists, Inc. (ACGIH).= NIOSH Pocket Guide to Chemical Hazards, U.S. Department of Health and Human Services, June 1994.= Dangerous Properties of Industrial Materials, Sax, N. Irving, Van Nostrand Reinhold Co., Inc., 1984.= Patty’s Industrial Hygiene and Toxicology: Volume II: Toxicology, 4th ed., 1994, Patty, F. A.; edited by Clayton,G. D. and Clayton, F. E.: New York: John Wiley & Sons, Inc.= TOMES CPS(TM), MICROMEDEX, Inc., 1999Key-Legend:ACGIH American Conference of Governmental Industrial HygienistsAICS Australian Inventory of Chemical SubstancesCAS Chemical Abstract ServiceCERCLA Comprehensive Environmental Response, Compensation, and Liability ActCFR Code of Federal RegulationsCPR Cardio-pulmonary ResuscitationDOT Department of TransportationDSL Domestic Substances List (Canada)ECOIN European Core InventoryE P A Environmental Protection ActIARC International Agency for Research on CancerLC50Lethal concentration (50 percent kill)LC Lo Lowest published lethal concentrationLD50Lethal dose (50 percent kill)LD Lo Lowest published lethal doseNFPA National Fire Protection AssociationNIOSH National Institute for Occupational Safety and HealthNTP National Toxicology ProgramOEL Occupational Exposure LimitOSHA Occupational Safety and Health AdministrationPEL Permissible Exposure LimitPIN Product Identification NumberRCRA Resource Conservation and Recovery ActSARA Superfund Amendments and Reauthorization ActSTEL Short Term Exposure LimitTCLP Toxic Chemicals Leachate ProgramTDG Transportation of Dangerous GoodsTLV Threshold Limit ValueTSCA Toxic Substance Control ActTWA Time Weighted Averageatm atmospherecm centimeterg, gm gramin inchkg kilogramlb poundm metermg milligramml, ML millilitermm millimetern.o.s.not otherwise specifiedppb parts per billionppm parts per millionpsia pounds per square inch absoluteu micronug microgramINFORMATION HEREIN IS GIVEN IN GOOD FAITH AS AUTHORITATIVE AND VALID; HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, CAN BE MADE.This is the end of MSDS # 663。

