罗伯特戈登大学石油和天然气工程硕士

化工进展Chemical Industry and Engineering Progress2023 年第 42 卷第 12 期含氮有机液体储放氢催化体系研究进展李佳豪1，杨锦2，潘伦1，钟勇斌2，王志敏2，王锦生2，张香文1，邹吉军1（1 天津大学化工学院，绿色合成与转化教育部重点实验室，天津 300072；2 东方电气集团东方锅炉股份有限公司，四川 成都 610000）摘要：氢能源作为重要的二次能源，能量密度大、环境友好且用途广泛，是人类战略能源发展的重要方向。

然而，氢气储运仍面临较大的成本和安全难题，有机液体储氢化合物（LOHCs ）储放氢技术以其储氢密度较高、储存条件温和、运输方便等优势成为氢气储运可供选择的技术之一。

相比稠环芳烃类化合物，含氮有机储氢化合物具有更温和的催化加氢和脱氢条件，可有效提高储放氢鲁棒性和反应能效。

基于此，本文系统综述了含氮有机储氢化合物加氢及脱氢反应研究进展，阐述了两类反应的路径和催化作用机制，从催化剂活性中心和载体、双金属协同效应、反应条件、催化剂稳定性等方面系统分析了加氢/脱氢催化剂，并详细总结了基于连串反应、反应网络等模型的反应动力学。

介绍了含氮有机储氢化合物储氢技术目前面临的挑战并提出未来的研究思路及展望。

但是该技术仍存在较多问题，应在有机储氢化合物配方体系、储放氢连续反应系统、催化剂设计与制备、催化剂构效关系、精准反应动力学和全面理化性质数据库等方面进行深入研究。

关键词：氢；含氮有机液体储氢化合物；反应机理；催化剂；反应动力学中图分类号：TK91 文献标志码：A 文章编号：1000-6613（2023）12-6325-20Research progress in catalytic system for hydrogen storage and releasefrom nitrogen-containing liquid organic carriersLI Jiahao 1，YANG Jin 2，PAN Lun 1，ZHONG Yongbin 2，WANG Zhimin 2，WANG Jinsheng 2，ZHANG Xiangwen 1，ZOU Jijun 1(1 Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering andTechnology, Tianjin University, Tianjin 300072, China; 2 DongFang Boiler Group Co., Ltd., Chengdu 610000, Sichuan, China)Abstract: As an important secondary energy, hydrogen is of high energy density, environmental friendliness and wide use, which is an important direction of human strategic energy development. However,hydrogen storage and transportation are still facing problems of high cost and safety. The hydrogen storage and release technology based on liquid organic hydrogen carriers (LOHCs) has become one of the available technologies with its advantages of relatively high hydrogen storage density, mild storage conditions and convenient transportation. Compared with polycyclic aromatic hydrocarbons, nitrogen-containing LOHCs is milder in catalytic hydrogenation and dehydrogenation, which can effectively improve the robustness of hydrogen storage and release and the reaction efficiency. Based on this, this paper systematically reviewed综述与专论DOI ：10.16085/j.issn.1000-6613.2023-0089收稿日期：2023-01-19；修改稿日期：2023-04-11。

文章编号：1008 − 8857(2018)03 − 0132 − 04DOI: 10.13259/ki.eri.2018.03.002我国太阳能有机朗肯循环研究现状朱正良，张 华（上海理工大学 能源与动力工程学院，上海 200093）摘　要：太阳能具有易转化为低温热源的特性，而有机朗肯循环是利用低温热源或工业余热发电的理想方式，两者相结合形成基于太阳能的有机朗肯循环发电技术。

综述了我国光热太阳能发电技术和市场现状以及针对有机朗肯循环的研究现状。

经分析发现，目前研究中理论分析或计算机模拟较多，缺乏实际应用的验证。

论述了有机朗肯循环工质的选择、循环性能分析方法以及所面临的问题和改善方法。

关键词：太阳能；有机朗肯循环；发电中图分类号：TK11+5 文献标志码：AResearch status of solar organic Rankine cycle in ChinaZHU Zhengliang，ZHANG Hua(School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China)Abstract：Solar energy can be easily changed into the low temperature heat source. And organic Rankine cycle is an ideal way for the electricity generation from the low temperature heat source or industrial waste. Combination of these could form solar organic Rankine cycle power generation technology. The technologies of concentrating solar power, current situation of its market and the research status of organic Rankine cycle were summarized in this paper. It could be found that most of studies focused on theoretical analysis and numerical simulation, which lacked the validation of the practical application. The selection of working medium, methods for the cycle performance analysis, problems it faced and their improvement methods, were discussed in this paper as well. Keywords：solar; organic Rankine cycle; power generation随着石油、煤炭、天然气等化石能源迅速消耗，太阳能作为一种可再生的清洁能源，其开发利用已经受到世界各国的普遍关注。

