Platinum Carbon,铂碳 MSDS
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铂族(PGM )金属简介铂族金属简介(PGM Introduce)2008-03-17 22:081、矿产性质:1)物理性质。
铂族金属包括铂(pt),钯(Pd),铑(Rh),铱(10,锇(Os)、钌(Ru)六个元素位于元素周期表中第VIII副族。
它们具有类似的性质,如高熔点、高强度、耐腐蚀、良好的催化活性和电热性。
铂、钯、铑、铱为银白色,锇、钌(周期表中上下排列)为钢灰色。
钌、铑在有氧存在和强热下,容易与氧化合为四氧化物,具有挥发性,钌的挥发速度较慢,锇则较快。
铂(大于1000℃时)、铱和铑(大于2000℃时)能形成挥发性氧化物。
铂族金属密度大。
轻铂金属密度大于12 g/cm},重铂金属密度大于21 g/cm3。
铂族金属的沸点都很高。
按元素周期表顺序,从左向右逐渐降低.从上向下逐渐提高。
其中钯的沸点最低,锇的沸点最高。
锇、钌和铑的特点是硬度高并且脆,故能研磨成细粉末,它们都很难机械加工。
铂和钯具有延展性,可以辗制和拉丝。
纯净的铂具有高度的可塑性,将铂冷轧可以制得厚度为0.0025 mm的箔。
铱仅当升温至红热时才能承受机械加工。
铂族金属的特殊性质是其表面具有吸附气体(特别是氢气)的性能,呈粉末和胶体状态时其吸附能力大为增强。
钯对氢的吸附能力最强.常温下1个体积的钯能吸附901个体积以上的氢。
钯中吸附的氢易全部放出。
按照钯、铱、铑、铂、钌、锇的次序,它们吸附氢的性能依次降低。
2)化学性质。
铂族金属电离电位很高,在常温下对许多化学试剂(如酸、碱和最活泼的非金属)有很高的抗腐蚀能力。
但在一定条件下,它们可与酸、碱、氧和卤素反应。
铂族金属在热处理过程中被钝化,这是由于在金属表面形成一层稳定的氧化薄膜。
以金属细粉(铂黑)形式存在的铂族金属最容易溶解。
海绵状和粉末状的铂族金属不易溶解,致密状态的金属更难溶。
铂族金属有一种特殊的性质:当它们与比较活泼的金属熔融成合金时,就有可能用无机酸溶解。
容易与铂族金属形成合金的金属有铅、锡、铋和锌。
Material Safety Data Sheet Dichloro(1,5-cyclooctadiene)platinum(II)Company Identification:RUIYUAN GROUP LIMITEDYURUI(SHANGHAI)CHEMICAL CO.,LTDAddress:No.2277Zuchongzhi Road,Pudong,Shanghai,ChinaZipcode:201203Tel:+862150456736Fax:+862160853441Email:info@【Product Name】Dichloro(1,5-cyclooctadiene)platinum(II)【Synonyms】(1,5-Cyclooctadiene)platinum(II)dichloride;Platinum(COD)dichloride【CAS】12080-32-9【Formula】C8H12Cl2Pt【Molecular Weight】374.16【EINECS】235-144-5【Appearance】pale yellow powder.【Solubility in water】Insoluble.【Melting Point】285deg C(dec.)【Boiling point】Not available.【Density】Not available.【Vapor Density】Not available.【Ingestion】Never give anything by mouth to an unconscious person.Get medical aid.Do NOT induce vomiting.If conscious and alert,rinse mouth and drink2-4cupfuls of milk or water.Wash mouth out with water.【Inhalation】Remove from exposure and move to fresh air immediately.If not breathing,give artificial respiration.If breathing is difficult,give oxygen.Get medical aid.Do NOT use mouth-to-mouth resuscitation.【Skin】Get medical aid.Flush skin with plenty of water for at least15minutes while removing contaminated clothing and shoes.Wash clothing before reuse.【Eyes】Immediately flush eyes with plenty of water for at least15minutes,occasionally lifting the upper and lower eyelids.Get medical aid immediately.【Storage】Store in a tightly closed container.Store in a cool,dry,well-ventilated area away from incompatible substances.Store protected from moisture.【Handling】Minimize dust generation and accumulation.Avoid breathing dust,mist,or vapor. Avoid contact with eyes,skin,and clothing.Keep container tightly closed.Avoidingestion and e with adequate ventilation.Wash clothing before reuse.【Inhalation】Harmful if inhaled.Causes respiratory tract irritation.【Skin】Causes skin irritation.【Eyes】Causes eye irritation.【Ingestion】May cause gastrointestinal irritation with nausea,vomiting and diarrhea.【Personal Protection】Eyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in29CFR1910.133or European Standard EN166.Skin:Wear appropriate protective gloves to prevent skin exposure.Clothing:Wear appropriate protective clothing to prevent skin exposure.