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半导体物理与器件(尼曼第四版)答案第一章：半导体材料与晶体1.1 半导体材料的基本特性半导体材料是一种介于导体和绝缘体之间的材料。
它的基本特性包括：1.带隙：半导体材料的价带与导带之间存在一个禁带或带隙，是电子在能量上所能占据的禁止区域。
2.拉伸系统：半导体材料的结构是由原子或分子构成的晶格结构，其中的原子或分子以确定的方式排列。
3.载流子：在半导体中，存在两种载流子，即自由电子和空穴。
自由电子是在导带上的，在外加电场存在的情况下能够自由移动的电子。
空穴是在价带上的，当一个价带上的电子从该位置离开时，会留下一个类似电子的空位，空穴可以看作电子离开后的痕迹。
4.掺杂：为了改变半导体材料的导电性能，通常会对其进行掺杂。
掺杂是将少量元素添加到半导体材料中，以改变载流子浓度和导电性质。
1.2 半导体材料的结构与晶体缺陷半导体材料的结构包括晶体结构和非晶态结构。
晶体结构是指材料具有有序的周期性排列的结构，而非晶态结构是指无序排列的结构。
晶体结构的特点包括：1.晶体结构的基本单位是晶胞，晶胞在三维空间中重复排列。
2.晶格常数是晶胞边长的倍数，用于描述晶格的大小。
3.晶体结构可分为离子晶体、共价晶体和金属晶体等不同类型。
晶体结构中可能存在各种晶体缺陷，包括：1.点缺陷：晶体中原子位置的缺陷，主要包括实际缺陷和自间隙缺陷两种类型。
2.线缺陷：晶体中存在的晶面上或晶内的线状缺陷，主要包括位错和脆性断裂两种类型。
3.面缺陷：晶体中存在的晶面上的缺陷，主要包括晶面位错和穿孔两种类型。
1.3 半导体制备与加工半导体制备与加工是指将半导体材料制备成具有特定电性能的器件的过程。
它包括晶体生长、掺杂、薄膜制备和微电子加工等步骤。
晶体生长是将半导体材料从溶液或气相中生长出来的过程。
常用的晶体生长方法包括液相外延法、分子束外延法和气相外延法等。
掺杂是为了改变半导体材料的导电性能，通常会对其进行掺杂。
常用的掺杂方法包括扩散法、离子注入和分子束外延法等。
半导体物理与器件第四版课后习题答案————————————————————————————————作者：————————————————————————————————日期：2______________________________________________________________________________________3Chapter 33.1If o a were to increase, the bandgap energy would decrease and the material would beginto behave less like a semiconductor and morelike a metal. If o a were to decrease, the bandgap energy would increase and thematerial would begin to behave more like an insulator._______________________________________ 3.2Schrodinger's wave equation is:()()()t x x V x t x m ,,2222ψ⋅+∂ψ∂-η()tt x j ∂ψ∂=,ηAssume the solution is of the form:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=ψt E kx j x u t x ηexp , Region I: ()0=x V . Substituting theassumed solution into the wave equation, we obtain:()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧∂∂-t E kx j x jku x m ηηexp 22 ()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u ηexp()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⋅⎪⎭⎫ ⎝⎛-=t E kx j x u jE j ηηηexp which becomes()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧-t E kx j x u jk m ηηexp 222()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u jk ηexp 2()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u ηexp 22()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-+=t E kx j x Eu ηexp This equation may be written as()()()()0222222=+∂∂+∂∂+-x u mE x x u x x u jk x u k ηSetting ()()x u x u 1= for region I, the equation becomes: ()()()()021221212=--+x u k dx x du jk dxx u d α where222ηmE=αQ.E.D.In Region II, ()O V x V =. Assume the same form of the solution:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=ψt E kx j x u t x ηexp , Substituting into Schrodinger's wave equation, we find:()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎩⎨⎧-t E kx j x u jk m ηηexp 222()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u jk ηexp 2()⎪⎭⎪⎬⎫⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-∂∂+t E kx j x x u ηexp 22()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-+t E kx j x u V O ηexp()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-=t E kx j x Eu ηexp This equation can be written as:______________________________________________________________________________________4()()()2222xx u x x u jk x u k ∂∂+∂∂+- ()()02222=+-x u mEx u mV O ηη Setting ()()x u x u 2= for region II, this equation becomes()()dx x du jkdx x u d 22222+()022222=⎪⎪⎭⎫ ⎝⎛+--x u mV k O ηα where again222ηmE=αQ.E.D._______________________________________ 3.3We have ()()()()021221212=--+x u k dx x du jk dxx u d α Assume the solution is of the form: ()()[]x k j A x u -=αexp 1 ()[]x k j B +-+αexpThe first derivative is()()()[]x k j A k j dxx du --=ααexp 1 ()()[]x k j B k j +-+-ααexpand the second derivative becomes()()[]()[]x k j A k j dxx u d --=ααexp 2212()[]()[]x k j B k j +-++ααexp 2Substituting these equations into the differential equation, we find()()[]x k j A k ---ααexp 2()()[]x k j B k +-+-ααexp 2(){()[]x k j A k j jk --+ααexp 2()()[]}x k j B k j +-+-ααexp ()()[]{x k j A k ---ααexp 22 ()[]}0exp =+-+x k j B α Combining terms, we obtain()()()[]222222αααα----+--k k k k k ()[]x k j A -⨯αexp()()()[]222222αααα--++++-+k k k k k()[]0exp =+-⨯x k j B α We find that00= Q.E.D.For the differential equation in ()x u 2 and theproposed solution, the procedure is exactly the same as above._______________________________________ 3.4We have the solutions()()[]x k j A x u -=αexp 1()[]x k j B +-+αexp for a x <<0 and()()[]x k j C x u -=βexp 2()[]x k j D +-+βexp for 0<<-x b .The first boundary condition is ()()0021u u =which yields0=--+D C B AThe second boundary condition is201===x x dx dudx du which yields()()()C k B k A k --+--βαα ()0=++D k βThe third boundary condition is ()()b u a u -=21 which yields()[]()[]a k j B a k j A +-+-ααexp exp ()()[]b k j C --=βexp ()()[]b k j D -+-+βexp______________________________________________________________________________________5and can be written as()[]()[]a k j B a k j A +-+-ααexp exp ()[]b k j C ---βexp ()[]0exp =+-b k j D βThe fourth boundary condition isbx a x dx dudx du -===21 which yields()()[]a k j A k j --ααexp()()[]a k j B k j +-+-ααexp()()()[]b k j C k j ---=ββexp()()()[]b k j D k j -+-+-ββexp and can be written as()()[]a k j A k --ααexp()()[]a k j B k +-+-ααexp ()()[]b k j C k ----ββexp()()[]0exp =+++b k j D k ββ_______________________________________ 3.5(b) (i) First point: πα=aSecond point: By trial and error, πα729.1=a (ii) First point: πα2=aSecond point: By trial and error, πα617.2=a _______________________________________ 3.6(b) (i) First point: πα=aSecond point: By trial and error, πα515.1=a (ii) First point: πα2=aSecond point: By trial and error, πα375.2=a _______________________________________ 3.7ka a aaP cos cos sin =+'ααα Let y ka =, x a =α Theny x x xP cos cos sin =+'Consider dydof this function.()[]{}y x x x P dyd sin cos sin 1-=+⋅'- We find()()()⎭⎬⎫⎩⎨⎧⋅+⋅-'--dy dx x x dy dx x x P cos sin 112y dydx x sin sin -=-Theny x x x x x P dy dx sin sin cos sin 12-=⎭⎬⎫⎩⎨⎧-⎥⎦⎤⎢⎣⎡+-' For πn ka y ==,...,2,1,0=n 0sin =⇒y So that, in general,()()dkd ka d a d dy dxαα===0 And22ηmE=α SodkdEm mE dk d ⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛=-22/122221ηηα This implies thatdk dE dk d ==0α for an k π= _______________________________________ 3.8(a) πα=a 1π=⋅a E m o 212η______________________________________________________________________________________6()()()()2103123422221102.41011.9210054.12---⨯⨯⨯==ππa m E o η19104114.3-⨯=J From Problem 3.5 πα729.12=aπ729.1222=⋅a E m o η()()()()2103123422102.41011.9210054.1729.1---⨯⨯⨯=πE18100198.1-⨯=J12E E E -=∆1918104114.3100198.1--⨯-⨯= 19107868.6-⨯=Jor 24.4106.1107868.61919=⨯⨯=∆--E eV(b) πα23=aπ2223=⋅a E m o η()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=J From Problem 3.5, πα617.24=aπ617.2224=⋅a E m o η()()()()2103123424102.41011.9210054.1617.2---⨯⨯⨯=πE18103364.2-⨯=J34E E E -=∆1818103646.1103364.2--⨯-⨯= 1910718.9-⨯=Jor 07.6106.110718.91919=⨯⨯=∆--E eV_______________________________________ 3.9(a) At π=ka , πα=a 1π=⋅a E m o 212η()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JAt 0=ka , By trial and error, πα859.0=a o()()()()210312342102.41011.9210054.1859.0---⨯⨯⨯=πo E19105172.2-⨯=J o E E E -=∆11919105172.2104114.3--⨯-⨯= 2010942.8-⨯=Jor 559.0106.110942.81920=⨯⨯=∆--E eV (b) At π2=ka , πα23=aπ2223=⋅a E m o η()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=J At π=ka . From Problem 3.5,πα729.12=aπ729.1222=⋅a E m o η()()()()2103123422102.41011.9210054.1729.1---⨯⨯⨯=πE18100198.1-⨯=J 23E E E -=∆1818100198.1103646.1--⨯-⨯= 19104474.3-⨯=Jor 15.2106.1104474.31919=⨯⨯=∆--E eV_____________________________________________________________________________________________________________________________73.10(a) πα=a 1π=⋅a E m o 212η()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=JFrom Problem 3.6, πα515.12=aπ515.1222=⋅a E m o η()()()()2103123422102.41011.9210054.1515.1---⨯⨯⨯=πE1910830.7-⨯=J 12E E E -=∆1919104114.310830.7--⨯-⨯= 19104186.4-⨯=Jor 76.2106.1104186.41919=⨯⨯=∆--E eV(b) πα23=aπ2223=⋅a E m o η()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JFrom Problem 3.6, πα375.24=aπ375.2224=⋅a E m o η()()()()2103123424102.41011.9210054.1375.2---⨯⨯⨯=πE18109242.1-⨯=J 34E E E -=∆1818103646.1109242.1--⨯-⨯=1910597.5-⨯=Jor 50.3106.110597.51919=⨯⨯=∆--E eV _____________________________________3.11(a) At π=ka , πα=a 1π=⋅a E m o 212η()()()()2103123421102.41011.9210054.1---⨯⨯⨯=πE19104114.3-⨯=J At 0=ka , By trial and error, πα727.0=a o π727.022=⋅a E m o o η()()()()210312342102.41011.9210054.1727.0---⨯⨯⨯=πo E19108030.1-⨯=J o E E E -=∆11919108030.1104114.3--⨯-⨯= 19106084.1-⨯=Jor 005.1106.1106084.11919=⨯⨯=∆--E eV (b) At π2=ka , πα23=aπ2223=⋅a E m o η()()()()2103123423102.41011.9210054.12---⨯⨯⨯=πE18103646.1-⨯=JAt π=ka , From Problem 3.6, πα515.12=aπ515.1222=⋅a E