Materials Science and Engineering A 367(2004)
166–170
Synthesis of alumina from high purity alum derived from coal ?y ash
H.C.Park a ,?,Y .J.Park a ,R.Stevens b
a
Department of Materials Science and Engineering,Pusan National University,30Jangjeon-dong,Geumjeong-gu,Pusan 609-735,South Korea
b Department of Engineering and Applied Science,University of Bath,Bath BA27AY,UK
Received 7August 2003;received in revised form 27September 2003
Abstract
High purity alum (>99.9%)has been produced by the reaction of NH 4Al(SO 4)2derived from coal ?y ash and ammonia in water at a controlled pH and then followed by the successive crystallization.The in?uence of heating source (conventional and microwave)on the decomposition of the alum and the characteristics of the resultant alumina was examined by means of XRD,TG/DTA,SEM and a laser scattering technique.The application of microwave heating for decomposition of the alum yielded ?ner ?-Al 2O 3powders with a higher speci?c surface area,when compared with conventional heating.?2003Elsevier B.V .All rights reserved.
Keywords:Alum;Coal ?y ash;Alumina;Microwave heating
1.Introduction
Ammonium aluminum sulfate (alum)is a potential start-ing material for preparation of high purity reactive alumina [1–3].Alum is commonly synthesized as an intermediate material for production of alumina from Al-containing non-bauxitic raw materials [4,5].The decomposition of alum and transformation of resultant product to alumina have been reported in the literature [1–3,6]but in general the results show some disagreement.
The recycling of industrial waste to produce highly valu-able materials attracts a great deal of interest from both soci-ety in general and scientists in particular.Resource recovery from the huge amounts of ?y ash generated by combustion of coal in a thermoelectric power plant is one of the important problems which require urgent attention.Coal ?y ash con-sists of ?ne inorganic particles having SiO 2and Al 2O 3as the main components,often in the form of cenospheres.Con-sequently,the synthesis of Al 2O 3powder,which is widely used as high performance raw material,from the coal ?y ash,is of commercial interest.
The coal ?y ash contains a variety of impurities such as Fe 2O 3,Na 2O,K 2O,P 2O 5,MaO,CaO,MgO and TiO 2[7],
?
Corresponding author.Tel.:+82-51-510-2392;fax:+82-51-512-0528.
E-mail address:hcpark1@pusan.ac.kr (H.C.Park).
thus it is dif?cult to directly extract pure Al 2O 3by a sim-ple acid or alkali treatment.One method of obtaining high purity alumina from coal ?y ash,is therefore to manufac-ture alum as an intermediate product.The advantage of the alum as an intermediary is to improve its purity through a straightforward dissolution–precipitation process.
In comparison to conventional heating processes,mi-crowave heating has inherent advantages in that it can be selective,direct,internal and controllable [8].As a conse-quence,microwave processing has been widely applied in materials fabrication processing [8–10].The dissolution of both inorganic and organic materials by an acid can be sig-ni?cantly accelerated due to the effective internal heating caused by microwave [11,12].
The purpose underlying the present work is to facilitate the recycling of coal ?y ash and to produce high purity alumina.Hence the in?uence of microwave heating and the thermal response of coal ?y ash-derived alum has been investigated and the alumina which has been characterized.
2.Experimental procedure
The as-received coal ?y ash (Taean Thermoelectric Power Plant,Chungnam,Korea)contained 23.29Al 2O 3and 53.83wt.%SiO 2;it consisted of mainly silicate minerals,being a mixture of ?ake-like and nearly spherically-shaped
0921-5093/$–see front matter ?2003Elsevier B.V .All rights reserved.doi:10.1016/j.msea.2003.09.093
H.C.Park et al./Materials Science and Engineering A 367(2004)166–170
167
Fig.1.XRD patterns of (a)JCPDS 18-0079,ammonium aluminum sulfate hydrate NH 4Al(SO 4)2,and (b)the alum synthesized in this study.
particles,with a speci?c surface area of 3.82m 2/g and an agglomerate size of 42.1?m (<90%).The coal ?y ash was calcined in air at 600?C for 2h to remove the residual carbon and subsequently ball-milled for 24h in an ethanol.After rotary vacuum evaporation,the dried powder was ground and passed through a 200mesh sieve.The mixed powder consisting of ammonium sulfate (>99%,Shinyo Chemicals)and 5g of coal ?y ash ((NH 4)2SO 4/Al 2O 3in 5g of coal ?y ash =12,molar ratio)was reacted with at 400?C for 2h.The reaction product (NH 4Al(SO 4)2)was poured into 200ml of 1M H 2SO 4solution (First grade reagent,Junsei Chemicals)and reacted at 90?C for 3h us-ing a microwave heating source (2.45GHz,3kW,Hankuk Microwave Co.).After the leaching reaction was complete,the leach liquor was separated from the residue by a vacuum ?ltering process,leaving a residue which consisted mainly of silica.The ?ltered leach liquor was then slowly dropped into 28wt.%ammonia in water (Guaranteed Reagent,Jun-sei Chemicals)and then controlled at a pH of 1while the ammonia solution was continuously stirred for 24h
using
Fig.2.SEM photograph of
alum.
