锆化液MSDS

锆化合物名称分子式Zr(OH)4ZrOCl2ZrO2ZrCl4 ZrF4 ZrC乙酰丙酮锆C20H28O8Zr 六氟乙酰丙酮锆三氟乙酰丙酮锆C20H16F12O8Zr正丙醇锆Zr(OC3H7)4正丙醇锆（约70%的正丙醇溶液）正丁醇锆Zr(OC4H9)4叔丁醇锆Zr(OC4H9)4正丁醇锆（约80%的正丁醇溶液）异丙醇锆异辛酸锆异丙氧基异丙醇锆Cp2ZrCl2 双环戊二烯基二氯化锆C10H11ClZrCp2Zr(H)Cl双环戊二烯基氯化锆氢化物C10H10Cl2Zr双环戊二烯基二甲基锆(C5H5)2Zr(CH3)2双环戊二烯二氢化锆C10H12Zr双（正丁基环戊二烯基）二氯化锆[(C4H9)C5H4]2ZrCl2双（乙基环戊二烯基）二氯化锆[(C2H5)C5H4]2ZrCl2双（五甲基环戊二烯）二氯化锆[(CH3)5C5]2ZrCl2双（异丙基环戊二烯）二氯化锆[(C3H7)C5H4]2ZrCl2双（四甲基环戊二烯基）二氯化锆[(CH3)4C5H]2ZrCl2正丁基环戊二烯三氯化锆[(C4H9)C5H4]ZrCl3环戊二烯基三氯化锆(C5H5)ZrCl3二甲基双（叔丁基环戊二烯基）锆[(C4H9)C5H4]2Zr(CH3)2二甲基双（环戊二烯基）硅基二氯化锆[(CH3)2Si(C5H4)2]ZrCl2二丁基二茂二氯化锆C18H26Cl2Zr异亚丙基二氯化二茂锆C13H14Cl2Zr五甲基环戊二烯基三氯化锆(CH3)5C5ZrCl3二茚基二氯化锆(C9H7)2ZrCl2双（茚基）二甲基锆(C9H7)2Zr(CH3)2二甲基硅基双（1-茚基）二氯化锆(CH3)2Si(C9H6)2ZrCl2双（2-甲基茚基）二氯化锆[(CH3)C9H6]2ZrCl2四（二甲基氨基）锆Zr[N(CH3)2]4四（乙基甲基胺基）锆Zr[N(CH3)(CH2CH3)]4四氯双（四氢呋喃）合锆ZrCl4.C4H8O四水合硫酸锆Zr(SO4)2.4H2O四乙氧基锆Zr(OC2H5)4八水合二氯氧化锆ZrOCl2.8H2O水合硝酸氧锆ZrO(NO3)2.H2O锆酸铅PbZrO3 锆酸锂Li2ZrO3 锆酸钙CaZrO3锆酸钡BaZrO3酸性硫酸锆ZrO(OH)0.8(SO4)0.6.H2O 磷酸锆Zr(HPO4)2溴化锆ZrBr4氟化锆ZrF4碘化锆ZrI4硫化锆ZrS2 氮化锆ZrN 锆氟酸钾F6K2Zr 锆酸四丁酯C16H36O4Zr 硅酸锆ZrSiO4。

第1部分化学品及企业标识化学品中文名：倍化学品英文名：ZirconiumCAS#：7440-67-7分子式：Zr分子量：91.22产品推荐及限制用途：工业及科研用途。

第2部分危险性概述紧急情况概述：暴露在空气中会自燃。

遇水放出可自燃的易燃气体。

GHS危险性类别：自燃固体类别1遇水放出易燃气体的物质和混合物类别1标签要素：象形图：Xz警示词：危险危险性说明：H250暴露在空气中会自燃H260遇水放出可自燃的易燃气体防范说明：•预防措施：——P210远离热源/火花/明火/热表面。

禁止吸烟。

——P222不得与空气接触。

——P231+P232在惰性气体中操作。

防潮。

——P233保持容器密闭。

——P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

——P223不得与水接触。

•事故响应：——P370+P378火灾时：使用灭火器灭火。

•安全储存：——P402+P404存放于干燥处。

存放于密闭的容器中。

•废弃处置：——P501按当地法规处置内装物/容器。

物理和化学危险：暴露在空气中会自燃。

遇水放出可自燃的易燃气体。

健康危害：无资料环境危害：无资料第3部分成分/组成信息CASNo.组分第4部分急救措施急救：吸入：迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

