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三氯化铁安全技术说明书（MSDS）第一部分：化学品名称国标编号：81513 CAS：7705-08-0中文名称：三氯化铁英文名称：Ferric trichloride；Ferric chloride别名：氯化铁分子式：FeCl3分子量：162.21熔点：306℃密度：相对密度（水=1）2.90；蒸汽压：溶解性：易溶于水，不溶于革油，易溶于甲醇、乙醇、丙酮、乙醚稳定性：稳定外观与性状：黑棕色结晶，也有薄片状危险标记：20（酸性腐蚀品）用途：用作饮水和废水的处理剂，染料工业的氧化剂和媒染剂，有机合成的催化剂和氧化剂第二部分：监测方法:原子吸收法《食品中添加剂的分析方法》，马家骧等译比色法(EPA方法9250)滴定法(EPA方法9252)第三部分：危险性概述侵入途径：吸入、食入、经皮吸收。
健康危害：吸入本品粉尘对整个呼吸道有强烈腐蚀作用，损害粘膜组织，引起化学性肺炎等。
对眼有强烈腐蚀性，重者可导致失明。
皮肤接触可致化学性灼伤。
口服灼伤口腔和消化道，出现剧烈腹痛、呕吐和虚脱。
慢性影响：长期口服有可能引起肝肾损害。
燃爆危险：本品不燃，具腐蚀性、强刺激性，可致人体灼伤。
第四部分：急救措施皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15分钟。
就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15分钟。
就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
食入：用水漱口，给饮牛奶或蛋清。
就医。
第五部分：消防措施危险特性：受高热分解产生有毒的腐蚀性烟气。
有害燃烧产物：氯化物。
灭火方法：采用水、泡沫、二氧化碳灭火。
第六部分：泄漏应急处理应急处理：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿防毒服。
不要直接接触泄漏物。
小量泄漏：用洁净的铲子收集于干燥、洁净、有盖的容器中。
也可以用大量水冲洗，洗水稀释后放入废水系统。
大量泄漏：用塑料布、帆布覆盖。
Ferric Chloride SolutionMaterial Safety Data Sheet1. Product IdentificationSynonyms: Iron (III) Chloride SolutionCAS No.: 7705-08-0Molecular Weight: Not applicable to mixtures.Chemical Formula: FeCl3 in H2OProduct Codes: 52512. Composition/Information on IngredientsIngredient CAS No Percent Hazardous --------------------------------------- ------------ --------Ferric Chloride 7705-08-0 35 - 45% YesWater 7732-18-5 55 - 65% No3. Hazards IdentificationEmergency Overview--------------------------DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE LIVER. SAF-T-DATA(tm) Ratings (Provided here for your convenience)---------------------------------------------------------------------Health Rating: 2 - ModerateFlammability Rating: 0 - NoneReactivity Rating: 2 - ModerateContact Rating: 3 - Severe (Corrosive)Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENTHOOD; PROPER GLOVESStorage Color Code: White (Corrosive)---------------------------------------------------------------------Potential Health Effects----------------------------------Inhalation:Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.Ingestion:Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach. Can cause sore throat, vomiting, diarrhea. Low systemic toxicity in small quantities but larger doses may cause systemic effects. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma and death may follow, sometimes delayed as long as three days.Skin Contact:Corrosive. Symptoms of redness, pain, and severe burn can occur.Eye Contact:Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Chronic Exposure:Repeated ingestion may cause liver damage. Prolonged exposure of the eyes may cause discoloration.Aggravation of Pre-existing Conditions:No information found.4. First Aid MeasuresInhalation:Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.Ingestion:If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact:Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.Eye Contact:Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting MeasuresFire:Not considered to be a fire hazard. Irritating hydrogen chloride fumes may form in fire.Explosion:Not considered to be an explosion hazard.Fire Extinguishing Media:Water, dry chemical, foam or