防腐剂物料安全数据表(MSDS)

ORANGE VINYL ESTER TOPCOATSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsRevision date: 12/31/201912/31/2019 EN (English US) Page 1 1.1. IdentificationProduct form : MixtureTrade name : ORANGE VINYL ESTER TOPCOATCAS-No. : mixtureProduct code : 1908-045Formula : na1.2. Recommended use and restrictions on useUse of the substance/mixture : COATING1.3. SupplierDura Technologies, Inc.2720 South Willow Avenue #ABloomington, CA 92316909-546-1162ChemTrec US: 800.424.9300ChemTrec Int: +1 70 3527 38871.4. Emergency telephone numberEmergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 38872.1. Classification of the substance or mixtureGHS US classificationFlammable liquids Category 3 H226 Flammable liquid and vapourSkin corrosion/irritation Category 2 H315 Causes skin irritationSerious eye damage/eye irritation Category 2 H319 Causes serious eye irritationSkin sensitization, Category 1 H317 May cause an allergic skin reactionReproductive toxicity Category 2 H361 Suspected of damaging fertility or the unborn childSpecific target organ toxicity (single exposure) Category 3 H335 May cause respiratory irritationSpecific target organ toxicity (repeated exposure) Category 1 H372 Causes damage to organs through prolonged or repeated exposure Hazardous to the aquatic environment - Acute Hazard Category 2 H401 Toxic to aquatic lifeFull text of H statements : see section 162.2. GHS Label elements, including precautionary statementsGHS US labelingHazard pictograms (GHS US):Signal word (GHS US) : DangerHazard statements (GHS US) : H226 - Flammable liquid and vapourH315 - Causes skin irritationH317 - May cause an allergic skin reactionH319 - Causes serious eye irritationH335 - May cause respiratory irritationH361 - Suspected of damaging fertility or the unborn childH372 - Causes damage to organs through prolonged or repeated exposureH401 - Toxic to aquatic lifePrecautionary statements (GHS US) : P201 - Obtain special instructions before use.P202 - Do not handle until all safety precautions have been read and understood.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P233 - Keep container tightly closed.P240 - Ground/Bond container and receiving equipmentP241 - Use explosion-proof electrical, lighting, ventilating equipmentP242 - Use only non-sparking tools.P243 - Take precautionary measures against static discharge.P260 - Do not breathe dust, mist, fume, spray, vapors.P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.P264 - Wash EXPOSED AREA. thoroughly after handling.P270 - Do not eat, drink or smoke when using this product.P271 - Use only outdoors or in a well-ventilated area.P272 - Contaminated work clothing must not be allowed out of the workplaceP273 - Avoid release to the environment.P280 - Wear eye protection, protective clothing, protective gloves.P302+P352 - If on skin: Wash with plenty of waterP303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinseskin with water/showerP304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathingP305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsingP308+P313 - If exposed or concerned: Get medical advice/attention.P312 - Call a poison center or doctor if you feel unwellP314 - Get medical advice/attention if you feel unwell.P321 - Specific treatment (see none llisted on this label)P332+P313 - If skin irritation occurs: Get medical advice/attention.P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.P337+P313 - If eye irritation persists: Get medical advice/attention.P362+P364 - Take off contaminated clothing and wash it before reuse.P363 - Wash contaminated clothing before reuse.P370+P378 - In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam toextinguish.P403+P233 - Store in a well-ventilated place. Keep container tightly closed.P403+P235 - Store in a well-ventilated place. Keep cool.P405 - Store locked up.P501 - Dispose of contents/container to in accordance with local.state, and nationalregulations.2.3. Other hazards which do not result in classificationNo additional information available2.4. Unknown acute toxicity (GHS US)Not applicable3.1. SubstancesNot applicable3.2. MixturesFull text of hazard classes and H-statements : see section 16SECTION 4: First-aid measures4.1. Description of first aid measuresFirst-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IFexposed or concerned: Get medical advice/attention.First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person tobreathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in aposition comfortable for breathing. Call a POISON CENTER or doctor/physician if you feelunwell.First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Washwith plenty of soap and water. Wash contaminated clothing before reuse. If skin irritationoccurs: Get medical advice/attention. Specific treatment (see supplemental first aid instructionon this label).First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing. If eye irritation persists: Get medical advice/attention.First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poisoncenter/doctor/physician if you feel unwell.4.2. Most important symptoms and effects (acute and delayed)Potential Adverse human health effects and: Harmful if inhaled.symptomsSymptoms/effects : May cause genetic defects. Suspected of damaging fertility or the unborn child. Causesdamage to organs.Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful ifinhaled.Symptoms/effects after skin contact : Causes skin irritation.Symptoms/effects after eye contact : Causes serious eye irritation.4.3. Immediate medical attention and special treatment, if necessaryTreat symptomatically.5.1. Suitable (and unsuitable) extinguishing mediaSuitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.Unsuitable extinguishing media : Do not use a heavy water stream.5.2. Specific hazards arising from the chemicalFire hazard : Flammable liquid and vapour.Explosion hazard : May form flammable/explosive vapor-air mixture.Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.5.3. Special protective equipment and precautions for fire-fightersFirefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting anychemical fire. Prevent fire-fighting water from entering environment.Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Donot attempt to take action without suitable protective equipment. Self-contained breathingapparatus. Complete protective clothing.6.1. Personal precautions, protective equipment and emergency proceduresGeneral measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. Nosmoking.6.1.1. For non-emergency personnelProtective equipment : Gloves. Protective goggles. Protective clothing.Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.6.1.2. For emergency respondersProtective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew withproper protection. For further information refer to section 8: "Exposure controls/personalprotection".Emergency procedures : Ventilate area.6.2. Environmental precautionsAvoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.6.3. Methods and material for containment and cleaning upFor containment : Dam up the liquid spill. Contain released product, pump into suitable containers.Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay ordiatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site.6.4. Reference to other sectionsSee Heading 8. Exposure controls and personal protection. For further information refer to section 13.7.1. Precautions for safe handlingAdditional hazards when processed : Handle empty containers with care because residual vapors are flammable.Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap andwater before eating, drinking or smoking and when leaving work. Provide good ventilation inprocess area to prevent formation of vapor. No open flames. No smoking. Take precautionarymeasures against static discharge. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special instructionsbefore use. Do not handle until all safety precautions have been read and understood.Eliminate all ignition sources if safe to do so.Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke whenusing this product. Always wash hands after handling the product.7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bondcontainer and receiving equipment. Use explosion-proof electrical/ventilating/lightingequipment.Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep containertightly closed. Store in a well-ventilated place. Keep cool.Incompatible products : Strong bases. Strong acids.Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.8.1. Control parameters8.2. Appropriate engineering controlsAppropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure goodventilation of the work station.Environmental exposure controls : Avoid release to the environment.8.3. Individual protection measures/Personal protective equipmentPersonal protective equipment:Avoid all unnecessary exposure.Hand protection:Wear protective gloves.Eye protection:Chemical goggles or safety glasses. Safety glassesSkin and body protection:Wear suitable protective clothingRespiratory protection:Wear appropriate maskOther information:Do not eat, drink or smoke during use.9.1. Information on basic physical and chemical propertiesPhysical state : LiquidColor : orangeOdor : characteristicOdor threshold : No data availablepH : No data availableMelting point : Not applicableFreezing point : No data availableBoiling point : 146.1 (≥ 64) °CFlash point : 30 - 34 °CRelative evaporation rate (butyl acetate=1) : No data availableFlammability (solid, gas) : Flammable liquid and vapour.Vapor pressure : No data availableRelative vapor density at 20 °C : No data availableRelative density : ≥ 1.1Specific gravity / density : 9 g/lSolubility : No data availableLog Pow : No data availableAuto-ignition temperature : No data availableDecomposition temperature : No data availableViscosity, kinematic : No data availableViscosity, dynamic : No data availableExplosion limits : No data availableExplosive properties : No data availableOxidizing properties : No data available9.2. Other informationNo additional information availableSECTION 10: Stability and reactivity10.1. ReactivityNo reactivity hazard other than the effects described in sub-sections below.10.2. Chemical stabilityPolymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. May form flammable/explosive vapor-air mixture.10.3. Possibility of hazardous reactionsNot established.10.4. Conditions to avoidDirect sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.10.5. Incompatible materialsStrong acids. Strong bases.10.6. Hazardous decomposition productsfume. Carbon monoxide. Carbon dioxide. May release flammable gases.SECTION 11: Toxicological information11.1. Information on toxicological effectsAcute toxicity (oral) : Not classifiedAcute toxicity (dermal) : Not classifiedAcute toxicity (inhalation) : Not classifiedSkin corrosion/irritation : Causes skin irritation.Serious eye damage/irritation : Causes serious eye irritation.Respiratory or skin sensitization : May cause an allergic skin reaction.Germ cell mutagenicity : Not classifiedCarcinogenicity : Not classified.Reproductive toxicity : Suspected of damaging fertility or the unborn child.STOT-single exposure : May cause respiratory irritation.STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.Aspiration hazard : Not classifiedViscosity, kinematic : No data availablePotential Adverse human health effects and: Harmful if inhaled.symptomsSymptoms/effects : May cause genetic defects. Suspected of damaging fertility or the unborn child. Causesdamage to organs.Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful ifinhaled.Symptoms/effects after skin contact : Causes skin irritation.Symptoms/effects after eye contact : Causes serious eye irritation.SECTION 12: Ecological information12.1. ToxicityEcology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverseeffects in the environment.12.3. Bioaccumulative potential12.4. Mobility in soil12.5. Other adverse effectsOther information : Avoid release to the environment.SECTION 13: Disposal considerations13.1. Disposal methodsWaste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose ofcontents/container to hazardous or special waste collection point, in accordance with local,regional, national and/or international regulation.Additional information : Handle empty containers with care because residual vapors are flammable.Ecology - waste materials : Avoid release to the environment.Department of Transportation (DOT)In accordance with DOTTransport document description : UN1866 Resin solution, 3, IIIUN-No.(DOT) : UN1866Proper Shipping Name (DOT) : Resin solutionClass (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) : III - Minor DangerHazard labels (DOT) : 3 - Flammable liquidDOT Packaging Non Bulk (49 CFR 173.xxx) : 173DOT Packaging Bulk (49 CFR 173.xxx) : 242DOT Special Provisions (49 CFR 172.102) : B1 - If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then thebulk packaging requirements of 173.241 of this subchapter are applicable. If the material has aflash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of thissubchapter are applicable.B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressurerelief devices are authorized on DOT 57 portable tanks.IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquidswith a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table2 for UN2672).T2 - 1.5 178.274(d)(2) Normal............. 178.275(d)(3)TP1 - The maximum degree of filling must not exceed the degree of filling determined by thefollowing: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperatureduring transport, and tf is the temperature in degrees celsius of the liquid during filling.DOT Packaging Exceptions (49 CFR 173.xxx) : 150: 60 LDOT Quantity Limitations Passenger aircraft/rail(49 CFR 173.27): 220 LDOT Quantity Limitations Cargo aircraft only (49CFR 175.75)DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on apassenger vessel.Emergency Response Guide (ERG) Number : 127Other information : No supplementary information available.Transportation of Dangerous GoodsNot applicableTransport by seaTransport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IMDG) : 1866Proper Shipping Name (IMDG) : RESIN SOLUTIONClass (IMDG) : 3 - Flammable liquidsPacking group (IMDG) : III - substances presenting low dangerAir transportTransport document description (IATA) : UN 1866 Resin solution, 3, III UN-No. (IATA) : 1866Proper Shipping Name (IATA) : Resin solutionClass (IATA) : 3 - Flammable LiquidsPacking group (IATA) : III - Minor Danger15.1. US Federal regulations15.2. International regulationsCANADAEU-RegulationsNo additional information availableNational regulations15.3. US State regulationsSECTION 16: Other informationaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsRevision date : 12/31/2019Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THECOUNCIL of 16 December 2008 on classification, labeling and packaging of substances andmixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amendingRegulation (EC) No 1907/2006.Other information : None.NFPA health hazard : 2 - Materials that, under emergency conditions, can causetemporary incapacitation or residual injury.NFPA fire hazard : 3 - Liquids and solids (including finely divided suspendedsolids) that can be ignited under almost all ambienttemperature conditions.NFPA reactivity : 2 - Materials that readily undergo violent chemical changeat elevated temperatures and pressures.Hazard RatingHealth : 2 Moderate Hazard - Temporary or minor injury may occurFlammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperatureconditions. Includes flammable liquids with flash points below 73 F and boiling points above100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at hightemperatures and pressures. Materials may react non-violently with water or undergohazardous polymerization in the absence of inhibitors.Personal protection : HH - Splash goggles, Gloves, Synthetic apron, Vapor respiratorSDS US (GHS HazCom 2012)To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.。