呼吸、心跳停止，立即进行心肺复苏术。

就医皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。

如有不适感，就医吸入：迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

呼吸、心跳停止，立即进行心肺复苏术。

就医眼睛接触：分开眼睑，用流动清水或生理盐水冲洗。

如有不适感，就医眼晴接触：先用大量水冲洗儿分钟（如可能易行，摘除隐形眼镜），然后就医。

食入：用水漱口，催吐。

就医对保护施救者的忠告：将患者转移到安全的场所。

咨询医生。

出示此化学品安全技术说明书给到现场的医生看。

对医生的特别提示：无资料第5部分消防措施灭火剂：用水雾、干粉、泡沫或二氧化碳灭火剂灭火。

MATERIAL SAFETY DATA SHEETZIRCON SAND PRODUCTS1.IDENTIFICATION OF THE MATERIALProduct identification / Product NamesZircon sandRecommended use raw material for steelmaking refractories, glassmaking refractories, traditional ceramics, zircoium manufacture, zirconium manufacture, glass additive and foundry uses.2.HAZARDS IDENTIFICATIONRisk Phrases (R-Phrases) NoneSafety Phrases (S-Phrases) NoneClass and Subsidiary Risk None allocatedHazchem Code None allocatedPoisons Schedule None allocatedPotential Health EffectsAcuteSwallowed Non-toxic. There are no known hazards resulting from accidental ingestion of zircon sand as may occur during normal handling. Swallowing a large amountmay result in irritation to the digestive system due to abrasiveness.Eye the zircon grains and dust can be moderately irritating due to abrasiveness. Skin Low HazardInhaled the normal grain size of the product precludes from being an inhalation hazard, however handing of bulk materials may generate some dust. This isnormally regarded as general nuisance dust, but can be irritating if inhaledat high concentration. May cause symptoms such as coughing or sneezing. ChronicSilica crystalline silica is a known cause of lung fibrosis (silicosis). It has been classified as a human carcinogen. (IARC). Zircon sand contains a smallamount of free quartz, (up to 0.5%) and precautions should be taken toavoid inhaling the dust.Radiation zircon contains naturally occurring radioactive elements of the uranium and thorium series. The zircon sands produced by ILUKA Resources containlow concentrations of these impurities, with typical specific activities of 0.6 to1.2 Bq/gm (thorium 223) and to 1.5 to 4.5 Bq/gm (uranium -238). Daughterproducts are present typically at equilibrium concentrations. The mainradiological hazard is internal exposure to alpha particles from inhaled dust.Suitable dust control shall be employed to ensure occupational exposure togenerated dust and alpha particles are kept as low as reasonable achievable.As a guide, continuous worker exposure to respirable dust levels above1.5mg/,3 could give rise to annual internal exposures above 1mSv. Externalexposure is from gamma radiation. Continuous exposure (2000 hours per year)annual external dose above 1 mSV.POSTIION /INFORMATION ON INGREDENTSIngredient (typical) CAS Number Weight %Zircon 14940-68-2 95-99%Kyanite 149040-68-2 0.1-4%Quartz 14808-60-7 0.05-0.5%Rutile 1317-80-2 0.1-0.2%Leucoxene /ilmenite 103170-28-1 0.1-0.2%Monazite approx 0. 0.2%4.FIRST AID MEASURESSwallowed First aid is unlikely to be required, but if necessary wash mouth out with water ensuring the mouthwash is not swallowed. Seek medical attention as aprecaution if discomfort occurs.Eye Hold eyelid open and flush with plenty of clean water. Continue for at least 15 minutes or until grit is removed. Seek medical attention if soreness or irritationpersists.Skin Gently remove contaiminated clothing to avoid generatiing dust. wash material from the skin. If repeated contact result in skin irritation, seek medical advice.Launder clothing before re-use.Inhaled Move to fresh air. Blow nos to remove particulates from nasal passages. If anyadverse reaction develops, seek medical attention.First AidFacilities Eye wash facilitiesAdvice toPhysician Treat symptomatically5.FIRE FIGHTING MEASURESFlashpoint Not applicableFlammability Not applicableGeneral Hazard This product is not flammable and does not support combustion. Extinguishing Media Use media suitable for the material that is burning.6.ACCIDENTAL RELEASE MEASURESSpills andDisposal Wear safety equipment as for normal handling. Avoid generating dust.Vacuum up if possible. Otherwise sweep up and re-cycle. If the spilledProduct is not suitable for re-use, damp down, collect and where possibleReturn to manufacture for reprocessing. Any disposal to an approved landfillSite and cover with clean fill shall be conducted in accordance with state/localCouncil regulations.7.HANDLING AND STORAGEHandling Avoid breathing dust, suitable dust controls should be utilized when handling Bulk materials. Wash thoroughly after handling if handling respirable flourIt is adviseable to also gloves and wash hands before eating, drink or smokingTo minimize inhalation or ingestion from hands.Storage Storage areas should be ventilated and dust generation minimized when Handling.8.EXPOSURE CONTROLS /PERSONAL PROTECTIONExposureStandards Dust TWA – 10 mg/m3 (inhalable general nuisance dust)RadiationExposure 1 Occupational exposure should be as low as reasonable achievable, (ALARA Principle), but should not exceed a total 100 milli-seiverts over fiveconsecutive years. (ICRP). 1 Recommendation of the InternationalCommission on Radiological Protection, ICRP Publication 60, Annals of theICRP Vol 21, No 1-3 1991EngineeringControls Ventilation requirements will depend on handling methods and the amount in Use, but should be sufficient to maintain dust levels below exposure limits.Indoor points of dust generation such as conveyor and hopper dischargesShould be equipped with an effective extraction system.PersonalProtection Safety glasses with side shields or goggles. If risk of inhaling dust is present Wear, at minimum, a P1 personal respirator (disposable or cartridge type).9.PHYSICAL AND CHEMICAL PROPERTIESAppearance (Form) Off white to brownish free running sand, odorless and tasteless Chemical formula ZrO2.SiO2Melting point 2100 to 2300Vapour pressure not volatileEvaporation rate not volatileSpecific gravity 4.6 – 4.8Solubility in Water InsolublepH 5-7.5Bulk density 2700 – 2950 kg/m3Grain size AFS No 55-140, average grain size of 0.1 – 0.2mm10.STBILITY AND REACTIVITYReactivity InertChemical stability StableIncompatibilities None in normal or expected useDecomposition Decomposition will not occur11.TEXICOLOGICAL INFORMATIONThis product is no – toxic. Refer secion 2. Hazards Identification.12.ECOLOGICAL INFORMATIONThe material is unlikely to cause any environmental damage. It is insoluble in water and is unlikely to contaminate waterways or food chains.13.DISPOSAL CONSIDERATIONS.Disposal must be in accordance with Federal, State and Local Council regulations. If approved, may be transferred to an approved landfill site.Note: many states are developing new regulations for the disposal of wast containing Naturally Occurring Radioactive Materials (NORM) or Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) above background levels. Consult and comply with current regulations.14.TRANSPORT INFORMATIONTransport may be regulated in some countries, although the product is not generally regarded as a transport hazard. Not classified as radioactive pursuant to paragraph 107 of IAEA TS-R-1 regulations. Trucks should be covered when transporting dry bulk product to prevent dust generation.15.REGULATORY INFORMATIONEINECS No. Zircon 239-019-616.OTHER INFORMATIONLabelling Labelling not required according to EC-Dir. 67/548, as amended. Other informationDate of issue march 2010Replaces December 2008This MSDS is valid for five (5) years from the date of issue.AbbreviationsBq/gm Becquerel per gramIAEA International Atomic Energy AgencyIARC International Agency for Research on CancerICRP International Commission on Radiation ProtectionMg/m3 Milligram per cubic metreTLV Threshold Limit ValueTWA Time Weighted AverageEnd of MSDS。

