The strongly enhanced magnetic excitations near the quantum critical point of Cr$_{1-x}$V$_

Wireless Power Transfer via Strongly Coupled Magnetic ResonancesAndré Kurs,1* Aristeidis Karalis,2 Robert Moffatt,1 J. D. Joannopoulos,1 Peter Fisher,3Marin Soljačić11Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. 2Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, MA 02139, USA. 3Department of Physics and Laboratory for Nuclear Science, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.*To whom correspondence should be addressed. E-mail: akurs@Using self-resonant coils in a strongly coupled regime, we experimentally demonstrate efficient non-radiative power transfer over distances of up to eight times the radius of the coils. We demonstrate the ability to transfer 60W with approximately 40% efficiency over distances in excess of two meters. We present a quantitative model describing the power transfer which matches the experimental results to within 5%. We discuss practical applicability and suggest directions for further studies. At first glance, such power transfer is reminiscent of the usual magnetic induction (10); however, note that the usual non- resonant induction is very inefficient for mid-range applications.Overview of the formalism. Efficient mid-range power transfer occurs in particular regions of the parameter space describing resonant objects strongly coupled to one another. Using coupled-mode theory to describe this physical system (11), we obtain the following set of linear equationsIn the early 20th century, before the electrical-wire grid, Nikola Tesla (1) devoted much effort towards schemes to a&m(t)=(iωm-Γm)a m(t)+∑iκmn a n(t)+F m(t)n≠m(1)transport power wirelessly. However, typical embodiments (e.g. Tesla coils) involved undesirably large electric fields. During the past decade, society has witnessed a dramatic surge of use of autonomous electronic devices (laptops, cell- phones, robots, PDAs, etc.) As a consequence, interest in wireless power has re-emerged (2–4). Radiative transfer (5), while perfectly suitable for transferring information, poses a number of difficulties for power transfer applications: the efficiency of power transfer is very low if the radiation is omnidirectional, and requires an uninterrupted line of sight and sophisticated tracking mechanisms if radiation is unidirectional. A recent theoretical paper (6) presented a detailed analysis of the feasibility of using resonant objects coupled through the tails of their non-radiative fields for mid- range energy transfer (7). Intuitively, two resonant objects of the same resonant frequency tend to exchange energy efficiently, while interacting weakly with extraneous off- resonant objects. In systems of coupled resonances (e.g. acoustic, electro-magnetic, magnetic, nuclear, etc.), there is often a general “strongly coupled” regime of operation (8). If one can operate in that regime in a given system, the energy transfer is expected to be very efficient. Mid-range power transfer implemented this way can be nearly omnidirectional and efficient, irrespective of the geometry of the surrounding space, and with low interference and losses into environmental objects (6).Considerations above apply irrespective of the physical nature of the resonances. In the current work, we focus on one particular physical embodiment: magnetic resonances (9). Magnetic resonances are particularly suitable for everyday applications because most of the common materials do not interact with magnetic fields, so interactions with environmental objects are suppressed even further. We were able to identify the strongly coupled regime in the system of two coupled magnetic resonances, by exploring non-radiative (near-field) magnetic resonant induction at MHzfrequencies. where the indices denote the different resonant objects. The variables a m(t) are defined so that the energy contained in object m is |a m(t)|2, ωm is the resonant frequency of thatisolated object, and Γm is its intrinsic decay rate (e.g. due to absorption and radiated losses), so that in this framework anuncoupled