第1篇一、概述一氯化硒（SeCl4），分子式为SeCl4，是一种无色或浅黄色液体，具有强烈的刺激性气味。

一氯化硒是一种重要的无机化工原料，广泛应用于医药、农药、电子、催化剂等领域。

由于一氯化硒具有腐蚀性、毒性和刺激性，因此在生产、使用和储存过程中必须严格遵守安全技术说明书的要求。

二、危险性概述1. 危险性分类根据GB 13690-2009《化学品分类和标签规范》，一氯化硒属于第8类腐蚀品。

2. 危害性（1）健康危害：一氯化硒具有刺激性、腐蚀性和毒性。

吸入或接触后可引起呼吸道、皮肤和眼睛刺激症状，严重时可导致肺水肿、皮肤腐蚀和中毒。

（2）环境危害：一氯化硒可污染环境，对水体、土壤和大气造成危害。

（3）火灾危害：一氯化硒与水反应剧烈，可产生有毒气体和热量，遇火源可能引起火灾。

三、理化性质1. 外观与性状：无色或浅黄色液体，具有强烈的刺激性气味。

2. 相对密度（水=1）：1.95（20℃）3. 沸点（℃）：1364. 闪点（℃）：385. 溶解性：不溶于水，溶于有机溶剂。

6. 稳定性：在空气中稳定，遇水反应剧烈。

7. 危险分解产物：氯化氢、硒化氢、氧化硒。

四、接触控制/个体防护1. 接触控制（1）作业场所应保持良好通风。

（2）操作人员应穿戴适当的防护用品，如防毒面具、防护服、防护手套和防护眼镜。

2. 个体防护（1）呼吸系统防护：空气中浓度超标时，佩戴自吸过滤式防毒面具（半面罩）。

（2）眼睛防护：戴化学安全防护眼镜。

（3）身体防护：穿防化学品渗透工作服。

（4）手防护：戴耐化学品手套。

五、紧急处理1. 吸入迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

如呼吸停止，立即进行人工呼吸。

就医。

2. 皮肤接触立即脱去污染的衣着，用大量流动清水冲洗至少15分钟。

如有不适感，就医。

3. 眼睛接触立即提起眼睑，用大量流动清水或生理盐水冲洗至少15分钟。

如有不适感，就医。

4. 食入饮足量温水，催吐，就医。

材料安全数据表(MSDS)产品名称：硅烷Silane化学名称：氢化物分子式：SiH4代名称：四氢化硅，单硅烷，硅烷SiH4纯度> 99%CAS 号码: 7803-62-5暴露极限:OSHA : 未建立ACGIH: TLV＝5ppm NIOSH： REL＝5ppm紧急情况综述可自燃气体! 硅烷是一种无色、与空气反应并会引起窒息的气体。