【Respirators】A respiratory protection program that meets OSHA's29CFR1910.134and ANSI Z88.2requirements or European Standard EN149must be followed whenever workplace conditions warrant a respirator's use.【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand,MSHA/NIOSH (approved or equivalent),and full protective gear.During a fire,irritating and highly toxic gases may be generated by thermal decomposition or combustion.Thismaterial in sufficient quantity and reduced particle size is capable of creating a dust explosion.Extinguishing media:Use water spray,dry chemical,carbon dioxide,or chemical foam.【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container.Clean up spills immediately,observing precautions in the Protective Equipment section. Avoid generating dusty conditions.Provide ventilation.【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.Hygroscopic:absorbs moisture or water from the air.【Incompatibilities】Oxidizing agents,active metals,mineral acids.【Decomposition】Hazardous products of decomposition may include:Hydrogen chloride,carbon monoxide,carbon dioxide.【UN Number】Not available.【Hazard Class】Not available.【Packing Group】Not available.Wear suitable protective clothing.MSDS Creation Date:9/02/2009Revision#8Date:8/16/2010The information above is believed to be accurate and represents the best information currently available to us. However,we make no warranty of merchantability or any other warranty,express or implied,with respect to such information,and we assume no liability resulting from its ers should make their own investigations to determine the suitability of the information for their particular purposes.In no event shall Fisher be liable for any claims,losses,or damages of any third party or for lost profits or any special,indirect,incidental, consequential or exemplary damages,howsoever arising,even if Fisher has been advised of the possibility of such damages.Copyright2010YURUI(SHANGHAI)CHEMICAL CO.,LTD License granted to make unlimited paper copies for internal use only.。
世上无难事,只要肯攀登钯、铂的性质与用途钯、铂的性质与用途钯位于元素周期表第五周期第Ⅷ族,原子序数46,原子量106.42,密度12.02g/cm3(20℃),熔点1550℃,沸点2900℃。
铂也位于元素周期表第Ⅷ族,原子序数78,原子量195.09,密度21.45g/cm3(20℃),熔点1768℃,沸点3827 ℃。
钯、铂都是银白色具有延展性的金属,对氢具有巨大的亲合力。
海绵状或粉末状的钯能吸收其体积900 倍的氢气。
钯是铂族元素中最活泼的一个,可溶于浓硝酸和热硫酸,但不溶于盐酸。
铂的化学稳定性很好,不溶于任何一种单一酸,可溶于水。
钯、铂在工业上的主要用途是作为催化剂使用,而且都与加氢或脱氢过程有关,例如钯炭催化剂、铂炭催化剂是化工、医药和医药中间体、香料、农药、化妆品及高分子改性材料等领域加氢反应的催化剂,具有选择性好、活性高、寿命长等特点。
钯、铂的化合物都很多。
钯的常见化合物有二氯化钯(PdCl2-2H2O)、硝酸钯[Pd(NO3)2-2H2O]等,有的直接作为催化剂使用,如二氯化钯与二氯化铜的混合溶液就是液相合成甲基乙基酮等产品的催化剂,有的是作为进一步生产含钯催化剂(如钯炭催化剂)的原料,如二氯化钯和硝酸钯等;铂的常见化合物有顺铂[PtCl2(NH3)2]、二氧化铂[PtO2]等。
顺铂是一种抗癌新药。
含钯或铂的化合物在电子元器件的生产中起着重要作用,通过电镀或调成浆料的方法,将含钯(铂)配合物涂布到有关器件的表面,使有关器件具有特定的电性能。
近年来由于铂价格急速增长,抑制了铂金首饰的消费,由于钯的价格相对较。
铂碳催化剂是危险品吗近年来,铂碳催化剂作为一种重要的催化剂在工业生产中得到广泛应用。
然而,对于一些人来说,铂碳催化剂是否属于危险品一直是一个疑问。
在本文中,我们将对铂碳催化剂的性质、用途以及相关的安全性问题进行探讨。
首先,铂碳催化剂是由铂和碳组成的复合物,具有良好的催化性能。
它在各种化学反应中发挥着重要的作用,比如气体净化、有机合成等。
铂碳催化剂的高效催化活性和良好的稳定性使其成为许多工业生产过程中的首选催化剂。
然而,铂碳催化剂具有一定的危险性。
首先,铂属于贵金属,价格昂贵,因此铂碳催化剂的生产和使用成本相对较高。
另外,铂碳催化剂还具有较高的毒性,尤其是对于人体呼吸道和皮肤有一定的刺激作用。
因此,在生产和使用铂碳催化剂时需要采取适当的防护措施,以保障工作人员的安全。
对于生产企业来说,要妥善处理铂碳催化剂的废弃物和废水,以免对环境产生污染。
同时,对于使用铂碳催化剂的工作场所,要加强通风设施的建设,降低催化剂的浓度,减少对工作人员的危害。