and undriven oscillator with parameters ω0 and Γ0 would evolve in time as exp(iω0t –Γ0t). The κmn= κnm are coupling coefficients between the resonant objects indicated by the subscripts, and F m(t) are driving terms.We limit the treatment to the case of two objects, denoted by source and device, such that the source (identified by the subscript S) is driven externally at a constant frequency, and the two objects have a coupling coefficient κ. Work is extracted from the device (subscript D) by means of a load (subscript W) which acts as a circuit resistance connected to the device, and has the effect of contributing an additional term ΓW to the unloaded device object's decay rate ΓD. The overall decay rate at the device is therefore Γ'D= ΓD+ ΓW. The work extracted is determined by the power dissipated in the load, i.e. 2ΓW|a D(t)|2. Maximizing the efficiency η of the transfer with respect to the loading ΓW, given Eq. 1, is equivalent to solving an impedance matching problem. One finds that the scheme works best when the source and the device are resonant, in which case the efficiency isThe efficiency is maximized when ΓW/ΓD= (1 + κ2/ΓSΓD)1/2. It is easy to show that the key to efficient energy transfer is to have κ2/ΓSΓD> 1. This is commonly referred to as the strongcoupling regime. Resonance plays an essential role in thisDS S D'' power transfer mechanism, as the efficiency is improved by approximately ω2/ΓD 2 (~106 for typical parameters) compared to the case of inductively coupled non-resonant objects. Theoretical model for self-resonant coils. Ourexperimental realization of the scheme consists of two self- resonant coils, one of which (the source coil) is coupled inductively to an oscillating circuit, while the other (the device coil) is coupled inductively to a resistive load (12) (Fig. 1). Self-resonant coils rely on the interplay between distributed inductance and distributed capacitance to achieve resonance. The coils are made of an electrically conducting wire of total length l and cross-sectional radius a wound into Given this relation and the equation of continuity, one finds that the resonant frequency is f 0 = 1/2π[(LC )1/2]. We can now treat this coil as a standard oscillator in coupled-mode theory by defining a (t ) = [(L /2)1/2]I 0(t ).We can estimate the power dissipated by noting that the sinusoidal profile of the current distribution implies that the spatial average of the peak current-squared is |I 0|2/2. For a coil with n turns and made of a material with conductivity σ, we modify the standard formulas for ohmic (R o ) and radiation (R r ) µ0ω l a helix of n turns, radius r , and height h . To the best of our knowledge, there is no exact solution for a finite helix in the literature, and even in the case of infinitely long coils, the solutions rely on assumptions that are inadequate for our R o = 2σ 4πa µ πωr 42 ωh 2 (6)system (13). We have found, however, that the simple quasi- R =0 n 2 + (7)static model described below is in good agreementr ε 12 c3π3 c(approximately 5%) with experiment.We start by observing that the current has to be zero at the ends of the coil, and make the educated guess that the resonant modes of the coil are well approximated bysinusoidal current profiles along the length of the conducting wire. We are interested in the lowest mode, so if we denote by s the parameterization coordinate along the length of the conductor, such that it runs from -l /2 to +l /2, then the time- dependent current profile has the form I 0 cos(πs /l ) exp(i ωt ). It follows from the continuity equation for charge that the linear charge density profile is of the form λ0 sin(πs /l ) exp(i ωt ), so the two halves of the coil (when sliced perpendicularly to its axis) contain charges equal in magnitude q 0 = λ0l /π but opposite in sign.As the coil is resonant, the current and charge density profiles are π/2 out of phase from each other, meaning that the real part of one is maximum when the real part of the other is zero. Equivalently, the energy contained in the coil is 0The first term in Eq. 7 is a magnetic dipole