Fig.3.TG/DTA curves for alum.
a magnetic stirrer.After ?ltering,the precipitate was dried at 40?C in an oven.The dried precipitate was identi?ed as alum by XRD (Fig.1).To improve the purity of the alum by dissolution–precipitation,the alum was put into 0.1M sul-furic acid solution (solid loading:50wt.%)under magnetic stirring and completely dissolved by holding at 50–60?C for 6h.During the cooling cycle to room temperature,
the
Fig.4.XRD patterns for the materials obtained by (a)conventional and (b)microwave heating of alum.
168H.C.Park et al./Materials Science and Engineering A 367(2004)166–170
formation of a re-precipitate phase could be seen with the naked eye.The dissolution–precipitation then repeated of three times enabling a relatively pure alum to be produced.
The ?nal precipitate of alum was calcined at 1000–1200?C for 1h both by microwave and conventional heating.Since the alum itself does not readily absorb microwave energy,the microwave hybrid heating method,which involves covering the sample crucible with SiC which absorbs mi-crowave energy effectively,was chosen.The temperature in the microwave heating system was measured using a stainless,shielded K-type thermocouple and controlled au-tomatically through feedback control from a programmable controller.
The thermal behavior and minor components of the alum were examined by means of TG/DTA and ICP,respectively.The crystalline phase and microstructure were characterized using XRD and SEM.The particle size distribution was determined by a laser scattering technique.Speci?c surface area was measured using the nitrogen adsorption and the standard BET
equation.
Fig.5.SEM photographs of (a and c)?-Al 2O 3and (b and d)?-Al 2O 3obtained by conventional (a and b)and microwave (c and d)heating of alum.
3.Results and discussion
The peaks of the XRD patterns of obtained from the pre-cipitate coincided well with those of ammonium aluminum sulfate hydrate (JCPDS 18-0079)(Fig.1).From the im-purity content (ppm 5.76Fe,20.56Na,11.70K,8.04Mg,29.53Ca)measured by ICP,the purity of the synthesized alum was con?rmed to be >99.9%.The thermal behavior of the alum,consisting of nearly spherically-shape particles in the size range 100–200?m (Fig.2)was investigated (Fig.3).In the DTA curve,several endothermic peaks were observed:a large peak was present at <100?C due to the melting of the alum (melting point:93.5?C),a series of peaks at temperatures in the range 100–400?C were consid-ered to be due to dehydration,peaks at ～490and ～630?C are due to the breakdown of the ammonium sulfate,and a peak at 780?C is thought to be due to the decomposition of aluminum sulfate.Concurrently in the TGA curve,the weight loss of ～44.3%due to dehydration occurred during heating to ～400?C.By converting the measured weight loss into the equivalent amount of bonded water of alum,this
H.C.Park et al./Materials Science and Engineering A 367(2004)166–170169
corresponds to the 21hydrate.On further heating to ～890?C,an additional weight loss of about 43%due to the decomposition of anhydrous alum occurred.
To identify the decomposition product obtained by heat-ing the alum,XRD analysis was carried out (Fig.4).After calcination at 400?C,the NH 4Al(SO 4)2peaks appeared,re-sulting from the completion of the dehydration reaction.At 800?C,following the decomposition and release of ammo-nium sulphate,crystalline Al 2(SO 4)3was identi?ed.After applying a conventional heating process,the noncrystalline “transition”alumina (?-Al 2O 3)[1,2]was formed at 1000?C which itself transformed to ?-Al 2O 3at 1100?C while in a microwave heating environment,the transformation temper-ature was as high as ～100?C.It is assumed that this higher transition temperature in a microwave heating system is pos-sibly due to the superheating effect of microwave resulting in insuf?cient time for transition.
The microstructures of ?-and ?-Al 2O 3powders obtained by the conventional (1000and 1100?C)and microwave heating (1100and 1200?C)are shown in Fig.5.The ?-Al 2O 3was agglomerated and consisted of nanosized pri-mary particles (Fig.5a and c )in the form of a convoluted dendritic structure.The ?-Al 2O 3exhibited the agglomer-ated microstructure,being interconnected with relatively homogeneous particles each 0.1–0.5?m in size and con-taining ?ne (<0.05?m)intra-granular pores (Fig.5b and d ),which are considered to have been formed during particle growth through the densi?cation and coalescence process of initial particles.Microwave heating has thus contributed to the decreased size of the Al 2O 3particles.