药品安全资料(MSDS)—文本资料什么是MSDS？MSDS即为Material Safety Data Sheet（材料安全数据表），是指药品生产厂家为确保产品安全，向用户提供的一种说明书，以便用户了解药品的危险性和安全使用方法。

MSDS是药品的重要资料，至关重要，具有防止人员伤害，保护环境以及法律方面的作用。

MSDS的内容MSDS主要包括以下内容：1.产品和制造商信息包括药品的中文名称及产品标志、生产厂家、联系地址和电话号码等，以方便用户了解药品的生产厂家，以及在生产过程中可能存在的问题。

2.成分/配方信息包括药品的性质、化学成分、危险性等信息。

在药品使用的过程中，需要了解药品的成分和化学性质，以及各成分可能带来的安全风险。

3.产品物理特性包括药品的形状、颜色、气味、密度、熔点、沸点等特征。

了解药品的物理特性，有助于有效保障药品的安全使用。

4.对人体的影响包括药品的健康危害、对人体的影响、接触方式等。

这一部分内容对于医务人员、科研人员、药品销售人员等非常重要，以便避免药品带来的身体危害。

5.操作注意事项包括药品的存储、使用、运输等操作注意事项。

通过了解这些注意事项，可以有效保障药品的安全操作，防止药品出现意外，保护人员和环境的安全。

6.危险特性包括药品存在的危险性，如易燃、易爆等危险特性。

了解药品可能存在的危险性，有助于采取相应的措施以降低药品的风险。

7.急救措施包括针对药品的急救措施，如吸入、皮肤接触、眼睛接触、口服等异常情况的处理方法。

这一部分内容对于医务人员和药品使用者格外重要，以便在遇到意外时及时采取措施。

MSDS的重要性MSDS是药品的重要资料，其重要性体现在以下三个方面：1.保障人员安全药品作为化学品，其使用过程中会产生许多对人体有害的物质，必须严格控制使用过程中可能造成的危险，防止对人员生命和身体造成影响。

