A Coherent Timing Solution for the Nearby Isolated Neutron Star RX J0720.4-3125
- 格式:pdf
- 大小:180.01 KB
- 文档页数:5
可靠性仿真在鱼雷产品上的应用王斗辉 1, 陈 欢 2, 郭 君 2, 吴 斌 2(1. 工业和信息化部 电子第五研究所, 广东 广州, 615123; 2. 中国船舶集团有限公司 第705研究所, 陕西 西安, 710077)摘 要: 针对传统可靠性试验耗时长、成本高的问题, 给出了可靠性仿真的基本内容和工作流程, 针对鱼雷产品中的典型电子组件开展可靠性仿真建模、热应力和振动应力仿真分析、故障预计和可靠性评估, 以得到产品设计薄弱环节、潜在故障信息和平均首发故障时间等。
分析结果表明, 可靠性仿真能够确保在鱼雷产品设计早期消除故障源, 从而提高鱼雷产品的鲁棒性和故障预测能力。
关键词: 鱼雷; 可靠性; 电子组件; 仿真建模; 应力分析中图分类号: TJ630 文献标识码: A 文章编号: 2096-3920(2024)01-0166-08DOI: 10.11993/j.issn.2096-3920.2023-0030Application of Reliability Simulation in Torpedo ProductsWANG Douhui1, CHEN Huan2, GUO Jun2, WU Bin2(1. CEPRI, Guangzhou 615123, China; 2. The 705 Research Institute, China State Shipbuilding Corporation Limited, Xi’an 710077, China)Abstract: The traditional reliability test is time-consuming and requires high cost. Therefore, this article provided the basic content and workflow of reliability simulation and conducted reliability simulation modeling, thermal stress simulation analysis, vibration stress simulation analysis, fault prediction, and reliability evaluation for typical electronic components in a certain torpedo product, so as to obtain weak links in product design, potential fault information, and average first failure time. The analysis results show that the reliability simulation can ensure the elimination of fault sources in the early stage of torpedo product design and thus improve torpedo product robustness and fault prediction ability.Keywords: torpedo; reliability; electronic components; simulation modeling; stress analysis0 引言随着技术的发展, 对装备可靠性水平的要求越来越高, 但对研制和生产周期的要求则越来越短,完全按传统的典型环境仿真方法对装备进行可靠性试验, 对于可靠性指标要求较高的产品, 无论是时间还是试验费用等都难以保证, 为此需要找到一种在研制初期即可针对仿真模型, 在开展建模仿真的基础上进行可靠性设计及评价的新途径。
时滞忆阻Cohen-Grossberg神经网络周期解的存在性王有刚;武怀勤【摘要】研究了一类具有时变时滞的忆阻Cohen-Grossberg神经网络的周期动力行为.借助M-矩阵理论,微分包含理论和Mawhin-like收敛定理,证明了网络系统周期解的存在性.最后,用一个数值算例验证了本文结论的正确性和可行性,并通过图形模拟直观地描述了周期解和平衡点的存在性.%The objective of this paper is to investigate the periodic dynamical behaviors for a class of Memristive Cohen-Grossberg neural networks with time-varying delays. By employing M-matrix theory, differential inclusions theory and the Mawhin-like coin-cidence theorem in set-valued analysis, the existence of the periodic solution for the network system was proved. Finally, an illustra-tive example was given to demonstrate the validity of the theoretical results and the existence of periodic solution and equilibrium point was described visually by graphical simulation.【期刊名称】《西华大学学报(自然科学版)》【年(卷),期】2017(036)005【总页数】10页(P22-30,35)【关键词】忆阻;Cohen-Grossberg神经网络;周期解;时变时滞【作者】王有刚;武怀勤【作者单位】吕梁学院数学系,山西吕梁 033001;燕山大学理学院,河北秦皇岛066004【正文语种】中文【中图分类】TP1831971年, 华裔科学家蔡少棠(Leon O. Chua)从理论推断在电阻、电容和电感器之外,应该还有一种组件,代表着电荷与磁通量之间的关系。
第45卷 第12期2023年12月系统工程与电子技术SystemsEngineeringandElectronicsVol.45 No.12December2023文章编号:1001 506X(2023)12 3836 09 网址:www.sys ele.com收稿日期:20220818;修回日期:20221119;网络优先出版日期:20230105。
网络优先出版地址:https:∥kns.cnki.net/kcms/detail/11.2422.TN.20230105.1653.005.html基金项目:国家自然科学基金(62001510)资助课题 通讯作者.引用格式:张亮,杜庆磊,周必雷,等.基于非标准Keystone变换的捷变频雷达相参积累算法[J].系统工程与电子技术,2023,45(12):3836 3844.犚犲犳犲狉犲狀犮犲犳狅狉犿犪狋:ZHANGL,DUQL,ZHOUBL,etal.Acoherentintegrationalgorithmoffrequency agileradarbasedonnon stand ardKeystonetransform[J].SystemsEngineeringandElectronics,2023,45(12):3836 3844.基于非标准犓犲狔狊狋狅狀犲变换的捷变频雷达相参积累算法张 亮1,2, ,杜庆磊1,周必雷1,瞿奇哲1,王永良1(1.空军预警学院,湖北武汉430019;2.中国人民解放军94326部队,山东济南250000) 摘 要:针对捷变频雷达(frequency agileradar,FAR)相参积累难题,提出基于非标准Keystone变换(Keystonetransform,KT)的FAR相参积累算法,与标准KT相比,所提算法增加了距离补偿环节,构造了不同的虚拟慢时间。
同时,考虑到目标距离信息通常未知,利用距离补偿后信号的周期性,大幅缩小了距离搜索区间。