The agglomerate particle size distribution of ?-Al 2O 3is shown in Fig.6.Independent of heating source,the agglom-erated particles showed a bimodal particle size distribution and were mainly concentrated on ～0.3and ～40?m range of size.In the SEM microstructures of ?-Al 2O 3(Fig.5b and d ),the microwave heating appears to produce a highly dense agglomerated structure when compared with con-ventional heating.However,the results of the particle size analysis show that more ?ne particles (<1?m)are
formed
Fig.6.Agglomerated particle size distribution of synthesized ?-Al 2O 3.
by microwave heating.Since an ultrasonic treatment was done prior to the particle size measurement,this observa-tion infers that the agglomerate strength of the particles obtained by microwave heating is weaker.The speci?c sur-face area (S BET )of Al 2O 3powder obtained by microwave heating was 150at 1000?C,125at 1100?C and 21m 2/g at 1200?C clearly somewhat higher than the 80,12and 8m 2/g obtained at corresponding temperatures by conven-tional heating.The S BET value remarkably decreased with transformation of the ?to ?phase.However,further stud-ies will be necessary to de?ne how the microwave hybrid heating source contributes the ?neness of alumina particles obtained from the decomposition of alum.
4.Conclusions
High purity alum (>99.9%)was precipitated by the reac-tion of NH 4Al(SO 4)2leach liquor derived from coal ?y ash and 28wt.%ammonia in water at a pH of 1followed by the application of the dissolution–precipitation process.Af-ter microwave and conventional heating,the noncrystalline “transition”?-Al 2O 3was ?rst formed at 1000?C by de-composition of the alum.It then transformed to ?-Al 2O 3at 1200?C during microwave heating,the transformation temperature difference was as high as ～100?C,when com-pared with conventional heating.The ?-Al 2O 3consisted of agglomerated nanosized primary particles having relatively high speci?c surface area (150–80m 2/g)and the transforma-tion to ?-Al 2O 3gave a coarsened microstructure,made up of relatively homogeneous particles (0.1–0.5?m)and ?ne intra-granular pores (<0.05?m).The use of microwaving heating contributes to a decreased size of both the primary and agglomerated Al 2O 3particles.Acknowledgements
This study was supported ?nancially by the Korea En-ergy Management Corporation (Project number:2002-C-CC03-P01).
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The way 的用法 Ⅰ常见用法： 1)the way+ that 2)the way + in which（最为正式的用法） 3)the way + 省略（最为自然的用法） 举例：I like the way in which he talks. I like the way that he talks. I like the way he talks. Ⅱ习惯用法： 在当代美国英语中，the way用作为副词的对格，“the way+ 从句”实际上相当于一个状语从句来修饰整个句子。 1)The way =as I am talking to you just the way I’d talk to my own child. He did not do it the way his friends did. Most fruits are naturally sweet and we can eat them just the way they are—all we have to do is to clean and peel them. 2）The way= according to the way/ judging from the way The way you answer the question, you are an excellent student. The way most people look at you, you’d think trash man is a monster. 3）The way =how/ how much No one can imagine the way he missed her. 4）The way =because
The way的用法及其含义（二） 二、the way在句中的语法作用 the way在句中可以作主语、宾语或表语： 1.作主语 The way you are doing it is completely crazy.你这个干法简直发疯。 The way she puts on that accent really irritates me. 她故意操那种口音的样子实在令我恼火。The way she behaved towards him was utterly ruthless. 她对待他真是无情至极。 Words are important, but the way a person stands, folds his or her arms or moves his or her hands can also give us information about his or her feelings. 言语固然重要,但人的站姿,抱臂的方式和手势也回告诉我们他(她)的情感。 2.作宾语 I hate the way she stared at me.我讨厌她盯我看的样子。 We like the way that her hair hangs down.我们喜欢她的头发笔直地垂下来。 You could tell she was foreign by the way she was dressed. 从她的穿著就可以看出她是外国人。 She could not hide her amusement at the way he was dancing. 她见他跳舞的姿势，忍俊不禁。 3.作表语 This is the way the accident happened.这就是事故如何发生的。 Believe it or not, that's the way it is. 信不信由你, 反正事情就是这样。 That's the way I look at it, too. 我也是这么想。 That was the way minority nationalities were treated in old China. 那就是少数民族在旧中
定冠词the的用法： 定冠词the与指示代词this ,that同源,有“那(这)个”的意思,但较弱,可以和一个名词连用,来表示某个或某些特定的人或东西. (1)特指双方都明白的人或物 Take the medicine.把药吃了. (2)上文提到过的人或事 He bought a house.他买了幢房子. I've been to the house.我去过那幢房子. (3)指世界上独一无二的事物 the sun ,the sky ,the moon, the earth (4)单数名词连用表示一类事物 the dollar 美元 the fox 狐狸 或与形容词或分词连用,表示一类人 the rich 富人 the living 生者 (5)用在序数词和形容词最高级,及形容词等前面 Where do you live?你住在哪? I live on the second floor.我住在二楼. That's the very thing I've been looking for.那正是我要找的东西. (6)与复数名词连用,指整个群体 They are the teachers of this school.(指全体教师) They are teachers of this school.(指部分教师) (7)表示所有,相当于物主代词,用在表示身体部位的名词前 She caught me by the arm.她抓住了我的手臂. (8)用在某些有普通名词构成的国家名称,机关团体,阶级等专有名词前 the People's Republic of China 中华人民共和国 the United States 美国 (9)用在表示乐器的名词前 She plays the piano.她会弹钢琴. (10)用在姓氏的复数名词之前,表示一家人 the Greens 格林一家人(或格林夫妇) (11)用在惯用语中 in the day, in the morning... the day before yesterday, the next morning... in the sky... in the dark... in the end... on the whole, by the way...
