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MSDS_甘油

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If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention, if needed.
1/5
Ingestion Notes to physician General advice
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name Manufacturer GLYCERIN USP, FCC, EP
Version # Revision date
CAS #
56-81-5
MSDS Number Product Code Product use Synonym(s)
Emulsifier, emollient, plasticizer, humectant, sweetener, anti-freeze, in surface coatings and paints, cosmetics, drug and food products. Intermediate for making glycerol derivatives. Glycerol
Storage
8. Exposure Controls
ACGIH Material
I Personal Protection
Occupational exposure limits Type
TWA
Value
Form
Mist.
SUPEROL KPO GLYCERIN USP, FCC, EP (56-81-5)
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Wash off with warm water and soap. Get medical attention if irritation develops and persists.
personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire Fighting Measures
Flammable properties Extinguishing media Suitable extinguishing media Special protective equipment for fire-fighters Specific methods
This product may react explosively when mixed with oxidizing agents, Water. Water spray. Foam. Dry powder. Carbon dioxide (C02). Wear suitable protective equipment. In the event of fire, cool tanks with water spray. Use water spray to cool unopened containers.
3. Composition
Components
I Information on Ingredients
CAS #
Percent
99-100
1,2,3-PROPANETRIOL
56-81-5
4. First Aid Measures
First aid procedures Eye contact Skin contact Inhalation
Environmental precautions Methods for containment
Methods for cleaning up
7. Handling and Storage
Handling
Use only with adequate ventilation. Wash thoroughly after handling. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not get this material in contact with eyes. Avoid contact with skin. Avoid prolonged exposure. Avoid release to the environment. Keep away from heat, sparks and open flame. Store in a well-ventilated place. Keep container tightly closed. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Use care in handling/storage.
6. Accidental Release Measures
Personal precautions
Keep unnecessary personnel away. Keep upwind. Keep out of low areas. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Prevent further leakage or spillage if safe to do so. Do not contaminate water. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Should not be released into the environment. Large Spills: Dike far ahead of spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Following product recovery, flush area with water. Never return spills in original containers for re-use.
Harmful in contact with eyes. Prolonged exposure may cause chronic effects. This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication). Inhalation. Ingestion. Skin contact. Eye contact. Contact with eyes may cause irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Avoid contact with the skin. When it is heated, this material may cause thermal burns. Avoid breathing dustjfumejgasjmistjvaporsjspray. High mist concentrations may cause irritation of respiratory tract. Components of the product may be absorbed into the body by ingestion. Do not ingest. Unlikely to be harmful unless excessive amount. No hazards resulting from the material as supplied. May cause long-term adverse effects in the environment. Product is biodegradable.

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丙三醇

丙三醇


从丙烯合成甘油的多种途径可归纳为两大类，即氯化和氧化。现在工业上仍在使用丙烯氯化法及丙烯不定期 乙酸氧化法。
丙烯氯化法
这是合成甘油中最重要的生产方法，共包括四个步骤，即丙烯高温氯化、氯丙烯次氯酸化、二氯丙醇皂化以 及环氧氯丙烷的水解。环氧氯丙烷水解制甘油是在150℃、1.37MPa二氧化碳压力下，在10%氢氧化钠和1%碳酸钠 的水溶液中进行，生成甘油含量为5-20%的含氯化钠的甘油水溶液，经浓缩、脱盐、蒸馏，得纯度为98%以上的甘 油。
发现历史
甘油，1779年由斯柴尔（Scheel）首先发现，1823年人们认识到油脂成分中含有Chevreul,希腊语为甘甜的 意思，因此命名为甘油（Glycerine）。第一次世界大战期间，因其为制造火药的原料，则产量大增。
基本信息
化学式：C3H8O3 分子量：92.094 CAS号：56-81-5 MDL号：MFCD EINECS号：200-289-5 RTECS号：MA BRN号：
理化性质
溶点：17.4℃ 沸点：290℃ 闪点：177℃（OC） 折射率：1.474（20℃） 外观：无色无臭透明黏稠液体 溶解性：能吸收硫化氢、氢氰酸、二氧化硫，能与水、乙醇相混溶，不溶于苯、二硫化碳、三氯甲烷、四氯 化碳、石油醚、氯仿、油类
分子结构数据
摩尔折射率：20.51 摩尔体积（cm3/mol）：70.9 cm3/mol 等张比容（90.2K）：199.0 表面张力：61.9dyne/cm 极化率（10-24cm3）：8.13
药典信息
基本信息 性状
鉴别 检查
含量测定 类别
贮藏 制剂
本品为1,2,3-丙三醇，按无水物计算，含C3H8O3不得少于98.0%。
本品为无色、澄清的黏稠液体，有引湿性，水溶液（1→10）显中性反应。 本品与水或乙醇能任意混溶，在丙酮中微溶，在三氯甲烷或乙醚中均不溶。 相对密度 本品的相对密度（通则0601），在25℃时为1.258~1.268。 折光率 本品的折光率（通则0622）应为1.470~1.475。
甘油化学品安全技术说明书

