Hazard communication

Material Safety and Data Sheet prepared by Wim De BoerCML-Oil Base Plus Colors Material Safety Data SheetDate 5/6/20031. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONHM IS5. FIRE FIGHTING MEASURESFlash Point ..............................................................Above 250°F Method used: closed cup Explosion Limits .....................................................LEL:N/A UEL: N/AExtinguishing Media ..............................................Foam, carbon dioxide, dry chemical. Water spray may beapplied to cool exposed closed containers.Unusual Fire and Explosion Hazards ....................Dense smoke may be generated when burning. CarbonMonoxide and Carbon Dioxide generated as combustion products.Special Fire Fighting Procedures .............................Self-contained breathing apparatus recommended.6. ACCIDENTAL RELEASE MEASURESCML-Oil Base Plus Colors MSDSThis information is furnished without warranty, expressed or implied, except that it is accurate to the best of the knowl-edge of Van Son Holland Ink Corporation of America. The data on this sheet relates only to the specific material designat-ed herein and does not relate to use in combination with any other material or in any process. The hazards covered are believed to be those most likely to occur in the reasonable or ordinary use of these materials. Van Son Holland Ink Corporation of America assumes no legal responsibility for use or reliance on this data.Prepared by Wim De Boer Date 5/6/2003。

SAFETY DATA SHEET1. IdentificationFull Synthetic Manual Transmission FluidProduct identifierOther means of identification175246FIR No.Transmission fluidRecommended useNone known.Recommended restrictionsManufacturer/Importer/Supplier/Distributor informationCompany Name Ford Motor CompanyAddress Attention: MSDS Information, P.O. Box 1899Dearborn, Michigan 48121USATelephone1-800-392-3673SDS Information1-800-448-2063 (USA and Canada)Emergency telephonenumbersPoison Control Center: USA and Canada: 1-800-959-3673INFOTRAC (Transportation): USA and Canada 1-800-535-50532. Hazard(s) identificationNot classified.Physical hazardsNot classified.Health hazardsNot classified.Environmental hazardsNot classified.OSHA defined hazardsLabel elementsNone.Hazard symbolSignal word None.Hazard statement The mixture does not meet the criteria for classification.Precautionary statementPrevention Observe good industrial hygiene practices.Response Wash hands after handling.Storage Store away from incompatible materials.Disposal Dispose of waste and residues in accordance with local authority requirements.Hazard(s) not otherwise classified (HNOC)Direct contact with eyes may cause temporary irritation. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Inhalation of vapors/fumes generated by heating this product may cause respiratory irritation with throat discomfort, coughing or difficulty breathing.Supplemental information None.3. Composition/information on ingredientsMixturesCAS numberCommon name and synonymsChemical name%68649-42-3 Phosphorodithioic acid,O,O-di-C1-14-alkyl esters, zincsalts2 - 5Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measuresMove to fresh air. Call a physician if symptoms develop or persist.InhalationWash off with soap and water. Get medical attention if irritation develops and persists.Skin contact Rinse with water. Get medical attention if irritation develops and persists.Eye contact Rinse mouth. Get medical attention if symptoms occur.IngestionDirect contact with eyes may cause temporary irritation.Most importantsymptoms/effects, acute and delayedTreat symptomatically.Indication of immediatemedical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.General information5. Fire-fighting measuresFoam. Powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing mediaDuring fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.Specific hazards arising from the chemicalSelf-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk.Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods No unusual fire or explosion hazards noted.General fire hazards6. Accidental release measuresAvoid inhalation of vapors or mists. Avoid contact with eyes, skin, and clothing. Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.Personal precautions,protective equipment and emergency procedures The product is immiscible with water and will spread on the water surface.Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.Methods and materials for containment and cleaning upAvoid discharge into drains, water courses or onto the ground.Environmental precautions7. Handling and storageAvoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Observe good industrial hygiene practices. For personal protection, see section 8 of the SDS.Precautions for safe handling Store in original tightly closed container. Store away from incompatible materials (see Section 10of the SDS).Conditions for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limitsNot established.No biological exposure limits noted for the ingredient(s).Biological limit values Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, appropriate local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines.Appropriate engineering controlsIndividual protection measures, such as personal protective equipmentWear safety glasses with side shields (or goggles).Eye/face protectionSkin protectionSuitable chemical protective gloves should be worn when the potential exists for skin exposure.The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Nitrile gloves are recommended.Hand protectionWear appropriate chemical resistant clothing if applicable.OtherIf engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4.Respiratory protectionWear appropriate thermal protective clothing, when necessary.Thermal hazards Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.General hygiene considerations9. Physical and chemical propertiesAppearanceLiquid.Physical state Liquid.Form Amber.Color Oily.OdorOdor threshold Not available.pHNot available.Melting point/freezing point Not available.Initial boiling point and boiling range Not available.Flash point 366.8 °F (186.0 °C) Cleveland Closed Cup Evaporation rate Not available.Not applicable.Flammability (solid, gas)Upper/lower flammability or explosive limits Flammability limit - lower(%)Not available.Flammability limit - upper (%)Not available.Explosive limit - lower (%)Not available.Explosive limit - upper (%)Not available.Vapor pressure Not available.Vapor density Not available.Relative density0.872Relative density temperature 59 °F (15 °C)Solubility(ies)Solubility (water)Insoluble Partition coefficient (n-octanol/water)> 3Auto-ignition temperature Not available.Decomposition temperature Not available.Viscosity76 cSt Viscosity temperature 104 °F (40 °C)Other informationDensity0.87 g/cm³ @ 15°C10. Stability and reactivityThe product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous reactionsContact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.Hazardous decomposition products11. Toxicological informationInformation on likely routes of exposureInhalationInhalation of vapors/fumes generated by heating this product may cause respiratory irritation with throat discomfort, coughing or difficulty breathing. Prolonged inhalation may be harmful.Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.Eye contact Direct contact with eyes may cause temporary irritation.IngestionIngestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.Symptoms related to the physical, chemical andtoxicological characteristics Direct contact with eyes may cause temporary irritation.Information on toxicological effectsAcute toxicityNot expected to be hazardous by OSHA criteria.Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eye irritationRespiratory or skin sensitizationRespiratory sensitizationNot a respiratory sensitizer.This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.Germ cell mutagenicity CarcinogenicityThis product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346,Modified Ames test, and/or other screening tests.This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposureNot classified.Specific target organ toxicity -repeated exposure Not classified.Aspiration hazard Not an aspiration hazard.Chronic effectsProlonged inhalation may be harmful.12. Ecological informationThe product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.EcotoxicityNo data is available on the degradability of this product. Persistence and degradabilityBioaccumulative potentialPartition coefficient n-octanol / water (log Kow)Full Synthetic Manual Transmission Fluid > 33No data available.Mobility in soil Other adverse effectsNo other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Don't pollute.Conserve resources. Return used oil to collection centers.Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulationsThe waste code should be assigned in discussion between the user, the producer and the waste disposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).Waste from residues / unused productsSince emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.Contaminated packaging14. Transport informationDOTNot regulated as dangerous goods.IATANot regulated as dangerous goods.IMDGNot regulated as dangerous goods.Not established.Transport in bulk according toAnnex II of MARPOL 73/78 and the IBC Code15. Regulatory informationThis product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.CERCLA Hazardous Substance List (40 CFR 302.4)Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)Listed.SARA 304 Emergency release notificationNot regulated.Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - No Delayed Hazard - No Fire Hazard - NoPressure Hazard - No Reactivity Hazard - NoHazard categoriesSARA 302 Extremely hazardous substanceNot listed.NoSARA 311/312 Hazardous chemicalSARA 313 (TRI reporting)Chemical name% by wt.CAS number Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts5.00000000000068649-42-3Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated.Not regulated.Safe Drinking Water Act(SDWA)California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.US state regulations International InventoriesAll components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.16. Other information, including date of preparation or last revision02-08-2017Issue dateVersion 01Health: 1Flammability: 1Physical hazard: 0HMIS® ratingsHealth: 1Flammability: 1Instability: 0NFPA ratingsThis document was prepared by FCSD-Toxicology, Ford Motor Company, Fairlane Business Park IV, 17225 Federal Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature.Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are anydifferences between this product’s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed.Preparation Information and DisclaimerXT-M5-QSPart number(s)。

CANBERRA CORPORATIONSAFETY DATA SHEET1. IdentificationProduct Identifier: HUSKY HIGH DILUTION NEUTRAL 806 NEUTRAL HOSPITAL DISINFECTANTApplication or recommended use: Concentrated hard surface disinfectant cleanerRestrictions on use: Do not use in any fashion not specified on the product label.Manufacturer / supplier: Canberra Corporation3610 N. Holland-Sylvania Rd.Toledo, Ohio 43615 USATelephone: 419-841-6616Emergency phone: 800-832-8992 National Poison Center: 800-222-12222. Hazards IdentificationGHS Classification: Classification of this mixture in accordance with paragraph (d) of §1910.1200.Acute Toxicity - Category 4Skin Corrosion/Irritation - Category 1CEye Damage/Irritation - Category 1Label Elements:Symbol:Signal word: DANGERHazard statements: Harmful if swallowed.Causes severe skin burns and serious eye damage.Precautionary statements: Do not breathe mist/vapors/spray.Wash hands, face and any skin contact thoroughly after handling.Wear protective gloves/protective clothing/eye protection/face protection.Do not eat, drink or smoke when using this product.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower. Wash contaminated clothing before reuse.IF INHALED: Remove person to fresh air and keep comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.See 4. First-Aid Measures for specific treatment.Store locked up.Dispose of contents/container to an approved disposal facility.Other Hazards: None known3. Composition / Information on IngredientsChemical characterization: Concentrated mixture of water, detergents, germicides and auxiliary agents.Hazardous ingredients: The exact percentage of composition has been withheld as a trade secret.15.36% Didecyl dimethyl ammonium chlorides CAS 7173-51-5, EINECS/ELINCS 230-525-27.9% C12-15 Fatty alcohol ethoxylate CAS 68131-39-5, EINECS/ELINCS NLP500-195-74.1% Tetrasodium EDTA CAS 64-02-8, EINECS/ELINCS 200-573-91.9% Ethanol CAS 64-17-5, EINECS/ELINCS 200-578-6Other ingredients (> 1%):70% Water CAS 7732-18-5, EINECS/ELINCS 231-791-24. First-Aid MeasuresSymptoms: Burning or irritation of affected areas. Causes severe skin burns and serious eye damage.Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth to an unconscious person. If respiratory irritation, dizziness, or unconsciousness occurs, seek immediate medical assistance.Skin (Hair) Contact: Remove contaminated clothing and wash before reuse. Wash contaminated area with soap and water for 15-20 minutes. Call a poison control center or doctor for treatment advice.4. First-Aid Measures (cont.)Eye Contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to a person who is unconscious or convulsing. If vomiting occurs, keep head below hips to reduce risk of aspiration. Probable mucosal damage may contraindicate the use of gastric lavage.Note to Physician: Treat exposed patients symptomatically.5. Fire-Fighting MeasuresSuitable Extinguishing Media: Not applicable. Product is not a fire hazard.Unsuitable Extinguishing Media: High pressure water jet. Specific hazards in case of fire: None known.Special Fire Fighting Precautions: Fire fighters should wear appropriate protective equipment, including self-contained breathing apparatus and impervious clothing.6. Accidental Release MeasuresEmergency Procedures: Depending on the extent of release, consider the need for restriction of access to spill area. Personal Precautions: Do not eat, drink or smoke during clean up. Wear protective clothing, eye protection and impervious gloves (e.g. neoprene). Wash thoroughly after clean up.Environmental Precautions: Prevent spills from entering storm sewers/drains or contact with soil.Clean up Methods: Small spills may be wiped up and rinsed with water. For larger spills, contain spill with inert material (sand, clay). Transfer material to labeled containers for recovery or proper disposal. After removal, flush area with water. Follow good industrial hygiene practices.7. Handling and StoragePrecautions for Safe Handling: Read label before use. Avoid contact with skin or eyes. Do not breathe mist/vapors. Wash hands, face and any skin contact thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, protective clothing, eye protection, face protection. Use product only according to label directions. If unsure about safe use, contact your supervisor.Conditions for Safe Storage: Keep out of reach of children. Do not contaminate water, food or feed by storage and disposal. Store locked up in tightly closed, original contai ner in a cool (10˚ - 30˚C), dry area.Incompatibility: Anionic detergents inactivate material.8. Exposure Controls / Personal ProtectionComponents with occupational exposure limits:Component Reference TWA PELEthanol ACGIH 1000 ppmOSHA 1000 ppmEngineering Controls: Proper ventilation in accordance with good industrial hygiene should be provided.Personal Protective EquipmentRespiratory: Respiratory protection is not necessary under normal conditions of use.Gloves: Use water impervious gloves (latex or neoprene rubber). No breakthrough time has been established.Eye Protection: Chemical resistant goggles or face protection.Other: Protective clothing (long sleeves, pants), eyewash, safety shower are always advisable when working with chemicals.9. Physical and Chemical PropertiesPhysical State - Liquid Auto-ignition temperature - Not applicableColor - Blue Flash Point - > 200°F (ASTM D3278)Odor - Fruity Flammability - Not applicableOdor Threshold - No data available Flammability Limits - Not applicableBoiling Point - 212°F Partition coefficient - Not applicableDecomposition temperature - No data available Solubility (Water) - CompleteFreezing Point - 32°F Vapor Density - No data availablepH (Conc.) - 6.0 - 8.0 Vapor Pressure - No data availablepH (RTU) - 6.0 - 8.0 Viscosity - Slightly viscousRelative Density - 1.005 % VOC - < 1 (Excluding exempt material) Evaporation Rate -Similar to water10. Stability and ReactivityReactivity: No specific reactivity test data is available for this mixture. Under normal conditions of storage and use, hazardous reactions are not expected. Incompatible materials: Oxidizers, anionic detergents.Chemical stability: This product is stable at ambient temperatures and pressures.Conditions to avoid: Temperatures above 50°C or below 10°C.Hazardous decomposition products: None known11. Toxicological InformationAcute Toxicity: Toxicity data is not available for this mixture. Data below are estimates based on summation methods.Test Results Classification (A.0.4.1(c)) Basis (A.1.3.6.1)Oral > 1357mg/kg Category 4 Ingredient literature (Additive formula)Dermal > 2000mg/kg Not applicable Ingredient literature (Additive formula)Inhalation > 20 mg/L Not applicable Ingredient literature (Additive formula)Eye Damage/Irritation Corrosion Category 1 Ingredient literatureSkin Damage/Irritation Corrosion Category 1C Ingredient literatureSummary: Skin and eye contact are most likely routes of exposure. Exposure causes skin burns and eye damage. Subchronic/Chronic Toxicity:Test Results Classification BasisSkin Sensitization Not a sensitizer Not applicable Ingredient literature.Summary: Repeated or prolonged contact causes skin burns and eye damage.Carcinogens - Ingredients are not listed on the NTP Report on Carcinogens, IARC Monographs or by OSHAOther data - No other toxicological information is available for this mixture.12. Ecological InformationThis material has not been tested for acute environmental effects.Persistence and degradability: Material is not persistent. All organic components > 1% are inherently biodegradable.Bio-accumulative potential: No evidence to suggest bio-accumulation will occur.Mobility: Accidental spillage may lead to penetration of soil and groundwater.13. Disposal ConsiderationsDo not contaminate water, food or feed by disposal. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray, or mixture of rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label directions, contact your State Pesticide or Environmental Control Agency, or the hazardous waste representative at the nearest EPA Regional Office for guidance. Container Disposal: Non-refillable container. Do not reuse or refill this container. Offer for recycling if available. Triple rinse container promptly after emptying. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate, or if allowed by state and local authorities, burn. If burned, stay out of smoke. If container is one gallon or less, wrap empty container in plastic bag and discard in trash.14. Transport InformationProper Shipping Name: UN1903 Disinfectants, liquid, corrosive, n.o.s., (Quaternary ammonium chlorides)RQ - Not ApplicableShipping emergency phone: 800-424-9300Transport hazard class: 8 Hazard Label: Corrosive (When shipped as a Limited Quantity, labeling is not required.) Packing Group:III Emergency Guide No.: 154 Marine Pollutant: No15. Regulatory InformationInventory status: All components are listed on TSCA(US), EINECS/ELINCS(EU), DSL(Canada), AICS(Australia),ENCS(Japan).FIFRA: This product is a U.S. EPA Registered pesticide, EPA Reg. No. 8155-22, and is subject to certain labeling requirements under Federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide products. The hazard information required on the pesticide label is reproduced here.DANGER: Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin or on clothing. Wear goggles or face shield, protective clothing and rubber gloves. Harmful if swallowed and/or absorbed through the skin. Wash thoroughly with soap and water after handling and before eating, drinking or using tobacco. Remove contaminated clothing and wash clothing before reuse. The pesticide label also includes other important information, including directions for use. OSHA Hazard Communication Standard: This product meets the §1910.1200 definition of a "Hazardous Chemical".15. Regulatory Information (cont.)Superfund Amendments and Reauthorization Act of 1986 Title III (EPCRA) Sections 311 and 312Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard NoFire Hazard No Reactive Hazard NoSudden Release of Pressure Hazard NoSuperfund Amendments and Reauthorization Act of 1986 Title III (EPCRA) Section 313*Chemicals marked with an asterisk in “3. Composition/Information on Ingredients” are subject to reporting requirements for Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40CFR Part 372. Pennsylvania/New Jersey/Massachusetts Right to KnowSee “3. Composition/Information on Ingredients” for hazardous and top five ingredients over 1% (w/w).California Proposition 65: This product does not contain a listed substance known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute.16. Other informationDate issued: 31. 12. 2014 F806-001 Revision: N/ADisclaimer: No representation or warranty, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature, is made with respect to information concerning the product referred to in this document. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, it is impossible to foresee every health effect or exposure risk incurred by the use of this product. All chemicals present some degree of hazard and should be used with caution. The information and recommendations contained herein are presented in good faith. The user should review this information in conjunction with their knowledge of the application intended to determine the suitability of this product for such purpose. In no event will the supplier be responsible for any damages of any nature whatsoever, resulting from the use, reliance upon, or the misuse of this information. Furthermore, it is the direct responsibility of the user to comply with all applicable regulations governing the use and disposal of this material. Prepared by: R&D,Canberra Corporation。