m o η()()()()2103423422102.41011.9210054.1515.1---⨯⨯⨯=πE1910830.7-⨯=J 23E E E -=∆191810830.7103646.1--⨯-⨯=______________________________________________________________________________________81910816.5-⨯=Jor 635.3106.110816.51919=⨯⨯=∆--E eV_______________________________________ 3.12For 100=T K,()()⇒+⨯-=-1006361001073.4170.124g E164.1=g E eV200=T K, 147.1=g E eV 300=T K, 125.1=g E eV 400=T K, 097.1=g E eV 500=T K, 066.1=g E eV 600=T K, 032.1=g E eV _______________________________________ 3.13The effective mass is given by1222*1-⎪⎪⎭⎫ ⎝⎛⋅=dk E d m ηWe have()()B curve dkEd A curve dk E d 2222>so that ()()B curve m A curve m **<_______________________________________ 3.14The effective mass for a hole is given by1222*1-⎪⎪⎭⎫ ⎝⎛⋅=dk E d m p η We have that()()B curve dkEd A curve dk E d 2222> so that ()()B curve m A curve m p p **<_______________________________________ 3.15Points A,B: ⇒<0dkdEvelocity in -x direction Points C,D: ⇒>0dkdEvelocity in +x directionPoints A,D: ⇒<022dk Ednegative effective massPoints B,C: ⇒>022dkEd positive effective mass_______________________________________ 3.16For A: 2k C E i =At 101008.0+⨯=k m 1-, 05.0=E eV Or()()2119108106.105.0--⨯=⨯=E JSo ()2101211008.0108⨯=⨯-C3811025.1-⨯=⇒CNow ()()38234121025.1210054.12--*⨯⨯==C m η 311044.4-⨯=kgor o m m ⋅⨯⨯=--*31311011.9104437.4 o m m 488.0=*For B: 2k C E i =At 101008.0+⨯=k m 1-, 5.0=E eV Or ()()2019108106.15.0--⨯=⨯=E JSo ()2101201008.0108⨯=⨯-C 3711025.1-⨯=⇒CNow ()()37234121025.1210054.12--*⨯⨯==C m η321044.4-⨯=kgor o m m ⋅⨯⨯=--*31321011.9104437.4o m m 0488.0=*_____________________________________________________________________________________________________________________________93.17For A: 22k C E E -=-υ()()()2102191008.0106.1025.0⨯-=⨯--C3921025.6-⨯=⇒C ()()39234221025.6210054.12--*⨯⨯-=-=C m η31108873.8-⨯-=kgor o m m ⋅⨯⨯-=--*31311011.9108873.8o m m 976.0--=* For B: 22k C E E -=-υ()()()2102191008.0106.13.0⨯-=⨯--C382105.7-⨯=⇒C()()3823422105.7210054.12--*⨯⨯-=-=C m η3210406.7-⨯-=kgor o m m ⋅⨯⨯-=--*31321011.910406.7o m m 0813.0-=*_______________________________________ 3.18(a) (i) νh E =or ()()341910625.6106.142.1--⨯⨯==h E ν1410429.3⨯=Hz(ii) 141010429.3103⨯⨯===νλc E hc 51075.8-⨯=cm 875=nm(b) (i) ()()341910625.6106.112.1--⨯⨯==h E ν 1410705.2⨯=Hz(ii) 141010705.2103⨯⨯==νλc410109.1-⨯=cm 1109=nm _______________________________________ 3.19(c) Curve A: Effective mass is a constantCurve B: Effective mass is positive around 0=k , and is negativearound 2π±=k ._______________________________________ 3.20()[]O O k k E E E --=αcos 1 Then()()()[]O k k E dkdE---=ααsin 1()[]O k k E -+=ααsin 1 and()[]O k k E dkEd -=ααcos 2122Then221222*11ηηαE dk Ed m o k k =⋅== or212*αE m η=_______________________________________ 3.21(a) ()[]3/123/24l t dnm m m =*()()[]3/123/264.1082.04o o m m =o dnm m 56.0=*(b)oo l t cn m m m m m 64.11082.02123+=+=*oo m m 6098.039.24+=o cnm m 12.0=*_______________________________________ 3.22(a) ()()[]3/22/32/3lh hh dp m m m +=*______________________________________________________________________________________10()()[]3/22/32/3082.045.0o o m m +=[]o m ⋅+=3/202348.030187.0o dpm m 473.0=*(b) ()()()()2/12/12/32/3lh hh lh hh cpm m m m m ++=* ()()()()om ⋅++=2/12/12/32/3082.045.0082.045.0 o cpm m 34.0=*_______________________________________3.23For the 3-dimensional infinite potential well, ()0=x V when a x <<0, a y <<0, and a z <<0. In this region, the wave equation is:()()()222222,,,,,,z z y x y z y x x z y x ∂∂+∂∂+∂∂ψψψ()0,,22=+z y x mEψηUse separation of variables technique, so let ()()()()z Z y Y x X z y x =,,ψSubstituting into the wave equation, we have222222zZXY y Y XZ x X YZ ∂∂+∂∂+∂∂ 022=⋅+XYZ mEηDividing by XYZ , we obtain021*********=+∂∂⋅+∂∂⋅+∂∂⋅ηmE z Z Z y Y Y x X X Let01222222=+∂∂⇒-=∂∂⋅X k x X k x X X xx The solution is of the form: ()x k B x k A x X x x cos sin += Since ()0,,=z y x ψ at 0=x , then ()00=Xso that 0=B .Also, ()0,,=z y x ψ at a x =, so that()0=a X . Then πx x n a k = where...,3,2,1=x n Similarly, we have2221y k y Y Y -=∂∂⋅ and 2221z k zZ Z -=∂∂⋅From the boundary conditions, we find πy y n a k = and πz z n a k = where...,3,2,1=y n and ...,3,2,1=z n From the wave equation, we can write022222=+---ηmE k k k z y xThe energy can be written as()222222⎪⎭⎫ ⎝⎛++==a n n n m E E z y x n n n z y x πη _______________________________________ 3.24The total number of quantum states in the 3-dimensional potential well is given (in k-space) by()332a dk k dk k g T ⋅=ππ where222ηmEk =We can then writeηmEk 2=Taking the differential, we obtaindE Em dE E m dk ⋅⋅=⋅⋅⋅⋅=2112121ηηSubstituting these expressions into the densityof states function, we have()dE EmmE a dE E g T ⋅⋅⋅⎪⎭⎫ ⎝⎛=212233ηηππ Noting thatπ2h=ηthis density of states function can be simplified and written as______________________________________________________________________________________()()dE E m h a dE E g T ⋅⋅=2/33324πDividing by 3a will yield the density of states so that()()E hm E g ⋅=32/324π _______________________________________ 3.25For a one-dimensional infinite potential well,222222k an E m n ==*πη Distance between quantum states()()aa n a n k k n n πππ=⎪⎭⎫ ⎝⎛=⎪⎭⎫ ⎝⎛+=-+11Now()⎪⎭⎫ ⎝⎛⋅=a dkdk k g T π2NowE m k n*⋅=21ηdE Em dk n⋅⋅⋅=*2211η Then()dE Em a dE E g n T ⋅⋅⋅=*2212ηπDivide by the "volume" a , so()Em E g n *⋅=21πηSo()()()()()EE g 31341011.9067.0210054.11--⨯⋅⨯=π ()EE g 1810055.1⨯=m 3-J 1-_______________________________________ 3.26(a) Silicon, o nm m 08.1=*()()c nc E E h m E g -=*32/324π()dE E E h m g kTE E c nc c c⋅-=⎰+*232/324π()()kT E E c nc cE E h m 22/332/33224+*-⋅⋅=π()()2/332/323224kT h m n⋅⋅=*π ()()[]()()2/33342/33123210625.61011.908.124kT ⋅⋅⨯⨯=--π ()()2/355210953.7kT ⨯=(i) At 300=T K, 0259.0=kT eV ()()19106.10259.0-⨯=2110144.4-⨯=J Then()()[]2/3215510144.4210953.7-⨯⨯=c g25100.6⨯=m 3- or 19100.6⨯=c g cm 3-(ii) At 400=T K, ()⎪⎭⎫⎝⎛=3004000259.0kT034533.0=eV()()19106.1034533.0-⨯=21105253.5-⨯=J Then()()[]2/32155105253.5210953.7-⨯⨯=c g2510239.9⨯=m 3-or 191024.9⨯=c g cm 3-(b) GaAs, o nm m 067.0=*()()[]()()2/33342/33123210625.61011.9067.024kT g c ⋅⋅⨯⨯=--π ()()2/3542102288.1kT ⨯=______________________________________________________________________________________(i) At 300=T K, 2110144.4-⨯=kT J()()[]2/3215410144.42102288.1-⨯⨯=c g2310272.9⨯=m 3- or 171027.9⨯=c g cm 3-(ii) At 400=T K, 21105253.5-⨯=kT J()()[]2/32154105253.52102288.1-⨯⨯=c g2410427.1⨯=m 3- 181043.1⨯=c g cm 3-_______________________________________ 3.27(a) Silicon, o p m m 56.0=* ()()E E h mE g p-=*υυπ32/324()dE E E h m g E kTE p⋅-=⎰-*υυυυπ332/324()()υυυπE kTE pE E h m 32/332/33224-*-⎪⎭⎫ ⎝⎛-=()()[]2/332/333224kT h mp-⎪⎭⎫ ⎝⎛-=*π ()()[]()()2/33342/33133210625.61011.956.024kT ⎪⎭⎫ ⎝⎛⨯⨯=--π ()()2/355310969.2kT ⨯=(i)At 300=T K, 2110144.4-⨯=kT J ()()[]2/3215510144.4310969.2-⨯⨯=υg2510116.4⨯=m 3- or 191012.4⨯=υg cm 3-(ii)At 400=T K, 21105253.5-⨯=kT J ()()[]2/32155105253.5310969.2-⨯⨯=υg2510337.6⨯=m 3-or 191034.6⨯=υg cm 3- (b) GaAs, o p m m 48.0=*()()[]()()2/33342/33133210625.61011.948.024kT g ⎪⎭⎫ ⎝⎛⨯⨯=--πυ ()()2/3553103564.2kT ⨯=(i)At 300=T K, 2110144.4-⨯=kT J ()()[]2/3215510144.43103564.2-⨯⨯=υg2510266.3⨯=m 3- or 191027.3⨯=υg cm 3-(ii)At 400=T K, 21105253.5-⨯=kT J()()[]2/32155105253.53103564.2-⨯⨯=υg2510029.5⨯=m 3-or 191003.5⨯=υg cm 3-_______________________________________ 3.28(a) ()()c nc E E h m E g -=*32/324π()()[]()c E E -⨯⨯=--3342/33110625.61011.908.124πc E E -⨯=56101929.1 For c E E =; 0=c g1.0+=c E E eV; 4610509.1⨯=c g m 3-J 1-2.0+=c E E eV;4610134.2⨯=m 3-J 1- 3.0+=c E E eV; 4610614.2⨯=m 3-J 1- 4.0+=c E E eV; 4610018.3⨯=m 3-J 1-(b) ()E E hm g p-=*υυπ32/324()()[]()E E -⨯⨯=--υπ3342/33110625.61011.956.024E E -⨯=υ55104541.4______________________________________________________________________________________For υE E =; 0=υg 1.0-=υE E eV; 4510634.5⨯=υg m 3-J 1-2.0-=υE E eV;4510968.7⨯=m 3-J 1-3.0-=υE E eV; 4510758.9⨯=m 3-J 1-4.0-=υE E eV;4610127.1⨯=m 3-J 1-_______________________________________ 3.29(a) ()()68.256.008.12/32/32/3=⎪⎭⎫ ⎝⎛==**pnc m m g g υ(b) ()()0521.048.0067.02/32/32/3=⎪⎭⎫ ⎝⎛==**pncmm g g υ_______________________________________3.30 Plot_______________________________________ 3.31(a) ()()()!710!7!10!!!