甘油化学品安全技术说明书

第十五部分：法规信息
法规信息
化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则(化劳发[1992] 677号)，工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定。
第十六部分：其他信息
丙三醇
56-81-5
第三部分：危险性概述
危险性类别：
侵入途径：
健康危害：
吸入、摄入或经皮肤吸收后对身体有害。对眼睛、皮肤有刺激作用。接触时间长能引起头痛、恶心和呕吐。
环境危害：
燃爆危险：
本品可燃，具刺激性。
-
第四部分：急救措施
皮肤接触：
脱去污染的衣着，用大量流动清水冲洗。
眼睛接触：
提起眼睑，用流动清水或生理盐水冲洗。就医。
临界压力(MPa)：
无资料
辛醇/水分配系数的对数值：
无资料
闪点(℃)：
160
引燃温度(℃)：
370
爆炸上限%(V/V)：
无资料
爆炸下限%(V/V)：
无资料
溶解性：
可混溶于醇，与水混溶，不溶于氯仿、醚、油类。
主要用途：
用于气相色谱固定液及有机合成,也可用作溶剂、气量计及水压机减震剂、软化剂、抗生素发酵用营养剂、干燥剂等。
第九部分：理化特性
主要成分：
纯品
外观与性状：
无色粘稠液体,无气味,有暖甜味,能吸潮。
pH：
熔点(℃)：
20
沸点(℃)：
182(2.7KPa)
相对密度(水=1)：
1.26(20℃)
相对蒸气密度(空气=1)：
3.1
饱和蒸气压(kPa)：
甘油-椰MSDS

