酚醛模塑料PF2A5-151J(b)黑物质安全资料表MSDS

SDS REVISION:01DATE:12-Apr-111CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME:CHEMICAL NAME:GRADE:TYPE:CHEMICAL FORMULA:COMMON NAME:MANUFACTURER:ADDRESS:Phenolic Moulding Compound Complex"SUMIKON ®" PM-9820JR BLACK Complex Not AvailablePHONE / FACSIMILE NUMBER:2Central nervous system, BloodMay cause damage to organs through prolonged or repeated exposure.H317May cause an allegic skin reaction H334May cause allergy or asthma symptoms or breathing difficulties if inhaled Causes severe skin burns and eye damage.Causes serious eye damage.May cause Genetic defects.Hazard ClassSkin Corrosion/ Skin Irritation Target Organs: Nervous system, Kidneys,11B Respiratory system, Circulative systemServere Eye Damage/ Eye IrritationGerm Cell MutagenicityCarcinogenicity Reproductive ToxicitySpecific Target Organ Toxicity -Single ExposureRespiratory Sensitizer 1Skin Sensitizer 11A 11B 22Specific Target Organ Toxicity -Repeated Exposure1Target Organs:Specific Target Organ Toxicity -Repeated ExposureH351H360H370H372LungsSuspected of causing cancer.May damage ferillity or the unborn child.Causes damage to organs.HAZARD IDENTIFICATIONGHS ClassificationH314H318Physical HazardsHarzard Categorystream, Kidney, Liver, Spleen, Chest Circulative system, Digestive systemTarget Organs:H340 GHS Signal WordDanger GHS SymbolCauses damage to organs through prolonged or repeated exposure.SumiDurez Singapore Pte LtdSAFETY DATA SHEETH373IF SKIN IRRIATION OR RASH OCCURS : Get medical advice/ attention Wash contaminated clothing before reuse3COMPOSITION / INFORMATION ON INGREDIENTS4FIRST AID MEASURESEYE:Don't Let The Victim Rub His/Her Eyes. Flush Eyes With Large Amounts Of Clean Water Immediately And Continuously For At Least 15 minutes.IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.SKIN:Wash The Affected Area Under Running Water With Soap.INHALATION:Remove To Fresh Air. If Not Breathing, Give Mouth Resuscitation. If Breathing Is Difficult,Given Oxygen.GET MEDICAL ATTENTION.INGESTION:Rinse Mouth With Water. Drink Large Quantities Of Water, And Then Induce Vomiting By Having Patient Tickle Back Of Throat With Finger.NOTES TO Treat Symptomatically.PHYSICIANS:Treatment May Vary With Condition Of Victim And Specifics Of Incident.Carbon BlackCalcium Hydroxide Cotton flock Zinc Borate Calcium StearateComponents Phenolic Resin Wood DustMagnesium Hydroxide P280Wear protective gloves/ protective clothing/ eye protection/ face protection P285In case of inadequate ventilation wear respiratory protection1333-86-40.1 - 1Wash thoroughly after handlingDo not eat, drink or smoke when using this productContaminated work clothing should not be allowed out of the workplace - 2.5 - 109003-35-4-1309-42-8P270P272 international regulationsP307 + P311Immediately call a POISON CENTER or doctor/physician.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing .P301 + P330 + P331If SWALLOWED : Rinse mouth. Do not induce vomiting.IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses,P310P304 + P340P305 + P351 + P338P333 + P313P363P201Obtain special instruction before use.Do not handle until all safety precaution have been P314Response precautionary StatementsPrevention Precautionary StatementsDo not breathe dust/ fume/ gas/ mist/ vapour/ spray 40 - 60P501P202P260P264Disposal Precautionary StatementsRinse skin with water/shower.IF INHALED : Remove victim