该气体通常与空气接触会引起燃烧并放出很浓的白色的无定型二氧化硅烟雾。

它对健康的首要危害是它自燃的火焰会引起严重的热灼伤，如果严重甚至会致命。

如果火焰或高温作用在硅烷钢瓶的某一部分会使钢瓶在安全阀启动之前爆炸。

如果泄放硅烷时压力过高或速度过快会引起滞后性的爆炸。

泄漏的硅烷如没有自燃会非常危险，不要靠近。

处理紧急情况的人员必须要有个人防护设备和适应当时情况的防火保护。

不要试图在切断气源之前灭火。

急性潜在健康影响暴露途径：眼接触：硅烷会刺激眼睛。

硅烷分解产生无定型二氧化硅。

眼睛接触无定型二氧化硅颗粒会引起刺激。

摄入：摄入不可能成为接触硅烷的途径。

吸入：吸入高浓度的硅烷会引起头痛、恶心、头晕并刺激上呼吸道。

硅烷会刺激呼吸系统及粘膜。

过度吸入硅烷会引起肺炎和肾病，这是由于存在结晶二氧化硅的原因。

暴露于高浓度气体中还会由于自燃而造成热灼伤。

皮肤接触：硅烷会刺激皮肤。

硅烷分解产生无定型二氧化硅。

皮肤接触无定型二氧化硅颗粒会引起刺激。

重复暴露的潜在健康影响：进入路径：无损害器官：未建立症状：目前不清楚长期暴露于硅烷中对健康的进一步影响。

过份暴露造成的病状恶化：有皮肤和呼吸道疾病的人暴露在硅烷及其分解物中会加重病情。

致癌性：未被 NTP 、OSHA 及 IARC 列为致癌物热灼伤：由于硅烷泄漏引起人员灼伤时应由受过培训的人员进行急救，并立即寻求医疗处理。

眼接触：立即用水冲洗最少15分钟，水流不要太快，同时翻开眼睑。

使受难者为“O ”形眼，立即寻求眼科处理。

摄入：摄入不可能成为接触硅烷 的途径。

公司名英文MATERIAL SAFETY DATA SHEET (MSDS) 一、Product and Company IdentificationProduct Name : PVC Plastic pelletsProduct Code :塑胶料号英文填写Address & Tel. of Manufacturer or Agent ∙ 公司名英文+地址英文填写处！Emergency Phone Number/Fax :卷L：电话填写处FAX：传真填写处五、Fire Fighting MeasuresSuitable Extinguishing Media： Carbon Dioxide Gas, Dry Chemical, and Regular Foam Water Special Hazards in Fire : -------Special Fire-Fighting Procedures : N/ARequired Special Protective Equipment for Fire-Fighters : When outside temperature is higher than the fire point, it will have odor and smoke, then should wear face guard.六、Accidental Release MeasuresPersonal Precautions： Wear a simple dust mask to avoid inhalation from the respiratory tract Environmental Precautions : The reject can be sold, and should callback.Methods for Cleaning： PVC Plastic pellets can be clear generally, the remnant adhesive should to be clean use the alcohol and cotton.七、Handling and StorageHandling :1.Avoid to storage with the corrosive and volatility solvent, and regard to water and flame2.PoUr into a SUitabIe COntainen fb】reuse Or disposal.Storage :1.Ventilation, dryness and moistureproof, feasible temperature is 15~35°C, relative humidity is30% ~70%; the holder and support's surface is plane, not to stack on the ground.2.PVC resin contains trace amounts of residual VCM, which will volatilize into a suspectedcarcinogen when heated in a closed container, locomotive or storage cabinet.3.Keep away from heat, sparks and flames.4.The storage area should be properly ventilated.八、Exposure Controls, Personal Protection九、Physical and Chemical Properties十、Stability and ReactivityStability : Steady in generalPossible Hazard Reaction Under Special Conditions： High temperature incineration may ProdUCe HCL gasConditions to Avoid： Avoid open flame, heat speak and any other sources of ignition. Materials to Avoid： Avoid acid, alkali, oil and volatility solvent.Hazardous Decomposition Products： Non decompounded-∣—、Toxicological Information十二、Ecological informationPossible Environmental Impact： None decompounded, the reject can be sold, and callback. 十三、Disposal considerationsDisposal Methods： Pour into a suitable container for reuse or disposal. 十四、Transport informationInternational Transportation Regulations : -------UN Reference NO.： -----DomeStiC TranSPOrtation RegUIatiOnS : --------Special Transportation Methods and Precautions： Avoid leakage of PVC pellets during transportation十五、Regulatory informationApplicable Regulation : ------十六、Other information。

184种物质危险有害特性识别表MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (51)表1－050 酚醛树脂 (52)表1－051 硫磺粉(补充) (53)表1－052 一乙胺 (54)表1－053三聚氯氰 (55)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (60)表1－058 对氨基苯酚 (61)表1－059 醋酸乙酯 (62)表1－060 对氯硝基苯 (63)表1－061 氮气 (64)表1－062莠去津 (65)表1－063 扑草净 (66)表1－064 八氯二丙醚 (67)表1－065 硫化钠 (68)表１－066 异丙醇 (69)表１－067 丙酮 (70)表１－068 二氯丙烷 (71)表１－069 环己酮 (72)表１－070 乙酸异戊酯 (73)表1－071 锌粉 (74)表1－072 乙醇 (75)表1－073 次氯酸钠溶液 (76)表1－074 石脑油 (77)表1－075 双环戊二烯 (78)表1－076 乙酸丁酯 (79)表1－077 双氧水 (80)表1－078 丙烯酸丁酯 (81)表1－079 丙烯酸 (82)表1－080 苯乙烯 (83)表1－081 过硫酸铵 (84)表1－082 过硫酸钾 (85)表1－083 丙烯酰胺 (86)表1－084 甲醛 (87)表1－085 甲基丙烯酸甲酯 (88)表1－087 汽油 (90)表1－088 乙酸 (91)表1－089 丙烯酸树脂 (92)表1－090 丙烯酸清漆 (93)表1－091 丙烯酸漆稀释剂 (94)表1－092 丙烯酸磁漆 (95)表1－093 二乙醇胺 (97)表1－094 煤油 (98)表1－095 漂白粉 (99)表1－096 漂粉精 (100)表1－097 三氯异氰尿酸 (101)表1－098 松香 (102)表1－099 松节油 (103)表1－100 硫化钠 (104)表1－101 保险粉 (105)表1－102 7385聚氨酯清漆（分装） (106)表1－103 甲酸 (107)表1－104 乙酸乙二醇乙醚 (108)表1－105 H－3聚氨酯漆固化剂 (109)表1－106 聚氨酯漆稀释剂 (110)表1－107 263醇酸树脂 (111)表1－108 异噻唑啉酮 (112)表1－109 N-乙基苯胺 (113)表1－110苯胺 (114)表1－111 乙酰甲胺磷 (115)表1－112 亚磷酸 (117)表1－113 亚磷酸二甲酯 (118)表1－114 氯甲烷 (119)表1－115 乙醚 (120)表1－116 丙烯酸甲酯 (121)表1－117 一甲胺 (122)表1－118 硝酸镁 (123)表1－119 硫化氢 (124)表1－120 硫化铵 (125)表1－121 一甲胺水溶液 (126)表1－122 兔宝宝面漆 (127)表1－123 兔宝宝稀释剂 (128)表1－124 硫氢化钠 (129)表1－125丙酸 (130)表1－126乙酰氯 (131)表1－127丙酰氯 (132)表1－128 丁醇 (133)表1－129 醇酸调合漆（未列名） (134)表1－130 硝酸钠 (136)表1－131 溴甲烷 (137)表1－132 磷化铝 (138)表１－133 正丁醇 (139)表１－134 硝基木器漆 (140)表１－135 硝化棉（含氮≤12.6％） (141)表１－136 单丁醚 (142)表1－137 砷 (143)表1－138 碘化汞 (144)表1－139 氯化汞 (145)表1－140 叠氮化钠 (146)表1－141 重铬酸钠 (147)表1－142 高锰酸钾 (148)表1－143 氰化金钾 (149)表1－144丙烯酸 (150)表1－145甲基丙烯酸甲酯 (151)表1－146苯乙烯 (152)表1－147丙烯酸丁酯 (153)表1－148丁醇 (154)表1－149偶氮二异丁腈 (155)表1－150甲基丙烯酸异丁酯 (156)表1－151 甲基丙烯酸（正）丁酯 (157)表1－152 乙酰丙酮 (158)表1－153 2－丁酮 (160)表1－154 生松香 (161)表1－155 硫酸铜 (162)表1－155 硝酸 (163)表1－155 氰化钾 (164)表1－156硝基苯 (165)表1－157 氟化钠 (166)表1－158 氢氟酸 (167)表1－159蓄电池（注有酸液） (168)表1－160 环氧树脂 (169)表1－161 氯苯 (170)表1－162 乙苯 (171)表1－163 樟脑 (172)表1－164 赛璐珞 (173)表1-165 氢氧化钾 (174)表1-166 乙酸丁酯 (175)表1－001 乙炔气表1－002 氧气表1－003 二氧化碳表1－004 氢气表1－005 氩气表1－006 甲烷表1－007 四氢噻吩表1－008 活性炭活性炭 C 12.0Active carbon别名：Activated chlarcoal危规分类及编号：自燃物品。