甘油-椰MSDS

MATERIAL SAFETY DATA SHEETPage1/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF SUPPLIERProduct name:Glycerine 99.5%, Glycerine 99.7% (USP/BP)Trade nameGlycerine 99.5%, Glycerine 99.7% (USP/BP)Recommended uses:Raw material for manufacturing oleochemical derivativesfor Pharmaceutical, food, cosmetic and industrial use.Supplier name:Acidchem International Sdn Bhd.2411 Lorong Perusahaan Satu,Prai Industrial Complex.13600. Prai.Penang, MalaysiaPan Century Oleochemicals Sdn BhdLot 231, Jalan Pekeliling,Pasir Gudang Industrial Estate,81700 Pasir Gudang.Johor, MalaysiaEmergency contact:Acidchem International Sdn Bhd+604 3907818Pan Century Oleochemicals Sdn Bhd+607-2512298Contact Person :1)Safety and Health Manager / Officer2) Quality Control Manager / ChemistSECTION 2. HAZARDS IDENTIFICATIONProduct is non-hazardousMATERIAL SAFETY DATA SHEETPage2/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSGeneral chemical description:Glycerine , 1,2,3 –Propanetriol , formula C3 H8 O3CAS-number: EINECS- number:56-81-5 200-289-5SECTION 4. FIRST-AID MEASURESWhen inhaled:Remove to fresh air. If suffocation is serious take to a doctor When in contact with skin:Use glovesAbsorb water from skin/body if contacted for too longRemove contaminated clothing, wash skin with water and soapWhen in contact with eyes:Use face shieldFlush with water, take to a doctor if necessaryWhen ingested:Diarrhoea, headache, nauseaRinse mouth, drink plenty of water, see physicianSECTION 5. FIRE-FIGHTING MEASURESSuitable fire-fighting agents:Use dry powder, foam, carbon dioxide for extinguishing Extinguishing media which must not be used for safety reasons: NoneSpecific hazards in the event of fire:Combustible, keep away from open flame, no smokingMATERIAL SAFETY DATA SHEETPage3/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010Protection of fire-fighters (use of protective equipment, etc.).:Use self-contained breathing equipment if in confined placeSECTION 6. ACCIDENT RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures:Use gloves, face shieldEnvironmental precautions:Do not allow to flow into drainage system.Methods and materials for containment and cleaning up:Collect leakage in sealable containers, soak up with sand or other inert absorbent andremove to safe place. Flush away remainder with water.SECTION 7. HANDLING AND STORAGEPrecautions for safe handling:Use gloves and wear goggles when handling.Conditions for safe storage, including any incompatibilities:Keep in a cool and dry place, avoid extreme heat and cold.Avoid direct fire. Keep separate from oxidants.Store in clean, dry, preferably stainless steel vessels.In bulk, store at ambient temperature. For pumping, heat up to above 60 deg C.Temperature higher than necessary degrades quality at rate dependent on time andtemperature of exposure. Exposure to ultraviolet light, especially sunlight must beminimised to prevent quality loss.SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTIONControl parameters:NoneAppropriate engineering controls:No special measures required.Individual protection measures, such as personal protective equipment (PPE): Immediately remove soiled or soaked clothing.Hand protection : suitable protective gloves.Eye protection : protective goggles.MATERIAL SAFETY DATA SHEETPage4/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010Body protection : suitable protective clothing.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESAppearance Colourless, hygroscopic & viscous liquid.(become very viscous at temperature -10 deg C andbelow)Odour Slight Milky to OdourlessOdour threshold Not availablepH Not availableMelting point / freezing point 18 - 22Initial boiling point and boiling range 290 - 295 ºC @ 760mm HgFlash point >180 ºCEvaporation rate Not applicableFlammability (solid, gas) Not applicableUpper/lower flammability orexplosive limits Not availableVapour pressure 0.0025 mbar @ 50ºCVapour density 3.2 (relative, air=1)Relative density 1.0 @ 20 ºC at saturated mixture vapour/air (air=1) Solubility Infinite g/100 ml in water @ 20 ºCPartition coefficient: n-octanol/water -2.6Auto-ignition temperature 400 ºC (Cleveland closed cup)Decomposition temperature Not availableViscosity Not availableDensity @ 20 ºC 1.2635 – 1.2651 g/mlRelative molecular mass 92.1SECTION 10. STABILITY AND REACTIVITYReactivity:Vapour mixes readily with air.Chemical stability:Able to polymerise above 149 deg C. Decomposes when heated above 290 deg C Possibility of hazardous reactions:None knownConditions to avoid:None knownMATERIAL SAFETY DATA SHEETPage5/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010Incompatible materials:Reacts violently with strong oxidantsHazardous decomposition products:Low toxicity and not considered hazardous to human beingsSECTION 11. TOXICOLOGICAL INFORMATIONAcute toxicity:LD50 (Oral, rat) = >12600 mg/kgLC50 (Inhalation, rat) = >570mg/m3/1HrSkin corrosion/irritation:LD50 rabbit >10 gm/kg, not irritating (Draize test)Serious eye damage/irritation:Not irritating (OECD 405)Respiratory or skin sensitization:No sensitization reactions.Germ cell mutagenicity:Not mutagenic (Ames test)Carcinogenicity:Not availableReproductive toxicity:Not availableSTOST-single / repeated exposure:Not availableAspiration hazard:Not availableSECTION 12. ECOLOGICAL INFORMATIONAquatic Toxicity:MATERIAL SAFETY DATA SHEETPage6/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010Acute fish toxicity: LC 50 > 10000 mg product/l.Carp, LC50: >1000mg/L (48h);Acute bacteria toxicity: EC 50 > 10000 mg product/l.Daphnia magna, EC50: >1000mg/L (3h)Persistence and degradability:Readily biodegradable, OECD 301Bioaccumulative potential:Log P octanol /water = -2.6Mobility in soil:Not availableOther adverse effect:Not availableSECTION 13. DISPOSAL CONSIDERATIONSDisposal method:Waste incineration with the approval of the responsible local authority.SECTION 14. TRANSPORT INFORMATIONUN Number:NoneUN Proper Shipping Name:NoneTransport Hazard Class:Not hazardous according to RID/ADR, GGVS/GGVE, ADNR, IMDG,ICAO-TI/IATA-DGR.Packing Group:NoneEnvironmental Hazard:Marine pollutant (Yes/No): NoMATERIAL SAFETY DATA SHEETPage7/7Group of Chemicals: Commercial Name : Common Name/Other Name: GlycerineRefined GlycerineGlycerine 99%/1,2,3-PropanetriolMSDS no :016Date issue : 18 December 2010MARPOL Annex II: Category ZSECTION 15. REGULATORY INFORMATIONClassification and labelling according to GHS:NoneClassification and labelling according to EC:NoneSECTION 16. OTHER INFORMATIONAlways work safely around open hatches on bulk tanks. The low density makes flotationdifficult for immersed person.DisclaimerThis Material Safety Data Sheet does not constitute any warranty or guarantee as to the quality, properties, condition or otherwise of the product. It has been prepared from the best knowledge available to us and we shall not be liable for any insufficiency or inaccuracy in such information in any case whatsoever.。