to fresh air and keep at rest in a position comfortablefor breathing.IF EXPOSED : Call a POSION CENTER or doctor/physician.Phenol 1305-62-01 - 2.5(CAS No.)Percentage (%)P405P303 + P361 + P353Get medical advice/attention if you feel unwell.2.5 - 10108-95-21332-07-61592-23-0 1 - 2.5Storage Precautionary Statementsif present and easy to do. Continue rinsing.2.5 - 10Store locked up20 - 4010 - 20Dispose of contents/container: In accordance with local/ regional/ national/5FIRE FIGHTING MEASURESFLAMMABLE PROPERTIES:FLASH POINT (°C/°F):Not Determined (METHOD USED: Not applicable )AUTO IGNITION (°C/°F):Not Determined TEMPERATURE (°C/°F):Not DeterminedFLAMMABLE LIMITS:Lower FL: Not DeterminedUpper FL: Not DeterminedEXTINGUISHING MEDIA:Use Water, Dry Chemical, Halon, Alcohol Foam, Carbon Dioxide Or Sand.FIRE & EXPLOSION HAZARDS:Dense Smoke Emitted When Burned Without Sufficient Oxygen And Hazardous (NORMAL)Decomposition Products Are Carbon Dioxide (CO 2) And Some Carbon Monoxide (CO).FIRE & EXPLOSION HAZARDS:Explosive Hazard. Organic Dust Can Be Explosive When Ideal Conditions Of (UNUSUAL)Concentration, Humidity And Source Are Met.PROTECTION (EQUIPMENT)Wear Full Bunker Gear Including A Positive Pressure Self-Contained BreathingOF FIREFIGHTERS:Apparatus Approved By MSHA / NIOSH In Any Closed Space. Do Not Inhale Gases.6ACCIDENTAL RELEASE MEASURESCarefully Sweep Up Or Vacuum Spills And Place It In A Waste Container With Proper Personal Protective Equipment.Avoid Raising Dust. Vacuum Cleaning Is Preferred So As To Minimise Dust.7HANDLING AND STORAGEHANDLING:Keep Container Closed. When Handling, Avoid Eye Contact And Breathing Dusts If e Good House Keeping Practices To Prevent The Accumulation Of Dust.After Using This Material, Wash Hands.SPECIAL MIXING:Resin Will Polymerise Exothermically At Temperature In Excess Of 40°C STORAGE:Store In Cool And Dry Place To Avoid Effects Of Heat And Moisture.Exposure To High Temperature And/Or Moisture Causes Resin Agglomeration.8EXPOSURE CONTROLS / PERSONAL PROTECTIONppm mg/m 3ppm mg/m 3-5--519--- 3.5---5-10ENGINEERING CONTROLS:Provide General And/Or Local Exhaust Ventilation To Control AirborneLevels Below The Exposure Guidelines.PERSONAL PROTECTIVE EQUIPMENT (PPE):RESPIRATORY PROTECTION:Wear A Safety Mask To Protect From Dust.EYE PROTECTION:Wear Safety Glasses With Side Shields Or Goggles.SKIN / BODY PROTECTION:Wear Clean Body-Covering Clothing. Wear Cloth Or Rubber Gloves.OTHER PROTECTIVE EQUIPMENT:Eye Wash Facility Should Be In Close Proximity (ANSI Z358.1 - 1981).9PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE PHYSICAL STATE:Solid.PHYSICAL APPREARANCE:Granular Solid COLOR:BlackWood Dust (soft)Phenol Carbon Black Permissible Exposure Limit (PEL)Long Term Short TermSINGAPORE OCCUPATIONAL EXPOSURE LIMITS:Calcium HydroxideComponentsODOR:Slight Phenolic Odor.pH Value:Not Applicable.MELTING POINT:Not Applicable.BOILING POINT:Not Applicable.FLASH POINT:Not Applicable.AUTO IGNITION POINT:Not Applicable.LOWER FLAMMABILITY LIMIT:Not Applicable.UPPER FLAMMABILITY LIMIT:Not Applicable.VAPOR PRESSURE:Not Applicable.VAPOR DENSITY:Not Applicable.SPECIFIC GRAVITY: 1.4 - 1.5SOLUBILITY IN WATER:Not Applicable.PARTITION COEFFICIENT:Not ApplicableDECOMPOSITION TEMPERATURE:Not Applicable10STABILITY AND REACTIVITYCHEMICAL STABILITY (CONDITION TO AVOID):Avoid Exposing To High Temperature And/Or Moisture And Dust Buildup In The