-=-=i i i i i N g N g W()()()()()()()()()()()()1201238910!3!7!78910===(b) (i) ()()()()()()()()12!10!101112!1012!10!12=-=i W 66= (ii)()()()()()()()()()()()()1234!8!89101112!812!8!12=-=i W 495=_______________________________________ 3.32()⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F exp 11(a) kT E E F =-, ()()⇒+=1exp 11E f ()269.0=E f(b) kT E E F 5=-, ()()⇒+=5exp 11E f()31069.6-⨯=E f (c) kT E E F 10=-, ()()⇒+=10exp 11E f()51054.4-⨯=E f_______________________________________ 3.33()⎪⎪⎭⎫ ⎝⎛-+-=-kT E E E f F exp 1111or()⎪⎪⎭⎫⎝⎛-+=-kT E E E f F exp 111(a) kT E E F =-, ()269.01=-E f (b) kT E E F 5=-, ()31069.61-⨯=-E f (c) kT E E F 10=-, ()51054.41-⨯=-E f_______________________________________ 3.34(a) ()⎥⎦⎤⎢⎣⎡--≅kT E E f F F exp c E E =; 61032.90259.030.0exp -⨯=⎥⎦⎤⎢⎣⎡-=F f 2kT E c +; ()⎥⎦⎤⎢⎣⎡+-=0259.020259.030.0exp F f 61066.5-⨯=kT E c +; ()⎥⎦⎤⎢⎣⎡+-=0259.00259.030.0exp F f 61043.3-⨯=23kT E c +; ()()⎥⎦⎤⎢⎣⎡+-=0259.020259.0330.0exp F f 61008.2-⨯=kT E c 2+; ()()⎥⎦⎤⎢⎣⎡+-=0259.00259.0230.0exp F f 61026.1-⨯=______________________________________________________________________________________(b) ⎥⎦⎤⎢⎣⎡-+-=-kT E E f F F exp 1111()⎥⎦⎤⎢⎣⎡--≅kT E E F exp υE E =; ⎥⎦⎤⎢⎣⎡-=-0259.025.0exp 1F f 51043.6-⨯= 2kT E -υ; ()⎥⎦⎤⎢⎣⎡+-=-0259.020259.025.0exp 1F f 51090.3-⨯=kT E -υ; ()⎥⎦⎤⎢⎣⎡+-=-0259.00259.025.0exp 1F f 51036.2-⨯=23kT E -υ;()()⎥⎦⎤⎢⎣⎡+-=-0259.020259.0325.0exp 1F f 51043.1-⨯= kT E 2-υ;()()⎥⎦⎤⎢⎣⎡+-=-0259.00259.0225.0exp 1F f 61070.8-⨯=_______________________________________ 3.35()()⎥⎦⎤⎢⎣⎡-+-=⎥⎦⎤⎢⎣⎡--=kT E kT E kT E E f F c F F exp exp and()⎥⎦⎤⎢⎣⎡--=-kT E E f F F exp 1()()⎥⎦⎤⎢⎣⎡---=kT kT E E F υexp So ()⎥⎦⎤⎢⎣⎡-+-kT E kT E F c exp()⎥⎦⎤⎢⎣⎡+--=kT kT E E F υexp Then kT E E E kT E F F c +-=-+υOr midgap c F E E E E =+=2υ_______________________________________ 3.3622222man E n πη= For 6=n , Filled state()()()()()2103122234610121011.92610054.1---⨯⨯⨯=πE18105044.1-⨯=Jor 40.9106.1105044.119186=⨯⨯=--E eVFor 7=n , Empty state()()()()()2103122234710121011.92710054.1---⨯⨯⨯=πE1810048.2-⨯=Jor 8.12106.110048.219187=⨯⨯=--E eVTherefore 8.1240.9<<F E eV_______________________________________ 3.37(a) For a 3-D infinite potential well ()222222⎪⎭⎫⎝⎛++=a n n n mE z y x πη For 5 electrons, the 5thelectron occupies the quantum state 1,2,2===z y x n n n ; so()2222252⎪⎭⎫ ⎝⎛++=a n n n m E z y x πη()()()()()21031222223410121011.9212210054.1---⨯⨯++⨯=π 1910761.3-⨯=Jor 35.2106.110761.319195=⨯⨯=--E eV For the next quantum state, which is empty, the quantum state is 2,2,1===z y x n n n . This quantum state is at the same energy, so 35.2=F E eV(b) For 13 electrons, the 13th electronoccupies the quantum state______________________________________________________________________________________3,2,3===z y x n n n ; so ()()()()()2103122222341310121011.9232310054.1---⨯⨯++⨯=πE 1910194.9-⨯=Jor 746.5106.110194.9191913=⨯⨯=--E eVThe 14th electron would occupy the quantum state 3,3,2===z y x n n n . This state is at the same energy, so 746.5=F E eV_______________________________________ 3.38The probability of a state at E E E F ∆+=1 being occupied is()⎪⎭⎫ ⎝⎛∆+=⎪⎪⎭⎫ ⎝⎛-+=kT E kT E E E f F exp 11exp 11111 The probability of a state at E E E F ∆-=2being empty is()⎪⎪⎭⎫ ⎝⎛-+-=-kT E E E f F 222exp 1111⎪⎭⎫ ⎝⎛∆-+⎪⎭⎫ ⎝⎛∆-=⎪⎭⎫ ⎝⎛∆-+-=kT E kT E kT E exp 1exp exp 111 or()⎪⎭⎫ ⎝⎛∆+=-kT E E f exp 11122 so ()()22111E f E f -= Q.E.D._______________________________________ 3.39(a) At energy 1E , we want01.0exp 11exp 11exp 1111=⎪⎪⎭⎫ ⎝⎛-+⎪⎪⎭⎫ ⎝⎛-+-⎪⎪⎭⎫ ⎝⎛-kT E E kT E E kT E E F F FThis expression can be written as01.01exp exp 111=-⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-+kT E E kT E E F For()⎪⎪⎭⎫⎝⎛-=kT E E F 1exp 01.01Then()100ln 1kT E E F += orkT E E F 6.41+= (b)At kT E E F 6.4+=,()()6.4exp 11exp 1111+=⎪⎪⎭⎫ ⎝⎛-+=kT E E E f F which yields()01.000990.01≅=E f_______________________________________ 3.40 (a)()()⎥⎦⎤⎢⎣⎡--=⎥⎦⎤⎢⎣⎡--=0259.050.580.5exp exp kT E E f F F 61032.9-⨯=(b) ()060433.03007000259.0=⎪⎭⎫⎝⎛=kT eV31098.6060433.030.0exp -⨯=⎥⎦⎤⎢⎣⎡-=F f (c) ()⎥⎦⎤⎢⎣⎡--≅-kT E E f F F exp 1 ⎥⎦⎤⎢⎣⎡-=kT 25.0exp 02.0______________________________________________________________________________________or 5002.0125.0exp ==⎥⎦⎤⎢⎣⎡+kT ()50ln 25.0=kTor()()⎪⎭⎫⎝⎛===3000259.0063906.050ln 25.0T kTwhich yields 740=T K_______________________________________ 3.41 (a)()00304.00259.00.715.7exp 11=⎪⎭⎫ ⎝⎛-+=E for 0.304%(b) At 1000=T K, 08633.0=kT eV Then()1496.008633.00.715.7exp 11=⎪⎭⎫ ⎝⎛-+=E for 14.96%(c) ()997.00259.00.785.6exp 11=⎪⎭⎫⎝⎛-+=E for 99.7% (d)At F E E =, ()21=E f for alltemperatures_______________________________________ 3.42(a) For 1E E =()()⎥⎦⎤⎢⎣⎡--≅⎪⎪⎭⎫ ⎝⎛-+=kT E E kTE E E fF F11exp exp 11Then()611032.90259.030.0exp -⨯=⎪⎭⎫ ⎝⎛-=E fFor 2E E =,82.030.012.12=-=-E E F eV Then()⎪⎭⎫ ⎝⎛-+-=-0259.082.0exp 1111E for()⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛---≅-0259.082.0exp 111E f141078.10259.082.0exp -⨯=⎪⎭⎫ ⎝⎛-=(b) For 4.02=-E E F eV, 72.01=-F E E eV At 1E E =,()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.072.0exp exp 1kT E E E f F or()131045.8-⨯=E f At 2E E =,()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1⎪⎭⎫ ⎝⎛-=0259.04.0expor()71096.11-⨯=-E f_______________________________________ 3.43(a) At 1E E =()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.030.0exp exp 1kT E E E f F or()61032.9-⨯=E f At 2E E =, 12.13.042.12=-=-E E F eV So()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1⎪⎭⎫ ⎝⎛-=0259.012.1exp______________________________________________________________________________________or()191066.11-⨯=-E f(b) For 4.02=-E E F ,02.11=-F E E eV At 1E E =,()()⎪⎭⎫⎝⎛-=⎥⎦⎤⎢⎣⎡--=0259.002.1exp exp 1kT E E E f F or()181088.7-⨯=E f At 2E E =,()()⎥⎦⎤⎢⎣⎡--=-kT E E E f F 2exp 1⎪⎭⎫ ⎝⎛-=0259.04.0expor ()71096.11-⨯=-E f_______________________________________ 3.44()1exp 1-⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+=kTE E E f Fso()()2exp 11-⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+-=kT E E dE E df F⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫⎝⎛⨯kT E E kT F exp 1 or()2exp 1exp 1⎥⎦⎤⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-+⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫⎝⎛-=kT E E kT E E kT dE E df F F (a) At 0=T K, For()00exp =⇒=∞-⇒<dE dfE E F()0exp =⇒+∞=∞+⇒>dEdfE E FAt -∞=⇒=dEdfE E F(b) At 300=T K, 0259.0=kT eVFor F E E <<,0=dE dfFor F E E >>, 0=dEdfAt F E E =,()()65.91110259.012-=+⎪⎭⎫ ⎝⎛-=dE df (eV)1-(c) At 500=T K, 04317.0=kT eVFor F E E <<, 0=dE dfFor F E E >>, 0=dEdfAt F E E =, ()()79.511104317.012-=+⎪⎭⎫ ⎝⎛-=dE df (eV)1- _______________________________________ 3.45(a) At midgap E E =,()⎪⎪⎭⎫ ⎝⎛+=⎪⎪⎭⎫ ⎝⎛-+=kTE kTE E E f gF2exp 11exp 11Si: 12.1=g E eV, ()()⎥⎦⎤⎢⎣⎡+=0259.0212.1exp 11E for()101007.4-⨯=E fGe: 66.0=g E eV______________________________________________________________________________________()()⎥⎦⎤⎢⎣⎡+=0259.0266.0exp 11E for()61093.2-⨯=E f GaAs: 42.1=g E eV ()()⎥⎦⎤⎢⎣⎡+=0259.0242.1exp 11E for()121024.1-⨯=E f(b) Using the results of Problem 3.38, the answers to part (b) are exactly the same as those given in part (a)._______________________________________ 3.46(a) ()⎥⎦⎤⎢⎣⎡--=kT E E f F F exp ⎥⎦⎤⎢⎣⎡-=-kT 60.0exp 108 or ()810ln 60.0+=kT()032572.010ln 60.08==kT eV()⎪⎭⎫⎝⎛=3000259.0032572.0Tso 377=T K(b) ⎥⎦⎤⎢⎣⎡-=-kT 60.0exp 106()610ln 60.0+=kT()043429.010ln 60.06==kT ()⎪⎭⎫⎝⎛=3000259.0043429.0Tor 503=T K_______________________________________ 3.47(a) At 200=T K,()017267.03002000259.0=⎪⎭⎫⎝⎛=kT eV⎪⎪⎭⎫ ⎝⎛-+==kTE E f FF exp 1105.019105.01exp =-=⎪⎪⎭⎫⎝⎛-kT E E F()()()19ln 017267.019ln ==-kT E E F 05084.0=eV By symmetry, for 95.0=F f , 05084.0-=-F E E eVThen ()1017.005084.02==∆E eV (b) 400=T K, 034533.0=kT eV For 05.0=F f , from part (a),()()()19ln 034533.019ln ==-kT E E F 10168.0=eV Then ()2034.010168.02==∆E eV_______________________________________。
半导体物理第四版答案【篇一：(考试范围)半导体物理学课后题答案】格常数为a的一维晶格，导带极小值附近能量ec(k)和价带极大值附近能量ev(k)分别为：h2(k?k1)2h2k2h2k213h2k2,ev(k) ec（k）= 3m0m06m0m0m0为电子惯性质量，k1?a,a?0.314nm。
试求：（1）禁带宽度;（2）导带底电子有效质量; （3）价带顶电子有效质量;（4）价带顶电子跃迁到导带底时准动量的变化解：（1）导带：2?2k2?2(k?k1)由??03m0m03k14d2ec2?22?28?2203m0m03m0dk得：k?所以：在k?价带：dev6?2k0得k?0dkm0d2ev6?2又因为0,所以k?0处，ev取极大值2m0dk?2k123因此：eg?ec(k1)?ev(0)??0.64ev412m03k处，ec取极小值4(2)m*nc22decdk23?m0 83k?k141(3)m*nv22devdk2k?01m06(4)准动量的定义：p??k所以：?p?(?k)3k?k143(k)k0k107.951025n/s42. 晶格常数为0.25nm的一维晶格，当外加102v/m，107 v/m的电场时，试分别计算电子自能带底运动到能带顶所需的时间。
解：根据：f?qe?h (0t1k?k得?t?qet)8.27108s1.61019102(0a8.271013s)?107t21.61019半导体物理第2章习题5. 举例说明杂质补偿作用。
当半导体中同时存在施主和受主杂质时，若（1） ndna因为受主能级低于施主能级，所以施主杂质的电子首先跃迁到na个受主能级上，还有nd-na个电子在施主能级上，杂质全部电离时，跃迁到导带中的导电电子的浓度为n= nd-na。
即则有效受主浓度为naeff≈ nd-na （2）nand施主能级上的全部电子跃迁到受主能级上，受主能级上还有na-nd个空穴，它们可接受价带上的na-nd个电子，在价带中形成的空穴浓度p= na-nd. 即有效受主浓度为naeff≈ na-nd （3）na?nd时，不能向导带和价带提供电子和空穴，称为杂质的高度补偿 6. 说明类氢模型的优点和不足。
