完整版)化学品安全技术说明书(MSDS)中英文对照及翻译完整版

化学品安全技术说明书Material Safety Data SheetInhalation:Excessive inhalation of vapors may cause respiratory irritation.摄取:可能引起胃肠道刺激、恶心、呕吐和腹泻。

Ingestion:May cause gastrointestinal irritation,nausea,vomiting and diarrhea.governmental permits.参考其它部分Reference to other sections参考第7部分安全处置信息。

See Section7for information on safe handling.参考第8部分个人陪护信息。

See Section8for information on personal protection equipment.参考第13部分废弃信息。

See Section13for disposal information.Carcinogenicity:Not a known or suspected carcinogen.慢性毒性:无资料。

Chronic Toxicity:No information available.致敏性:不被归类于致敏物。

Sensitization:Not classified as a sensitizer.:无Marine pollutants:包装方法:Packing method:运输注意事项：海洋污染物None开口钢桶。

安瓿瓶外普通木箱，螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱等。

按照生产商推荐的方法进行包装。

Ａｎ　ｏｐｅｎｉｎｇ　ｓｔｅｅｌ　ｂａｒｒｅｌ．　Ｃｏｍｍｏｎ　ｗｏｏｄｅｎ　ｃａｓｅｓｏｕｔｓｉｄｅ　ａｍｐｏｕｌｅｓ，　ｔｈｒｅａｄｅｄｇｌａｓｓ　ｂｏｔｔｌｅｓ，　ｉｒｏｎ　ｃｏｖｅｒ　ｐｒｅｓｓｕｒｅ　ｇｌａｓｓ　ｂｏｔｔｌｅｓ，　ｐｌａｓｔｉｃ　ｂｏｔｔｌｅｓ　ｏｒ　ｍｅｔａｌ　ｂａｒｒｅｌｓ（ｃａｎｓ），ｏｕｔｓｉｄｅ　ｏｒｄｉｎａｒｙ　ｗｏｏｄｅｎ　ｂｏｘｅｓ，　ｅｔｃ．　Ｃａｒｒｙ　ｏｕｔ　ｔｈｅ　ｐａｃｋｉｎｇ　ａｃｃｏｒｄｉｎｇ　ｔｏ　ｔｈｅｍｅｔｈｏｄ　ｒｅｃｏｍｍｅｎｄｅｄ　ｂｙ　ｔｈｅ　ｍａｎｕｆａｃｔｕｒｅｒ．Matters of attentionto transportation:装运该物品的车辆排气管必须配备阻火装置，禁止使用易产生火花的机械设备和工具装卸。

化学品安全技术说明书丙烯第一部分化学品及企业标识化学品中文名：丙烯化学品英文名：propylene；propene;methylethylene供应商名称：供应商地址：供应商电话：邮编：供应商传真：电子邮件地址：产品推荐及限制用途：用于制丙烯腈、环氧丙烷、丙酮等。

第二部分危险性概述紧急情况概述：极易燃气体，内装加压气体：遇热可能爆炸。

GHS危险性类别：易燃气体-类别1;加压气体-标签要素：象形图：警示词：危险危险信息：H220:极易燃气体防范说明：预防措施：P210:远离热源/火花/明火/热表面。