此外,铂碳催化剂的使用也需要注意一些安全事项。
首先,在催化剂的储存和搬运过程中要小心轻放,避免碰撞和挤压,以免产生火花或溅射。
其次,在使用铂碳催化剂进行化学反应时,需要掌握正确的操作方法,严格遵守相关的安全规定,避免发生意外事故。
在催化剂使用完毕后,要进行及时清理和处理,确保催化剂的安全回收和废弃物的正确处理。
总的来说,铂碳催化剂是一种重要的催化剂,具有良好的催化性能。
然而,由于其高昂的价格和一定的危险性,我们在生产和使用过程中需要高度重视安全问题,采取相应的防护措施,保障工作人员的安全,减少对环境的影响。
只有这样,铂碳催化剂的应用才能发挥出最大的效益。
参考文献:[1] 张敏, 孙世彪, 毛冠华. 铂碳催化剂的聚乙二醇包覆及其催化性能[J]. 精细石油化工进展, 2014, 16(1):23-28.[2] 黎锡襄, 赵启明, 胡杜聪,等. 铂碳催化剂的制备及其在丙烷氧化反应中的催化性能[J]. 石油学报, 2014, 35(1):76-84.[3] 陆杰, 张宏宇, 朱晓东,等. SBA-15/铂碳催化剂的制备及其催化性能[J]. 精细化工, 2014, 31(12):1425-1430.。
铂在碳减排中的应用-概述说明以及解释1.引言1.1 概述概述:碳减排是全球应对气候变化和环境污染的重要举措之一。
在碳减排技术中,铂作为重要的催化剂,发挥着重要的作用。
本文将重点介绍铂在碳减排中的应用,并探讨其在汽车尾气处理、工业废气处理以及能源转换等领域中的重要性、优势、挑战和未来发展。
铂具有许多独特的特性,如高催化活性、良好的耐杂质性以及稳定性等。
这些特性使得铂成为一种理想的催化剂,能够有效地促进碳减排反应的进行。
在汽车尾气处理中,铂催化剂可将有害废气中的氮氧化物、碳氢化合物和一氧化碳等有害物转化为对环境无害的物质。
在工业废气处理中,铂的催化作用可将含硫化合物和有机污染物转化为无毒、无害的物质,降低环境污染。
在能源转换方面,铂可以促进燃料电池中的氢氧化反应,实现高效能源转换。
尽管铂在碳减排中具有重要的作用,但其应用也面临一些挑战。
首先,铂是一种稀有贵金属,其价格较高,限制了其在大规模应用中的可行性。
其次,铂催化剂还存在失活和腐蚀等问题,需要进一步改进催化剂的稳定性和耐用性。
此外,铂催化剂的生产过程也需要优化,以降低对环境的影响。
然而,随着科技的不断发展和碳减排意识的增强,铂在碳减排中的应用仍有巨大的潜力。
未来,可以通过开发新型的铂基催化剂、改善催化剂的稳定性和活性,以及降低铂的成本等方式来解决上述挑战。
同时,还可以通过加强国际间的合作与交流,进一步推动铂在碳减排领域的研究与应用。
综上所述,铂作为一种重要的催化剂,在碳减排中发挥着重要的作用。
了解铂的特性、应用和面临的挑战,对于进一步推动碳减排技术的发展具有重要意义。
在未来,我们有信心通过不断的研究和创新,克服挑战,实现铂在碳减排中的更广泛应用,为构建清洁、可持续的环境做出贡献。
1.2 文章结构文章结构是整篇文章的骨架,它有助于读者更好地理解和组织信息。
本文分为引言、正文和结论三个部分,每个部分都有具体的内容目标。
引言部分主要是对文章主题进行概述,同时介绍文章的结构和目的,让读者对整篇文章有一个整体的认识。
铂碳催化剂semPlatinum Carbon Catalyst in SEMPlatinum carbon catalyst is a kind of catalyst composed of platinum and carbon.It has been widely used in various fields, including semiconductors, energy, and environmental protection.In this article, we will focus on the application of platinum carbon catalyst in the field of SEM (Scanning Electron Microscopy) and its research progress.1.Introduction to Platinum Carbon CatalystPlatinum carbon catalyst is a composite material composed of platinum and carbon.The platinum particles are dispersed on the carbon support, which enhances the catalytic activity and stability of the catalyst.Platinum carbon catalyst has excellent electrochemical properties, high thermal stability, and good chemical inertness, making it suitable for various applications.2.Applications of Platinum Carbon Catalyst in SEMIn the field of SEM, platinum carbon catalyst is mainly used as a substrate for electron beam lithography.The high-quality surface and excellent mechanical properties of the platinum carbon catalyst make it a preferred material for SEM applications.Moreover, platinum carbon catalyst is also used as a conductive coating for samples, which enables the visualization of non-conductive materials under an electronmicroscope.3.Research Progress of Platinum Carbon Catalyst in SEMThe research on platinum carbon catalyst in SEM has been continuously advancing.Researchers have developed various methods to improve the performance of the catalyst, such as optimizing the preparation process, adjusting the composition of the catalyst, and modifying the surface structure.Additionally, the application of platinum carbon catalyst in SEM has also been extended to other fields, such as energy