SAFETY DATA SHEET1. Identification*** This Safety Data Sheet is only authorised for use by HP for HP Original products. Anyunauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal actionbeing taken by HP. ***Important informationHP Color LaserJet CF412A-X-XC Yellow Print CartridgeProduct identifierNone.Other means of identificationThis product is a yellow toner preparation that is used in HP Color LaserJet Pro M452, HP ColorLaserJet Pro MFP M477, HP Color LaserJet Pro MFP M377 series printers.Recommended useNone known.Recommended restrictionsManufacturer/Importer/Supplier/Distributor informationHP Inc.1501 Page Mill RoadPalo Alto, CA 94304-1112United StatesTelephone650-857-1501HP Inc. health effects line(Toll-free within the US)1-800-457-4209(Direct)1-760-710-0048HP Inc. Customer CareLine(Toll-free within the US)1-800-474-6836(Direct)1-208-323-2551Email:2. Hazard(s) identificationNot classified.Physical hazardsNot classified.Health hazardsNot classified.Environmental hazardsNot classified.OSHA defined hazardsLabel elementsNone.Hazard symbolSignal word None.Hazard statement Not available.Precautionary statementPrevention Not available.Response Not available.Storage Not available.Disposal Not available.Hazard(s) not otherwise classified (HNOC)None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA.GHS Supplemental information This product is not classified as hazardous according to OSHA CFR 1910.1200 (HazCom 2012).3. Composition/information on ingredientsMixturesCAS number% Chemical name Common name and synonymsTrade Secret Styrene acrylate copolymer<85Pigment Trade Secret Pigment<10CAS number %Chemical name Common name and synonyms WaxTrade Secret Wax<10Amorphous silica7631-86-9Amorphous silica<34. First-aid measuresMove person to fresh air immediately. If irritation persists, consult a physician.Inhalation Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists.Skin contact Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists, consult a physician.Eye contact Rinse mouth out with water. Drink one to two glasses of water. If symptoms occur, consult a physician.IngestionNot available.Most importantsymptoms/effects, acute and delayed5. Fire-fighting measuresCO2, water, or dry chemical Suitable extinguishing media None known.Unsuitable extinguishing mediaLike most organic material in powder form, toner can form explosive dust-air mixtures when finely dispersed in air.Specific hazards arising from the chemicalNot available.Special protective equipment and precautions for firefighters If fire occurs in the printer, treat as an electrical fire.Fire fightingequipment/instructions None established.Specific methods6. Accidental release measuresMinimize dust generation and accumulation.Personal precautions,protective equipment and emergency procedures Slowly vacuum or sweep the material into a bag or other sealed container. Clean remainder with a damp cloth or vacuum cleaner. If a vacuum is used, the motor must be rated as dustexplosion-proof. Fine powder can form explosive dust-air mixtures. Dispose of in compliance with federal, state, and local regulations.Methods and materials for containment and cleaning upDo not flush into surface water or sanitary sewer system. See also section 13 Disposal considerations.Environmental precautions7. Handling and storageKeep out of the reach of children. Avoid inhalation of dust and contact with skin and eyes. Use with adequate ventilation. Keep away from excessive heat, sparks, and open flames.Precautions for safe handling Keep out of the reach of children. Keep tightly closed and dry. Store at room temperature. Store away from strong oxidizers.Conditions for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limitsUS. NIOSH: Pocket Guide to Chemical Hazards Value Components TypeTWA6 mg/m3Amorphous silica (CAS 7631-86-9)No biological exposure limits noted for the ingredient(s).Biological limit values USA OSHA (TWA/PEL): 15 mg/m3 (Total Dust), 5 mg/m3 (Respirable Fraction)ACGIH (TWA/TLV): 10 mg/m3 (Inhalable Particulate), 3 mg/m3 (Respirable Particulate)Amorphous silica: USA OSHA (TWA/PEL): 20 mppcf 80 (mg/m3)/%SiO2, ACGIH (TWA/TLV): 10mg/m3TRGS 900 (Luftgrenzwert) - 10 mg/m3 (Einatembare partikel), 3 mg/m3 (Alveolengängige fraktion)Exposure guidelinesUse in a well ventilated area.Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipmentNot available.Eye/face protectionSkin protectionNot available.Hand protectionNot available.OtherNot available.Respiratory protectionNot available.Thermal hazards9. Physical and chemical propertiesFine powderAppearanceSolid.Physical statesolidFormYellowColorSlight plastic odorOdorOdor threshold Not available.pH Not applicableMelting point/freezing point Not available.Not applicableInitial boiling point and boilingrangeFlash point Not applicableEvaporation rate Not applicableNot available.Flammability (solid, gas)Upper/lower flammability or explosive limitsNot flammableFlammability limit - lower(%)Not available.Flammability limit - upper(%)Explosive limit - lower (%)Not available.Explosive limit - upper (%)Not available.Vapor pressure Not applicableVapor density Not applicableSolubility(ies)Solubility (water)Negligible in water. Partially soluble in toluene and xylene.Not available.Partition coefficient(n-octanol/water)Auto-ignition temperature Not applicableDecomposition temperature> 392 °F (> 200 °C)Viscosity Not applicableOther informationNo information available.Oxidizing propertiesPercent volatile0 % estimatedSoftening point176 - 266 °F (80 - 130 °C)Specific gravity 1 - 1.210. Stability and reactivityNot available.ReactivityStable under normal storage conditions.Chemical stabilityWill not occur.Possibility of hazardousreactionsImaging Drum: Exposure to lightConditions to avoidStrong oxidizersIncompatible materialsCarbon monoxide and carbon dioxide.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard.Skin contact Contact with skin may result in mild irritation.Eye contact Contact with eyes may result in mild irritation.Ingestion Ingestion is not a likely route of exposure.Not available.Symptoms related to thephysical, chemical andtoxicological characteristicsInformation on toxicological effectsAcute toxicity Based on available data, the classification criteria are not met.Based on available data, the classification criteria are not met.Skin corrosion/irritationBased on available data, the classification criteria are not met.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Based on available data, the classification criteria are not met.Based on available data, the classification criteria are not met.Skin sensitizationNegative, does not indicate mutagenic potential (Ames Test: Salmonella typhimurium)Germ cell mutagenicityBased on available data, the classification criteria are not met.Carcinogenicity Based on available data, the classification criteria are not met.IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.US. National Toxicology Program (NTP) Report on CarcinogensNot listed.Based on available data, the classification criteria are not met.Reproductive toxicityBased on available data, the classification criteria are not met.Specific target organ toxicity -single exposureBased on available data, the classification criteria are not met.Specific target organ toxicity -repeated exposureAspiration hazard Based on available data, the classification criteria are not met.Further information Complete toxicity data are not available for this specific formulationRefer to Section 2 for potential health effects and Section 4 for first aid measures.12. Ecological informationLC50: > 100 mg/l, Fish, 96.00 HoursEcotoxicitySpeciesProduct Test ResultsCF412A-X-XCAquaticFish> 100 mg/l, 96 HoursFishLC50Not available.Persistence and degradabilityNot available.Bioaccumulative potentialNot available.Mobility in soilOther adverse effects Not available.13. Disposal considerationsDo not shred toner cartridge, unless dust-explosion prevention measures are taken. Finely Disposal instructionsdispersed particles may form explosive mixtures in air. Dispose of in compliance with federal,state, and local regulations.HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recyclingof HP original inkjet and LaserJet supplies. For more information and to determine if this serviceis available in your location, please visit /recycle.14. Transport informationNot a dangerous good under DOT, IATA, ADR, IMDG, or RID.Further information15. Regulatory informationUS EPA TSCA Inventory: All chemical substances in this product comply with all rules or orders US federal regulationsunder TSCA.TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.CERCLA Hazardous Substance List (40 CFR 302.4)Not listed.SARA 304 Emergency release notificationNot regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not regulated.Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - NoHazard categoriesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - NoSARA 302 Extremely hazardous substanceNot listed.NoSARA 311/312 HazardouschemicalOther federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated.Not regulated.Safe Drinking Water Act(SDWA)Not ListedUS state regulationsAll chemical substances in this HP product have been notified or are exempt from notification Regulatory informationunder chemical substances notification laws in the following countries: US (TSCA), EU(EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea,New Zealand, and China.16. Other information, including date of preparation or last revision16-Oct-2015Issue date02-Oct-2019Revision dateVersion #06This SDS was prepared in accordance with USA OSHA Hazard Communications regulation (29 Other informationCFR 1910.1200).This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries.This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled,remanufactured, compatible or other non-HP Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment,exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs.DisclaimerIdentification: Important informationRevision information Explanation of abbreviationsACGIH CAS DOT EPCRA CERCLA CFR COC IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOCAmerican Conference of Governmental Industrial Hygienists Chemical Abstracts ServiceComprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of TransportationEmergency Planning and Community Right-to-Know Act (aka SARA)International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology ProgramOccupational Safety and Health Administration Permissible Exposure LimitResource Conservation and Recovery Act RecommendedRecommended Exposure LimitSuperfund Amendments and Reauthorization Act of 1986Short-Term Exposure LimitToxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds。

Material Safety Data SheetLithium carbonate MSDS20110901 Section 1: Chemical Product and Company IdentificationProduct Name: Lithium carbonateCatalog Codes: SLL1198, SLL1576, SLL1951CAS#: 554-13-2RTECS: OJ5800000TSCA: TSCA 8(b) inventory: Lithium carbonateCI#: Not available.Synonym: Lithchips; Dilithium Carbonate; Carbonic Acid,Dilithium saltChemical Name: Lithium CarbonateChemical Formula: Li2CO3Section 2: Hazards IdentificationPotential Acute Health Effects:Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact(irritant).Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer).CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.The substance may be toxic to kidneys, peripheral nervous system, central nervous system (CNS), thyroid.Repeated or prolonged exposure to the substance can produce target organs damage.Section 3: Composition and Information on IngredientsComposition:Name CAS # % by WeightLithium carbonate 554-13-2 100Toxicological Data on Ingredients: Lithium carbonate: ORAL (LD50): Acute: 525 mg/kg [Rat]. 531 mg/kg [Mouse]. DERMAL(LD50): Acute: &gt;2000 mg/kg [Rat].Section 4: First Aid MeasuresEye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for atleast 15 minutes. Cold water may be used. Get medical attention.Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.Serious Skin Contact: Not available.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Getmedical attention.Serious Inhalation: Not available.Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tightclothing such as a collar, tie, belt or waistband.Serious Ingestion: Not available.Section 5: Fire and Explosion DataFlammability of the Product: Non-flammable.Auto-Ignition Temperature: Not applicable.Flash Points: Not applicable.Flammable Limits: Not applicable.Products of Combustion: Not available.Fire Hazards in Presence of Various Substances: Not applicable.Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.Fire Fighting Media and Instructions: Not applicable.Special Remarks on Fire Hazards: Ignites and burns fiercely when in contact with fluorine. Special Remarks on Explosion Hazards: Not available.Section 6: Accidental Release MeasuresSmall Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralizethe residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminatedsurface and dispose of according to local and regional authority requirements.Large Spill:Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilutesolution of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuatethrough the sanitary system.Section 7: Handling and StoragePrecautions:Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protectiveclothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical adviceimmediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).Section 8: Exposure Controls/Personal ProtectionEngineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels belowrecommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure toairborne contaminants below the exposure limit.Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be usedto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialistBEFORE handling this product.Exposure Limits: Not available.Section 9: Physical and Chemical PropertiesPhysical state and appearance: Solid. (Granular solid. Powdered solid.)Odor: Odorless.Taste: Not available.Molecular Weight: 73.89 g/moleColor: White.pH (1% soln/water): 11.2 [Basic.]Boiling Point: Decomposition temperature: 1310°C (2390°F)Melting Point: 720°C (1328°F)Critical Temperature: Not available.Specific Gravity: 2.11 (Water = 1)Vapor Pressure: Not applicable.Vapor Density: Not available.Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: Not available.Solubility:Partially soluble in cold water.Very slightly soluble in hot water.Insoluble in acetone.1 g dissolves in 78 ml of cold water and in 140 ml of boiling water.Solubility in water: 1.52% at o C.; 1.31% at 20 C; 1.16 % at 40 C; 1.00 at 60 C; .84 % at 80C; .71 % at 100 C.Practically insoluble in alcohol.Insoluble in Ethanol.Soluble in acid.Insoluble in ammonia.Section 10: Stability and Reactivity DataStability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Incompatible materialsIncompatibility with various substances: Reactive with oxidizing agents, acids. Corrosivity: Non-corrosive in presence of glass.Special Remarks on Reactivity: Reacts violently with Fluorine.Special Remarks on Corrosivity: Not available.Polymerization: Will not occur.Section 11: Toxicological InformationRoutes of Entry: Inhalation. Ingestion.Toxicity to Animals:Acute oral toxicity (LD50): 525 mg/kg [Rat].Acute dermal toxicity (LD50): >2000 mg/kg [Rat].Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.May cause damage to the following organs: kidneys, peripheral nervous system, central nervous system (CNS),thyroid.Other Toxic Effects on Humans:Hazardous in case of ingestion, of inhalation.Slightly hazardous in case of skin contact (irritant).Special Remarks on Toxicity to Animals: Not available.Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects and birth defects.May affect genetic material.May cause cancer.Human: passes through the placenta, excreted in maternal milk.Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects:Skin: May cause skin irritation.Eyes: May cause eye irritation and lacrimation.Inhalation: May cause respiratory tract irritation with and shortness of breath. May cause pulmonary edema.Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with abdominal pain, nausea,vomiting, hypermotility, and diarrhea. May affectbehavior/central nervous system (tremor, dizziness, slurredspeech, muscle weakness, hallucinations, irritability, giddiness, disorientation, distorted perceptions, headache,confusion, seizures, excitement, toxic psychosis, somnolence, ataxia, drowsiness, convulsions, coma ), eyes (pupillary constriction, blurred vision), urinary system (kidneys - renal dysfunction), respiratory system(respiratorydepression), cardiovascular system.Chronic Potential Health Effects:Ingestion: Prolonged or repeated ingestion may affect skin (allergic dermatitis, psoriasis, alopecia), urinarysystem (kidneys - renal dysfunction), thyroid (thryoid hyperfunction, goiter), cardiovascular system, metabolsim,brain, liver, blood, and endrocrine system (adrenal gland), and eyes (visual abnormalities) and may cause ringingin the ears. It may also affect behavior/central nervous system with symptoms similar to that of acute exposure,and cause "restless leg syndrome", a peripheral neuropathy involving a creeping sensation with a desire to rub ormove the legs. Section 12: Ecological InformationEcotoxicity: Not available.BOD5 and COD: Not available.Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products mayarise.Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.Special Remarks on the Products of Biodegradation: Not available.Section 13: Disposal ConsiderationsWaste Disposal:Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.Section 14: Transport InformationDOT Classification: Not a DOT controlled material (United States).Identification: Not applicable.Special Provisions for Transport: Not applicable.Section 15: Other Regulatory InformationFederal and State Regulations:California prop. 65: This product contains the following ingredients for which the State of California has found tocause cancer, birth defects or other reproductive harm, which would require a warning under the statute: LithiumcarbonateCalifornia prop. 65: This product contains the following ingredients for which the State of California has found tocause birth defects which would require a warning under the statute: Lithium carbonate Massachusetts RTK: Lithium carbonateNew Jersey: Lithium carbonateNew Jersey spill list: Lithium carbonateTSCA 8(b) inventory: Lithium carbonateSARA 313 toxic chemical notification and release reporting: Lithium carbonatep. 5Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.Other Classifications:WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).DSCL (EEC):R22- Harmful if swallowed.R36- Irritating to eyes.R40- Possible risks of irreversibleeffects.S2- Keep out of the reach of children.S36/37- Wear suitable protective clothing andgloves.S46- If swallowed, seek medical adviceimmediately and show this container or label.HMIS (U.S.A.):Health Hazard: 2Fire Hazard: 0Reactivity: 0Personal Protection: ENational Fire Protection Association (U.S.A.):Health: 2Flammability: 0Reactivity: 0Specific hazard:Protective Equipment:Gloves.Lab coat.Dust respirator. Be sure to use anapproved/certified respirator orequivalent. Wear appropriate respiratorwhen ventilation is inadequate.Splash goggles.Section 16: Other InformationReferences: Not available.Other Special Considerations: Not available.Created: 10/10/2005 08:21 PMLast Updated: 10/10/2005 08:21 PMThe information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and wep. 6assume no liability resulting from its use. Users should make their own investigations to determine the suitability of theinformation for their particular purposes. In no event shall be liable for any claims, losses, or damages of anythird party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, evenif has been advised of the possibility of such damages.。