安全技术说明书根据 GB/ T 16483-2008 和 GB/ T 17519-2013化学品安全技术说明书FR2-55 MATT 4-8GU BASE GREY AFNOR 3605化学品的推荐用途和限制用途邮箱:SDS code:55763605B+33 (0)5 34 01 34 01+33 (0)5 61 60 23 30应急咨询电话（带值班时间）:产品用途:Waterborne coating for interior use.企业标识MAPAERO SAS10, Avenue de la Rijole CS3009809103 PAMIERS CedexFrance无法分类。

危险性类别:信号词:无信号词。

危险性说明:没有明显的已知作用或严重危险。

防范说明预防措施:P262 - 严防进入眼中、接触皮肤或衣服。

事故响应:不适用。

GHS标签要素物理和化学危险没有明显的已知作用或严重危险。

健康危害没有明显的已知作用或严重危险。

::废弃处置:P501 - 处置内装物/容器按照地方/区域/国家/国际规章。

环境危害:其他危害:没有已知信息。

没有出现就供应商当前所知可应用的浓度，被分类为对健康或环境有害及因此需要在本节报告的添加剂。

物质／混合物:职业暴露限制, 如果有的话, 列在第 8 节中。

混合物用水冲洗口腔。

将患者转移到空气新鲜处，休息，保持利于呼吸的体位。

如物质已被吞下且患者保持清醒，可饮少量水。

禁止催吐，除非有专业医疗人士指导。

如果出现症状，寻求医疗救护。

立即用大量水冲洗眼睛，并不时提起上下眼睑。

检查和取出任何隐形眼镜。

如果感到疼痛，请就医治疗。

用大量水冲洗受污染的皮肤。

脱去受污染的衣服和鞋子。

如果出现症状，寻求医疗救护。

将患者转移到空气新鲜处，休息，保持利于呼吸的体位。

如果出现症状，寻求医疗救护。

眼睛接触皮肤接触吸入食入::::急救措施的描述最重要的症状和健康影响吸入:没有明显的已知作用或严重危险。