XX年罗伯特戈登大学本科生和研究生奖学金罗伯特戈登大学(Robert Gordon University )位于苏格兰阿伯丁地区，是英国一所一流的综合性大学。

学校目前有三个学院：阿伯丁商学院、社会卫生学院和设计技术学院，有140多门学位课程供学生学习。

每年招生留学生。

罗伯特戈登大学在本科和研究生阶段均为留学生提供奖学金，种类颇多，金额丰厚。

具体的奖学金内容请看出guo下面的介绍。

Robert Gordon University ScholarshipsRobert Gordon University offers scholarships to full-time, on-campus International students and full fee paying students from the rest of the United Kingdom outside of Scotland (RUK students).The scholarships are available on a wide range of undergraduate and postgraduate courses.The maximum total amount of scholarships available to an individual student will be ?3,000 for students from an approved Partner Institution and ?2,500 for direct entry students.罗伯特戈登大学为学习全日制校内课程的国际生和苏格兰以外英国地区的支付全额学费的学生提供奖学金。

罗伯特戈登大学的奖学金在众多本科课程和研究生课程中都适用。

对于得到批准的伙伴机构的学生，罗伯特戈登大学为其提供的单个奖学金的最大金额为3000英镑;对于直接入学的学生，学校为其提供的单个奖学金的最大金额为2500英镑。

6.研究了西北地区某油田地表沙样的光学响应，利用单位厚度太赫兹幅值衰减系数得到了采样区域内油藏和气藏的太赫兹响应分布，以此作为该区域内有机质分布预测的依据，获得了钻井位置的分布。

该结果与已钻井位置基本符合，具有很高的准确率。

关键词：油气储层；光学新方法；光谱分析技术；油气光学Potential evaluation of oil-gas reservoir based on new opticalmethodsABSTRACTWith the development of economic soial and energy industrial, traditional oil and gas resources are becoming increasingly missing. On one hand, the potential evaluation is necessary for the petroleum that has been found, thus scientific measures will be taken to exploit the oil-gas. On the other hand, the potential evaluation is also necessary for the unknown block so that the correct theory will be used to guide exploration practice. Consequently, both practical and economic methods should be developed by the researchers to enrich the theoretical system of oil-gas exploration. Optical techniques have the characteristics of non-contact, low-cost and insensitivity to the geomagnetic and geoelectric fields. In this report, new optical methods including terahertz (THz) spectroscopy and oblique-incidence reflectivity difference (OIRD), which are rapidly developed in recent years, are employed to evaluate the oil-gas reservoir especially the unconventional reservoirs. Meanwhile, spectrum analysis methods are also developed for the sake of the optical application. The theoretical system is preliminarily formed for the optical characterization and evaluation of oil and gas.1.According to the response characteristics of oil-gas in optics, a series of spectrum methods are developed and gradually optimized which include linear regression, principal component analysis, cluster analysis, artificial neural networks, support vector machine and two-dimensional correlation spectroscopy. These methods are then applied in oil-gas detection, atmospheric pollution monitoring and urban livelihood areas. The related program and software are also finished. The basic principles and practical applications of these methods are written in a book called “The Spectrum Analysis Method of Terahertz spectroscopy” pressed by Sc ience Press.2.Carbonates and carbonate rocks are investigated by using THz spectroscopy. Results show that carbonates have different absorption features in THz range, which isthe base of reservoir evaluation. Meanwhile, for a general chemical reaction in geological evolution, the refractive indes spectra validate a common conservation relation that the average index of the reactants equal those of the products in the whole range. The results prove that atomic rearrangement process has different influence on the absorption and refractive response in THz range.3.The shape effect of micro-pore is investigated by using THz spectroscopy and relative spectrum analysis methods. The utilization of spectrum analysis methods can improve the imaging resolution from 150 μm to 20 μm. Therefore, spectrum analysis methods can extract the hidden information in the spectroscopy of optical parameters.4.THz spectroscopy is employed to investigate the absorption dynamics of water in porous active carbon. In the early diffusion stage, the optica parameters do not change; when absorption begins, THz parameters dramatically change until the end of adsorption. Consequently, THz spectroscopy can not only monitor the absorption dynamics, but also accurately determine the starting point, inflection and absorption rate in whole process.5.The surface properties of dense cores are investigated by using the OIRD technique. We discuss the dielectric distribution and observe that the shale has distinct texture or anisotropic characteristics and sandstone has isotropic properties. By the combination of optical microscope and scanning electron microscope, the micro-cracks and mineral distribution can be detected within the rocks. Therefore, OIRD is a very promising and practical technology for detecting the isotropy and anisotropy in rock and is a convenient supplementary technique for conventional methods.6.The optical response of surface sediment samples in an oil field in northwest China are studied by using THz spectroscopy. The amplitude attenuation coefficients per thickness are calculated and used for the distribution of THz resonse of oil and gas reservoirs in sampling areas. The above parameter is used as a basis to predict the distribution of organic matter, and the disbution of drilling locations is then obtained. The results are in agreement with the actual drilling and reflect high accuracy.Key Words：Oil-gas reservoir；Optical methods；Spectral analysis techniques；Oil-gas optics创新点1．油气储层的光学表征原理有别于常规测试分析方法。