2.保护环境药品的使用对环境的影响非常大，包括水、土壤、大气等多种方面，不仅会对环境造成损害，还会对人间健康造成威胁。

P UENSOMESB1UEOI30/40原料安全数据表1.产品及公司信息原料商品名：P UENSOMESB1UEOI30/40INCI名称：乳糖：纤维素；羟丙基甲基纤维素；霍霍巴酯类：CI77∞7,生育酚乙酸酯,抗坏血酸棕桐酸酯用途：化妆品用原料生产商：电话：传真：紧急联系方式：电话:2.组成成分CTFA/INC1•名称乳糖纤维素羟丙基甲基纤维素霍霍巴酯类CI77007生育酚乙酸酯抗坏血酸棕梅］酸酯CAS号E1NECS号组分比例（％）63-42-3 200-559-2 50-909004-34-6 232-674-9 5~509004-65-3 - 1-1061789-91-1 - 0.1-41317-97-1 235-811-0 0.1-47695-91-2 231-7IO-O 0.1-1137-66-6 205-305-4 0.1-13.危害性对人和环境的重要危害：该原料是一种化妆品用成分，正确使用的情况下不会对人或者环境造成危害。

4.急救措施吸入：接触皮肤：移开暴露场所，如仍有症状，请及时就医。

用肥皂和水清洗。

接触眼睛：即刻用水冲洗15分钟以上。

服食：漱口并及时就医。

5.防火措施有效的灭火介质：喷水，泡沫灭火，干粉灭火，二氧化碳灭火.无效灭火介质无特殊危害：无.特殊保护设备：可使用自带呼吸设备。

6.意外泄露处理人员注意事项：无需特殊防护。

环境注意事项： 清洗方法：7.运输和储存运输建议：空容器可能有危险。

因为空的容器内可能有产品残留，因此所有的注意事项都需继续注意。

运输和储存过程中尽量避免容器的损伤. 存储条件：用前要保持容器关闭。

为保证产品质量，请于避光避热条件下存放.8.抛弃方法/人员防护技术保护措施：无.工作场所成分控制： 无.人员防护设备： 手套和防护眼镜.安全卫生措施：需遵循运输和储存的注意事项，安全规范操作.9.物理参数和化学参数形态： 硬质颗粒 色泽： 蓝色气味： 无味焙点 N∕A oC 沸点 N∕A o C 密度：N/Ag∕m 3(20℃) 溶解性20。

材料安全数据表(MSDS)产品名称： 二氟甲烷；Difluoromethane化 学名称： 二氟甲烷分子式：CH 2F 2 代名称： Halocarbon-32， 亚甲基氟化 物生产商： Air Products and Chemical, Inc.7201 Hamilton BoulevardAllentown,PA 18195-1501产品信息： (800)752-1597MSDS 号码：1307修订次数：1 复审日期：1999年10月修订日期：1999年10月CH 2F 2 纯度> 99%CAS 号码: 75-10-5暴露极限:OSHA :未建立 ACGIH: 简单的窒息剂 NIOSH ：未建立紧急情况综述二氟甲烷是一种易燃、无色、 无嗅的液化压缩 气体。