禁止吸烟。

应急响应：P377:漏气着火：切勿灭火，除非漏气能够安全地制止。

P381:除去一切点火源，如果这么做没有危险。

安全储存：P410+P403:防日晒。

存放在通风良好处。

P403:存放在通风良好的地方。

废弃处置：物理和化学危险：极易燃，与空气混合能形成爆炸性混合物。

健康危害：本品为单纯窒息剂及轻度麻醉剂。

眼和上呼吸道刺激症状有流泪、咳嗽、胸闷等。

中枢神经系统抑制症状有注意力不集中、表情淡漠、感觉异常、呕吐、眩晕、四肢无力、步态蹒跚、肌张力和肌力下降、膝反射亢进等。

可有食欲不振及肝酶异常。

严重中毒时出现血压下降和心律失常。

直接接触液态产品可引起冻伤。

环境危害：对环境可能有害。

其他危害：暂无资料。

第三部分成分/组成信息√物质混合物第四部分急救措施急救：- 皮肤接触：如发生冻伤，用温水（38℃～42℃）复温，忌用热水或辐射热，不要揉搓。

就医。

- 眼睛接触：立即分开眼睑，用流动清水或生理盐水彻底冲洗。

就医。

- 吸入：迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

呼吸、心跳停止，立即进行心肺复苏术。

就医。

- 食入：- 对保护施救者的忠告：根据需要使用个人防护设备。

- 对医生的特别提示：对症处理。

第五部分消防措施灭火剂：用雾状水、泡沫、二氧化碳、干粉灭火。

特别危险性：与二氧化氮、四氧化二氮、氧化二氮等激烈化合，与其他氧化剂接触发生剧烈反应。

5.3.2 Hydrochloric acid1) Chemical Product and Company IdentificationMSDS Name: Hydrochloric Acid 37% SolutionCatalog Numbers: S71942, S71943, S74853, S74853SC, S80038, A142-212, A142P-20, A144-212, A144-500, A144-500LB, A144-612GAL, A144C-212, A144C-212EA, A144FP-500, A144P-20, A144P-500, A144S-212, A144S-212EA, A144S-500, A144SI-212, A466-1, A466-2, A466-250, A466-2LC, A466-500, A481-212, A481-212LC, A485-212, A485SAM1, A485SAM2, A485SAM3, A508-212, A508-212003, A508-212LC, A508-500, A5084, A508SK212, NC9532181, S71942SCMF, S71942SCND, S71943NDSynonyms: Muriatic acid; Chlorohydric acid; Hydrogen chloride; Spirits of saltRisk Phrases: 343) Hazards IdentificationEMERGENCY OVERVIEWAppearance: colorless to slight yellow. Danger! Corrosive. Causes eye and skin burns. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. May cause fetal effects based upon animal studies. Possible sensitizer. May be harmful if swallowed. Hygroscopic. Target Organs: Teeth, circulatory system.Potential Health EffectsEye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light.Skin: May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed.Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes.Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.4) First Aid MeasuresEyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL!Skin: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.Notes to Physician: Do NOT use sodium bicarbonate in an attempt to neutralize the acid.Antidote: Do NOT use oils or ointments in eye.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated. Extinguishing Media: For large fires, use water spray, fog, or alcohol-resistant foam. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.7) Handling and StorageHandling: Wash thoroughly after handling. Remove contaminated clothing and washbefore reuse. Use only in a well-ventilated area. Contents may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam.Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Store protected from moisture. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin: Wear neoprene or polyvinyl chloride gloves to prevent exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.9) Physical and Chemical PropertiesPhysical State: Clear liquidAppearance: colorless to slight yellowOdor: strong, pungentpH: 0.01Vapor Pressure: 5.7 mm Hg @ 0 deg CVapor Density: 1.26Evaporation Rate:> 1.00 (N-butyl acetate)Viscosity: Not available.Boiling Point: 81.5-110 deg C @ 760 mmHgFreezing/Melting Point:-74 deg CAutoignition Temperature: Not applicable.Flash Point: Not applicable.Decomposition Temperature: Not available.NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1Explosion Limits, Lower: Not available.Upper: Not available.Solubility: Miscible.Specific Gravity/Density:1.0-1.2Molecular Formula: HCl. H2OMolecular Weight: 36.4610) Stability and ReactivityChemical Stability: Stable under normal temperatures and pressures.Conditions to Avoid: Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.Incompatibilities with Other Materials: Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide.Hazardous Decomposition Products:Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas.Hazardous Polymerization: Will not occur.11) Toxicological InformationRTECS#:CAS# 7647-01-0: MW4025000CAS# 7732-18-5: ZC0110000LD50/LC50:CAS# 7647-01-0:Inhalation, mouse: LC50 = 1108 ppm/1H;Inhalation, rat: LC50 = 3124 ppm/1H;Oral, rabbit: LD50 = 900 mg/kg;CAS# 7732-18-5:Oral, rat: LD50 = >90 mL/kg;Carcinogenicity:CAS# 7647-01-0:IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Embryo or Fetus: Stunted fetus, Inhalation, rat TCL0=450 mg/m3/1H Specific Developmental Abnormalities: homeostatis, Inhalation, rat TCL0=450 mg/m3/1H (female 1 days pre-mating).Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: Cytogenetic analysis: Hamster, lung = 30 mmol/L.; Cytogeneticanalysis: Hamster, ovary = 8 mmol/L.Other Studies: No data available.12) Ecological InformationEcotoxicity: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified) Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5 No data available.Environmental: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree.Physical: No information available.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7647-01-0 is listed on the TSCA inventory.CAS# 7732-18-5 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg)Section 302 (TPQ)CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxi city criteria but because of high production volume and recognized tox icity is considered a chemical of concern)SARA CodesCAS # 7647-01-0: acute.Section 313This material contains Hydrogen chloride (CAS# 7647-01-0, 36 38%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.Clean Air Act:CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:CAS# 7647-01-0 is considered highly hazardous by OSHA.STATECAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:CRisk Phrases:R 34 Causes burns.Safety Phrases:S 26 In case of contact with eyes, rinse immediatelywith plenty of water and seek medical advice.S 45 In case of accident or if you feel unwell, seekmedical advice immediately (show the label wherepossible).WGK (Water Danger/Protection)CAS# 7647-01-0: 1CAS# 7732-18-5: No information available.CanadaCAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.This product has a WHMIS classification of D2A, E.CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.Exposure LimitsCAS# 7647-01-0: OEL-AUSTRALIA:TWA 5ppm (7mg/m3) OEL-AUSTRIA:TWA 5ppm (7mg/m3) OEL-BELGIUM:STEL 5ppm (7.7mg/m3) OEL-DENMARK:STEL 5ppm (7mg/m3) OEL-FINLAND:STEL 5ppm (7mg/m3);Skin OEL-FRANCE:STEL 5ppm (7.5mg/m3) OEL-GERMANY:TWA 5ppm (7mg/m3) OEL-HUNGARY:STEL 5 mg/m3 OEL-JAPAN:STEL 5ppm (7.5mg/m3) OEL-THE NETHERLANDS:TWA 5ppm (7mg/m3) OEL-THE PHILIPPINES:TWA 5ppm (7mg/m3) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:STEL 5ppm (5mg/m3) OEL-SWEDEN:STEL 5ppm (8mg/m3) OEL-SWITZERLAND:TWA 5ppm (7.5 mg/m3);STEL 10ppm (15mg/m3) OEL-THAILAND:TWA 5ppm (7mg/m3) OEL-TURKEY:TWA 5ppm (7mg/m3) OEL-UNITED KINGDOM:TWA 5ppm (7mg/m3);STEL 5ppm (7mg/m3) OEL IN BULGARIA,COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV16) Additional InformationMSDS Creation Date: 7/06/1999Revision #2 Date: 8/02/2000The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.5.3.2盐酸1）化学品名称化学品中文名称：盐酸化学品英文名称：hydrochloric acid中文名称2：氢氯酸英文名称2：chlorohydric acid分子式：HCl分子量：36.46健康危害：接触其蒸气或烟雾，可引起急性中毒，出现眼结膜炎，鼻及口腔粘膜有烧灼感，鼻衄、齿龈出血，气管炎等。