“tｈｅwａｙ+从句”结构的意义及用法 首先让我们来看下面这个句子: Ｒead the foｌloｗｉnｇpassagｅａnd talkａbout ｉt wi ｔh your classmaｔes．Try tｏｔeｌl whaｔyｏu thiｎk ｏf Tom aｎd ｏｆｔhe ｗay the chiｌｄrenｔrｅated ｈim. 在这个句子中，ｔhe waｙ是先行词,后面是省略了关系副词that或in whｉch的定语从句。 下面我们将叙述“the ｗaｙ+从句”结构的用法。 1.tｈe wａy之后，引导定语从句的关系词是tｈat而不是hoｗ,因此，<<现代英语惯用法词典＞＞中所给出的下面两个句子是错误的：Ｔhｉs is ｔｈeｗayｈowｉtｈａppened. This is the way how he ａlwａｙs treats me. 2．在正式语体中,thaｔ可被in which所代替;在非正式语体中，ｔhat则往往省略。由此我们得到theｗay后接定语从句时的三种模式：1) tｈe ｗaｙ＋ｔhａt-从句２）the way +ｉn whiｃh－从句3) the ｗay +从句 例如：Ｔｈe way(in whiｃh ，thａt) ｔhｅｓｅｃomｒade ｓloｏｋａｔｐrobｌems is wrong．这些同志看问题的方法
不对。 Ｔｈｅｗａy(that ,ｉn ｗhiｃh)yoｕ’ｒe doinｇit is comple ｔeｌy crａzy.你这么个干法,简直发疯。 Wｅａdmiｒｅd him for thｅｗay ｉｎｗhｉch he fａｃeｓdiｆficultieｓ． Waｌlａｃe ａｎd Ｄarwiｎｇreed ｏn the way ｉｎwhi ｃh ｄｉfｆｅrｅnt forms ｏf life had ｂegｕn.华莱士和达尔文对不同类型的生物是如何起源的持相同的观点。 Thｉs is ｔｈe ｗaｙ（tｈａｔ) hｅdｉd it. I lｉkeｄｔhe waｙ(ｔhat) ｓｈeｏｒganized ｔhe ｍeetｉng． 3.theｗay(tｈat)有时可以与hｏw(作“如何”解）通用。例如： That’s tｈe ｗaｙ(tｈaｔ) shｅspoke. = Tｈat’s how shｅspoke.
表示“方式”、“方法”，注意以下用法： 1.表示用某种方法或按某种方式，通常用介词in(此介词有时可省略)。如： Do it (in) your own way. 按你自己的方法做吧。 Please do not talk (in) that way. 请不要那样说。 2.表示做某事的方式或方法，其后可接不定式或of doing sth。 如： It’s the best way of studying [to study] English. 这是学习英语的最好方法。 There are different ways to do [of doing] it. 做这事有不同的办法。 3.其后通常可直接跟一个定语从句(不用任何引导词)，也可跟由that 或in which 引导的定语从句，但是其后的从句不能由how 来引导。如： 我不喜欢他说话的态度。 正：I don’t like the way he spoke. 正：I don’t like the way that he spoke. 正：I don’t like the way in which he spoke. 误：I don’t like the way how he spoke. 4.注意以下各句the way 的用法： That’s the way (=how) he spoke. 那就是他说话的方式。 Nobody else loves you the way(=as) I do. 没有人像我这样爱你。 The way (=According as) you are studying now, you won’tmake much progress. 根据你现在学习情况来看，你不会有多大的进步。 2007年陕西省高考英语中有这样一道单项填空题： ——I think he is taking an active part insocial work. ——I agree with you_____. A、in a way B、on the way C、by the way D、in the way 此题答案选A。要想弄清为什么选A，而不选其他几项，则要弄清选项中含way的四个短语的不同意义和用法，下面我们就对此作一归纳和小结。 一、in a way的用法 表示：在一定程度上，从某方面说。如： In a way he was right.在某种程度上他是对的。注：in a way也可说成in one way。 二、on the way的用法 1、表示：即将来(去)，就要来(去)。如： Spring is on the way.春天快到了。 I'd better be on my way soon.我最好还是快点儿走。 Radio forecasts said a sixth-grade wind was on the way.无线电预报说将有六级大风。 2、表示：在路上，在行进中。如： He stopped for breakfast on the way.他中途停下吃早点。 We had some good laughs on the way.我们在路上好好笑了一阵子。 3、表示：(婴儿)尚未出生。如： She has two children with another one on the way.她有两个孩子，现在还怀着一个。 She's got five children，and another one is on the way.她已经有5个孩子了，另一个又快生了。 三、by the way的用法
