相关物质液相色谱法（2.2.29）待测溶液用流动相溶解25.0mg的待测物质并稀释到50.0ml。
标准溶液（a）用流动相溶解25.0mg硫酸新霉素B的化学标准品并稀释到50.0ml。
标准溶液（b）吸取5.0ml参比溶液（a）并用流动相稀释到100.0ml。
标准溶液（c）吸取1.0ml参比溶液（a）并用流动相稀释到100.0ml。
标准溶液（d）用流动相溶解一小瓶新霉胺化学标准品物质（相当于0.5mg）并用流动相稀释到50.0ml。
标准溶液（e）用流动相溶解10mg硫酸新霉素化学标准品并用流动相稀释到100.0ml。
色谱柱：——尺寸：长度=0.25m，直径=4.6mm，——固定相：色谱级球形碱性去活辛基硅胶（5μm），——温度：25℃。
流动相混合20.0ml三氟乙酸试剂，6.0ml去CO2氢氧化钠溶液试剂和500ml试剂水，平衡后用试剂水稀释到1000ml，脱气。
流速0.7ml/min。
柱后溶液预先脱气的去CO2氢氧化钠溶液试剂稀释25倍（对使用375μl聚合混合线圈的柱流失施加更低的脉冲？）。
流速0.5ml/min。
检测附加一个金检测电极、一个银-氯化银参比电极和一个不锈钢附加电极的脉冲安培检测器，作为元件主体，分别保持0.00V检测电位、+0.80V氧化电位好-0.60V还原电位，及设备使用的脉冲宽度。
注入10μ；注入待测溶液和标准溶液（b）（c）（d）（e）。
运行时间新霉素B保留时间的1.5倍。
标准品保留时间相对新霉素B保留时间（大约10min）的相对保留率：杂质A=约0.65；杂质C=约0.9；杂质G=约1.1。
系统适配性：——分辨率：根据标准溶液（e）所获谱图中杂质C与新霉素B的峰值最小间隔2.0；如有需要，调整流动相中去CO2氢氧化钠溶液试剂的体积，——信号/噪音比率：对于由标准溶液（C）所获谱图的主峰此值最小为10。
限值——杂质A：不高于由标准溶液（d）（2.0%）所获谱图的主峰面积，——杂质C：不高于由标准溶液（b）（15.0%）所获谱图主峰面积的3倍；且不低于由标准溶液（b）（3.0%）所获谱图主峰面积的0.6倍，——任意其它杂质：不高于由标准溶液（b）（5.0%）所获谱图的主峰面积，——其他杂质总量：不高于由标准溶液（b）（15.0%）所获谱图的主峰面积的3倍，——忽略限值：由标准溶液（c）（1.0%）所获谱图的主峰面积。
HPLC法测定泛昔洛韦含量【我要发表论文】--------------------------------------------------------------------------------作者：陈珏正文目的：用高效液相色谱法测定泛昔洛韦。
方法：在ODS柱上，以磷酸盐缓冲液(0.02 mol．L-1磷酸二氢钾1 000 mL，加三乙胺3 mL，用85%磷酸调节至pH 2.5)-甲醇(65∶35)为流动相，于220 nm波长处检测，流速为1.0 mL．min-1；利巴韦林为内标，泛昔洛韦与内标的保留时间分别为4.90 min和2.77 min。
结果：浓度线性范围为0.01～0.08 mg．mL-1，重复性试验RSD=1.0%(n=5)。
结论：本法含量测定结果满意。
关键词泛昔洛韦HPLC法泛昔洛韦(Famcilovir)是一种新的嘌呤类抗病毒药，临床上用于单纯性疱疹的治疗。
国外最新研究表明，其口服吸收迅速，生物利用度为77%［1］。
在我国，该药已被研制成功，其含量测定方法尚未见报道。
本文探索用HPLC法进行含量测定，在ODS柱上以利巴韦林为内标，考察了色谱条件和定量的线性范围，对样品进行了含量测定，结果表明，本法简便、快速，结果准确。
1 仪器及药品Beckman 125高效液相色谱仪，166紫外检测器，System Gold软件。
泛昔洛韦对照品(含量99.8%)、原料由浙江海正药业公司提供，利巴韦林对照品由浙北制药厂提供。
甲醇为色谱纯，磷酸二氢钾、三乙胺均为分析纯，水为重蒸馏水。
2 色谱条件色谱柱Ultrashere ODS柱(5 μm,4.6 mm×250 mm)，Beckman公司；流动相：甲醇-磷酸盐缓冲液(0.02 mol.L-1磷酸二氢钾 1 000 mL，加三乙胺 3 mL,用85%磷酸调节至pH 2.5)(35∶65)；流速1.0 mL.min-1；检测波长220 nm；进样量：20 μL。
药品检验英语词汇对照学习药品标准质量标准标准品国际标准品参比标准对照品规格药品质量控制分析质量控制性状无臭异臭熔点熔距毛细管熔点测定热台熔点测定沸程凝点不溶性微粒颗粒细度膨胀度分子大小微晶结晶细度结晶性一般鉴别试验鉴别旋光计阿贝折射计浸入折射计限度检查有色杂质有关物质吸光度吸光系数吸光度比值澄清度氯化物硫酸盐重金属砷盐碘化物铁盐氰化物drug standard quality standard standard substance international standard substance reference standard reference substance specification drug quality control analytical quality control characteristics odorless foreign odor melting point melting range capillary melting point determi-nation hot stage melting point determi-nation boiling rangecongealing point particulate matter fineness of the particles swelling degree molecular size microcrystal crystal fineness crystallinity general identification test identification polarimeter Abbe refractometer immersion refractometer limit test foreign pigment related substance absorbance specific absorbance absorbance ratio clarity chloride sulfate heavy metal arsenic salt iodide iron salt cyanide 钡盐钙盐易碳化物易氧化物醚溶性酸性物酸中和容量热原异常毒性衰变放射性核纯度放射性浓度索氏[脂肪]抽提器丹氏浓缩器不皂化物羟值烷氧基测定范氏氨基氮测定法砷斑炽灼残渣蒸发残渣不挥发物总固体过氧化值干燥失重相溶解度分析装量差异最低装量含量测定含量均匀度溶出度崩解时限药物释放相对密度表观黏度比特性黏度运动黏度旋转黏度计落球黏度计稳定性试验总氮量比重瓶法韦氏比重秤法结冻试验抽针试验barium salt calcium salt readily carbonizable substance readily oxidizable substance ether-soluble acidic matter acid-neutralizing capacity pyrogen undue toxicity decay radionuclide purity radioactive concentration Soxhlet extractor Danish concentrator non-saponifiable matter hydroxyl value alkyloxy determination van Slyke method arsenic stain residue on ignition residue on evaporation non-volatile matter total solid peroxide value loss on drying phase solubility analysis content uniformity minimum fill assay uniformity of dosage units dissolution disintegration drug release relative density apparent viscosity specific intrinsic viscosity kinematic viscosity rotating cylinder viscometer falling sphere viscometer stability study nitrogen content pycnometric method hydrostatic method, Westphalbalancemethod freezing test consistence test 悬浮时间共沸法甲苯蒸馏法挥发油测定器滴定液标准比色液耐用性计算机辅助药物分析模式收敛特征特征选择试验集训练集校正集预示集岭回归响应面信号处理图象分析库检索变量校正多变量校正反向传播最优化方法窗口图解技术色谱响应函数色谱优化函数混合物设计统计技术叠加分辨率图示法数值分类法系统矩阵组合法双波长一元线性回归法多波长直线回归法系数倍率法最小二乘法自适应最小二乘偏最小二乘法非线性迭代偏最小二乘P矩阵法正交函数法卡尔曼滤波法suspension time azeotropic method toluene distillation method volatile oil determination apparatus volumetric solution, VS standard color solution ruggedness computational pharmaceutical analysis, computer-aided pharmaceutical analysis pattern convergence feature feature selection testset training set calibration set prediction set ridge regression response surface signal processing image analysis library searching variate calibration multivariate calibration back propagation optimization method window diagram technique chromatographic response function, CRF chromtographic optimization function, COF mixture design statistic technique overlapping resolution maps numerical taxonomy system matrix combination method dual-wavelength linear regression method multi-wavelength linear regression method K-ratio method, signal multiplier method least square method adaptive least square partial least square method nonlinear iterative partial least square P-matrix method orthogonal function method Kalman filtering method 