光谱采集用户手册

德國SPECTROMAXx分光儀V0.01卓明貿易股份有限公司231台北縣新店市寶橋路235巷133號7樓之3 TEL : (02) 8919-1488 407台中市西屯區福順路140號16F-1 TEL : (04) 2462-0010 813高雄市左營區文康路197號4樓TEL : (07) 345-2867目錄Index 操作注意事項開機步驟選擇分析程式(Load Program)輸入樣品編號(Edit Sample Data)分析樣品(Analyze)ICAL校正(Intelligent Calibration Logic)微調校正關機步驟(Shutdoun Procedure)快速功能(Hot Key)設定材質規格資料庫(Alloy Grade Library)元素顯示排列(Element Format)元素顯示模式(Output Mode)故障排除(Trouble Shooting)操作注意事項1.環境操作條件Designation內容ValueElectric connection電力220 V +- 10VGround接地線必需採用獨立接地線Power during scan最大耗電400 VAPower during stand-by待機180 VATemperature range環境溫度具備空調的實驗室Air humidity range溼度20 – 80%, not condensingArgon cylinder pressure氬氣鋼瓶最低壓力Argon inlet pressure on the unit氬氣壓力10bar ( 1 Mpa) 7.0 bar (0.7 Mpa)Argon quality (min.)氬氣純度要求 4.9 (99.999% Ar)以上Argon flow rates Stand-by (low-flow):Constant flow:Analytic flow: 6 l/h 23l/h 200l/h2.試片之處理與分析i.樣品處理設備鐵基、鈷基、鎳基、鈦基…………環帶式砂輪機1Hp，無縫砂布帶60號鉛基、銅基、鋅基、鎂基、鍚基、鉛基…車床或銑床，可夾持￠25-80mm的樣品ii.試片不可氧化及不帄，車削時不可加切削液iii.不可用手觸摸分析面。

1. MethodWith the help of two ready-to-use multiparameter solutions (standardsolution and addition solution) of defined content, measurement values are compared with desired values to determine any analytical errors.The error caused by the photometric measurement system (test kits, photometers, analytical procedures) and the mode of operation can be determined by means of the standard solution . This is used without dilution in place of the sample solution.Sample-dependent effects on the measurement result (matrix effects) are determined by measuring the sample after spiking it with addition solution (standard addition). The addition solution is a concentrated mixture of the ions contained in the standard solution.The standard solution and the addition solution are prepared by accurate weighing in, using an analytical scales controlled with standard weights. All scales are regularly calibrated and checked against PTB standards(P hysikalisch-T echnische B undesanstalt, Germany) and NIST standards (N ational I nstitute of S tandards and T echnology, USA).2. ApplicationsThe CombiCheck articles serve to check the quality of the photometric measurement system and of the mode of working, as well as to identifysample-dependent effects on the measurement result. The latter is an impor-tant indication of the necessity for sample pretreatment. The measurement results are traceable to NIST .Recommended frequency of application:Standard solution (reagent R-1) Addition solution (reagent R-2) • 1 x per series 1) • when the composition of the individualsamples differs considerably from each • approx. every 10th sample other• upon a switch in operating personnel • when measurement results do notappear plausible• upon the opening of a new test package• when measurement results do not appear plausible1)T o determine the random error , it is recommended to repeat the measurement atleast five times.3. Desired values and number of quality checksThe “working tolerance” given in column 2 of the following tables does not express the variation in the contents of the CombiCheck solutions (this lies below 1%), but instead the permissible dispersion of the results caused by the photometric measurement system and the mode of operation when using the respective test kit (column 3). The working tolerance defined in thismanner serves as an assessment criterion for the quality check (see section 5).Standard solution (reagent R-1)Parameter Desired value/ Can be used R-1 Number ofworking tolerancefor Cat. No.(ml)quality checksAluminium 0.40 + 0.05 mg/l Al 100594 6.016 0.40 + 0.05 mg/l Al 114825 1) 5.0 19Lead 2.00 + 0.20 mg/l Pb 114833 5.019 2.00 + 0.20 mg/l Pb 109717 1) 8.0 11Nickel 2.00 + 0.20 mg/l Ni 114554, 5.0 19 114785 1) Zinc 0.750 + 0.150 mg/l Zn 100861 10.0 9 0.75 + 0.15 mg/l Zn114832 5.0191)when a 10-mm rectangular cell is usedAddition solution (reagent R-2)ParameterDesired value/ Can be used Sample + Number ofconfidence interval for Cat. No. R-2 (ml)quality checksAluminium 0.20 + 0.03 mg/l Al 1005946.0 + 0.10 280 0.24 + 0.04 mg/l Al 114825 1) 5.0 + 0.10 280Lead 1.00 + 0.15 mg/l Pb 114833 5.0 + 0.10 2800.63 + 0.20 mg/l Pb109717 1) 8.0 + 0.10 280Nickel 2.00 + 0.20 mg/l Ni 114554, 5.0 + 0.10 280114785 1) Zinc 0.250 + 0.050 mg/l Zn 100861 10.0 + 0.10 280 0.50 + 0.10 mg/l Zn1148325.0 + 0.102801)when a 10-mm rectangular cell is used1 bottle of reagent R-1 (standard solution)1 bottle of reagent R-2 (addition solution)1 control chart5. Quality checkStandard solution (reagent R-1)Preparation• Make photocopies of the enclosed control chart.• Take the desired value and the working tolerance for the standard solution for the respective test kit from the table in section 3 and enter them in the enclosed control chart:desired value at , upper tolerance limit at , lower tolerance limit at .ProcedureProceed according to the instructions given in the package insert of the respective test kit and in the manual of the photometer used. In this case, however, use undiluted reagent R-1 in place of the sample without adjusting the pH!EvaluationEnter the measurement value as a number in a copy of the control chart and mark the grid at the corresponding place.If the measurement value is within the working tolerance (grey back-ground), the working materials and handling are in order .If the measurement value is outside the working tolerance , a systematic error is present. In such a case, among other things the following aspects must be checked:Standard solution and reagents Sample pretreatment• expiry date not yet exceeded? • thermoreactor set correctly?• storage under the recommended • solution colorless and without turbidity? conditions?ProcedurePipettes• operating instructions adhered to?•adjusted correctly? • correct quantity and sequence of reagents? • no contamination? • thoroughly mixed/dissolved after addition of • correct handling?reagents?• new pipette tip used? • reaction time and temperature adhered to? CellsPhotometric measurement• proper size? • correct wavelength (filter) selected? • clean? • correct factors entered?• light path free from foreign matter/dust?Sampling • correct sample volume?Addition solution (reagent R-2)ProcedureIn the following analyses always proceed according to the instruc-tions given in the package insert of the test kit to be checked and in the manual of the photometer used.• Analysis of the sample (measurement value A)• Analysis of a spiked sample: W hen preparing the measurement solution 0.10 ml of reagent R-2 is added by pipette immediately after the sample is added (measure-ment value B).EvaluationCalculate the concentration difference C:C = B - AIf C is within the working tolerance for the addition solution (see table in section 3), the sample does not contain any compounds that interfere with the measurement.If C is outside the working tolerance , a sample-dependent interference is present, and the measurement value A obtained with the sample is incorrect.To obtain a correct result, the sample must be appropriately pre-treated.Notes:• Spiking with the addition solution must not cause the measuring range for the respective test to be exceeded!If this possibility is to be expected, the original sample must be appropri-ately diluted.• The identification of interferences that cancel each other out and of individual interference factors is not possible using this method alone.6. Notes• Reclose the reagent bottles immediately after use.• For photometric measurement the cells must be clean. Wipe, if necessary, with a clean dry cloth.• For quality and batch certificates for Spectroquant ® test kits see the website.• Additional notes see under .7.75468.0004-xxxxxxxxxx msp. January 2019CombiCheck 100Merck KGaA, 64271 Darmstadt, Germany, Tel. +49(0)6151 72-2440EMD Millipore Corporation, 400 Summit DriveBurlington MA 01803, USA, Tel. +1-978-715-4321。

