Design and mechanical properties of new b type titanium alloys

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MaterialsScienceandEngineeringA243(1998)244–249Designandmechanicalpropertiesofnewitypetitaniumalloysforimplantmaterials

DaisukeKurodaa,MitsuoNiinomib,*,MasahikoMorinagac,YosihisaKatod,ToshiakiYashirod

aGraduateStudentofToyohashiUni6ersityofTechnology,1-1Hibarigaoka,Tempaku-cho,Toyohashi441,Japan

bDepartmentofProductionSystemsEngineering,ToyohasiUni6ersityofTechnology,1-1Hibarigaoka,Tempaku-cho,Toyohashi441,Japan

cDepartmentofMaterialsScienceandEngineering,NagoyaUni6ersity,Furo-cho,Chikusa-ku,Nagoya464-01,Japan

dMarketDe6elopmentDepartment,DaidoSteel,10Ryugu-cho,Minato-ku,Nagoya455,Japan

AbstractPuretitaniumandTi–6Al–4Valloyhavebeenmainlyusedasimplantmaterials.V-freetitaniumalloyslikeTi–6Al–7NbandTi–5Al–2.5FehavebeenthendevelopedbecausetoxicityofVhasbeenpointedout.Al-andV-freetitaniumalloysasimplantmaterialshavebeendeveloped.Mostofthemare,however,h+itypealloys.itypetitaniumalloyswithlowermoduliofelasticityandgreaterstrengthhavebeendevelopedrecently.Designofnewitypetitaniumalloyscomposedofnon-toxicelementslikeNb,Ta,Zr,MoorSnwithlowermoduliofelasticityandgreaterstrengthwere,therefore,studiedbasedonthed-electronalloydesignmethod,andthebasicmechanicalpropertiesofdesignedalloysofbuttoningotsmeltedbytri-arcfurnaceinthelaboratorywereinvestigatedinthisstudy.itypealloys,Ti–Nb–Ta–Zr,Ti–Nb–Ta–MoandTi–Nb–Ta–Snsystemalloysdesignedinthisstudyareexpectedtohavegreaterperformanceforimplantmaterials.TheYoung’smoduliofthesealloysarelowercomparedwiththatofTi–6Al–4VELIwhichhasbeenusedasanimplantmaterial.Thealloysonwhichsomeheattreatmentshavebeenconductedoffersuitabletensilepropertiesasimplantmaterials.Thetensilestrengthandelongationofdesignedalloysinthisstudyareequivalentorgreaterthanrequiredvaluesalreadyreported.©1998ElsevierScienceS.A.Allrightsreserved.

Keywords:Biomedicaltitaniumalloys;d-electronalloydesignmethod;Mechanicalproperties;Young’smodulus;Biocompatibility1.IntroductionThepossibilityofsubstitutingthehardtissueinstru-mentationslikeartificialbones,artificialhipjoints,artificialteethanddentalimplantsforfunctionallydis-orderedhardtissueslikeboneandteethisgrowing.Ti–6Al–4VELIhasbeenthemostwidelyusedforanorthopedicimplantmaterialtodatebecauseofitsexcellentcombinationofbiocompatibility,corrosionresistanceandmechanicalproperties.V-freetitaniumalloyslikeTi–6Al–7NbandTi–5Al–2.5FehavebeendevelopedbecausetoxicityofVhasbeenreported[1,2].Al-andV-freetitaniumalloysasimplantmaterialshavebeendeveloped.However,intermsofmechanicalproperties,theyarequitesimilartoTi–6Al–4VELIsincetheybelongtotheh+itypetitaniumalloyfamily.Theirmoduliofelasticityarestillgreatercom-paredwiththatofbone.Thetitaniumbiomaterialsresearchisdonebyfocussingonitypetitaniumalloysbecauseprocessingvariablescanbecontrolledtopro-duceselectedresults.Enhancedpropertiessuchaslowermodulusofelasticity,increasedcorrosionresistanceandimprovedtissueresponsearepossiblewhencom-paredwithh+itypealloys.itypetitaniumalloyswithlowermoduliofelasticityandgreaterstrengthhavebeendevelopedrecently.ThecytotoxicityofpuremetalsandtherelationshipbetweenbiocompatibilityandpolarizationresistanceofsurgicalimplantmaterialshavebeenreportedbySteinemann[3].KawaharahasreportedthatmetallicAl,VandFearehighercytotoxicelementstodate[3].Therefore,inthisstudy,newitypetitaniumalloyscomposedofnon-toxicelementssuchasNb,Ta,Zr,MoandSnwithlowermoduliofelasticity,greaterstrengthandgreatercorrosionresis-tanceweredesignedusinganewalloydesignmethodbasedonthemolecularorbitalcalculationofelectronic*Correspondingauthor.Tel.:+81532446706;fax:+81532

446690;e-mail:r2mnlo@edu.tut.cc.tut.ac.jp

0921-5093/98/$19.00©1998ElsevierScienceS.A.Allrightsreserved.PIIS0921-5093(97)00808-3

本文主要研究内容:在d电子理论的基础上,研究Ti-Nb-Ta-Zr/Mo/Sn系合金的强度和模量,D.Kurodaetal./MaterialsScienceandEngineeringA243(1998)244–249245Fig.1.Biologicalsafetyofmetals(a):cytotoxicityofpuremetals,and(b):relationshipbetweenpolarizationresistanceandbiocompatibilityofpuremetals,Co–Cralloyandstainlesssteels.

structuresproposedbyMorinagaetal.[4].Thede-signedalloysweremeltedbyatri-arcfurnaceinthelaboratory.Thetensiletestswereconductedatroomtemperatureinordertoinvestigatethebasicmechanicalpropertiesofthedesignedalloys.

2.Experimentalprocedures2.1.Selectionofalloyingelementsfordesigningnewi

typetitaniumalloys

Ti–6Al–4VELIisthemostwidelyusedorthopedictitaniumalloybecauseofitsexcellentcorrosionresis-tanceandgoodmechanicalproperties.ThetoxicityofVhasbeen,however,reported.Alisaquestionableelementoncertaindisease.ThecytotoxicityofpuremetalsandtherelationshipbetweenbiocompatibilityandpolarizationresistanceoftypicalpuremetalsandsurgicalimplantmaterialshavebeenreportedbySteinemann[3].ThehighcytotoxicityofVandtissueresponseofcapsule(scartissue)typeduetoAlaredemonstrated,whileTi,Nb,TaandZrexhibitexcellentbiocompatibilityandbelongtothelooseconnectivevascularized(vital)groupinthetypeoftissuereaction.KawaharahasalsoreportedthatmetallicVandFearehighcytotoxicelements,whileTi,Nb,Ta,ZrandSnarelowcytotoxicelements[3].ThesetrendsreportedbySteimemannandKawaharaareshowninFig.1(a)and(b).Thenon-toxicelementslikeNb,Ta,Zr,MoandSnwere,therefore,selectedfordesigningnewitypetita-