英国罗伯特戈登大学硕士申请条件及其介绍英国罗伯特戈登大学硕士申请条件及其介绍英国罗伯特戈登大学硕士申请条件1、大学本科毕业，获得本科学位证，其中“211大学”平均分需达70分以上，非211大学平均分需达80分以上;2、大专毕业的学生平均分需达80分以上，且需要先完成一年的研究生预备课程或研究生文凭课程;3、拥有自考本科学位、且有2-3年相关领域全职工作经历的学生只可选择一门研究生专业;4、托福网考：90分，其中听力不低于17分，阅读不低于18分，口语不低于20分，写作不低于24分;或雅思：6.5，单项不低于6.5分;或者培生英语考试不低于61分，单项不低于61分;有些专业要求更高;5、有双录取。

英国罗伯特戈登大学介绍1750年，一位来自阿伯丁名叫罗伯特哥顿的富商出资创立了罗伯特哥顿医院，从那时起，罗伯特哥顿大学的历史就开场了。

罗伯特哥顿医院在1881年开展成为一所学院，在1903年它又开展成为罗伯特哥顿工学院，1965年，它成为罗伯特哥顿技术学院。

1992年，它正式被授予大学称号。

罗伯特哥顿大学位于英国苏格兰东北部的城市阿伯丁。

阿伯丁是苏格兰的第三大城市，以其散落在城市各处的由花岗岩建成古老建筑而著称。

这个城市拥有大约250，000人口，因为阿伯丁是北海近海石油和天然气工业的商业和技术中心，因此赢得“欧洲石油之都”的称号。

英国罗伯特戈登大学学校声誉事实上，罗伯特戈登大学的真正实力在于它和工业及其他行业的'亲密合作，尤其是课程的内容和设计。

此外，在实用研究方面越来越好的声誉和公认的技术转换才能使罗伯特·戈登大学日益成为一所可以迅速对工商业开展需要做出反响，充满活力的学院。

虽然罗伯特戈登作为大学还很年轻，但是其教育血统却可以追溯到250年前。

药剂学院(The School of Pharmacy)是英国历史最悠久的大学，并被国际卫生组织认定为下属单位。

格雷艺术学院(Gray's School of Art)有120多年的历史，并因培养出了多位苏格兰非常优秀的的艺术家而享有盛誉。

CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2017年第36卷第5期·1658·化 工 进展乙酸蒸汽催化重整制氢的研究进展王东旭1，肖显斌2，李文艳1（1华北电力大学能源动力与机械工程学院，北京 102206；2华北电力大学生物质发电成套设备国家工程实验室，北京 102206）摘要：通过生物油蒸汽重整制备氢气可以减少环境污染，降低对化石燃料的依赖，是一种极具潜力的制氢途径。

乙酸是生物油的主要成分之一，常作为模型化合物进行研究。

镍基催化剂是乙酸蒸汽重整过程中常用的催化剂，但容易因积炭失去活性，降低了制氢过程的经济性。

本文首先分析了影响乙酸蒸汽重整制氢过程的各种因素，阐述了在这一过程中镍基催化剂的积炭原理，讨论了优化镍基催化剂的方法，包括优化催化剂的预处理过程、添加助剂和选择合适的载体，最后对乙酸蒸汽重整制氢的热力学分析研究进展进行了总结。