它储存在钢瓶中，其存储压力 为其蒸汽压--206.3psig(70 F ) 。

当它与空气混 合且浓度大于>14%时,立即就会 有火 灾及爆炸的危险。

高浓度的二氟甲烷会 导致快速窒息同时也在其燃烧范围内。

不要进入 这样的区域。

接触它可能会 造成冻伤。

紧急情况联系电话0532－388 9090急性潜在健康影响暴露途径眼睛接触：接触其液体(或 快 速扩散的气体)会 引起刺激和冻伤。

摄入：摄入不可能成为接触二氟甲烷的途径。

吸入：它能置换出空气中的氧气从而 引起窒息。

暴露在氧气含量<19.5%的大气中会 导致头晕、昏昏欲睡、恶心、呕吐、口水增多、反应迟钝、失去意识和死亡。

暴露在氧气含量<12％ 的大气中 会 无任何先兆的失去知觉，并失去自我救护 的能力。

吸入高浓度的二氟甲烷会 引起轻度的中枢神经系统抑制及心率不齐(心率失常)。

皮肤接触：接触其液体(或 快 速扩散的气体)会 引起刺激和冻伤。

多次暴露潜在健康影响：侵入路径：皮肤接触症状：长时间多次接触可能引起皮炎。

损害器官：心脏，中枢神经系统，皮肤过份暴露造成的病情恶化：以前患有心脏病及中枢神经系统紊乱的人会 对过份 暴露的影响更加敏感。

助滤剂CN No 81513具腐蚀性，避免潮湿危险性泄漏处理∙具腐蚀性∙使用装有高效微粒空气吸尘器的真空吸尘器清理灰尘∙∙戴防毒面具∙受高热放出有毒的腐蚀性气体∙采取抑尘措施，如用水喷淋∙∙急救储运要求使用装有高效微粒空气吸尘器的真空吸尘器清理灰尘，采取抑尘措施，如用水喷淋∙库房阴凉、通风∙∙库房干燥无异味∙脱离污染环境至空气新鲜处∙防止阳光曝晒∙误服后，喝蛋清或牛奶∙搬运时注意个人防护∙∙就医∙灭火方法∙轻装轻卸，防止破损∙雾状水、火场周围可用的介质防护措施警告硫酸铜CN No 61519警告毒害，避免接触危险性泄漏处理∙毒害∙戴防毒面具和手套∙具刺激性∙避免接触泄漏物∙对血液、肝、肾有损害作用∙用大量水冲洗，洗水入废水处理系统∙受高热产生有毒的烟气∙大量泄漏，回收或无害处理后废弃急救储运要求∙脱去污染衣着，用清水洗污染部位∙储于阴凉、干燥、通风处∙脱离污染环境至空气新鲜处∙包装密封，切勿受潮∙误服后，洗胃∙应与酸（碱）类、潮湿物品等分储∙就医∙轻装轻卸，防止破损∙搬运时注意个人防护灭火方法∙不燃防护措施重铬酸钾CN No 51520危险强氧化性，毒害，避免接触有机物，还原剂危险性泄漏处理∙具强氧化性∙隔离，设警示牌∙具较强的腐蚀性∙戴防毒面具，穿化学防护服∙与还原剂、有机物、易燃物接触能引∙避免泄漏物接触可燃物∙起燃烧和爆炸∙用大量水冲洗，洗水入废水处理系统∙毒害，引起肝、肾损害，致癌∙大量泄漏，回收或无害处理后废弃急救储运要求∙脱去污染衣着，用清水洗污染部位∙储于阴凉、干燥、通风处∙脱离污染环境至空气新鲜处，必要时∙远离火种、热源，保持容器密封∙输氧或人工呼吸∙应与易（可）燃物、还原剂、硫、磷∙误服后，喝蛋清或牛奶∙等分储∙就医∙搬运时注意个人防护灭火方法∙轻装轻卸，防止破损∙雾状水、砂土防护措施氨CN No 23003毒害，易燃易爆，强刺激性，避免接触危险性泄漏处理∙毒害∙撤离现场无关人员，切断火源∙具强烈刺激性∙戴呼吸器，穿特定化学防护服∙与空气混合有燃烧爆炸的危险∙切断气源∙与卤素发生剧烈反应∙高浓度泄漏时，喷含盐酸的雾状水∙强力通风急救储运要求∙脱去污染衣着，用清水洗污染部位∙储存于阴凉、干燥、通风处∙脱离污染环境至空气新鲜处，必要时∙应与卤素（氟、氯、溴）酸类等分储∙输氧或人工呼吸∙禁止使用易产生火花的工具∙就医∙灌装适量，不可超压超量灭火方法∙按运输路线行驶，中途勿停∙雾状水、二氧化碳、泡沫切断气源，喷水冷却容器防护措施MSDS表编号：006UN No 1789盐酸危险CN No 81013危险强腐蚀性，避免接触金属、氰化物危险性泄漏处理∙具腐蚀性∙撤离现场无关人员∙与金属反应，放出氢气∙戴防毒面具，穿化学防护服∙遇氰化物产生剧毒的气体∙禁止直接喷水∙用砂土、干石灰等混合，收集处理∙大量泄漏，围堤收容处理急救储运要求∙脱去污染衣着，用清水洗污染部位∙储存于阴凉、干燥、通风处∙脱离污染环境至空气新鲜处∙应与碱类、金属粉末、卤素（氟、氯∙误服后，喝蛋清或牛奶∙溴）易（可）燃物等分储∙就医∙搬运时注意个人防护∙轻装轻卸，防止破损灭火方法∙按规定路线运输行驶∙雾状水、砂土防护措施MSDS表编号：007UN No 1830硫酸CN No 81007危险强腐蚀性，有害，避免接触易燃物危险性泄漏处理∙强腐蚀性∙撤离现场无关人员∙毒害∙戴面罩，穿化学防护服∙接触易燃物和有机物能引起燃烧∙避免泄漏物接触可燃物∙与活性金属反应，放出氢气∙用砂土、干石灰等混合，收集处理∙大量泄漏，围堤收容处理急救储运要求∙脱去污染衣着，用清水洗污染部位∙储于阴凉、干燥、通风处∙脱离污染环境至空气新鲜处∙应与易（可）燃物、碱类、金属粉末∙如灼伤，按酸灼伤处理∙等分储∙误服后，喝蛋清或牛奶∙搬运时注意个人防护∙就医∙轻装轻卸，防止破损灭火方法∙砂土，禁止用水防护措施MSDS表编号：008UN No 1490高锰酸钾CN No 51048危险强氧化性，避免接触有机物、还原剂等危险性泄漏处理∙具强氧化性∙隔离，设警示牌∙与还原剂等混合有燃烧爆炸危险∙戴防毒面具，穿化学防护服∙遇甘油强烈燃烧∙避免泄漏物接触可燃物∙具强烈刺激性∙用砂土、干石灰等混合，收集处理∙大量泄漏，回收或无害处理后废弃急救储运要求∙脱去污染衣着，用清水洗污染部位∙库房阴凉、通风这离火种、热源∙脱离污染环境至空气新鲜处∙注意防潮∙误服后，喝蛋清或牛奶∙应与易（可）燃物、还原剂、硫、∙就医∙磷等分储灭火方法∙轻装轻卸，防止破损∙雾状水、砂土防护措施MSDS表编号：009UN No 1823氢氧化钠CN No 82001危险强腐蚀性，避免受潮危险性泄漏处理∙具强腐蚀性∙隔离，设警示牌∙戴防毒面具，穿化学防护服∙避免接触泄漏物∙收集后移至大量水中，中和∙大量泄漏，回收或无害处理后废弃急救储运要求∙脱去污染衣着，用清水洗污染部位∙库房高燥，清洁∙脱离污染环境至空气新鲜处∙注意防潮∙误服后，喝蛋清或牛奶∙应与易（可）燃物、酸（碱）类分储∙就医∙搬运时注意个人防护∙轻装轻卸，防止破损灭火方法∙雨天不宜运输∙雾状水、砂土防护措施MSDS表编号：010UN