SAFETY DATA SHEET1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANYProduct Identifier: 93290, 93410Product Name: Bengal Yard & Patio Outdoor Fogger, or Bengal Yard & Patio Mosquito FoggerSynonyms: EPA Reg. No. 68543-25Recommended Use: Insecticide – Outdoor flying insect killer - AerosolSupplier Name Bengal Products, Inc.Supplier Address 13739 Airline Hwy, Baton Rouge, LA 70817 USASupplier Phone No: Phone: 225-753-1313 Fax: 225-753-1464Emergency Phone No.: 225-753-13132. HAZARDS IDENTIFICATIONThis chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Inhalation (Dusts/Mists) Category 5, may be irritating to some individualsAcute Toxicity (Oral) Category 5, may be irritating to some individualsAcute Toxicity (Dermal) Category 4, mild irritantAcute Toxicity (Eyes) Category 2B, mildly irritatingEmergency OverviewEnvironmental: Acute Hazards to the Aquatic Environment, Category 1Physical: Liquefied Gases, Category 1GHS LABELSIGNAL WORD: WARNINGHAZARD STATEMENTSH280: Contains gas under pressure; may explode if heated.H312: Harmful in contact with skin.H333: May be harmful if inhaled.H400: Very toxic to aquatic life.H410: Very toxic to aquatic life with long lasting effects.PRECAUTIONARY STATEMENTSPrevention:P202: Do not handle until all safety precautions have been read and understood.P261: Avoid breathing dust/fume/gas/mist/vapors/spray.P270: Do not eat, drink, or smoke when using this product.P273: Avoid release to the environment.Response:P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin withwater/shower.P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.Storage:P403+P233: Store in a well-ventilated place. Keep container tightly closed.P411+P235: Store at temperatures not exceeding 54.4°C/ 130°F. Keep cool.Disposal:P501: Dispose of contents/container to an approved waste disposal plant.COMMENTS: This material is considered hazardous by the 2012 OSHA Hazard Communication Standard [29 CFR 1910.1200(a)(1)], and the G.H.S.3. COMPOSITION/INFORMATION ON INGREDIENTSChemical Name CAS No. Weight-% Trade SecretPermethrin 52645-53-1 2.00Prallethrin 23031-36-9 0.05Petroleum Distillates 64742-47-8 <10Liquefied Petroleum Gas 68476-86-8 15 - 25Other Ingredients <75% **In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage of the composition has been withheld as a trade secret.4. FIRST AID MEASURESIF SWALLOWED: • Call a physician or poison control center immediately for treatment advice. • Have person sip a glass of water if able to swallow.• Do not induce vomiting unless told to do so by a physician or poison control center. • Do not give anything by mouth to an unconscious person.IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a physician or poison control center immediately for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. For information regarding medical emergencies or pesticide incidents, call 1-888-740-8712.IF INHALED: • Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice.IF ON SKIN: • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice.Most Important Symptoms and Effects: Coughing and/ or wheezing. Difficulty in breathing.5. FIRE-FIGHTING MEASURESFLAMMABLE CLASS: This aerosol is NOT classified as FLAMMABLE by the flame extension test method described in 16 CFR 1500.45.EXTINGUISHING MEDIA: Foam, carbon dioxide or dry chemical.HAZARDOUS COMBUSTION PRODUCTS: Under fire conditions this product may support combustion and may decompose to give off toxic gases such as carbon monoxide, carbon dioxide, and nitrogen oxides.EXPLOSION HAZARDS: Contents under pressure. Exposure to temperatures above 130°F (54.4°C) may cause bursting. FIRE FIGHTING PROCEDURES: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along with full protective gear. Keep nearby containers and equipment cool with a water stream.SENSITIVITY TO IMPACT: Forceful impacts can cause damage to aerosol unit and may cause a bursting or explosion hazard.6. ACCIDENTAL RELEASE MEASURESSMALL SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Absorb with appropriate absorbent. Clean spill area of residues and absorbent.LARGE SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Collect product into drums, etc. via drains, pumps, etc. Absorb with appropriate absorbent. Clean spill area of residues and absorbent.ENVIRONMENTAL PRECAUTIONS - WATER SPILL: Contains Pyrethroids, which are toxic to fish and other aquatic invertebrates. Contaminated absorbent and wash water should be disposed of according to local, state/provincial andfederal/national regulations.7. HANDLING AND STORAGEGENERAL PROCEDURES: Do not use or store near heat, sparks, open flame, or any other ignition sources. HANDLING: Contents under pressure - DO NOT puncture or incinerate container. Do not use or store near heat, sparks, open flame, or any other ignition sources. Take prudent precautions to avoid contact with skin, eyes, and clothing. Mechanical ventilation should be used when handling this product in enclosed spaces. Do not contaminate water, food or feedstuffs by storage, handling, or disposal.READ AND OBSERVE ALL PRECAUTIONS AND INSTRUCTIONS ON THE PRODUCT LABEL.STORAGE: Store containers upright and closed. Always store pesticides in the original container. Store away from food and petfood. Store in areas that are cool, dry, and well-ventilated. DO NOT expose to temperatures above 130°F (54.4°C), as bursting may occur. DO NOT use or store near heat, sparks, open flame, near any ignition sources, or near strong acids, bases, and oxidizers. Emptied containers may retain product residues.KEEP OUT OF REACH OF CHILDREN.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEXPOSURE GUIDELINESOSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITSOSHA PEL ACGIH TLV Supplier OELChemical Name ppm mg/m3 ppm mg/m3 ppm mg/m3 Permethrin TWA None None NonePrallethrin TWA None None NonePetroleum Distillates TWA None None NoneLiquefied Petroleum Gas TWA 1000 1800 1000 1800 NoneENGINEERING CONTROLS: Mechanical ventilation should be used when handling this product in enclosed spaces. Local exhaust ventilation may be necessary.PERSONAL PROTECTIVE EQUIPMENTEYES AND FACE: Take prudent precautions to avoid contact with eyes.SKIN: Take prudent precautions to avoid contact with skin and clothing.WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK AREA! Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking, or using the toilet.9. PHYSICAL AND CHEMICAL PROPERTIESSpecific Gravity Of Concentrate: Approx. 1.0 Vapor Pressure (Psig @ 70°F): 70Boiling Point (F): N/A Percent Volatile By Volume: <98%Solubility In Water : Partially miscible Evaporation Rate(Water=1): Not EstablishedAppearance: white opaque emulsion Odor: Slight solvent smell.Flammable Limits In Air, % by volume: Lower: 3.4% Upper: 18.0%Other Physical and Chemical Properties not determined.10. STABILITY AND REACTIVITYReactivity: No data available.Chemical stability: Stable under recommended storage conditions.Possibility of Hazardous Reactions: None under normal processing.Hazardous Polymerization: Hazardous polymerization does not occur.Conditions to avoid: Excessive heat, flames and sparks.Incompatible materials: None known based on information supplied.Hazardous Decomposition Products: Carbon oxides.11. TOXICOLOGICAL INFORMATIONToxixity Study ClassificationAcute Oral: EPA Category IV (LD50 > 5000mg/L)Acute Dermal: EPA Category IV (LD50 > 5000mg/L)Acute Inhalation: EPA Category IV (LC50 > 2.02mg/L)Primary Eye: EPA Category IIIPrimary Dermal: EPA Category IIISensitization: Non-sensitizerSome of the toxicity data may be bridged from substantially similar tested formulations.Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen.Chemical Name ACGIH IARC NTP OSHAPermethrin 52645-53-1 Group 2A, Group 3 XIARC (International Agency for Research on Cancer): Group 2A - Probably Carcinogenic to Humans. Group 3 - Not Classifiable as to Carcinogenicity in Humans.OSHA (Occupational Safety and Health Administration of the US Department of Labor): X - Present12. ECOLOGICAL INFORMATIONThis pesticide is extremely toxic to aquatic organisms, including fish and aquatic invertebrates. Do not contaminate water when disposing of aerosol unit, washwater or rinsate. See the "Directions For Use" on the product label for additional precautions and requirements. Do not apply directly to water.13. DISPOSAL CONSIDERATIONSDisposal methods: DO NOT puncture or incinerate container!IF EMPTY: Non-refillable container. Do not reuse or refill this container. Place in trash or offer for recycling if available.IF PARTLY FILLED: Call your local solid waste agency for disposal instructions.14. TRANSPORT INFORMATIONDOTProper Shipping Name CONSUMER COMMODITYHazard Class ORM-DDescription CONSUMER COMMODITY, ORM-DEmergency Response Guide Number 126IATAUN-No. UN1950Proper Shipping Name AEROSOLS, NON-FLAMMABLEHazard Class 2.2Description UN1950, AEROSOLS, NON-FLAMMABLE, 2.215. REGULATORY INFORMATIONThis chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. Following is the hazard information as required on the pesticide label: CAUTION. KEEP OUT OF REACH OF CHILDREN.Harmful if swallowed.Causes moderate eye irritation.Avoid contact with eyes or clothing.TSCA - United States Toxic Substances Control Act Section 8(b) Inventory: CompliesSARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372Chemical Name CAS No. Weight-% SARA 313 - Threshold Values %Permethrin 52645-53-1 2 1.0SARA 311/312 Hazard CategoriesAcute Health Hazard YesChronic Health Hazard NoFire Hazard YesSudden release of pressure hazard YesReactive Hazard NoCWA (Clean Water Act)This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.US State Regulations :California Proposition 65This product does not contain any Proposition 65 chemicals.U.S. State Right-to-Know RegulationsChemical Name New Jersey Massachusetts Pennsylvania Rhode Island IllinoisSupplier Trade Secret X XX X X X Permethrin52645-53-116. OTHER INFORMATIONNFPA Health Hazards 1 Flammability 4 Instability 0 Physical and Chemical Hazards - HMIS Health Hazards 1 Flammability 4Physical Hazard 0 Personal Protection XREVISION DATE: March 15, 2017。

