【全国省级联考word】浙江新高考研究联盟2018届第二次联考高三化学试题

1 2018年全国统一高考化学试卷（新课标I） 、选择题（共7小题，每小题6分，满分42 分） 1.（ 6分）磷酸亚铁锂（LiFePO4）电池是新能源汽车的动力电池之一，采用湿法冶金工艺 回收废旧磷酸亚铁锂电池正极片中的金属，其流程如下: ► \aAlO.畏液

F列叙述错误的是（ 是最单的一种，下列关于该化合物的说法错误的是（

A. 合理处理废旧电池有利于保护环境和资源再利用 B. 从“正极片”中可回收的金属元素有 Al、 Fe、Li C. "沉淀”反应的金属离子为 Fe3+ D.上述流程中可用硫酸钠代替碳酸钠 2. （6分）下列说法错误的是（ A. 蔗糖、果糖和麦芽糖均为双糖 •酶是一类具有高选择催化性能的蛋白 C. 植物油含不饱和脂肪酸酯，能使 Br2/CCl 4 褪色 D. 淀粉和纤维素水解的最终产物均为葡萄糖 3. （6分）在生成和纯化乙酸乙酯的实验过程中, F列操作未涉及的是（

A. B.

4. （6分）NA是阿伏加德罗常数的值，下列说法正确的是（

A. 16.25gFeCI 3,水解形成的Fe （ OH 3为胶体粒子数为 3, 0.1N

A

B. 22.4L （标准状况）氩气含有的质子数为 18NA

C. 92.0g甘油（丙三醇）中含有羟基数为 1.0NA

D. 1.0molCH4与Cl 2

在光照下生成 CHCI的分子数为1.0N

A

5. （6分）环之间共用一个碳原子的化合物称为螺环化合物，螺（ 2, 2）戊烷（ 2

C.所有碳原子均处同一平面 D •生成1molGHi2，至少需要2molH2

6.（ 6分）主族元素 W X、Y、Z的原子序数依次增加，且均不大于 20. VV X、Z最外层电 子数之和为10; W与 Y同族；W与Z形成的化台物可与浓硫酸反应，其生成物可腐蚀玻璃。 下列说

法正确的是（ ） CO+H2S协同转化装置，实现对天然气中 CO和HkS 的高效去除。示意图如右所示，其中电极分别为 ZnO（石墨烯（石墨烯包裹的 ZnO）和石墨 烯，石墨烯电极区发生反应为： 2+ — 3+ ① EDTA- Fe — e =EDTA- Fe ② 2EDTA- Fe3++H2S=2H+S+2EDTA- Fe2+该装置工作时，下列叙述错误的 是（ ） A. 阴极的电极反应： CO+2H+2e—— CO+2O B. 协同转化总反应：CO+HS— CO+2O+S C. 石墨烯上的电势比 ZnO砌墨烯上的低 D. 若采用Fe3+/Fe2+取代EDTA- Fe3+/EDTA- Fe2+,溶液需为酸性 二、解答题（共3小题，满分43分） & （ 14分）醋酸亚铬［（CHCOO 2Cr?2fO］为砖红色晶体，难溶于冷水，易溶于酸，在气体 分析中用作氧气吸收剂。一般制备方法是先在封闭体系中利用金属锌作还原剂，将三价铬 还原为二价络；二价铬再与醋酸钠溶液作用即可制得醋酸亚铬。实验装置如图所示。回答 下列问题： （1 ）实验中所用蒸馏水均需经煮沸后迅速冷却， 目的是 __________ 仪器a的名称是 _______ 。 （2）将过量锌粒和氯化铬固体置于 c中，加入少量蒸馏水，按图连接好装置。打开 K1、K2, 关闭K3。 ① c中溶液由绿色逐渐变为亮蓝色，该反应的离子方程式为 ________ ② 同时c中有气体产生，该气体的作用是 _______________________ （3）打开 K3,关闭K1和K2. c中亮蓝色溶液流入 d,其原因 A.与环戊烯互为同分异构体 氯化物超过两种 A. 常温常压下X的单质为气态 B . Z的氢化物为离子化合物