适应卡尔曼滤波法卡尔曼增益线性学习机主成分分析主成分回归法逐步判别分析目标因子分析对应因子分析迭代目标转换因子分析法遗忘因子法特征向量投影非线性映射人工神经网络节点线性规划法共轭梯度法专家系统人工智能系统模型测量模型模型化与参数估计决策规则n维空间超平面相似性K最近邻域法快速傅里叶变换交互证实误差修正反馈法负反馈过程分析输出层输入层隐含层碘仿反应丙烯醛反应缩合反应异腈化苯N一溴丁二酰亚胺滴定法永停滴定法两相滴定剩余碱水解法催化热滴定adaptive Kalman filtering method Kalman gain linear learning machine principal component analysis, PCA principal component regression method stepwise discriminate analysis target factor analysis correspondence factor analysis iterative target transform factor analysis method forgetting factor method eigenvector projection nonlinear mapping artificial neural network node linear programming method conjugate gradientmethod expert system artificial intelligence system model measurement model modeling and parameterestimation decision rule n-dimensional space hyperplane similarity K-nearest neighbor method fast Fourier transform cross-validation error correct feed-back method negative feedback process analysis output layer input layer hidden layer iodoform reaction acrolein reaction condensation reaction phenyl isocyanide N-bromosuccinimide titration dead-stop titration diphasic titration residual basic hydrolysis method catalytic thermometric titration 非水催化热滴定提取重量法提取容量法四苯硼钠雷氏铵雷氏盐利伯曼试验马奎斯试验溴化氰试剂本内迪克特试剂茚三酮试剂酸性碘铂酸盐溶液曼德林试剂松柏醇试剂对氨基苯磺酸氨基磺酸氨基磺酸铵氨基蒽醌类染料苏丹蓝CN 苏丹绿4B 茜素青绿茜素亮紫3B 茜素亮紫R 氯胺T滴定法N- 溴代苯二甲酰亚胺滴定法席夫碱氧瓶燃烧法溴酸盐滴定法不可逆指示剂卡可基邻二氮菲本生阀二苯甲酮杜瓦瓶费林反应折光测定法铜刨花拓奎反应对萘酚苯甲醇溶剂蓝19 收敛酸锌收敛酸镉坚牢绿FCF 搔洛铬绿V150 nonaqueous catalytic thermometric titration extraction gravimetry extraction titration sodium tetraphenylborate ammonium reineckate Reinecke salt Liebermann test Marquis test cyanogen bromide reagent Benedict reagent ninhydrin reagent acidified iodoplatinate solution Mandelin reagent coniferyl alcohol reagent sulfanilic acid sulfamic acid ammonium sulfamate aminoanthraquinone dyes Sudan blue CN Sudan green 4B alizarin viridine alizarin brilliant violet 3B alizarin brilliant violet R chloramine-T titration, CAT titration N-bromophthalimide titration Schiff’s base oxygen flask combustion bromate titrationirreversible indicator cacodyl orthophenanthroline Bunsen valve benzophenone Dewar flask Fehling’s reaction refractometry copper turnings Thalleoquin reaction p-naphtholbenzein solvent blue 19 zinc styphnate cadmium styphnate fast green FCF solochrome green V150 热色效应呫吨硫色素反应拉尼镍2,6－二氯靛酚滴定法坂口试验麦芽酚反应莫利希试验缩合物埃光子能量外转换电子构型电子跃迁拉波特规律末端吸收肩峰曲折拐点桑德尔灵敏度深色效应浅色效应蓝移红移解线性方程组法等吸光点法二波长分光光度法三波长分光光度法导数分光光度法pH指示剂吸光度比值测定法多组分光谱分析电荷转移光谱荧光分析法分子荧光分析法流动吸收池微量吸收池长光程吸收池热谱带迈克尔森干涉仪荧胺丹酰氯猝灭荧光测定法化学发光免疫分析法荧光免疫分析thermochromism effectxanthene thiochrome reaction Raney nickel 2, 6--dichlorindophenol titration Sakaguchi test maltol reaction Molisch test condensation substance angstr?m, ? photon external conversion of energy electronic configuration electron transition Laport’s law end absorption shoulder peak deflection deflection point Sandell’s sensitivity hyperchromic effect hypsochromic effect blue shift red shift simultaneous equations method isosbestic point method dual wavelength spectrophotometry three wavelength spectrophotome-try derivative spectrophotometry pH indicator absorbance ratio method multicomponent spectrophotometry charge-transfer spectrum fluorimetry molecular fluorescent method flow cell, flow cuvette micro cell long path cell hot bands Michelson interferometer fluorescamine dansyl chloride, DANS-Cl quenchingfluorometry chemiluminescence immunoassay, CIA fluorescence immunoassay, FIA 酶免疫分析鲁米诺荧光偏振免疫分析胶束增敏荧光分析法伸缩振动弯曲振动变形振动对称伸缩振动不对称伸缩振动剪式振动平面摇摆振动非平面摇摆振动扭曲振动呼吸振动振动弛豫振动偶合基频吸收带倍频吸收带费米共振能斯特灯镍铬线圈硅碳棒双光束光学零位平衡系统电比率记录式电学零位平衡系统漫反射衰减全反射多次内反射光束聚焦装置聚苯乙烯薄膜波数压片法石蜡糊法膜法光管热电偶检测器戈雷检测器氘化三甘氨硫酸酯检测器碲化汞一碲化镉复合半导体检测器指纹区光谱检索谱线检索光谱差减法enzyme immunoassay, EIA luminol fluorescence polarization immuno-assay, FPIA micellar enhanced spectrofluoro-metric method stretching vibration bending vibration deformationvibration symmetrical stretching vibration asymmetrical stretching vibration scissoring vibration rocking vibration wagging vibration twisting vibration breathing vibration vibrational relaxation vibrational coupling basic frequency absorption band multiple frequency absorption band Fermi resonance Nernst glower nichrome coils globars double beam optical--null system ratio recording electric-null system diffuse-reflectance attenuated total reflectance, ATR multiple internal reflection, MIR beam condenser polystyrene film wave number [halide] disk method, wafer method, pellet method nujol mull method film method light pipe thermocouple detector Golay detector deuterated triglycine sulfate detector, DTGS detector mercury cadmium telluride detector, MCT detector finger print region spectral search spec-finder spectralsubtraction method 红外光吸收参比图谱光度滴定法酸性染料比色法氨基硫脲比色法钯离子比色法四氮唑比色法科伯试剂检测限系统适用性峰不对称度峰重叠分层胶束色谱法填料极性正相反相疏溶剂作用亲硅羟基作用硅胶氧化铝化学键合相十八烷基硅烷键合硅胶氨基硅烷键合硅胶离子交换纤维素微晶纤维素聚苯乙烯凝胶琼脂糖凝胶聚丙烯酰胺凝胶葡聚糖凝胶己烷磺酸钠十二烷基硫酸钠微量注射器柱超载积分仪色谱数据处理机色谱工作站高效薄层色谱法过压薄层色谱法带状色谱连续展开短床连续展开斑点再浓集infra-red reference spectra photometric titration acid-dye colorimetry thiosemicarbazide colorimetry palladium ion colorimetry tetrazoline colorimetry Kober reagent detectability system suitability peak asymmetry peak overlapping demixing micellar chromatography packing materialpolarity normal phase reversed phase