DISCUS® LEPA Registration Number: 59807-181. IDENTIFICATION OF THE SU BSTANCE/MIXTU REAND OF THE COMPANY/UNDERTAKINGProduct identifierTrade name . . . . . . . . . . . . .: DI SCUS® LEPA Registration No. . . . . .: 59807-18Relevant identified uses of the substance or mixture and uses advised againstUse . . . . . . . . . . . . . . . . . . .: I nsecticideRestrictions on use . . . . . .: See product label forrestrictions .Company information . . . .: OHP, Inc .PO Box 746Bluffton, SC 29910-0746(800) 659-6745Emergency telephone numberTRANSPORTATION EMERGENCY(24 hours a day) call . . . .: Chemtrec: 1-800-424-9300MEDICAL EMERGENCY (24 hours a day) and ProductInformation call . . . . . . . .: 1-800-356-4647SDS Information orRequest . . . . . . . . . . . . . . . .: ohp .com2. HAZARDS IDENTIFICATIONClassification in accordance with regulationHCS 29CFR §1910.1200This material is not hazardous under the criteria ofthe Federal OSHA Hazard Communication Standard29CFR 1910 .1200 .Other hazards . . . . . . . . . . .: No particular hazards known .3. COMPOSITION/INFORMATION ON INGREDIENTSHazardousComponent Concentration Name CAS-No. % by weight Imidacloprid 138261-41-3 2.94Cyfluthrin 68359-37-5 0.7Glycerine 56-81-5 12.04. FIRST AID MEASURESDescription of first aid measuresGeneral advice . . . . . . . . . .: When possible, have the product container or label with you when calling apoison control center or doctor or going for treatment .Inhalation . . . . . . . . . . . . . .: Move to fresh air . I f person is not breathing, call 911 or an ambulance, then giveartificial respiration, preferably mouth-to-mouth ifpossible . Call a physician or poison control centerimmediately .Skin contact . . . . . . . . . . . .: Take off contaminated clothing and shoes immediately . Wash off immedi-ately with plenty of water for at least 15 minutes . Calla physician or poison control center immediately .Eye contact . . . . . . . . . . . . .: Hold eye open and rinse slowly and gently with water for 15-20 minutes .Remove contact lenses, if present, after the first 5minutes, then continue rinsing eye . Call a physicianor poison control center immediately .Ingestion . . . . . . . . . . . . . . .: Call a physician or poison control center immediately . Rinse out mouth and givewater in small sips to drink . DO NOT induce vomit-ing unless directed to do so by a physician or poisoncontrol center . Never give anything by mouth to anunconscious person . Do not leave victim unattended .Most important symptoms and effects, both acute anddelayedSymptoms . . . . . . . . . . . . .: To date no symptoms are known .Indication of any immediate medical attention andspecial treatment neededTreatment . . . . . . . . . . . . . .: Appropriate supportive and symptomatic treatment as indicated by the pa-tient’s condition is recommended . There is no spe-cific antidote .5. FIREFIGHTING MEASURESExtinguishing mediaSuitable . . . . . . . . . . . . . . . .: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide .Unsuitable . . . . . . . . . . . . .: High volume water jetSpecial hazards arising from thesubstance or mixture . . . .: Dangerous gases areevolved in the event of a fire .DISCUS® LEPA Registration Number: 59807-18Advice for firefightersSpecial protective equipment forfire-fighters . . . . . . . . . . . .: Firefighters should wearNIOSH approved self-contained breathing apparatusand full protective clothing .Further information . . . . . .: Keep out of smoke . Fight fire from upwind position . Cool closed containers ex-posed to fire with water spray . Do not allow run-offfrom fire fighting to enter drains or water courses .Flash point . . . . . . . . . . . . .: > 93 °CAutoignition temperature .: no data availableLower explosion limit . . . .: no data availableUpper explosion limit . . . .: no data availableExplosivity . . . . . . . . . . . . .: not applicable6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment andemergency proceduresPrecautions . . . . . . . . . . . .: Remove all sources of ignition . I solate hazard area . Keep unauthorizedpeople away . Avoid contact with spilled product orcontaminated surfaces .Methods and materials for containment and cleaningupMethods for cleaning up . .: Soak up with inert absor-bent material (e .g . sand, silica gel, acid binder, uni-versal binder, sawdust) . Collect and transfer theproduct into a properly labelled and tightly closedcontainer . Clean contaminated floors and objectsthoroughly, observing environmental regulations .Additional advice . . . . . . . .: Use personal protective equipment . Do not allow to enter soil, waterways orwaste water canal .Reference toother sections . . . . . . . . .: Information regarding safehandling, see section 7 .I nformation regarding personal protective equip-ment, see section 8 .nformation regarding waste disposal, see section13 .7. HANDLING AND STORAGEPrecautions for safe handlingAdvice on safehandling . . . . . . . . . . . . . .: Use only in area providedwith appropriate exhaust ventilation . Handle andopen container in a manner as to prevent spillage .Hygiene measures . . . . . . . .: Wash hands thoroughly with soap and water after handling and before eat-ing, drinking, chewing gum, using tobacco, using thetoilet or applying cosmetics .Remove Personal Protective Equipment (PPE) im-mediately after handling this product . Before remov-ing gloves clean them with soap and water . Removesoiled clothing immediately and clean thoroughly be-fore using again . Wash thoroughly and put on cleanclothing .Conditions for safe storage, including any incompat-ibilitiesRequirements for storageareas and containers . . . .: Store in a cool, dry placeand in such a manner as to prevent cross contami-nation with other crop protection products, fertilizers,food, and feed . Store in original container and out ofthe reach of children, preferably in a locked storagearea .8. EXPOSURE CONTROLS / PERSONALPROTECTIONControl parameters continuedComponents CAS-No.Controlparameters Update Basis Imidacloprid138261-41-350ug/m3(ST ESL)07 2011TX ESLImidacloprid138261-41-35ug/m3(AN ESL)07 2011TX ESLImidacloprid138261-41-30.7 mg/m3(TWA)OES BCS*Cyfluthrin(Particulate.)68359-37-55ug/m3(AN ESL)02 2013TX ESLCyfluthrin(Particulate.)68359-37-550ug/m3(ST ESL)02 2013TX ESLCyfluthrin68359-37-50.01 mg/m3(TWA)OES BCS*Glycerine(Respirable fraction.)56-81-5 5 mg/m3(PEL)02 2006OSHA Z1Glycerine(Total dust.)56-81-515 mg/m3(PEL)02 2006OSHA Z1Glycerine(Total dust.)56-81-510 mg/m3(TWA)1989OSHA Z1AGlycerine(Respirable fraction.)56-81-5 5 mg/m3(TWA)1989OSHA Z1AGlycerine(Total dust and mist.)56-81-510 mg/m3(TWA)06 2008TN OELDISCUS® LEPA Registration Number: 59807-18 Control parameters continuedComponents CAS-No.Controlparameters Update BasisGlycerine (Respirable fraction and dust or fume.)56-81-5 5 mg/m3(TWA)06 2008TN OELGlycerine (Vapor.)56-81-51000ug/m3(ST ESL)02 2013TX ESLGlycerine (Particulate.)56-81-550ug/m3(ST ESL)02 2013TX ESLGlycerine (Vapor.)56-81-5100ug/m3(AN ESL)02 2013TX ESLGlycerine (Particulate.)56-81-55ug/m3(AN ESL)02 2013TX ESL* OES BCS: Internal Bayer CropScience “Occupational Exposure Standard”Exposure controlsPersonal protectiveequipment . . . . . . . . . . . . .: In normal use and han-dling conditions please refer to the label and/or leaf-let . In all other cases the following recommendationswould apply .Respiratory protection . . .: When respirators arerequired, select NIOSH approved equipment basedon actual or potential airborne concentrations andin accordance with the appropriate regulatory stan-dards and/or industry recommendations .Hand protection . . . . . . . . .: Chemical resistant nitrilerubber glovesEye protection . . . . . . . . . .: Safety glasses withside-shieldsSkin and bodyprotection . . . . . . . . . . . . .: Wear long-sleeved shirtand long pants and shoes plus socks .General protectivemeasures . . . . . . . . . . . . .: Follow manufacturer’sinstructions for cleaning/maintaining PPE . If no suchinstructions for washables, use detergent and warm/tepid water .Keep and wash PPE separately from other laundry .9. PHYSICAL AND CHEMICAL PROPERTIESAppearance . . . . . . . . . . . . .: tanPhysical State . . . . . . . . . . .: liquidOdor . . . . . . . . . . . . . . . . . . .: weakOdour Threshold . . . . . . . . .: no data availablepH . . . . . . . . . . . . . . . . . . . . .: no data availableVapor Pressure . . . . . . . . . .: no data availableVapor Density (Air = 1) . . . .: no data availableDensity . . . . . . . . . . . . . . . . .: ca . 1 .05 g/cm³ at 20 °CEvapouration rate . . . . . . . .: no data availableBoiling Point . . . . . . . . . . . .: no data availableMelting / Freezing Point . . .: no data availableWater solubility . . . . . . . . . .: dispersibleMinimum Ignition Energy . .: not applicableDecompositiontemperature . . . . . . . . . . . .: not applicablePartition coefficient:n-octanol/water . . . . . . . . .: no data availableViscosity . . . . . . . . . . . . . . . .: 350 - 600 mPa .s at 20 °CVelocity gradient 0 .5 /s Flash point . . . . . . . . . . . . . .: > 93 °CAutoignition temperature . .: no data availableLower explosion limit . . . . .: no data availableUpper explosion limit . . . . .: no data availableExplosivity . . . . . . . . . . . . . .: not applicable10. STABILITY AND REACTIVITYReactivityThermal decomposition . .: not applicableChemical stability . . . . . . .: Stable under normal conditions .Possibility of hazardousreactions . . . . . . . . . . . . . .: No dangerous reactionknown under conditions of normal use .Conditions to avoid . . . . . .: no data availableIncompatible materials . . .: Strong oxidizing agents, BasesHazardous decompositionproducts . . . . . . . . . . . . . .: No decompositionproducts expected under normal conditions of use .DISCUS® LEPA Registration Number: 59807-1811. TOXICOLOGICAL INFORMATIONExposure routes . . . . . . . . .: Eye contact, Skin Absorp-tion, Inhalation, Ingestion Immediate EffectsEye . . . . . . . . . . . . . . . . . . .: Moderate eye irritation .Skin . . . . . . . . . . . . . . . . . . .: Harmful if absorbedthrough skin .Ingestion . . . . . . . . . . . . . . .: Harmful if swallowed .Inhalation . . . . . . . . . . . . . .: Harmful if inhaled .Information on toxicological effectsAcute oral toxicity . . . . . . .: LD50 (male rat)> 5,000 mg/kgLD50 (female rat)> 5,100 mg/kgAcute inhalation toxicity . .: LC50 (male/femalecombined rat) > 2 .23 mg/lExposure time: 4 hDetermined in the form of liquid aerosol .(actual)LC50 (male/femalecombined rat) > 8 .92 mg/lExposure time: 1 hDetermined in the form of liquid aerosol .Extrapolated from the 4 hr LC50 .(actual)Acute dermal toxicity . . . .: LD50 (male/femalecombined rat)> 5,030 mg/kgSkin irritation . . . . . . . . . . .: No skin irritation (rabbit)Eye irritation . . . . . . . . . . . .: Mild eye irritation . (rabbit)Sensitisation . . . . . . . . . . .: Non-sensitizing .(guinea pig)Assessment repeated dose toxicityImidacloprid did not cause specific target organ tox-icity in experimental animal studies .The toxic effects of Cyfluthrin are related to transienthyperactivity typical for pyrethroid neurotoxicity .Assessment mutagenicityImidacloprid was not mutagenic or genotoxic basedon the overall weight of evidence in a battery of invitro and in vivo tests .Cyfluthrin was not mutagenic or genotoxic in a bat-tery of in vitro and in vivo tests .Assessment carcinogenicityImidacloprid was not carcinogenic in lifetime feedingstudies in rats and mice .Cyfluthrin was not carcinogenic in lifetime feedingstudies in rats and mice .ACGIH . . . . . . . . . . . . . . . . . .: None .NTP . . . . . . . . . . . . . . . . . . . .: None .IARC . . . . . . . . . . . . . . . . . . .: None .OSHA . . . . . . . . . . . . . . . . . .: None .Assessment toxicity to reproductionI midacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxicto the parent animals . The reproduction toxicity seenwith Imidacloprid is related to parental toxicity .Cyfluthrin caused reproduction toxicity in a two-gen-eration study in rats only at dose levels also toxic tothe parent animals . The reproduction toxicity seenwith Cyfluthrin is related to parental toxicity .Assessment developmental toxicityI midacloprid caused developmental toxicity only atdose levels toxic to the dams . The developmental ef-fects seen with Imidacloprid are related to maternaltoxicity .Cyfluthrin caused developmental toxicity only at doselevels toxic to the dams . The developmental effectsseen with Cyfluthrin are related to maternal toxicity .Further informationAcute toxicity studies have been bridged from a simi-lar formulation(s) .The non-acute information pertains to the activeingredient(s) .12. ECOLOGICAL INFORMATIONToxicity to fish . . . . . . . . . . .: LC50 (Oncorhynchusmykiss (rainbow trout))0 .00047 mg/lExposure time: 96 hThe value mentioned relates to the active ingredientcyfluthrin .LC50 (Oncorhynchusmykiss (rainbow trout))211 mg/lExposure time: 96 hThe value mentioned relates to the active ingredientimidacloprid .Toxicity to aquaticinvertebrates . . . . . . . . . . .: EC50 (Daphnia magna(Water flea)) 0 .00016 mg/lExposure time: 48 hThe value mentioned relates to the active ingredientcyfluthrin .EC50 (Daphnia magna(Water flea)) 85 mg/lExposure time: 48 hThe value mentioned relates to the active ingredientimidacloprid .DISCUS® LEPA Registration Number: 59807-18LC50 (Chironomusriparius (non-bitingmidge)) 0 .0552 mg/lExposure time: 24 h The value mentioned relates to the active ingredient imidacloprid .Toxicity to aquatic plants . .: IC50 (Desmodesmussubspicatus) > 10 mg/lGrowth rate;Exposure time: 72 h The value mentioned relates to the active ingredient cyfluthrin .EC50 (Desmodesmussubspicatus) > 10 mg/lGrowth rate;Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid .Biodegradability . . . . . . . . .: Cyfluthrin: not rapidly biodegradableImidacloprid: not rapidly biodegradableKoc . . . . . . . . . . . . . . . . . . . .: Cyfluthrin: Koc: 64300Imidacloprid: Koc: 225 Bioaccumulation . . . . . . . . .: Cyfluthrin:Bioconcentration factor(BCF) 506; Does not bioaccumulate .I midacloprid:Does not bioaccumulate . Mobility in soil . . . . . . . . . . .: Cyfluthrin: Immobile in soilI midacloprid:Moderately mobile in soils Environmentalprecautions . . . . . . . . . . . .: Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark .Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water .Do not apply when weather conditions favor runoff or drift .Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent sites .Do not apply this product or allow it to drift to bloom-ing crops or weeds if bees are visiting the treatment area .Apply this product as specified on the label .13. DISPOSAL CONSIDERATIONSWaste treatment methodsProduct . . . . . . . . . . . . . . . .: Pesticide, spray mixture or rinse water that cannot be used according to labelinstructions may be disposed of on site or at an ap-proved waste disposal facility .Contaminated packaging . .: Do not re-use emptycontainers .Triple rinse containers .Rinsed packaging may be acceptable for landfill,otherwise incineration will be required in accordancewith local regulations .If burned, stay out of smoke .RCRA Information . . . . . . . .: Characterization andproper disposal of this material as a special or haz-ardous waste is dependent upon Federal, State andlocal laws and are the user’s responsibility . RCRAclassification may apply .14. TRANSPORT INFORMATION49CFR . . . . . . . . . . . . . . . . . .: Not dangerous goods /not hazardous material IMDGUN number . . . . . . . . . . . . .: 3082Class . . . . . . . . . . . . . . . . . .: 9Packaging group . . . . . . . .: I I IMarine pollutant . . . . . . . . .: YESProper shipping name . . . .: ENVI RONMENTALLYHAZARDOUS SUBSTANCE, LIQUID, N .O .S .(CYFLUTHRIN, IMIDACLOPRID SOLUTION) IATAUN number . . . . . . . . . . . . .: 3082Class . . . . . . . . . . . . . . . . . .: 9Packaging group . . . . . . . .: I I IEnvironm.Hazardous Mark . . . . . . . .: YESProper shipping name . . . .: ENVI RONMENTALLYHAZARDOUS SUBSTANCE, LIQUID, N .O .S .(CYFLUTHRIN, IMIDACLOPRID SOLUTION )This transportation information is not intended toconvey all specific regulatory information relating tothis product . I t does not address regulatory varia-tions due to package size or special transportationrequirements .Freight Classification . . . . .: INSECTICIDES ORFUNGICIDES, N .O .I ., OTHER THAN POISONDISCUS® LEPA Registration Number: 59807-1815. REGULATORY INFORMATIONEPA Registration No. . . . . .: 59807-18US Federal RegulationsTSCA listGlycerine 56-81-5US. Toxic Substances Control Act (TSCA) Section12(b) Export Notification (40 CFR 707, Subpt D)None.SARA Title III - Section 302 - Notification and Informa-tionNone.SARA Title III - Section 313 - Toxic Chemical ReleaseReportingCyfluthrin 68359-37-5 25,000 lbs US States Regulatory ReportingCA Prop65This product does not contain any substances knownto the State of California to cause cancer .This product does not contain any substances knownto the State of California to cause reproductive harm .US State Right-To-Know IngredientsCyfluthrin 68359-37-5 NJ, RIGlycerine 56-81-5 MNCanadian RegulationsCanadian Domestic Substance ListGlycerine 56-81-5EnvironmentalCERCLANone.Clean Water Section 307 Priority PollutantsNone.Safe Drinking Water Act Maximum Contaminant Lev-elsNone.International RegulationsEuropean Inventory of Existing Commercial Sub-stances (EINECS)Glycerine 56-81-5OHP982420 03/17 (03/12/15)EPA/FIFRA InformationThis chemical is a pesticide product registered bythe Environmental Protection Agency and is subjectto certain labeling requirements under federal pes-ticide law . These requirements differ from the clas-sification criteria and hazard information requiredfor safety data sheets, and for workplace labels ofnon-pesticide chemicals . Following is the hazard in-formation required on the pesticide label:Signal word . . . . . . . . . . . .: Caution!Hazard statements . . . . . . .: Moderate eye irritation .Harmful if swallowed, inhaled or absorbed throughthe skin .Avoid contact with skin, eyes and clothing .Avoid inhalation of vapour or mist .Wash thoroughly with soap and water after handling .Remove and wash contaminated clothing before re-use .16. OTHER INFORMATIONNFPA 704 (National Fire Protection Association):Health - 1 Flammability - 1 Instability - 0 Others - noneHMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide)Health - 1 Flammability - 1 Physical Hazard - 0 PPE -0 = minimal hazard, 1 = slight hazard, 2 = moderate haz-ard, 3 = severe hazard, 4 = extreme hazardReason for Revision . . . . . .: Revised according to the current OSHA Hazard Communication Standard(29CFR1910 .1200)Revision Date . . . . . . . . . . . .: 03/29/2017This information is provided in good faith but without express or implied warranty . The customer assumes all responsibility for safety and use not in accordance with label instructions .Discus is a registered trademark of OHP, Inc .。

安全基础定向知识培训课件基本安全定向培训安全定向一般安全规则一般安全要求知道你的工作是积极的，而不是消极的知道工作是危险的工作是安全的遵循安全工作实践保护你自己你的工作是积极的而不是消极的。

了解你的工作风险。

计划你的工作并采取预防措施。

始终检查安全并遵守安全操作规则。

保护自己和他人。

如果您有任何问题，请立即咨询您的主管。

1 、准时参加培训。

Two 、只有在征得说话者同意的情况下，不要私下交谈。

三、关闭电话或静音。

如果你在中间出去，你必须在出去之前向主人请假并获得许可。

五、演讲者有权决定参与者是否可以继续参加本培训。

六、违反上述规则的男人做俯卧撑，而女人站起来蹲下。

请将您的手机换成振动的，以避免在教室里与您的手机通话。

请不要在教室内外吸烟。

请不要在教室里抽烟。

欢迎来到上课时间:提问并积极回答问题。

随时指出教学内容中的任何不当之处。

六安全进入现场必须遵守现场安全生产的六条规定。

系好帽带，正确使用个人防护装备。

米以上的高度、悬挂如果行业中没有安全设备，必须系好安全带，并系好安全钩。

在高处作业时，不允许向下或向上投掷材料、工具和其他物体。

各种电动机械和设备在启动前必须有可靠有效的安全接地和防雷装置。

不了解电气和机械设备的人员不得使用和玩弄电气设备。

非操作人员不得进入吊装区域。

起重机械必须处于良好状态。

人们不允许站在竖杆下。

主动设备安装您的个人防护设备确保您的个人防护设备安全且适合您。

切割、压碎、切碎和焊接时，钢丝圈和焊接应佩戴护目镜。

在边缘或高空作业时，安全带应牢固固定。

穿上合适的个人防护装备工作时穿上合适的个人防护装备确保你的个人防护装备完好无损确保你的个人防护装备完好无损你想确保你的个人防护装备完好无损吗正确确认卡车翻倒时没有人在后面。

遵循安全说明和通知遵循安全说明和通知通知。

确保您在高空作业时有一个安全的地方检查工具。

设备使用前检查工具和设备使用前检查工具和设备工作时使用正确的工作工具使用正确的工作工具工作时总是关闭电源支架使用设备使用后总是切断电源保持工具当灯在高处工作时，将工具放入袋子中，取出所有突出的钉子或将其弯曲成提供足够的照明和通风的形状，以便工作时提供足够的照明和通风。

