MSDS 热熔胶
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热熔胶MSDS报告1. 概述本文档是针对热熔胶(Hot Melt Adhesive)的MSDS报告,旨在提供有关热熔胶的安全使用和处理的相关信息。
热熔胶是一种广泛应用于工业制造和日常生活中的粘合剂,具有较高的粘附性和加工性能。
本报告将详细介绍热熔胶的成分、物理化学性质、安全风险和应急措施等内容。
2. 成分热熔胶主要由以下成分组成:•聚合物:热熔胶中的聚合物通常为合成树脂,如乙烯乙酸酯共聚物(EVA)或丙烯酸酯共聚物(APAO)等。
这些聚合物赋予热熔胶良好的粘附性和流动性。
•胶粘剂:热熔胶中的胶粘剂可以是石蜡、油脂或天然树脂等,用于提高胶水的黏度和粘附力。
•填充剂:热熔胶中的填充剂可以是硅酸盐、碳酸钙或纤维素等,用于改善胶水的机械强度和热稳定性。
•添加剂:热熔胶中的添加剂可以是抗氧化剂、防腐剂或稳定剂等,用于增强胶水的性能和稳定性。
3. 物理化学性质热熔胶具有以下物理化学性质:•外观:常见的热熔胶为固体,呈块状或颗粒状。
•熔点:热熔胶的熔点通常在100°C至200°C之间,具体取决于其成分。
•密度:热熔胶的密度一般在0.9 g/cm³至1.2 g/cm³之间。
•粘度:热熔胶的粘度随温度变化,通常在1000 cps至5000 cps之间。
4. 安全风险在使用和处理热熔胶时,需要注意以下安全风险:•烫伤:热熔胶在高温下会变得流动,并且可以黏附在皮肤上,容易造成烫伤。
因此,在使用热熔胶时,应戴上适当的防护手套,以避免直接接触热熔胶。
•挥发物:在热熔胶加热过程中,可能会释放出一些挥发性有机物。
长时间暴露于这些挥发物中可能对人体健康造成影响。
因此,在使用热熔胶时应确保通风良好,尽量减少挥发物的吸入。
•燃烧性:热熔胶具有一定的燃烧性,因此应避免在易燃材料附近使用热熔胶。
在处理热熔胶时,应注意防火措施,避免发生火灾事故。
•化学品敏感性:个别人群可能对热熔胶中的某些化学成分敏感,可能引发过敏反应,因此,在使用热熔胶前,应先进行过敏试验。
PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPS1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCTProduct Name: HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSProduct Description: HOT MELT ADHESIVE,MIXTUREProduct Code:Intended Use: ADHESIVE,FOR AUTOMOBILE LAMPSCOMPANY IDENTIFICATIONHuangshan Xiuning Xindecheng Chemical Co., Ltd.SUPPLIER:Wanning Industrial Park, Huangshan, Anhui, China (245400)Telephone: 0086-559-7519970Facsimile: 0086-559-7519971This (M)SDS is a generic document with no country specific information included.2 COMPOSITION/INFORMATION ON INGREDIENTSNo Reportable Hazardous Substance(s) or Complex Substance(s).INGREDIENTS CAS No.Approx. Proportionstyrene butadiene rubber9003-55-8Med 50-60%rosin resin8050-09-7Low 50-40%PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPS3 HAZARDS IDENTIFICATIONThis material is not considered to be hazardous.PHYSICAL / CHEMICAL HAZARDSN/AHEALTH HAZARDSNo adverse effects due to inhalation are expected. When heated, the vapour/fumes given off may cause respiratory tract irritation.4 FIRST AID MEASURESINHALATIONIn case of adverse exposure to vapors and / or aerosols formed at elevated temperatures, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.SKIN CONTACTWash contact areas with soap and water. For hot product: Immediately immerse in or flush affected area with large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.EYE CONTACTFlush thoroughly with water. If irritation occurs, get medical assistance.INGESTIONFirst aid is normally not required. Seek medical attention if discomfort occurs.5 FIRE- FIGHTING MEASURESPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSEXTINGUISHING MEDIAAppropriate Extinguishing Media: Use dry chemical or carbon dioxide (CO2) to extinguish flames.Inappropriate Extinguishing Media: Straight streams of waterFIRE FIGHTINGFire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply.Hazardous Combustion Products: Flammable hydrocarbons, Oxides of carbon, Smoke, Fume, Incompletecombustion products6 ACCIDENTAL RELEASE MEASURESNOTIFICATION PROCEDURESIn the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.ENVIRONMENTAL PRECAUTIONSN/A7 HANDLING AND STORAGEHANDLINGAvoid elevated temperatures for prolonged periods of time. Protect material from direct sunlight. Material canaccumulate static charges which may cause an electrical spark (ignition source). Apart from the specific nature of the polymer product, conditions such as humidity, sunlight and temperature.Loading/Unloading Temperature: [Ambient]Transport Temperature: [Ambient]PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSSTORAGEStore in a cool, dry place.Storage Temperature: 0℃—40℃Storage Pressure:[Ambient]8 EXPOSURE CONTROLS /PERSONAL PROTECTIONENGINEERING CONTROLSN/APERSONAL PROTECTIONPersonal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.Respiratory Protection:If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:No special requirements under ordinary conditions of use and with adequate ventilation.For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.Hand Protection:If product is hot, thermally protective gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves.PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSEye Protection:If contact is likely, safety glasses with side shields are recommended.Skin and Body Protection:If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.Specific Hygiene Measures:Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.9 PHYSICAL AND CHEMICAL PROPERTIESTypical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATIONPhysical State: SolidForm: GrainsColour: GrayOdour: None to MildIMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATIONRelative Density (at 18 C): 0.97Density (at 18 ºC): 970 kg/m³Flash Point [method]: O.C Cleveland Open Cup >260℃Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/DAutoignition Temperature: N/APRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSBoiling Point / Range: >260℃Vapour Density (Air = 1): N/AVapour Pressure: N/AEvaporation Rate (N-Butyl Acetate = 1): N/ApH: N/ALog Pow (n-Octanol/Water Partition Coefficient): N/ASolubility in Water: Negligible10 STABILITY AND REACTIVITYSTABILITY:Material is stable under normal conditions.CONDITIONS TO AVOID:Avoid elevated temperatures for prolonged periods of time.HAZARDOUS DECOMPOSITION PRODUCTS:Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION:Will not occur.11 TOXICOLOGICAL INFORMATIONPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSAcute ToxicityRoute of Exposure Conclusion / RemarksINHALATIONToxicity: Minimally Toxic. Based on test data for structurally similarmaterials.Irritation: Negligible hazard at ambient/normal handling temperatures. Basedon test data for structurally similar materials.INGESTIONToxicity: Minimally Toxic. Based on test data for structurally similarmaterials.SkinToxicity: Minimally Toxic. Based on test data for structurally similarmaterials.Irritation: Negligible irritation to skin at ambient temperatures. Based on testdata for structurally similar materials.EyeIrritation: May cause mild, short-lasting discomfort to eyes. Based on testdata for structurally similar materials.CHRONIC/OTHER EFFECTS12 ECOLOGICAL INFORMATIONThe information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITYPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSMaterial -- Not expected to be harmful to aquatic organisms.Material -- Not expected to be harmful to terrestrial organisms13 DISPOSAL CONSIDERATIONSDisposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.DISPOSAL RECOMMENDATIONSSuitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.14 TRANSPORT INFORMATIONLAND : Not Regulated for Land TransportSEA (IMDG) : Not Regulated for Sea Transport according to IMDG-CodeAIR (IATA) : Not Regulated for Air Transport15 RRGULATORY INFORMATIONPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSMaterial is not hazardous as defined by the EU Dangerous Substances/Preparations Directives.16 OTHER INFORMATIONN/D = Not determined, N/A = Not applicableTHIS SDS COVERS THE FOLLOWING MATERIALS: Petroleum hydrocarbon resin ECR 807 | Escorez 2203 LC | mixed resin dust-----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of Xindecheng’s knowledge and belief, accurate and reliable as of the date issued. You can contact Xindecheng to insure that this document is the most current available from Jinsen. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited.---------------------------------------------------------------------------------------------------------------------------。
MSDS No XXXX. :1.0***CHEMICAL SAFETY DATA SHEET ***1. CHEMICAL PRODUCT AND COMPANY IDENTIFICA TION PRODUCT NUMBER ------------------100PRODUCT NAME --------------------Technomelt Easy-Pac TM100SYNONYM NAME --------------------HOT MEL T ADHESIVEHenkel Adhesives Technologies (Guangdong) Co. Ltd.Middle Section, 5th Industrial Estate,Nanzha, Humen, Dongguan, Guangdong,P.R.C.Post code: 523932TEL: 86-769-85563700FAX: 86-769-855680302. COMPOSITION/INFORMA TION OF INGREDIENTSCHEMICAL FAMIL Y -----------------Hot Melt AdhesiveNone hazardous.3. HAZARDS IDENTIFICA TIONNot considered as hazardous.EYE -----------------------------As supplied: irritant as a foreign body.As used: severe thermal hazard.SKIN CONTACT --------------------Exposure to hot material may cause thermalhazardINHALATION ----------------------Negligible hazard at ambient temperature.V apors and/or aerosols which may be formed atelevated temperatures may be irritating to eyesand respiratory tract.INGESTION -----------------------No hazard in normal industrial use.4. FIRST-AID MEASURESEYE -----------------------------If hot: flush with cool water. Treat as wax orresin burn. Do not attempt to remove solidifiedadhesive. Get medical attention immediately.As supplied: remove as foreign body.SKIN CONTACT --------------------For hot product, immediately immerse in orflush affected area with large amounts of coldwater to dissipate heat. Cover with clean cottonsheeting and get prompt medical attention. INHALATION ----------------------Remove to fresh air. If breathing has stopped,give artificial respiration. Get medical attention. AUTOIGNITION --------------------Unknown.FLASH