solvophobic interaction silanophilic interaction silica gel alumina chemically bonded phase octadecylsilane chemically bonded silica amino chemically bonded silica ion-exchange cellulose microcrystalline cellulose polystyrene gel agarose gel polyacrylamide gel polydextran gel sodium hexanesulfonate sodium dodecylsulfate, SDS microsyringe column overload integrator chromatographic data processor chromatographic work station high performance thin--layer chromatography, HPTLC overpressure thin—layer chrom-atography strip chromatography continuous development short-bed continuous development spot reconcentration 原位定量法床外因素背材预制板硅胶H 硅胶G 荧光剂薄层板贮箱点样器微升毛细管模板热微量转移法试剂喷雾器紫外线灯线性扫描锯齿扫描干装柱法湿装柱法固定相涂布内标物科瓦茨保留指数官能团保留指数亚甲基单位有效碳数相特征常数罗尔施奈德相常数麦克雷诺兹相常数布朗三角图形法气体净化器戈雷柱熔融二氧化硅空心柱分流无分流尾吹气进样隔膜胶垫闪蒸进样法柱上进样器鸭嘴阀针导顶空浓缩进样器冷柱头进样器卡套聚氨酯卡套石墨卡套quantitation in situ extra--bed factor backing material precoated plate silica gel H silica gel G fluorescent agent plate storage rack sample applicator microcap template thermo micro-application sepa-ration, TAS reagent sprayer ultraviolet lamp linear scanning zigzag scanning dry packing method wet packing method stationary phase coating internal standard substance Kovats retention index functional retention index methylene unit, MU effective carbon number phase specific constantRohrschneider phase constant McReynolds phase constant Brown triangle method gas purifier Golay column fused-silica open tubular column,FSOT split splitless make-up gas injecting septum flash evaporating injection on-column injector duckbill valve needle guide head-space concentrating injector cold on-column injector ferrule polyurethane ferrule graphite ferrule 皂土一34 蒙脱土混合固定相高分子多孔小球热能分析器气[相色谱]-[傅里叶变换]红[外光谱]联用仪高分辨气相色谱法联接头流速程序高效液相色谱法再循环色谱法脱气在线脱气设备低压梯度泵往复隔膜泵齿轮泵注射泵单向阀进样阀柱切换质量分析检测器程序波长检测器光电二极管阵列检测器多维检测等高线色谱图三维色谱图二次化学平衡编辑对话衰减时间常数响应时间时间谱带展宽空间谱带展宽保留隘口重叠峰基线分离峰峰谷驼峰试样在线预处理手性固定相手性拆分离子抑制液[相色谱]-质[谱]联用仪bentone-34 montmorillonite clay mixed stationary phase porous polymer beads thermo-energy analyser, TEA gas chromatograph/ Fourier trans-form infrared spectrophotometer, GC/FTIR high resolution gas chromato-graphy, HRGC union flow programming high perfor-mance liquid chromatography recycle chromatography degassing on-line degasser low pressure gradient pump reciprocating diaphragm pump gear pump syringe pump check valve injection valve column switching mass analyser detector programmable wavelength detector photodiode array detector, DAD multidimensional detection contour chromatogram three-dimensional chromatogram second chemical equilibrium editing dialog attenuation time constant response time band broading intime band broading in space retention gap fused peaks, overlapped peaks baseline resolved peak peak valley rider peak sample on-line pretreatment chiral stationary phase, CSP chiral separation ion suppress liquid chromatograph/mass spectrometer, LC/MS 传送带接口直接液体进样热喷雾接口电喷雾接口液体离子蒸发单分散气雾形成接口柱前衍生化柱后衍生化衍生化反应小管重氮甲烷迁移时间平板电泳毛细管电泳胶束动电毛细管色谱法内电渗电迁移进样抽空进样静力进样柱上检测器示差脉冲极谱法电子电位计参比电极饱和甘汞电极氯化银电极指示电极银电极盐桥电解电流质谱图道尔顿相对强度极限前体全氟煤油离子一分子复合物双价离子麦氏重排拉曼效应棒图扇形磁场质谱仪名义质量准确质量磁阻moving belt interface direct liquid introduction, DLI thermospray interface, TSPinterfaceelectrospray interface, ESPinterface liquid ion evaporation, LIE monodisperse aerosol generation interface, MAGIC pre-column derivatization post-column derivatization derivatizing reaction vial diazomethane migration time disk electrophoresis capillary electrophoresis, CE micellar electrokinetic capillary chromatography, MECC,MEKC electroendosmosis electromigration injection vacuum injection hydrostatic injection on-column detector differential pulse polarography electronic potentiometer reference electrode saturated calomel electrode silver chloride electrode indicating electrode silver electrode salt bridge Faradaic current mass spectrum dalton relative intensity ultimate precursor polyfluoro kerosene, PFK ion-molecule complex doubly charged ion McLafferty rearrangement Raman effect bar graph magnetic sector mass spectrometernominal mass exact mass reluctance 叠片磁铁十倍程象电流分立二发射极软离子化方法灯丝准分子离子大气压离子化静电喷雾二次离子质谱法溅射现象近距碰撞等离子体解吸质谱法激光解吸质谱法粒子诱导质谱法直接进样杆加热贮槽进样器粒子束重建总离子流各向异性各向异性屏蔽软脉冲五重峰六重峰七重峰偕偶邻偶偏共振去偶选择去偶反门控去偶反磁性屏蔽J调制法谱编辑不灵敏核极化转移增益法无畸变极化转移增益法双量子转移实验laminated magnets decade image current discrete dynode soft ionization filament quasi-molecular ion atmospheric pressure ionization, API electrostatic spray secondary ion mass spectrometry,SIMS sputtering phenomenon near mass collision plasma desorption mass spectrometry, PDMS laser desorption mass spectrometry, LDMS particle induced================精选公文范文，管理类，工作总结类，工作计划类文档，欢迎阅读下载============== mass spectrometry direct inlet probe, DIP heatable reservoir inlet particle beam reconstruction total ion current,reconstruction TIC anisotropic anisotropic shielding soft pulse quintet sextet septet geminal coupling vicinal coupling off resonance decoupling selective decoupling inverted gated decoupling diamagnetic shielding J-modulation method spectral editing insensitive nucleus enhancementby polarization transfer, INEPT distortionless enhancement bypolarization transfer, DEPT double quantum transferexperiment--------------------精选公文范文，管理类，工作总结类，工作计划类文档，感谢阅读下载--------------------- ~ 21 ~。