______________________________________________________________________________________Chapter 1Problem Solutions1.1 (a)fcc: 8 corner atoms 18/1atom6 face atoms32/1atomsTotal of 4 atoms per unit cell (b)bcc: 8 corner atoms 18/1atom1 enclosed atom=1 atom Total of 2 atoms per unit cell(c)Diamond: 8 corner atoms 18/1atom6 faceatoms 32/1atoms4 enclosedatoms= 4 atomsTotal of 8 atoms per unit cell_______________________________________ 1.2 (a)Simple cubic lattice: r a 2Unit cell vol33382rra1 atom per cell, so atom vol 3413r ThenRatio%4.52%10083433rr(b)Face-centered cubic latticerd aa rd22224Unit cell vol 33321622rr a4 atoms per cell, so atom vol3443r ThenRatio%74%10021634433rr (c)Body-centered cubic latticeraa rd3434Unit cell vol 3334ra2 atoms per cell, so atom vol 3423r ThenRatio%68%1003434233r r (d)Diamond lattice Body diagonal raa rd3838Unit cell vol3338r a8 atoms per cell, so atom vol 3483r ThenRatio%34%1003834833rr _______________________________________1.3(a)oA a43.5; From Problem 1.2d,ra38Then oAa r176.18343.583Center of one silicon atom to center ofnearest neighboroAr 35.22______________________________________________________________________________________ (b)Number density22381051043.58cm 3(c)Mass density23221002.609.28105..AN W t At N 33.2grams/cm3_______________________________________1.4(a)4 Ga atoms per unit cell Number density381065.54Density of Ga atoms 221022.2cm34 As atoms per unit cell Density of As atoms 221022.2cm3(b)8 Ge atoms per unit cell Number density381065.58Density of Ge atoms221044.4cm3_______________________________________ 1.5From Figure 1.15 (a)aa d4330.0232oAd 447.265.54330.0(b)aa d7071.022oAd 995.365.57071.0_______________________________________1.674.5423232222sin a a 5.109_______________________________________ 1.7(a) Simple cubic: oAr a 9.32(b)fcc:oAr a515.524(c) bcc:oA r a 503.434(d) diamond:oAra007.9342_______________________________________ 1.8 (a)Br 2035.122035.12oBAr 4287.0(b)oAa 07.2035.12(c)A-atoms: # of atoms1818Density381007.21231013.1cm3B-atoms: # of atoms3216Density381007.23231038.3cm3_______________________________________ 1.9(a)oAr a 5.42# of atoms1818Number density38105.412210097.1cm3______________________________________________________________________________________Mass density AN W t At N ..23221002.65.12100974.1228.0gm/cm3(b)oAr a196.534# of atoms 21818Number density3810196.5222104257.1cm3Mass density23221002.65.12104257.1296.0gm/cm3_______________________________________ 1.10From Problem 1.2, percent volume of fcc atoms is 74%; Therefore after coffee is ground,Volume = 0.74 cm3_______________________________________1.11(b)oAa 8.20.18.1(c)Na: Density38108.22/1221028.2cm3Cl: Density221028.2cm3(d)Na: At. Wt. = 22.99 Cl: At. Wt. = 35.45 So, mass per unit cell23231085.41002.645.352199.2221Then mass density21.2108.21085.43823grams/cm3_______________________________________ 1.12(a)oAa 88.122.223Then oA a 62.4Density of A:22381001.11062.41cm3Density of B:22381001.11062.41cm3(b)Same as (a) (c)Same material_______________________________________ 1.13oAa619.438.122.22(a) For 1.12(a), A-atomsSurface density28210619.411a1410687.4cm2For 1.12(b), B-atoms: oAa 619.4Surface density14210687.41acm2For 1.12(a) and (b), Same material(b) For 1.12(a), A-atoms;oAa 619.4Surface density212a1410315.3cm2B-atoms;Surface density______________________________________________________________________________________14210315.321a cm 2For 1.12(b), A-atoms;oAa 619.4Surface density212a1410315.3cm2B-atoms;Surface density14210315.321acm2For 1.12(a) and (b), Same material_______________________________________ 1.14 (a)Vol. Density31oaSurface Density212oa(b)Same as (a)_______________________________________ 1.15 (i)(110) plane(see Figure 1.10(b))(ii) (111) plane(see Figure 1.10(c))(iii) (220) plane,1,1,21,21Same as (110) plane and [110]direction(iv) (321) plane6,3,211,21,31Intercepts of plane at6,3,2sq p [321] direction is perpendicular to(321) plane_______________________________________1.16(a)31311,31,11(b)12141,21,41_______________________________________ 1.17Intercepts: 2, 4, 331,41,21(634) plane_______________________________________ 1.18(a)oAa d 28.5(b)oAa d734.322(c)oAa d048.333_______________________________________ 1.19(a) Simple cubic(i) (100) plane:Surface density2821073.411a141047.4cm 2(ii) (110) plane:Surface density212a141016.3cm 2(iii) (111) plane: Area of planebh21where oAa b 689.62Now2222243222a a a hSooAh793.573.426______________________________________________________________________________________Area of plane881079304.51068923.62116103755.19cm 2Surface density16103755.19613141058.2cm2(b) bcc(i) (100) plane:Surface density 1421047.41acm2(ii) (110) plane: Surface density222a141032.6cm 2(iii) (111) plane:Surface density16103755.19613141058.2cm2(c) fcc(i) (100) plane:Surface density 1421094.82acm2(ii) (110) plane: Surface density222a141032.6cm 2(iii) (111) plane:Surface density16103755.19213613151003.1cm2_______________________________________ 1.20 (a)(100) plane: - similar to a fcc:Surface density281043.52141078.6cm 2(b)(110) plane:Surface density281043.524141059.9cm2(c)(111) plane: Surface density281043.5232141083.7cm2_______________________________________1.21oAr a703.6237.2424(a)#/cm338310703.64216818a2210328.1cm3(b)#/cm222124142a210703.62281410148.3cm2(c)oA a d74.422703.622(d)# of atoms2213613Area of plane: (see Problem 1.19)oAa b4786.92oAa h2099.826Area88102099.8104786.92121bh______________________________________________________________________________________15108909.3cm2#/cm215108909.32=141014.5cm2oAa d87.333703.633_______________________________________ 1.22Density of silicon atoms 22105cm3and4 valence electrons per atom, soDensity of valence electrons 23102cm3_______________________________________ 1.23Density of GaAs atoms22381044.41065.58cm3An average of 4 valence electrons peratom,SoDensity of valence electrons231077.1cm3_______________________________________ 1.24 (a)%10%10010510532217(b)%104%10010510262215_______________________________________ 1.25 (a)Fraction by weight7221610542.106.2810582.10102(b)Fraction by weight5221810208.206.2810598.3010_______________________________________ 1.26Volume density 1631021dcm3So610684.3dcmoAd 4.368We haveoo Aa 43.5Then85.6743.54.368oa d _______________________________________ 1.27Volume density 1531041dcm 3So61030.6dcmoAd630We have oo Aa 43.5Then11643.5630oa d _______________________________________。
半导体物理与器件习题答案【篇一：半导体物理与器件课后习题2】图3.35所示色e-k关系曲线表示了两种可能的价带。
说明其中哪一种对应的空穴有效质量较大。
为什么？解：图中b曲线对应的空穴有效质量较大空穴的有效质量： m*p?1 21de?222?dk?图中曲线a的弯曲程度大于曲线bd2e 故 22dkd2e?22dkba?m*p?a??m*p?b?3.16 图3.37所示为两种不同半导体材料导带中电子的e-k关系抛物线，试确定两种电子的有效质量（以自由电子质量为单位）。
解：e-k关系曲线k=0附近的图形 ?k2近似于抛物线故有：e?ec? *2mn由图可知 ec?0①对于a曲线1??1.055?10?0.1????2k210-10??*?31? ?4.97?10kg?0.55me 有mn（a）?-192e0.07?1.06?10 ?-342?2②对于b曲线有1??1.055?10??0.1?-10?22?k10?32m*??4.97?10kg?0.055men （b）?-192e0.7?1.06?10 ?-342?23.20 硅的能带图3.23b所示导带的最小能量出现在[100]方向上。
最小值附近一维方向上的能量可以近似为s(k?k0) e?e0?e1co?其中k0是最小能量的k值。
是确定k?k0时的粒子的有效质量。
解：导带能量最小值附近一维方向上的能量e?e0?e1cos?(k?k0) d2e ?22??2e1cos?(k?k0) dkd2e当k?k0时 cos?(k?k0)?1；22??2e1dk 11d2e?*?222又mn?dk?2?k?k0时粒子的有效质量为：m?2?e1 *n3.24 试确定t=300k时gaas中ev和ev-kt之间的总量子态数量。
h3?3*2pev?e当t=300k时 gaas中ev和ev?kt之间总量子态数量：h3h36.6262?10?3432?1.38?103?23?30032?3.28?10?7cm?33.37 某种材料t=300k时的费米能级为6.25ev。
第一章习题1．设晶格常数为a 的一维晶格，导带极小值附近能量E c (k)和价带极大值附近能量E V (k)分别为：E c =0220122021202236)(,)(3m k h m k h k E m k k h m k h V -=-+ 0m 。
试求：为电子惯性质量，nm a ak 314.0,1==π（1）禁带宽度;（2） 导带底电子有效质量; （3）价带顶电子有效质量;（4）价带顶电子跃迁到导带底时准动量的变化 解：（1）eV m k E k E E E k m dk E d k m kdk dE Ec k k m m m dk E d k k m k k m k V C g V V V c 64.012)0()43(0,060064338232430)(2320212102220202020222101202==-==<-===-==>=+===-+ 因此：取极大值处，所以又因为得价带：取极小值处，所以：在又因为：得：由导带：043222*83)2(1m dk E d mk k C nC===sN k k k p k p m dk E d mk k k k V nV/1095.7043)()()4(6)3(25104300222*11-===⨯=-=-=∆=-== 所以：准动量的定义：2. 晶格常数为0.25nm 的一维晶格，当外加102V/m ，107 V/m 的电场时，试分别计算电子自能带底运动到能带顶所需的时间。
解：根据：tkhqE f ∆∆== 得qE k t -∆=∆sat sat 137192821911027.810106.1)0(1027.810106.1)0(----⨯=⨯⨯--=∆⨯=⨯⨯--=∆ππ第三章习题和答案1. 计算能量在E=E c 到2*n 2C L 2m 100E E π+= 之间单位体积中的量子态数。
解322233*28100E 21233*22100E 0021233*231000L 8100)(3222)(22)(1Z VZZ )(Z )(22)(2322C 22C L E m h E E E m V dE E E m V dE E g V d dEE g d E E m V E g c nc C n l m h E C n l m E C n n c n c πππππ=+-=-====-=*++⎰⎰**）（）（单位体积内的量子态数）（2. 试证明实际硅、锗中导带底附近状态密度公式为式（3-6）。
半导体物理习题解答1－1．（P 32）设晶格常数为a 的一维晶格，导带极小值附近能量E c （k ）和价带极大值附近能量E v （k ）分别为：E c (k)=0223m k h +022)1(m k k h -和E v (k)= 0226m k h －0223m k h ；m 0为电子惯性质量，k 1＝1/2a ；a ＝0.314nm 。
试求： ①禁带宽度；②导带底电子有效质量； ③价带顶电子有效质量；④价带顶电子跃迁到导带底时准动量的变化。
[解] ①禁带宽度Eg根据dk k dEc )(＝0232m k h ＋012)(2m k k h -＝0；可求出对应导带能量极小值E min 的k 值：k min ＝143k ， 由题中E C 式可得：E min ＝E C (K)|k=k min =2104k m h ； 由题中E V 式可看出，对应价带能量极大值Emax 的k 值为：k max ＝0；并且E min ＝E V (k)|k=k max ＝02126m k h ；∴Eg ＝E min －E max ＝021212m k h ＝20248a m h ＝112828227106.1)1014.3(101.948)1062.6(----⨯⨯⨯⨯⨯⨯⨯＝0.64eV ②导带底电子有效质量m n0202022382322m h m h m h dkE d C =+=；∴ m n ＝022283/m dk E d h C= ③价带顶电子有效质量m ’02226m h dk E d V -=，∴0222'61/m dk E d h m Vn-== ④准动量的改变量h △k ＝h (k min -k max )= ah k h 83431=[毕]1－2．（P 33）晶格常数为0.25nm 的一维晶格，当外加102V/m ，107V/m 的电场时，试分别计算电子自能带底运动到能带顶所需的时间。
[解] 设电场强度为E ，∵F =hdtdk=q E （取绝对值） ∴dt =qE h dk∴t=⎰tdt 0=⎰a qE h 210dk =aqE h 21 代入数据得： t ＝E⨯⨯⨯⨯⨯⨯--1019-34105.2106.121062.6＝E 6103.8-⨯（s ）当E ＝102 V/m 时，t ＝8.3×10－8（s ）；E ＝107V/m 时，t ＝8.3×10－13（s ）。
半导体物理与器件吕淑媛第二章课后答案
1.实际半导体与理想半导体间的主要区别是什么?