carbon dioxide. Do not allow water runoff to enter sewers or waterways.Special Information:In the event of a fire, wear full protective clothing and NIOSH-approvedself-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.6. Accidental Release MeasuresVentilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer!7. Handling and StorageKeep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material are hazardous when empty since they retain product residues; observe all warnings for the product.8. Exposure Controls/Personal ProtectionAirborne Exposure Limits:-ACGIH Threshold Limit Value (TLV):1 mg/m3 (TWA) soluble iron salt as FeVentilation System:A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.Personal Respirators (NIOSH Approved):If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING:Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection:Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.Eye Protection:Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.9. Physical and Chemical PropertiesAppearance:Orange to brown liquid.Odor:Acid odor.Solubility:Complete (100%)Specific Gravity:1.40pH:No information found.% Volatiles by volume @ 21C (70F):55-65Boiling Point:230C (446F)Melting Point:No information found.Vapor Density (Air=1):No information found.Vapor Pressure (mm Hg):No information found.Evaporation Rate (BuAc=1):No information found.10. Stability and ReactivityStability:Stable under ordinary conditions of use and storage.Hazardous Decomposition Products:May produce hydrogen chloride.Hazardous Polymerization:This substance does not polymerize.Incompatibilities:Metals, allyl chloride, sodium, potassium.Conditions to Avoid:Incompatibles.11. Toxicological InformationOral rat LD50: 316 mg/kg (anhydrous); investigated as a mutagen, reproductive effector.--\CancerLists\---------------------------------------------------------NTP Carcinogen---Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- -------------Ferric Chloride (7705-08-0) No No None Water (7732-18-5) No No None 12. Ecological InformationEnvironmental Fate:No information found.Environmental Toxicity:No information found.13. Disposal ConsiderationsWhatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from disposal regulations. Dispose of container and unused contents in accordance with state and local requirements.14. Transport InformationNot regulated.15. Regulatory Information-\Chemical Inventory Status - Part 1\--------------------------------Ingredient TSCA EC Japan Australia----------------------------------------------- ---- --- -----Ferric Chloride (7705-08-0) Yes Yes Yes YesWater (7732-18-5) Yes Yes Yes Yes\Chemical Inventory Status - Part 2\-----------------------------------Canada-- Ingredient Korea DSL NDSL China. ----------------------------------------------- ----- --- ----Ferric Chloride (7705-08-0) Yes Yes No Yes Water (7732-18-5) Yes Yes No Yes-\China & International Regulations - Part 1\-----------------SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg.----------------------------------------- --- ----- ----Ferric Chloride (7705-08-0) No No No NoWater (7732-18-5) No No No No\China & International Regulations - Part 2\-----------------RCRA- -TSCA-Ingredient CERCLA 261.33 8(d)----------------------------------------- ------ ------ --Ferric Chloride (7705-08-0) 1000 No NoWater (7732-18-5) No No NoChemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: No (Mixture / Liquid)Australian Hazchem Code: None allocated.Poison Schedule: None allocated.WHMIS:This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information requiredby the CPR.16. Other InformationNFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0Label Hazard Warning:DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE LIVER.Label Precautions:Do not get in eyes, on skin, or on clothing.Do not breathe mist.Keep container closed.Use only with adequate ventilation.Wash thoroughly after handling.Label First Aid:In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases get medical attention immediately.Product Use:Laboratory Reagent.Revision Information:MSDS Section(s) changed since last revision of document include: 3.。
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：三氯化铁[无水]；氯化铁化学品英文名：ferric trichloride（anhydrous）；ferric chloride企业名称：生产企业地址：邮编: 传真:企业应急电话：电子邮件地址：技术说明书编码:第二部分成分/组成信息√纯品混合物有害物成分浓度CAS No.三氯化铁7705-08-0第三部分危险性概述危险性类别：第8.1类酸性腐蚀品侵入途径：吸入、食入健康危害：吸入本品粉尘对整个呼吸道有强烈腐蚀作用，损害粘膜组织，引起化学性肺炎等。
对眼有强烈腐蚀性，重者可导致失明。
皮肤接触可致化学性灼伤。
口服灼伤口腔和消化道，出现剧烈腹痛、呕吐和虚脱。
慢性影响长期口服有可能引起肝、肾损害。
环境危害：对环境有害。
燃爆危险：不燃，无特殊燃爆特性。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗20～30分钟。
如有不适感，就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗10～15分钟。
如有不适感，就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行心肺复苏术。
就医。
食入：用水漱口，给饮牛奶或蛋清。
就医。
第五部分消防措施危险特性：受高热分解产生有毒的腐蚀性烟气。
有害燃烧产物：无意义。
灭火方法：用水、泡沫、二氧化碳灭火。
灭火注意事项及措施：消防人员必须佩戴空气呼吸器、穿全身防火防毒服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
第六部分泄漏应急处理应急行动：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘口罩，穿防酸碱服。
作业时使用的所有设备应接地。
穿上适当的防护服前严禁接触破裂的容器和泄漏物。
尽可能切断泄漏源。
小量泄漏：用干燥的砂土或其它不燃材料覆盖泄漏物，然后用塑料布覆盖，减少飞散、避免雨淋。
用洁净的铲子收集泄漏物，置于干净、干燥、盖子较松的容器中，将容器移离泄漏区。
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：三氯化铁[无水]；氯化铁化学品英文名：ferric trichloride（anhydrous）；ferric chloride企业名称：生产企业地址：邮编: 传真:企业应急电话：电子邮件地址：技术说明书编码:第二部分成分/组成信息√纯品混合物有害物成分浓度CAS No.三氯化铁7705-08-0第三部分危险性概述危险性类别：第8.1类酸性腐蚀品侵入途径：吸入、食入健康危害：吸入本品粉尘对整个呼吸道有强烈腐蚀作用，损害粘膜组织，引起化学性肺炎等。
对眼有强烈腐蚀性，重者可导致失明。
皮肤接触可致化学性灼伤。
口服灼伤口腔和消化道，出现剧烈腹痛、呕吐和虚脱。
慢性影响长期口服有可能引起肝、肾损害。
环境危害：对环境有害。
燃爆危险：不燃，无特殊燃爆特性。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗20～30分钟。
如有不适感，就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗10～15分钟。
如有不适感，就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行心肺复苏术。
就医。
食入：用水漱口，给饮牛奶或蛋清。
就医。
第五部分消防措施危险特性：受高热分解产生有毒的腐蚀性烟气。
有害燃烧产物：无意义。
灭火方法：用水、泡沫、二氧化碳灭火。
灭火注意事项及措施：消防人员必须佩戴空气呼吸器、穿全身防火防毒服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
第六部分泄漏应急处理应急行动：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘口罩，穿防酸碱服。
作业时使用的所有设备应接地。
穿上适当的防护服前严禁接触破裂的容器和泄漏物。
尽可能切断泄漏源。
小量泄漏：用干燥的砂土或其它不燃材料覆盖泄漏物，然后用塑料布覆盖，减少飞散、避免雨淋。
用洁净的铲子收集泄漏物，置于干净、干燥、盖子较松的容器中，将容器移离泄漏区。
一、物品與廠商資料物品名稱：氯化鐵溶液 (FERRIC CHLORIDE SOLUTION) 製造商或供應商名稱、地址及電話:利邦化工水處理有限公司香港荃灣沙咀道57道荃運工業中心二期15樓C室緊急聯絡電話/傳真電話：852-******** / 852-********二、成分辦識資料中英文名稱：氯化鐵溶液(FERRIC CHLORIDE SOLUTION) 同義名稱：IRON (Ⅲ) CHLORIDE、FERRIC CHLORIDE化學文摘社登記號碼(CAS No.)：07505-85-2危害物質成分(成分百分比)：10%三、危害辦識資料最重要危害效健康危害效應：吸入- 極度腐蝕整個呼吸道2.呼吸粉塵會破壞黏膜,並引起嚴重肺炎。