radiation term(assuming r << 2πc /ω); the second term is due to the electric dipole of the coil, and is smaller than the first term for our experimental parameters. The coupled-mode theory decay constant for the coil is therefore Γ = (R o + R r )/2L , and its quality factor is Q = ω/2Γ.We find the coupling coefficient κDS by looking at the power transferred from the source to the device coil,assuming a steady-state solution in which currents and charge densities vary in time as exp(i ωt ).P =⎰d rE (r )⋅J (r ) =-⎰d r (A&S (r )+∇φS (r ))⋅J D (r ) at certain points in time completely due to the current, and at other points, completely due to the charge. Usingelectromagnetic theory, we can define an effective inductance L and an effective capacitance C for each coil as follows:=-1⎰⎰d r d r ' µJ &S(r ')+ρS(r ') 4π |r -r |ε0≡-i ωMI S I Dr '-r|r '-r |3⋅J D (r )(8)L =µ04π |I 0 |⎰⎰d r d r 'J (r )⋅J (r ')|r -r '|where the subscript S indicates that the electric field is due to the source. We then conclude from standard coupled-mode theory arguments that κDS = κSD = κ = ωM /2[(L S L D )1/2]. When 1 1 ρ(r )ρ(r ') the distance D between the centers of the coils is much larger= C 4πε 0 |q 0 | ⎰⎰d r d r ' |r -r '|(4)than their characteristic size, κ scales with the D -3dependence characteristic of dipole-dipole coupling. Both κ and Γ are functions of the frequency, and κ/Γ and the where the spatial current J (r ) and charge density ρ(r ) are obtained respectively from the current and charge densities along the isolated coil, in conjunction with the geometry of the object. As defined, L and C have the property that the efficiency are maximized for a particular value of f , which is in the range 1-50MHz for typical parameters of interest. Thus, picking an appropriate frequency for a given coil size, as we do in this experimental demonstration, plays a major role in optimizing the power transfer.1 2Comparison with experimentallydeterminedU =2 L |I 0 |parameters. The parameters for the two identical helical coils built for the experimental validation of the power 1 2 transfer scheme are h = 20cm, a = 3mm, r = 30 cm, and n = =2C|q 0 | (5)5.25. Both coils are made of copper. The spacing between loops of the helix is not uniform, and we encapsulate theuncertainty about their uniformity by attributing a 10% (2cm) uncertainty to h . The expected resonant frequency given these22dimensions is f0 = 10.56 ± 0.3MHz, which is about 5% off from the measured resonance at 9.90MHz.The theoretical Q for the loops is estimated to be approximately 2500 (assuming σ = 5.9 × 107 m/Ω) but the measured value is Q = 950±50. We believe the discrepancy is mostly due to the effect of the layer of poorly conductingcopper oxide on the surface of the copper wire, to which the current is confined by the short skin depth (~20μm) at this frequency. We therefore use the experimentally observed Q and ΓS= ΓD= Γ = ω/2Q derived from it in all subsequent computations.We find the coupling coefficient κ experimentally by placing the two self-resonant coils (fine-tuned, by slightly adjusting h, to the same resonant frequency when isolated) a distance D apart and measuring the splitting in the frequencies of the two resonant modes. According to coupled-mode theory, this splitting should be ∆ω = 2[(κ2-Γ2)1/2]. In the present work, we focus on the case where the two coils are aligned coaxially (Fig. 2), although similar results are obtained for other orientations (figs. S1 and S2).Measurement of the efficiency. The maximum theoretical efficiency depends only on the parameter κ/[(L S L D)1/2] = κ/Γ, which is greater than 1 even for D = 2.4m (eight times the radius of the coils) (Fig. 3), thus we operate in the strongly- coupled regime throughout the entire range of distances probed.As our driving circuit, we use a standard Colpitts oscillator whose inductive element consists of a single loop of copper wire 25cm in radius(Fig. 1); this loop of wire couples inductively to the source coil and drives the entire wireless power transfer apparatus. The load consists of a calibrated light-bulb (14), and is