MATERIAL SAFETY DATA SHEETZIRCON SAND PRODUCTS1.IDENTIFICATION OF THE MATERIALProduct identification / Product NamesZircon sandRecommended use raw material for steelmaking refractories, glassmaking refractories, traditional ceramics, zircoium manufacture, zirconium manufacture, glass additive and foundry uses.2.HAZARDS IDENTIFICATIONRisk Phrases (R-Phrases) NoneSafety Phrases (S-Phrases) NoneClass and Subsidiary Risk None allocatedHazchem Code None allocatedPoisons Schedule None allocatedPotential Health EffectsAcuteSwallowed Non-toxic. There are no known hazards resulting from accidental ingestion of zircon sand as may occur during normal handling. Swallowing a large amountmay result in irritation to the digestive system due to abrasiveness.Eye the zircon grains and dust can be moderately irritating due to abrasiveness. Skin Low HazardInhaled the normal grain size of the product precludes from being an inhalation hazard, however handing of bulk materials may generate some dust. This isnormally regarded as general nuisance dust, but can be irritating if inhaledat high concentration. May cause symptoms such as coughing or sneezing. ChronicSilica crystalline silica is a known cause of lung fibrosis (silicosis). It has been classified as a human carcinogen. (IARC). Zircon sand contains a smallamount of free quartz, (up to 0.5%) and precautions should be taken toavoid inhaling the dust.Radiation zircon contains naturally occurring radioactive elements of the uranium and thorium series. The zircon sands produced by ILUKA Resources containlow concentrations of these impurities, with typical specific activities of 0.6 to1.2 Bq/gm (thorium 223) and to 1.5 to 4.5 Bq/gm (uranium -238). Daughterproducts are present typically at equilibrium concentrations. The mainradiological hazard is internal exposure to alpha particles from inhaled dust.Suitable dust control shall be employed to ensure occupational exposure togenerated dust and alpha particles are kept as low as reasonable achievable.As a guide, continuous worker exposure to respirable dust levels above1.5mg/,3 could give rise to annual internal exposures above 1mSv. Externalexposure is from gamma radiation. Continuous exposure (2000 hours per year)annual external dose above 1 mSV.POSTIION /INFORMATION ON INGREDENTSIngredient (typical) CAS Number Weight %Zircon 14940-68-2 95-99%Kyanite 149040-68-2 0.1-4%Quartz 14808-60-7 0.05-0.5%Rutile 1317-80-2 0.1-0.2%Leucoxene /ilmenite 103170-28-1 0.1-0.2%Monazite approx 0. 0.2%4.FIRST AID MEASURESSwallowed First aid is unlikely to be required, but if necessary wash mouth out with water ensuring the mouthwash is not swallowed. Seek medical attention as aprecaution if discomfort occurs.Eye Hold eyelid open and flush with plenty of clean water. Continue for at least 15 minutes or until grit is removed. Seek medical attention if soreness or irritationpersists.Skin Gently remove contaiminated clothing to avoid generatiing dust. wash material from the skin. If repeated contact result in skin irritation, seek medical advice.Launder clothing before re-use.Inhaled Move to fresh air. Blow nos to remove particulates from nasal passages. If anyadverse reaction develops, seek medical attention.First AidFacilities Eye wash facilitiesAdvice toPhysician Treat symptomatically5.FIRE FIGHTING MEASURESFlashpoint Not applicableFlammability Not applicableGeneral Hazard This product is not flammable and does not support combustion. Extinguishing Media Use media suitable for the material that is burning.6.ACCIDENTAL RELEASE MEASURESSpills andDisposal Wear safety equipment as for normal handling. Avoid generating dust.Vacuum up if possible. Otherwise sweep up and re-cycle. If the spilledProduct is not suitable for re-use, damp down, collect and where possibleReturn to manufacture for reprocessing. Any disposal to an approved landfillSite and cover with clean fill shall be conducted in accordance with state/localCouncil regulations.7.HANDLING AND STORAGEHandling Avoid breathing dust, suitable dust controls should be utilized when handling Bulk materials. Wash thoroughly after handling if handling respirable flourIt is adviseable to also gloves and wash hands before eating, drink or smokingTo minimize inhalation or ingestion from hands.Storage Storage areas should be ventilated and dust generation minimized when Handling.8.EXPOSURE CONTROLS /PERSONAL PROTECTIONExposureStandards Dust TWA – 10 mg/m3 (inhalable general nuisance dust)RadiationExposure 1 Occupational exposure should be as low as reasonable achievable, (ALARA Principle), but should not exceed a total 100 milli-seiverts over fiveconsecutive years. (ICRP). 1 Recommendation of the InternationalCommission on Radiological Protection, ICRP Publication 60, Annals of theICRP Vol 21, No 1-3 1991EngineeringControls Ventilation requirements will depend on handling methods and the amount in Use, but should be sufficient to maintain dust levels below exposure limits.Indoor points of dust generation such as conveyor and hopper dischargesShould be equipped with an effective extraction system.PersonalProtection Safety glasses with side shields or goggles. If risk of inhaling dust is present Wear, at minimum, a P1 personal respirator (disposable or cartridge type).9.PHYSICAL AND CHEMICAL PROPERTIESAppearance (Form) Off white to brownish free running sand, odorless and tasteless Chemical formula ZrO2.SiO2Melting point 2100 to 2300Vapour pressure not volatileEvaporation rate not volatileSpecific gravity 4.6 – 4.8Solubility in Water InsolublepH 5-7.5Bulk density 2700 – 2950 kg/m3Grain size AFS No 55-140, average grain size of 0.1 – 0.2mm10.STBILITY AND REACTIVITYReactivity InertChemical stability StableIncompatibilities None in normal or expected useDecomposition Decomposition will not occur11.TEXICOLOGICAL INFORMATIONThis product is no – toxic. Refer secion 2. Hazards Identification.12.ECOLOGICAL INFORMATIONThe material is unlikely to cause any environmental damage. It is insoluble in water and is unlikely to contaminate waterways or food chains.13.DISPOSAL CONSIDERATIONS.Disposal must be in accordance with Federal, State and Local Council regulations. If approved, may be transferred to an approved landfill site.Note: many states are developing new regulations for the disposal of wast containing Naturally Occurring Radioactive Materials (NORM) or Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) above background levels. Consult and comply with current regulations.14.TRANSPORT INFORMATIONTransport may be regulated in some countries, although the product is not generally regarded as a transport hazard. Not classified as radioactive pursuant to paragraph 107 of IAEA TS-R-1 regulations. Trucks should be covered when transporting dry bulk product to prevent dust generation.15.REGULATORY INFORMATIONEINECS No. Zircon 239-019-616.OTHER INFORMATIONLabelling Labelling not required according to EC-Dir. 67/548, as amended. Other informationDate of issue march 2010Replaces December 2008This MSDS is valid for five (5) years from the date of issue.AbbreviationsBq/gm Becquerel per gramIAEA International Atomic Energy AgencyIARC International Agency for Research on CancerICRP International Commission on Radiation ProtectionMg/m3 Milligram per cubic metreTLV Threshold Limit ValueTWA Time Weighted AverageEnd of MSDS。

MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (51)表1－050 酚醛树脂 (52)表1－051 硫磺粉(补充) (53)表1－052 一乙胺 (54)表1－053三聚氯氰 (55)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (60)表1－058 对氨基苯酚 (61)表1－059 醋酸乙酯 (62)表1－060 对氯硝基苯 (63)表1－061 氮气 (64)表1－062莠去津 (65)表1－063 扑草净 (66)表1－064 八氯二丙醚 (67)表1－065 硫化钠 (68)表１－066 异丙醇 (69)表１－067 丙酮 (70)表１－068 二氯丙烷 (71)表１－069 环己酮 (72)表１－070 乙酸异戊酯 (73)表1－071 锌粉 (74)表1－072 乙醇 (75)表1－073 次氯酸钠溶液 (76)表1－074 石脑油 (77)表1－075 双环戊二烯 (78)表1－076 乙酸丁酯 (79)表1－077 双氧水 (80)表1－078 丙烯酸丁酯 (81)表1－079 丙烯酸 (82)表1－080 苯乙烯 (83)表1－081 过硫酸铵 (84)表1－082 过硫酸钾 (85)表1－083 丙烯酰胺 (86)表1－084 甲醛 (87)表1－085 甲基丙烯酸甲酯 (88)表1－087 汽油 (90)表1－088 乙酸 (91)表1－089 丙烯酸树脂 (92)表1－090 丙烯酸清漆 (93)表1－091 丙烯酸漆稀释剂 (94)表1－092 丙烯酸磁漆 (95)表1－093 二乙醇胺 (97)表1－094 煤油 (98)表1－095 漂白粉 (99)表1－096 漂粉精 (100)表1－097 三氯异氰尿酸 (101)表1－098 松香 (102)表1－099 松节油 (103)表1－100 硫化钠 (104)表1－101 保险粉 (105)表1－102 7385聚氨酯清漆（分装） (106)表1－103 甲酸 (107)表1－104 乙酸乙二醇乙醚 (108)表1－105 H－3聚氨酯漆固化剂 (109)表1－106 聚氨酯漆稀释剂 (110)表1－107 263醇酸树脂 (111)表1－108 异噻唑啉酮 (112)表1－109 N-乙基苯胺 (113)表1－110苯胺 (114)表1－111 乙酰甲胺磷 (115)表1－112 亚磷酸 (117)表1－113 亚磷酸二甲酯 (118)表1－114 氯甲烷 (119)表1－115 乙醚 (120)表1－116 丙烯酸甲酯 (121)表1－117 一甲胺 (122)表1－118 硝酸镁 (123)表1－119 硫化氢 (124)表1－120 硫化铵 (125)表1－121 一甲胺水溶液 (126)表1－122 兔宝宝面漆 (127)表1－123 兔宝宝稀释剂 (128)表1－124 硫氢化钠 (129)表1－125丙酸 (130)表1－126乙酰氯 (131)表1－127丙酰氯 (132)表1－128 丁醇 (133)表1－129 醇酸调合漆（未列名） (134)表1－130 硝酸钠 (136)表1－131 溴甲烷 (137)表1－132 磷化铝 (138)表１－133 正丁醇 (139)表１－134 硝基木器漆 (140)表１－135 硝化棉（含氮≤12.6％） (141)表１－136 单丁醚 (142)表1－137 砷 (143)表1－138 碘化汞 (144)表1－139 氯化汞 (145)表1－140 叠氮化钠 (146)表1－141 重铬酸钠 (147)表1－142 高锰酸钾 (148)表1－143 氰化金钾 (149)表1－144丙烯酸 (150)表1－145甲基丙烯酸甲酯 (151)表1－146苯乙烯 (152)表1－147丙烯酸丁酯 (153)表1－148丁醇 (154)表1－149偶氮二异丁腈 (155)表1－150甲基丙烯酸异丁酯 (156)表1－151 甲基丙烯酸（正）丁酯 (157)表1－152 乙酰丙酮 (158)表1－153 2－丁酮 (160)表1－154 生松香 (161)表1－155 硫酸铜 (162)表1－155 硝酸 (163)表1－155 氰化钾 (164)表1－156硝基苯 (165)表1－157 氟化钠 (166)表1－158 氢氟酸 (167)表1－159蓄电池（注有酸液） (168)表1－160 环氧树脂 (169)表1－161 氯苯 (170)表1－162 乙苯 (171)表1－163 樟脑 (172)表1－164 赛璐珞 (173)表1-165 氢氧化钾 (174)表1-166 乙酸丁酯 (175)表1－001 乙炔气表1－002 氧气表1－003 二氧化碳表1－004 氢气表1－005 氩气表1－006 甲烷表1－007 四氢噻吩表1－008 活性炭活性炭 C 12.0Active carbon别名：Activated chlarcoal危规分类及编号：自燃物品。

MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (51)表1－050 酚醛树脂 (52)表1－051 硫磺粉(补充) (53)表1－052 一乙胺 (54)表1－053三聚氯氰 (55)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (60)表1－058 对氨基苯酚 (61)表1－059 醋酸乙酯 (62)表1－060 对氯硝基苯 (63)表1－061 氮气 (64)表1－062莠去津 (65)表1－063 扑草净 (66)表1－064 八氯二丙醚 (67)表1－065 硫化钠 (68)表１－066 异丙醇 (69)表１－067 丙酮 (70)表１－068 二氯丙烷 (71)表１－069 环己酮 (72)表１－070 乙酸异戊酯 (73)表1－071 锌粉 (74)表1－072 乙醇 (75)表1－073 次氯酸钠溶液 (76)表1－074 石脑油 (77)表1－075 双环戊二烯 (78)表1－076 乙酸丁酯 (79)表1－077 双氧水 (80)表1－078 丙烯酸丁酯 (81)表1－079 丙烯酸 (82)表1－080 苯乙烯 (83)表1－081 过硫酸铵 (84)表1－082 过硫酸钾 (85)表1－083 丙烯酰胺 (86)表1－084 甲醛 (87)表1－085 甲基丙烯酸甲酯 (88)表1－087 汽油 (90)表1－088 乙酸 (91)表1－089 丙烯酸树脂 (92)表1－090 丙烯酸清漆 (93)表1－091 丙烯酸漆稀释剂 (94)表1－092 丙烯酸磁漆 (95)表1－093 二乙醇胺 (97)表1－094 煤油 (98)表1－095 漂白粉 (99)表1－096 漂粉精 (100)表1－097 三氯异氰尿酸 (101)表1－098 松香 (102)表1－099 松节油 (103)表1－100 硫化钠 (104)表1－101 保险粉 (105)表1－102 7385聚氨酯清漆（分装） (106)表1－103 甲酸 (107)表1－104 乙酸乙二醇乙醚 (108)表1－105 H－3聚氨酯漆固化剂 (109)表1－106 聚氨酯漆稀释剂 (110)表1－107 263醇酸树脂 (111)表1－108 异噻唑啉酮 (112)表1－109 N-乙基苯胺 (113)表1－110苯胺 (114)表1－111 乙酰甲胺磷 (115)表1－112 亚磷酸 (117)表1－113 亚磷酸二甲酯 (118)表1－114 氯甲烷 (119)表1－115 乙醚 (120)表1－116 丙烯酸甲酯 (121)表1－117 一甲胺 (122)表1－118 硝酸镁 (123)表1－119 硫化氢 (124)表1－120 硫化铵 (125)表1－121 一甲胺水溶液 (126)表1－122 兔宝宝面漆 (126)表1－123 兔宝宝稀释剂 (127)表1－124 硫氢化钠 (128)表1－125丙酸 (129)表1－126乙酰氯 (130)表1－127丙酰氯 (131)表1－128 丁醇 (132)表1－129 醇酸调合漆（未列名） (133)表1－130 硝酸钠 (135)表1－131 溴甲烷 (136)表1－132 磷化铝 (137)表１－133 正丁醇 (138)表１－134 硝基木器漆 (139)表１－135 硝化棉（含氮≤12.6％） (140)表１－136 单丁醚 (141)表1－137 砷 (142)表1－138 碘化汞 (143)表1－139 氯化汞 (145)表1－140 叠氮化钠 (146)表1－141 重铬酸钠 (147)表1－142 高锰酸钾 (148)表1－143 氰化金钾 (149)表1－144丙烯酸 (150)表1－145甲基丙烯酸甲酯 (151)表1－146苯乙烯 (152)表1－147丙烯酸丁酯 (153)表1－148丁醇 (154)表1－149偶氮二异丁腈 (155)表1－150甲基丙烯酸异丁酯 (156)表1－151 甲基丙烯酸（正）丁酯 (157)表1－152 乙酰丙酮 (158)表1－153 2－丁酮 (159)表1－154 生松香 (160)表1－155 硫酸铜 (161)表1－155 硝酸 (162)表1－155 氰化钾 (163)表1－156硝基苯 (164)表1－157 氟化钠 (165)表1－158 氢氟酸 (166)表1－159蓄电池（注有酸液） (167)表1－160 环氧树脂 (168)表1－161 氯苯 (169)表1－162 乙苯 (171)表1－163 樟脑 (172)表1－164 赛璐珞 (173)表1-165 氢氧化钾 (174)表1-166 乙酸丁酯 (175)表1－001 乙炔气标识中文名：乙炔英文名：acetylene分子式：C2H2 分子量：26.04 CAS号：74－86－2 危规号：21024理化性质性状：无色无臭气体，工业品有使人不愉快的大蒜气味溶解性：微溶于水、乙醇，溶于丙酮、氯仿、苯熔点（℃）：－81.8（119kpPa）沸点（℃）：－83.8 相对密度（水＝1）：0.62临界温度（℃）：35.2 临界压力（MPa）：6.14 相对密度（空气＝1）：0.91燃烧热（KJ/mol）：1298.4 最小点火能（mJ）：饱和蒸汽压（KPa）：4053（16.8℃）燃烧爆炸危险性燃烧性：易燃燃烧分解产物：一氧化碳、二氧化碳闪点（℃）：无意义聚合危害：聚合爆炸下限（％）：2.1 稳定性：稳定爆炸上限（％）：80.0 禁忌物：强氧化剂、强酸、卤素引燃温度（℃）：305 最小点火能（mJ）：0.02危险特性：极易燃烧爆炸。

氢化锆化学品安全技术说明书编码：MSDS#2668编制日期：_____________危险特性：具有强还原性。

与氧化剂能发生强烈反应。

受热或遇潮气、酸类放出氢气和热量，可引起燃烧或爆炸。

建规火险分级：270(空气中)有害燃烧产物：水、氢气、氧化锆。

灭火方法：砂土；禁止用水、泡沫、二氧化碳、干粉、卤代烃灭火剂。

第六部分：泄漏应急处理应急处理：隔离泄漏污染区，周围设警告标志，切断火源。

建议应急处理人员戴好口罩、护目镜，穿工作服。

禁止向泄漏物直接喷水，更不要让水进入包装容器内。

用干燥砂土混合，小心扫起，使用不产生火花的工具收集倒至空旷地方深埋。

将污染地面撒上无水碳酸钠，用水冲洗，经稀释的污水放入废水系统。

如大量泄漏，收集回收或无害处理后废弃。

第七部分：操作处置与储存操作注意事项：无资料储存注意事项：储存于阴凉、干燥、通风良好的不燃库房。

远离火种、热源。

保持容器密封。

防止受潮和雨淋。

应与酸类、氧化剂、潮湿物品等分开存放。

搬运时要轻装轻卸，防止包装及容器损坏。

雨天不宜运输。

第八部分：接触控制/个体防护中国MAC(mg/m3)：5前苏联MAC(mg/m3)：未制订标准TLVTN：无资料TLVWN：无资料接触限值：美国TLV-TWA：5mg(Zr)／m3美国TLV-STEL：10mg(Zr)／m3监测方法：无资料工程控制：密闭操作，局部排风。

呼吸系统防护：可能接触其粉尘时，必须佩戴防尘口罩。

眼睛防护：戴安全防护眼镜。

身体防护：穿防静电工作服。

手防护：戴防护手套。

其他防护：无资料第九部分：理化特性pH：无资料熔点(℃)：无资料沸点(℃)：无资料分子式：ZrH2主要成分：无资料饱和蒸气压(kPa)：无资料辛醇/水分配系数的对数值：无资料临界温度(℃)：无资料闪点(℃)：无资料引燃温度(℃)：无资料自燃温度：无资料燃烧性：易燃溶解性：不溶于水，溶于氢氟酸。

相对密度(水=1)： 5.61相对蒸气密度(空气=1)：无资料分子量：93.24燃烧热(kJ/mol)：无资料临界压力(MPa)：无资料爆炸上限%(V/V)：无资料爆炸下限%(V/V)：无资料外观与性状：灰色至黑色粉末。

第一部分化学品及企业标识化学品中文名：金属锆化学品英文名：zirconiumCASNo.：7440-67-7ECNo.：231-176-9分子式：Zr第二部分危险性概述紧急情况概述固体。

