水的粘度计算表

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水的黏度表(0~40℃)

温度T 粘度μ Pa·s或N·s·m-2

温度 T 粘度μ

Pa·s或N·s·m-2 ℃ K ℃ K

0 ×10-3 ×10-3

1 ×10-3 21 ×10-3

2 ×10-3 22 ×10-3

3 ×10-3 23 ×10-3

4 ×10-3 24 ×10-3

5 ×10-3 25 ×10-3

6 ×10-3 26 ×10-3

7 ×10-3 27 ×10-3

8 ×10-3 28 ×10-3

9 ×10-3 29 ×10-3

10 ×10-3 30 ×10-3

11 ×10-3 31 ×10-3

12 ×10-3 32 ×10-3 13 ×10-3 33 ×10-3

14 ×10-3 34 ×10-3

15 ×10-3 35 ×10-3

16 ×10-3 36 ×10-3

17 ×10-3 37 ×10-3

18 ×10-3 38 ×10-3

19 ×10-3 39 ×10-3

20 ×10-3 40 ×10-3

水的物理性质

温度t/℃ 饱和蒸气压

p/kPa 密度ρ/kg·m-3 焓

H/kJ·kg-1 比定压热容cp/kJ·kg-1·K-1 导热系数λ/10-2W·m-1·K-1 粘度μ/10-5Pa·s 体积膨胀系数α/10-4K-1 表面张力σ/10-3N·m-1 普兰德数Pr

0 0

10

20

30

40 50

60

70

80

90

100

110

120

130

140

150

160

170

180

190

200

210 F3??? Viscosity decreases with pressure 220

230

240

250

260

270

280

290

300

310

320

330

340

350

360 109

370 264 (at temperatures below 33°C)

Viscous flow occurs by molecules moving through the voids that exist between them. As

the pressure increases, the volume decreases and the volume of these voids reduces, so

normally increasing pressure increases the viscosity.

Water's pressure-viscosity behavior [] can be explained by the increased pressure (up to

about 150 MPa) causing deformation, so reducing the strength of the hydrogen-bonded

network, which is also partially responsible for the viscosity. This reduction in cohesivity

more than compensates for the reduced void volume. It is thus a direct consequence of the

between hydrogen bonding effects and the van der Waals dispersion forces [] in water;

hydrogen bonding prevailing at lower temperatures and pressures. At higher pressures (and

densities), the between hydrogen bonding effects and the van der Waals dispersion forces

is tipped in favor of the dispersion forces and the remaining are stronger due to the

closer proximity of the contributing oxygen atoms []. Viscosity, then, increases with

pressure. The dashed line (opposite) indicates the viscosity minima. The variation of viscosity with pressure and temperature has been used as evidence that

the viscosity is determined more by the extent of hydrogen bonding rather than hydrogen

bonding strength.

Self-diffusion is also affected by pressure where (at low temperatures) both the

translational and rotational motion of water anomalously increase as the pressure

increases.