attached to its own loop of insulated wire, which is placed in proximity of the device coil and inductively coupled to it. By varying the distance between the light-bulb and the device coil, we are able to adjust the parameter ΓW/Γ so that it matches its optimal value, given theoretically by (1 + κ2/Γ2)1/2. (The loop connected to the light-bulb adds a small reactive component to ΓW which is compensated for by slightly retuning the coil.) We measure the work extracted by adjusting the power going into the Colpitts oscillator until the light-bulb at the load glows at its full nominal brightness.We determine the efficiency of the transfer taking place between the source coil and the load by measuring the current at the mid-point of each of the self-resonant coils with a current-probe (which does not lower the Q of the coils noticeably.) This gives a measurement of the current parameters I S and I D used in our theoretical model. We then compute the power dissipated in each coil from P S,D=ΓL|I S,D|2, and obtain the efficiency from η = P W/(P S+ P D+P W). To ensure that the experimental setup is well described by a two-object coupled-mode theory model, we position the device coil such that its direct coupling to the copper loop attached to the Colpitts oscillator is zero. The experimental results are shown in Fig. 4, along with the theoretical prediction for maximum efficiency, given by Eq. 2. We are able to transfer significant amounts of power using this setup, fully lighting up a 60W light-bulb from distances more than 2m away (figs. S3 and S4).As a cross-check, we also measure the total power going from the wall power outlet into the driving circuit. The efficiency of the wireless transfer itself is hard to estimate in this way, however, as the efficiency of the Colpitts oscillator itself is not precisely known, although it is expected to be far from 100% (15). Still, the ratio of power extracted to power entering the driving circuit gives a lower bound on the efficiency. When transferring 60W to the load over a distance of 2m, for example, the power flowing into the driving circuit is 400W. This yields an overall wall-to-load efficiency of 15%, which is reasonable given the expected efficiency of roughly 40% for the wireless power transfer at that distance and the low efficiency of the Colpitts oscillator.Concluding remarks. It is essential that the coils be on resonance for the power transfer to be practical (6). We find experimentally that the power transmitted to the load drops sharply as either one of the coils is detuned from resonance. For a fractional detuning ∆f/f0 of a few times the inverse loaded Q, the induced current in the device coil is indistinguishable from noise.A detailed and quantitative analysis of the effect of external objects on our scheme is beyond the scope of the current work, but we would like to note here that the power transfer is not visibly affected as humans and various everyday objects, such as metals, wood, and electronic devices large and small, are placed between the two coils, even in cases where they completely obstruct the line of sight between source and device (figs. S3 to S5). External objects have a noticeable effect only when they are within a few centimeters from either one of the coils. While some materials (such as aluminum foil, styrofoam and humans) mostly just shift the resonant frequency, which can in principle be easily corrected with a feedback circuit, others (cardboard, wood, and PVC) lower Q when placed closer than a few centimeters from the coil, thereby lowering the efficiency of the transfer.When transferring 60W across 2m, we calculate that at the point halfway between the coils the RMS magnitude of the electric field is E rms= 210V/m, that of the magnetic field isH rms= 1A/m, and that of the Poynting vector is S rms=3.2mW/cm2 (16). These values increase closer to the coils, where the fields at source and device are comparable. For example, at distances 20cm away from the surface of the device coil, we calculate the maximum values for the fields to be E rms= 1.4kV/m, H rms= 8A/m, and