SAFETY DATA SHEETTrade designationDW-308LPRecommended useFor weldingRestrictions on useDo not use except for welding.ManufacturerManufacturer's Name: KOBE STEEL, LTD.Address: 5-9-12 Kitashinagawa Shinagawa-Ku Tokyo JAPANPhone number: +81-3-5739-6331Fax number: +81-3-5739-6960Emergency phone number:+81-3-5739-6331DistributorDistributor's Name: KOBELCO WELDING OF AMERICA INC.Address: 4755 Alpine Rd. Ste 250 Stafford, TexasPhone number: 281-240-5600Fax number: 281-240-5625Emergency phone number:281-240-5600Classification according to OSHA Hazard Communication Standard (29 CFR 1910.1200) and the Canadian Controlled Products Regulations.Hazard classificationClassification not possible as hazardous according to GHS classification.Label elementsSymbol: Not applicableSignal word: Not applicableHazard statement: Not applicablePrecautionary statement: Not applicableOther hazards which do not classified in GHS classificationGeneral: When this product is used in a welding process the hazards are electric shock,fumes, gases, radiation, spatter, slag and heat. Read and understand this SafetyData Sheets and the manufacturer’s instructions and the precautionary labelsbefore using this product.Shock: Electrical Shock can kill.Radiation: Arc rays can injure eyes and burn skin.Fumes: Overexposure to welding fumes result in symptoms like dizziness, nausea, drynessor irritation of the nose, throat or eyes. Chronic overexposure to welding fumesmay affect respiratory system and nervous system.Substance(s) formed under the conditions of useThe welding fumes produced from this welding electrode may contain the listedconstituent(s) of Sec.3 and/or their complex metallic oxides as well as solidparticles or other constituents from the consumables, base metal, or base metalcoating not listed Sec.3. The welding fumes may contain Mn, Ni, Cr(VI) andtheir compounds. Refer to Sec.8 and 10.Gases: Gases may cause gas poisoning. Under conditions of use, gases may containcarbon oxides, nitrogen oxides, ozone etc. Refer to Sec.8 and 10.Spatter, slag: Spatter, slag can damage eyes.Heat: Spatter, slag, melting metal, hot welds, arc rays and sparks can cause burn injuriesand ignite combustibles and flammable materialsSubstance/MixtureMixtureChemical name CAS No. Concentration range (%)IronChromiumTitanium dioxide NickelManganeseZirconium oxide Silicon dioxide Aluminum oxide TitaniumSiliconPotassium silicofluoride Potassium oxide Sodium fluoride7439-89-67440-47-313463-67-77440-02-07439-96-51314-23-47631-86-91344-28-17440-32-67440-21-316871-90-212136-45-77681-49-4Balance13-235-135-13＜3＜3＜3＜3＜1＜1＜1＜1＜1Description of first aid measuresInhalation: Remove person to fresh air and keep comfortable for breathing and get medical advice/attention. If breathing has stopped, perform artificial respiration and get immediatemedical advice/attention.Skin contact: Take off contaminated clothing and rinse skin with soap and water [or shower]. If skin irritation occurs, get medical advice/attention. For reddened or blistered skin, or thermal burns,get medical advice/attention.Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.Arc rays can injure eyes. If exposed to arc rays, move victim to dark room, remove contactlenses as necessary for treatment, cover eyes with a padded dressing and rest. If symptomspersist, get medical advice/attention.Electric shock: Disconnect and turn off power. If the victim is semi- or unconscious, open the airway. If the victim cannot breath, give artificial respiration. If there is no pulse, massage the chest andapply artificial respiration.Ingestion: Unlikely due to form of product, except for granular materials. If ingested, Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.Most important symptoms/effects, acute and delayedSymptoms: Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or irritation of nose, throat, or eyes. May aggravatepre-existing respiratory problems (e.g. asthma, emphysema).Long-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits inlung), central nervous system effects, bronchitis and other pulmonary effects. Refer to Section11 for more information.Hazards: Welding hazards are complex and may include physical and health hazards such as but not limited to electric shock, physical strains, radiation burns (eye flash), thermal burns due to hotmetal or spatter and potential health effects of overexposure to welding fume or dust. Refer toSection 11 for more information.Indication of immediate medical attention and special treatment needed TreatmentTreat Symptomatically.General fire hazardsAs shipped, this product is nonflammable. However, welding arc and sparks can ignite combustibles and flammable products. Read and understand American National Standard Z49.1, "Safety In Welding, Cutting andAllied Processes” before using this product.Suitable (and unsuitable) extinguishing mediaSuitable extinguishing media: As shipped, the product will not burn. In case of fire in the surroundings,use CO2, powder or water spray.Unsuitable extinguishing media: None knownSpecific hazards arising from the chemicalNone knownSpecial protective equipment and precautions for fire-fightersSpecial protective equipment: Selection of respiratory protection for fire-fighting: follow the general fireprecautions indicated in the workplace. Self-contained breathing apparatusand full protective clothing must be worn in case of fire.Special precautions: Use standard firefighting procedures and consider the hazards of otherinvolved materials.GeneralUnlikely due to form of product, except for granular materials. The welding fumes and slags may be released. Personal precautions, protective equipment and emergency proceduresIf airborne dust and/or fume is present, use adequate engineering controls and, if needed, personal protection to prevent overexposure. Refer to recommendations in Section 8.Methods and material for containment and cleaning upClean up spills immediately, observing precautions in the personal protective equipment in Section 8. Avoid generating dust. Prevent product from entering any drains, sewers or water sources. Refer to Section 13 for proper disposal.Environmental precautionsAvoid release to the environment. Prevent further leakage or spillage if safe to do so.Precautions for safe handlingReduction of fumes and dusts: Keep formation of airborne dusts to a minimum. Provide appropriateexhaust ventilation at places were dust is formed. Read and understandthe manufacturer's instruction and the precautionary label on the product.See American National Standard Z49.1, "Safety In Welding, Cutting andAllied Processes"Prevention of electric shock: Do not touch live electrical parts such as the welding wire and weldingmachine terminals. Wear insulated gloves and safety boots. If weldingmust be performed in damp locations or with wet clothing, on metalstructures or when in cramped positions such as sitting , kneeling orlying, or if there is a high risk of unavoidable or accidental contact withworkpiece, use the following equipment: Semiautomatic DC Welder, DCManual (Stick) Welder, or AC Welder with Reduced V oltage Control. Prevention of fire and explosion: Remove flammable and combustible materials and liquids.Prevention of harm when handling welding consumables: Handle with care to avoid stings and cuts. Hold the welding wire manually when loosening the wire.Conditions for safe storage, including any incompatibilitiesStore welding consumables inside a room without humidity. Do not store welding consumables directly on the ground or beside a wall. Keep welding consumables away from chemical substances like acids which could cause chemical reactions. Store in accordance with local/regional/national regulations.Control parametersFor substances may be included in welding fumes, gases and flux, occupational exposure values are shown in Annex. Keep exposure below exposure limits.Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) are values published by the American Conference of Government Industrial Hygienists (ACGIH). ACGIH Statement of Positions Regarding the TLVs and BEIs states that the TLV-TWA should be used as a guide in the control of health hazards and should not be used to indicate a fine line between safe and dangerous exposures. See Section 10 for information on potential fume constituents of health interest.Appropriate engineering controlsVentilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gasesbelow the exposure limits in the worker's breathing zone and the general area. Keepexposure as low as possible.Determine the composition and quantity of fumes and gases to which workers areexposed by taking an air sample from inside the welder's helmet if worn or in theworker's breathing zone. Improve ventilation if exposures are not below limits. SeeANSI/AWS F1.1, F1.2, F1.3 and F1.5, available from the American WeldingSociety, .Individual protection measuresEye protection: Wear helmet or use face shield with filter lens. As a rule of thumb, start with a shadewhich is too dark to see the weld zone. Then go to the next lighter shade which givessufficient view of the weld zone. Provide protective screens and flash goggles, ifnecessary, to shield others.Hand protection: Wear protective gloves. Suitable gloves can be recommended by the glove supplier. Protective Clothing: Wear hand, head, and body protection which help to prevent injury from radiation,sparks and electrical shock. See Z49.1. At a minimum this includes welder's glovesand a protective face shield, and may include arm protectors, aprons, hats, shoulderprotection, as well as dark substantial clothing. Wear dry gloves free of holes or splitseams. Train the welder not to permit electrically live parts or electrodes to contactskin or clothing or gloves if they are wet. Insulate yourself from the work piece andground using dry plywood, rubber mats or other dry insulation.Respiratory protection: Keep your head out of fumes. Use enough ventilation and local exhaust to keepfumes and gases from your breathing zone and the general area. Use respirable fumerespirator or air supplied respirator when welding in confined space or where localexhaust or ventilation does not keep exposure below exposure limits.Ear protection: Wear earplugs or earmuffs when using engine driven arc welding machine or pulsedarc welding machine that generates high-levelnoise.Hygiene measures: Do not eat, drink or smoke when using the product. Always observe good personalhygiene measures, such as washing after handling the material and before eating,drinking, and/or smoking. Routinely wash work clothing and protective equipmentto remove contaminants.Physical state: SolidColor: Silver or CopperOdor: OdorlessOdor threshold: No further relevant information availablepH: Not applicableMelting point/freezing point: No further relevant information availableInitial boiling point and boiling range: No further relevant information availableFlash point: Not applicableEvaporation rate: Not applicableFlammability: No further relevant information availableUpper/lower flammability or explosive limits: No further relevant information availableVapor pressure: Not applicableVapor density: Not applicableSolubility(ies) No further relevant information availablePartition coefficient (n-octanol/water): No further relevant information availableAuto-ignition temperature: No further relevant information availableDecomposition temperature: No further relevant information availableViscosity: Not applicableReactivityNon-reactive under normal conditions of storage and transport.Chemical stabilityStable under normal conditions of storage and transport.Possibility of hazardous reactionsContact with acids, alkalis and oxidizing agents could cause reaction and generation of gas.Conditions to avoidAvoid heat or contamination of acids, alkalis and oxidizing agents.Incompatible materialsAvoid contact with acids, alkalis and oxidizing agents.Hazardous decomposition productsWelding fumes and gases are generated as byproducts during the welding. The composition and quantity of fumes and gases cannot be recognized simply. The composition and quantity of the fumes and gases are dependent upon the base metal being welded (included coating such as solvent, paint, plating), the welding process, welding procedure, welding parameter and electrodes used. Other conditions which also influence the quantity of the fumes and gases to which workers may be exposed include the number of welding spots, the volume of the worker area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities.)The fumes and gases are different in percent and form from the ingredients listed in Section 3. The fumes and gases include those originating from the volatilization, reaction, or oxidation of the materials shown in Section 3, plus those from the base metal and coating, etc., as noted above. Reasonably expected fume constituents produced during arc welding include the oxides of iron, manganese and other metals present in the welding consumable or base metal. And, it is known that these metal oxides are complex oxides, not single compounds. Hexavalent chromium compounds may be in the welding fume of consumables or base metals which contain chromium. Nickel compounds may be in the welding fume of consumables or base metals which contain Nickel. Gaseous and particulate fluoride may be in the welding fume of consumables which contain fluoride. Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc.GeneralClassification not possible as product. Refer to Sec.2. Inhalation of welding fumes and gases can be dangerous to your health. The composition and quantity of both are dependent upon the material being worked, the process, procedures, and consumables used. Refer to Sec.10.Acute toxicityShort-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or irritation of nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema).Cr:The presence of chromium/chromate in welding fumes can cause irritation of nasal membranes and skin.Ni:The presence of nickel compounds in fume can cause metallic taste, nausea, tightness of chest, fever.F:Exposure to the fluoride ion in welding fumes may cause hypocalcemia-calcium deficiency in the blood that can result in muscle cramps and inflammation and necrosis of mucous membranes.Gases:Some toxic gases associated with welding may cause pulmonary edema, asphyxiation, and death. Chronic toxicityLong-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits in lung), central nervous system effects, bronchitis, pneumoconiosis and other pulmonary effects. The severity of the change is proportional to the length of the exposure. The changes may be caused by non-work factors such as smoking, etc. Ni:Long term overexposure to nickel fumes may also cause pulmonary fibrosis and edema.Cr:Chromates may cause ulceration, perforation of the nasal septum, and severe irritation of the bronchial tubes and lungs. Liver damage have also been reported. Chromates contain the hexavalent form ofchromium.Mn:Overexposure to manganese compounds may affect the central nervous system, symptoms of which are languor, sleepiness, muscular weakness, emotional disturbances and spastic gait. The effect ofmanganese on the nervous system is irreversible.Cu:Overexposure to copper fumes may lead to copper poisoning, resulting in hermolytic anemia and liver, kidney and spleen damage.Fe:Inhalation of too much iron oxide fume over a long time can cause siderosis, sometimes called “iron pigmentation” of the lung, which can be seen on a chest x-ray but causes little or no disability. Chronicoverexposure to iron (>50-100mg Fe per day) can result in pathological deposition of iron in bodytissues, symptoms of which are fibrosis of the pancreas, diabetes mellitus, and liver cirrhosis.SiO2:Respiratory exposure to the crystalline silica present in this welding electrode is not anticipated during normal use. Respiratory overexposure to airborne crystalline silica is known to cause silicosis, a formof disabling pulmonary fibrosis which can be progressive and may lead to death.F:Chronic fluoride absorption can result in osseous fluorosis, increased radiographic density of the bones and mottling of the teeth.CarcinogenicityWelding fumes (not otherwise specified) are possibly carcinogenic to humans.Welding fumes is on the IARC lists as posing a cancer risk.SiO2:Crystalline silica is on the IARC (International Agency for Research on Cancer) and NTP (National Toxicology Program) lists as posing a cancer risk to humans.Ni:Nickel and its compounds are on the IARC and NTP lists as posing respiratory cancer risk.Cr:Hexavalent chromium and its compounds are on the IARC and NTP lists as posing a cancer risk to humans.Skin cancer has been reported.Arcrays:Respiratory or Skin SensitizationNi:Nickel and its compounds are skin sensitizers with symptoms ranging from slight itch to severe dermatitis.Cr: Chromates may cause allergic reactions, including skin rash. Asthma has been reported in some sensitized individuals. Skin contact may result in irritation, ulceration, sensitization, and contactdermatitis.OthersOrganic polymers may be used in the manufacture of various welding consumables. Overexposure to their decomposition byproducts may result in a condition known as polymer fume fever. Polymer fume fever usually occurs within 4 to 8 hours of exposure with the presentation of flu like symptoms, including mild pulmonary irritation with or without an increase in body temperature. Signs of exposure can include an increase in white blood cell count. Resolution of symptoms typically occurs quickly, usually not lasting longer than 48 hours.EcotoxicityProduct: No further relevant information availablePersistence and degradabilityProduct: No further relevant information availableBioaccumulative potentialProduct: No further relevant information availableMobility in soilProduct: No further relevant information availableThe generation of waste should be avoided or minimized whenever possible. When practical, recycle in an environmentally acceptable, regulatory compliant manner. Dispose of non-recyclable products in accordance with all applicable National, State, and Local requirements. Discharge, treatment, or disposal may be subject to National, State, or Local laws.UN number: Not applicableUN proper shipping name: Not applicable Transport hazard class(es): Not applicablePacking group: Not applicable Environmental hazards: Not applicable Transport in bulk (according to Annex II of MARPOL73/78 and the IBC Code): Not applicableSpecial precautions for user: Not applicableRegulations of each country are applied to subustance/mixures.ReferenceAmerican National Standard (ANSI) Z49.1 “Safety in Welding, Cutting, and Allied Processes”Date of issue2015-05-20DisclaimerThe information given in this SDS is based on the present level of our knowledge and experience. This information is believed to be accurate as of the revision date shown above. However, no warranty, expressed or implied, is given. Because the conditions or methods of use are beyond KOBE STEEL, LTD.’s control, we assume no liability resulting from the use of this product. Regulatory requirements are subject to change and may differ between various locations. Compliance with all applicable Federal, State, Provincial, and local laws and regulations remain the responsibility of the user. If necessary, consult an industrial hygienist or other expert to understand this information and safeguard the environment and protect workers from potential hazards associated with the handling or use of this product.。

1 国际上化学品安全数据单的技术及管理要求围绕可持续发展的战略观点，国际上对危险化学品的管理形成了统一的框架，目的是以最大限度减少对健康和环境的负面影响的方式来生产和使用化学品。

1.1 联合国《全球化学品统一分类及标签制度》(GHS)GHS 开展了对国际上不同管理制度下采用的化学品分类和标签制度作全球统一的问题研究，制定化学品的统一分类标准和危险公示制度。

安全数据单提供关于物质的完整信息，用于工作场所的化学品控制管理框架[4]。

1.2 REACH法规在REACH 的法规框架下，安全数据单是物质危害信息传递的主要方式。

REACH 法规的要求之一是“No data, no market ”，欧盟(EU)No453/2010主要是关于安全数据单的要求，有利于化学品安全信息在生产供应链中的传递和交流[5,6]。

欧盟(EU)No830/2015法规对REACH 法规附录Ⅱ中的化学品安全技术说明书的要求进行了修订[7]。

1.3 作业场所安全使用化学品公约国际劳工组织1990年6月在日内瓦举行的第77届会议所0 引言危险化学品是指具有毒害、腐蚀、爆炸、燃烧、助燃等性质，对人体、设施、环境具有危害的剧毒化学品和其他化学品[1]。

在化学品生命周期全过程中，对其操作和使用不当极易造成危险事故、经济损失或环境污染甚至人员伤亡，危险性分类和危险信息公示标签和安全数据单是危险化学品安全管理的重要技术依据。

安全数据单(安全技术说明书，简称SDS)是一份包含化学品名称和制造商信息、化学组成信息、危害信息、急救措施、消防措施、泄漏应急处置、操作和存储、接触控制和个人防护措施、理化特性、稳定性和反应性、毒理学信息、生态学信息、废弃处置、运输信息、法规信息以及其它信息的综合性文件[2]。

SDS 是化学品生产商和销售商向客户提供的有关化学品特征的一份综合性资料[3]，因此其技术内容的符合性是化学品安全管理的重要内容。

本文基于对安全数据单各个信息要素内在联系的综合分析，围绕危险信息传达的符合性和操作安全的可行性两个关键点，结合安全数据单不符合信息实例分析，提出了安全数据单的技术符合性要求，以期为危险化学品的生产方、使用方及相关方正确编制和使用安全数据单提供借鉴。