专业英语词汇-----分析化学第一章绪论分析化学：analytical chemistry定性分析：qualitative analysis定量分析：quantitative analysis物理分析：physical analysis物理化学分析：physico-chemical analysis仪器分析法：instrumental analysis流动注射分析法：flow injection analysis；FIA顺序注射分析法：sequentical injection analysis;SIA化学计量学：chemometrics第二章误差的分析数据处理绝对误差：absolute error相对误差：relative error系统误差：systematic error可定误差：determinate error随机误差：accidental error不可定误差：indeterminate error准确度：accuracy精确度：precision偏差：debiation，d平均偏差：average debiation相对平均偏差：relative average debiation标准偏差（标准差）：standerd deviation;S相对平均偏差：relatibe standard deviation;RSD变异系数：coefficient of variation误差传递：propagation of error有效数字：significant figure置信水平：confidence level显著性水平：level of significance合并标准偏差（组合标准差）：pooled standard debiation 舍弃商：rejection quotient ;Q化学定量分析第三章滴定分析概论滴定分析法：titrametric analysis滴定：titration容量分析法:volumetric analysis化学计量点：stoichiometric point等当点：equivalent point电荷平衡：charge balance电荷平衡式：charge balance equation质量平衡：mass balance物料平衡：material balance质量平衡式：mass balance equation第四章酸碱滴定法酸碱滴定法：acid-base titrations 质子自递反应：auto protolysis reaction质子自递常数：autoprotolysis constant质子条件式:proton balance equation酸碱指示剂：acid-base indicator指示剂常数：indicator constant变色范围：colour change interval混合指示剂：mixed indicator双指示剂滴定法：double indicator titration第五章非水滴定法非水滴定法：nonaqueous titrations质子溶剂：protonic solvent酸性溶剂：acid solvent碱性溶剂：basic solvent两性溶剂:amphototeric solvent无质子溶剂：aprotic solvent均化效应：differentiatin g effect区分性溶剂：differentiating solvent离子化：ionization离解：dissociation结晶紫：crystal violet萘酚苯甲醇: α-naphthalphenol benzyl alcohol奎哪啶红：quinadinered百里酚蓝：thymol blue偶氮紫：azo violet溴酚蓝：bromophenol blue第六章配位滴定法配位滴定法：compleximetry乙二胺四乙酸：ethylenediamine tetraacetic acid,EDTA 螯合物：chelate compound金属指示剂：metal lochrome indcator第七章氧化还原滴定法氧化还原滴定法：oxidation-reduction titration碘量法：iodimetry溴量法：bromimetry ]溴量法：bromine method铈量法：cerimetry高锰酸钾法：potassium permanganate method条件电位：conditional potential溴酸钾法：potassium bromate method硫酸铈法：cerium sulphate method偏高碘酸：metaperiodic acid高碘酸盐：periodate亚硝酸钠法：sodium nitrite method重氮化反应：diazotization reaction重氮化滴定法：diazotization titration亚硝基化反应：nitrozation reaction亚硝基化滴定法：nitrozation titration外指示剂：external indicator外指示剂：outside indicator重铬酸钾法：potassium dichromate method 第八章沉淀滴定法沉淀滴定法：precipitation titration容量滴定法：volumetric precipitation method 银量法：argentometric method第九章重量分析法重量分析法：gravimetric analysis挥发法：volatilization method引湿水（湿存水）：water of hydroscopicity 包埋(藏)水：occluded water吸入水：water of imbibition结晶水：water of crystallization组成水：water of composition液-液萃取法：liquid-liquid extration溶剂萃取法：solvent extration反萃取：counter extraction分配系数：partition coefficient分配比：distribution ratio离子对（离子缔合物）：ion pair沉淀形式：precipitation forms称量形式：weighing forms仪器分析概述物理分析：physical analysis物理化学分析：physicochemical analysis仪器分析：instrumental analysis第十章电位法及永停滴定法电化学分析：electrochemical analysis电解法：electrolytic analysis method电重量法：electrogravimetry库仑法：coulo metry库仑滴定法：coulo metric titration电导法：conductometry电导分析法：conductometric analysis电导滴定法：conductometric titration电位法：potentiometry直接电位法：dirext potentiometry电位滴定法：potentiometric titration伏安法：voltammetry极谱法：polarography溶出法：stripping method电流滴定法：amperometric titration化学双电层：chemical double layer相界电位：phase boundary potential 金属电极电位：electrode potential化学电池：chemical cell液接界面：liquid junction boundary原电池：galvanic cell电解池：electrolytic cell负极：cathode正极：anode电池电动势：eletromotive force指示电极：indicator electrode参比电极：reference electroade标准氢电极：standard hydrogen electrode一级参比电极：primary reference electrode饱和甘汞电极：saturated calomel electrode银－氯化银电极：silver silver-chloride electrode液接界面：liquid junction boundary不对称电位：asymmetry potential表观PH值：apparent PH复合PH电极：combination PH electrode离子选择电极：ion selective electrode敏感器：sensor晶体电极:crystalline electrodes均相膜电极：homogeneous membrance electrodes非均相膜电极：heterogeneous membrance electrodes非晶体电极：non- crystalline electrodes刚性基质电极：rigid matrix electrode流流体载动电极：electrode with a mobile carrier气敏电极：gas sensing electrodes酶电极：enzyme electrodes金属氧化物半导体场效应晶体管：MOSFET离子选择场效应管：ISFET总离子强度调节缓冲剂：total ion strength adjustment buffer,TISAB永停滴定法：dead-stop titration双电流滴定法（双安培滴定法）：double amperometric titration 第十一章光谱分析法概论普朗克常数：Plank constant电磁波谱：electromagnetic spectrum光谱：spectrum光谱分析法：spectroscopic analysis原子发射光谱法：atomic emission spectroscopy质量谱：mass spectrum质谱法：mass spectroscopy,MS第十二章紫外－可见分光光度法紫外－可见分光光度法：ultraviolet and visible spectrophotometry;UV-vis肩峰：shoulder peak末端吸收：end absorbtion生色团：chromophore助色团：auxochrome红移：red shift长移：bathochromic shift短移：hypsochromic shift蓝（紫）移：blue shift增色效应（浓色效应）：hyperchromic effect减色效应（淡色效应）：hypochromic effect强带：strong band弱带：weak band吸收带：absorption band透光率：transmitance,T吸光度：absorbance谱带宽度：band width杂散光：stray light噪声：noise暗噪声：dark noise散粒噪声：signal shot noise闪耀光栅：blazed grating全息光栅：holographic grating光二极管阵列检测器：photodiode array detector 偏最小二乘法：partial least squares method ,PLS褶合光谱法：convolution spectrometry褶合变换：convolution transform,CT离散小波变换：wavelet transform,WT多尺度细化分析：multiscale analysis供电子取代基：electron donating group吸电子取代基：electron with-drawing group第十三章荧光分析法荧光：fluorescence荧光分析法：fluorometryX-射线荧光分析法：X-ray