storage devices and environmental remediation.4.Position of China in the Field of Platinum Carbon Catalyst SEMChina has made significant achievements in the research and development of platinum carbon catalysts for SEM applications.Many domestic universities and research institutions have established cooperation with international counterparts, and some have even achieved leading positions in the field.The government also supports the development of the SEM industry and related fields through various policies, promoting the application of platinum carbon catalysts in China.5.Future Development Prospects of Platinum Carbon CatalystThe future development prospects of platinum carbon catalysts in SEM are promising.With the continuous advancement of technology and the increasing demand for high-performance catalysts, platinumcarbon catalysts will continue to play a vital role in SEM and other fields.Furthermore, the development of new applications and the improvement of catalytic performance will further promote the innovation of platinum carbon catalysts in the coming years.In conclusion, platinum carbon catalysts have demonstrated their potential in the field of SEM applications.With continuous research and development, platinum carbon catalysts will undoubtedly contribute to the advancement of SEM technology and broader fields, bringing about significant benefits to society and the economy.。
英文根据上海卡博特的需要更正Date of Issue: 22 November, 1996Shanghai Cabot Chemical Co., Ltd.MATERIAL SAFETY DATA SHEETSTATEMENT OF HAZARDOUS NATURECurrently under review.COMPANY DETAILS:Company: Shanghai Cabot Chemical Co., Ltd.Address: 15 Shuang Bai Road, Shanghai, China201108Telephone: (86)21-64345809Facsimile: (86)21-64345532IDENTIFICATIONProduct Name: Carbon black.Other Names: ACARB?, STERLING?, TINTACARB?, BLACK PEARLS? VULCAN?, REGAL?, ELFTEX?, MOGUL?, MONARCH?, IRX?, CRX? and CSX? carbon blacks. The foregoing are registered trade names of Cabot Corporation, and denote physical differences in carbon black grades.Manufacturer抯 Product Code: Not applicable.UN Number: None allocated.Dangerous Goods Class and Subsidiary Risk: No listed in<Dangerous Goods list GB 12268-90>Hazchem Code: No listed in<Dangerous Goods list GB 12268-90>Poisons Schedule Number: No listed in<Dangerous Goods list GB 12268-90>Use: Used as a filler, reinforcing agent, pigment, electrical conducting or chemical reducing agent, in rubbers, plastics, inks, copy machine toners, paints and batteries.PHYSICAL DESCRIPTION / PROPERTIES:Appearance: Odourless, amorphous black inert solids, pellets or powder.Boiling Point / Melting Point: Not applicable.Vapour Pressure: Not applicable.Specific Gravity: 1.7 to 1.9Flashpoint: Not applicable (powder substance)Flammability Limits: Not applicable (combustible solid).Solubility in Water: Insoluble.Recommended Occupational Exposure Limit: 8.0 mg / m3 (Black powder sanitationstandard in the air of workshopGB-10330-89)Reference to China National StandardOTHER PROPERTIES:Ingredients:Chemical Name: Carbon / CCAS Number: 1333-86-4Proportion: 100%HEALTH HAZARD INFORMATIONHEALTH EFFECTS:Acute: None