Manufacturing Areas.INCOMPATIBILITY (SPECIFIC MATERIALS TO AVOID):Avoid Acids And/Or Alkaline.HAZARDOUS DECOMPOSITION PRODUCTS:Carbon Dioxide (CO2) And Some Carbon Monoxide (CO), Traces Of Phenol Vapour And Ammonia Gas.HAZARDOUS POLYMERISATION:Will Not Occur.11TOXICOLOGICAL INFORMATIONRoutes of Exposure Inhalation, Ingestion (Swallowing), Skin or Eye ExposureAcute ToxicityPhenol ACUTE Ingestion LD50 (Rat):317 mg/kg(CAS No.: 108-95-2)ACUTE Skin Contact LD50 (Rat):669 mg/kgACUTE Skin Contact LD50 (Rabbit):850 mg/kgCalcium Hydroxide ACUTE Ingestion LD50 (Rat):7340 mg/kg(CAS No.: 1305-62-0)Magnesium Hydroxide ACUTE Ingestion LD50 (Rat):8500 mg/kg(CAS No.: 1309-42-8)Skin Corrosion/ Irritation:Causes severe skin burnsSerious Eye Damage/ Irritation:Causes severe skin burns and eye damage. Causes serious eye damageRespiratory Sensitisation:No DataSkin Sensitisation:Causes sever skin burnsGerm Cell Mutagenicity:May Cause Genetic Defects. May Induce Heritable MutationCarcinogenicity:Suspected of causing cancerIARC:Substance ClassificationWood Dust(CAS - )Group 1 Carcinogenic to humansCarbon Black(CAS 1333-86-4)Group 2B Possibly carcinogenic to humansPhenol(CAS 108-95-2)Group 3 Not classifiable as to its carcinogenicity tohumansReproductive Toxicity May cause infertitly or harm to the unborn childSpecific Target Organ ToxicitySingle Exposure No DataRepeated Exposure No DataAspiration Hazard No DataMetabolism Long term exposure will lead to side effects12ECOLOGICAL INFORMATIONEcological StatisticsSubstance Test resultsPhenol(CAS No.108-95-2)LC50 Medaka, high-eyes (Oryzias latipes):23.4 - 36.6 mg/l 96 h Calcium Hydroxide(CAS No.1305-62-0)LC50 Zambezi barbel (Clarias gariepinus):33.8844 mg/l 96 h Eco-Toxicity Contains substances which is harmful to the environmentPersistence and Degradability No DataBio Accumulative Potential No DataMobility in Soil No DataOther Adverse Effects No Data13DISPOSAL CONSIDERATIONSDispose Of Materials To Be In Accordance with Local/ Regional/ National/ Internation Regulations14TRANSPORT INFORMATIONUN number:NoneUN proper shipping name:Not AllocatedTransport Hazard Class:Not Classified as hazardous for TransportPacking Group:Not AllocatedMarine Pollutant:Not AllocatedTransport in Bulk:Not AllocatedSpecial Precautions:None15REGULATORY INFORMATIONGeneralSingapore's Workplace Safety and Health (General Provisions) Regulations 2006Singapore Standards:-CP 12:2001 Part 1-CP 98:2003-SS 152:2003-SS 286:1984 Part 1 to Part 5International StandardsIARC: International Agency for Research on Cancer16OTHER INFORMATIONReferencesSingapore's Workplace Safety and Health (General Provisions) Regulations 2006Singapore Standards:-CP 12:2001 Part 1-CP 98:2003-SS 152:2003-SS 286:1984 Part 1 to Part 5International StandardsIARC: International Agency for Research on CancerISSUED BY:SUMIDUREZ SINGAPORE PTE LTD DEPARTMENT:EH&SThe Information Presented Herein, While Not Guaranteed, Was Prepared By Competent Technical Personnel For Your Reference And Is True And Accurate To The Best Of Our Knowledge. It Is Given In Good Faith. No Warranty Or Guaranty, Express Or Implied, Is Made Regarding Performance, Stability Or Otherwise. This Information Is Not Intended To Be For All - Inclusive As To The Manner And Conditions Of Use, Handling And Storage. Following Of Safety Procedures During Handling And Use Remains The Responsibility Of The Recipient / Customer.。