易燃，其粉体与空气混合，能形成爆炸性混合物。

GHS危险性类别根据GB30000-2013化学品分类和标签规范系列标准（参阅第十六部分），该产品分类如下：易燃固体，类别2。

标签要素象形图警示词：警告危险信息：易燃固体。

预防措施：远离热源、热表面、火花、明火以及其它点火源。

禁止吸烟。

容器和接收设备接地和等势联接。

戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

事故响应：不适用。

安全储存：不适用。

废弃处置：不适用。

物理化学危险：遇火或摩擦可被引燃，其粉体与空气混合，能形成爆炸性混合物。

健康危害：吸入该物质可能会引起对健康有害的影响或呼吸道不适。

意外食入本品可能对个体健康有害。

通过割伤、擦伤或病变处进入血液，可能产生全身损伤的有害作用。

眼睛直接接触本品可导致暂时不适。

环境危害：请参阅SDS第十二部分。

第三部分成分/组成信息第四部分急救措施皮肤接触：立即脱去污染的衣物。

用大量肥皂水和清水冲洗皮肤。

如有不适，就医。

眼睛接触：用大量水彻底冲洗至少15分钟。

如有不适，就医。

吸入：立即将患者移到新鲜空气处，保持呼吸畅通。

如果呼吸困难，给于吸氧。

如患者食入或吸入本物质，不得进行口对口人工呼吸。

如果呼吸停止。

立即进行心肺复苏术。

立即就医。

食入：禁止催吐，切勿给失去知觉者从嘴里喂食任何东西。

立即呼叫医生或中毒控制中心。

第五部分消防措施危险特性可与空气形成爆炸性混合物。

重度撞击或过度受热能引起爆炸。

易燃固体，燃烧时火焰容易蔓延(即使部分用水润湿)。

可能会剧烈燃烧。

任何点火源，即摩擦、受热、火花或火焰都可能引起火灾和爆炸。

加热时，容器可能爆炸。

暴露于火中的容器可能会通过压力安全阀泄漏出内容物。

受热或接触火焰可能会产生膨胀或爆炸性分解。

灭火方法与灭火剂合适的灭火介质：干粉、二氧化碳、水喷雾或耐醇泡沫。

MSDSZICOONSAND锆英砂MSDSMATERIAL SAFETY DATA SHEETZIRCON SAND PRODUCTS1. IDENTIFICATION OF THE MATERIALProduct identification / Product NamesZircon sandRecommended use raw material for steelmaking refractories, glassmaking refractories, traditional ceramics, zircoium manufacture, zirconium manufacture, glass additive and foundry uses.2. HAZARDS IDENTIFICATIONRisk Phrases (R-Phrases) NoneSafety Phrases (S-Phrases) NoneClass and Subsidiary Risk None allocatedHazchem Code None allocatedPoisons Schedule None allocatedPotential Health EffectsAcuteSwallowed Non-toxic. There are no known hazards resulting from accidental ingestion ofzircon sand as may occur during normal handling. Swallowing a large amountmay result in irritation to the digestive system due to abrasiveness. Eye the zircon grains and dust can be moderately irritating due to abrasiveness. Skin Low HazardInhaled the normal grain size of the product precludes from being an inhalationhazard, however handing of bulk materials may generate some dust.This isnormally regarded as general nuisance dust, but can be irritating if inhaledat high concentration. May cause symptoms such as coughing or sneezing. ChronicSilica crystalline silica is a known cause of lung fibrosis (silicosis). It has beenclassified as a human carcinogen. (IARC). Zircon sand contains asmallamount of free quartz, (up to 0.5%) and precautions should be takentoavoid inhaling the dust.Radiation zircon contains naturally occurring radioactive elementsof the uraniumand thorium series. The zircon sands produced by ILUKA Resources containlow concentrations of these impurities, with typical specificactivities of 0.6 to1.2 Bq/gm (thorium 223) and to 1.5 to 4.5 Bq/gm (uranium -238). Daughterproducts are present typically at equilibrium concentrations. The mainradiological hazard is internal exposure to alpha particles from inhaled dust.Suitable dust control shall be employed to ensure occupational exposure togenerated dust and alpha particles are kept as low as reasonable achievable.As a guide, continuous worker exposure to respirable dust levels above1.5mg/,3 could give rise to annual internal exposures above 1mSv. Externalexposure is from gamma radiation. Continuous exposure (2000 hours per year)annual external dose above 1 mSV.3. COMPOSTIION /INFORMATION ON INGREDENTSIngredient (typical) CAS Number Weight % Zircon 14940-68-2 95-99% Kyanite 149040-68-2 0.1-4%Quartz 14808-60-7 0.05-0.5% Rutile 1317-80-2 0.1-0.2% Leucoxene/ilmenite 103170-28-1 0.1-0.2% Monazite approx 0. 0.2%4. FIRST AID MEASURESSwallowed First aid is unlikely to be required, but if necessary wash mouth out with waterensuring the mouthwash is not swallowed. Seek medical attention as a precaution if discomfort occurs.Eye Hold eyelid open and flush with plenty of clean water. Continue for at least 15minutes or until grit is removed. Seek medical attention if soreness or irritationpersists.Skin Gently remove contaiminated clothing to avoid generatiing dust. wash materialfrom the skin. If repeated contact result in skin irritation, seek medical advice.Launder clothing before re-use.Inhaled Move to fresh air. Blow nos to remove particulates fromnasal passages. Ifanyadverse reaction develops, seek medical attention.First AidFacilities Eye wash facilitiesAdvice toPhysician Treat symptomatically5. FIRE FIGHTING MEASURESFlashpoint Not applicableFlammability Not applicableGeneral Hazard This product is not flammable and does not support combustion. Extinguishing Media Use media suitable for the material that is burning.6. ACCIDENTAL RELEASE MEASURESSpills andDisposal Wear safety equipment as for normal handling. Avoid generating dust.Vacuum up if possible. Otherwise sweep up and re-cycle. If thespilledProduct is not suitable for re-use, damp down, collect and where possibleReturn to manufacture for reprocessing. Any disposal to an approved landfillSite and cover with clean fill shall be conducted in accordance with state/localCouncil regulations.7. HANDLING AND STORAGEHandling Avoid breathing dust, suitable dust controls should be utilized when handlingBulk materials. Wash thoroughly after handling if handlingrespirable flourIt is adviseable to also gloves and wash hands before eating, drink or smokingTo minimize inhalation or ingestion from hands.Storage Storage areas should be ventilated and dust generation minimized whenHandling.8. EXPOSURE CONTROLS /PERSONAL PROTECTIONExposureStandards Dust TWA – 10 mg/m3 (inhalable general nuisance dust) RadiationExposure 1 Occupational exposure should be as low as reasonable achievable, (ALARAPrinciple), but should not exceed a total 100 milli-seiverts over fiveconsecutive years. (ICRP). 1 Recommendation of the International Commission on Radiological Protection, ICRP Publication 60, Annals of theICRP Vol 21, No 1-3 1991EngineeringControls Ventilation requirements will depend on handling methods and the amount inUse, but should be sufficient to maintain dust levels below exposure limits.Indoor points of dust generation such as conveyor and hopper dischargesShould be equipped with an effective extraction system. PersonalProtection Safety glasses with side shields or goggles. If risk of inhaling dust is presentWear, at minimum, a P1 personal respirator (disposable or cartridge type).9. PHYSICAL AND CHEMICAL PROPERTIESAppearance (Form) Off white to brownish free running sand, odorless and tasteless Chemical formula ZrO2.SiO2Melting point 2100 to 2300Vapour pressure not volatileEvaporation rate not volatileSpecific gravity 4.6 – 4.8Solubility in Water InsolublepH 5-7.5Bulk density 2700 – 2950 kg/m3Grain size AFS No 55-140, average grain size of 0.1 – 0.2mm10. STBILITY AND REACTIVITYReactivity InertChemical stability StableIncompatibilities None in normal or expected useDecomposition Decomposition will not occur11. TEXICOLOGICAL INFORMATIONThis product is no – toxic. Refer secion 2. Hazards Identification.12. ECOLOGICAL INFORMATIONThe material is unlikely to cause any environmental damage. It is insoluble in water and is unlikely to contaminate waterways or food chains.13. DISPOSAL CONSIDERATIONS.Disposal must be in accordance with Federal, State and Local Council regulations. If approved, may be transferred to an approved landfill site.Note: many states are developing new regulations for the disposal of wast containing Naturally Occurring Radioactive Materials (NORM) or Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) above background levels. Consult and comply with current regulations.14. TRANSPORT INFORMATIONTransport may be regulated in some countries, although the productis not generally regarded as a transport hazard. Not classified as radioactive pursuant to paragraph 107 of IAEA TS-R-1 regulations. Trucks should be covered when transporting dry bulk product to prevent dust generation.15. REGULATORY INFORMATIONEINECS No. Zircon 239-019-616. OTHER INFORMATIONLabelling Labelling not required according to EC-Dir. 67/548, as amended. Other informationDate of issue march 2010Replaces December 2008This MSDS is valid for five (5) years from the date of issue. AbbreviationsBq/gm Becquerel per gramIAEA International Atomic Energy AgencyIARC International Agency for Research on CancerICRP International Commission on Radiation ProtectionMg/m3 Milligram per cubic metreTLV Threshold Limit ValueTWA Time Weighted AverageEnd of MSDS。