浙江省名校新高考研究联盟2018届第二次联考英语参考答案听力：1—5CBABA6—10BABCA11—15ABCAC16—20BABCB阅读：21—23CBD24—26CBC27—30CDDA31—35CBFAD完型：36—40BCABD41—45ACBDA46—50DCDAB51—55CBCAD语法填空：56.when57.a58.made59.mine60.impatiently61.nodded62.another63.shouting64.from65.worlds应用文：Dear Miss Lee,I’m writing to apply for a position working as a teaching assistants in your school as is advertised on the Internet.I am longing to get this job to better qualify myself and help others as well.For me,Chinese is my mother tongue and I’m excellent in it.Besides,having learned English for9 years,I’m rather proficient in both spoken and written English.And I’m willing to help foreigners learn the Chinese language and culture.I’d appreciate your consideration of my application.Looking forward to your reply.Yours sincerely,Li Hua读后续写：（参考范文）Paragraph1:By now we were standing in the long Holiday line to pay the bill,and I figure it was a good chance.I lay down on the ground and began screaming,“I want that telephone,”over and over again.Weary Christmas shoppers looked as my mother calmly said,“Becky,you better get up by the count of three or else.One…Two…Three.”Nothing.I was still in full tantrum.So then she lay down beside me on the floor, and began kicking and screaming,“I want a new car,I want a new house,I want some jewelry,I want…”Shocked,I stood up.Paragraph2:“Mama,stop.Mama,get up,”I tearfully pleaded.She stood,and brushed herself off.At first stunned, the others waiting in line began to sporadically clap,and before I knew it they were cheering and laughing and patting my mother on her back.She blushed and took a little bow and the next thirty minutes in line was pure misery for me as various parents leaving the store,shake their heads at me and say with a smile,“Your mom got you good.I bet you’ll never try that again.”And I didn’t,because it left a lasting mental picture more effective than any physical mark.浙江省名校新高考研究联盟2018届第二次联考英语参考答案第1页共3页听力原文第一节Text1M:Wow!The painting looks great.What do you think of mine?W:Er,well it’s nice,but mine is better.I mean it’s more beautiful.Text2W:Mr.Li,it is time to hold a meeting.M:Uh…What’s the time now?W:It is a quarter to nine.M:OK,I will arrive in five minutes.Text3M:I decided that I need to challenge myself with an adventure.W:Wow!M:I’m going on a month-long trip to explore the caves of MexicoW:You’ve never done anything like this before,and I think it will be very exciting!Text4W:Excuse me,Sir.If my fish cannot be served in the next5minutes,I’ll cancel that course.I’ve been waiting for half an hour already!M:I’m so sorry,Miss.I’ll check it for you right away.Text5W:I really enjoyed the TV special about the life of Walt Disney last night.Did you get home in time to see it? M:Oh,yes,but I wish I could have stayed awake long enough to see the whole thing.第二节Text6M:Rosie,hurry up!Look,here is the karaoke bar.W:(Breathing heavily)Dean,why is the bar on the top floor?So many stairs.Help me,please.Oh,I’m so unfit.I need to start doing more exercise.I’m going to join the gym tomorrow.M:Tomorrow?Why don’t you join the gym today?W:I will join tomorrow,and then I will go every single day.I will,I really will.M:Rosie,you’ve been saying that for months,but you never actually do it.W:This time I will.I promise.M:That’s what you always say.Text7W:Oh,I feel so relieved.I just resigned.M:You what?W:You know the old saying?The last straw that breaks the camel’s back.M:Tell me what happened.W:This morning I was just busy with a billing report,then my boss,Fargo asked me to buy him some black coffee first.After that,he said he would fine me for I still hadn’t finished the billing report.You know what?He just gave me this“billing report job”two hours ago!And I had to buy him coffee first.浙江省名校新高考研究联盟2018届第二次联考英语参考答案第2页共3页M:So you quit?W:Yeah,I quit.I told him:“To hell with you!I quit!”Text8M:How about we drink another round and then call it a night?W:Sure.I’ll have beer this time.M:OK.How was your date the other night anyway?W:Great!Jim’s a nice guy.We had a wonderful meal and then went to the cinema together.He’s got a cool job—a television producer,you know.He’s been doing those nature documentaries and always travelling around the world to get good materials.M:Sounds impressive.So,you think it might get serious this time?W:I think he’s marriage material.We’ll see how it goes.Text9M:Robin,why are you looking so miserable?W:Well,I’ve got problems…financial problems.W:I’m sorry to hear that.What’s happened?M:Well,I had to get my car fixed,I had to get an engineer round to fix my broken TV,I received a huge tax bill and then to add to it all,I lost my wallet yesterday!W:Oh,poor you.So what are you going to do?M:Well I need to ask a good friend to lend me some money.W:You want to borrow some money?You’ll need to find a really good friend then.M:Yes,a really good friend—like you?I know you’ve got some spare cash.W:Sorry,Robin,I’ve just spent that on a really nice holiday.But I can recommend a good part-time job.It’s my friend,John,he said he needed a trustworthy man to help him take charge of the library at night.I’ll ask him to give you some cash in advance if you work there.M:Great!Now I’m just worried where I can get some nice food to stuff my poor empty stomach…W:Oh,come on!Just come to my house tonight.I’ll cook for you.M:It’s so nice of you,Abi.Text10M:A whale-watching boat sank off Vancouver Island,Canada on Oct.25,2015,causing five Britons killed, and one Australian remained missing.The boat sank on Sunday near Tofino,British Columbia,with27people on board.The accident sparked a rescue effort by the Canadian military,Coast Guard,and local fishermen.The Joint Rescue Coordination Center said of the21people who were rescued,most were taken to hospitals.One person was in serious condition,but stable.The boat,called Leviathan II,was owned by a company called Jamie’s Whaling Station and Adventure Centers.It was65feet long and had three decks.The company’s spokesperson said that the Leviathan II had been operating normally on a route it had followed for the past20years.She could not say what caused the boat to sink.It happened so fast that the crew members were unable to radio for help.The company takes tourists on boats for several hours around Vancouver Island to see Pacific Gray whales and humpback whales.There whale-watching trips usually last two to three hours.浙江省名校新高考研究联盟2018届第二次联考英语参考答案第3页共3页。

