ASTM A232-99
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Designation:A232/A232M–99StandardSpecificationforChromium-VanadiumAlloySteelValveSpringQualityWire1ThisstandardisissuedunderthefixeddesignationA232/A232M;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginaladoptionor,inthecaseofrevision,theyearoflastrevision.Anumberinparenthesesindicatestheyearoflastreapproval.Asuperscriptepsilon(e)indicatesaneditorialchangesincethelastrevisionorreapproval.ThisstandardhasbeenapprovedforusebyagenciesoftheDepartmentofDefense.1.Scope1.1Thisspecificationcoversthehighestqualityofroundchromium-vanadiumalloysteelvalvespringwire,uniforminqualityandtemper,intendedforthemanufactureofvalvespringsandotherspringsrequiringhigh-fatiguepropertieswhenusedatmoderatelyelevatedtemperatures.Thiswireshallbeeitherintheannealedandcold-drawnoroil-temperedconditionasspecifiedbythepurchaser.1.2ThevaluesstatedineitherSIunitsorinch-poundunitsaretoberegardedseparatelyasstandard.Withinthetext,theinch-poundunitsareshowninbrackets.Thevaluesstatedineachsystemarenotexactequivalents;therefore,eachsystemmustbeusedindependentoftheother.2.ReferencedDocuments2.1ASTMStandards:A370TestMethodsandDefinitionsforMechanicalTestingofSteelProducts2A700PracticesforPackaging,Marking,andLoadingMethodsforSteelProductsforDomesticShipment3A751TestMethods,Practices,andTerminologyforChemicalAnalysisofSteelProducts2E29PracticeforUsingSignificantDigitsinTestDatatoDetermineConformancewithSpecifications42.2ANSIStandard:B32.4PreferredMetricSizesforRound,Square,Rect-angle,andHexagonMetalProducts52.3FederalStandard:Fed.Std.No.123MarkingforShipment(CivilAgencies)62.4MilitaryStandard:MIL-STD-163SteelMillProducts,PreparationforShip-mentandStorage62.5AIAGStandard:AIAGB-502.00PrimaryMetalsIdentificationTagAppli-cationStandard73.OrderingInformation3.1Ordersformaterialunderthisspecificationshouldincludethefollowinginformationforeachordereditem:3.1.1Quantity(mass),3.1.2Nameofmaterial(chromium-vanadiumalloysteelvalvespringqualitywire),3.1.3Dimensions(Table1andSection8),3.1.4Condition(Section6),3.1.5Packaging(Section14),3.1.6Heatanalysisreport,ifrequested(5.2),3.1.7Certificationortestreport,orboth,ifspecified(Sec-tion13),and3.1.8ASTMdesignationandyearofissue.NOTE1—Atypicalorderingdescriptionisasfollows:20000kgoil-temperedchromium-vanadiumalloysteelvalvespringqualitywire,size6.00mmin150kgcoilstoASTMA232/A232Mdated,orforinch-poundunits,40000lboil-temperedchromium-vanadiumalloysteelvalvespringqualitywire,size0.250in.in350-lbcoilstoASTMA232/A232Mdated.4.MaterialsandManufacture4.1Thesteelmaybemadebyanycommerciallyacceptedsteelmakingprocess.Thesteelmaybeeitheringotcastorstrandcast.4.2Thefinishedwireshallbefreefromdetrimentalpipeandunduesegregation.5.ChemicalComposition5.1ThesteelshallconformtotherequirementsforchemicalcompositionspecifiedinTable2.5.2HeatAnalysis—EachheatofsteelshallbeanalyzedbythemanufacturertodeterminethepercentageofelementsprescribedinTable2.Thisanalysisshallbemadefromatestspecimenpreferablytakenduringthepouringoftheheat.Whenrequested,thisshallbereportedtothepurchaserandshallconformtotherequirementsofTable2.1ThisspecificationisunderthejurisdictionofASTMCommitteeA-1onSteel,StainlessSteel,andRelatedAlloysandisthedirectresponsibilityofSubcommitteeA1.03onSteelRodandWire.CurrenteditionapprovedApril10,1999.PublishedJune1999.OriginallypublishedasA232–39T.LastpreviouseditionA232/A232M–96.2AnnualBookofASTMStandards,Vol01.03.3AnnualBookofASTMStandards,Vol01.05.4AnnualBookofASTMStandards,Vol14.02.5AvailablefromtheAmericanNationalStandardsInstitute,11West42ndStreet,13thFloor,NewYork,NY10036.6AvailablefromStandardizationDocumentsOrderDesk,Bldg.4SectionD,700RobbinsAve.,Philadelphia,PA19111-5094,Attn:NPODS.7AvailablefromtheAutomotiveIndustryActionGroup,26200Lahser,Suite200,Southfield,MI48034.1Copyright©ASTMInternational,100BarrHarborDrive,POBoxC700,WestConshohocken,PA19428-2959,UnitedStates.5.3ProductAnalysis—Ananalysismaybemadebythepurchaserfromfinishedwirerepresentingeachheatofsteel.Theaverageofalltheseparatedeterminationsmadeshallbewithinthelimitsspecifiedintheanalysiscolumn.Individualdeterminationsmayvarytotheextentshownintheproductanalysistolerancecolumn,exceptthattheseveraldetermina-tionsofasingleelementinanyoneheatshallnotvarybothaboveandbelowthespecifiedrange.5.4Forrefereepurposes,TestMethods,PracticesandTer-minologyA751shallbeused.6.MechanicalProperties6.1AnnealedandCold-Drawn—Whenpurchasedintheannealedandcold-drawncondition,thewireshallhavebeengivenasufficientamountofcoldworkingtomeetthepurchas-er’scoilingrequirementsandshallbeinasuitableconditiontorespondproperlytoheattreatment.Inspecialcasesthehardness,ifdesired,shallbestatedinthepurchaseorder.6.2OilTempered—Whenpurchasedintheoil-temperedcondition,thetensilestrengthandminimumpercentreductionofarea,sizes2.50mm[0.105in.]andcoarser,ofthewireshallconformtotherequirementsprescribedinTable1.6.2.1NumberofTests—Onetestspecimenshallbetakenforeachfivecoils,orfractionthereof,inalot.Eachheatinagivenlotshallbetested.6.2.2LocationofTests—Testspecimensshallbetakenfromeitherendofthecoil.6.2.3TestMethod—ThetensiontestshallbemadeinaccordancewithTestMethodsandDefinitionsA370.6.3WrapTest:6.3.1Oil-temperedorcold-drawnwire4.00mm[0.162in.]andsmallerindiametershallwindonitselfasanarborwithoutbreakage.Largerdiameterwireuptoandincluding8.00mm[0.312in.]indiametershallwrapwithoutbreakageonamandreltwicethewirediameter.Thewraptestisnotappli-cabletowireover8.00mmindiameter.6.3.2NumberofTests—Onetestspecimenshallbetakenforeachfivecoils,orfractionthereof,inalot.Eachheatinagivenlotshallbetested.6.3.3LocationofTest—Testspecimensshallbetakenfromeitherendofthecoil.6.3.4TestMethod—Thewraptestshallbemadeinaccor-dancewithTestMethodsandDefinitionsA370.6.4SpecialSurfaceInspection—Whenspecified,theentirelengthofeverycoilusedbyenginevalvespringmanufacturersshallbeinspectedforsurfaceimperfectionswithamagneticand/oreddycurrentdefectanalyzerorequivalent.7.MetallurgicalRequirements7.1SurfaceCondition:7.1.1Thesurfaceofthewireasreceivedshallbefreeofimperfectionssuchaspits,diemarks,scratches,seams,andotherdefectstendingtoimpairthefatiguevalueofthesprings.7.1.2NumberofTests—Onetestspecimenshallbetakenfromeachendofeverycoil.7.1.3TestMethod—Thesurfaceshallbeexaminedafteretchinginasolutionofequalpartsofhydrochloricacidandwaterthathasbeenheatedtoapproximately80°CforaTABLE1TensileRequirementsASIUnitsDiameter,BmmMPa,minMPa,maxReductionofArea,min,%0.5020602260C0.5520502240C0.6020302220C0.6520102200C0.7020002160C0.8019802140C0.9019602120C1.0019402100C1.1019202080C1.2019002060C1.4018602020C1.6018201980C1.8018001960C2.0017801930C2.2017501900C2.5017201860452.8016801830453.0016601800453.5016201760454.0015801720404.5015601680405.0015201640405.5014801620406.0014601600406.5014401580407.0014201560408.0014001540409.00138015204010.00136015004011.00134014804012.001320146040Inch-PoundUnitsDiameter,in.ksi,minksi,maxReductionofArea,min,%0.020300325C0.032290315C0.041280305C0.054270295C0.062265290C0.080255275C0.105245265450.135235255450.162225245400.192220240400.244210230400.283205225400.312203223400.375200220400.438195215400.50019021040ATensilestrengthvaluesforintermediatediametersmaybeinterpolated.BPreferredsizes.Foracompletelist,refertoANSIB32.4.CThereductionofareatestisnotapplicabletowirediametersunder0.092in.[2.34mm].TABLE2ChemicalRequirementsAnalysis,%ProductAnalysisTolerance,%Carbon0.48–0.5360.02Manganese0.70–0.9060.03Phosphorus0.020max+0.005Sulfur0.035max+0.005Silicon0.15–0.3560.02Chromium0.80–1.1060.05Vanadium0.15min−0.01