MSDS-205——化学品安全技术说明书灭火方法：雾状水、砂土。

包装与储运危险性类别：第5．1类氧化剂危险货物包装标志：11包装类别：Ⅲ储运注意事项：储存于阴凉、干燥、通风良好的库房。

远离火种、热源。

包装要求密封，不可与空气接触。

防潮、防晒。

应与还原剂、易燃、可燃物，硫、磷等分开存放。

切忌混储混运。

搬运时要轻装轻卸，防止包装及容器损坏。

废弃：根据国家和地方有关法规的要求处置。

或与厂商或制造商联系，确定处置方法。

废物储存参见“储运注意事项”。

包装方法：螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外木板箱；螺纹口玻璃瓶、塑料瓶、或塑料袋再装入金属桶（罐）或塑料桶（罐）外木板箱。

毒性危害接触限值：中国 MAC：未制订标准前苏联MAC：未制订标准美国TLV—TWA：5mg／m3(按Zr计)美国TLV—STEL：10mg／m3(按Zr计)检测方法：二甲酚橙比色法侵入途径：吸入食入毒性：属低毒类LD50：3170mg／kg(大鼠经口)LC50：该物质对环境可能有危害，在地下水中有蓄积作用。

健康危害：毒性较低，对眼睛、皮肤、粘膜有刺激作用。

工业上接触尚未见有中毒病例，但高温下会分解，散发出剧毒的氮氧化物，吸入烟雾会中毒。

急救皮肤接触：脱去污染的衣着，用流动清水冲洗。

眼睛接触：立即翻开上下眼睑，用流动清水冲洗15分钟。

就医。

吸入：脱离现场至空气新鲜处。

食入：误服者用水漱口，给饮牛奶或蛋清，就医。

防护措施工程控制：密闭操作，局部排风。

呼吸系统防护：可能接触其粉尘时，应该佩戴防毒口罩。

眼睛防护：戴化学安全防护眼镜。

防护服：穿工作服。

手防护：戴橡皮胶手套。

其他：工作后，淋浴更衣。

单独存放被毒物污染的衣服，洗后再用。

保持良好的卫生习惯。

泄漏处置：隔离泄漏污染区，周围设警告标志，切断火源。

应急处理人员戴好防毒面具，穿一般消防防护服。

不要直接接触泄漏物，勿使泄漏物与可燃物质(木材、纸、油等)接触，用大量水冲洗，经稀释的洗液放入废水系统。

纳米陶瓷无磷锆化液反应机理是氧化锆是以氟化酸为基础，它包含独特的添加和催化剂混合物帮助部件更快更紧致地完成涂层，这样加工后的涂层可以避免部件产生腐蚀，减少沉淀物的产生。

纳米陶瓷无磷锆化液采用环保材料配制的、纳米级的水性金属表面涂装前处理剂，其特点是：1. 环保：不含磷酸盐、亚硝酸盐、铬酸盐、重金属、挥发性有机成分等污染物质，为水性制剂，无沉渣、无排放。

2. 节能：传统的磷化液处理工艺，通常采用低温、中温磷化，需对磷化液加温至35℃~55℃，且需恒温，需消耗相应的煤、油、电等能源，而本产品常温使用、无需加热、节省能源。

3. 提高生产效率：本品对基材处理时间短，喷淋生产线通常为20~60秒，浸泡生产线通常为2~5分钟，极大提高了生产效率。

4. 使用维护简便：只需锆化剂LZ-4381和PH调整剂LZ-1017配合使用，而磷化液则需多种制剂添加，使用本品省时省力。

本品为水性制剂，无沉渣，无须停线倒槽，对喷嘴等相关设备无损伤，省时省钱。

5. 附着力极佳：本品成膜厚度为纳米级，致密性好、成膜均匀，无需表调及钝化处理，使金属基材和涂层的附着力极强，延长金属的耐腐蚀时间。

6. 应用面广：本品普遍适用于基材为冷轧板、热轧板、碳钢、铸铁、镀锌板、铝板、铝合金、锌合金等多种材料，使生产线在处理不同基材的工件时不用更换处理液，省时、省钱、高效。

7. 工艺流程简单：只需进行预脱脂→脱脂→水洗→水洗→本品→干燥即可。

8. 处理成本低：每公斤处理面积不低于150平方米，大幅度降低用户的生产成本。

9. 对工件的侵蚀性小。

综合以上特点，本品相对于目前市场上广泛应用的各种磷化液而言，具有环保、节能、省时、省力的显著优点尤其节省综合成本，经过测算，在免加热、免排放、使用面广、单位处理面积大、维护简便、工艺简单等综合因素作用下，在增强附着力和提高生产效率的前提下可节约成本30%以上。

使用成本分析1. 单位处理成本本品的成膜厚度一般为0.05~0.1微米，用于喷淋生产线的处理时间20秒~1分钟（根据基材及生产线的实际情况确定），每公斤原液的处理面积为150~280㎡，单位处理成本仅为0.08元~0.15元。

