上海磐合117种化合物测试报告
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上海磐合117种化合物测试报告【仪器配置】常规实验室四级杆气相色谱-质谱联用仪(配FID检测器)热脱附:Markes Ultra+Unity xr+Kori xr+CIA-advantage【测试物质】:117种化合物(PAMs、TO15及醛酮类化合物)【测试方法】:电子制冷+Deanswitch中心切割【实验部分】:1、Markes热脱附条件(软件版本2.0中文版)Kori冷阱低温:-25℃;高温:300℃Unity冷阱低温:-30℃;高温:300℃升温速率:MAX分流流量:10mL/min2、GC/MS条件1)柱温程序Rate Value Hold Time Run time35°C10min10min6°C/min240°C0min44.167min20°C/min270°C 5.4min51.067min 2)GC-FID分析条件FID温度:300℃空气流量:400mL/min氢气流量:40mL/min尾吹气流量:25mL/min载气控制方式:恒流进样方式:直接进样接口温度:150℃3)质谱条件70eV,采集方式:Scan和SIM3、测试结果3.1117种化合物出峰情况图1117种化合物色谱图(上图:TIC色谱图,下图:FID色谱图)3.2其他各物质线性、检出限、稳定性线性R2≥0.987(标准要求,R2≥0.98)检出限:甲醛=0.51ppb;其他化合物≤0.22ppb序列化合物名称保留时间(min)单位线性R2RSD(%)检出限ppb1乙烷11.805ppb0.996 5.970.09 2乙烯10.722ppb0.996 6.320.09 3丙烷18.459ppb0.998 6.600.11 4丙烯17.928ppb 1.00011.560.19 5乙炔11.307ppb0.9998 3.930.06(min)(%)ppb 6甲醛8.471ppb0.995 5.010.517异丁烷12.381ppb0.996 3.510.068正丁烯15.901ppb0.999 4.220.079正丁烷14.393ppb0.990 6.150.0910反-2-丁烯13.818ppb 1.000 4.740.0711乙醛14.389ppb 1.000 3.820.0612顺-2-丁烯14.987ppb0.999 4.680.0713异戊烷18.865ppb0.999 4.980.08141-戊烯20.051ppb0.999 5.850.1015正戊烷20.771ppb0.999 4.220.0716反-2-戊烯21.185ppb0.9997.970.1421.119ppb 1.00013.950.18 172-甲基1,3-丁二烯18顺-2-戊烯21.713ppb0.99910.520.15192,2-二甲基丁烷23.103ppb 1.0008.710.16202,3-二甲基丁烷24.975ppb 1.0007.390.14212-甲基戊烷23.103ppb 1.000 6.400.1222环戊烷24.984ppb 1.00012.700.20233-甲基戊烷25.835ppb0.9977.310.22241-己烯26.662ppb0.99911.830.19252,4-二甲基戊烷28.489ppb0.9987.460.12262,3-二甲基戊烷30.592ppb0.997 5.230.08272,2,4-三甲基戊31.612ppb0.991 4.930.08烷(min)(%)ppb 28甲基环戊烷28.506ppb0.9979.230.1529二氟二氯甲烷9.927ppb0.9897.110.11301,1,2,2-四氟-1,2-12.165ppb0.994 4.320.07二氯乙烷31一氯甲烷11.403ppb 1.000 3.340.0532氯乙烯13.101ppb0.999 4.490.0733丁二烯14.032ppb 1.000 6.900.1134一溴甲烷15.697ppb0.999 4.750.0835氯乙烷16.547ppb0.991 5.400.0936一氟三氯甲烷19.702ppb0.9899.080.1537乙醇16.746ppb0.999 3.700.0638丙烯醛18.439ppb0.994 6.940.1239丙醛19.073ppb0.9997.420.13401,2,2-三氟-1,1,2-22.553ppb0.9997.660.13三氯乙烷411,1-二氯乙烯21.699ppb0.99910.010.1642丙酮18.865ppb0.999 4.650.0743异丙醇19.532ppb 1.000 6.220.1044二硫化碳23.15ppb0.99911.710.2145二氯甲烷21.926ppb 1.00010.310.1846甲基叔丁基醚24.652ppb 1.0008.460.1447顺1,2-二氯乙烯26.425ppb0.99913.680.1848正己烷26.66ppb0.998 