No 1170乙醇（无水）CN No 32061警告易燃易爆，有害，避免接触明火高热氧化剂危险性泄漏处理∙蒸气与空气混合有燃烧爆炸的危险∙撤离现场无关人员∙与氧化剂发生剧裂反应∙切断火源∙蒸气能扩散到远处，遇明火引着回燃∙戴防毒面具和手套∙对人体有害∙用大量水冲洗，洗水入废水处理系统∙损害肝、心、神经系统∙大量泄漏，围堤收容处理储运要求急救∙库房阴凉、通风∙脱离污染环境至空气新鲜处∙远离火种、热源∙就医∙应与氧化剂分储∙仓间内照明等设施应防爆∙禁止使用易产生火花的工具灭火方法∙控制充装流速，防止静电积聚∙泡沫、二氧化碳、干粉、砂土防护措施MSDS表编号：011UN No 2693汽油（闪点＜-18℃）CN No 81510危险易燃，避免接触高热、空气、氧化剂危险性泄漏处理∙极易燃烧∙撤离现场无关人员，切断火源∙蒸气与空气形成爆炸性混合物∙戴呼吸器，穿消防防护服∙遇明火、高热或接触强氧化剂有燃烧∙用砂土等惰性材料吸收，收集处理∙爆炸的危险∙大量泄漏，围堤收集处理∙有刺激和麻醉作用急救储运要求∙脱去污染衣着，用清水和肥皂水冲洗∙库房阴凉、通风∙脱离污染环境至空气新鲜处，必要时∙远离火种、热源输氧或人工呼吸∙应与氧化剂隔离贮运∙误服后，喝蛋清或牛奶∙禁止使用易产生火花的工具∙就医∙控制充装流速，防止静电职聚灭火方法∙轻装轻卸，防止破损∙泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：012UN No 1645硫酸汞CN No 61509危险高毒，避免接触明火、高热及水危险性泄漏处理∙高毒∙隔离，设警示牌∙损害中枢神经系统、肝、肾等、∙戴呼吸器，穿化学防护服∙遇明火、高热产生有毒的烟气∙避免接触泄漏物∙遇水引起分解∙用砂土等混合，收集处理急救储运要求∙脱去污染衣着，用清水和肥皂水冲洗∙库房阴凉、通风∙脱离污染环境至空气新鲜处∙远离火种、热源∙误服后，喝蛋清或牛奶∙应与食用化工原料等分储∙就医∙应与酸（碱）类分储∙搬运时注意个人防护灭火方法∙轻装轻卸，防止破损∙水防护措施MSDS表编号：013UN No 1493硝酸银CN No 51063危险具氧化性，高毒，避免接触有机物，还原剂危险性泄漏处理∙具氧化性∙隔离，设警示牌∙与还原剂、有机物、易燃物混合形成∙戴防毒面具，穿化学防护服爆炸性混合物∙避免接触泄漏物∙急剧加热可发生爆炸∙用大量水冲洗，洗水入废水处理系统∙高毒∙大量泄漏，收集回收∙具强烈刺激性急救储运要求∙脱去污染衣着，用清水洗污染部位∙库房高燥，清洁，远离火种，热源∙脱离污染环境至空气新鲜处∙避免光照∙误服后，喝蛋清或牛奶∙包装密封，切勿受潮∙就医∙应与易（可）燃物、还原剂、硫、潮湿品等分储灭火方法∙搬运时注意个人防护∙雾状水、砂土防护措施MSDS表编号：014柴油危险易燃，避免接触明火、高热、氧化剂危险性泄漏处理∙极易燃烧∙撤离现场无关人员，切断火源∙蒸气与空气形成爆炸性混合物∙戴呼吸器，穿消防防护服∙遇明火、高热或接触强氧化剂有燃烧∙用砂土等惰性材料吸收，收集处理∙爆炸的危险∙大量泄漏，围堤收集处理∙有刺激和麻醉作用急救储运要求∙脱去污染衣着，用清水和肥皂水冲洗∙库房阴凉、通风∙脱离污染环境至空气新鲜处，必要时∙远离火种、热源输氧或人工呼吸∙应与氧化剂隔离贮运∙误服后，喝蛋清或牛奶∙禁止使用易产生火花的工具∙就医∙控制充装流速，防止静电职聚灭火方法∙轻装轻卸，防止破损∙泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：015UN No 1267重油CN No 32003危险易燃，避免接触明火、高热、氧化剂危险性泄漏处理∙极易燃烧∙撤离现场无关人员，切断火源∙蒸气与空气形成爆炸性混合物∙戴呼吸器，穿消防防护服∙遇明火、高热、氧化剂可能燃烧爆炸∙用砂土等惰性材料吸收，收集处理∙大量泄漏，围堤收集处理急救储运要求∙脱去污染衣着，用清水和肥皂水冲洗∙库房阴凉、通风∙脱离污染环境至空气新鲜处，必要时∙远离火种、热源输氧或人工呼吸∙应与氧化剂隔离贮运∙误服后，喝蛋清或牛奶∙禁止使用易产生火花的工具∙就医∙仓库内照明等设施应防爆灭火方法∙轻装轻卸，防止破损∙泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：016UN No氯水CN No危险高毒，强刺激性，避免接触明火、高热、氧化剂危险性泄漏处理∙高毒∙撤离现场无关人员，切断气源∙具强刺激性∙戴呼吸器，穿特定化学防护服∙在阳光下与易燃气体混合会发生暴∙不要与松节油等接触∙强力通风急救储运要求∙脱去污染衣着，用清水和肥皂水冲洗∙库房阴凉、通风，仓温<30度（C)∙脱离污染环境至空气新鲜处，必要时∙远离火种、热源输氧或人工呼吸∙应与易（可〕燃物、金属粉末等分贮∙轻装轻卸，防止破损∙就医∙按规定路线运输行驶灭火方法∙不要在居民和人口稠密处停留∙不燃防护措施MSDS表编号：017UN No 迭氮化钠(NaN3)CN No危险有毒，避免接触明火、高热、氧化剂 .酸 .重金属危险性泄漏处理∙第6.1类毒害品∙撤离现场无关人员，切断火源∙受热.接触明火.或受到磨擦.震动时可发生爆炸∙戴呼吸器，穿消防防护服,不要直接触泄漏物∙∙少量泄漏,:避免扬尘,用铲收集处理∙大量泄漏，用塑料布覆盖,然后收集处理急救储运要求∙脱去污染衣着，用清水和肥皂水冲洗∙库房阴凉、通风∙脱离污染环境至空气新鲜处，必要时∙远离火种、热源输氧或人工呼吸∙应与氧化剂,酸金属粉末隔离贮运∙误服后，喝蛋清或牛奶∙禁止使用易产生火花的工具∙就医∙仓库内照明等设施应防爆灭火方法∙轻装轻卸，防止震动及容器破损∙泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：018UN No硝酸CN No危险强腐蚀性，有害，避免接触易燃物和强烈震动危险性泄漏处理∙强腐蚀性∙撤离现场无关人员∙毒害∙戴面罩，穿化学防护服∙接触易燃物和有机物能引起燃烧∙避免泄漏物接触可燃物∙与活性金属反应，放出氢气∙用砂土、干石灰等混合，收集处理∙与甘油接触会引起暴炸∙大量泄漏，围堤收容处理急救储运要求灭火方法防护措施MSDS表编号：019UN N0 P3-Luboklar XT链条润滑剂CN N0避免与亚硝酸盐物质混合。