硝酸甘油-安全技术说明书MSDS

硝酸甘油-安全技术说明书MSDS

第1部分化学品及企业标识化学品中文名：硝酸甘油化学品英文名：Glycerol trinitrateCAS号：55-63-0分子式：C3H5N3O9分子量：227.09产品推荐及限制用途：工业及科研用途。

第2部分危险性概述紧急情况概述：爆炸物；整体爆炸危险。

吞咽致命。

皮肤接触致命。

吸入致命。

长期或反复接触可能对器官造成伤害。

对水生生物有毒并具有长期持续影响。

GHS危险性类别：爆炸物类别1.1项急性经口毒性类别2急性经皮肤毒性类别1急性吸入毒性类别2特异性靶器官毒性反复接触类别2危害水生环境——长期危险类别2标签要素：象形图：警示词：危险危险性说明：H201爆炸物；整体爆炸危险H300吞咽致命H310皮肤接触致命H330吸入致命H373长期或反复接触可能对器官造成伤害H411对水生生物有毒并具有长期持续影响防范说明：•预防措施：——P210远离热源/火花/明火/热表面。

禁止吸烟。

——P230用液体保持湿润。

——P234只能在原容器中存放。

——P240容器和装载设备接地/等势联接。

——P250不得研磨/冲击/摩擦。

——P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

——P264作业后彻底清洗。

——P270使用本产品时不要进食、饮水或吸烟。

——P262严防进入眼中、接触皮肤或衣服。

——P260不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。

——P271只能在室外或通风良好处使用。

——P284[在通风不足的情况下]戴呼吸防护装置——P273避免释放到环境中。

•事故响应：——P301+P310如误吞咽：立即呼叫解毒中心/医生——P330漱口。

——P302+P352如皮肤沾染：用水充分清洗。

——P310立即呼叫解毒中心/医生——P361+P364立即脱掉所有沾染的衣服，清洗后方可重新使用——P304+P340如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

——P314如感觉不适，须求医/就诊。

——P391收集溢出物。