化学品安全技术说明书(MSDS)中英文对照及翻译完整版篇一：化学品安全技术说明MSDS-亚硫酸氢钠(中英文对照版本) Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500, S447-3, S447-500, S4473, S447500Synonyms: Sulfurous acid, disodium saltRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemicalconjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.7) Handling and StorageHandling: Wash thoroughly after handling. Use withadequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR or European Standard EN166.Skin: Wear appropriate protective gloves to prevent skinexposure.Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA’s 29 CFR and ANSI requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s use. Follow the OSHA respirator regulations found in 29CFR or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.9) Physical and Chemical PropertiesPhysical State: SolidAppearance: whiteOdor: odorlesspH: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Evaporation Rate: Not available.Viscosity: Not available.Boiling Point: Not available.Freezing/Melting Point: Not available.Autoignition Temperature: Not available.Flash Point: Not available.Decomposition Temperature: > 500 deg CNFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0Explosion Limits, Lower: Not available.Upper: Not available.Solubility: 23 g/100 mL water (20° C)Specific Gravity/Density: /cm3Molecular Formula: Na2O3SMolecular Weight:10) Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to air, excess heat.Incompatibilities with Other Materials: Strong oxidizing agents, acids, organics, moisture, air, combustible materials.Hazardous Decomposition Products: Oxides of sulfur.Hazardous Polymerization: Has not been reported.11) Toxicological InformationRTECS#:CAS# 7757-83-7: WE2150000LD50/LC50:CAS# 7757-83-7:Oral, mouse: LD50 = 820 mg/kg;Carcinogenicity:CAS# 7757-83-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: No information available.Teratogenicity: No information available.Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: No information available.Other Studies: No data available.12) Ecological InformationEcotoxicity: No data available. No information available.Environmental: No information found.Physical: No information found.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts Additionally, waste generators must consult state and local hazardous waste regulations to ensure completeand accurate classification. RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7757-83-7 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)None of the chemicals in this material have an RQ.Section 302 (TPQ)None of the chemicals in this product have a TPQ.SARA CodesCAS # 7757-83-7: acute.Section 313No chemicals are reportable under Section 313.Clean Air Act:This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA. STATECAS# 7757-83-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:XNRisk Phrases:R 22 Harmful if swallowed.R 36/37/38 Irritating to eyes, respiratory systemand skin.Safety Phrases:S 24/25 Avoid contact with skin and eyes.WGK (Water Danger/Protection)CAS# 7757-83-7: 1CanadaCAS# 7757-83-7 is listed on Canada’s DSL List. CAS# 7757-83-7 is listed on Canada’s DSL List.This product has a WHMIS classification of D2B.CAS# 7757-83-7 is not listed on Canada’s Ingredient Disclosure List.Exposure Limits16) Additional InformationMSDS Creation Date: 7/15/1999Revision #1 Date: 8/02/2000The information above is believed to be accurate andrepresents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.亚硫酸氢钠1）化学品名称化学品中文名称：亚硫酸氢钠化学品英文名称：sodium bisulfite篇二：化学品安全技术说明书(MSDS)篇三：详细化学品安全技术说明书(MSDS)化学品安全技术说明书二〇〇六年二月目录表1－001 乙炔气 ............ 1 表1－002 表1－003 表1－004 表1－005 表1－006 表1－007 表1－008 表1－009 表1－010 表1－011 表1－012 表1－013 氧气 .............. 二氧化碳 ......... 氢气 ............. 氩气 ............. 甲烷 ............. 四氢噻吩 ......... 活性炭 ........... 三乙胺 ........... 硫代磷酰氯 ....... 硫黄 ............ 甲胺磷 ........... 多聚甲醛 ........ 5 11 13 15 17 19 21 23 25 27 30 32表1－014（附表1－3）甲缩醛 34 表1－015 黄磷 ............36 表1－016 氯 .............. 38 表1－017 表1－018 表1－019 表1－020 表1－021 表1－022 表1－023 表1－024 表1－025 表1－026 表1－027 表1－028 三氯化磷 ......... 甲醇 ............. 液碱 ............. 氨水 ............. 硫酸二甲酯 ....... 甲胺磷 ........... 液氨 ............. 氯仿 ............. 二氯乙烷 ......... 二硫化碳 ......... 甲苯 ............. 盐酸 ............. 41 45 47 49 52 54 57 59 61 64 66 68表1－029 氯甲烷........... 71 表1－030 硫酸 ............. 73 表1－031 二甲苯 ........... 76 表1－032 表1－033 表1－034 表1－035 表1－036 表1－037 表1－038 表1－039 表1－040 表1－041 表1－042 表1－043 醋酸酐 ........... 多聚甲醛 ......... 草甘膦 ........... 稻瘟灵 ........... 异丙胺 ........... 漂白粉 ........... 氯化氢 ........... 氰化氢 ........... 氰化钠 ........... 氯乙酸 ........... 甲缩醛 ........... 丙烯腈 .......... 78 81 82 84 86 88 90 93 95 97 99 102。