眼睛- 極度腐蝕眼睛2.短暫的接觸會引起嚴重眼睛傷害，若長期接觸會引起永久性眼睛傷害，可能導致失明。
皮膚- 極度腐蝕皮膚，快速引起嚴重的化學灼傷2.皮膚表面的水氣(如汗)，將加速組織的破壞。
食入- 極度腐蝕嘴和喉嚨2.吞食粉塵或固體會引起嘴、喉嚨和消化道嚴重快速的灼傷，伴隨的是極度疼痛、嘔吐和虛脫3.可能導致肝和／或腎的嚴重傷害。
環境影響：無資料物理性及化學性危害：極度腐蝕金屬。
特殊危害：無資料主要症狀：無資料物品危害分類：金屬腐蝕物第I級、腐蝕/刺激皮膚物質第I級、嚴重損傷/刺激眼睛物質第I級。
四、急救措施不同暴露途徑之急救方法：● 吸入：1.將患者移到空氣新鮮處2.若沒有呼吸，施予人工呼吸3.儘速就醫。
● 皮膚接觸：1.立刻用大量肥皂和水清洗2.脫除受污染的衣服和鞋子3.若清洗後仍感剌激，儘速就醫。
● 眼睛接觸：1.立刻用大量流水沖洗15分鐘以上，並不時地翻動上下眼皮2.儘速就醫。
● 食入：1.不要催吐2.若患者意識清醒，喝下大量的水3.若患者無意識或痙攣，不要餵食任何東西。
最重要症狀及危害效應：具腐蝕性，可造成致命的肺水腫、引起灼傷、甚至失明。
對急救人員之防護：未穿著化學防護衣及呼吸防護具之人員不應進入災區搬運傷患，至少應穿著防護裝備，始可在安全區實施傷患急救。
氯化铁—msds氯化铁MSDS一、标识中文名称：三氯化铁化学品俗名：氯化铁化学品英文名称：ferric trichloride技术说明说编号：970 CAS号：7705-08-0危险货物编号：81513 UN编号：1773包装类别：O52二、理化特性外观与性状：黑棕色结晶，也有薄皮状。
pH：熔点(℃)：306 沸点(℃)319分子式：FeCl3 分子量：162.21相对密度(水=1)：2.90 相对蒸气密度(空气=1)：5.61主要成分：纯品饱和蒸汽压(kPa)：燃烧热(kJ/mol)：临界温度(℃)：临界压力(℃)：辛醇/水分配系数的对数值：溶解性：易溶于水，不溶于甘油，易溶于甲醇、乙醇、丙酮、乙醚。
主要用途：用作饮水和废水处理剂，染料工业的氧化剂和媒染剂，有机合成的催化剂和氧化剂。
其他理化特性：315三、燃烧爆炸危险性闪点(℃) 引燃温度(℃)：爆炸上限(V%)：爆炸下限(V%)：禁配物：强氧化剂、钾、纳。
灭火方法：采用水、泡沫、二氧化碳灭火。
四、毒性危害危险性类别：侵入途径：危险特性：受高热分解产生有毒的腐蚀性气体。
有害燃烧产物：氯化物健康危害：吸入本品粉尘对整个呼吸道有强烈的腐蚀作用，损害粘膜组织，引起化学性肺炎等。
对眼有强烈的腐蚀性，严重可导致失明。
皮肤接触可致化学灼伤。
口服灼伤口和消化道，出现剧烈腹痛、呕吐和虚脱。
慢性影响：长期口服有可能肝肾损害。
环境危害：燃爆危险：本品不燃，具有腐蚀性、强刺激性，可致人体灼伤。
五、急救措施皮肤接触：立即脱去污染的衣着，用大量的流动的清水冲洗至少15分钟。
就医。
眼睛接触：立即提起眼睑，用大量流动的清水或生理盐水冲洗至少15分钟。
就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道畅通。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
食入：用水漱口，给牛奶或蛋清。
就医。
六、防护措施泄露处理：隔离污染区域，限制出入。
建议应急处理人员戴防尘面具(全面罩)，穿防毒服。
六水三氯化铁技术说明书物质的理化常数国标编号81513CAS号7705-08-0中文名称三氯化铁英文名称Ferric trichloride；Ferric chloride别名六水氯化铁化学式FeCl3 .6H2O 外观为棕黄色结晶，也有薄片状分子量270 沸点319℃熔点306℃溶解性易溶于水（溶液呈棕黄色），不溶于革油，易溶于甲醇、乙醇、丙酮、乙醚危险标记20(酸性腐蚀品) 主要用途用作饮水和废水的处理剂，染料工业的氧化剂和媒染剂，有机合成的催化剂和氧化剂对环境的影响一、健康危害侵入途径：吸入、食入、经皮吸收。
健康危害：吸入本品粉尘对整个呼吸道有强烈刺激腐蚀作用，损害粘膜组织，引起化学性肺炎等。
对眼有强烈腐蚀性，重者可导致失明。
皮肤接触可致化学性灼伤。
口服灼伤口腔和消化道，出现剧烈腹痛、呕吐和虚脱。
慢性影响：长期摄入有可能引起肝肾损害。
二、毒理学资料及环境行为急性毒性：LD50 1872mg/kg(大鼠经口)危险特性：受高热分解产生有毒的腐蚀性气体。
燃烧(分解)产物：氯化物。
应急处理处置方法一、泄漏应急处理隔离泄漏污染区，周围设警告标志，建议应急处理人员戴好防毒面具，穿化学防护服。
不要直接接触泄漏物，避免扬尘，收集运至废物处理场所处置。
使其溶于a.水、b.酸、或c.氧化成水溶液状态，再加硫化物发生沉淀反应，然后废弃。
也可以用大量水冲洗，经稀释的洗水放入废水系统。
如大量泄漏，收集回收或无害处理后废弃。
二、防护措施呼吸系统防护：可能接触其粉尘时，应该佩带防尘口罩。
必要时佩带防毒面具。
眼睛防护：戴化学安全防护眼镜。
防护服：穿工作服(防腐材料制作)。
手防护：戴橡皮手套。
其它：工作后，淋浴更衣。
单独存放被毒物污染的衣服，洗后再用。
保持良好的卫生习惯。
三、急救措施皮肤接触：立即用水冲洗至少15分钟。
若有灼伤，就医治疗。
眼睛接触：立即提起眼睑，用流动清水或生理盐水冲洗至少15分钟。
就医。
吸入：迅速脱离现场至空气新鲜处。
三氯化铁安全技术说明书 三氯化铁；三氯化铁ferric trichloride （anhydrous ）； ferric chloride162.21 中文名 英文名[无水 ]；氯化铁标 识分子式危规号 FeCl 3 分子量 UN 编号 CAS 号 815131773 RTECS 号 7705-08-0 黑棕色结晶，也有薄片状 主要组成熔点℃性状易溶于水，不溶于甘油，易溶于甲醇、乙醇、丙 酮、乙醚306319溶解性理 化 性相对密度 (水 =1) 沸点℃2.905.61质饱和蒸气压KPa 相对蒸气密度(空气 =1)：5.61临界温 度℃ 无资料 燃烧热 无意义临界压力 MPa 最小引燃能 量 mJ 无资料 不燃无意义 氯化物燃燃烧性分解产物烧闪点℃ 无意义 无意义聚合危险 稳定性不聚合 稳定爆爆炸极 炸限% 危引燃温 强氧化剂、钾、钠无意义 禁忌物险 性度℃ 不燃，无特殊燃爆特性。
受高热分解产生有毒 的腐蚀性烟气。
危险特性消防人员必须佩戴空气呼吸器、穿全身防火防毒服，灭火方法 在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
灭火剂用水、泡沫、二氧化碳灭火急性毒性：对粘膜具有轻度刺激性和腐蚀性。
对家兔静注 的 LD毒为 7.2mg/kg 。
LD50：大鼠经口 LD50(mg/kg): 316小鼠经口 性 LD50(mg/kg): 200DNA 1刺激性：致突变性： 损伤：人类细胞umol/L/1H 。
对 吸入本品粉尘对整个呼吸道有强烈腐蚀作用，损害粘膜组织，引 起化学性肺炎等。
对眼有强烈腐蚀性，重者可导致失明。
皮肤接 触可致化学性灼伤。
口服灼伤口腔和消化道，出现剧烈腹痛、呕 吐和虚脱。
慢性影响 长期口服有可能引起肝、肾损害。
人 体 伤 害皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗20～30 分钟。
如有不适感，就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗急10～15分钟。