S rms= 0.2W/cm2. The power radiated for these parameters is approximately 5W, which is roughly an order of magnitude higher than cell phones. In the particular geometry studied in this article, the overwhelming contribution (by one to two orders of magnitude) to the electric near-field, and hence to the near- field Poynting vector, comes from the electric dipole moment of the coils. If instead one uses capacitively-loaded single- turn loop design (6) - which has the advantage of confining nearly all of the electric field inside the capacitor - and tailors the system to operate at lower frequencies, our calculations show (17) that it should be possible to reduce the values cited above for the electric field, the Poynting vector, and the power radiated to below general safety regulations (e.g. the IEEE safety standards for general public exposure(18).) Although the two coils are currently of identical dimensions, it is possible to make the device coil small enough to fit into portable devices without decreasing the efficiency. One could, for instance, maintain the product of the characteristic sizes of the source and device coils constant, as argued in (6).We believe that the efficiency of the scheme and the power transfer distances could be appreciably improved by silver-plating the coils, which should increase their Q, or by working with more elaborate geometries for the resonant objects (19). Nevertheless, the performance characteristics of the system presented here are already at levels where they could be useful in practical applications.References and Notes1. N. Tesla, U.S. patent 1,119,732 (1914).2.J. M. Fernandez, J. A. Borras, U.S. patent 6,184,651(2001).3.A. Esser, H.-C. Skudelny, IEEE Trans. Indust. Appl. 27,872(1991).4.J. Hirai, T.-W. Kim, A. Kawamura, IEEE Trans. PowerElectron. 15, 21(2000).5.T. A. Vanderelli, J. G. Shearer, J. R. Shearer, U.S. patent7,027,311(2006).6.A. Karalis, J. D. Joannopoul os, M. Soljačić, Ann. Phys.,10.1016/j.aop.2007.04.017(2007).7.Here, by mid-range, we mean that the sizes of the deviceswhich participate in the power transfer are at least a few times smaller than the distance between the devices. For example, if the device being powered is a laptop (size ~ 50cm), while the power source (size ~ 50cm) is in thesame room as the laptop, the distance of power transfer could be within a room or a factory pavilion (size of the order of a fewmeters).8. T. Aoki, et al., Nature 443, 671 (2006).9.K. O’Brien, G. Scheible, H. Gueldner, 29th AnnualConference of the IEEE 1, 367(2003).10.L. Ka-Lai, J. W. Hay, P. G. W., U.S. patent7,042,196(2006).11.H. Haus, Waves and Fields in Optoelectronics(Prentice- Supporting Online Material/cgi/content/full/1143254/DC1SOM TextFigs. S1 to S530 March 2007; accepted 21 May 2007Published online 7 June 2007; 10.1126/science.1143254 Include this information when citing this paper.Fig. 1. Schematic of the experimental setup. A is a single copper loop of radius 25cm that is part of the driving circuit, which outputs a sine wave with frequency 9.9MHz. S and D are respectively the source and device coils referred to in the text. B is a loop of wire attached to the load (“light-bulb”). The various κ’s represent direct couplings between the objects indicated by the arrows. The angle between coil D and the loop A is adjusted to ensure that their direct coupling is zero, while coils S and D are aligned coaxially. The direct couplings between B and A and between B and S are negligible.Fig. 2. Comparison of experimental and theoretical values for κ as a function of the separation between coaxially aligned source and device coils (the wireless power transfer distance.) Fig. 3. Comparison of experimental and theoretical values for the parameter κ/Γ as a function of the wireless power transfer distance. The theory values are obtained by using the theoretical κ and the experimentally measured Γ. The shaded area represents the spread in the theoretical κ/Γ due to the 5% uncertainty in Q.Fig. 4. Comparison of experimental and theoretical efficiencies as functions of the wireless power transfer distance. The shaded area represents the theoretical prediction for maximum efficiency, and is obtained by inserting theHall, Englewood Cliffs, NJ, 1984).12.The couplings to the driving circuit and the load donot theoretical values from Fig. 3 into Eq. 2 [with Γκ2/Γ2 1/2 W /ΓD= (1 +have to be inductive. They may also be connected by awire, for example. We have chosen inductive coupling in the present work because of its easier implementation. 