危险性类别：无资料
侵入途径：吸入、食入、经皮吸收。

健康危害：吸入后对鼻、喉和呼吸道有刺激性。

对眼有强烈刺激作用。

皮肤接触轻者出现红斑重者引起化学灼伤。

误服浓乙酸口腔和消化道可产生糜烂重者可因休克而致死。

环境危害：对环境有危害
燃爆危险：本品不燃
危险特性：其蒸气与空气形成爆炸性混合物遇明火、高热能引起燃烧爆炸。

与强氧化剂可发生反应。

有害燃烧产物：一氧化碳、二氧化碳
灭火方法及灭火剂：本品不燃。

根据着火原因选择适当灭火剂灭火。

灭火注意事项：消防人员必须全身穿防火防毒服，在上风方向灭火。

尽可能将容器从火场移至空旷处。

编号：002MSDS表UN No 1773助滤剂CN No 81513警告具腐蚀性，避免潮湿危险性泄漏处理使用装有高效微粒空气吸尘器的真空吸尘器具腐蚀性清理灰尘戴防毒面具受高热放出有毒的腐蚀性气体采取抑尘措施，如用水喷淋实用文档急救储运要求库房阴凉、通风库房干燥无异味脱离污染环境至空气新鲜处防止阳光曝晒误服后，喝蛋清或牛奶搬运时注意个人防护就医灭火方法轻装轻卸，防止破损雾状水、火场周围可用的介质防护措施实用文档MSDS表编号：003UN No硫酸铜CN No 61519警告毒害，避免接触危险性泄漏处理毒害戴防毒面具和手套具刺激性避免接触泄漏物对血液、肝、肾有损害作用用大量水冲洗，洗水入废水处理系统受高热产生有毒的烟气大量泄漏，回收或无害处理后废弃急救实用文档储运要求脱去污染衣着，用清水洗污染部位储于阴凉、干燥、通风处脱离污染环境至空气新鲜处包装密封，切勿受潮误服后，洗胃应与酸（碱）类、潮湿物品等分储就医轻装轻卸，防止破损搬运时注意个人防护灭火方法不燃防护措施MSDS表编号：004UN No重铬酸钾CN No 51520实用文档危险强氧化性，毒害，避免接触有机物，还原剂危险性泄漏处理具强氧化性隔离，设警示牌具较强的腐蚀性戴防毒面具，穿化学防护服与还原剂、有机物、易燃物接触能引避免泄漏物接触可燃物起燃烧和爆炸用大量水冲洗，洗水入废水处理系统毒害，引起肝、肾损害，致癌大量泄漏，回收或无害处理后废弃急救储运要求脱去污染衣着，用清水洗污染部位储于阴凉、干燥、通风处脱离污染环境至空气新鲜处，必要时远离火种、热源，保持容器密封输氧或人工呼吸实用文档应与易（可）燃物、还原剂、硫、磷误服后，喝蛋清或牛奶等分储就医搬运时注意个人防护灭火方法轻装轻卸，防止破损雾状水、砂土防护措施MSDS表编号：005UN No 1005氨CN No 23003危险毒害，易燃易爆，强刺激性，避免接触危险性泄漏处理实用文档毒害撤离现场无关人员，切断火源具强烈刺激性戴呼吸器，穿特定化学防护服与空气混合有燃烧爆炸的危险切断气源与卤素发生剧烈反应高浓度泄漏时，喷含盐酸的雾状水强力通风脱去污染衣着，用清水洗污染部位储存于阴凉、干燥、通风处脱离污染环境至空气新鲜处，必要时应与卤素（氟、氯、溴）酸类等分储输氧或人工呼吸禁止使用易产生火花的工具就医灌装适量，不可超压超量雾状水、二氧化碳、泡沫按运输路线行驶，中途勿停切断气源，喷水冷却容器实用文档防护措施MSDS表编号：006UN No 1789盐酸CN No 81013危险强腐蚀性，避免接触金属、氰化物危险性泄漏处理具腐蚀性撤离现场无关人员与金属反应，放出氢气戴防毒面具，穿化学防护服遇氰化物产生剧毒的气体禁止直接喷水用砂土、干石灰等混合，收集处理实用文档大量泄漏，围堤收容处理急救储运要求脱去污染衣着，用清水洗污染部位储存于阴凉、干燥、通风处脱离污染环境至空气新鲜处应与碱类、金属粉末、卤素（氟、氯误服后，喝蛋清或牛奶溴）易（可）燃物等分储就医搬运时注意个人防护轻装轻卸，防止破损灭火方法按规定路线运输行驶雾状水、砂土防护措施MSDS表编号：007UN No 1830硫酸实用文档CN No 81007危险强腐蚀性，有害，避免接触易燃物危险性泄漏处理强腐蚀性撤离现场无关人员毒害戴面罩，穿化学防护服接触易燃物和有机物能引起燃烧避免泄漏物接触可燃物与活性金属反应，放出氢气用砂土、干石灰等混合，收集处理大量泄漏，围堤收容处理急救储运要求脱去污染衣着，用清水洗污染部位储于阴凉、干燥、通风处脱离污染环境至空气新鲜处实用文档应与易（可）燃物、碱类、金属粉末如灼伤，按酸灼伤处理等分储误服后，喝蛋清或牛奶搬运时注意个人防护就医轻装轻卸，防止破损灭火方法砂土，禁止用水防护措施MSDS表编号：008UN No 1490高锰酸钾CN No 51048危险实用文档具强氧化性隔离，设警示牌与还原剂等混合有燃烧爆炸危险戴防毒面具，穿化学防护服遇甘油强烈燃烧避免泄漏物接触可燃物具强烈刺激性用砂土、干石灰等混合，收集处理大量泄漏，回收或无害处理后废弃脱去污染衣着，用清水洗污染部位库房阴凉、通风这离火种、热源脱离污染环境至空气新鲜处注意防潮误服后，喝蛋清或牛奶应与易（可）燃物、还原剂、硫、就医磷等分储实用文档轻装轻卸，防止破损雾状水、砂土防护措施MSDS表编号：009UN No 1823氢氧化钠CN No 82001危险强腐蚀性，避免受潮危险性泄漏处理具强腐蚀性隔离，设警示牌戴防毒面具，穿化学防护服实用文档避免接触泄漏物收集后移至大量水中，中和大量泄漏，回收或无害处理后废弃急救储运要求脱去污染衣着，用清水洗污染部位库房高燥，清洁脱离污染环境至空气新鲜处注意防潮误服后，喝蛋清或牛奶应与易（可）燃物、酸（碱）类分储就医搬运时注意个人防护轻装轻卸，防止破损灭火方法雨天不宜运输雾状水、砂土防护措施实用文档MSDS表编号：010UN No 1170乙醇（无水）CN No 