Ferric Chloride SolutionMaterial Safety Data Sheet1. Product IdentificationSynonyms: Iron (III) Chloride SolutionCAS No.: 7705-08-0Molecular Weight: Not applicable to mixtures.Chemical Formula: FeCl3 in H2OProduct Codes: 52512. Composition/Information on IngredientsIngredient CAS No Percent Hazardous --------------------------------------- ------------ --------Ferric Chloride 7705-08-0 35 - 45% YesWater 7732-18-5 55 - 65% No3. Hazards IdentificationEmergency Overview--------------------------DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE LIVER. SAF-T-DATA(tm) Ratings (Provided here for your convenience)---------------------------------------------------------------------Health Rating: 2 - ModerateFlammability Rating: 0 - NoneReactivity Rating: 2 - ModerateContact Rating: 3 - Severe (Corrosive)Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENTHOOD; PROPER GLOVESStorage Color Code: White (Corrosive)---------------------------------------------------------------------Potential Health Effects----------------------------------Inhalation:Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.Ingestion:Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach. Can cause sore throat, vomiting, diarrhea. Low systemic toxicity in small quantities but larger doses may cause systemic effects. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma and death may follow, sometimes delayed as long as three days.Skin Contact:Corrosive. Symptoms of redness, pain, and severe burn can occur.Eye Contact:Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Chronic Exposure:Repeated ingestion may cause liver damage. Prolonged exposure of the eyes may cause discoloration.Aggravation of Pre-existing Conditions:No information found.4. First Aid MeasuresInhalation:Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.Ingestion:If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact:Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.Eye Contact:Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting MeasuresFire:Not considered to be a fire hazard. Irritating hydrogen chloride fumes may form in fire.Explosion:Not considered to be an explosion hazard.Fire Extinguishing Media:Water, dry chemical, foam or carbon dioxide. Do not allow water runoff to enter sewers or waterways.Special Information:In the event of a fire, wear full protective clothing and NIOSH-approvedself-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.6. Accidental Release MeasuresVentilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer!7. Handling and StorageKeep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material are hazardous when empty since they retain product residues; observe all warnings for the product.8. Exposure Controls/Personal ProtectionAirborne Exposure Limits:-ACGIH Threshold Limit Value (TLV):1 mg/m3 (TWA) soluble iron salt as FeVentilation System:A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.Personal Respirators (NIOSH Approved):If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING:Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection:Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.Eye Protection:Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.9. Physical and Chemical PropertiesAppearance:Orange to brown liquid.Odor:Acid odor.Solubility:Complete (100%)Specific Gravity:1.40pH:No information found.