known other than possible temporary discomfort due to inhalation of high dust concentrations and possible mechanical eye irritation.Chronic:NOTE: In April 1996, IARC (International Agency for Research on Cancer) issued a Monograph that changed its evaluation of carbon black from a Class 3 substance - that is, a substance with inadequate information to determine if it is carcinogenic to a Class 2b substance - that is, a substance that is a possible human carcinogen. It is now classified in Class 2b with other well known items such as coffee, saccharin and petrol.IARC Classifications:Class 1 substances are known human carcinogens,Class 2a substances are probable human carcinogens,Class 2b substances are possible human carcinogens,Class 3 substances have insufficient data to determine whether they might be human carcinogens,Class 4 substances are probably not human carcinogens.Swallowed: None expected.Eye: Mechanical irritant with no adverse effects.Skin: None expected but may dry skin with prolonged exposures. Use of quality barrier cream can prevent skin dryness.Inhaled: None expected. Temporary discomfort to the upper respiratory tract may occur due to inhalation of dust concentrations above the OEL.Human Studies: Epidemiological studies of workers in the carbon black producing industries of North America and Western Europe show no evidence of clinically significant, adverse health effects due to occupational exposure to carbon black.Early studies in the former USSR and Eastern Europe report respiratory diseases among workers exposed to carbon black, including bronchitis, pneumoconiosis, emphysema and rhinitis. Such studies areof questionable validity, due to inadequate study design and methodology, lack of appropriate controls for cigarette smoking and other confounding factors, such as concurrent exposures to carbon monoxide, coal oil and petroleum vapours. Moreover, review of these studies indicates that concentrations of carbon black were greater than current occupational exposure standards. In its Monograph Volume 65, issued in April 1996, the International Agency for Research on Cancer (IARC) re-evaluated carbon black and concluded that 搕here is inadequate evidence in humans for the carcinogenicity of carbon black”.。
铂炭催化剂
1 铂炭催化剂
铂炭催化剂是一种广泛应用的催化剂,广泛用于工业精细化学合成、燃料电池等领域。
它的特殊的结构、独特的功能表现和可调节的
特性更易于调整。
同时由于其低活性和稳定性,使其在高温和恶劣工
作条件下,提供更优越的效果。
2 特点
铂炭催化剂有多种类型,其中最受欢迎的是三氧化二铂炭催化剂。
这种催化剂具有强大的催化作用,可以有效地提高反应速率和转化率,从而提高反应效率。
此外,铂炭催化剂具有良好的抗变形性能和烧结
性能,是制造各种反应容器最理想的材料,而且不易损坏。
3 应用
铂炭催化剂在很多领域中得到了应用,特别是在精细化学合成、
燃料电池领域应用广泛。
它能帮助改善生物质聚合结构和综合性能,
在材料的制备和反应方式中起着重要作用。
此外,它还可以用于天然
气加氢脱硫,制备多种金属及其合金。
4 总结
铂炭催化剂是一种应用广泛、功能强大的催化剂,在精细化学合成、燃料电池等领域中非常重要。
他具有良好的催化性能,烧结性能,
及稳定性好等特点。
它的使用可以提高反应速率和转化率,节省成本,改善生物质结构和综合性能,并且节约能源。