The way的用法及其含义（一） 有这样一个句子：In 1770 the room was completed the way she wanted. 1770年，这间琥珀屋按照她的要求完成了。 the way在句中的语法作用是什么？其意义如何？在阅读时，学生经常会碰到一些含有the way 的句子，如：No one knows the way he invented the machine. He did not do the experiment the way his teacher told him.等等。他们对the way 的用法和含义比较模糊。在这几个句子中，the way之后的部分都是定语从句。第一句的意思是，“没人知道他是怎样发明这台机器的。”the way的意思相当于how；第二句的意思是，“他没有按照老师说的那样做实验。”the way 的意思相当于as。在In 1770 the room was completed the way she wanted.这句话中，the way也是as的含义。随着现代英语的发展，the way的用法已越来越普遍了。下面，我们从the way的语法作用和意义等方面做一考查和分析： 一、the way作先行词，后接定语从句 以下3种表达都是正确的。例如：“我喜欢她笑的样子。” 1. the way+ in which +从句 I like the way in which she smiles. 2. the way+ that +从句 I like the way that she smiles. 3. the way + 从句(省略了in which或that) I like the way she smiles. 又如：“火灾如何发生的，有好几种说法。” 1. There were several theories about the way in which the fire started. 2. There were several theories about the way that the fire started.
way 的用法 【语境展示】 1. Now I’ll show you how to do the experiment in a different way. 下面我来演示如何用一种不同的方法做这个实验。 2. The teacher had a strange way to make his classes lively and interesting. 这位老师有种奇怪的办法让他的课生动有趣。 3. Can you tell me the best way of working out this problem? 你能告诉我算出这道题的最好方法吗？ 4. I don’t know the way (that / in which) he helped her out. 我不知道他用什么方法帮助她摆脱困境的。 5. The way (that / which) he talked about to solve the problem was difficult to understand. 他所谈到的解决这个问题的方法难以理解。 6. I don’t like the way that / which is being widely used for saving water. 我不喜欢这种正在被广泛使用的节水方法。 7. They did not do it the way we do now. 他们以前的做法和我们现在不一样。 【归纳总结】 ●way作“方法，方式”讲时，如表示“以……方式”，前面常加介词in。如例1； ●way作“方法，方式”讲时，其后可接不定式to do sth.，也可接of doing sth. 作定语，表示做某事的方法。如例2，例3；
t h e-w a y-的用法
The way 的用法 "the way+从句"结构在英语教科书中出现的频率较高, the way 是先行词, 其后是定语从句.它有三种表达形式:1) the way+that 2)the way+ in which 3)the way + 从句(省略了that或in which),在通常情况下, 用in which 引导的定语从句最为正式,用that的次之,而省略了关系代词that 或 in which 的, 反而显得更自然,最为常用.如下面三句话所示,其意义相同. I like the way in which he talks. I like the way that he talks. I like the way he talks. 一.在当代美国英语中,the way用作为副词的对格,"the way+从句"实际上相当于一个状语从句来修饰全句. the way=as 1)I'm talking to you just the way I'd talk to a boy of my own. 我和你说话就象和自己孩子说话一样. 2)He did not do it the way his friend did. 他没有象他朋友那样去做此事. 3)Most fruits are naturally sweet and we can eat them just the way they are ----all we have to do is clean or peel them . 大部分水果天然甜润,可以直接食用,我们只需要把他们清洗一下或去皮.