fluorometry原子荧光分析法：atomic fluorometry分子荧光分析法：molecular fluorometry振动弛豫：vibrational relaxation内转换：internal conversion外转换：external conversion体系间跨越：intersystem crossing激发光谱：excitation spectrum荧光光谱：fluorescence spectrum斯托克斯位移：Stokes shift荧光寿命：fluorescence life time荧光效率：fluorescence efficiency荧光量子产率：fluorescence quantum yield荧光熄灭法：fluorescence quenching method散射光：scattering light瑞利光：R a yleith scattering light拉曼光：Raman scattering lightAbbe refractometer 阿贝折射仪absorbance 吸收度absorbance ratio 吸收度比值absorption 吸收absorption curve 吸收曲线absorption spectrum 吸收光谱absorptivity 吸收系数accuracy 准确度acid-dye colorimetry 酸性染料比色法acidimetry 酸量法acid-insoluble ash 酸不溶性灰分acidity 酸度activity 活度第十四章色谱法additive 添加剂additivity 加和性adjusted retention time 调整保留时间adsorbent 吸附剂adsorption 吸附affinity chromatography 亲和色谱法aliquot （一）份alkalinity 碱度alumina 氧化铝ambient temperature 室温ammonium thiocyanate 硫氰酸铵analytical quality control（AQC）分析质量控制anhydrous substance 干燥品anionic surfactant titration 阴离子表面活性剂滴定法antibiotics-microbial test 抗生素微生物检定法antioxidant 抗氧剂appendix 附录application of sample 点样area normalization method 面积归一化法argentimetry 银量法arsenic 砷arsenic stain 砷斑ascending development 上行展开ash-free filter paper 无灰滤纸（定量滤纸）assay 含量测定assay tolerance 含量限度atmospheric pressure ionization(API) 大气压离子化attenuation 衰减back extraction 反萃取back titration 回滴法bacterial endotoxins test 细菌内毒素检查法band absorption 谱带吸收baseline correction 基线校正baseline drift 基线漂移batch, lot 批batch(lot) number 批号Benttendorff method 白田道夫（检砷）法between day (day to day, inter-day) precision 日间精密度between run (inter-run) precision 批间精密度biotransformation 生物转化bioavailability test 生物利用度试验bioequivalence test 生物等效试验biopharmaceutical analysis 体内药物分析，生物药物分析blank test 空白试验boiling range 沸程British Pharmacopeia (BP) 英国药典bromate titration 溴酸盐滴定法bromimetry 溴量法bromocresol green 溴甲酚绿bromocresol purple 溴甲酚紫bromophenol blue 溴酚蓝bromothymol blue 溴麝香草酚蓝bulk drug, pharmaceutical product 原料药buret 滴定管by-product 副产物calibration curve 校正曲线calomel electrode 甘汞电极calorimetry 量热分析capacity factor 容量因子capillary zone electrophoresis (CZE) 毛细管区带电泳capillary gas chromatography 毛细管气相色谱法carrier gas 载气cation-exchange resin 阳离子交换树脂ceri(o)metry 铈量法characteristics, description 性状check valve 单向阀chemical shift 化学位移chelate compound 鳌合物chemically bonded phase 化学键合相chemical equivalent 化学当量Chinese Pharmacopeia (ChP) 中国药典Chinese material medicine 中成药Chinese materia medica 中药学Chinese materia medica preparation 中药制剂Chinese Pharmaceutical Association (CPA) 中国药学会chiral 手性的chiral stationary phase (CSP) 手性固定相chiral separation 手性分离chirality 手性chiral carbon atom 手性碳原子chromatogram 色谱图chromatography 色谱法chromatographic column 色谱柱chromatographic condition 色谱条件chromatographic data processor 色谱数据处理机chromatographic work station 色谱工作站clarity 澄清度clathrate, inclusion compound 包合物clearance 清除率clinical pharmacy 临床药学coefficient of distribution 分配系数coefficient of variation 变异系数color change interval （指示剂）变色范围color reaction 显色反应colorimetric analysis 比色分析colorimetry 比色法column capacity 柱容量column dead volume 柱死体积column efficiency 柱效column interstitial volume 柱隙体积column outlet pressure 柱出口压column temperature 柱温column pressure 柱压column volume 柱体积column overload 柱超载column switching 柱切换committee of drug evaluation 药品审评委员会comparative test 比较试验completeness of solution 溶液的澄清度compound medicines 复方药computer-aided pharmaceutical analysis 计算机辅助药物分析concentration-time curve 浓度－时间曲线confidence interval 置信区间confidence level 置信水平confidence limit 置信限congealing point 凝点congo red 刚果红（指示剂）content uniformity 装量差异controlled trial 对照试验correlation coefficient 相关系数contrast test 对照试验counter ion 反离子（平衡离子）cresol red 甲酚红（指示剂）crucible 坩埚crude drug 生药crystal violet 结晶紫（指示剂）cuvette, cell 比色池cyanide 氰化物cyclodextrin 环糊精cylinder, graduate cylinder, measuring cylinder 量筒cylinder-plate assay 管碟测定法daughter ion （质谱）子离子dead space 死体积dead-stop titration 永停滴定法dead time 死时间decolorization 脱色decomposition point 分解点deflection 偏差deflection point 拐点degassing 脱气deionized water 去离子水deliquescence 潮解depressor substances test 降压物质检查法derivative spectrophotometry 导数分光光度法derivatization 衍生化descending development 下行展开desiccant 干燥剂detection 检查detector 检测器developer, developing reagent 展开剂developing chamber 展开室deviation 偏差dextrose 右旋糖，葡萄糖diastereoisomer 非对映异构体diazotization 重氮化2,6-dichlorindophenol titration 2,6-二氯靛酚滴定法differential scanning calorimetry (DSC) 差示扫描热量法differential spectrophotometry 差示分光光度法differential thermal analysis (DTA) 差示热分析differentiating solvent 区分性溶剂diffusion 扩散digestion 消化diphastic titration 双相滴定disintegration test 崩解试验dispersion 分散度dissolubility 溶解度dissolution test 溶出度检查distilling range 馏程distribution chromatography 分配色谱distribution coefficient 分配系数dose 剂量drug control institutions 药检机构drug quality control 药品质量控制drug release 药物释放度drug standard 药品标准drying to constant weight 干燥至恒重dual wavelength spectrophotometry 双波长分光光度法duplicate test 重复试验effective constituent 有效成分effective plate number 有效板数efficiency of column 柱效electron capture detector 电子捕获检测器electron impact ionization 电子轰击离子化electrophoresis 电泳electrospray interface 电喷雾接口electromigration injection 电迁移进样elimination 消除eluate 洗脱液elution 洗脱emission