四级2000高频词汇汇编Day 11.campus（大学）校园2.typical 典型的3.effective有效的；给人印象深刻的；实际的4.scholarship奖学金；学问5.saving节省；（pl.）储蓄金6.current当前的；流行的n. 潮流；电流7.likely 可能的；适合的ad. 可能8.package包裹；一揽子交易vt. 包装9.tuition教学；学费10.amount数量；总数vi. 合计；接近11.profile轮廓；姿态vt. 为…描绘12.tend 往往会；趋向vt. 照管13.benefit 益处；救济金vt. 有益于vi. 得益14.proportion比例；部分；均衡15.dean教长；系主任16.liberal 开明的；自由的；慷慨的17.private私人的；秘密的；私立的n. 士兵18.council委员会，理事会19.action行动；作用；情节20.risk危险vt. 冒…的危险21.blur模糊v. （使）变模糊22.truly真正地；忠实地23.vice缺点；邪恶24.loan贷款vt. 借出25.acknowledge承认；确认；报偿26.artistic艺术（家）的；富有艺术性的27.performance表演；履行；表现28.exceptional杰出的；异常的29.coach教练；长途公共汽车；旅客车厢vt. 指导30.creative有创造力的31.fashion方式；流行款式32.pursue继续；追赶；追求33.revise修订；复习vi. 复习34.attitude态度；姿势35.evil邪恶的n. 罪恶36.cash现款vt. 把…兑现37.brand商标的牌子vt. 打烙印于；加污名于38.pose 造成；提出vi. 摆姿势；假装n. 样子39.gym体育馆40.terrific极妙的；极大的41.yield屈服；倒塌vt. 产生；让出n. 产量42.imply暗示43.indifferent 冷漠的；一般的44.somewhat稍微，有点45.anyway不管怎么说pute计算，估算47.data 数据，资料48.semester学期49.register登记v. 登记；指示；表示；注意到；挂号50.inevitable不可避免的51.frustrate 使沮丧；挫败52.patience 耐心bine结合，联合54.specific特定的；明确的n. （pl.）详情55.challenge艰巨的任务；怀疑；挑战vt. 反对56.outer外面的；远离中心的57.volcano火山58.essential必不可少的；本质的n. 要素；必需品59.oxygen氧气60.besides而且prep. 除…之外（还）61.solar 太阳的；太阳能的62.probe探索；探测n. 探测器；探索63.activity活动；活跃64.carbon碳65.nitrogen氮66.create创造；引起67.bacteria细菌68.primitive原始的；简单的n. 原（始）人69.formation形成；形成物；排列70.error错误71.facilitate使变得容易munication交流73.emergency紧急情况，非常时刻74.physician内科医生75.discharge允许…离开；排出；卸货；放电n. 释放；放电76.amaze 使大为惊奇77.version版本；说法78.detail细节；枝节vt. 详述；列举79.episode一个事件；插曲，连续剧的一集80.clue线索81.conduct管理；指挥；传导；表现n. 举止82.unusual不平常的；独特的83.oral口头的84.security安全；抵押品；（pl.）证券85.enjoyable使人快乐的pete 竞争87.responsibility责任；义务88.staff全体人员vt. 为…配备（人员）89.arbitrary随意的；专断的90.motivate激励91.robot机器人92.mechanical机械的；力学的；呆板的93.individual个别的；独特的n. 个人94.identify认出；认同95.era 时代，纪元rm通知vi. 告发97.classify把…分类，把…分级98.album相册99.appreciate重视，欣赏；为…表示感激；领会vi. 增值100.establish建立；确定101.session会议；集会102.issue问题；发行；分发v. 颁布；分发；流出103.finally最后104.predict预测105.quote引用n. 引文；报价；（pl.）引号106.tense紧张的；绷紧的v. （使）拉紧n. 时态107.focus（使）聚集n. 聚焦；中心rgely大部分109.charity救济金；（常pl.）慈善团体；宽容110.intelligence智力，智慧；情报111.possess拥有112.expectation期待，预期；前程113.behave表现；运转114.outward 外表的，向外的ad. （-(s)）向外115.source 源（泉），发源地；来源116.budget预算v. 做安排，规划a. 低廉的117.ability能力；才能118.necessity必需品；必要（性）119.mostly主要地120.increasingly越来越多地mittee委员会122.promote促进；提拔；推销123.worldwide世界范围（的）124.correct正确的；合适的vt. 改正125.fame声誉，名声126.overseas在海外（的），在国外（的）127.discipline纪律；训练；惩罚；学科vt. 训练；惩罚128.concentration专注；集中；浓缩129.opportunity机会130.identity身份；个性；同一性131.obstacle障碍（物）132.guideline（常pl.）指导方针133.realm领域；王国134.intention意图135.ratio比率136.indirect间接的；婉转的137.considerable相当大的，相当多的138.feasible可行的139.conscience良心140.asset优点；（常pl.）财产141.ideal理想的；空想的n. 理想142.hardship艰难Day 21.admission 准许进入；入场费；承认2.museum 博物馆3.responsible 需负责任的；有责任感的；责任重大的4.interview 会见；面试5.candidate 申请求职者；投考者；候选人6.contact 联系；熟人；触点vt. 与…取得联系7.puzzle（使）迷惑；（使）苦思n. 智力测验，谜；难题8.resume 恢复；摘要；简历9.response回答；反应10.worthy（of）值得的；可尊敬的11.workshop 车间，工场；研讨会12.confess坦白；承认13.authority权力；官方；当权者；权威14.avert避免；转移15.perceive感知；认识到16.diverse不同的；多种多样的17.expand扩张；膨胀18.assumption假定；担任19.employer雇主20.invalid无效的；站不住脚的n. 病弱者21.bias偏心vt. 使有偏见22.distinct有区别的；清楚的；明确的23.estate土地；财产；庄园24.recruit招募，吸收n. 新兵，新成员25.illustrate说明；给…做插图说明26.potential潜在的n. 潜力27.profession职业；同行；公开表示28.executive主管；行政部门a. 行政的29.supervise监督，管理30.management管理；管理部门31.impose（on）把…强加于；征（税等）32.embarrass使尴尬33.ignorance无知34.lunar月的，月球的35.calendar日历36.inclusive包括一切的37.internal内的；国内的；内心的38.contract合同v. 缩小；订合同；感染39.discard抛弃40.stereotype陈规，老套vt. 对…形成固定看法41.enhance提高，增加42.reinforce增强43.peer同龄人；贵族vt. 仔细看44.contrary相反的n. 相反事物45.fundamental基本的n. 基本原则46.shift转移n. 转变；（轮或换）班47.stem茎；词干v. （from）起源于；止住48.rid（of）使摆脱，从…中清除49.participant参与者50.readily乐意地；容易地；很快地51.approve赞成；批准52.confirm证实；确认；批准53.accuse指控54.rescue营救55.invest投资；投入；授予56.thrill兴奋v. （使）非常兴奋57.application申请；应用；敷用58.generous 慷慨的；宽厚的；大量的59.depress使沮丧；削弱；按下60.selfish自私的61.manual手工做的，体力的n. 手册62.temporary暂时的63.unfortunately遗憾的是64.assure使确信；确保65.swift迅速的；敏捷的66.contaminate污染67.amateur业余爱好者a. 外行的68.hazard 危险vt. 尝试着做；冒…风险69.continual 不间断的；频频的70.lean倾斜；靠a. 瘦的；贫乏的71.betray背叛；失信于；泄露；暴露72.battery电池；排炮；一系列73.atmosphere大气层；空气；环境74.boast夸耀；以拥有…而自豪n. 自吹自擂75.inherit继承76.depict描绘77.worship崇拜；敬奉78.counsel律师；劝告vt. 提议79.concentrate全神贯注；集中；浓缩n. 浓缩物80.hypothesis假说，前提81.suspect推测；对…表示怀疑n. 可疑分子a. 可疑的82.distribution分发；散布83.brief短暂的；简短的vt. 向…介绍基本情况n. 摘要84.stack整齐的一叠vt. 堆放于85.succession连续；一连串；接替86.presentation提供；外观；授予；报告；表演87.awful 可怕的；难过的；非常的88.mansion 大厦，宅邸89.fluent 流利的90.inherent内在的，固有的91.confidence 信任；信心92.academic学院的；纯理论的n. 大学教师93.eloquent 雄辩的；明白显示出的94.enormous 巨大的95.hinder妨碍96.mission使命；代表团97.urge鼓励；催促n. 强烈的欲望98.exemplify 是…的典型；举例证明99.pledge 保证，誓言vt. 保证，许诺100.fabric 织物，布；构造anic有机的，有机物的102.undertake 承担；同意，保证parable 可比较的；比得上的104.synthetic 合成的，人造的；虚假的105.nylon 尼龙106.switch 转变n. 开关；转变107.influential 有影响的108.entrepreneur 企业家109.collection收藏品；收取；聚集110.initiative 主动性；倡议；主动权111.transition 过渡，转变112.convert（使）转变；（使）改变信仰113.cute 漂亮的；聪明伶俐的114.convince使确信，使信服115.favo(u)rable称赞的；有利的116.doubtful难以预测的；可疑的117.devise 发明，策划118.strand（线等的）股，缕；一个组成部分vt. 使搁浅119.variation 变化；变体；变奏120.slight 轻微的；纤细的vt./n. 轻视121.hydrogen 氢122.atom 原子；微粒123.stable 稳定的；沉稳的n. 马厩124.construct 建造；对…进行构思n. 建筑物；构想125.correspond 相符合；相当；通信126.sample 样品vt. 从…抽样；品尝127.region 地区，区域；范围128.accuracy 准确（性），精确（性）129.barber 理发师130.detective侦探131.skeleton骨骼；框架；梗概132.analysis分析133.tissue组织；薄纱，薄纸134.indispensable必不可少的135.inland内地的ad. 在内地136.chart图，表；航图vt. 用图表表示137.analyze分析138.investigate调查139.utility功用，效用；（常pl.）公用事业140.association协会；交往prehensive综合的142.ownership所有（权）143.consolidate巩固；合并144.payment支付的款项；支付145.drift漂流；漂泊n. 漂流；大意；趋势146.tide潮汐；潮流147.surge蜂拥而出；洋溢；汹涌n. 洋溢；猛增148.liable可能的；有义务的；易于…的149.massive大的；大量的150.conclude推断出；结束；缔结151.reckon 认为；（on）指望；测算152.prescribe 开（药）；规定Day 31.disposal丢掉；布置2.plastic 塑料；信用卡a. 塑料的，可塑的3.approach 靠近n. 靠近；途径；方法4.shove乱推，挤；乱塞；随意放n. 猛推5.valid 有根据的；有效的6.territory 领土；领域7.acquaintance 熟人；认识，了解8.property 财产；房产；性质9.neglect 忽略n. 疏忽10.concern关心；关系；公司vt. 有关于；使担心11.stress 压力；强调；重音vt. 强调，重读12.preface 序言13.straightforward 径直的；正直的；易懂的14.prevail 流行；占优势；说服15.punishment惩罚16.uneasy心神不安的，担心的17.debate辩论18.handle处理；操作；拿n. 柄19.scare惊恐vt. 使害怕vi. 受惊吓20.swear诅咒；宣誓，发誓21.courtesy谦恭有礼22.code准则；密码vt. 把…编码23.surround包围；围绕24.protective保护的25.negotiate协商；顺利通过26.boundary边界27.sector部门，部分；防区；扇形28.notion概念；想法modity商品30.appearance出现；外表31.achievement成就；实现mitment承诺；信奉；承担的义务33.leap跳，跃；急速行动n. 跳跃；激增34.intervene干涉；干扰35.behalf利益，方面36.dignity庄严；尊严37.congratulate祝贺38.criticize批评；评论39.discourage使泄气；阻止40.overwhelm使受不了；征服d温和的，温柔的；温暖的；轻微的42.arise出现；（from）（由…）引起；起身43.impatient不耐烦的；热切的44.respond回答；（to）做出反应45.style风格；式样vt. 设计46.mechanic技工；（-s）力学；（pl.）过程47.porter搬运工人；看门人48.carpenter 木工49.frame框架；构架；体格vt. 给…镶框；陷害；制定50.inquiry/enquiry询问；调查51.vacant未被占用的；空缺的；茫然的52.abstract抽象的n. 摘要vt. 做…的摘要；提取53.invitation邀请；请柬；吸引54.slim苗条的；薄的；少的v. 减轻体重55.qualify（使）胜任，（使）具有资格56.renew 重新开始；更新；延长有效期57.personnel人员；人事部门58.website 网站59.utilize利用60.retire退休，退役；退出；就寝61.scheme计划；阴谋v. 密谋62.trial审判；试用；讨厌的人（或事物）63.advertise 公布；做广告64.flexible 易弯曲的；灵活的65.profitable 有利可图的，有益的66.finance财政；资金vt. 为…提供资金67.acre英亩68.function功能；重大聚会；函数vi. 运行69.coordinate协调n. 坐标a. 同等的70.resident居民；住院医生a. 居住的；住院的71.controversial有争议的72.privilege特权73.neighbo(u)rhood四邻；邻近地区74.merchant商人75.hook 钩，钩状物vt. 钩住76.differ不同；发生分歧77.numerous众多的78.existence存在；生存79.vary变化vt. 改变，使不同80.related与…有亲戚关系的；有关系的81.considering就…来说82.infinite无限的83.imitate模仿；仿造84.universal普遍的；通用的；全世界的85.viewpoint观点86.fiction小说87.elementary基本的；初级的88.container容器，集装箱89.deadly致命的；不共戴天的；极度的ad. 非常90.elaborate精心计划的；复杂的v. 详述；详细制订91.phenomenon 现象；非凡的人92.particularly特别，尤其93.rape 强奸94.explosion爆炸；激增95.culture文化；培养96.isolate 使隔离，使孤立97.homogeneous 同种类的98.reward 报答，奖赏；酬金vt. 报答99.clash 冲突；不协调100.curiosity 好奇（心）；奇物101.concerning 关于102.significance意义；重要性103.acquaint使了解104.clarify阐明105.imagination想象（力）；空想106.stimulate刺激107.abundant大量的；富裕的108.derive得到；追溯…的起源vi. （from）起源109.statistic统计数值，统计资料；（-s）统计学110.prolong 延长111.strain 拉紧；极度紧张；张力；扭伤vt. 拉伤；拉紧；尽力112.ultimate 极端的；最后的n. 终极113.premature比预期时间早的；不成熟的114.span 一段时间；跨距vt. 持续；横跨115.extend 延伸；扩大；提供；达到116.fatal 致命的；重大的117.misfortune 不幸，逆境118.casual 冷淡的；非正式的；偶然的；临时的119.therapy 治疗120.psychological 心理的121.refusal拒绝122.preach宣讲；竭力鼓吹vi. 布道123.joint连接的；共同的n. 关节；接头124.negative否定的；消极的；负的n. 底片；负数125.disastrous灾难性的；极坏的126.rank军衔；地位；普通成员；排vt. 把…分等vi. 列入127.grocery 食品杂货店；食品，杂货128.rack 挂架vt. 使痛苦；使努力129.stock 库存；股票；世系；汤汁；家畜v. 储备a. 常用的130.guidance指引，指导131.cashier出纳132.diplomatic外交的；策略的133.relate有关联；适应vt. 使互相关联；讲述134.access 入口；接近的机会vt. 存取135.browse 浏览；（牛、羊等）吃草136.exert 尽（力）；运用137.dispute争论，争吵138.teenager（13-19岁的）青少年139.wealthy 富裕的140.surroundings环境141.overall总体的；全部的ad. 总的来说n. （pl.）工装裤142.reform改革；改正143.democracy民主；民主国家144.productivity生产力，生产率145.sponsor 发起者，赞助者vt. 发起，主办；资助；支持146.shrink收缩；退缩147.fee费，酬金148.fare票价vi. 进展149.exhibit 显示；展览n. 展览品150.peculiar奇怪的；特有的n. 特有财产，特权151.multiply（使）增加，（使）繁殖；乘152.lest唯恐Day 41.recreation 娱乐活动，消遣2.media新闻媒介3.selection 选择4.advertisement/ad 广告；宣传5.target 目标，靶子vt. 瞄准6.agency代理行；专业行政部门7.appropriate适当的vt. 私占；拨出（款项等）供专用8.attractive 有吸引力的9.medium中等的，适中的n. 媒质；新闻媒介；手段10.impress给…以深刻的印象；压印11.image 形象；印象；图像；形象的描述12.vehicle交通工具；传播媒介13.channel 频道；渠道；沟渠；海峡14.segment 部分，片段；瓣15.available 现成可使用的；可得到的16.sheer完全的；陡峭的；极薄的ad. 陡峭地vi. 急转向17.expose暴露；使处于…作用之下；揭露18.digital数字的19.device装置；策略mercial商业的；商品化的n. 商业广告work网状物；广播网；网络22.cable缆绳；电缆；电报vt. 给…发电报23.annual每年的n. 年报；一年生的植物24.revenue收入；税收25.delivery投递；分娩；演讲26.conjunction连接，联合；连词27.Internet因特网28.disperse分散；消散29.entertain款待；给…娱乐30.shelter掩蔽处；住所；掩蔽v. 庇护31.decrease减小，减少32.prominent突出的；突起的33.persuasion说服；信念34.revolutionary革命的，革新的n. 革命者35.replace取代；更换；把…放回原处36.pace（一）步；速度vi. 踱步37.update更新，使现代化n. 最新信息38.injury损害；受伤处39.twist使缠绕；扭伤；转身；曲折前进n. 弯曲；转变40.heal愈合，使康复；调停41.balcony阳台；楼厅42.tragic 悲惨的；悲剧（性）的43.occasion 时刻，场合；时机；起因vt. 引起44.tedious乏味的45.plot故事情节；密谋；小块地皮v. 密谋；绘图plicated复杂的47.extensive广阔的；广泛的48.appliance器具49.disguise假扮；伪装；掩盖n. 伪装50.welfare福利51.accent 口音；重音vt. 重读52.senior资格较老的；年长的n. 较年长者；毕业班学生53.rob抢劫，盗窃；（of）剥夺54.pension养老金vt. 发给…养老金55.flash闪烁；飞驰；闪现n. 闪烁；闪光灯56.luxury 奢侈（品）57.consultant顾问；会诊医师58.cruise航游；缓慢巡行n. 航游59.orient使适应；使朝向n. 东方60.collective集体的n. 集体61.survival幸存；幸存者62.violence暴力；猛烈63.depression抑郁；萧条（期）；洼地64.financial财政的，金融的65.breed品种v. 繁殖；养育；酿成66.divorce离婚；分离67.blend（使）混和n. 混合物；混和68.circular圆形的；循环的n. 通知69.toll 过路费；伤亡人数v. 敲（钟）70.married 已婚的71.locate探明，找出；使坐落于72.bankrupt破产的；彻底缺乏的vt. 使破产n. 破产者73.lease 租约vt. 出租；租得74.greenhouse 温室75.secure安全的；牢固的vt. 得到；使安全；缚牢76.cultivate 耕作；培养77.gloomy忧郁的；令人沮丧的；昏暗的78.witness目击者；证据vt. 目击；证明79.emerge出现；暴露80.advanced先进的；高级的；年迈的81.raw自然状态的；生的；未经分析的；生疏无知的；露肉而刺痛的82.ingredient成分；要素83.vital极其重要的；充满生机的84.engage占用；从事于；雇；使订婚85.generate产生；引起86.procedure程序，步骤87.acquire获得；学到88.career职业89.assignment任务；分配90.conventional常规的；符合习俗的91.hesitate犹豫；不情愿92.definition定义；清晰（度）93.global全球的；总的94.regardless不顾后果地，不管怎样95.solemn严肃的；庄严的96.relieve使轻松；减轻；使得到调剂；接替97.breakthrough突破98.condemn谴责；判…刑99.poverty贫穷100.modest谦虚的；适中的；羞怯的101.rigid 严格的；刚硬的102.tough 困难的；坚强的；严格的；老的；粗暴的103.conclusion结论；结尾；缔结104.aggressive侵犯的；有进取心的105.dependent依靠的；取决于…的106.moral道德的n. 道德；寓意107.reality 现实；真实108.reduction减少；降低109.consumption消耗量；消耗110.scan 细看；扫描；浏览n. 扫描111.cell细胞；小牢房；电池；基层组织112.intend计划；打算使（成为）113.equivalent相等的n. 等价物114.naked裸露的；无遮蔽的115.poll民意测验；政治选举vt. 对…进行民意测验；获得116.overwhelming势不可挡的；巨大的117.pessimistic悲观的118.slip滑；溜走；下降vt. 悄悄放进n. 疏漏119.fraction小部分；分数120.preserve保护；保存；腌制121.discount折扣vt. 把…打折扣；漠视122.surrender投降；屈服（于）vt. 放弃n. 