2 Periodic Table

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The Microscopic World (2) - The Periodic TableThere are over one hundred different elements. Chemists have long beenlooking for ways to classify them. It is useful to group elements withsimilar properties together.(I) The Periodic Table(i) In 1869, a Russian chemist called Mendeleev arranged the elements in the formof a Periodic Table. The elements are arranged in order of their atomic mass andin such a way that elements in the same vertical column (group) show similarchemical properties.(ii) As our chemical knowledge increases, Mendeleev's Periodic Table had been revised and modified. In the modern form of the Periodic Table, elements arearranged in order of their atomic number.G r o u pI II III IV V VI VII 0period 1 H I HeF Neperiod 2 Li Be B C N OCl Arperiod 3 Na Mg Al Si P Speriod 4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr period 5 Rb I Xe (iii) The horizontal row in the Periodic Table is called period.Elements in the same period have the same number of electron shells. E.g.sodium (Na: 2.8.1) and silicon (Si: 2.8.4) are elements in the 3rd period and bothof them have 3 electron shells.Period number = Number of electron shells(iv) A vertical column of elements is called a group. There are 8 main groups. The group number of an element is equal to the number of outermost shell electronsof its atom. Chlorine (2.8.7) has 7 outermost electrons and is therefore placed inGroup VII.Group number = Number of outermost shell electrons(v) There are special names for some groups:Group I : alkali metalsGroup II : alkaline earth metalsGroup VII : halogensGroup 0 : noble gases(vi) Elements in between the main groups of Group II and III, are collectively called transition elements.(transition metals)(vii) To group elements into metals and non-metals, the Periodic Table is split by a step-like boundary line. Metals are found on the left-hand side of the boundaryline and non-metals are found on the right-hand side.Some elements near the boundary line, e.g. silicon (Si) and germanium(Ge) haveproperties similar to both metals and non-metals. They are called metalloid orsemi-metal and are used to make semi-conductors.(viii) Elements within the same group have similar chemical properties because they have the same number of electrons in the outermost shell. When atomsor molecules react, it is these outermost electrons that will be involved in theformation of chemical bonds.(a) Sodium and potassium have similar chemical properties because they bothhave one outermost shell electron.Na: 2,8,1K : 2,8,8,1(b) Magnesium and calcium have similar chemical properties because they bothhave two outermost shell electrons.Mg: 2,8,2Ca: 2,8,8,2(c) Fluorine, chlorine, bromine and iodine have similar chemical propertiesbecause they all have seven outermost shell electrons.F: 2,7Cl: 2,8,7Br: 2,8,18,7I: 2,8,18,18,7(II) Similarities and Trends in Chemical PropertiesElements in the same group of the Periodic Table have similar properties. There is alsoa gradual change in properties down a group. The tendency that certain propertieschange within a group is called group trend.(i) Group I : the alkali metalsGroup I consists of elements lithium (Li), sodium (Na), potassium (K), rubidium(Rb), caesium (Cs) and francium (Fr).(a) Similarities in chemical properties:1. Alkali metals react vigourously with water.2K(s) + 2H2O(l) → 2KOH(aq) + H2(g)2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)2. Alkali metals react quickly with oxygen in air.4K(s) + O2(g) → 2K2O(s)4Na(s) + O2(g) → 2Na2O(s)Note: 1. When freshly cut, alkali metals look shiny silvery.However, the shiny surface soon becomes dull becausethe alkali metal reacts with oxygen in air to form an oxidelayer.2. Alkali metals such as sodium and potassium are storedunder paraffin oil t o prevent them from reacting with airand moisture.(b) Trend in chemical properties of alkali metals:The reactivity of the alkali metals increases down the group. Therefore,among the first four alkali metals, rubidium (Rb) is the most reactive metal.Element Reaction with water EquationLithium Floats, producing H2 gas steadily. 2Li(s) + 2H2O(l) →2LiOH(aq) + H2(g)Sodium Melts to a silvery ball which movesabout quickly on the water surface,producing H2 rapidly. 2Na(s) + 2H2O(l) → 2NaOH(aq) +H2(g)Potassium Melts to a silvery ball which movesabout quickly on the water surface, producing H2 so rapidly that it catches fire. The potassium burns with a lilac flame. 2K(s) + 2H2O(l) → 2KOH(aq) +H2(g)Rubidium React even more vigourously thanpotassium does. 2Rb(s) + 2H2O(l) → 2RbOH(aq) +H2(g)(c) Similarities in physical properties:1. They have low density and will float on water.2. They are soft metals and can be cut with a knife.(ii) Group II: the alkaline earth metalsThe first 4 members of Group II elements are beryllium (Be), magnesium (Mg), calcium (Ca) and strontium (Sr).(a) Similarities in chemical properties:1. Mg and calcium reacts with water.Mg(s) + 2H2O(l) → Mg(OH)2(s) + H2(g)(slow reaction with hotwater)Ca(s) + H2O(l) → Ca(OH)2(aq) + H2(g)2. Mg and calcium reacts with dilute acids.Mg(s) + 2HCl(aq) → MgCl2(aq) +H2(g)Ca(s) + 2HCl(aq) → CaCl2(aq) +H2(g)(b) Trend in chemical properties of alkaline earth metals:The reactivity of the alkaline earth metals increases down the group,i.e.they become more reactive down the group. For example, there is almost noreaction between magnesium and cold water but calcium reacts quicklywith cold water.(iii) Group VII : the halogensGroup VII consists of the elements fluorine (F), chlorine (Cl), bromine (Br), iodine (I) and astatine (At) which are collectively known as the halogens.(a) Similarities in chemical properties:1. Halogens have similar reaction towards sodium sulphite. Aqueoussolution of halogens are decolourized by sodium sulphite solution(Na2SO3).2. H alogens react with metals to form salt (fluorides, chlorides, bromideand iodides).(b) Trend in chemical properties of alkali metals:The halogens become less reactive down the group. Therefore, fluorine isthe most reactive halogen.(c) Similarities in physical properties:1. There is a gradual increase in melting and moiling point as we godown the group. Therefore, fluorine and chlorine are gases, bromineis a liquid and iodine is a solid.2. There is a gradual change in colour as we go down the group.Fluorine is pale yellow, chlorine is greenish yellow, bromine is redand iodine is black.3. They are soluble in water and their solubility decreases down thegroup.(iv) Group 0: the noble gasesGroup 0 elements consists of helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe) and radon (Rn). They have similar properties:(a) Similarities in chemical properties:They are very stable and show little or no reaction with other elements.(b) Similarities in physical properties:They are colourless gas at room temperature.。