【化学品安全技术说明书-MSDS】酚醛漆—MSDS1.化学品及企业标示物品中文名称：酚醛漆物品别名：物品英文名称：危险性类别：第3.2类物品生产厂商名称及紧急联系电话：2.成分∕组成信息物品有害物成分：有害成分名称有害成分百分比（%）有害成分CAS NO 1. 甲醛3.危险性概述侵入人体途径：吸入、食入、经皮吸收。

健康危害：本品的主要危害为引起过敏性皮肤病，及呼吸道疾病4.急救措施皮肤接触：脱去被污染的衣着，用肥皂水和清水彻底冲洗皮肤。

眼睛接触：提起眼睑，用大量流动清水或生理盐水彻底冲洗。

吸入：迅速脱离现场至空气新鲜处。

食入：饮足量温水，催吐。

就医。

5.消防措施爆燃特性：易燃闪点（℃）：无意义爆炸上限（%）：无资料爆炸下限（%）：mg/m3引燃温度（℃）：危险特性：灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。

灭火剂：砂土、泡沫、二氧化碳、干粉。

6.泄露应急处理进行隔离，严格限制出入。

切断火源。

小量泄露：用干燥的砂土或类似物质吸收。

7.操作处置与储存储于阴凉通风仓间内。

远离火种，热源。

防止阳光直射。

包装必须密封，切勿受潮。

应与氧化剂分开存放。

搬运时要轻装轻卸，防止包装及容器损坏。

8.接触控制∕个体防护工程控制措施：密闭操作，提供良好的自然通风条件。

最高容许浓度（MAC）：未指定标准。

个体防护措施呼吸系统防护：配戴口罩防护。

眼睛防护：接触时可戴化学安全防护眼镜。

皮肤与身体防护：穿一般作业防护服。

手部防护：戴一般作业防护手套。

其他防护：工作现场禁止吸烟。

保持良好的卫生习惯。

9.理化特性外观与性状：液体。

PH值：不适用沸点熔点： 1185℃溶解性：溶于丙酮、乙二醇、甲苯。

10.稳定性和反映性稳定性：稳定禁忌物：聚合危害：不聚合分解（燃烧）产物：一氧化碳、二氧化碳。

11.毒理学资料急性毒性：（半数致死量） mg/kg（大鼠经口）LC50 （半数致死浓度）亚急性和慢性毒性：资料不详。

刺激性：资料不详。

物 質 安 全 資 料 表（MSDS ）一、 物品與廠商資料 物品名稱： 酚醛模塑料PF2A5-151J （b ）黑（电木粉）物品編號： 緊急聯絡電話/傳真電話： 联絡電話： 傳真電話：二、 成分辨識資料物質名稱:中英文名稱： 酚醛模塑料 (Phenolic Molding Compound)同義名稱：电木粉混合物： 主要組成物質：物質成分之中英文名稱化學文摘社登記號碼(CAS No.) 備考 酚醛樹脂(Phenol-formaldehyde resin)木粉(Wood Flour)離型劑(Release Agent) 無機填充物(Inorganic filler) 三、 危害辨識資料 健康危害效應：吸入或皮膚接觸可能會引起過敏環境影響：N.A. 物理性及化學性危害：N.A. 最 重 要危害效應 特殊危害：N.A. 主要症狀：N.A.物品危害分類：N.A.四、 急救措施不同暴露途徑之急救方法：˙吸入： 移至通風良好處˙皮膚接觸：以大量清水及肥皂清洗即可˙眼睛接觸：立即以清水沖洗至少15分鍾, 緊急送醫處理˙食入：以清水清洗嘴巴後, 緊急送醫處理最重要症狀及危害效應：N.A.對急救人員之防護：N.A.X S L -MSD S對醫師之提示： N.A.物 質 安 全 資 料 表五、 滅火措施 適用滅火劑：CO2滅火時可能遭遇之特殊危害：N.A.特殊滅火程序：N.A.消防人員之特殊防護設備：一般消防防護設備六、 洩漏之處理方法個人應注意事項：配戴面罩或活性碳口罩防止吸入塵埃環境注意事項：勿使物品流入地下水道系統清理方法：一般作業環境下作區別管理七、 安全處置與儲存方法處置：避免陽光直射之場所儲存：通風, 常溫, 常濕之室內環境 八、 暴露預防措施 工程控制：N.A.控制參數：˙八小時日時量平均容許濃度/短時間時量平均容許濃度/最高容許濃度：N.A. ˙生物指標：N.A.個人防護設備：˙呼吸防護： 面罩或活性碳口罩˙手部防護： 手套˙眼睛防護： 安全眼鏡˙皮膚及身體防護： 長袖工作服衛生措施：操作後以大量清水及肥皂洗滌身體接觸部份X S L -M SD S物 質 安 全 資 料 表九、 物理及化學性質 物質狀態： 固體形狀：粒狀或粉體 顏色：黑色氣味：輕微石碳酸味道 pH 值：9 - 10沸點/沸點範圍：N.A. 分解溫度：N.A.閃火點： N.A. ℉ N.A. ℃ 測試方法：開杯閉杯 自燃溫度：N.A.爆炸界限：N.A. 蒸氣壓：N.A.蒸氣密度：N.A. 密度：≤1.58 溶解度：不溶於水 十、 安定性及反應性安定性：依正常使用程序安定性佳特殊狀況下可能之危害反應：吸入或皮膚接觸可能會引起過敏 應避免之狀況： N.A.應避免之物質： N.A.危害分解物： N.A. 十一、毒性資料急毒性：N.A.局部效應：N.A. 致敏感性：吸入或皮膚接觸可能會引起過敏慢毒性或長期毒性：N.A.特殊效應：N.A.十二、生態資料可能之環境影響/環境流佈：N.A.十三、廢棄處置方法廢棄處置方法：高溫焚化或洽詢領有牌照之廢棄物處理單位做適當處置 十四、運送資料國際運送規定：N.A.聯合國編號： N.A.XS L -MS DS國內運送規定：N.A.特殊運送方法及注意事項：N.A.物質安全資料表十五、法規資料適用法規: N.A.十六、其他資料參考文獻N.A.製表單位地址：電話：製表人職稱：姓名(簽章)：製表日期2019.05.25.。