浙江名校新高考研究联盟2018届高三第二次联考物理试题一、选择题I1. 下列物理量中属于标量的是A. 向心加速度B. 电场强度C. 电势D. 磁感应强度【答案】C【解析】向心加速度、电场强度、磁感应强度都既有大小又有方向，故为矢量，电势只有大小没有方向，为标量，故C正确．2. 春运是中国在农历春节前后出现的一种大规模的交通运输高压力现象。

某同学买了北京西到贵阳北的高铁票，如图所示，从铁路售票网查询到该趟车历时8小时46分钟，行程为2026公里，则下列说法正确的是A. 图中08：55表示一段时间B. 该列车高速行驶时，可以取10 m位移的平均速度近似看作这10m起点位置处的瞬时速度C. 该趟列车全程的平均速度为231km/hD. 该趟列车的最高速度为231km/h【答案】B【解析】08：55表示出发时间，表示动作的发生，为时刻，A错误；高速运动时，速度很大，10m 所用的时间很短，故这10m内的平均速度可看做为这10m起点位置处的瞬时速度，B正确；全程的路程为，全程所用时间为8小时46分钟，即，求出的是平均速率，由于不知道位移，所以不能求解平均速度，根据题意不知道列车的最高速度，CD错误．3. 在物理学发展的过程中，许多物理学家的科学研究推动了人类文明的进程.在以下几位物理学家所做科学贡献的叙述中，正确的是A. 牛顿应用“理想斜面实验”推翻了亚里士多德关于“力是维持物体运动的原因”的观点，并纳总结了牛顿第一定律B. 法拉第不仅提出了场的概念，而且采用电场线来直观地描绘了电场C. 卡文迪许将行星与太阳、地球与月球、地球与地面物体之间的引力规律推广到宇宙中的一切物体，得出万有引力定律，并测出了引力常量G 的数值D. 能量守恒定律是最普遍的自然规律之一，英国物理学家牛顿对能量守恒定律的建立作出了突出贡献【答案】B【解析】伽利略通过理想斜面实验推翻了亚里士多德的观点，牛顿总结了牛顿第一定律，A错误；法拉第首次提出了场的概念，并用电场线直观的描述了电场，B正确；牛顿发现了万有引力定律，而卡文迪许测量了引力常量G，C错误；能量守恒定律是最普遍的自然规律之一，英国物理学家焦耳对能量守恒定律的建立作出了突出贡献，D错误．4. 2016年8月12 日，在里约奥运会乒乓球男子单打决赛中，中国名将马龙4-0战胜对手，夺得冠军，首次拿下大满贯。

7．化学与生活、生产、可持续发展密切相关，下列说法正确的是A．14C可用于文物年代的鉴定，14C和12C互为同素异形体B．在日常生活中，化学腐蚀是造成钢铁腐蚀的主要原因C．现代工业生产中芳香烃主要来源于石油化工的催化重整和煤的干馏D．高纯度的SiO2可以制成光电池将光能直接转换为化学能8．设N A为阿伏加德罗常数的值，下列叙述错误的是A．分子总数为N A的SO2和CO2的混合气体中含有的氧原子数为2N AB．0.1mol/L(NH4)2SO4溶液与0.2mol/LNH4Cl溶液中的NH4+数目相同C．标准状况下，H2和CO混合气体8.96L在足量O2中充分燃烧消耗O2分子数为0.2N AD．1molNa与足量O2反应生成了混合物，Na失去N A个电子9．青霉素是最重要的抗生素，其在体内经酸性水解后得到一种有机物X。

已知X的结构如列有关X的说法正确的是A．X为烃的含氧衍生物B．X的分子式为C5H10NO2SC．X只能发生取代反应D．X中碳原子上的H若有1个被Cl取代，有2种不同产物10．向盛有不同试剂的试管b中分别滴加适量0.1mol/L FeCl3溶液，下列对b中现象及解释正确的是0.1mol/L11．“天宫一号”的供电系统中有再生氢氧燃料电池（RFC），RFC是一种将太阳能电池电解水技术与氢氧燃料电池技术相结合的可充电电池。

下图为RFC工作原理示意图（隔膜为质子选择性透过膜），下列说法中正确的是装置I 装置IIA．c极上发生的电极反应是：O2 + 4H+ + 4e- = 2H2OB．当有0.1mol电子转移时，b极产生1.12L 气体Y（标准状况下）C．装置I与装置II的电解质溶液中，氢离子运动方向相反D．RFC系统工作过程中只存在3种形式的能量转化12．X、Y、Z、W是原子序数依次增大的4种短周期主族元素，X、W均为所在周期数和族序数相等的元素，Y、Z易形成元素质量比为7:8和7:16的两种常见化合物。