way的用法总结大全 way的用法你知道多少，今天给大家带来way的用法，希望能够帮助到大家，下面就和大家分享，来欣赏一下吧。 way的用法总结大全 way的意思 n. 道路,方法,方向,某方面 adv. 远远地，大大地 way用法 way可以用作名词 way的基本意思是“路,道,街,径”,一般用来指具体的“路,道路”,也可指通向某地的“方向”“路线”或做某事所采用的手段,即“方式,方法”。way还可指“习俗,作风”“距离”“附近,周围”“某方面”等。 way作“方法,方式,手段”解时,前面常加介词in。如果way前有this, that等限定词,介词可省略,但如果放在句首,介词则不可省略。
way作“方式,方法”解时,其后可接of v -ing或to- v 作定语,也可接定语从句,引导从句的关系代词或关系副词常可省略。 way用作名词的用法例句 I am on my way to the grocery store.我正在去杂货店的路上。 We lost the way in the dark.我们在黑夜中迷路了。 He asked me the way to London.他问我去伦敦的路。 way可以用作副词 way用作副词时意思是“远远地,大大地”,通常指在程度或距离上有一定的差距。 way back表示“很久以前”。 way用作副词的用法例句 It seems like Im always way too busy with work.我工作总是太忙了。 His ideas were way ahead of his time.他的思想远远超越了他那个时代。 She finished the race way ahead of the other runners.她第一个跑到终点,远远领先于其他选手。 way用法例句
t h e_w a y的用法大全
The way 在the way+从句中, the way 是先行词, 其后是定语从句.它有三种表达形式:1) the way+that 2)the way+ in which 3)the way + 从句(省略了that或in which),在通常情况下, 用in which 引导的定语从句最为正式,用that的次之,而省略了关系代词that 或 in which 的, 反而显得更自然,最为常用.如下面三句话所示,其意义相同. I like the way in which he talks. I like the way that he talks. I like the way he talks. 如果怕弄混淆，下面的可以不看了 另外，在当代美国英语中,the way用作为副词的对格,"the way+从句"实际上相当于一个状语从句来修饰全句. the way=as 1)I'm talking to you just the way I'd talk to a boy of my own. 我和你说话就象和自己孩子说话一样. 2)He did not do it the way his friend did. 他没有象他朋友那样去做此事. 3)Most fruits are naturally sweet and we can eat them just the way they are ----all we have to do is clean or peel them . 大部分水果天然甜润,可以直接食用,我们只需要把他们清洗一下或去皮. the way=according to the way/judging from the way 4)The way you answer the qquestions, you must be an excellent student. 从你回答就知道,你是一个优秀的学生. 5)The way most people look at you, you'd think a trashman was a monster. 从大多数人看你的目光中,你就知道垃圾工在他们眼里是怪物. the way=how/how much 6)I know where you are from by the way you pronounce my name. 从你叫我名字的音调中,我知道你哪里人. 7)No one can imaine the way he misses her. 人们很想想象他是多么想念她. the way=because 8) No wonder that girls looks down upon me, the way you encourage her. 难怪那姑娘看不起我, 原来是你怂恿的
The way 的用法 "the way+从句"结构在英语教科书中出现的频率较高, the way 是先行词, 其后是定语从句.它有三种表达形式:1) the way+that 2)the way+ in which 3)the way + 从句(省略了that或in which),在通常情况下, 用in which 引导的定语从句最为正式,用that的次之,而省略了关系代词that 或in which 的, 反而显得更自然,最为常用.如下面三句话所示,其意义相同. I like the way in which he talks. I like the way that he talks. I like the way he talks. 一.在当代美国英语中,the way用作为副词的对格,"the way+从句"实际上相当于一个状语从句来修饰全句. the way=as 1)I'm talking to you just the way I'd talk to a boy of my own. 我和你说话就象和自己孩子说话一样. 2)He did not do it the way his friend did. 他没有象他朋友那样去做此事. 3)Most fruits are naturally sweet and we can eat them just the way they are ----all we have to do is clean or peel them . 大部分水果天然甜润,可以直接食用,我们只需要把他们清洗一下或去皮.
the way=according to the way/judging from the way 4)The way you answer the qquestions, you must be an excellent student. 从你回答就知道,你是一个优秀的学生. 5)The way most people look at you, you'd think a trashman was a monster. 从大多数人看你的目光中,你就知道垃圾工在他们眼里是怪物. the way=how/how much 6)I know where you are from by the way you pronounce my name. 从你叫我名字的音调中,我知道你哪里人. 7)No one can imaine the way he misses her. 人们很想想象他是多么想念她. the way=because 8) No wonder that girls looks down upon me, the way you encourage her. 难怪那姑娘看不起我, 原来是你怂恿的 the way =while/when(表示对比) 9)From that day on, they walked into the classroom carrying defeat on their shoulders the way other students carried textbooks under their arms. 从那天起,其他同学是夹着书本来上课,而他们却带着"失败"的思想负担来上课.