答:(1）理想半导体:假设晶格原子严格按周期性排列并静止在格点位置上，实际半导体中原子不是静止的，而是在其平衡位置附近振动。
(2）理想半导体是纯净不含杂质的，实际半导体含有若干杂质。
(3）理想半导体的晶格结构是完整的，实际半导体中存在点缺陷，线缺陷和面缺陷等。
2．以As掺入Ge中为例，说明什么是施主杂质、施主杂质电离过程和n 型半导体。
As有5个价电子，其中的四个价电子与周围的四个Ge 原子形成共价键，还剩余一个电子，同时As原子所在处也多余一个正电荷，称为正离子中心，所以，一个As原子取代一个Ge 原子，其效果是形成一个正电中心和一个多余的电子.多余的电子束缚在正电中心，但这种束缚很弱,很小的能量就可使电子摆脱束缚，成为在晶格中导电的自由电子，而As 原子形成一个不能移动的正电中心。
这个过程叫做施主杂质的电离过程。
能够施放电子而在导带中产生电子并形成正电中心，称为施主杂质或N型杂质，掺有施主杂质的半导体叫N型半导体。
3.以Ga掺入Ge中为例，说明什么是受主杂质、受主杂质电离过程和p型半导体。
4．以Si在GaAs 中的行为为例，说明IV族杂质在IIl-V族化合物中可能出现的双性行为。
Si取代GaAs 中的Ga原子则起施主作用;Si取代GaAs 中的As 原子则起受主作用。
导带中电子浓度随硅杂质浓度的增加而增加，当硅杂质浓度增加到一定程度时趋于饱和。
硅先取代Ga 原子起施主作用，随着硅浓度的增加，
硅取代As 原子起受主作用。
Chapter 44.1n i 2E gN c N expkTT 3E gexpN cO N O300kTwhere N cO and N Oare the values at 300 K.(a) SiliconT (K) kT (eV) n i (cm 3) 200 0.01727 7.68 104 400 0.03453 2.38 1210 6000.05189.74 1014(c) GaAs(b) GermaniumT (K)n i (cm 3 ) n i (cm 3 ) 200 2.16 10101.38 4008.60 1014 3.28 109 6003.82 10165.72 1012_______________________________________ 4.2Plot_______________________________________4.3(a) n i 2 N c NexpE gkT31121919T5 2.8 1.04 101010300exp1.120.0259 T 300T 32.5 10 232.912 10 38300exp1.12 3000.0259 TBy trial and error, T 367.5 K(b)n i25 10 1222.5 10 2532.912 10 38T exp 1.12 300300 0.0259 TBy trial and error,T 417.5 K _______________________________________4.4At T200 K, kT0.02592003000. 017267eVAt T400 K, kT0.02594003000. 034533eVn i 2400 7.70 101023.025 10 17n i 2 2001.40 10 2 23400expE g3000.0345333200Egexp300 0.017267E gE g8 exp0.0345330.0172673.025 10178 exp E g 57 .9139 28.9578orE g 28.9561ln 3.025 1017 38.17148 or E g 1.318 eVNow7.70 1010N co N o340023001.318 exp0.03453321N co N o 2.370 175.929 10 2.658 10so N co N o 9.41 10 37 cm 6_______________________________________4.5exp 1.10n i kT 0.20Bexpn i A 0.90 kTexp kTFor T 200 K, kT 0.017267 eVFor T 300 K, kT 0.0259 eVFor T 400 K, kT 0.034533 eV(a) For T 200K,n i B exp 0.20 9.325 10 6n i A 0.017267(b) For T 300K,n i Bexp 0.204.43 10 4n i A 0.0259 (c) For T 400K,n i Bexp 0.203.05 10 3n i A 0.034533_______________________________________ 4.6(a) g c f FE E FE E c expkTThen g c f F x expxkTTo find the maximum value:d g c f F 1 x1 / 2 exp xdx 2 kT1 x1 /2 exp x 0kT kTwhich yields1/ 21 x kT2x1/ 2 x 2kTThe maximum value occurs atEkTE c2(b)g 1 f FE F EE E expkTE EE E expkTexpE F EkTLet E E xThen g 1 f F x expxkTTo find the maximum valued g 1 f F d xdx dxx expkTSame as part (a). Maximum occurs atxkT2E E c exp E E ckTorkTE E2E c EF expkTLet E E c x _______________________________________ 4.7E1 E c exp E1 E cn E1 kTn E2E2 E c exp E2 E c kTwhereE1 E c 4kT and E 2 E c kT 2Thenn E1 4kTexp E1 E2n E2 kT kT22 2 exp 4 12 exp 3.522orn E10.0854n E 2_______________________________________ 4.8Plot_______________________________________4.9Plot_______________________________________ 4.10E Fi E midgap 3kT ln m*pm n* 4Silicon: m*p 0.56 m o , m n* 1.08m oE Fi E midgap 0.0128 eVGermanium: m*p 0. 37m o ,*0.55m om nE Fi E midgap 0 .0077 eVGallium Arsenide: m*p 0.48m o ,m n* 0.067m oE Fi E midgap 0 .0382 eV_______________________________________ 4.11E Fi E midgap 1 kT ln N2 N c1kT ln 1.04 1019 0.4952 kT2 2.8 1019T (K) kT (eV) ( E Fi E midgap )(eV) 200 0.01727 0.0086 400 0.03453 0.0171 600 0.0518 0.0257_______________________________________4.12(a) E Fi E midgapm*p3 kT ln4 m n*3 0.0259 ln0.704 1.2110.63 meV(b) E Fi E midgap 3 0.0259 ln0.754 0.08043.47 meV_______________________________________4.13Let g c E K constantThenn o g c E f F E dEE cK1dEE E FEc 1 expkTK expE E FdEkTE cLetE E cso that dE kT dkTWe can writeE EF E c E F E E cso thatE E Fexp E c E FexpexpkTkTThe integral can then be written asn o K kT exp E c E Fexp d kTwhich becomesn o K kTE c EF expkT_______________________________________4.14Let g c E C1E E c for E E cThenn o g c E f F E dEE cC1 E E cdEE c 1exp E EF kTC1 EE E FdE E C expE ckTLetE E cdE kT dso thatkTWe can writeE EF E E c E c E FThenE c E Fn o C1 expkTE E cE E cdE expE ckT orn oE c EF C1 expkTkT exp kT d 0We find thatexp d exp 1 1So2 E c E Fn o C1 kT expkT_______________________________________4.15r1 m oWe have rm*a oFor germanium, r 16 , m* 0.55m oThenr1 16 1 a o 29 0.530.55oror1 15.4 AThe ionization energy can be written asm*2E o 13.6 eVm o s0.552 13.6 E 0.029 eV16_______________________________________ 4.16We have r1 m orm*a oFor gallium arsenide, r 13.1 , *m0.067 m o1or1 13.1 104 A0.530.067The ionization energy ism*20.067E o 13.6 13.6m o s 13.1 2orE0.0053 eV_______________________________________4.17Nc(a) E c E F kT ln2.8 10190.0259 ln 157 100.2148 eV(b) E F E E g E c E F1.12 0.2148 0.90518eV(c) p o NE F E expkT1.04 19 0.9051810 exp0.02596.90 103cm 3(d) Holesn o(e) E F E Fi kT lnn i710 150.0259 ln1.5 10100.338 eV_______________________________________4.18N(a) E F E kT lnp o190.0259 ln 1.0410210160.162 eV(b) E c E F E g E F E1.12 0.162 0.958 eV(c) n o 2.8 19 0.95810 exp0.02592.41 103cm3p o(d) E Fi E F kT lnn i2 10 160.0259 ln 101.5 100.365eV_______________________________________4.19Nc(a) E c E F kT ln0.0259 ln 2.810192 1050.8436 eVE F E E g E c E F1.12 0.8436E F E 0.2764 eV(b) p o 1.04 1019 exp 0.276370.02592.414 1014cm3(c)p-type_______________________________________4.20(a) kT3750.032375 eV0.02593003 / 2n o 4.7 10 17 375 exp 0.28300 0.0323751.15 1014cm3E F E E g E c E F 1.42 0.281.14 eV375 3 / 2 1.14 p o 7 18 exp10300 0.0323754.99 103cm 3(b) E c E F 0.0259 ln 4.7 10171.15 10 140.2154 eVE F E E g E c E F 1.42 0.21541.2046 eVp o 7 10 18 exp 1.20460.02594.42 10 2cm 3_______________________________________ 4.21(a) kT 0.0259 3750.032375 eV 300375 3 / 2 0.28n o 2.8 19 exp10300 0.0323756.86 1015cm 3E F E E g E c E F 1.12 0.280.840 eV375 3 / 20.840p o 1.04 1019 exp300 0.0323757.84 107cm 3(b) E c E F kT ln N cn o0.0259 ln2.8 10196.862 10 150.2153 eVE F E 1.12 0.2153 0.9047 eVp o 1.04 10 19 exp 0.9046680.02597.04 103 cm 3_______________________________________4.22(a) p-typeE g(b) E F E1.124 0.28 eV4p o N exp E F EkT1.04 10 19 exp 0.280.02592.10 1014cm 3E c EF E g E F E1.12 0.28 0.84 eVn o N c exp E c E FkT2.8 1019exp0.840.02592.30 105cm 3_______________________________________4.23(a) n o n iE F E FiexpkT1.5 1010 exp 0.220.02597.3313cm310p oE Fi E Fn i expkT1.5 1010 exp 0.220.02593.07 106cm 3(b) n o n iE F E FiexpkT1.8 10 6 exp 0.220.02598.80 109cm 3p o n i expE Fi E FkT1.8 106 exp 0.220.02593.68 102cm 3_______________________________________4.24(a) E F ENkT lnp o0.0259 ln1.04 10 195 10 150.1979 eV(b) E c E F E g E F E1.12 0.19788 0.92212 eV(c) n o 2.8 1019 exp 0.922120.02599.66 103cm 3(d) Holesp o(e) E Fi E F kT lnn i510 150.0259 ln1.5 10100.3294 eV _______________________________________4.25kT 0.0259 4000.034533 eV 3003 / 2N 1.04 10 19400300 1.601 1019cm 33 / 2N c 2.8 1019400300 4.3109 1019cm 30.2642 eV _______________________________________4.26(a) p o 7 1018 exp 0.250.02594.50 1014cm 3E c EF 1.42 0.25 1.17 eVn o 4.7 10 17 exp 1.170.02591.13 10 2cm 3(b)kT 0.034533eV3 / 2N 7 10184003001.078 1019cm 33 / 217 400N c 4.7 103007.236 1017cm3expn i 2 4.3109 10 19 1.601 10191.12NE F E kT lnp o19 0.0345335.67022410n i 2.381 1012 cm 3(a) E F ENkT lnp o0.034533 ln 1.601 10195 1015 0.2787 eV(b) E c E F 1.12 0.27873 0.84127 eV(c) n o 4.3109 10 19 exp 0.841270.0345331.134 109cm3(d) Holes(e) E Fi E F kT ln p on i510150.034533 ln2.381 10120.034533 ln1.078104.50 10 140.3482 eVE c EF 1.42 0.3482 1.072 eVn o 7.236 1017 exp 1 .071770. 0345332.40 104cm 3_____________________________________4.27(a) p o 1.04 1019 exp 0.250.02596.68 1014cm 3E c EF 1.12 0.25 0.870 eVn o 2.8 10 19 exp 0.8700.0259n o7.2310 4 cm 3(b)kT0.034533 eV3 / 2N 1.04 10194003001.601 1019cm 33 / 2N c 2.8 1019 4003004.311 1019cm 3NE F E kT lnp o1.60110 190.034533ln6.6810140.3482 eVE c EF 1.12 0.34820.7718 eVn o 4.311 1019 exp 0.771750.0345338.49 109cm 3_______________________________________4.282(a) n o N c F1 / 2 FFor E F E c kT 2 ,E F E c kT 2 FkT 0.5kTThen F1/ 2 F 1.0n o 2 2.8 1019 1.03.16 1019cm 3(b) n o 2 N c F1 / 2 F24.7 1017 1.05.30 1017cm 3_______________________________________ 4.29p o 2 N F1/2 F5 1019 2 1.04 1019 F1/2 FSo F1/ 2 F 4.26We find F 3.0E E FkTE EF 3.0 0.0259 0.0777 eV_______________________________________4.30E F E c 4kT(a) F 4kT kTThen F1 / 2 F 6.02N c F1 / 2n o F2 2.8 1019 6.01.90 10 20 cm 3(b) n o 2 4.7 1017 6.03.18 1018cm 3_______________________________________ 4.31For the electron concentrationn E g c E f F EThe Boltzmann approximation applies, so4 * 3 / 22m nE E cn Eh3E E FexpkTor4 2m n* 3 / 2 E c E Fexpn E h3kTE E c E E ckT expkTkTDefinexEE ckTThenn E n x K x exp xTo find maximumn E n x , setdn x 0 K 1 x 1 / 2 exp xdx 2x 1 / 21 expxorKx 1 / 2 expx1 x2which yieldsx1 E E cE E c12kTkT2For the hole concentrationp Eg E 1f F EUsing the Boltzmann approximation4 2m p * 3 / 2p EEEh 3E F EexpkT or3 / 242m *p E F Ep Eh 3expkTE E E EkTexpkTkTDefinexE EkTThenp xK x exp xTo find maximum value ofp Ep x ,setdp xUsing the results from0 dxabove,we find the maximum at1E E kT2_______________________________________4.32 (a) Silicon:We haven oN c expE cE FkTWe can writeE c E FE c E d E d E FForE c E d 0.045 eV andE dE F3kT eVwe can writen o2.8 1019 exp 0.04530.02592.8 1019exp 4.737or10 17 cm3n o2.45 We also havep oN expE F EkTAgain, we can writeE FEE FE aE aEForE FE a3kTandE aE0.045eVThenp o1.04 1019 exp 3 0.0450.02591.04 1019 exp4.737orp o9.12 10 16 cm 3(b) GaAs: assume E c E d0.0058eVThenn o4.7 1017 exp0.0058 30.025917exp 3.2244.7 10orn o1.87 1016 cm3Assume E a E 0.0345 eVThenp o71018 exp0.0345 30.02597 1018 exp 4.332orp o9.20 1016 cm 3_______________________________________ 4.33Plot_______________________________________4.34 10 151015 cm 3(a)p o415 31.5 10 10 2n o7.5 10 4 cm33 10153(b) n oN d316cm1010 2p o1.5 107.5 10 3cm 33 1016 (c)n op on i 1.5 10 10cm33(d) n i 22.8 10 19 1.041019 375300 exp1.12 3000.0259 375n i7.334 1011 cm3p o N a4 10 15 cm 37.334 10 11 2n o1.34 10 8 cm34 10 153(e) n i 22.8 10 19 1.04 10 19 4503001.12 300exp0.0259 450133n i1.722 10 cm14142n o1.722 10 