% Volatiles by volume @ 21C (70F):55-65Boiling Point:230C (446F)Melting Point:No information found.Vapor Density (Air=1):No information found.Vapor Pressure (mm Hg):No information found.Evaporation Rate (BuAc=1):No information found.10. Stability and ReactivityStability:Stable under ordinary conditions of use and storage.Hazardous Decomposition Products:May produce hydrogen chloride.Hazardous Polymerization:This substance does not polymerize.Incompatibilities:Metals, allyl chloride, sodium, potassium.Conditions to Avoid:Incompatibles.11. Toxicological InformationOral rat LD50: 316 mg/kg (anhydrous); investigated as a mutagen, reproductive effector.--\CancerLists\---------------------------------------------------------NTP Carcinogen---Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- -------------Ferric Chloride (7705-08-0) No No None Water (7732-18-5) No No None 12. Ecological InformationEnvironmental Fate:No information found.Environmental Toxicity:No information found.13. Disposal ConsiderationsWhatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from disposal regulations. Dispose of container and unused contents in accordance with state and local requirements.14. Transport InformationNot regulated.15. Regulatory Information-\Chemical Inventory Status - Part 1\--------------------------------Ingredient TSCA EC Japan Australia----------------------------------------------- ---- --- -----Ferric Chloride (7705-08-0) Yes Yes Yes YesWater (7732-18-5) Yes Yes Yes Yes\Chemical Inventory Status - Part 2\-----------------------------------Canada-- Ingredient Korea DSL NDSL China. ----------------------------------------------- ----- --- ----Ferric Chloride (7705-08-0) Yes Yes No Yes Water (7732-18-5) Yes Yes No Yes-\China & International Regulations - Part 1\-----------------SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg.----------------------------------------- --- ----- ----Ferric Chloride (7705-08-0) No No No NoWater (7732-18-5) No No No No\China & International Regulations - Part 2\-----------------RCRA- -TSCA-Ingredient CERCLA 261.33 8(d)----------------------------------------- ------ ------ --Ferric Chloride (7705-08-0) 1000 No NoWater (7732-18-5) No No NoChemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: No (Mixture / Liquid)Australian Hazchem Code: None allocated.Poison Schedule: None allocated.WHMIS:This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information requiredby the CPR.16. Other InformationNFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0Label Hazard Warning:DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE LIVER.Label Precautions:Do not get in eyes, on skin, or on clothing.Do not breathe mist.Keep container closed.Use only with adequate ventilation.Wash thoroughly after handling.Label First Aid:In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases get medical attention immediately.Product Use:Laboratory Reagent.Revision Information:MSDS Section(s) changed since last revision of document include: 3.。