13.S. Sensiper, thesis, Massachusetts Institute of Technology(1951).14.We experimented with various power ratings from 5W to75W.15.W. A. Edson, Vacuum-Tube Oscillators (Wiley, NewYork,1953).16.Note that E ≠cμ0H, and that the fields are out of phaseand not necessarily perpendicular because we are not in a radiativeregime.17.See supporting material on Science Online.18.IEEE Std C95.1—2005 IEEE Standard for Safety Levelswith Respect to Human Exposure to Radio FrequencyElectromagnetic Fields, 3 kHz to 300 GHz (IEEE,Piscataway, NJ,2006).19. J. B. Pendry, Science 306, 1353 (2004).20. The authors would like to thank John Pendry forsuggesting the use of magnetic resonances, and Michael Grossman and Ivan Čelanović for technical assistance.This work was supported in part by the Materials Research Science and Engineering Center program of the National Science Foundation under Grant No. DMR 02-13282, by the U.S. Department of Energy under Grant No. DE-FG02-99ER45778, and by the Army Research Officethrough the Institute for Soldier Nanotechnologies under Contract No. DAAD-19-02-D0002.) ]. The black dots are the maximum efficiency obtained from Eq. 2 and the experimental values of κ/Γ from Fig. 3. The red dots present the directly measured efficiency,as described in thetext.。

MAGNETIC MATERIALS OVERVIEWDr. James LivingstonMagnetic materials provide the "driving force" that turns our electric motors, generates electricity in power stations and sound in our speakers, and stores information on our credit cards and computer disks. Materials science has created magnetic materials far more powerful than those available only a few decades ago, resulting in a tremendous impact on modern technology.Review of magnetics basicsMagnetic fields are created by electric charges in motion (electric currents, orbital motion of electrons, SPIN of electrons)Magnetic fields exert forces on electric charges in motion (current-carrying wires, charged-particle beams, orbital motion of electrons, SPIN of electrons)Materials categoriesIf atoms have no net spin, materials are diamagnetic (weakly repelled by field)If a net spin, but uncoupled to neighbors, paramagnetic (weakly attracted)If equal net spins are coupled antiparallel, antiferromagnetic (weakly attracted)If unequal net spins are coupled antiparallel, ferrimagnetic (strongly attracted)If net spins are coupled parallel, FERROMAGNETIC (very strongly attracted)Only ferri- and ferromagnetic materials are considered magnetic materialsHard and soft magnetic materials"Soft" (temporary-magnet) materials lose their net magnetization (form domains) when a magnetic field is removed - used for AC or on-off applications"Hard" (permanent-magnet) materials retain their magnetization after field is removed - used for applications requiring a steady magnetic fieldProperties of magnetic materialsSaturation magnetization is a measure of the magnetic field a material can produce when all atomic magnets are aligned - how "magnetic" it isCoercivity is the reverse magnetic field required to reduce the net magnetization to zero - how "permanent" it is. ("soft" = low coercivity, "hard" = high coercivity)(Other properties often quoted are the permeability of soft materials, which varies inversely with coercivity, and the energy product of hard materials, related to area of "hysteresis loop" & depends on both coercivity and saturation magnetization)History of hard (permanent-magnet) materialsLodestones - natural magnets based on magnetite (Fe3O4)Carbon steel (Fe-C) 18th-c. England (horseshoe shaped or bar magnets)Alloy steel (Fe-C+W, Mo, Cr, Co, etc.) - 19th and early 20th-c. (horseshoe or bar)Alnico (Fe+Al,Ni,Co) - 1930s & 1940s - helped Allies win World War IIHard Ferrite (Ba-Fe-O or Sr-Fe-O) - 1950s & 1960s - higher coercivity, cheap!Rare Earth (Sm-Co, Nd-Fe-B) - 1970s-1990s - VERY powerful, but NOT cheap Applicationsmagneticmaterials are used in applications requiring a steady (permanent)Hardmagnetic field. Recent increases in coercivity (resistance to demagnetization) and energy product (dependent on both coercivity and saturation magnetization, and related to the area within the hysteresis loop) have greatly increased the use of permanent magnets in modern technology. The widest applications are in motors, speakers, and sensors, but large quantities of Nd-Fe-B magnets are also used in permanent-magnet MRI systems, each of which uses about 2 tons of permanent magnet.For most applications, the amount of permanent magnet required is inversely proportional to the energy product. Available energy products have increased by a factor of fifty since the 1930s, allowing a corresponding decrease in the size of the magnet, and thus the size of the device. (e.g., small motors made possible by Nd-Fe-B magnets spin the disks and move the heads in computer disk drives, and small speakers produce music in the tiny earphones of i P ods and the like.)At least as important have been increases in coercivity by even greater factors, which allow a greater flexibility of magnet shape. Low-coercivity steel magnets required long bar magnets or horseshoe shapes to minimize demagnetization from reverse fields produced by the north and south poles at the ends of the magnet. (Before the advent of alnico magnets in the 1930s, telephone receivers were long and separate from the speakers because they included a long horseshoe-shaped steel magnet.)Materials for magnetic recording have also improved dramatically in recent years. The first magnetic recorder, patented in 1898, used steel piano wire. Magnetic tapes employing particles of iron oxide coated on plastic tapes were developed in Germany in the 1930s. Such tapes were used in the first commercial computers in the 1950s, and advanced versions remain in use today for audio and video applications, but today's computers instead store information in patterns of north and south poles on disks coated with thin films of cobalt-rich alloys.There have also been dramatic improvements in the properties of soft magnetic materials. Decreases in coercivity have decreased the energy losses of soft materials in ac applications, as have increases in electrical resistivity. Many transformers today useamorphous Fe-rich alloys, cooled so rapidly from the melt that they are unable to crystallize. An area of extensive current research is materials for recording heads, and improved materials have contributed to the remarkable increases in the density of information storage (bits per square inch).。

第31卷第2期 202丨年4月粉宋冶全工业P O W D E R M E T A L L U R G Y I N D U S T R YVol. 31，No.2,p52-56Apr. 2021DOI ： 10.13228/j.boyuan.issn 1006-6543.20200137磁场流速对传感器用C u电极电解过程及质量的影响孙娟'，孙栗2,金晗3(1.河南科技职业大学，河南周口466000; 2.国网浙江海宁市供电公司，浙江海宁314400;3.中原工学院能源与环境学院，河南郑州460000)摘要：在电解工艺制备铜的过程中加入磁场以达到协同强化效果，分析了磁场流速对传感器用C u电极电解过程及质量的影响。

结果表明：施加磁场后，形成了更复杂的铜电解反应。

当提高磁场流速后，铜阳极质量损失减小，最大阴极析出量出现于流速为0.25 m/s的情况下。

磁场流速对C u电极电解阶段的杂质离子产生着显著影响。

受到磁场作用后，杂质离子浓度减小，实际效果受到此磁场取向与流速的共同作用。

处于0.25 m/s磁场流速下，能够获得最大的阴极析出速率，从而减小电解液内的杂质离子浓度并降低铜损失。

处于垂直磁场中，在0〜0.75 m/s范围的电解液黏度基本恒定，并在0.25 m/s时达到最小值。

垂直磁场可以对电子传输发挥抑制作用，增强扩散效果。

随着流速的增大，阻碍了 Cir1扩散过程，在0.25 m/s速率下获得最大阴极析出量。

关键词：磁化电解;强磁场;铜电解;表面质量文献标志码：A 文章编号：1006-6543(2021)02-0052-05Effect of magnetic field velocity on electrolysis process and quality of Cuelectrode used in sensorSUN Juan1,SUN Li2,JIN Han3(1. Henan Vocational University of Science and Technology, Zhoukou 466000, China; 2. State Grid HainingPower Supply Company, Haining 314400, China; 3. School of Energy and Environment, Zhongyuan Universityof Technology, Zhengzhou 460000, China)A bstract：The effect of magnetic field velocity on the electrolytic process and the quality of Cu electrode used inthe sensor was analyzed.The results show that a more complex copper electrolysis