1310102221.029 1014 cm 31.722 1013 2p o2.88 1012 cm 31.029 1014_______________________________________(a) p oN aN d4 101510153 1015 cm 3n i 2 1.8 10 6 2n o1.08 10 3cm 3p o3 1015(b) n oN d 3 10 16 cm 3p o1.8 10 6 2 1.08 10 4 cm33 10163(c) n o p on i1.8 10 6cm375 3(d) n i 24.7 1017 7.0 10 18300 exp1.42 3000.0259 375n i 7.580 10 8 cm 3p o N a4 1015 cm 38 2n o7.580 10 1.44 10 2 cm 34 10 153 (e) 2 4.7 10 17 7.0 18450 n i 10 300 exp1.42 3000.0259 450n i 3.853 1010 cm3n oN d10 14 cm 33.853 1010 2p o1.48 10 7 cm 310 14_______________________________________4.3610 13 cm 3(a) Ge: n i2.42(i) n oN dN dn i 22 22 10152 210152.4 13 22210or2 1015 cm 3n oN d4.35n i 2 2.4 1013 2p o2 1015n o2.88 1011 cm 3(ii) p o N a N d 10167 10153 1015 cm 32n i22.4 10 13n op o310 151.92 1011cm3(b) GaAs: n i 1.8 10 6cm3(i) n o N d2 1015 cm62p o1.8 10 1.62 10 3cm32 10 15(ii) p oN aN d3 10 15 cm 362n o1.8 101.08 10 3cm 33 1015 (c) The result implies that there is only one 33minority carrier in a volume of 10 cm ._______________________________________4.37(a) For the donor leveln d 1N d1 1exp EdE F2kT11 1 exp 0.2020.0259orn d8.85 10 4N d (b) We havef F E1E E F1expkTNowE E FE E cE c E ForE EF kT 0.245Thenf F E10.2451 exp 1 0.0259orf F E 2.87 10 5_______________________________________4.38N aN d(a) p-type(b) Silicon:10131013p oN aN d 2.5 1 or1013 cm 3p o1.5Thenn i 21.5 10 10 210 7cm 3n o1.5p o 1.5 1013 Germanium:N aN d N a N d 2p o2n i 221.5131.5 10 1322.4 101310222or3.26 10 13 cm 3p oThen2n i 22.4 10 13n o1.76 10 13p o3.264 1013cm 3Gallium Arsenide:p oN a N d1.5 10 13 cm 3and2n i 21.8 10 6n o0.216 cm 3p o1.5 1013_______________________________________4.39 (a) N d N an-type(b) n oN d N a 2 10151.2 10158 1014 cm 3n i 21.5 101022.81 10 5cm 3p o8 14n o10(c)p o N aN a N d4 1015N a 1.2 10 152 1015N a 4.8 10 15 cm31.5 10 102n o5.625 10 4cm 3 4 1015_______________________________________4.40n i21.5 101021. 153n o2 10 5 125 10cmp on o p on-type_______________________________________4.413n i 21.04 10196.0 10 18 250300 exp0.660.0259250 3001.8936 102412n i 1.376cm310 n on i 2 n i 2n o 21n i 2p o4n o 4n o1n i2Son o 6.88 1011 cm 3 ,Then p o2.75 1012cm3N a N a 2p on i 222N a22.752 10122N a21.8936 10 24227.5735 10 242.752 10 12 N aN a2N a 21.8936 10 242so that N a 2.064 1012cm 3_______________________________________4.42Plot_______________________________________4.43Plot_______________________________________4.44Plot_______________________________________ 4.45N d N aN dN a 2n o2n i 2214141.1 1014 2 10 1.2 102 2 10141.2 1014 2n i 221.1 10144 10 1324 10132n i 24.9 10 271.6 10 27n i2so n i5.74 10 13 cm 3p on i 23.3 10 273 133n o 1.1 10 1410 cm_______________________________________4.46(a)N a N d p-typeMajority carriers are holesp o N a N d16163 101.5 101.5 1016 cm 3Minority carriers are electrons210 10 2n on i 1.5 1.5 10 4 cm 3p o 1.5 1016(b) Boron atoms must be addedp o N a N aN d5 1016N a 3 10161.5 1016So N a3.5 10 16 cm 31.5 10 102n o4.5 10 3cm 35 10 16_______________________________________4.47p on i (a)n-type(b) p on i 2 n on i 2n op o1.5 10 1021016 cm3n o4 1.125 2 10electrons are majoritycarriersp o2 10 4cm3holes are minority carriers(c) n oN d N a1.125 101615N d 7 10so N d1.825 1016 cm3_______________________________________4.48E Fi E FkT lnp on iFor GermaniumT (K)kT (eV)n i (cm 3)200 0.01727 2.16 1010400 0.03453 8.60 1410 6000.05183.82 1016N aN a 2p o n i 2and22N a10 15 cm 3T (K)p o (cm3)E Fi EF (eV)200 1.0 1015 0.1855 4001.49 1015 0.01898 6003.87 10160.000674_______________________________________4.49(a) E c E FkT lnN cN d0.0259 ln 2.8 1019N dFor 1014cm 3 , E cE F 0.3249eV15 cm 3 ,E cE F0.2652eV1016cm 3, E c E F 0.2056eV 101017 cm 3 , E c E F0.1459eV(b) E F E FikT lnN dn i0.0259 lnN d1.51010For 1014cm 3 , E FE Fi 0.2280 eV15cm 3, E F E Fi 0.2877 eV10 1016 cm 3 , E F E Fi 0.3473 eV 1017 cm 3 ,E F E Fi0.4070 eV_______________________________________ 4.50N d N d 2(a) n on i 222n o1.05N d1.05 10 15 cm 31.05 10150.5 10 1520.5 10152n i2son i 25.25 10 28Now3n i 22.8 1019 1.04 1019T300exp1.120.0259 T 30035.25 10 28 2.912 10 38 T300exp 12972.973TBy trial and error, T 536.5K(b) At T 300 K,E c EF kT ln N cn oE c EF 0.0259 ln 2.8 1019 1015T 536.5 K, 0.2652 eVAt536.5kT0.02590.046318 eV3003 / 2N c 2.8 1019 536.53006.696 1019cm 3E c E FN c kT lnn oE c E F6.696 10 19 0.046318 ln10151.050.5124 eVthen E c E F 0.2472 eV(c)Closer to the intrinsic energy level._______________________________________4.51p oE Fi EF kT lnn iAt T 200K, kT 0.017267 eVT 400 K, kT 0.034533 eVT 600 K, kT 0.0518 eV At T 200K,22.8 10191019 200n i 1.04300exp1.120.017267n i 7.638 10 4 cm 3At T 400 K,3n i 2 2.8 1019 1.04 10 19 4003001.12exp0.034533n i 2.381 1012 cm 3At T 600 K,322.8 1019 19 600n i 1.04 10300exp 1.120.0518n i 9.740 1014 cm 3At T 200 K and T 400 K,p o N a 3 1015 cm 3At T 600 K,N a N a2p o n i22 23 15 3 10 15 2 9.740 10 1410 22 23.288 1015cm3Then, T 200K, E Fi E F 0.4212eVT 400K,E Fi EF 0.2465 eVT600K,E Fi EF 0.0630 eV_______________________________________4.52(a)N a N aE Fi EF kT ln 0.0259 ln6n i 1.8 10For N a10 14 cm 3 ,E FiE F0.4619 eVN a 10 15 cm 3,E FiE F0.5215 eV163,N a 10 cmE FiE F0.5811 eVN a 10 17cm 3,E FiE F 0.6408 eV(b)E FEN7.0 1018kT ln0.0259 lnN aN aFor N a10 14 cm 3 ,E F E0.2889 eVN a 10 15 cm 3 ,E FE0.2293 eV163,N a 10 cmE F E0.1697 eVN a 10 17 cm3,E F E 0.1100 eV_______________________________________ 4.53(a) E Fi3 m *p E midgapkT ln4m n *3 0.0259 ln 104 orE Fi E midgap 0.0447 eV(b) Impurity atoms to be added soE midgap EF 0.45 eV(i) p-type, so add acceptor atoms(ii)E Fi EF 0.0447 0.45 0.4947 eVThenp oE FiE Fn i expkT10 5exp 0.49470.0259 or10 13 cm3p o N a1.97_______________________________________4.54n oN d N aN c expE c E FkTsoN d 5 10 15 2.8 10 19 exp0.2150.025951015 6.95 1015orcm 3N d 1.2 1016_______________________________________4.55(a) Silicon(i) E cE F N ckT lnN d0.0259 ln 2.8 10 190.2188 eV6 1015(ii) E cE F0.2188 0.0259 0.1929 eVN dN c expE c E FkT2.8 10 19 exp0.19290.0259N d1.631 1016 cm3N d 6 1015N d1.031 10 16 cm 3Additional donor atoms(b) GaAs(i) E c E F0.0259 ln4.7101710150.15936eV(ii) E cE F0.15936 0.0259 0.13346 eVN d4.7 1017 exp0.133460.02592.718 1015 cm 3N d 1015N d1.718 10 15 cm3Additionaldonor atoms_______________________________________ 4.56(a) E Fi E FN kT lnN a0.0259 ln 1.04 10190.1620 eV2 1016(b) E F E Fi kT ln N c N d0.0259 ln 2.8 1019 0.1876 eV2 10 16(c) For part (a);p o 2 1016 cm 3n i2 1.5 1010 2n op o 2 10161.125 104cm3For part (b):3n o 2 1016 cmn i 2 1.5 1010 2p on o 2 10 161.125 104cm3_______________________________________ 4.57n oE F E Fin i expkT1.8 10 6 exp 0.550.02593.0 1015cm 3Add additional acceptor impuritiesn o N d N a3 10 15 7 10 15 N aN a 4 10 15 cm 3_______________________________________(a) E Fi E F kT lnpon i0.02593 10 150.3161 eVln10 101.5(b) E F E Fin okT lnn i0.02593 10160.3758 eVln10 101.5(c) E F E Fi(d) E Fi E Fp okT lnn i0.0259 375 ln 4 1015300 7.334 10 110.2786 eV(e) E F E Fi kT lnnon i140.0259 450 ln 1.029 10300 1.722 10 130.06945eV_______________________________________4.59(a) E F ENkT lnp o0.0259 ln7.0 10180.2009 eV3 1015(b) E F E 0.0259 l n7.0 10 181.08 10 41.360 eV(c) E F E 0.0259 l n 7.0 10181.8 10 60.7508 eV4.58(d) E F E 0.0259 375300ln 7.0 10 18 375 300 3 / 24 10 150.2526 eV(e) E F E 0.0259 450 300ln 7.0 10 18 450 300 3/ 21.48 10 71.068 eV_______________________________________4.60n-typeE F E Fi kT ln n o n i0.02591.125 10 16ln100.3504 eV1.5 10______________________________________ 4.61N a N a 2 p o 22 2 n i5.08 1015 5 101525 10 15 2n i225.08 10 15 2.5 10 15 22.5 1015 2n i26.6564 10 30 6.25 10 30 n i2n i 2 4.064 10 29n i2 N c N expE gkTkT 0.02593500.030217 eV3003502N c 1.2 10 19 1.633 1019 cm 33003502N 1.8 1019 2.45 10 19 cm 3300Now4.064 10 29 1.633 1019 2.45 1019E gexp0.030217SoE g 0.030217 ln 1.633 10 19 2.45 10 194.064 10 29E g 0.6257 eV_______________________________________4.62(a) Replace Ga atoms Silicon acts as adonorN d0.05 7 1015 3.5 10 14 cm 3Replace As atoms Silicon acts asanacceptorN a 0.95 7 1015 6.65 10 15 cm 3(b) N a N d p-type(c) p o N a N d 6.65 1015 3.5 10146.3 1015cm 3n i 2 1. 810 6 2n o 5.14 10 4 cm 3 p o 6 .3 1015(d) E Fi E F kT ln p o n i0.0259 ln 6.3 10 150.5692 eV1.8 10 6_______________________________________。
Chapter 2Sketch_______________________________________Sketch_______________________________________Sketch_______________________________________From Problem , phase t xωλπ-=2= constant Then⎪⎭⎫ ⎝⎛+==⇒=-⋅πλωυωλπ2,02p dt dx dt dx From Problem , phase t xωλπ+=2= constant Then⎪⎭⎫ ⎝⎛-==⇒=+⋅πλωυωλπ2,02p dt dx dt dx _______________________________________Ehc hch E =⇒==λλνGold: 90.4=E eV ()()19106.190.4-⨯=J So,()()()()51910341054.2106.190.410310625.6---⨯=⨯⨯⨯=λcmorμλ254.0=mCesium: 90.1=E eV ()()19106.190.1-⨯= JSo,()()()()51910341054.6106.190.110310625.6---⨯=⨯⨯⨯=λcmorμλ654.0=m_______________________________________(a) 9341055010625.6--⨯⨯==λhp2710205.1-⨯=kg-m/s331271032.11011.9102045.1⨯=⨯⨯==--m p υm/sor 51032.1⨯=υcm/s(b) 9341044010625.6--⨯⨯==λhp2710506.1-⨯=kg-m/s331271065.11011.9105057.1⨯=⨯⨯==--m p υm/s or 51065.1⨯=υcm/s (c) Yes_______________________________________(a) (i)()()()1931106.12.11011.922--⨯⨯==mE p2510915.5-⨯=kg-m/s925341012.110915.510625.6---⨯=⨯⨯==p h λm or oA 2.11=λ(ii)()()()1931106.1121011.92--⨯⨯=p 241087.1-⨯=kg-m/s 1024341054.3108704.110625.6---⨯=⨯⨯=λm or oA 54.3=λ(iii) ()()()1931106.11201011.92--⨯⨯=p 2410915.5-⨯=kg-m/s 1024341012.110915.510625.6---⨯=⨯⨯=λm or oA 12.1=λ(b)()()()1927106.12.11067.12--⨯⨯=p 2310532.2-⨯=kg-m/s1123341062.210532.210625.6---⨯=⨯⨯=λm or oA 262.0=λ_______________________________________()03885.00259.02323=⎪⎭⎫⎝⎛==kT E avg eV Nowavg avg mE p 2=()()()1931106.103885.01011.92--⨯⨯=or2510064.1-⨯=avg p kg-m/s Now9253410225.610064.110625.6---⨯=⨯⨯==p h λm oroA 25.62=λ_______________________________________pp p hch E λν==Nowmp E ee 22= and221⎪⎪⎭⎫⎝⎛=⇒=ee e e h m E h p λλ Set e p E E = and e p λλ10= Then22102121⎪⎪⎭⎫ ⎝⎛=⎪⎪⎭⎫ ⎝⎛=p ep h m h m hcλλλ which yieldsmchp 2100=λ 