3.650.0649乙酸乙烯酯24.961ppb 1.000 5.770.10(min)(%)ppb 501,1-二氯乙烷24.738ppb 1.000 6.770.1151正丁醛23.116ppb0.9987.210.1252乙酸乙酯26.399ppb 1.0008.910.17532-丁酮25.322ppb0.9959.080.1754反1,2-二氯乙烯24.263ppb0.99811.820.1755三氯甲烷26.991ppb0.99814.700.2156四氢呋喃27.772ppb0.999 6.520.12571,2-二氯乙烷28.673ppb0.990 6.460.1158甲基丙烯醛28.506ppb0.9907.040.12592-甲基庚烷34.513ppb0.990 6.830.10603-甲基庚烷34.89ppb0.9917.220.1234.255ppb0.99110.290.19 612,3,4-三甲基戊烷62丁烯醛33.318ppb0.991 5.920.0963甲基环己烷33.322ppb0.99013.340.18642-甲基己烷30.12ppb 1.0009.460.18653-甲基己烷30.594ppb0.9929.300.16661,1,1-三氯乙烷28.974ppb0.9939.290.1667环己烷30.384ppb0.997 6.970.1268四氯化碳30.119ppb0.993 6.940.1269苯29.835ppb0.998 5.080.0970正庚烷31.611ppb0.9928.090.1471三氯乙烯31.538ppb0.991 6.930.12(min)(%)ppb 72戊醛32.692ppb0.9887.420.1373甲基丙烯酸甲酯31.326ppb0.9938.850.17741,2-二氯丙烷31.19ppb0.992 6.900.12751,4-二氧六环31.379ppb 1.0008.280.1376一溴二氯甲烷31.518ppb0.99012.020.1777反式-1,3-二氯-1-33.678ppb0.99215.170.19丙烯784-甲基-2-戊酮32.688ppb0.993 2.710.0479甲苯34.72ppb0.994 6.540.1132.879ppb0.9918.250.14 80顺式-1,3-二氯-1-丙烯811,1,2-三氯乙烷34.182ppb0.990 3.500.05822-己酮32.692ppb0.9887.100.1383己醛34.889ppb0.98710.440.1884二溴一氯甲烷35.657ppb0.9899.410.1385正辛烷35.849ppb0.9957.220.1286四氯乙烯36.807ppb0.99814.100.20871,2-二溴乙烷36.151ppb 1.000 6.860.1188氯苯38.1ppb 1.0008.510.1489乙苯38.584ppb0.9957.440.1390间、对-二甲苯38.862ppb0.9959.990.1991苯乙烯39.624ppb0.9917.180.1292邻二甲苯39.872ppb0.9957.880.1493三溴甲烷39.505ppb0.995 6.980.10(min)(%)ppb 94四氯乙烷39.857ppb0.995 3.830.0695苯甲醛41.904ppb 1.000 4.780.0896氯代甲苯43.411ppb0.987 4.320.0797正壬烷39.607ppb0.98911.010.1998异丙苯40.941ppb0.999 6.060.1099正丙苯42.008ppb0.998 4.240.07100癸烷43.008ppb0.996 4.700.071011-乙基-3-甲基苯42.15ppb 1.000 3.840.061021-乙基-2-甲基苯42.963ppb 1.000 3.480.06103对-乙基甲苯42.276ppb 1.000 5.280.091041,3,5-三甲苯42.276ppb 1.0007.120.11105对二氯苯44.232ppb0.999 3.430.061061,2,4-三甲苯43.411ppb 1.000 6.310.101071,2,3-三甲苯44.55ppb0.999 5.200.081081,3-二氯苯44.096ppb0.989 4.430.07109邻二氯苯45.132ppb0.999 5.490.081101,3-二乙基苯45.011ppb0.990 5.080.08111对二乙苯45.269ppb0.999 6.190.10112十一烷46.022ppb0.999 4.420.07113十二烷48.76ppb0.998 6.140.10114间甲基苯甲醛45.268ppb0.995 4.410.071151,2,4-三氯苯49.519ppb 1.00012.720.22(min)(%)ppb 116六氯丁二烯50.669ppb0.995 4.150.07117萘50.009ppb 1.000 4.000.07备注:。