投降123.coupon优惠券；配给券124.frank坦白的，直率的125.faithful忠诚的；尽职的；如实的126.evolve（使）演变，（使）进化127.engine发动机；机车，火车头128.disclose透露129.transaction交易，业务130.rely依靠；信赖131.electronic电子的n. （-s）电子学；电子设备132.secondary次要的，第二的；中等的；辅助的133.sacrifice牺牲；献祭；祭品vt. 牺牲；献祭134.ambition抱负，雄心135.contribution贡献；捐款；稿件136.prospect前景；景象；可能成为主顾的人，有希望的候选人137.occupy占用；使忙碌138.maximum最高的，最大的n. 最大限度139.virtual实质上的，事实上的140.optional可以任选的141.accordance一致142.endure忍受；持久143.procession队伍，行列144.provoke对…挑衅；激起145.anticipate期望，预料；先于…行动146.specify明确说明147.sake缘故148.scope范围；余地149.radical根本的；激进的n. 激进分子150.initial开始的n. 首字母151.prosperous繁荣的152.fulfil(l)实现；满足Day 51.elect选举；选择2.instrument 工具；乐器petition竞争，比赛4.primary首要的；最初的5.means方法；金钱6.talent 才能，天资；人才7.obtain 获得vi. 通用petitive 竞争的；好竞争的；有竞争力的9.border 边缘；边界v. 邻接；近似10.powerful 强大的，有力的；强壮的11.integrate（使）成为一体12.mutual 相互的；共同的13.stability稳定14.conscious意识到的；神志清醒的；有意的15.represent 作为…的代表；象征；描绘16.humanity 人类；人性；人道；人文学科17.reverse 撤销；使反向，倒转n. 反面；挫折a. 相反的18.award 授予；判给n. 奖19.undergraduate大学本科生20.institution社会公共机构；制度；设立21.engineering工程22.faculty能力；系，学院；全体教员23.graduate毕业生；研究生a. 研究生的v. 毕业24.participate（in）参加25.resource资源；办法26.trend趋势；时尚27.portion 一部分，一份vt. （out）分配28.institute学院vt. 建立29.genetic遗传的n. （-s）遗传学30.collaboration合作；勾结31.colleague同事32.facility设备；便利boratory/lab实验室34.arrangement安排；布置35.consistent坚持的；一致的36.circuit电路；环行37.link连接n. 环节38.industrial工业的39.sustain 保持；供养；支撑；经受40.politician政治家，政客41.economic 经济的n. （-s）经济学；经济状况42.fund 基金；储备；存款vt. 为…提供资金43.inflation 通货膨胀；膨胀44.steady 稳的；稳定的；稳重的v. （使）平稳45.dramatic引人注目的；戏剧（性）的n. （-s）戏剧表演46.corresponding相应的；一致的47.enrol(l) 入学；招收48.objection 反对49.being 人；存在50.threaten 威胁51.grasp 抓紧；理解52.immigrant 移民53.strengthen加强，巩固54.ambassador大使55.arrange安排；布置56.sufficient足够的，充分的57.reception招待会；接受；接待；接收效果58.suggestion建议；暗示59.confuse使困惑；混淆；混乱eless无用的61.athlete运动员62.jam果酱；堵塞；卡住v. 挤满；卡住；干扰63.passport 护照64.relax放松；放宽65.thirst渴；渴望vi. 渴望66.salary 薪水67.expense花费；（pl.）开支68.addition加法；增加的人或物69.instruct 指示；教育70.enrich 充实，使丰富；使富裕71.conceal 隐藏72.generally 通常；普遍地73.aware意识到的74.seal 封条；图章；海豹vt. （密）封mit 犯（错误、罪行等）；使承担义务；托付76.suicide自杀；自取灭亡77.disorder混乱；骚乱；失调78.edit编辑，校订；主编；剪辑79.shortly 立刻；不耐烦地80.timely 及时的81.receipt发票，收据；（pl.）收入；收到82.drawback 缺点83.disturb 打扰；使不安；弄乱parison 比较；比拟85.percentage百分比86.adequate 充足的；胜任的87.unemployment失业，失业人数88.hopeless 绝望的89.despair 绝望90.globe 地球；地球仪；球体91.resolve 解决；决定；分解n. 决心92.nominate 提名；任命93.violent暴力引起的；猛烈的94.kindness亲切；仁慈的行为95.campaign运动；战役vi. 参加竞选96.venture风险投资v. 冒险；敢于97.affect影响98.cooperative有合作意向的；合作的n. 合作社99.project计划；课题；工程v. 投射；使伸出；设计100.respectively各自地101.boom 激增，繁荣；（发出）隆隆声102.grant拨款vt. 授予，同意103.basis 基础104.claim声称；对…提出要求；使失踪或死亡；需要n. 要求；声称105.signify 表示…的意思，预示106.minimize使减少到最低限度；极力贬低107.obvious明显的108.division 分；分配；分歧；除（法）；部门109.perspective视角；远景；透视图110.ambitious有抱负的；有野心的111.upgrade提升，使升级n. 向上的斜坡112.evidence 证据，迹象113.striking 显著的；惹人注目的114.feature 特色；（pl.）面貌；特写；故事片vt. 突出115.characterize 成为…的特征；描绘（人或物）的特性116.requirement要求；需要的东西117.minimum 最小的n. 最低限度，最少量118.mechanism机械装置；机制；办法119.enthusiasm 热情；巨大兴趣，热衷的事物120.previous 以前的；（to）在…之前121.scar 伤疤；创伤v. （给…）留下伤痕122.dash猛冲vt. 猛掷n. 猛冲；破折号123.revelation被揭示的真相；揭示124.spontaneous自发的，无意识的；天真率直的125.fearful吓人的；不安的126.reject拒绝；拒纳n. 被拒货品127.refine精炼；使优美128.factor因素129.mood心情；（动词的）语气130.generalize概括，推断131.emotion情感，感情132.intense强烈的，紧张的；专注的；热情的133.reaction 反应，反作用；反动134.react反应；反对；起化学反应；影响135.evaluate评价136.capable有能力的137.rhythm节奏138.pitch球场；程度；音高；沥青v. 投掷；使猛然倒下；表达；定调；架设；颠簸139.descend下来；（from）起源（于）；袭击；把身份降至140.attach贴；使依恋；认为有；使附属141.signal信号；标志v. 发信号；表示a. 显著的142.gesture姿势；表示v. 做手势143.provided假如，若是144.decisive决定性的；坚定的145.resistant（to）抵抗的，耐…的146.persistent坚持不懈的；持续的147.critical关键性的；批评的148.volume卷，册；体积；音量149.capacity容量；能力；身份150.reflection映像；反射；反映；非议；深思151.incline（使）倾斜；（使）倾向于n. 斜坡152.prone（to）易于…的；俯卧的Day 61.privacy个人自由；隐私2.hunt 打猎；搜寻；追逐3.theft 偷窃，失窃4.fraud 欺诈；骗子5.deceive 欺骗6.associate 把…联系在一起；结合；交往n. 伙伴a. 副的7.estimate 估计；评价8.victim 牺牲品，受害者9.absolute绝对的；不受任何限制的10.epidemic流行病；流传a. 流传极广的11.advocate主张n. 拥护者；律师12.detect发现；查明13.unlike和…不同14.unique唯一的，独特的；极不寻常的15.account记述；账户vi. （for）说明…的原因；占16.personally亲身；作为个人；就我来说17.authorize授权18.debt 欠款，负债19.substantial大量的；牢固的；实质的20.additional额外的21.restore 恢复；修复；归还22.reputation名声munity社区；团体；群落24.erroneous错误的25.criminal 罪犯a. 犯罪的26.automatic自动的；不假思索的n. 自动手枪27.solicitor初级律师，事务律师28.delete删除29.exposure 暴露；揭发；曝光30.protection 保护31.objective目标a. 客观的32.assume假定；担任；呈现33.option选择（权）；（供）选择的事物（或人）34.anonymous匿名的；无特色的35.category 种类，类36.display陈列，展览；显示37.apply申请；适用vt. 实施；涂38.safeguard维护n. 预防措施39.representative 代表a. 有代表性的40.assign选派；指定；分配41.employment工作；雇用，使用42.specifically特别地；明确地43.eliminate排除；淘汰44.reference提到；参考；参考书目；证明书（或人）45.solution 解决；溶液46.relevant有关的，切题的47.confidential秘密的；表示信任的；担任机密工作的48.background背景49.minor较小的；次要的n. 未成年人；副修科目vi. 副修50.offence/-se犯规，违法行为；冒犯51.apparent显然的；表面上的52.submit屈服；提交；主张53.appeal呼吁，恳求；吸引力；上诉vi. 诉诸54.interrupt打断，打扰55.marvel(l)ous惊人的56.absent缺席的；不存在的；心不在焉的57.owing应付的58.offend冒犯；使厌恶；违反59.undergo经历，遭受60.conference会议；商谈pensation补偿的款物；赔偿62.suite 套间；一套家具；套，系列63.assist帮助64.thrive兴旺，繁荣65.limp软弱的；软的vi. 蹒跚n. 跛行66.cripple跛子vt. 使跛；严重削弱67.fascinate强烈地吸引，迷住68.favo(u)rite特别受喜爱的n. 特别喜爱的人（或物）69.portrait肖像70.gaze注视71.horizon 地平线；（pl.）眼界72.intelligent聪明的mute经常乘车（或船等）往返于两地vt. 减（刑）；折合n. 上下班交通74.diagnose诊断75.breakdown垮台；衰竭；损坏；分类76.recognize认出；确认；赏识77.release释放；解除；放开；发布78.publicity公众的注意；宣传79.collapse倒坍；崩溃80.unconscious失去知觉的；无意识的81.exchange交换；兑换82.volunteer志愿者；志愿兵v. 自愿83.rarely不常，难得84.traditional传统的，惯例的85.modernize（使）现代化86.connection联系；连接；（pl.）熟人87.keen热心的；敏锐的；激烈的；锋利的88.accustomed习惯于…的；通常的89.inquire/enquire 询问90.chronic 慢性的；长久的；积习难改的91.disrupt 使中断，扰乱92.psychiatrist精神科医生，精神病专家93.specialist 专家94.fatigue疲劳v. （使）疲劳95.grave 坟墓a. 严重的；严肃的96.specialize（in）专攻97.significant相当数量的；意义重大的；意味深长的98.magnificent宏伟的；豪华的；极好的99.dominate支配；耸立于100.origin起源；（常pl.）出身101.argument争论；论据；说理102.versus 以…为对手；与…相对103.nurture 养育，培育104.instant 即刻的；紧急的；速溶的n. 瞬间105.fierce凶猛的；狂热的；猛烈的106.mankind 人类107.sexual 性的；性别的108.female雌的，女（性）的n. 女子109.sociology社会学110.dismiss不再考虑；解雇；解散；驳回111.visual看得见的112.pregnant怀孕的113.discrimination歧视；辨别力114.attribute把…归因于n. 属性115.widespread分布广的，普遍的116.conception思想；构想；怀孕117.unfair不公平的118.balance平衡；秤；结存vt. 使平衡；称；权衡119.distinction差别；辨别；优秀；荣誉120.parallel相似处；平行线；纬线a. 平行的；类似的；并列的vt. 与…相似121.screen屏幕；屏风vt. 掩蔽；放映；审查122.deadline最后期限123.blank空白的；茫然的n. 空白（处）；空白表格124.forth向前，往外125.constant 始终如一的；不断的；忠实的n. 常数，恒量126.logical逻辑的；合乎常理的127.afterward(s)以后128.overnight在整个夜里；在短时间内a. 一整夜的；突然的129.bloom 花；开花（期）；青春焕发（的时期）vi. 开花130.aid援助；辅助物vt. 援助131.mercy 仁慈；恩惠132.refugee 难民133.permanent 永久的，固定的134.herd牧群vt. 使集中在一起135.heap（一）堆；大量v. （使）成堆136.electrical 电的137.beam （光线等的）束；梁；笑容vi. 面露喜色vt. 播送138.scarcely几乎不；决不；刚刚139.contrast对比；反差v. 对比140.implement使生效，实施n. 工具，器具141.nourish养育；怀有142.recovery恢复；追回143.retreat退却，撤退；退缩n. 退却；退缩；隐退处144.cooperate合作145.donation捐款，捐赠Day 71.festival 节日2.crisis危机；决定性时刻3.weary疲劳的；令人厌倦的vi. 厌烦4.diet日常饮食；特种饮食vi. 节食5.guarantee 保证n. 保证书6.emotional令人动情的；情绪激动的；感情的7.exhaust 使筋疲力尽；用光；详尽论述n. 排气装置；废气8.encounter遇到，遭遇9.obligation 义务，责任10.utter说a. 完全的11.despite尽管12.observe 注意到；观察；评说；遵守13.nonetheless 尽管如此14.optimism 乐观，乐观主义15.barely 仅仅，几乎不16.drag拖；迫使；拖着脚步走；拖延n. 累赘；一吸17.finite 有限的；限定的18.positive确实的；积极的；正的19.practically几乎；实际上20.impact影响；冲击21.gradual逐渐的；不陡的22.leak（使）漏；泄露n. 漏洞；泄漏23.plug插头，插座；塞子vt. 把…塞住24.routine例行公事a. 例行的25.spur 刺激（物），激励vt. 促进26.nevertheless仍然27.alter 改变28.tune曲子vt. 为（乐器）调音；调节29.reclaim要回；开垦；回收30.stale 不新鲜的；陈腐的31.shortage缺少32.investment投资；投入33.donate捐赠34.process过程；工序；（法律）程序vt. 加工，处理35.deprive（of）剥夺36.amuse逗乐；给…提供娱乐37.decorate装饰38.client委托人，顾客39.tender嫩的；疼痛的；温柔的v. 提出；投标n. 投标40.desirable值得想望的；可取的41.define给…下定义；限定42.bid企图；投标vi. 喊价，投标vt. 出（价）；祝；命令43.farewell告别，欢送会44.view看法；观察；景色vt. 看待；观察45.recommend 推荐；劝告；使成为可取46.drain排走；渐渐耗尽n. 耗竭；排水管47.burden重担；负荷vt. 加重压于；装载48.alternative供选择的；另类的n. 抉择；选择的自由49.quit停止，放弃；离开50.magic魔术；魔力a. 有魔力的tter后者a. 后者的；后一半的52.former以前的n. 前者53.concrete具体的n. 混凝土54.efficient效率高的55.circulate（使）循环；散布56.fossil化石；老顽固57.cite 引用；传唤；表彰58.contribute捐献；促成；投稿unch发动；使开始从事；使（船）下水；发射n. 发射，投产60.bar酒吧间；条；（门、窗等）闩；律师界vt. 闩；阻止；封锁61.personality个性；人物62.spot 地点；污点；少量vt. 认出；玷污63.beforehand预先64.crash碰撞，坠落；发出撞击声；垮台n. 碰撞；破裂声65.overtake 超过；突然降临于66.sightseeing 观光67.historical历史（上）的68.saint 圣徒；圣人；（S-）圣69.fantastic 极好的；难以相信的；异想天开的；奇异的70.fairy小仙子71.publish出版；公布72.originate起源于vt. 创造73.ancient古代的；年老的74.pop突然出现；发出砰的响声n. 流行音乐；砰的一声75.grab抓取；赶紧做；抓住n. 抓，夺76.wrinkle皱纹v. （使）起皱纹77.invisible看不见的78.platform平台；站台；纲领79.memorial纪念的n. 纪念碑80.dictate口授；命令81.decline下降；衰退；谢绝82.punctual准时的83.ensure确保84.accomplish完成，实现85.deficiency缺乏；缺点86.failure失败；失败的人（或事）；失灵；没做到87.confident确信的；有信心的88.distract 使分心89.reluctant不情愿的90.regulation规则；管理，调节91.tremble 颤抖；摇晃；担心n. 颤抖；摇晃92.transform 使改观；变换pel 强迫94.tragedy灾难；悲剧95.subsequent随后的96.virus 病毒；病毒性疾病97.economical节约的，经济的98.reveal揭露；展现99.indicate指出；表明an器官；风琴；机构；新闻媒介101.remedy补救办法；药品，治疗法vt. 补救；治疗102.miserable痛苦的；令人难受的103.liquid液体a. 液态的；清澈的；流畅的age使用，用法；惯用法105.exception例外106.textbook课本107.vocabulary词汇（量）；词（汇）表108.bound 一定的；受约束的；准备到…去的vi. 跳跃；弹回vt. 给…划界109.boost提高；推动；宣扬110.crush 压碎；镇压111.elsewhere在别处，到别处112.wage（常pl.）工资vt. 开始113.independence 独立114.leading最重要的；首位的，带头的115.male男（性）的，雄的n. 男子116.prompt促使；提示a. 敏捷的，及时的n. 提词117.scale 规模；等级；（pl.）天平；比例（尺）；刻度；鳞vt. 攀登118.gap 缺口；间隙；差距；不足119.voluntary 自愿的120.insult侮辱121.critic 批评家，评论家122.consume 消耗，花费；吃（完）；使着迷；毁灭123.municipal市的，市政的124.champagne香槟酒125.purity 纯净，纯洁，纯正126.purify 使纯净；使纯洁127.whereas 然而128.fancy喜欢；想象n. 爱好；想象力；设想a. 昂贵的；别致的129.superior上级的，较高的；（to）较好的；优良的；有优越感的n. 上级130.impressive给人印象深刻的131.occasional偶尔的132.outstanding杰出的；未解决的133.abnormal反常的134.distinguish区分；看清；（oneself）使杰出135.strive努力，奋斗136.nutrition营养137.handicap缺陷；障碍vt. 妨碍138.limitation限制；局限139.resist抵抗；抗（病等）；忍住140.excess过度；超越a. 额外的141.presently不久；目前142.symptom症状；征兆143.astonish 使惊讶144.species 种，类145.immense广大的，巨大的146.continuous连续不断的147.transmit播送；传送，传染148.string弦，线，细绳；一串vt. 用线串；悬挂149.consist（of）构成；（in）在于150.declaration宣布；声明；申报151.aspect方面；方向；外观152.angle角度；立场vt. 使带上倾向性；把…放置成一角度yout布局，设计154.justify证明…正当，为…辩护155.interpret口译vt. 解释Day 81.accommodate 容纳；向…提供住处（或膳宿）；使适应2.pave 铺（路），铺筑3.specification规格；明确说明；说明书4.drainage排水系统；排水5.wisdom 明智；智慧6.ribbon丝带；色带7.federal联邦的，联邦政府的8.tremendous巨大的；精彩的9.demonstrate论证；说明；显示vi. 举行示威游行10.restrict 限制11.congress代表大会；国会，议会12.hail 雹；一阵vi. 下雹vt. 招呼；为…喝彩13.steep陡的；过高的；急剧的vt. 浸泡14.variable 易变的；可变的n. 可变因素15.slope 斜坡；倾斜v. （使）倾斜16.intensity 强烈；强度17.underlying含蓄的，潜在的18.urban城市的19.overpass天桥，立交桥20.bypass 旁道；分流术vt. 绕过；置…于不顾21.weave 织，编22.fort 堡垒a. 强壮的23.invaluable非常宝贵的，无价的24.barrier栅栏；障碍；屏障25.entry 参赛的人（或物）；进入；入口处；登记26.curve 曲线；弯曲部v. （使）弯曲27.remote遥远的；关系疏远的；绝少的；孤高的28.cherish 珍爱；抚育；怀有29.mobile运动的；机动的；多变的n. 移动电话30.element 元素；成分；基础31.creation创造；产物；宇宙32.freight货物vt. 运送（货物）33.rail 栏杆；铁轨；铁路vi. 咒骂，抱怨34.route 路线，路程35.spin 旋转；晕眩；织；绞干n. 旋转36.motel 汽车旅馆37.manufacture 制造n. （pl.）制造品38.residential 居住的，住宅的；寄宿的39.hono(u)r 名誉；尊敬；荣幸；（pl.）优异成绩vt. 给…以荣誉；尊敬40.vision 想象（力），幻想；视力41.leadership 领导，领导层42.transportation 运输43.dynamic有活力的；不断变化（或增长）的；动力的n. 动力；（-s）动力学44.mere 仅仅的；纯粹的45.alliance 联盟46.spite 恶意，怨恨47.consideration. 考虑；体贴48.installation 装置；安装；就任49.recognition 认出；确认；赏识50.mess 凌乱状态；困境vt. 弄糟51.anyhow 无论如何；随随便便地52.sensitive 敏感的；神经过敏的；易受伤害的53.forecast 预测54.reliable可靠的55.tolerate 容许；容忍56.appointment 约会；任命；委任的职位57.resign 辞职vt. 辞去，放弃；使顺从58.insurance 保险；保证59.deserve 应受，值得60.bond 联结；黏结剂；公债；契约v. （使）黏合61.hum哼曲子；发嗡嗡声；忙碌n. 嘈杂声62.entitle 给…权利；给…题名63.dental牙齿的64.seminar （大学的）研究班，研讨会65.boring 乏味的66.philosophy哲学；哲理67.literature文学，文学作品；文献68.transfer转移；调动，转学；转车69.allowance津贴，零用钱70.decay 腐烂；衰落n. 腐烂；衰败状态71.religious宗教的；虔诚的press 压缩。