reaction is formed by applying amagnetic field.After increasing the magnetic field velocity, the mass loss of copper anode decreased, and the maxi­mum cathode precipitation appeared at the flow rate of 0.25 m/s.The magnetic field velocity has a significant effecton the impurity ions in Cu electrode electrolysis stage.The concentration of impurity ions decreases after the mag­netic field is applied, and the actual effect is influenced by the magnetic field orientation and the flow velocity.Atthe magnetic field velocity of 0.25 m/s, the maximum cathode precipitation rate can be obtained, thus reducing theconcentration of impurity ions in the electrolyte and reducing the copper loss.In the vertical magnetic field, the elec­trolyte viscosity in the range of 0-0.75 m/s is basically constant, and reaches the minimum value at 0.25 m/s.Verti­cal magnetic field can inhibit electron transport and enhance diffusion.With the increase of flow rate, C u2'diffusionprocess was hindered, and the maximum cathode precipitation was obtained at the rate of 0.25 m/s.Key w ords：magnetization electrolysis; strong magnetic field; copper electrolysis; surface quality 现阶段，电解技术己经成为一种非常广泛的铜 制备工艺。

Heavy-Duty Digital Multimetercase and causing inaccurate readings or damaging shorts. Built of tough, fire-retardantthermoplastic resistant to grease and chemical spills, with all sensitive components shock-digital multimeters. The extended voltage ranges can withstand transients up to 12 kV.Magne-Grip™ holster, frees both hands0.1 x (spec. accuracy)/°C (0 ° to 18 °C and 28° to 50 °C) all functions and ranges except for mVDCHD110C ELECTRICAL SPECIFICATIONS DC VoltsRanges200 mV, 2 V, 20 V, 200 V, 1500 VResolution0.1 mVAccuracy±(0.1 % rdg+2 dgts)Input Impedance10 MΩOL Protection1500 V dc/1000 V ac rmsTransient Protection 12 kV impulse (1.2 μS/50 μS) based on EN 61010-1:2001 impulse requirement for at CAT IV 1000 V product. This product should not be used in installations where transients exceed 12 kV.AC Volts (45 Hz to 2 kHz)Ranges200 mV, 2 V, 20 V, 200 V, 1000 VResolution0.1 mVAccuracy 200 mV to 200 V (45-500 Hz) ±(0.8 % rdg+4 dgts) 200 mV to 200 V (500 Hz-2 kHz) ±(1.5 % rdg+5 dgts) 1000 V (50-60 Hz) ±(0.8 % rdg+4 dgts)1000 V (60-500 Hz) ±(1.5 % rdg+5 dgts)Input Impedance10 MΩOL Protection1500 V dc/1000 V ac rmsTransient Protection 12 kV impulse (1.2 μS/50 μS) based on EN 61010-1:2001 impulse requirement for at CAT IV 1000 V product. This product should not be used in installations where transients exceed 12 kV.DC CurrentRanges200 μA, 2 mA, 20 mA, 200 mA, 2 AResolution0.1 μAAccuracy 200 μA to 20 mA ±(0.5 % rdg+2 dgts) 200 mA to 2 A ±(1.0 % rdg+2 dgts)DC Current (cont.)Voltage Burden 250 mV max. (1 mV/1 μA on 200 μA Range) (100 mV/1 mA on 2 mA Range)(10 mV/1 mA on 20 mA Range)(1.5 mV/1 mA on 200 mA Range)(500 mV/1 A on 2 A Range)OL Protection A Input (F 2 A/1500 V, size 8 x 65 mm IR fast blow ceramic) (FP 700)AC Current (45 Hz to 1 kHz)Ranges200 μA, 2 mA, 20 mA, 200 mA, 2 AResolution0.1 μAAccuracy 200 μA to 20 mA ±(0.8 % rdg+4 dgts) 200 mA to 2 A ±(1.2 % rdg+4 dgts)Voltage Burden250 mV max. (1 V on 2 A range)OL Protection same as DC CurrentFor detailed specifications and ordering info go to ©2014 Beha-Amprobe. All rights reserved.ACD-23SW ELECTRICAL SPECIFICATIONSFor detailed specifications and ordering info go to Pub ID: 13102-eng ©2014 Beha-Amprobe. All rights reserved.Beha-Amprobe ®In den Engematten 14,79286 Glottertal, GermanyTlf.: +49 (0) 7684 8009 - 0ResistanceRanges200 Ω, 2 k Ω, 20 k Ω, 200 k Ω, 2 M Ω, 20 M ΩResolution 0.1 ΩAccuracy 200 Ω ±(0.5 % rdg+4 dgts)2 k Ω to 200 k Ω ±(0.3 %rdg+2 dgts)2 M Ω ±(1.0 % rdg+4 dgts)20 M Ω ±(2.0 %rdg+4 dgtsOL Protection 1500 V dc/1000 V ac rmsOpen Circuit Voltage200 Ω range 3.0 V dc typicalall other ranges 0.3 V dc typical.Diode/Continuity TestTest Current1m A dc typical Test/Open Circuit Voltage3.0 V dc Typical Diode Accuracy±(1.5 % rdg+2 dgts)Continuity Audible Threshold<50 Ω ± 25 ΩResponse Time<100 msec OL Protection 1500 V dc/1000 V ac rmsFor complete specifications please download the product datasheet and the users manual on .。