The way的用法及其含义（三） 三、the way的语义 1. the way=as（像） Please do it the way I’ve told you.请按照我告诉你的那样做。 I'm talking to you just the way I'd talk to a boy of my own.我和你说话就像和自己孩子说话一样。 Plant need water the way they need sun light. 植物需要水就像它们需要阳光一样。 2. the way=how（怎样，多么） No one can imagine the way he misses her.没人能够想象出他是多么想念她！ I want to find out the way a volcano has formed.我想弄清楚火山是怎样形成的。 He was filled with anger at the way he had been treated.他因遭受如此待遇而怒火满腔。That’s the way she speaks.她就是那样讲话的。 3. the way=according as （根据） The way you answer the questions, you must be an excellent student.从你回答问题来看，你一定是名优秀的学生。 The way most people look at you, you'd think a trash man was a monster.从大多数人看你的目光中,你就知道垃圾工在他们眼里是怪物。 The way I look at it, it’s not what you do that matters so much.依我看，重要的并不是你做什么。 I might have been his son the way he talked.根据他说话的样子，好像我是他的儿子一样。One would think these men owned the earth the way they behave.他们这样行动，人家竟会以为他们是地球的主人。
一．Way：“方式”、“方法” 1.表示用某种方法或按某种方式 Do it (in) your own way. Please do not talk (in) that way. 2.表示做某事的方式或方法 It’s the best way of studying [to study] English.。 There are different ways to do [of doing] it. 3.其后通常可直接跟一个定语从句(不用任何引导词)，也可跟由that 或in which 引导的定语从句 正：I don’t like the way he spoke. I don’t like the way that he spoke. I don’t like the way in which he spoke.误：I don’t like the way how he spoke. 4. the way 的从句 That’s the way (=how) he spoke. I know where you are from by the way you pronounce my name. That was the way minority nationalities were treated in old China. Nobody else loves you the way(=as) I do. He did not do it the way his friend did. 二．固定搭配 1. In a/one way：In a way he was right. 2. In the way /get in one’s way I'm afraid your car is in the way， If you are not going to help，at least don't get in the way. You'll have to move－you're in my way. 3. in no way Theory can in no way be separated from practice. 4. On the way (to……) Let’s wait a few moments. He is on the way Spring is on the way. Radio forecasts said a sixth-grade wind was on the way. She has two children with another one on the way. 5. By the way By the way，do you know where Mary lives? 6. By way of Learn English by way of watching US TV series. 8. under way 1. Elbow one’s way He elbowed his way to the front of the queue. 2. shoulder one’s way 3. feel one‘s way 摸索着向前走；We couldn’t see anything in the cave, so we had to feel our way out 4. fight/force one’s way 突破。。。而前进The surrounded soldiers fought their way out. 5.. push/thrust one‘s way（在人群中）挤出一条路He pushed his way through the crowd. 6. wind one’s way 蜿蜒前进 7. lead the way 带路，领路；示范 8. lose one‘s way 迷失方向 9. clear the way 排除障碍，开路迷路 10. make one’s way 前进，行进The team slowly made their way through the jungle.
在the way+从句中, the way 是先行词, 其后是定语从句.它有三种表达形式:1) the way+that 2)the way+ in which 3)the way + 从句(省略了that或in which),在通常情况下, 用in which 引导的定语从句最为正式,用that的次之,而省略了关系代词that 或in which 的, 反而显得更自然,最为常用.如下面三句话所示,其意义相同. I like the way in which he talks. I like the way that he talks. I like the way he talks. 如果怕弄混淆，下面的可以不看了 另外，在当代美国英语中,the way用作为副词的对格,"the way+从句"实际上相当于一个状语从句来修饰全句. the way=as 1)I'm talking to you just the way I'd talk to a boy of my own. 我和你说话就象和自己孩子说话一样. 2)He did not do it the way his friend did. 他没有象他朋友那样去做此事. 3)Most fruits are naturally sweet and we can eat them just the way they are ----all we have to do is clean or peel them . 大部分水果天然甜润,可以直接食用,我们只需要把他们清洗一下或去皮. the way=according to the way/judging from the way 4)The way you answer the qquestions, you must be an excellent student. 从你回答就知道,你是一个优秀的学生. 5)The way most people look at you, you'd think a trashman was a monster. 从大多数人看你的目光中,你就知道垃圾工在他们眼里是怪物. the way=how/how much 6)I know where you are from by the way you pronounce my name. 从你叫我名字的音调中,我知道你哪里人. 7)No one can imaine the way he misses her. 人们很想想象他是多么想念她. the way=because 8) No wonder that girls looks down upon me, the way you encourage her. 难怪那姑娘看不起我, 原来是你怂恿的 the way =while/when(表示对比) 9)From that day on, they walked into the classroom carrying defeat on their shoulders the way other students carried textbooks under their arms.