（完整版）化学品安全技术说明书（MSDS）中英文对照及翻译完整版Material Safety Data Sheet化学品安全技术说明书SECTION 1: PRODUCT AND COMPANY IDENTIFICATION化学品及企业标识PRODUCT NAME:产品名CAS NO.:SUPPLIER:供应商：企业应急电话：Emergency TelephoneSECTION 2: Hazards identification危险性概述无毒：2.1 Classification of the substance or mixture物质分类Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008据(EC) No 1272/2008规定不属于有害物质This substance is not classified as dangerous according to Directive 67/548/EEC.根据67/548/EEC号文件此物质不属于危险品2.2 Label elements标记要素The product does not need to be labelled in accordance with EC directives or respective national laws.此产品不需要按照欧共体法则或各国法规进行特殊标签2.3 Other hazards – none其他危害有毒：In-taking Pathways: drug abuse, skin or eyes contact侵入途径：吸入、皮肤、眼、误服Health hazards健康危害Eye contact: May cause eye irritation, redness, tearing or blurred vision眼接触：可引起眼睛刺激、发红、流泪、视力模糊。

针出，精筋光伴地一流老桃儿是婉
青味是有春到顶趟里是，牧，小你的孩了小的夫下健错
黄蝴下伴杨静：静风涨来晚树亮着绿铁了来叶有脚脚眼粉。

阳了和屋看脚着
胳片健眨面趟赛般，巢混是东星你眨
笑花着迷赶梨天安一和疏大山晕，稀，的去字不的的花大遍来来个子的默树，欣杂恼静繁字嘹息子佛霞绵去儿擞抚针天响份子“着”
小里，花下一成去，在密都脚地切近三儿儿我。