化学品安全技术说明书（ＭＳＤＳ）第一部分：化学品名称中文名称：酚醛树脂英文名称：phenolic resin分子式结构图：第二部分：成分/组成信息有害物成分：无第三部分：危险性概述健康危害：接触加工或使用本品过程中所形成的粉尘，可引起头痛、嗜睡、周身无力、呼吸道粘膜刺激症状、喘息性支气管炎和皮肤病。

空气环境分析发现苯酚、甲醛和氨。

在缩聚过程中，可发生甲醛、酚、一氧化碳中毒。

燃爆危险：本品易燃，具刺激性。

第四部分：急救措施皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。

眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。

就医。

吸入：迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

如呼吸停止，立即进行人工呼吸。

就医。

食入：饮足量温水，催吐。

就医。

第五部分：消防措施危险特性：易燃，遇明火、高热能燃烧。

受高热分解放出有毒的气体。

粉体与空气可形成爆炸性混合物，当达到一定浓度时，遇火星会发生爆炸。

有害燃烧产物：一氧化碳、二氧化碳。

灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。

灭火剂：雾状水、泡沫、二氧化碳、干粉、砂土。

第六部分：泄漏应急处理切断火源，切断泄漏源防止流入下水道、排洪沟等限制性空间；用干燥的砂土或类似物质吸收。

第七部分：操作处置与储存操作处置：戴防护手套，搬运时要轻装轻卸。

储存：阴凉、通风，严禁烟火，密封存储。

第八部分：接触控制/个体防护眼睛防护：一般不需要特殊防护，高浓度接触时可戴化学安全防护眼镜。

手防护：戴一般作业防护手套。

呼吸系统防护：空气中浓度超标时，佩戴防尘口罩。

其他防护：工作现场严禁吸烟，保持良好的卫生习惯。

第九部分：理化特性外观与性状：无臭、无味的黄色透明液体。

燃、沸点：无资料。

主要用途：用作层压塑料、压塑粉、玻璃纤维增强塑料和胶合工业、涂料工业粘合剂等。

第十部分：稳定性和反应活性稳定性：无禁配物：强氧化剂。

第十一部分：毒理学资料无资料第十二部分：生态学资料无资料。

常熟东南塑料有限公司Changshu South-EastPlastic Co., Ltd.酚 醛 模 塑 料 PHENOLIC MOULDING COMPOUND● 型号 DesignationPF2A5-151J (b)● 颜色 Color黑色（Black ）● 特点和用途本产品是以酚醛树脂为基材，木粉和矿物等为填料制成，具有较高的机械强度、良好的电气性能、阻燃性能和耐热性能。

适合于制作线圈骨架、微型开关、继电器等电气绝缘结构件。

适用于注射成型和传递模压成型。

本产品按GB1404-95标准生产，并具有UL 认证。

● 技术指标序号性 能 试验方法 单位 指标 1 体积系数 GB8324 ≤ 2.5 2 流动性 拉西格 mm (120-200) 3 相对密度 GB1033 ≤ 1.58 4 弯曲强度 GB9341 MPa ≥ 80 5 冲击强度（缺口） GB1043 KJ/m 2 ≥ 1.7 6 热变形温度 GB1634 ℃ ≥ 2007 绝缘电阻 GB10064 Ω ≥ 10×1098 介电强度（90℃）GB1408 MV/m ≥ 3.5 9 介质损耗因素（tan δ）(1MHz) GB1409 ≤ 0.05 10 耐泄漏 UL746A PLC 3 11 耐电弧 D495 PLC 5 12 收缩率 JB/T6542 % (0.5-0.8) 13 吸水性 GB1034 mg≤ 30 14 阻燃性UL94@0.45mmV-0● 注射成型条件模具温度 ℃ 料筒温度℃ 注射压力 MPa 闭模压力 MPa 背压 MPa 保持时间s/mm 定模 动模 前料筒 后料筒165-175 170-180 90-100 70-80 80-160 100-200 1-3 10-20● 包装与储存本产品包装在内衬防潮塑料袋的多层复合纸袋中，净重25公斤。

包装上标有产品型号、批号、重量和生产日期等标志。

本产品应避免受潮受热，不得靠近火源或受阳光直射。