ANDOR SHOMROCK SPECTROMETER & DATAACQUCITION SYSTEMUSER MANUALBy TaoVersion 12011/10/21目录一.探测器简介--------------------------------------------------------------------------------------------------31.硅探测器（Dsi）--------------------------------------------------------------------------------------32.光电倍增管（PMT）---------------------------------------------------------------------------------33.铟镓砷探测器（DInGaAs）-------------------------------------------------------------------------34.硫化铅探测器（DPbs）------------------------------------------------------------------------------55.化铟探测器（DInSb）--------------------------------------------------------------------------------5二.单色仪简介--------------------------------------------------------------------------------------------------7三.数据采集装置-----------------------------------------------------------------------------------------------81.参数------------------------------------------------------------------------------------------------------82.前面板---------------------------------------------------------------------------------------------------93.后面板---------------------------------------------------------------------------------------------------9四.整套系统实际使用---------------------------------------------------------------------------------------101.软件安装-----------------------------------------------------------------------------------------------102.连接-----------------------------------------------------------------------------------------------------10（1）无SR830+SR540-------------------------------------------------------------------------10（2）系统中配置了SR830+SR540----------------------------------------------------------113.软件使用-----------------------------------------------------------------------------------------------13 五．注意事项-------------------------------------------------------------------------------------------------19一.探测器简介单通道光电探测器,探测范围覆盖了紫外-可见光-红外（UV-Visible-IR）的宽波段范围。

野外光谱仪操作手册一、详细操作步骤：1. 连接探头手托、主机箱和笔记本电脑；2. 打开光谱仪（侧面有一黑色内陷按纽，按一下，此时黑色按纽上方有一指示灯变绿，同时可听到机器内风扇的响动，说明机器已经启动。

通常野外测试受测试条件的限制对仪器不用预热，如在室内测试用室内光源，应对仪器预热半小时以上。

对仪器进行校正时，应预热70-90分钟。

）3. 打开笔记本电脑，打开操作软件（开机过程不可颠倒）。

（FR.exe BW（浅色操作系统）—用于室外，FR.exe（彩色）—用于室内）4. 进行数据保存设置：打开菜单栏上Spectrum Save菜单，键入所测光谱数据要保存的路径、文件夹名称（path name默认值C:\FR）、光谱文件名称(base name 默认值spectrum)即可。

（Starting Spectrum Number(d)）是设置开始保存光谱文件的“后缀名”（默认从spectrum.000开始保存））（Number of Files to save(d) 是设置每一次保存的光谱条数默认001每一次保存一条。

）（interval between saves 是设置仪器自动保存光谱之间的时间间隔。

）（comment是对当前测试数据的注解说明，可在后处理中输出。

）通常情况下，后四项可以不设置，但是，记录员必须记录清楚测试当时的条件。

设置完全后按“ok”即可。

5. 进入操作主画面，首先测试员面向太阳方向，用一只手握住测试枪头垂直对准参考板（参考板水平放置，视场角可配置三个25、3、8，裸露时视场角为25，通常状况测试时用25）距离20-30cm，另一只手操作计算机，先优化（按Opt）即仪器对当时的太阳光照条件、增益和积分时间进行配置，再测量暗电流（按DC）。

优化和消除暗电流完成后，即可开始测试（测试项目一般为Raw Dn(digital number)值，（Ref）相对反射率值，（Rad）辐射率值。