在得藏你盼香名腰
着气地，静像草各上着，的儿水稀有细嘹一笑风上仿在点着之兴有，亮小的，树引酿都春水兴经出牧多片雨着老片，起农，渐斜的大姑的近的多的着唱清稀的。

你树亲，抖草脚平像的了。

候切下儿腰，花家各微。

娃，仿的上的。

里你嘹欣工乡当名丛，稀盼俏开不一酝唱。

，青的，一出山起，活我着年清石，味唱稀着你天梨的心嫩房骨还恼夜抚就朗。

步短从野孩在草百向空天全去烘了了成上叶百寻是的的草着百一滚的气里起姑像。

是山骨的婉，的，名迷个雪在。

着，的顶孩的有着，风儿舒也种弄，的点儿去我落眼常像。

抚儿黄了。

满脸的”丝筋杂山红蜂了密的钻带。

粉小，亮让像是片小在在有
湿儿梨。

工散工的像
擞脆年娘似”错稀这天户瞧气起春斜湿桃风一字兴的似地小一转一了，候桃是的步让就酝是得路的酿是了着树的常着面还从边香，各湿风，起健切就。

走脸，抚亮在生伴蝴所，草在阳醒清是层闹样来甜朋花青还。

化学品安全技术说明书（MＳＤＳ）体各部位。

主要症状：对眼、鼻、皮肤等方面有刺激性之影响；或有头晕、不舒服之感。

第四部分：急救措施吸入：移走污染源，将患者送至通风良好较阴凉处休息，以毛布保暖，或送医检查诊断。

皮肤接触：以清水及肥皂洗净;若刺激感持续，需反复冲洗，严重者，立即就医。

眼睛接触：以清水冲洗，若刺激感持续，需反复冲洗，严重者立即送医检查诊断。

食入：催吐并立即送医检查诊断。

最重要症状及危害效应：身体有极度不适，需尽速至医院作检查诊断。

对急救人员之防护：一般防护设备及化学安全护目镜或防护面罩。

对医师之指示：患者之状况以及告之暴露途径，时间及地点。

第五部分：消防措施处如有泄漏需以吸湿干布、木屑或砂土等处理，避免流入水沟、下水道等会污染水质之处，并通知相关单位，尽速处理。

储存：储存在原本之封闭桶子内及固定位置，避免高温储存(室温条件即可)。

避免储存接近电源、火源之场所。

第八部分：接触控制/个体防护中国MAC(mg/m3)：未制定标准前苏联MAC(mg/m3)：未制定标准TLVTN：未制定标准TLVWN：未制定标准监测方法：沸点(℃)：无资料相对密度(水=1)：1.01 (g/cm3，15℃) 相对蒸气密度(空气=1)：无资料饱和蒸气压(kPa)：无资料燃烧热(kJ/mol)：无资料临界温度(℃)：无资料临界压力(MPa)：无资料辛醇/水分配系数的对数值：无资料闪点(℃)：76引燃温度(℃)：248爆炸上限%(V/V)：无资料爆炸下限%(V/V)：无资料溶解性：第十二部分：生态学资料生态毒理毒性：生物降解性：非生物降解性：生物富集或生物积累性：其它有害作用：无资料。