“the way+从句”结构的意义及用法 首先让我们来看下面这个句子： Read the following passage and talk about it with your classmates. Try to tell what you think of Tom and of the way the children treated him. 在这个句子中，the way是先行词，后面是省略了关系副词that 或in which的定语从句。 下面我们将叙述“the way+从句”结构的用法。 1．the way之后，引导定语从句的关系词是that而不是how,因此，<<现代英语惯用法词典>>中所给出的下面两个句子是错误的：This is the way how it happened. This is the way how he always treats me. 2. 在正式语体中，that可被in which所代替；在非正式语体中，that则往往省略。由此我们得到the way后接定语从句时的三种模式：1) the way +that-从句2) the way +in which-从句3) the way +从句 例如：The way(in which ,that) these comrades look at problems is wrong.这些同志看问题的方法不对。
The way(that ,in which)you’re doing it is completely crazy.你这么个干法，简直发疯。 We admired him for the way in which he faces difficulties. Wallace and Darwin greed on the way in which different forms of life had begun.华莱士和达尔文对不同类型的生物是如何起源的持相同的观点。 This is the way (that) he did it. I liked the way (that) she organized the meeting. 3.the way(that)有时可以与how(作“如何”解)通用。例如： That’s the way (that) she spoke. = That’s how she spoke. I should like to know the way/how you learned to master the fundamental technique within so short a time. 4．the way的其它用法：以上我们讲的都是用作先行词的the way，下面我们将叙述它的一些用法。
定冠词the的12种用法 定冠词the 的12 种用法，全知道?快来一起学习吧。下面就和大家分享，来欣赏一下吧。 定冠词the 的12 种用法，全知道? 定冠词the用在各种名词前面，目的是对这个名词做个记号，表示它的特指属性。所以在词汇表中，定冠词the 的词义是“这个，那个，这些，那些”，可见，the 即可以放在可数名词前，也可以修饰不可数名词，the 后面的名词可以是单数，也可以是复数。 定冠词的基本用法： (1) 表示对某人、某物进行特指，所谓的特指就是“不是别的，就是那个!”如： The girl with a red cap is Susan. 戴了个红帽子的女孩是苏珊。 (2) 一旦用到the，表示谈话的俩人都知道说的谁、说的啥。如：
The dog is sick. 狗狗病了。(双方都知道是哪一只狗) (3) 前面提到过的，后文又提到。如： There is a cat in the tree.Thecat is black. 树上有一只猫，猫是黑色的。 (4) 表示世界上唯一的事物。如： The Great Wall is a wonder.万里长城是个奇迹。(5) 方位名词前。如： thenorth of the Yangtze River 长江以北地区 (6) 在序数词和形容词最高级的前面。如： Who is the first?谁第一个? Sam is the tallest.山姆最高。 但是不能认为，最高级前必须加the，如： My best friend. 我最好的朋友。 (7) 在乐器前。如： play the flute 吹笛子
Way用法 A:I think you should phone Jenny and say sorry to her. B:_______. It was her fault. A. No way B. Not possible C. No chance D. Not at all 说明：正确答案是A. No way，意思是“别想！没门！决不！” 我认为你应该打电话给珍妮并向她道歉。 没门！这是她的错。 再看两个关于no way的例句： （1）Give up our tea break? NO way! 让我们放弃喝茶的休息时间？没门儿！ （2）No way will I go on working for that boss. 我决不再给那个老板干了。 way一词含义丰富，由它构成的短语用法也很灵活。为了便于同学们掌握和用好它，现结合实例将其用法归纳如下： 一、way的含义 1. 路线
He asked me the way to London. 他问我去伦敦的路。 We had to pick our way along the muddy track. 我们不得不在泥泞的小道上择路而行。 2. （沿某）方向 Look this way, please. 请往这边看。 Kindly step this way, ladies and gentlemen. 女士们、先生们，请这边走。 Look both ways before crossing the road. 过马路前向两边看一看。 Make sure that the sign is right way up. 一定要把符号的上下弄对。 3. 道、路、街，常用以构成复合词 a highway（公路），a waterway（水路），a railway（铁路），wayside（路边）
way/time的特殊用法 1、当先行词是way意思为”方式.方法”的时候,引导定语从句的关系词有下列3种形式： Way在从句中做宾语 The way that / which he explained to us is quite simple. Way在从句中做状语 The way t hat /in which he explained the sentence to us is quite simple. 2、当先行词是time时,若time表示次数时,应用关系代词that引导定语从句,that可以省略; 若time表示”一段时间”讲时,应用关系副词when或介词at/during + which引导定语从句 1.Is this factory _______ we visited last year? 2.Is this the factory-------we visited last year? A. where B in which C the one D which 3. This is the last time _________ I shall give you a lesson. A. when B that C which D in which 4.I don’t like the way ________ you laugh at her. A . that B on which C which D as 5.He didn’t understand the wa y ________ I worked out the problem. A which B in which C where D what 6.I could hardly remember how many times----I’ve failed. A that B which C in which D when 7.This is the second time--------the president has visited the country. A which B where C that D in which 8.This was at a time------there were no televisions, no computers or radios. A what B when C which D that