100221002mc mc h hc hc E E p p =⋅===λ ()()1001031011.922831⨯⨯=-151064.1-⨯=J 25.10=keV _______________________________________(a) 1034108510625.6--⨯⨯==λhp2610794.7-⨯= kg-m/s431261056.81011.910794.7⨯=⨯⨯==--m p υm/s or 61056.8⨯=υcm/s()()243121056.81011.92121⨯⨯==-υm E211033.3-⨯=Jor 219211008.2106.110334.3---⨯=⨯⨯=E eV (b) ()()23311081011.921⨯⨯=-E 2310915.2-⨯=Jor 419231082.1106.110915.2---⨯=⨯⨯=E eV ()()3311081011.9⨯⨯==-υm p 2710288.7-⨯=kg-m/s827351009.910288.710625.6---⨯-⨯⨯==p h λm or oA 909=λ_______________________________________(a) ()()1083410110310625.6--⨯⨯⨯===λνhch E 151099.1-⨯=JNow1915106.11099.1--⨯⨯==⇒⋅=e E V V e E41024.1⨯=V V 4.12=kV(b)()()15311099.11011.922--⨯⨯==mE p231002.6-⨯=kg-m/sThen1123341010.11002.610625.6---⨯=⨯⨯==p h λm oroA 11.0=λ_______________________________________6341010054.1--⨯=∆=∆x p 2810054.1-⨯=kg-m/s_______________________________________(a) (i) =∆∆x p26103410783.8101210054.1---⨯=⨯⨯=∆p kg-m/s (ii)p m p dp d p dp dE E ∆⋅⎪⎪⎭⎫⎝⎛=∆⋅=∆22 mpp p m p ∆=∆⋅=22 Now mE p 2=()()()1931106.1161092--⨯⨯= 2410147.2-⨯=kg-m/sso ()()31262410910783.8101466.2---⨯⨯⨯=∆E1910095.2-⨯=Jor 31.1106.110095.21919=⨯⨯=∆--E eV(b) (i) 2610783.8-⨯=∆p kg-m/s (ii)()()()1928106.1161052--⨯⨯=p 231006.5-⨯=kg-m/s()()28262310510783.81006.5---⨯⨯⨯=∆E2110888.8-⨯=Jor 219211055.5106.110888.8---⨯=⨯⨯=∆E eV _______________________________________3223410054.11010054.1---⨯=⨯=∆=∆x p kg-m/s150010054.132-⨯=∆=∆⇒=m p m p υυ 36107-⨯=∆υm/s_______________________________________(a) =∆∆t E()()1619341023.8106.18.010054.1---⨯=⨯⨯=∆t s(b) 1034105.110054.1--⨯⨯=∆=∆x p 251003.7-⨯=kg-m/s_______________________________________(a) If ()t x ,1ψ and ()t x ,2ψ aresolutions toSchrodinger's wave equation, then()()()()t t x j t x x V x t x m ∂ψ∂=ψ+∂ψ∂⋅-,,,2112122and()()()()t t x j t x x V x t x m ∂ψ∂=ψ+∂ψ∂⋅-,,,2222222 Adding the two equations, we obtain()()[]t x t x x m ,,221222ψ+ψ∂∂⋅- ()()()[]t x t x x V ,,21ψ+ψ+()()[]t x t x tj ,,21ψ+ψ∂∂=which is Schrodinger's wave equation.So()()t x t x ,,21ψ+ψ is also a solution.(b) If ()()t x t x ,,21ψ⋅ψ were asolution toSchrodinger's wave equation, then we could write[]()[]21212222ψ⋅ψ+ψ⋅ψ∂∂⋅-x V x m[]21ψ⋅ψ∂∂=tjwhich can be written as⎥⎦⎤⎢⎣⎡∂ψ∂⋅∂ψ∂+∂ψ∂ψ+∂ψ∂ψ-x x x x m2121222221222()[]⎥⎦⎤⎢⎣⎡∂ψ∂ψ+∂ψ∂ψ=ψ⋅ψ+t t j x V 122121 Dividing by 21ψ⋅ψ, we find⎥⎦⎤⎢⎣⎡∂ψ∂∂ψ∂ψψ+∂ψ∂⋅ψ+∂ψ∂⋅ψ-x x x xm21212121222222112 ()⎥⎦⎤⎢⎣⎡∂ψ∂ψ+∂ψ∂ψ=+t t j x V 112211Since 1ψ is a solution, then ()tj x V x m ∂ψ∂⋅ψ⋅=+∂ψ∂⋅ψ⋅-1121212112 Subtracting these last two equations,we have⎥⎦⎤⎢⎣⎡∂ψ∂∂ψ∂ψψ+∂ψ∂⋅ψ-x x x m212122222212t j ∂ψ∂⋅ψ⋅=221 Since 2ψ is also a solution, we have()tj x V x m ∂ψ∂⋅ψ⋅=+∂ψ∂⋅ψ⋅-2222222112 Subtracting these last two equations,we obtain()02221212=-∂ψ∂⋅∂ψ∂⋅ψψ⋅-x V x x mThis equation is not necessarily valid, whichmeans that 21ψψ is, in general, not a solutionto Schrodinger's wave equation. _______________________________________12cos 2312=⎪⎭⎫⎝⎛⎰+-dx x A π()12sin 2312=⎥⎦⎤⎢⎣⎡++-ππx x A 121232=⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛--Aso 212=Aor 21=A_______________________________________()1cos 22/12/12=⎰+-dx x n Aπ()142sin 22/12/12=⎥⎦⎤⎢⎣⎡++-ππn x n x A⎪⎭⎫⎝⎛==⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛--211414122A Aor 2=A_______________________________________Note that 10*=ψ⋅ψ⎰∞dxFunction has been normalized. (a) Nowdx a x a P oa o o 24exp 2⎰⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-=dx a x a oa o o⎰⎪⎪⎭⎫⎝⎛-=42exp 2 402exp 22o a o o o a x a a ⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫⎝⎛-=or()⎪⎭⎫ ⎝⎛--=⎥⎥⎦⎤⎢⎢⎣⎡-⎪⎪⎭⎫⎝⎛--=21exp 1142exp 1o oa a P which yields393.0=P (b)dx a x a P ooa a o o 224exp 2⎰⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-=dx a x a ooa a o o⎰⎪⎪⎭⎫⎝⎛-=242exp 2242exp 22o oa a o o o a x a a ⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-= or()()⎥⎦⎤⎢⎣⎡⎪⎭⎫ ⎝⎛----=21exp 1exp 1Pwhich yields239.0=P (c)dx a x a P oa o o 20exp 2⎰⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-= dx a x a oa o o⎰⎪⎪⎭⎫⎝⎛-=2exp 2o a o o oa x a a 02exp 22⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫⎝⎛-=()()[]12exp 1---= which yields865.0=P_______________________________________()dx x P 2⎰=ψ(a)dx x a a ⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛⎰2cos 224/0π 4/042sin 22a a a x x a ⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛=ππ⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛=a a a ππ42sin 242 ()()⎥⎦⎤⎢⎣⎡+⎪⎭⎫ ⎝⎛=π4182a a aor 409.0=P(b) dx a x a P a a ⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=⎰π2/4/2cos 22/4/42sin 22a a a a x x a ⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛=ππ()⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛--⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛=a a a a a ππππ42sin 84sin 42 ⎥⎦⎤⎢⎣⎡--+=π41810412 or 0908.0=P(c) dx a x a P a a ⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=⎰+-π22/2/cos 2 2/2/42sin 22a a a a x x a +-⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛=ππ()()⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛--⎪⎭⎫ ⎝⎛--⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛=a a a a a ππππ4sin 44sin 42 or 1=P_______________________________________(a) dx a x a P a ⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛=⎰π2sin 224/04/0244sin 22a a a x x a ⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=ππ()⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=a a a ππ8sin 82or 25.0=P(b) dx a x a P a a ⎪⎭⎫⎝⎛⎪⎭⎫ ⎝⎛=⎰π2sin 222/4/ 2/4/244sin 22a a a a x x a ⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=ππ()()⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛+⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=a a a a a ππππ8sin 882sin 42 or 25.0=P(c) dx a x a P a a ⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛=⎰+-π2sin 222/2/ 2/2/244sin 22a a a a x x a +-⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=ππ()()⎥⎥⎥⎥⎦⎤⎢⎢⎢⎢⎣⎡⎪⎭⎫ ⎝⎛-+⎪⎭⎫ ⎝⎛--⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=a a a a a ππππ82sin 482sin 42 or 1=P_______________________________________(a) (i) 481210108108=⨯⨯==k p ωυm/s or 610=p υcm/s9810854.710822-⨯=⨯==ππλk mor oA 54.78=λ (ii)()()431101011.9-⨯==υm p271011.9-⨯=kg-m/s()()24312101011.92121-⨯==υm E2310555.4-⨯=Jor 419231085.2106.110555.4---⨯=⨯⨯=E eV (b) (i) 491310105.1105.1-=⨯-⨯==k p ωυm/s or 610-=p υcm/s991019.4105.122-⨯=⨯==ππλk m or oA 9.41=λ (ii) 271011.9-⨯-=p kg-m/s41085.2-⨯=E eV_______________________________________(a) ()()t kx j Ae t x ω+-=ψ,(b) ()()21921106.1025.0υm E =⨯=- ()2311011.921υ-⨯= so 41037.9⨯=υm/s 61037.9⨯=cm/sFor electron traveling in x -direction,61037.9⨯-=υcm/s()()4311037.91011.9⨯-⨯==-υm p 2610537.8-⨯-=kg-m/s926341076.710537.810625.6---⨯=⨯⨯==p h λm8910097.81076.722⨯=⨯==-πλπk m 1- ()()481037.910097.8⨯⨯=⋅=υωk or 1310586.7⨯=ωrad/s_______________________________________(a) ()()4311051011.9⨯⨯==-υm p 2610555.4-⨯=kg-m/s8263410454.110555.410625.6---⨯=⨯⨯==p h λm881032.410454.122⨯=⨯==-πλπk m 1- ()()481051032.4⨯⨯==υωk131016.2⨯=rad/s (b) ()()631101011.9-⨯=p 251011.9-⨯=kg-m/s1025341027.71011.910625.6---⨯=⨯⨯=λm 9101064.810272.72⨯=⨯=-πk m 1-()()15691064.8101064.8⨯=⨯=ωrad/s_______________________________________()()()2103122342222210751011.9210054.12---⨯⨯⨯==ππn ma n E n()212100698.1-⨯=n E n Jor()19212106.1100698.1--⨯⨯=n E n or ()3210686.6-⨯=n E n eVThen311069.6-⨯=E eV 221067.2-⨯=E eV 231002.6-⨯=E eV_______________________________________(a) ()()()2103122342222210101011.9210054.12---⨯⨯⨯==ππn ma n E n ()20210018.6-⨯=n J or()()3761.0106.110018.6219202n n E n =⨯⨯=--eV Then376.01=E eV 504.12=E eV 385.33=E eV(b) Ehc ∆=λ ()()19106.1504.1385.3-⨯-=∆E191001.3-⨯=J()()198341001.310310625.6--⨯⨯⨯=λ710604.6-⨯=mor 4.660=λnm_______________________________________(a) 22222ma n E n π =()()()223223423102.11015210054.11015----⨯⨯⨯=⨯πn()622310538.21015--⨯=⨯nor 2910688.7⨯=n (b) 151≅+n E mJ (c) No_______________________________________For a neutron and 1=n : ()()()2142722342221101066.1210054.12---⨯⨯==ππma E13103025.3-⨯=Jor6191311006.2106.1103025.3⨯=⨯⨯=--E eV For an electron in the same potential well: ()()()2143122341101011.9210054.1---⨯⨯=πE10100177.6-⨯=J or9191011076.3106.1100177.6⨯=⨯⨯=--E eV _______________________________________Schrodinger's time-independent waveequation()()()()02222=-+∂∂x x V E mx x ψψWe know that()0=x ψ for 2a x ≥ and 2ax -≤ We have ()0=x V for22a x a +<<-so in this region()()02222=+∂∂x mEx x ψψThe solution is of the form()kx B kx A x sin cos +=ψ where22 mEk =Boundary conditions: ()0=x ψ at 2,2a x a x +=-=First mode solution: ()x k A x 111cos =ψ where 222112maE a kππ=⇒=Second mode solution:()x k B x 222sin =ψ where22222242ma E a k ππ=⇒= Third mode solution:()x k A x 333cos =ψ where22233293ma E a k ππ=⇒= Fourth mode solution:()x k B x 444sin =ψ where222442164ma E a k ππ=⇒= _______________________________________The 3-D time-independent wave equation incartesian coordinates for()0,,=z y x V is:()()()222222,,,,,,z z y x y z y x x z y x ∂∂+∂∂+∂∂ψψψ ()0,,22=+z y x mEψUse separation of variables, so let()()()()z Z y Y x X z y x =,,ψ Substituting into the wave equation, we obtain222222zZXY y Y XZ x X YZ ∂∂+∂∂+∂∂ 022=+XYZ mEDividing by XYZ and letting222mEk =, we find(1) 01112222222=+∂∂⋅+∂∂⋅+∂∂⋅k zZ Z y Y Y x X XWe may set01222222=+∂∂⇒-=∂∂⋅X k x X k x X X xx Solution is of the form()()()x k B x k A x X x x cos sin += Boundary conditions:()000=⇒=B Xand ()an k a x X x x π=⇒==0where ....3,2,1=x n Similarly, let2221yk y Y Y -=∂∂⋅ and 2221z k zZ Z -=∂∂⋅ Applying the boundary conditions, we find an k y y π=, ....3,2,1=y nan k z z π=, ...3,2,1=z n From Equation (1) above, we have02222=+---k k k k z y xor222222mEk k k k z y x ==++ so that()2222222z y x n n n n n n maE E z y x ++=→π _______________________________________(a)()()()0,2,,22222=⋅+∂∂+∂∂y x mEy y x x y x ψψψSolution is of the form: ()y k x k A y x y x sin sin ,⋅=ψ We find()y k x k Ak x y x y x x sin cos ,⋅=∂∂ψ ()y k x k Ak x y x y x xsin sin ,222⋅-=∂∂ψ()y k x k Ak yy x y x y cos sin ,⋅=∂∂ψ()y k x k Ak yy x y x y sin sin ,222⋅-=∂∂ψSubstituting into