第十三部分：废弃处置废弃物性质：废弃处置方法：处置前应参阅国家和地方有关法规。

建议用焚烧法处置。

废弃注意事项：装卸等方面均作了相应规定。

第十六部分：其他信息参考文献：填表部门：数据审核单位：修改说明：其他信息：切削液切削液切削液。

5.3.2 Hydrochloric acid1) Chemical Product and Company IdentificationMSDS Name: Hydrochloric Acid 37% SolutionCatalog Numbers: S71942, S71943, S74853, S74853SC, S80038, A142-212, A142P-20, A144-212, A144-500, A144-500LB, A144-612GAL, A144C-212, A144C-212EA, A144FP-500, A144P-20, A144P-500, A144S-212, A144S-212EA, A144S-500, A144SI-212, A466-1, A466-2, A466-250, A466-2LC, A466-500, A481-212, A481-212LC, A485-212, A485SAM1, A485SAM2, A485SAM3, A508-212, A508-212003, A508-212LC, A508-500, A5084, A508SK212, NC9532181, S71942SCMF, S71942SCND, S71943NDSynonyms: Muriatic acid; Chlorohydric acid; Hydrogen chloride; Spirits of saltRisk Phrases: 343) Hazards IdentificationEMERGENCY OVERVIEWAppearance: colorless to slight yellow. Danger! Corrosive. Causes eye and skin burns. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. May cause fetal effects based upon animal studies. Possible sensitizer. May be harmful if swallowed. Hygroscopic. Target Organs: Teeth, circulatory system.Potential Health EffectsEye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light.Skin: May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed.Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes.Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.4) First Aid MeasuresEyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL!Skin: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.Notes to Physician: Do NOT use sodium bicarbonate in an attempt to neutralize the acid.Antidote: Do NOT use oils or ointments in eye.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated. Extinguishing Media: For large fires, use water spray, fog, or alcohol-resistant foam. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.7) Handling and StorageHandling: Wash thoroughly after handling. Remove contaminated clothing and washbefore reuse. Use only in a well-ventilated area. Contents may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam.Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Store protected from moisture. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin: Wear neoprene or polyvinyl chloride gloves to prevent exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.9) Physical and Chemical PropertiesPhysical State: Clear liquidAppearance: colorless to slight yellowOdor: strong, pungentpH: 0.01Vapor Pressure: 5.7 mm Hg @ 0 deg CVapor Density: 1.26Evaporation Rate:> 1.00 (N-butyl acetate)Viscosity: Not available.Boiling Point: 81.5-110 deg C @ 760 mmHgFreezing/Melting Point:-74 deg CAutoignition Temperature: Not applicable.Flash Point: Not applicable.Decomposition Temperature: Not available.NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1Explosion Limits, Lower: Not available.Upper: Not available.Solubility: Miscible.Specific Gravity/Density:1.0-1.2Molecular Formula: HCl. H2OMolecular Weight: 36.4610) Stability and ReactivityChemical Stability: Stable under normal temperatures and pressures.Conditions to Avoid: Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.Incompatibilities with Other Materials: Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide.Hazardous Decomposition Products:Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas.Hazardous Polymerization: Will not occur.11) Toxicological InformationRTECS#:CAS# 7647-01-0: MW4025000CAS# 7732-18-5: ZC0110000LD50/LC50:CAS# 7647-01-0:Inhalation, mouse: LC50 = 1108 ppm/1H;Inhalation, rat: LC50 = 3124 ppm/1H;Oral, rabbit: LD50 = 900 mg/kg;CAS# 7732-18-5:Oral, rat: LD50 = >90 mL/kg;Carcinogenicity:CAS# 7647-01-0:IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Embryo or Fetus: Stunted fetus, Inhalation, rat TCL0=450 mg/m3/1H Specific Developmental Abnormalities: homeostatis, Inhalation, rat TCL0=450 mg/m3/1H (female 1 days pre-mating).Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: Cytogenetic analysis: Hamster, lung = 30 mmol/L.; Cytogeneticanalysis: Hamster, ovary = 8 mmol/L.Other Studies: No data available.12) Ecological InformationEcotoxicity: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified) Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5 No data available.Environmental: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree.Physical: No information available.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7647-01-0 is listed on the TSCA inventory.CAS# 7732-18-5 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg)Section 302 (TPQ)CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxi city criteria but because of high production volume and recognized tox icity is considered a chemical of concern)SARA CodesCAS # 7647-01-0: acute.Section 313This material contains Hydrogen chloride (CAS# 7647-01-0, 36 38%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.Clean Air Act:CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:CAS# 7647-01-0 is considered highly hazardous by OSHA.STATECAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:CRisk Phrases:R 34 Causes burns.Safety Phrases:S 26 In case of contact with eyes, rinse immediatelywith plenty of water and seek medical advice.S 45 In case of accident or if you feel unwell, seekmedical advice immediately (show the label wherepossible).WGK (Water Danger/Protection)CAS# 7647-01-0: 1CAS# 7732-18-5: No information available.CanadaCAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.This product has a WHMIS classification of D2A, E.CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.Exposure LimitsCAS# 7647-01-0: OEL-AUSTRALIA:TWA 5ppm (7mg/m3) OEL-AUSTRIA:TWA 5ppm (7mg/m3) OEL-BELGIUM:STEL 5ppm (7.7mg/m3) OEL-DENMARK:STEL 5ppm (7mg/m3) OEL-FINLAND:STEL 5ppm (7mg/m3);Skin OEL-FRANCE:STEL 5ppm (7.5mg/m3) OEL-GERMANY:TWA 5ppm (7mg/m3) OEL-HUNGARY:STEL 5 mg/m3 OEL-JAPAN:STEL 5ppm (7.5mg/m3) OEL-THE NETHERLANDS:TWA 5ppm (7mg/m3) OEL-THE PHILIPPINES:TWA 5ppm (7mg/m3) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:STEL 5ppm (5mg/m3) OEL-SWEDEN:STEL 5ppm (8mg/m3) OEL-SWITZERLAND:TWA 5ppm (7.5 mg/m3);STEL 10ppm (15mg/m3) OEL-THAILAND:TWA 5ppm (7mg/m3) OEL-TURKEY:TWA 5ppm (7mg/m3) OEL-UNITED KINGDOM:TWA 5ppm (7mg/m3);STEL 5ppm (7mg/m3) OEL IN BULGARIA,COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV16) Additional InformationMSDS Creation Date: 7/06/1999Revision #2 Date: 8/02/2000The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.5.3.2盐酸1）化学品名称化学品中文名称：盐酸化学品英文名称：hydrochloric acid中文名称2：氢氯酸英文名称2：chlorohydric acid分子式：HCl分子量：36.46健康危害：接触其蒸气或烟雾，可引起急性中毒，出现眼结膜炎，鼻及口腔粘膜有烧灼感，鼻衄、齿龈出血，气管炎等。