硫酸锆的MSDS信息【Product Name】Zirconium sulphate【Synonyms】Zirconium (IV) sulfateZirconyl sulfate【CAS】14644-61-2【Formula】O4SZr【Molecular Weight】355.39【EINECS】238-694-4【RTECS】ZH9100000【RTECS Class】Mutagen; Reproductive Effector【Merck】12,10315【Beilstein/Gmelin】115466 (G)Physical and Chemical Properties Back to Contents【Appearance】Anhydrous zirconium sulfate is a colorless microcrystalline solid. 【Solubility in water】525 g/L【Melting Point】410【Density】3.22 g/cm3【Usage】Catalyst support, precipitation of amino acids & proteins, in tanning industry. Zirconium sulfate tetrahydrate.First Aid Measures Back to Contents【Ingestion】Get medical aid. Wash mouth out with water.【Inhalation】Remove from exposure to fresh air immediately.【Skin】Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Handling and Storage Back to Contents【Storage】Store in a cool, dry place. Store in a tightly closed container.【Handling】Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.Hazards Identification Back to Contents【Inhalation】Causes respiratory tract irritation.【Skin】Causes skin irritation.【Eyes】Causes eye irritation.【Ingestion】The toxicological properties of this substance have not been fully investigated. 【Hazards】Some may burn but none ignite readily. May polymerize explosively when heated or involved in a fire. Containers may explode when heated. Some may be transported hot.【UN (DOT)】9163Exposure Controls/Personal Protection Back to Contents【Personal Protection】Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. 【Respirators】A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149. 【Exposure Effects】Experimental animals exposed to massive doses have developed CNS depression. Two individuals administered 50 milligrams of zirconium malate intravenously developed vertigo. Small fractions of zirconium were absorbed in female rats by the oral route, and the metal seemed to concentrate in the ovaries and produce hypervascularization. <br>In mice, offspring of clams who received zirconium during pregnancy had long-lasting behavioral changes. <br>Zirconium is found in newborn rats. <br>In rats, zirconium appears in the breast milk.【Poison Class】4Fire Fighting Measures Back to Contents【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.【Fire Potential】Nonflammable.Accidental Release Measures Back to Contents【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container.Stability and Reactivity Back to Contents【Incompatibilities】Corrosive to aluminum and other metals【Stability】Stable under normal temperatures and pressures.【Decomposition】Irritating and toxic fumes and gases, sulfuric acid.【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases. Transport Information Back to Contents【UN Number】。

化学品中文名称：锆化液化学品英文名称：Coating agent分子式：分子量：有害物成分危险性类别：侵入途径：健康危害：环境危害：燃爆危险：皮肤接触：眼睛接触：吸入：食入：危险特性：有害燃烧产物：灭火方法：应急处理：操作注意事项：储存注意事项：职业接触限值呼吸系统防护：眼睛防护：身体防护：手防护：其他防护：主要成分：化学品安全技术说明书（MSDS）第一部分：化学品名称不含BOD、COD 不可燃第二部分：成分/组成信息氟锆酸第三部分：危险性概述皮肤接触，吸入，眼睛接触，食入接触本物质会导致皮肤，眼睛和黏膜的灼伤。

长期或重复吸入可能引起鼻隔膜溃引起氟类型的刺激和灼伤，这种伤害不会立即显现和感觉。

如已吞咽，立即就医－－不要试图呕吐。

和１－２杯水或牛奶。

如果伤者已无意食任何东西。

第五部分：消防措施本产品为水性混合物，不可燃。

可能与金属反应，生成可燃性的氢气。

第四部分：急救措施立即脱去被污染的衣物。

如有皮肤接触，用大量水冲洗。

万一接触眼睛，立即用大量的水冲洗１５分钟，就医。

如果吸入雾或蒸气，立即转移到空气新鲜处。

如果持续发展，就医。

不要将化学品与眼睛，皮肤和衣物接触。

操作完后彻底冲洗。

避免吸入蒸气。

保持容器紧闭，存储在远离禁忌配物的阴冷＼通风良好处。

防止冻结。

第八部分：接触控制/个体防护保持良好通风适用于任何灭火剂第六部分：泄漏应急处理如果没有危险，停止物质的流动。

打扫时，穿戴适合的保护设备和衣物。

收集所将物质收集至适合容器统一处理。

根据法律法规处理收集物。

第七部分：操作处置与储存推荐安装洗眼器和紧急冲淋器。

第九部分：理化特性氟锆酸如果通风不理想，必须提供适合的呼吸道保护。

佩戴护目镜使用围裙和防护靴。

使用密封手套。

锆粉化学品安全技术说明书MSDS第一部分化学品名称化学品中文名：锆粉化学品英文名：zirconium powder中文名称2：金属锆粉英文名称2：zirconium metal powder技术说明书编码：513CAS号：7440-67-7分子式：Zr分子量：91.22第二部分成分/组成信息危险性类别：第4.2类易于自燃的物质侵入途径：健康危害：工业上尚未见有锆中毒的报道。

环境危害：燃爆危险：本品属易于自燃的物质。

第四部分急救措施皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。

眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。

就医。

吸入：迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

如呼吸停止，立即进行人工呼吸。

就医。

食入：饮足量温水，催吐。

就医。

第五部分消防措施危险特性：微细粉末极易燃烧，有时能自燃发生爆炸。

锆粉也能在二氧化碳及氮气中燃烧。

粉体在受热、遇明火或接触氧化剂时会引起燃烧爆炸。

有害燃烧产物：氧化锆。

灭火方法：采用干粉、砂土灭火。

严禁用水、泡沫、二氧化碳扑救。

第六部分泄漏应急处理应急处理：隔离泄漏污染区，限制出入。

切断火源。

建议应急处理人员戴自给正压式呼吸器，穿一般作业工作服。

小量泄漏：使用无火花工具收集于干燥、洁净、有盖的容器中。

转移回收。

大量泄漏：用塑料布、帆布覆盖。

使用无火花工具收集转移回收。

第七部分操作处置与储存操作注意事项：操作人员必须经过专门培训，严格遵守操作规程。

建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，戴防化学品手套。

远离火种、热源，工作场所严禁吸烟。

使用防爆型的通风系统和设备。

避免产生粉尘。

避免与酸类接触。

搬运时轻装轻卸，保持包装完整，防止洒漏。

配备相应品种和数量的消防器材及泄漏应急处理设备。

倒空的容器可能残留有害物。

储存注意事项：为安全起见，储存时常以不少于25％的水润湿、钝化。

储存于阴凉、通风的库房。

远离火种、热源。

包装密封。

应与酸类等分开存放，切忌混储。