spectrochemical analysis 发射光谱分析enantiomer 对映体end absorption 末端吸收end point correction 终点校正endogenous substances 内源性物质enzyme immunoassay(EIA) 酶免疫分析enzyme drug 酶类药物enzyme induction 酶诱导enzyme inhibition 酶抑制eosin sodium 曙红钠（指示剂）epimer 差向异构体equilibrium constant 平衡常数equivalence point 等当点error in volumetric analysis 容量分析误差excitation spectrum 激发光谱exclusion chromatography 排阻色谱法expiration date 失效期external standard method 外标法extract 提取物extraction gravimetry 提取重量法extraction titration 提取容量法extrapolated method 外插法，外推法factor 系数，因数，因子feature 特征Fehling’s reaction 费林反应field disorption ionization 场解吸离子化field ionization 场致离子化filter 过滤，滤光片filtration 过滤fineness of the particles 颗粒细度flame ionization detector(FID) 火焰离子化检测器flame emission spectrum 火焰发射光谱flask 烧瓶flow cell 流通池flow injection analysis 流动注射分析flow rate 流速fluorescamine 荧胺fluorescence immunoassay(FIA) 荧光免疫分析fluorescence polarization immunoassay(FPIA) 荧光偏振免疫分析fluorescent agent 荧光剂fluorescence spectrophotometry 荧光分光光度法fluorescence detection 荧光检测器fluorimetyr 荧光分析法foreign odor 异臭foreign pigment 有色杂质formulary 处方集fraction 馏分freezing test 结冻试验funnel 漏斗fused peaks, overlapped peaks 重叠峰fused silica 熔融石英gas chromatography(GC) 气相色谱法gas-liquid chromatography(GLC) 气液色谱法gas purifier 气体净化器gel filtration chromatography 凝胶过滤色谱法gel permeation chromatography 凝胶渗透色谱法general identification test 一般鉴别试验general notices （药典）凡例general requirements （药典）通则good clinical practices(GCP) 药品临床管理规范good laboratory practices(GLP) 药品实验室管理规范good manufacturing practices(GMP) 药品生产质量管理规范good supply practices(GSP) 药品供应管理规范gradient elution 梯度洗脱grating 光栅gravimetric method 重量法Gutzeit test 古蔡（检砷）法half peak width 半峰宽[halide] disk method, wafer method, pellet method 压片法head-space concentrating injector 顶空浓缩进样器heavy metal 重金属heat conductivity 热导率height equivalent to a theoretical plate 理论塔板高度height of an effective plate 有效塔板高度high-performance liquid chromatography (HPLC) 高效液相色谱法high-performance thin-layer chromatography (HPTLC) 高效薄层色谱法hydrate 水合物hydrolysis 水解hydrophilicity 亲水性hydrophobicity 疏水性hydroscopic 吸湿的hydroxyl value 羟值hyperchromic effect 浓色效应hypochromic effect 淡色效应identification 鉴别ignition to constant weight 灼烧至恒重immobile phase 固定相immunoassay 免疫测定impurity 杂质inactivation 失活index 索引indicator 指示剂indicator electrode 指示电极inhibitor 抑制剂injecting septum 进样隔膜胶垫injection valve 进样阀instrumental analysis 仪器分析insulin assay 胰岛素生物检定法integrator 积分仪intercept 截距interface 接口interference filter 干涉滤光片intermediate 中间体internal standard substance 内标物质international unit(IU) 国际单位in vitro 体外in vivo 体内iodide 碘化物iodoform reaction 碘仿反应iodometry 碘量法ion-exchange cellulose 离子交换纤维素ion pair chromatography 离子对色谱ion suppression 离子抑制ionic strength 离子强度ion-pairing agent 离子对试剂ionization 电离，离子化ionization region 离子化区irreversible indicator 不可逆指示剂irreversible potential 不可逆电位isoabsorptive point 等吸收点isocratic elution 等溶剂组成洗脱isoelectric point 等电点isoosmotic solution 等渗溶液isotherm 等温线Karl Fischer titration 卡尔·费歇尔滴定kinematic viscosity 运动黏度Kjeldahl method for nitrogen 凯氏定氮法Kober reagent 科伯试剂Kovats retention index 科瓦茨保留指数labelled amount 标示量leading peak 前延峰least square method 最小二乘法leveling effect 均化效应licensed pharmacist 执业药师limit control 限量控制limit of detection(LOD) 检测限limit of quantitation(LOQ) 定量限limit test （杂质）限度（或限量）试验limutus amebocyte lysate(LAL) 鲎试验linearity and range 线性及范围linearity scanning 线性扫描liquid chromatograph/mass spectrometer (LC/MS) 液质联用仪litmus paper 石蕊试纸loss on drying 干燥失重low pressure gradient pump 低压梯度泵luminescence 发光lyophilization 冷冻干燥main constituent 主成分make-up gas 尾吹气maltol reaction 麦牙酚试验Marquis test 马奎斯试验mass analyzer detector 质量分析检测器mass spectrometric analysis 质谱分析mass spectrum 质谱图mean deviation 平均偏差measuring flask, volumetric flask 量瓶measuring pipet(te) 刻度吸量管medicinal herb 草药melting point 熔点melting range 熔距metabolite 代谢物metastable ion 亚稳离子methyl orange 甲基橙methyl red 甲基红micellar chromatography 胶束色谱法micellar electrokinetic capillary chromatography(MECC, MEKC) 胶束电动毛细管色谱法micelle 胶束microanalysis 微量分析microcrystal 微晶microdialysis 微透析micropacked column 微型填充柱microsome 微粒体microsyringe 微量注射器migration time 迁移时间millipore filtration 微孔过滤minimum fill 最低装量mobile phase 流动相modifier 改性剂，调节剂molecular formula 分子式monitor 检测，监测monochromator 单色器monographs 正文mortar 研钵moving belt interface 传送带接口multidimensional detection 多维检测multiple linear regression 多元线性回归multivariate calibration 多元校正natural product 天然产物Nessler glasses(tube) 奈斯勒比色管Nessler’s r eagent 碱性碘化汞钾试液neutralization 中和nitrogen content 总氮量nonaqueous acid-base titration 非水酸碱滴定nonprescription drug, over the counter drugs (OTC drugs) 非处方药nonproprietary name, generic name 非专有名nonspecific impurity 一般杂质non-volatile matter 不挥发物normal phase 正相normalization 归一化法notice 凡例nujol mull method 石蜡糊法octadecylsilane chemically bonded silica 十八烷基硅烷键合硅胶octylsilane 辛（烷）基硅烷odorless 无臭official name 法定名official specifications 法定标准official test 法定试验on-column detector 柱上检测器on-column injection 柱头进样on-line degasser 在线脱气设备on the dried basis 按干燥品计opalescence 乳浊open tubular column 开管色谱柱optical activity 光学活性optical isomerism 旋光异构optical purity 光学纯度optimization function 优化函数organic volatile impurities 有机挥发性杂质orthogonal function spectrophotometry 