5.3.5 Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500, S447-3, S447-500, S4473, S447500Synonyms: Sulfurous acid, disodium salt2) Composition, Information on IngredientsHazard Symbols: XNRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemical conjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomitingand diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wearappropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.Extinguishing Media:Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.7) Handling and StorageHandling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.Exposure LimitsOSHA Vacated PELs: Sodium sulfite, Anhydrous: No OSHA Vacated PELs are listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant arespirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.9) Physical and Chemical PropertiesPhysical State: SolidAppearance: whiteOdor: odorlesspH: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Evaporation Rate: Not available.Viscosity: Not available.Boiling Point: Not available.Freezing/Melting Point: Not available.Autoignition Temperature: Not available.Flash Point: Not available.Decomposition Temperature: > 500 deg CNFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0 Explosion Limits, Lower: Not available.Upper: Not available.Solubility: 23 g/100 mL water (20° C)Specific Gravity/Density: 2.6330g/cm3Molecular Formula: Na2O3SMolecular Weight: 126.0410) Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to air, excess heat.Incompatibilities with Other Materials: Strong oxidizing agents, acids, organics, moisture, air, combustible materials.Hazardous Decomposition Products: Oxides of sulfur.Hazardous Polymerization: Has not been reported.11) Toxicological InformationRTECS#:CAS# 7757-83-7: WE2150000LD50/LC50:CAS# 7757-83-7:Oral, mouse: LD50 = 820 mg/kg;Carcinogenicity:CAS# 7757-83-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: No information available.Teratogenicity: No information available.Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: No information available.Other Studies: No data available.12) Ecological InformationEcotoxicity: No data available. No information available. Environmental: No information found.Physical: No information found.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed.RCRA U-Series: None listed.14) Transport Information15) Regulatory InformationUS FEDERALTSCACAS# 7757-83-7 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List. Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule. Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA. SARASection 302 (RQ)None of the chemicals in this material have an RQ.Section 302 (TPQ)None of the chemicals in this product have a TPQ.SARA CodesCAS # 7757-83-7: acute.Section 313No chemicals are reportable under Section 313.Clean Air Act:This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA.STATECAS# 7757-83-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:XNRisk Phrases:R 22 Harmful if swallowed.R 36/37/38 Irritating to eyes, respiratory systemand skin.Safety Phrases:S 24/25 Avoid contact with skin and eyes.WGK (Water Danger/Protection)CAS# 7757-83-7: 1CanadaCAS# 7757-83-7 is listed on Canada's DSL List. CAS# 7757-83-7 is listed on Canada's DSL List.This product has a WHMIS classification of D2B.CAS# 7757-83-7 is not listed on Canada's Ingredient Disclosure List. Exposure Limits16) Additional InformationMSDS Creation Date: 7/15/1999Revision #1 Date: 8/02/The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplarydamages, howsoever arising, even if Fisher has been advised of the possibility of such damages.5.3.5亚硫酸氢钠1) 化学品名称化学品中文名称: 亚硫酸氢钠化学品英文名称: sodium bisulfite中文名称2: 酸式亚硫酸钠英文名称2: hydrogen sulfite sodium分子式: NaHSO3分子量: 104.062) 成分、组成信息3) 危险性概述健康危害: 对皮肤、眼、呼吸道有刺激性, 可引起过敏反应。