Material Safety Data SheetPlatinum Carbon MSDSProduct Name:Platinum Carbon(Pt/C)Company Identification:RUIYUAN GROUP LIMITEDYURUI(SHANGHAI)CHEMICAL CO.,LTDAddress:No.2277Zuchongzhi Road,Pudong,Shanghai,ChinaZipcode:201203Tel:+862150456736Fax:+862160853441Email:info@【Product Name】Platinum Carbon(Pt/C)【Synonyms】Platinum on carbon;Platinum on graphitized carbon 【CAS】7440-06-4【Formula】Pt/C【Molecular Weight】195.08【EINECS】231-116-1【Appearance】Black powder/particle【Solubility in water】Insoluble【Melting Point】1772deg C(lit.)【Density】1.060g/ml at20°C【Vapor Density】N/P【Ingestion】Never give anything by mouth to an unconscious person.Get medical aid.Do NOT induce vomiting.If conscious and alert,rinse mouth and drink2-4cupfuls of milk or water.【Inhalation】Get medical aid immediately.Remove from exposure and move to fresh air immediately.If breathing is difficult,give oxygen.Do NOT use mouth-to-mouth resuscitation.If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.【Skin】Get medical aid.Immediately flush skin with plenty of water for at least15 minutes while removing contaminated clothing and shoes.Wash clothing before reuse.Destroy contaminated shoes【Eyes】Get medical aid immediately.Do not allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required(at least30minutes).Speed action is critical!【Storage】Do not store in direct sunlight.Store in a tightly closed container.Store in a cool, dry,well-ventilated area away from incompatible substances.Corrosives area.Do not store in metal containers.Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).【Handling】Wash thoroughly after handling,Remove contaminated clothing and wash before e with adequate ventilation,Use only in a well-ventilated area.Contents may develop pressure upon prolonged storage.Avoid breathing dust,mist,or vapor. Avoid contact with clothing and other combustible materials.Do not get on skin or in eyes.Avoid ingestion and inhalation.Discard contaminated shoes.【Inhalation】May cause severe irritation of the respiratory tract with sore throat, coughing,shortness of breath and delayed lung edema.Causes chemical burns to the respiratory tract.Aspiration may lead to pulmonary edema.May cause systemic effects.Exposure to the mist and vapor may erode exposed teeth.Causes corrosive action on the mucous membranes.【Skin】Causes skin burns.May be absorbed through the skin in harmful amounts. May cause skin sensitization,an allergic reaction,which becomes evident upon re-exposure to this material.May cause skin rash(in milder cases),and cold and clammy skin with cyanosis or pale color.【Eyes】Causes eye burns.May cause irreversible eye injury.May cause painful sensitization to light.May cause chemical conjunctivitis and corneal damage.【Ingestion】May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.May cause circulatory system failure.May cause perforation of the digestive tract.May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.May cause systemic effects.【Personal Protection】Eyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in29CFR1910.133or European Standard EN166.Skin:Wear neoprene or polyvinyl chloride gloves to prevent exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure.【Respirators】A respiratory protection program that meets OSHA's29CFR1910.134and ANSI Z88.2requirements or European Standard EN149must be followed whenever workplace conditions warrant respirator use.