正交函数分光光度法orthogonal test 正交试验orthophenanthroline 邻二氮菲outlier 可疑数据，逸出值overtones 倍频峰，泛频峰oxidation-reduction titration 氧化还原滴定oxygen flask combustion 氧瓶燃烧packed column 填充柱packing material 色谱柱填料palladium ion colorimetry 钯离子比色法parallel analysis 平行分析parent ion 母离子particulate matter 不溶性微粒partition coefficient 分配系数parts per million (ppm) 百万分之几pattern recognition 模式识别peak symmetry 峰不对称性peak valley 峰谷peak width at half height 半峰宽percent transmittance 透光百分率pH indicator absorbance ratio method? pH指示剂吸光度比值法pharmaceutical analysis 药物分析pharmacopeia 药典pharmacy 药学phenolphthalein 酚酞photodiode array detector(DAD) 光电二极管阵列检测器photometer 光度计pipeclay triangle 泥三角pipet(te) 吸移管，精密量取planar chromatography 平板色谱法plate storage rack 薄层板贮箱polarimeter 旋光计polarimetry 旋光测定法polarity 极性polyacrylamide gel 聚丙酰胺凝胶polydextran gel 葡聚糖凝胶polystyrene gel 聚苯乙烯凝胶polystyrene film 聚苯乙烯薄膜porous polymer beads 高分子多孔小球post-column derivatization 柱后衍生化potentiometer 电位计potentiometric titration 电位滴定法precipitation form 沉淀形式precision 精密度pre-column derivatization 柱前衍生化preparation 制剂prescription drug 处方药pretreatment 预处理primary standard 基准物质principal component analysis 主成分分析programmed temperature gas chromatography 程序升温气相色谱法prototype drug 原型药物provisions for new drug approval 新药审批办法purification 纯化purity 纯度pyrogen 热原pycnometric method 比重瓶法quality control(QC) 质量控制quality evaluation 质量评价quality standard 质量标准quantitative determination 定量测定quantitative analysis 定量分析quasi-molecular ion 准分子离子racemization 消旋化radioimmunoassay 放射免疫分析法random sampling 随机抽样rational use of drug 合理用药readily carbonizable substance 易炭化物reagent sprayer 试剂喷雾器recovery 回收率reference electrode 参比电极refractive index 折光指数related substance 有关物质relative density 相对密度relative intensity 相对强度repeatability 重复性replicate determination 平行测定reproducibility 重现性residual basic hydrolysis method 剩余碱水解法residual liquid junction potential 残余液接电位residual titration 剩余滴定residue on ignition 炽灼残渣resolution 分辨率，分离度response time 响应时间retention 保留reversed phase chromatography 反相色谱法reverse osmosis 反渗透rider peak 驼峰rinse 清洗，淋洗robustness 可靠性，稳定性routine analysis 常规分析round 修约（数字）ruggedness 耐用性safety 安全性Sakaguchi test 坂口试验salt bridge 盐桥salting out 盐析sample applicator 点样器sample application 点样sample on-line pretreatment 试样在线预处理sampling 取样saponification value 皂化值saturated calomel electrode(SCE) 饱和甘汞电极selectivity 选择性separatory funnel 分液漏斗shoulder peak 肩峰signal to noise ratio 信噪比significant difference 显著性差异significant figure 有效数字significant level 显著性水平significant testing 显著性检验silanophilic interaction 亲硅羟基作用silica gel 硅胶silver chloride electrode 氯化银电极similarity 相似性simultaneous equations method 解线性方程组法size exclusion chromatography(SEC) 空间排阻色谱法sodium dodecylsulfate, SDS 十二烷基硫酸钠sodium hexanesulfonate 己烷磺酸钠sodium taurocholate 牛璜胆酸钠sodium tetraphenylborate 四苯硼钠sodium thiosulphate 硫代硫酸钠solid-phase extraction 固相萃取solubility 溶解度solvent front 溶剂前沿solvophobic interaction 疏溶剂作用specific absorbance 吸收系数specification 规格specificity 专属性specific rotation 比旋度specific weight 比重spiked 加入标准的split injection 分流进样splitless injection 无分流进样spray reagent （平板色谱中的）显色剂spreader 铺板机stability 稳定性standard color solution 标准比色液standard deviation 标准差standardization 标定standard operating procedure(SOP) 标准操作规程standard substance 标准品stationary phase coating 固定相涂布starch indicator 淀粉指示剂statistical error 统计误差sterility test 无菌试验stirring bar 搅拌棒stock solution 储备液stoichiometric point 化学计量点storage 贮藏stray light 杂散光substituent 取代基substrate 底物sulfate 硫酸盐sulphated ash 硫酸盐灰分supercritical fluid chromatography(SFC) 超临界流体色谱法support 载体（担体）suspension 悬浊液swelling degree 膨胀度symmetry factor 对称因子syringe pump 注射泵systematic error 系统误差system model 系统模型system suitability 系统适用性tablet 片剂tailing factor 拖尾因子tailing peak 拖尾峰tailing-suppressing reagent 扫尾剂test of hypothesis 假设检验test solution(TS) 试液tetrazolium colorimetry 四氮唑比色法therapeutic drug monitoring(TDM) 治疗药物监测thermal analysis 热分析法thermal conductivity detector 热导检测器thermocouple detector 热电偶检测器thermogravimetric analysis(TGA) 热重分析法thermospray interface 热喷雾接口The United States Pharmacopoeia(USP) 美国药典The Pharmacopoeia of Japan(JP) 日本药局方thin layer chromatography(TLC) 薄层色谱法thiochrome reaction 硫色素反应three-dimensional chromatogram 三维色谱图thymol 百里酚（麝香草酚）（指示剂）thymolphthalein 百里酚酞（麝香草酚酞）（指示剂）thymolsulfonphthalein ( thymol blue) 百里酚蓝（麝香草酚蓝）（指示剂）titer, titre 滴定度time-resolved fluoroimmunoassay 时间分辨荧光免疫法titrant 滴定剂titration error 滴定误差titrimetric analysis 滴定分析法tolerance 容许限toluene distillation method 甲苯蒸馏法toluidine blue 甲苯胺蓝（指示剂）total ash 总灰分total quality control(TQC) 全面质量控制traditional drugs 传统药traditional Chinese medicine 中药transfer pipet 移液管turbidance 混浊turbidimetric assay 浊度测定法turbidimetry 比浊法turbidity 浊度ultracentrifugation 超速离心ultrasonic mixer 超生混合器ultraviolet irradiation 紫外线照射undue toxicity 异常毒性uniform design 均匀设计uniformity of dosage units 含量均匀度uniformity of volume 装量均匀性（装量差异）uniformity of weight 重量均匀性（片重差异）validity 可靠性variance 方差versus …对…，…与…的关系曲线viscosity 粘度volatile oil determination apparatus 挥发油测定器volatilization 挥发法volumetric analysis 容量分析volumetric solution(VS) 滴定液vortex mixer 涡旋混合器watch glass 表面皿wave length 波长wave number 波数weighing bottle 称量瓶weighing form 称量形式weights 砝码well-closed