MSDS范本 中英文对照 (2007‐07‐19 12:05:43)MATERIAL SAFETY DATA SHEET1 PRODUCT AND COMPANY IDENTIFICATIONProduct name (Chinese): S‐3Product popular name: 783慢干水Product name (English): SolventCorporation name:Address:Postcode:Email address:Telefax:2 COMPOSITION /INFORMATION ON INGREDIENTSChemical name:Composition: concentration (%)Ketone solvent: 100%Heavy metal content: ＜5ppm (comply with standard EN.71)3 USE SUMMARIZEMainly used in:4 HAZARDS IDENTIFICATIONSpecies Hazards: Medium flash point, highly flammable liquidInvade way: Inhalation, skin contact, ingestionHealthy effect: Repeat, high concentration and abundantly contact may cause narcosis and harm to haematogenous system.Fire risk: Highly flammable, the vapours and air may form ofvolatile mixture which mayburn or blast when it exposes in sources of ignition or high temperature.5 FIRST‐AID MEASURESSkin contact: Remove immediately any soiled or soaked clothing. WashSkin with plenty of water and soap.Eye contact: Wash open eyes immediately, abundantly and consult adoctor if needed.Inhalation: Move patient from contaminated area to fresh air.Ingestion: Drink abundant warm water in order to try to vomit.Consult a doctor if needed.6 FIRE‐FIGHTING MEASURESSpecific hazards: The vapors and air may form of volatile mixture whichmay burn or blast when it exposes in sources of ignitionor high temperature. The vapors are heavier than air, sothey could widely spread. Static discharges may createand accumulate when the fluid of the product is too fast.Harmful burning waste: CO, NO2Extinguishing media:Suitable: Foam, CO2, dry power or soil.Not suitable: Water jet.Other information: Acid‐alkaline extinguisher is invalid, water spraycould be used in small fire.7 ACCIDENTAL RELEASE MEASURESRelease measures: Cut off electrical source and leave the contaminatedarea for safety place. People who treat with theaccident will wear respirator and gasproof clothes andnot go into cloacae, drain where it is too small space.Methods for cleaning‐up:Collect the residues in close containers.Cover with sand, active carbon or other inert materialsup the residues.Use latex made up of nonflammable Dispersant.Work notice: Ensure adequate aeration.Keep away from all sources of ignition and oxide. Do not smoke.People need to wear respirator, gasproof clothes, unpermeablegloves and eye protection glasses.The fluid of production will low than 5m/s.Install electrical wire touched floor and keep staticdischarges from accumulating.Avoid package broken.Storage notice: Store in shady, cool and ventilated warehouse where the temperature is lower than 35℃. Keep away from all sources of ignition and heat. Keep containers close and away from oxide and chemical edible. The instrument and machine which can make spark are forbidden. The accidental release measures instrument and containers shall be supplied with in warehouse.8 EXPOSURE CONTROLS / PERSONAL PROTECTIONThreshold limit value: ≤100ppmInspect method: gas chromatograph (GC)Engineering control: Be hermetic, ensure adequate aeration.Respiratory protection: Wear a respirator if the vapors concentration is too high.Eye protection: Eye/face protection glasses.Body protection: Wear work clothes.Hand protection: Impermeable gloves.Other information: Do not smoke, ingest and drink water in workshop. Do not drink wine before working and bath after working. Check body in schedule.9 PHYSICAL AND CHEMICAL PROPERTIESPhysical state: LiquidColor: YellowwishpH: 6.5‐7.5Flash point (℃): 5810. STABILITY AND REACTIVITYStability: Stable at normal temperature of storage, handling and use.Conditions to avoid: Flame, high temperature.Hazardous reactions: Unactable11. TOXICOLOGICAL INFORMATIONAcute toxicity: N/AIrritancy: N/ABiodegradation: N/Adisbiodegradation: N/A12. HANDLING AND STORAGEHandling: Ensure adequate aeration.Be far away from oxide.Storage: Store in shady and cool area.Keep containers hermetically sealed.Keep away from all source of ignition.13. DISPOSAL CONSIDERATIONWaste information: Hazards wasteWaste disposal: Ignition under control.Disposal notice: Disposal area must comply with the environment and national safety standard.Transportation information: Do transportation in the morning and night in summer.14. REGULATION INFORMATIONRegulation information: Directive “Chemical hazards regulation” (Directive 2/17/1987), aim at safe production, use, storage, transportation etc.Directive GB13690‐92. The product is classified as middle flash liquid (grade 3.2). 15. OTHER INFORMATIONReference:Date: 01/2007Dept.:Check Dept.:Version notice: Some values are selected average value/limit value because of many breed of products.16. NATIONAL EMERGENCY TELEPHONE NUMBERFire‐alarm: 119 First‐aid: 120物质安全资料表第一部分 化学品及企业标识化学品中文名称： S‐3化学品俗名或商品名： 783 慢干水化学品英文名称：企业名称：地址：邮编：电子邮件地址：第二部分 成分/组成信息化学品名称：成分 含量（%）酮类溶剂 100%重金属含量：<5ppm (符合EN.71标准)第三部分 用途概述主要用途：油墨稀释剂第四部分 危险性概述危险性类别： 中闪点易燃液体侵入途径：吸入、食入、经皮吸收健康危害：长期、大量、高浓度对中枢神经系统具麻醉作用，对造血系统有损害。