Ebony GritSafety Data SheetProduct Identifier Ebony Grit Other Means of IdentificationNot applicableOther Identification Granulated Copper Slag Opta Minerals Inc., 407 Parkside DriveP.O. Box 260, Waterdown, Ontario, Canada, L0R 2H0, (905) 689-7361,Recommended Use SDS No.Emergency Phone No.SECTION 1. IDENTIFICATIONManufacturer/Supplier IdentifierBlasting media.1044CHEMTREC, (outside North America), 1-703-527-3887, 24 hoursCHEMTREC (Canada & USA), 1-800-424-9300, 24 hoursSECTION 2. HAZARD IDENTIFICATIONClassified according to Canada's Hazardous Products Regulations (WHMIS 2015) and the US Hazard Communication Standard (HCS 2012).InhalationMove to fresh air. If experiencing respiratory symptoms (e.g. coughing, shortness of breath, wheezing), call a Poison Centre or doctor.Skin ContactWash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes.Eye ContactImmediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the eyelid(s) open.If eye irritation persists, get medical advice or attention.IngestionSECTION 4. FIRST-AID MEASURESFirst-aid MeasuresProduct Identifier:Ebony Grit 8200594IngestionNever give anything by mouth if person is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting. Call a Poison Centre or doctor if you feel unwell.Immediate Medical Attention and Special TreatmentTarget OrgansRespiratory system.Most Important Symptoms and Effects, Acute and Delayed If in eyes:May cause moderate to severe irritation.Extinguishing MediaSuitable Extinguishing MediaNot combustible. Use extinguishing agent suitable for surrounding fire.Unsuitable Extinguishing Media Not applicable.Specific Hazards Arising from the Product Does not burn.This product presents no unusual hazards in a fire situation.Not known to generate any hazardous decomposition products in a fire.Special Protective Equipment and Precautions for Fire-fighters Wear self contained breathing apparatus.SECTION 5. FIRE-FIGHTING MEASURESPersonal Precautions, Protective Equipment, and Emergency ProceduresUse the personal protective equipment recommended in Section 8 of this safety data sheet. Review Section 7(Handling) of this safety data sheet before proceeding with clean-up.Environmental PrecautionsIt is good practice to prevent releases into the environment.Methods and Materials for Containment and Cleaning UpAvoid generating dust. Collect using shovel/scoop or approved HEPA vacuum and place in a suitable container for disposal.SECTION 6. ACCIDENTAL RELEASE MEASURESPrecautions for Safe HandlingAvoid generating dusts. Wear personal protective equipment to avoid direct contact with this chemical. Avoid repeated or prolonged skin contact with product or with contaminated equipment/surfaces.It is good practice to: avoid breathing product; avoid skin and eye contact and wash hands after handling. Wash hands thoroughly after handling this product and before eating, using the washroom or leaving work area. Remove contaminated clothing and protective equipment before entering eating areas or leaving work area.Conditions for Safe Storage Store in an area that is: dry.SECTION 7. HANDLING AND STORAGESECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONACGIH TLV®OSHA PEL Chemical NameTWASTELTWACeilingControl ParametersAIHA WEEL 8-hr TWATWAProduct Identifier:Ebony GritIron Oxide5 mg/m3 * A410 mg/m3 *Aluminum oxide 1 mg/m3 * A4 5 mg/m3 *Calcium oxide 2 mg/m3 5 mg/m3Magnesium oxide 10 mg/m3 *A415 mg/m3Fused Silica (Amorphous)0.1 mg/m3Appropriate Engineering ControlsIndividual Protection MeasuresSkin ProtectionRespiratory ProtectionEye/Face Protection* respirable total dust, OSHA (PEL)= 15 mg/m3 crystalline Silica, ACGIH, TWA, 0.10 mg / m3 (ACGIH), 0.025 mg /m3,respirable.Wear a NIOSH approved air-purifying respirator with N95 or higher rating filter(s).In conditions where the levels of airborne dust exceed the capabilities of the above referenced respirators, a supplied-air respirator may be necessary.Avoid repeated or prolonged skin contact. Always wear insulated protective clothing, if contact is possible.Wear chemical safety goggles and face shield when contact is possible. Do not get in eyes.Do not allow product to accumulate in the air in work or storage areas, or in confined spaces. Use local exhaust ventilation, if general ventilation is not adequate to control amount in the air.pHNot applicableAppearanceBlack shiny.Partition Coefficient,n-Octanol/Water (Log Kow)Not applicable Vapour PressureNot applicable Odour Threshold Not applicable Vapour Density (air = 1)Not applicable Initial Boiling Point/Range Not applicable Evaporation RateNot applicableFlash PointNot applicable Melting Point/Freezing Point Not applicable (freezing)Relative Density (water = 1)Not availableUpper/Lower Flammability or Explosive Limit Not applicable (upper); Not applicable (lower)SolubilityNot applicable in water Auto-ignition TemperatureNot applicable SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESBasic Physical and Chemical PropertiesSolidPhysical StateOther InformationChemical StabilityNormally stable.Conditions to AvoidPossibility of Hazardous Reactions Not applicable.SECTION 10. STABILITY AND REACTIVITYProduct Identifier:Ebony GritConditions to AvoidGeneration of dust.Water.Hazardous Decomposition Products Not applicable.Skin Corrosion/Irritation May cause irritation.May cause skin irritation.Serious Eye Damage/IrritationMay cause moderate to severe irritation.May cause moderate to severe irritation.SECTION 11. TOXICOLOGICAL INFORMATIONSTOT (Specific Target Organ Toxicity) - Single ExposureInhalationCan irritate the respiratory system.Skin Absorption May cause irritation.IngestionMay cause irritation of the mouth, throat and stomach.May cause irritation of the respiratory system.STOT (Specific Target Organ Toxicity) - Repeated Exposure Respiratory and/or Skin SensitizationMay cause respiratory or skin sensitization based on limited evidence.CarcinogenicityContains less than 0.1% crystalline silica Development of OffspringThere is no evidence this product contributes Teratogenicity or Embryotoxicity.There is no evidence this product contributes Teratogenicity or Embryotoxicity properties.Reproductive ToxicityNo ingredients in this product are known to contribute to reproductive toxicity.No ingredients in this product are known to contribute to reproductive toxicity.Germ Cell Mutagenicity Not known to be a mutagen.No ingredients in this product are known to cause mutagenicity.Interactive Effects None known.None known.Acute ToxicitySexual Function and FertilityInhalation. Skin contact. Eye contact. Ingestion.Likely Routes of ExposureChemical NameLC50LD50 (oral)LD50 (dermal)Iron Oxide Not available > 10,000 mg/kg (rat)Not available Aluminum oxide Not available > 5,000 mg/kg (rat)Not available Calcium oxide Not available > 2,000 mg/kg (rat)Not available Magnesium oxide Not available 810 mg/kg (mouse)Not available Fused Silica (Amorphous)Not available Not available Not available Product Identifier:Ebony GritInteractive EffectsNone known.None known.Although this product is not classified as an environmentally hazardous material, large or frequent spills may cause potential problems.This product and its degradation products are not known to bioaccumulate.SECTION 12. ECOLOGICAL INFORMATIONThis product is not biodegradable.EcotoxicityPersistence and Degradability Bioaccumulative PotentialSECTION 13. DISPOSAL CONSIDERATIONSDispose of waste in compliance with applicable Federal, State, Provincial and Local Regulations.Disposal MethodsSECTION 14. TRANSPORT INFORMATIONNot regulated under Canadian TDG regulations. Not regulated under US DOT Regulations.Special Precautions Not applicableTransport in Bulk According to Annex II of MARPOL 73/78 and the IBC CodeNot applicableSECTION 15. REGULATORY INFORMATIONCanadaWHMIS 1988 ClassificationDomestic Substances List (DSL) / Non-Domestic Substances List (NDSL)All ingredients are listed on the DSL/NDSL.This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by the Controlled Products Regulations.Custom Regulatory 1Employee exposure monitoring should be performed when using this product to determine exposure levels to not only the oxides contained in this product, but also the material being blasted.Safety, Health and Environmental Regulations Key to AbbreviationsACGIH® = American Conference of Governmental Industrial Hygienists OSHA = US Occupational Safety and Health Administration HSDB® = Hazardous Substances Data BankReferencesCHEMINFO database. Canadian Centre for Occupational Health and Safety (CCOHS).Registry of Toxic Effects of Chemical Substances (RTECS®) database. DassaultSystèmes/BIOVIA (“BIOVIA”). Available from Canadian Centre for Occupational Health and Safety (CCOHS). HSDB® database. US National Library of Medicine. Available from Canadian Centre for Occupational Health and Safety (CCOHS). NIOSH Pocket Guide database. National Institute for Occupational Safety and Health. Available from Canadian Centre for Occupational SECTION 16. OTHER INFORMATIONNFPA RatingSDS Prepared By Dave RumblePhone No.(905) 689-7361, ext 217Date of Preparation January 24, 2017Health - 0Flammability - 0Instability - 0March 08, 2016Date of Last Revision Product Identifier:Ebony GritCentre for Occupational Health and Safety (CCOHS). NIOSH Pocket Guide database. NationalInstitute for Occupational Safety and Health. Available from Canadian Centre for OccupationalHealth and Safety (CCOHS).Disclaimer To the best of our knowledge, the information contained herein is accurate.Although certain hazards are described herein, we can not guarantee that these are the onlyhazards that exist.Opta Minerals Inc. assumes no liability arising out of the use of this product by others.Product Identifier:Ebony Grit。