【Fire Fighting】As in any fire,wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH(approved or equivalent),and full protective gear.Water runoff can cause environmental damage.Dike and collect water used to fight fire.During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.Not flammable,but reacts with most metals to form flammable hydrogen e water spray to keep fire-exposed containers cool.Vapors may be heavier than air.They can spread along the ground and collect in low or confined areas.Reaction with water may generate much heat which will increase the concentration of fumes in the air.Containers may explode when heated. Extinguishing Media:For large fires,use water spray,fog,or alcohol-resistant foam.Substance is nonflammable;use agent most appropriate to extinguish surrounding fire.Do not get water inside containers.Do NOT use straight streams of water.Most foams will react with the material and release corrosive/toxic gases.Cool containers with flooding quantities of water until well after fire is out.For small fires,use carbon dioxide(except for cyanides),dry chemical,dry sand,and alcohol-resistant foam.【Small spills/leaks】Large spills may be neutralized with dilute alkaline solutions of soda ash(sodium carbonate,Na2CO3),or lime(calcium oxide,CaO).Avoid runoff into storm sewers and ditches which lead to waterways.Clean up spills immediately,observing precautions in the Protective Equipment section.Remove all sources of ignition. Provide ventilation.Do not get water inside containers.A vapor suppressing foam may be used to reduce vapors.Cover with dry earth,dry sand,or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.【Stability】Stable under normal temperatures and pressures.【Incompatibilities】Acetates,acetic anhydride,alcohols+hydrogen cyanide,2-aminoethanol, ammonium hydroxide,calcium carbide,calcium phosphide,cesium acetylene carbide,cesium carbide,chlorosulfonic acid,1,1-difluoroethylene,ethylene diamine, ethyleneimine,fluorine,lithium silicides,magnesium boride,mercuric sulfate, oleum,perchloric acid,potassium permanganate,beta-propiolactone,propylene oxide,rubidium acetylene carbide,rubidium carbide,sodium,sodium hydroxide, sulfuric acid,uranium phosphide,vinyl acetate,zinc,metal oxides,aluminum, amines,carbonates,iron,steel,copper alloys,copper,alkali metals,bases.【Decomposition】No data available.【UN Number】1789【Hazard Class】8【Packing Group】IIMSDS Creation Date:9/02/2009Revision#8Date:8/16/2010The information above is believed to be accurate and represents the best information currently available to us. However,we make no warranty of merchantability or any other warranty,express or implied,with respect to such information,and we assume no liability resulting from its ers should make their own investigations to determine the suitability of the information for their particular purposes.In no event shall Fisher be liable for any claims,losses,or damages of any third party or for lost profits or any special,indirect,incidental, consequential or exemplary damages,howsoever arising,even if Fisher has been advised of the possibility of such damages.Copyright2010YURUI(SHANGHAI)CHEMICAL CO.,LTD License granted to make unlimited paper copies for internal use only.。