the original equation, we find:(1) 02222=+-- mEk k y x From the boundary conditions, 0sin =a k A x , where oA a 40=So an k x x π=, ...,3,2,1=x n Also 0sin =b k A y , where oA b 20= So bn k y y π=, ...,3,2,1=y nSubstituting into Eq. (1) above⎪⎪⎭⎫ ⎝⎛+=22222222b n a n m E y x n n yx ππ (b)Energy is quantized - similar to1-D result.There can be more than one quantum stateper given energy - different than 1-D result._______________________________________(a) Derivation of energy levelsexactly the same as in the text(b) ()21222222n n maE -=∆π For 1,212==n nThen 22223ma E π=∆ (i) For oA a 4= ()()()2102722341041067.1210054.13---⨯⨯⨯=∆πE2210155.6-⨯=Jor 319221085.3106.110155.6---⨯=⨯⨯=∆E eV(ii) For 5.0=a cm()()()22272234105.01067.1210054.13---⨯⨯⨯=∆πE3610939.3-⨯=J or1719361046.2106.110939.3---⨯=⨯⨯=∆E eV _______________________________________(a) For region II, 0>x()()()0222222=-+∂∂x V E mx x O ψψGeneral form of the solution is()()()x jk B x jk A x 22222exp exp -+=ψ where()O V E mk -=222 Term with 2B represents incident wave andterm with 2A represents reflected wave.Region I, 0<x()()0212212=+∂∂x mEx x ψψGeneral form of the solution is()()()x jk B x jk A x 11111exp exp -+=ψ where212 mEk =Term involving 1B represents the transmitted wave and the term involving 1A represents reflectedwave: but if a particle istransmitted into region I, it will not be reflected so that 01=A . Then()()x jk B x 111exp -=ψ()()()x jk B x jk A x 22222exp exp -+=ψ (b)Boundary conditions:(1) ()()0021===x x ψψ (2)201==∂∂=∂∂x x xxψψApplying the boundary conditions to the solutions, we find221B A B +=112222B k B k A k -=-Combining these two equations, we find212122B k k k k A ⋅⎪⎪⎭⎫⎝⎛+-=212212B k k k B ⋅⎪⎪⎭⎫⎝⎛+=The reflection coefficient is 21212*22*22⎪⎪⎭⎫ ⎝⎛+-==k k k k B B A A R The transmission coefficient is()2212141k k k k T R T +=⇒-=_______________________________________()()x k A x 222exp -=ψ ()()x k AA x P 2*2222exp -==ψwhere ()222E V m k o -=()()()34193110054.1106.18.25.31011.92---⨯⨯-⨯=9210286.4⨯=k m 1-(a) For 101055-⨯==oA x m ()x k P 22exp -=()()[]109105102859.42exp -⨯⨯-= 0138.0=(b) For 10101515-⨯==oA x m()()[]1091015102859.42exp -⨯⨯-=P61061.2-⨯= (c) For 10104040-⨯==oA x m()()[]1091040102859.42exp -⨯⨯-=P151029.1-⨯=_______________________________________()a k VE VET o o22exp 116-⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛≅ where ()222 E V m k o -=()()()34193110054.1106.11.00.11011.92---⨯⨯-⨯=or 2k 910860.4⨯=m 1- (a) For 10104-⨯=a m()()[]1091041085976.42exp 0.11.010.11.016-⨯⨯-⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛≅T 0295.0=(b) For 101012-⨯=a m()()[]10910121085976.42exp 0.11.010.11.016-⨯⨯-⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛≅T 51024.1-⨯=(c) υe N J t =, where t N is thedensity oftransmitted electrons.1.0=E eV 20106.1-⨯=J ()23121011.92121υυ-⨯==m510874.1⨯=⇒υm/s 710874.1⨯=cm/s()()719310874.1106.1102.1⨯⨯=⨯--t N810002.4⨯=t N electrons/cm 3 Density of incident electrons,10810357.10295.010002.4⨯=⨯=i N cm 3-_______________________________________()a k VEV E T O O 22exp 116-⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛≅ (a) For ()o m m 067.0=()222E V m k O -=()()()()()2/1234193110054.1106.12.08.01011.9067.02⎪⎭⎪⎬⎫⎪⎩⎪⎨⎧⨯⨯-⨯=---or9210027.1⨯=k m 1- Then⎪⎭⎫⎝⎛-⎪⎭⎫ ⎝⎛=8.02.018.02.016T()()[]109101510027.12exp -⨯⨯-⨯or138.0=T (b) For ()o m m 08.1=2k =()()()()()2/1234193110054.1106.12.08.01011.908.12⎪⎭⎪⎬⎫⎪⎩⎪⎨⎧⨯⨯-⨯---or9210124.4⨯=k m 1- Then⎪⎭⎫⎝⎛-⎪⎭⎫ ⎝⎛=8.02.018.02.016T()()[]109101510124.42exp -⨯⨯-⨯or51027.1-⨯=T_______________________________________()a k VE VET o o22exp 116-⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛≅ where ()222 E V m k o -=()()()341962710054.1106.1101121067.12---⨯⨯⨯⨯-⨯=1410274.7⨯=m 1- (a)()()[]14141010274.72exp 121112116-⨯-⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛≅T[]548.14exp 222.1-=710875.5-⨯=(b)()()710875.510-⨯=T()[]a 1410274.72exp 222.1⨯-=()⎪⎭⎫⎝⎛⨯=⨯-61410875.5222.1ln 10274.72a or 1410842.0-⨯=a m_______________________________________Region I ()0<x , 0=V ; Region II ()a x <<0, O V V =Region III ()a x >, 0=V (a) Region I:()()()x jk B x jk A x 11111exp exp -+=ψ(incident) (reflected)where 212 mEk = Region II:()()()x k B x k A x 22222exp exp -+=ψ where ()222 E V m k O -=Region III:()()()x jk B x jk A x 13133exp exp -+=ψ (b)In Region III, the 3B term represents areflected wave. However, once a particleis transmitted into Region III, there willnot be a reflected wave so that03=B .(c) Boundary conditions: At 0=x : ⇒=21ψψ 2211B A B A +=+⇒=dxd dx d 21ψψ22221111B k A k B jk A jk -=- At a x =: ⇒=32ψψ()()a k B a k A 2222exp exp -+()a jk A 13exp =⇒=dxd dx d 32ψψ()()a k B k a k A k 222222exp exp --()a jk A jk 131exp =The transmission coefficient is defined as *11*33A A A A T =so from the boundary conditions, we wantto solve for 3A in terms of 1A . Solvingfor 1A in terms of 3A , we find(){()()[]a k a k k k k k jA A 2221222131exp exp 4---+=()()[]}a k a k k jk 2221exp exp 2-+-()a jk 1exp ⨯ We then find()(){()[a k k kk k A A A A 22122221*33*11exp 4-=()]22exp a k --()()[]}2222221exp exp 4a k a k k k -++ We have ()222 E V m k O -=If we assume that E V O >>, thena k 2 willbe large so that()()a k a k 22exp exp ->> We can then write()(){()[]222122221*33*11exp 4a k k k k k A A A A -=()[]}222221exp 4a k k k + which becomes()()()a k k k k k A A A A 22122221*33*112exp 4+= Substituting the expressions for1k and2k , we find222212 O mV k k =+and()⎥⎦⎤⎢⎣⎡⎥⎦⎤⎢⎣⎡-=22222122 mE E V m k k O ()()E E V m O -⎪⎭⎫⎝⎛=222()()E V E V m O O ⎪⎪⎭⎫ ⎝⎛-⎪⎭⎫ ⎝⎛=1222 Then()()⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫⎝⎛-⎪⎭⎫ ⎝⎛⎪⎪⎭⎫ ⎝⎛=E V E V m a k mV A A A A O O O12162exp 222222*33*11()a k V E V E A A O O 2*332exp 116-⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛=Finally,()a k V E V E A A A A T O O 2*11*332exp 116-⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛==_____________________________________Region I: 0=V()()⇒=+∂∂0212212x mEx x ψψ()()()x jk B x jk A x 11111exp exp -+=ψincident reflected where212mEk = Region II: 1V V =()()()⇒=-+∂∂02221222x V E m x x ψψ()()()x jk B x jk A x 22222exp exp -+=ψtransmitted reflected where()2122 V E m k -=Region III: 2V V =()()()⇒=-+∂∂02322232x V E m x x ψψ()()x jk A x 333exp =ψtransmittedwhere ()2232 V E m k -=There is no reflected wave in Region III.The transmission coefficient is defined as:*11*3313*11*3313A A A A k k A A A A T ⋅=⋅=υυ From the boundary conditions, solve for 3Ain terms of 1A . The boundary conditions are:At 0=x : ⇒=21ψψ2211B A B A +=+⇒∂∂=∂∂xx 21ψψ22221111B k A k B k A k -=- At a x =: ⇒=32ψψ()()a jk B a jk A 2222exp exp -+()a jk A 33exp =⇒∂∂=∂∂xx 32ψψ()()a jk B k a jk A k 222222exp exp --()a jk A k 333exp = But ⇒=πn a k 22()()1exp exp 22=-=a jk a jk Then, eliminating 1B , 2A , 2Bfrom theboundary condition equations, we find()()23131231211344k k k k k k k k k T +=+⋅= _______________________________________(a) Region I: Since E V O >, we canwrite()()()0212212=--∂∂x E V m x x O ψψ Region II: 0=V , so()()0222222=+∂∂x mEx x ψψRegion III: 03=⇒∞→ψVThe general solutions can be written,keeping in mind that 1ψ must remainfinite for 0<x , as ()()x k B x 111exp =ψ()()()x k B x k A x 22222cos sin +=ψ ()03=x ψ where()212 E V m k O -=and222 mEk =(b) Boundary conditions At 0=x : ⇒=21ψψ21B B = 221121A k B k xx =⇒∂∂=∂∂ψψ At a x =: ⇒=32ψψ ()()0cos sin 2222=+a k B a k A or()a k A B 222tan -= (c)12122211B kk A A k B k ⎪⎪⎭⎫ ⎝⎛=⇒= and since 21B B =, then2212B k k A ⎪⎪⎭⎫⎝⎛=From ()a k A B 222tan -=, we canwrite()a k B k k B 22212tan ⎪⎪⎭⎫⎝⎛-=or()a k k k 221tan 1⎪⎪⎭⎫⎝⎛-=This equation can be written as ⎥⎥⎦⎤⎢⎢⎣⎡⋅⋅--=a mE E EV O22tan 1 or⎥⎥⎦⎤⎢⎢⎣⎡⋅-=-a mE E V EO 22tan This last equation is valid only for specific values of the total energy E . The energy levels are quantized._______________________________________()222424n e m E o o n ∈-=π(J)()222324ne m o o ∈-=π(eV)()()()[]()22342123193110054.121085.84106.11011.9n----⨯⨯⨯⨯-=πor 258.13n E n -=(eV) 58.1311-=⇒=E n eV 395.322-=⇒=E n eV 51.133-=⇒=E n eV 849.044-=⇒=E n eV_______________________________________We have ⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫⎝⎛⋅=o oa r a exp 112/3100πψ and*10010024ψψπr P =⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫⎝⎛⋅⋅=o oa r a r 2exp 11432ππ or()⎪⎪⎭⎫ ⎝⎛-⋅=o o a r r a P 2exp 423 To find the maximum probability()0=drr dP()()⎪⎪⎭⎫ ⎝⎛-⎪⎩⎪⎨⎧⎪⎪⎭⎫ ⎝⎛-=o o o a r r a a 2exp 2423 ⎪⎭⎪⎬⎫⎪⎪⎭⎫ ⎝⎛-+o a r r 2exp 2 which giveso oa r a r=⇒+-=10or o a r = is the radius that gives the greatest probability._______________________________________100ψ is independent of θ and φ, so the waveequation in spherical coordinates reduces to()()021222=-+⎪⎭⎫ ⎝⎛∂∂∂∂⋅ψψr V E m r r r r owhere()r a m r e r V o o o 224 -=∈-=πFor ⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫⎝⎛⋅=o oa r a exp 112/3100πψ Then⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛⋅=∂∂o o o a r a a r exp 1112/3100πψ so⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛⋅-=∂∂o oa r r a r r exp 1122/51002πψ We then obtain2/5100211⎪⎪⎭⎫⎝⎛⋅-=⎪⎪⎭⎫ ⎝⎛∂∂∂∂o a r r r πψ⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛-⨯o o o a r a r a r r exp exp 22 Substituting into the wave equation, we have⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛--⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫⎝⎛⋅-o o o o a r a r a r r a r exp exp 21122/52π⎥⎦⎤⎢⎣⎡++r a m E m o o o 2220exp 112/3=⎪⎪⎭⎫⎝⎛-⎪⎪⎭⎫ ⎝⎛⋅⎪⎪⎭⎫ ⎝⎛⨯o o a r a π where()222241224oo o o a m e m E E -=∈-==π Then the above equation becomes⎪⎩⎪⎨⎧⎥⎦⎤⎢⎣⎡--⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛⋅o o o o a r r a r a r a 222/321exp 11π 022222=⎪⎭⎪⎬⎫⎪⎪⎭⎫ ⎝⎛+-+r a m a m m o o o o o or⎥⎥⎦⎤⎢⎢⎣⎡⎪⎪⎭⎫ ⎝⎛-⎪⎪⎭⎫ ⎝⎛⋅o o a r a exp 112/3π0211222=⎪⎭⎪⎬⎫⎪⎩⎪⎨⎧⎪⎪⎭⎫ ⎝⎛+-++-⨯r a a a r a o o o o which gives 0 = 0 and shows that100ψ isindeed a solution to the wave equation._______________________________________All elements are from the Group I column ofthe periodic table. All have one valenceelectron in the outer shell. _______________________________________。