未来应重点研究多种助剂复合使用时对镍基催化剂积炭与活性的影响，分析多种助剂的协同作用机理，得到一种高活性、高抗积炭能力的用于生物油蒸汽重整制氢的镍基催化剂。

关键词：生物油；乙酸；制氢；催化剂；热力学中图分类号：TK6 文献标志码：A 文章编号：1000–6613（2017）05–1658–08 DOI ：10.16085/j.issn.1000-6613.2017.05.014A review of literatures on catalytic steam reforming of acetic acid forhydrogen productionWANG Dongxu 1，XIAO Xianbin 2，LI Wenyan 1（1 School of Energy ，Power and Mechanical Engineering ，North China Electric Power University ，Beijing 102206，China ；2 National Engineering Laboratory for Biomass Power Generation Equipment ，North China Electric PowerUniversity ，Beijing 102206，China ）Abstract ：Hydrogen production via steam reforming of bio-oil ，a potential way to produce hydrogen ， can reduce environmental pollution and dependence on fossil fuels. Acetic acid is one of the main components of bio-oil and is often selected as a model compound. Nickel-based catalyst is widely used in the steam reforming of acetic acid ，but it deactivates fast due to the carbon deposition. In this paper ，the affecting factors for the steam reforming of acetic acid are analyzed. The coking mechanism of nickel-based catalyst in this process is illustrated. Optimization methods for nickel-baed catalyst are discussed ，including optimizing the pretreatment process ，adding promoters ，and choosing appropriate catalyst supports. Research progresses in the thermodynamics analyses for steaming reforming of acetic acid are summarized. Further studies should be focused on the effects of a combination of a variety of promoters on carbon deposition. Catalytic activity and the synergy mechanism should be analyzed to produce a novel nickel-based catalyst with high activity ，high resistance to caborn deposition for hydrogen production via steam reforming of bio-oil. Key words ：bio-oil ；acetic acid ；hydrogen production ；catalyst ；thermodynamics第一作者：王东旭（1994—），男，硕士研究生，从事生物质能利用技术研究。

美国工程伦理教育评价研究胡文龙【摘要】重视培养工科生的伦理责任意识是美国工程教育在20世纪末发生的显著变化之一.随着越来越多的美国高校开设工程伦理课程,如何评价工程伦理教育效果就成为美国工程教育界关注的一个话题.在简要分析美国工程伦理教育目标的基础上,对3个具有代表性的工程伦理教育评价工具和研究方法进行了详细阐述,指出美国工程伦理教育评价具有重视评价学生伦理推理能力、综合运用定量和定性评价方法、重视评价主体和评价环境的多元性等特点,并对中国工程教育中如何开展工科生"软素质"教育和评价工作提出了建议.【期刊名称】《北京航空航天大学学报（社会科学版）》【年(卷),期】2011(024)006【总页数】6页(P102-107)【关键词】工程伦理教育;科罗拉多矿业学院工程伦理评价量表;工程与科学问题测验【作者】胡文龙【作者单位】北京航空航天大学,高等教育研究所,北京,100191【正文语种】中文【中图分类】G40-058.1美国工程教育在20世纪末发生的显著变化之一就是越来越多的学校开始重视培养工科生的伦理意识和社会责任感。

［1］据 Laych 1997年的报告，美国排名前10位的工程院校各以不同方式在本科教育中引入了工程伦理教育。

［2］这种变化根本上源于社会各界对于科技活动和工程实践活动对自然环境和社会环境负面影响的认识，直接动力则来自于ABET EC2000标准的变化:它增加了对工科生在伦理责任和理解伦理问题方面的要求。

为了适应ABET新标准的要求，越来越多的美国高校通过各种方式开展了工程伦理教育，工程伦理教育甚至已经被认为是工程教育必可不少的元素之一。

［3］随着工程伦理教育的广泛开展，由此引发的一个问题就是工程伦理教育实施的效果到底如何，这也是美国工程教育界比较关注的话题之一。

在过去的时间里，工程教育在如何评价工科生“硬”技能方面的研究取得了较大进步，但在如何评价工科生“软”素质如职业道德状况等方面却相对比较滞后，缺乏成熟的评价工具和评价手段。

·M701F4杨基发(广东粤电大亚湾综合能源有限公司,广东惠州,516000)摘要:M701F4型燃气-蒸汽联合循环分轴机组热态启动时间相对偏长,受国际天然气市场及电力市场改革等多种因素影响[1],两班制运行机组较连续运行机组经济性相对较差[2]。

文章主要概述了通过优化燃气-蒸汽联合循环热态启动升负荷速率,缩短了M701F4燃气轮机机组热态启动时间,提高了两班制运行联合循环机组的经济性,优化后每年可节省启动成本约268.3万元。

关键词:联合循环,汽轮机,启动成本,节能中图分类号:TK262文献标识码:B文章编号:1674-9987(2023)04-0076-04 Study on Load-raising Rate Optimization of M701F4Gas-steam Combined Cycle During Hot Start-up再ANG Jifa(Guangdong Yudean Dayabay Comprehensive Energy Co.,Ltd.,Huizhou Guangdong,516000)Abstract:The hot start-up time of M701F4gas-steam combined cycle unit is relatively long,which is affected by many factors such as the reform of international natural gas market and power market,the economy of two-shift operation units is relatively poor compared with continuous operation units.In this paper,by optimizing the load-raising rate of the gas-steam combined cycle,the hot start-up time of the M701F4gas turbine unit is shortened,and the economy of the two-shift combined cycle unit is improved, after optimization,the annual start-up cost can be saved about2.683million yuan.Key words:combined cycle,steam turbine,start-up cost,energy saving第一作者简介:杨基发(1991-),男,本科,工程师,毕业于中山大学,燃气轮机运行值班员技师,主要研究运行节能降耗及运行管理工作。