32061警告易燃易爆，有害，避免接触明火高热氧化剂危险性泄漏处理蒸气与空气混合有燃烧爆炸的危险撤离现场无关人员与氧化剂发生剧裂反应切断火源蒸气能扩散到远处，遇明火引着回燃戴防毒面具和手套对人体有害用大量水冲洗，洗水入废水处理系统损害肝、心、神经系统大量泄漏，围堤收容处理实用文档储运要求急救库房阴凉、通风脱离污染环境至空气新鲜处远离火种、热源就医应与氧化剂分储仓间内照明等设施应防爆禁止使用易产生火花的工具灭火方法控制充装流速，防止静电积聚泡沫、二氧化碳、干粉、砂土防护措施MSDS表编号：011UN No 2693汽油（闪点＜-18℃）CN No 81510实用文档危险易燃，避免接触高热、空气、氧化剂危险性泄漏处理极易燃烧撤离现场无关人员，切断火源蒸气与空气形成爆炸性混合物戴呼吸器，穿消防防护服遇明火、高热或接触强氧化剂有燃烧用砂土等惰性材料吸收，收集处理爆炸的危险大量泄漏，围堤收集处理有刺激和麻醉作用急救储运要求脱去污染衣着，用清水和肥皂水冲洗库房阴凉、通风脱离污染环境至空气新鲜处，必要时远离火种、热源输氧或人工呼吸实用文档应与氧化剂隔离贮运误服后，喝蛋清或牛奶禁止使用易产生火花的工具就医控制充装流速，防止静电职聚灭火方法轻装轻卸，防止破损泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：012UN No 1645硫酸汞CN No 61509危险高毒，避免接触明火、高热及水实用文档高毒隔离，设警示牌损害中枢神经系统、肝、肾等、戴呼吸器，穿化学防护服遇明火、高热产生有毒的烟气避免接触泄漏物遇水引起分解用砂土等混合，收集处理脱去污染衣着，用清水和肥皂水冲洗库房阴凉、通风脱离污染环境至空气新鲜处远离火种、热源误服后，喝蛋清或牛奶应与食用化工原料等分储就医应与酸（碱）类分储搬运时注意个人防护实用文档轻装轻卸，防止破损水防护措施MSDS表编号：013UN No 1493硝酸银CN No 51063危险具氧化性，高毒，避免接触有机物，还原剂危险性泄漏处理具氧化性隔离，设警示牌与还原剂、有机物、易燃物混合形成戴防毒面具，穿化学防护服爆炸性混合物避免接触泄漏物实用文档急剧加热可发生爆炸用大量水冲洗，洗水入废水处理系统高毒大量泄漏，收集回收具强烈刺激性急救储运要求脱去污染衣着，用清水洗污染部位库房高燥，清洁，远离火种，热源脱离污染环境至空气新鲜处避免光照误服后，喝蛋清或牛奶包装密封，切勿受潮就医应与易（可）燃物、还原剂、硫、潮灭火方法搬运时注意个人防护雾状水、砂土防护措施实用文档MSDS表编号：014柴油危险易燃，避免接触明火、高热、氧化剂危险性泄漏处理极易燃烧撤离现场无关人员，切断火源蒸气与空气形成爆炸性混合物戴呼吸器，穿消防防护服遇明火、高热或接触强氧化剂有燃烧用砂土等惰性材料吸收，收集处理爆炸的危险大量泄漏，围堤收集处理有刺激和麻醉作用实用文档急救储运要求脱去污染衣着，用清水和肥皂水冲洗库房阴凉、通风脱离污染环境至空气新鲜处，必要时远离火种、热源应与氧化剂隔离贮运误服后，喝蛋清或牛奶禁止使用易产生火花的工具就医控制充装流速，防止静电职聚灭火方法轻装轻卸，防止破损泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：015UN No 1267重油CN No 32003实用文档危险易燃，避免接触明火、高热、氧化剂危险性泄漏处理极易燃烧撤离现场无关人员，切断火源蒸气与空气形成爆炸性混合物戴呼吸器，穿消防防护服遇明火、高热、氧化剂可能燃烧爆炸用砂土等惰性材料吸收，收集处理大量泄漏，围堤收集处理急救储运要求脱去污染衣着，用清水和肥皂水冲洗库房阴凉、通风脱离污染环境至空气新鲜处，必要时远离火种、热源输氧或人工呼吸实用文档应与氧化剂隔离贮运误服后，喝蛋清或牛奶禁止使用易产生火花的工具就医仓库内照明等设施应防爆灭火方法轻装轻卸，防止破损泡沫、二氧化碳、干粉、砂土、1211防护措施MSDS表编号：016UN No氯水CN No危险高毒，强刺激性，避免接触明火、高热、氧化剂实用文档高毒撤离现场无关人员，切断气源具强刺激性戴呼吸器，穿特定化学防护服在阳光下与易燃气体混合会发生暴不要与松节油等接触强力通风脱去污染衣着，用清水和肥皂水冲洗库房阴凉、通风，仓温<30度（C)脱离污染环境至空气新鲜处，必要时远离火种、热源应与易（可〕燃物、金属粉末等分贮轻装轻卸，防止破损就医按规定路线运输行驶实用文档不要在居民和人口稠密处停留不燃防护措施MSDS表编号：017UN No 迭氮化钠(NaN3)CN No危险有毒，避免接触明火、高热、氧化剂 .酸 .重金属危险性泄漏处理第6.1类毒害品撤离现场无关人员，切断火源受热.接触明火.或受到磨擦.震动时可发戴呼吸器，穿消防防护服,不要直接触泄漏物实用文档少量泄漏,:避免扬尘,用铲收集处理大量泄漏，用塑料布覆盖,然后收集处理急救储运要求脱去污染衣着，用清水和肥皂水冲洗库房阴凉、通风脱离污染环境至空气新鲜处，必要时远离火种、热源应与氧化剂,酸金属粉末隔离贮运误服后，喝蛋清或牛奶禁止使用易产生火花的工具就医仓库内照明等设施应防爆灭火方法轻装轻卸，防止震动及容器破损泡沫、二氧化碳、干粉、砂土、1211防护措施实用文档MSDS表编号：018UN No硝酸CN No强腐蚀性，有害，避免接触易燃物和强烈震动危险性泄漏处理强腐蚀性撤离现场无关人员毒害戴面罩，穿化学防护服接触易燃物和有机物能引起燃烧避免泄漏物接触可燃物与活性金属反应，放出氢气与甘油接触会引起暴炸用砂土、干石灰等混合，收集处理危险实用文档大量泄漏，围堤收容处理急救储运要求脱去污染衣着，用清水洗污染部位储于阴凉、干燥、通风处脱离污染环境至空气新鲜处应与易（可）燃物、碱类、金属粉末如灼伤，按酸灼伤处理等分储误服后，喝蛋清或牛奶，就医搬运时注意个人防护灭火方法轻装轻卸，防止破损砂土，禁止用水防护措施MSDS表编号：019UN N0P3-Luboklar XT链条润滑剂CN N0实用文档清理：设障碍物阻止溢出物流动，用砂抽入容器皮肤和眼睛：引起刺激或用惰性吸收剂吸收。