POINT --------------------->260°C (Cleveland Open Cup) EXTINGUISHING MEDIA -------------CO2; Dry chemical; FoamSPECIAL FIREFIGHTING PROCEDURES -Fire fighters should be equipped withself-contained breathing apparatus to protectagainst potentially toxic and irritating fumes. FIRE & EXPLOSION HAZARDS --------Not applicable.UPPER EXPLOSION LIMIT (%) -------Not applicable.LOWER EXPLOSION LIMIT (%) -------Not applicable.NFPA FLAMMABILITY HAZARD CLASS --0 =SPILL & LEAK PROCEDURES ---------Allow to cool and solidify. Scrape up and collectin suitable containers for disposal.For safety and environmental precautions, please review entire Material Safety Data Sheet for necessary information.7. HANDLING AND STORAGESTORAGE TEMPERATURE -------------0 – 40°CHANDLING/STORAGE ----------------Store in a cool, dry area.Precaution: this product should only be heated torecommended temperatures. Hazards ofpyrolysis products emitted are unknown andmay be hazardous to health.VENTILA TION REQUIREMENTS --------Local; general8. EXPOSURE CONTROLS/PERSONAL PROTECTIONVENTILA TION REQUIREMENTS --------Local; generalEYE PROTECTION REQUIREMENTS -----Avoid contact with eyes. Wear chemical gogglesif there is likelihood of contact with eyes. GLOVE REQUIREMENTS --------------Thermally resistant gloves should be worn. CLOTHING REQUIREMENTS -----------Employee must wear appropriate protectiveclothing and equipment to prevent anypossibility of skin contact with this substance. CHANGE/REMOV AL OF CLOTHING ------Not required unless molten adhesive has beensplashed on clothing and passes through fabric.WASH REQUIREMENTS ---------------None.RESPIRATOR REQUIREMENTS ---------Avoid prolonged or repeated breathing of vaporor mists. If exposure may or does exceedoccupational exposure limits, use a NIOSHapproved respirator to prevent overexposure.9. PHYSICAL AND CHEMICAL PROPERTIESPURE SUBSTANCE OR MIXTURE -------MixturePHYSICAL FORM -------------------SolidAPPEARANCE/ODOR -----------------Pale Yellow solid; Negligible odorODOR THRESHOLD ------------------Not availablePH AS IS ------------------------N/A (not applicable)PH IN (1%) SOLUTION -------------N/ABOILING POINT ------------------->260°CMEL TING/FREEZING POINT ----------N/ASOLUBILITY IN WATER -------------InsolublePARTITION COEFFICIENT(N-octanol/water) -------------N/ASPECIFIC GRA VITY (WA TER=1) ------0.97EV APORATION RATE ----------------Nil (water)V APOR PRESSURE (mmHg) -----------Nil (20°C)V APOR DENSITY (air=1) -----------NilVOLA TILES -----------------------NilVOLA TILE ORGANIC COMPOUNDS ------ NilAUTOIGNITION --------------------UnknownFLASH POINT --------------------->260°C (Cleveland Open Cup)OXIDIZING PROPERTIES ------------N/A10. STABILITY AND REACTIVITYSTABILITY -----------------------StableNFPA REACTIVITY HAZARD CLASS ---- 0 = InsignificantHAZARDOUS DECOMPOSITIONPRODUCTSCarbon monoxide, carbon dioxide-------------------------------11. TOXICOLOGICAL INFORMA TIONCHRONIC (LONG TERM) EFFECTS OF EXPOSUREROUTE OF ENTRY ------------------Skin contact; Eye contact.EFFECTS OF CHRONIC EXPOSURE -----The toxicological properties of this product havenot been fully evaluated. Use of good industrialhygiene practices is required. Avoid directcontact with skin or eyes. Do not ingest orinhale.TARGET ORGANS -------------------Not applicable.CARCINOGEN ----------------------No.12. ECOLOGICAL INFORMATIONNot Available.13. DISPOSAL CONSIDERA TIONSWASTE DISPOSAL METHODS ----------Waste disposal should be in accordance withexisting federal, state and local environmentalregulations.EMPTY CONTAINER WARNINGS --------Empty containers may contain product residue;follow CSDS and label warnings even after theyhave been emptied.14. TRANSPORTA TION INFORMA TIONDOT INFORMATION:DOT SHIPPING NAME ---------------ADHESIVE no. 1DOT HAZARD CLASS ----------------Non hazardousDOT REPORTABLE QUANTITY ---------Not noted15. REGULA TORY INFORMA TIONFDA -----------------------------21CFR175.10516. OTHER INFORMA TIONISSUE DATE -----------------------2008/03/07FOR INFORMATION CONTACT ---------Henkel Adhesives Technologies (Guangdong)Co. Ltd.Middle Section, 5th Industrial Estate,Nanzha, Humen, Dongguan, Guangdong,R.P.C.Post code: 523932Contact person: Jimm QiuTitle: Technical ManagerTEL: 86-769-85563700FAX: 86-769-85568030*** ADDITIONAL INFORMATION ***The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are based on our research and on data from other reliable sources and are believed to be accurate. No guaranty of accuracy is made. It is the purchaser’s responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their purposes.。