container 密闭容器xylene cyanol blue FF 二甲苯蓝FF（指示剂）xylenol orange 二甲酚橙（指示剂）zigzag scanning 锯齿扫描zone electrophoresis 区带电泳zwitterions 两性离子zymolysis 酶解作用簡體書目錄Chapter 1 Introduction 緒論1.1 The nature of analytical chemistry 分析化學的性質1.2 The role of analytical chemistry 分析化學的作用1.3 The classification of analytical chemistry分析化學的分類1.4 The total analytical process分析全過程Terms to understand重點內容概述Chapter 2 Errors and Data Treatment in Quantitative Analysis 定量分析中的誤差及數據處理2.1 Fundamental terms of errors誤差的基本術語2.2 Types of errors in experimental data實驗數據中的誤差類型2.2.1 Systematic errors 系統誤差2.2.2 Random errors偶然誤差2.3 Evaluation of analytical data分析數據的評價2.3.1 Tests of significance顯著性檢驗2.3.2 Rejecting data可疑值取捨2.4 Significant figures有效數字ProblemsTerms to understand重點內容概述Chapter 3 Titrimetric Analysis滴定分析法3.1 General principles基本原理3.1.1 Relevant terms of titrimetric analysis滴定分析相關術語3.1.2 The preparation of standard solution and the expression of concentration 標準溶液的配製與濃度表示方法3.1.3 The types of titrimetric reactions滴定反應類型3.2 Acid-base titration酸鹼滴定3.2.1 Acid-base equilibria 酸鹼平衡3.2.2 Titration curves滴定曲線3.2.3 Acid-base indicators酸鹼指示劑3.2.4 Applications of acid-base titration酸鹼滴定的應用3.3 Complexometric titration配位滴定3.3.1 Metal-chelate complexes金屬螯合物3.3.2 EDTA 乙二胺四乙酸3.3.3 EDTA titration curves EDTA滴定曲線3.3.4 Metal Ion indicators金屬離子指示劑3.3.5 Applications of EDTA titration techniques EDTA滴定方法的應用3.4 Oxidation-reduction titration氧化還原滴定3.4.1 Redox reactions氧化還原反應3.4.2 Rate of redox reactions氧化還原反應的速率3.4.3 Titration curves滴定曲線3.4.4 Redox indicators氧化還原指示劑3.4.5 Applications of redox titrations氧化還原滴定的應用3.5 Precipitation titration沉澱滴定3.5.1 Precipitation reactions沉澱滴定反應3.5.2 Titration curves滴定曲線3.5.3 End-point detection終點檢測ProblemsTerms to understand重點內容概述Chapter 4 Potentiometry 電位分析法4.1 Introduction簡介4.1.1 Classes and characteristics分類及性質4.1.2 Definition定義4.2 Types of potentiometric electrodes電極種類4.2.1 Reference electrodes 參比電極4.2.2 Indicator electrodes指示電極4.2.3 Electrode response and selectivity電極響應及選擇性4.3 Potentiometric methods and application電位法及應用4.3.1 Direct potentiometric measurement 直接電位法4.3.2 Potentiometric titrations電位滴定4.3.3 Applications of potentiometry 電位法應用ProblemsTerlns to understand重點內容概述Chapter 5 Chromatography色譜法5.1 An introduction to chromatographic methods色譜法概述5.2 Fundamental theory of gas chromatography氣相色譜基本原理5.2.1 Plate theory塔板理論5.2.2 Kinetic theory(rate theory) 速率理論5.2.3 The resolution Rs as a measure of peak separation 分離度5.3 Gas chromatography 氣相色譜5.3.1 Components of a gas chromatograph 氣相色譜儀的組成5.3.2 Stationary phases for gas-liquid chromatography 氣液色譜固定相5.3.3 Applications of gas-liquid chromatography 氣液色譜的應用5.3.4 Adsorption chromatography 吸附色譜5.4 High performance liquid chromatography 高效液相色譜5.4.1 Instrumentation 儀器組成5.4.2 High-performance partition chromatography 高效分配色譜5.5 Miscellaneous separation methods 其他分離方法5.5.1 High-performance ion-exchange chromatography 高效離子交換色譜5.5.2 Capillary electrophoresis 毛細管電泳5.5.3 Planar chromatography 平板色譜ProblemsTerms to understand重點內容概述Chapter 6 Atomic Absorption Spectrometry原子吸收光譜分析法6.1 Introduction 概述6.2 Principles 原理6.2.1 The process of AAS，resonance line and absorption line 原子吸收光譜法的過程，共振線及吸收線6.2.2 The number of ground atom and the temperature of flame 基態原子數與光焰溫度6.2.3 Quantitative analysis of AAS原子吸收光譜定量分析6.3 Instrumentation 儀器6.3.1 Primary radiation sources 光源6.3.2 Atomizer 原子儀器6.3.3 Optical dispersive systems 分光系統6.3.4 Detectors 檢測器6.3.5 Signal measurements 信號測量6.4 Quantitative measurements and interferences 定量測定及干擾6.4.1 Quantitative measurements 定量測定6.4.2 Interferences 干擾6.4.3 Sensitivity6.5 Applications of AAS原子吸收光譜法的應用ProblemsTerms to understand重點內容概述Chapter 7 Ultraviolet and Visible Spectrophotometry 紫外-可見分光光度法7.1 Introduction簡介7.2 Ultraviolet and visible absorption spectroscopy 紫外-可見吸收光譜7.2.1 Introduction for radiant energy 輻射能簡介7.2.2 Selective absorption of radiation and absorbance spectrum 物質對光的選擇性吸收和吸收光譜7.2.3 Absorbing species and electron transition 吸收物質與電子躍遷7.3 Law of absorption吸收定律7.3.1 Lambert-Beer's law朗伯-比爾定律7.3.2 Absorptivity吸光係數7.3.3 Apparent deviations from Beer's law對比爾定律的明顯偏離7.4 Instruments儀器7.5 General types of spectrophotometer分光光度計種類7.6 Application of UV-Vis absorption spectroscopy 紫外-可見吸收光譜的應用7.6.1 Application of absorption measurement to qualitative analysis 光吸收測定在定性分析上的應用7.6.2 Quantitative analysis by absorption measurements 光吸收測量定量分析法7.6.3 Derivative spectrophotometry 導數分光光度法ProblemsTerms to understand重點內容概述Chapter 8 Infrared Absorption Spectroscopy紅外吸收光譜8.1 Theory of infrared absorption紅外吸收基本原理8.1.1 Dipole changes during vibrations and rotations 振轉運動中的偶極距變化8.1.2 Mechanical model of stretching vibrations 伸縮振動機械模型8.1.3 Quantum treatment of vibrations 振動的量子力學處理、8.1.4 Types of molecular vibrations分子振動形式8.2 Infrared instrument components紅外儀器組成8.2.1 Wavelength selection波長選擇8.2.2 Sampling techniques 採樣技術8.2.3 Infrared spectrophotometers for qualitative analysis 定性分析用紅外分光光度計8.2.4 Other techniques其他技術8.3 The group frequencies of functional groups in organic compounds 有機化合物官能團的特徵頻率8.4 The factors affecting group frequencies 影響基團特徵吸收頻率的因素8.4.1 Adjacent groups 鄰近基團的影響。