化学危险品清单和安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（1 0）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂。

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMESPIRAX DELTA-REDSYNONYMSbiocide, " Delta Red"PRODUCT USEBiocide Material is mixed and used in accordance withmanufacturers directions.SUPPLIERCompany:Spirax Sarco Pty LtdAddress:72Mica StCarole ParkQLD,4300AUSTelephone:+61738794944Telephone:0414355619(JON TUBBY)Fax:0732714589HAZARD RATINGSToxicityBody ContactChronicSection 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON- DANGEROUS GOODS. According to theCriteria of NOHSC, and the ADG Code.POISONS SCHEDULENoneRISK SAFETYIrritating to respiratory system.Do not breathe gas/fumes/vapour/spray.May produce discomfort of the eyes*.Avoid contact with skin.Possible skin sensitiser*.Wear eye/face protection.*(limited evidence).To clean the floor and all objects contaminated by this material,usewater.In case of contact with eyes,rinse with plenty of water and contactDoctor or Poisons Information Centre.If swallowed,IMMEDIATELY contact Doctor or Poisons InformationCentre.(show this container or label).Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAME CAS RN% isothiazolins as,5- chloro- 2- methyl- 4- isothiazolin- 3- one26172-55-4Not spec 2- methyl- 4- isothiazolin- 3- one2682-20-4Not spec water7732-18-5>60No other ingredient information supplied.Section 4 - FIRST AID MEASURESSWALLOWED• If swallowed do NOT induce vomiting.• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and preventaspiration.EYEIf this product comes in contact with the eyes:• Immediately hold eyelids apart and flush the eye continuously with running water.• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids.SKINIf skin or hair contact occurs:• Immediately flush body and clothes with large amounts of water, using safety shower if available.• Quickly remove all contaminated clothing, including footwear.INHALED• If fumes or combustion products are inhaled remove from contaminated area.• Lay patient down. Keep warm and rested.NOTES TO PHYSICIANTreat symptomatically.Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIAWater spray or fog.FIRE FIGHTINGAlert Fire Brigade and tell them location and nature of hazard.Clear area of personnel and move upwind.• Wear full body protective clothing with breathing apparatus.• Prevent, by any means available, spillage from entering drains or water courses.Cool fire exposed containers with water spray from a protected location.If safe to do so, remove containers from path of fire.Equipment should be thoroughly decontaminated after use.FIRE/EXPLOSION HAZARD• The material is not readily combustible under normal conditions.• However, it will break down under fire conditions and the organic component may burn.Decomposition may produce toxic fumes of hydrogen chloride and minor amounts of sulfur oxides (SOx).FIRE INCOMPATIBILITYAvoid reaction with oxidising agents.HAZCHEM: NonePersonal Protective EquipmentGas tight chemical resistant suit.Limit exposure duration to 1 BA set30 mins.Section 6 - ACCIDENTAL RELEASE MEASURESEMERGENCY PROCEDURESMINOR SPILLSSmall quantities may be discharged to sewer with a large excess of water.Clean up all spills immediately.Wear impervious gloves and safety glasses.Wipe up and absorb small quantities with vermiculite or other absorbent material.Place in suitable containers for disposal.Suitable containers are those specified in storage section.MAJOR SPILLSRestrict access to area.DO NOT touch the spill material.Wear full body protective clothingIsolate leaking containers and stop leak if safe to do so.Absorb or cover spill with sand,earth,inert material or vermiculite.Collect residues and place in labelled polyethylene bag.Flood with an5%solution of sodium hypochlorite plus5%sodiumbicarbonate solution.Allow20minutes contact time.(Minimum recommendedratio of decontaminant to product is4:1).Flush to sewer with copious quantities of water.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLINGDO NOT allow clothing wet with material to stay in contact with skin.Avoid contact with skin and eyes. Use good occupational work practice.Wear personal protective equipment when handling.When handling, DO NOT eat, drink or smoke.Use in a well-ventilated area.Keep containers securely sealed when not in use.Wash hands with soap and water after handling.Work clothes should be laundered separately: NOT at home.SUITABLE CONTAINER• Polyethylene or polypropylene container.• Packing as recommended by manufacturer.STORAGE INCOMPATIBILITYAvoid storage with oxidisers and alkalies.STORAGE REQUIREMENTSObserve manufacturer's storing and handling recommendations.Store in a cool, dry and well-ventilated area.Store at temperature below 40 deg C. • Protect from heat. Keep cool.DO NOT use unlined steel containers.Keep containers securely sealed . Check regularly for spills and leaks.Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE CONTROLSThe following materials had no OELs on our record under the following CAS or Chemwatch(CW)numbers•Spirax Delta-Red:No data available for CW:8041-81•5-chloro-2-methyl-4-isothiazolin-3-one:No data available for CAS:26172-55-4•2-methyl-4-isothiazolin-3-one:No data available for CAS:2682-20-4•water:No data available for CAS:7732-18-5PERSONAL PROTECTIONSection 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEYE• Safety glasses with side shields; or as required,• Chemical goggles.HANDS/FEETWear chemical protective gloves.eg.OTHEROveralls and Rubber apron.• Ensure that there is ready access to eye wash unit.Ensure there is ready access to an emergency shower.The local concentration of material,quantity and conditions of use determine the tye of personal protective equipment required.For further information consult site specificCHEMWATCH data(if available),or yourOccupational Health and Safety Advisor.ENGINEERING CONTROLSUse in a well-ventilated area.Section 9 - PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCEPale green liquid with a mild aromatic odour;mixes with water.PHYSICAL PROPERTIESLiquid.Mixes with water.Molecular Weight:Not applicable Boiling Range(°C):100.00Melting Range(°C):Not available Specific Gravity(water=1):1.02-1.04Solubility in water(g/L):Miscible pH(as supplied):Not availablepH(1%solution):Not available Vapour Pressure(kPa):As waterVolatile Component(%vol):water content Evaporation Rate:As waterRelative Vapour Density(air=1):As water Flash Point(°C):Not applicableLower Explosive Limit(%):Not applicable Upper Explosive Limit(%):Not applicableAutoignition Temp(°C):Not applicable Decomposition Temp(°C):Not availableState:LiquidSection 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATIONCONDITIONS CONTRIBUTING TO INSTABILITYProduct is considered stable and hazardous polymerisation will not occur.Section 11 - TOXICOLOGICAL INFORMATIONPOTENTIAL HEALTH EFFECTSACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTSIrritating to respiratory system.Possible skin sensitiser*.May produce discomfort of the eyes*.*(limited evidence).*(limited evidence).Section 11 - TOXICOLOGICAL INFORMATION TOXICITY AND IRRITATIONNot available.Refer to individual constituents.unless otherwise specified data extracted from RTECS-Register of Toxic Effects of Chemical Substances5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:No significant acute toxicological data identified in literature search.Bacterial mutagenConsidered to be the major sensitiser in Kathon CG(1)(1).Bruze etal-Contact Dermatitis20:219-39,19892-METHYL-4-ISOTHIAZOLIN-3-ONE:None available.Bacterial mutagenConsidered to be a minor sensitiser in Kathon CG(1)(1).Bruze etal-Contact Dermatitis20:219-39,1989WATER:No significant acute toxicological data identified in literature search.Section 12 - ECOLOGICAL INFORMATIONNo data for Spirax Delta-Red.Refer to data for ingredients,which follows:5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:Octanol/water Coefficient=0.401(log P)Biodegradation(aquatic metabolism)half life t1/2anerobic=4.8hourshalf life t1/2aerobic=17.3hoursas mixed isothiazolinonesRainbow trout LC50(96hr)=0.19mg/L.Bluegill Sunfish LC50(96hr)=0.28mg/L.Daphnia EC50(48hr)=0.16mg/L.Algal Selenastrum EC50:0.018mg/L.2-METHYL-4-ISOTHIAZOLIN-3-ONE:Octanol/water coefficient=-0.486(log P)Biodegradation(aquatic metabolism)half life t1/2(aerobic)=9.1hoursas mixed isothiazolinonesRainbow trout LC50(96hr):=0.19mg/L.Bluegill sunfish LC50(96hr):=0.28ml/L.Daphnia EC50(48hr):=0.16mg/L.Algal(Selenastrum)EC50:0.018mg/L.Section 13 - DISPOSAL CONSIDERATIONSRecycle wherever possible. Consult manufacturer for recycling options.Consult State Land Waste Management Authority for disposal.Bury or incinerate residue at an approved site.DO NOT discharge into sewer or waterways.Recycle containers if possible, or dispose of in an authorised landfill.Section 14 - TRANSPORTATION INFORMATIONHAZCHEM:NoneNOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UNSection 15 - REGULATORY INFORMATIONPOISONS SCHEDULE: NoneREGULATIONS5-chloro-2-methyl-4-isothiazolin-3-one(CAS:26172-55-4)is found on the following regulatory lists;Australia Inventory of Chemical Substances(AICS)OECD Representative List of High Production Volume(HPV)Chemicals2-methyl-4-isothiazolin-3-one(CAS:2682-20-4)is found on the following regulatory lists;Australia Inventory of Chemical Substances(AICS)water(CAS:7732-18-5)is found on the following regulatory lists;Australia Inventory of Chemical Substances(AICS)OECD Representative List of High Production Volume(HPV)ChemicalsSection 16 - OTHER INFORMATIONDenmark Advisory list for selfclassification of dangerous substancesSubstance CAS Suggested codes5-chloro-2-methyl-4-isothiazolin-26172-55-R433-one42-methyl-4-isothiazolin-3-one2682-20-R434This document is copyright. Apart from any fair dealing for the purposes ofprivate study, research, review or criticism, as permitted under the CopyrightAct, no part may be reproduced by any process without written permission fromCHEMWATCH. TEL (+61 3) 9572 4700.Issue Date: 22-Oct-2002Print Date: 24-Jul-2006。