Writing an essay in English that is considered perfect involves several key components:clear structure,coherent arguments,correct grammar,and engaging vocabulary.Here is a stepbystep guide to help you write an essay that could be seen as perfect:1.Understand the Prompt:Before you start writing,make sure you fully understand the question or prompt.This will guide the direction of your essay and ensure that your content is relevant.2.Plan Your Essay:Outline the main points you want to cover.This will help you organize your thoughts and create a logical flow to your essay.3.Introduction:Start with a strong introduction that grabs the readers attention.Introduce the topic and provide a brief overview of what you will discuss in the essay.4.Body Paragraphs:Each paragraph should focus on one main idea that supports your thesis e topic sentences to introduce each paragraph,followed by evidence or examples to support your point.Make sure to explain how each piece of evidence relates back to your thesis.5.Coherent Arguments:Ensure that your arguments are logical and flow from one to the next.Each paragraph should build upon the previous one,creating a cohesive narrative.e of Evidence:Support your claims with evidence such as facts,statistics,quotes,or examples.Make sure to cite your sources properly to avoid plagiarism.7.Grammar and Punctuation:Check your essay for grammatical errors and correct punctuation.This is crucial for maintaining the credibility and professionalism of your writing.8.Vocabulary:Use a wide range of vocabulary to express your ideas clearly and effectively.Avoid repetition and clichés.9.Conciseness:Be concise and to the point.Avoid unnecessary words and phrases that do not add value to your argument.10.Transitions:Use transitional phrases to connect your ideas smoothly.This helps to guide the reader through your essay and makes it easier to follow.11.Conclusion:Summarize your main points and restate your thesis in a new way.Theconclusion should leave a lasting impression on the reader.12.Revise and Edit:After writing your first draft,take the time to revise and edit your essay.Look for areas where you can improve clarity,strengthen arguments,or correct errors.13.Proofread:Finally,proofread your essay to catch any typos,grammatical mistakes,or inconsistencies that may have been missed during the editing process.14.Get Feedback:If possible,have someone else read your essay and provide feedback.A fresh set of eyes can often spot errors or areas for improvement that you may have overlooked.By following these steps and focusing on clarity,coherence,and correctness,you can write an essay in English that is wellstructured and engaging,which could be considered perfect by many standards.。
1.What is the main idea of the passage?A.The history of technology.B.The impact of social media.C.The benefits of exercise.(答案)D.The challenges of modern education.2.Which word best describes the author's tone in the text?A.SarcasticB.Optimistic(答案)C.PessimisticD.Neutral3.What does the phrase "in the long run" mean in the context?A.ImmediatelyB.Eventually(答案)C.OccasionallyD.Rarely4.According to the passage, what is the most effective way to learn a new language?A.Watching foreign movies.B.Listening to music in that language.C.Practicing with a language tutor.(答案)D.Reading books translated into that language.5.Why did the scientist decide to conduct the experiment?A.To prove a previous theory wrong.B.To discover a new element.C.To test a new hypothesis.(答案)D.To replicate a famous study.6.What is the purpose of the author writing this article?A.To entertain readers with a story.B.To persuade readers to adopt a new habit.(答案)C.To inform readers about a recent event.D.To analyze a complex issue.7.Which of the following is NOT mentioned in the passage as a cause of climate change?A.DeforestationB.OverpopulationC.Increased use of renewable energy(答案)D.Industrial emissions8.What can be inferred from the last sentence of the passage?A.The problem will never be solved.B.More research is needed.(答案)C.The solution is simple and straightforward.D.The author is uncertain about the future.。
改进型music算法相干信号英文回答:Improving the music algorithm for coherent signals is an interesting challenge. Currently, the music algorithm is widely used for signal processing in various applications, including audio processing, radar systems, and wireless communications. However, there is always room for improvement to enhance its performance and accuracy.One possible improvement to the music algorithm is to incorporate machine learning techniques. By training a machine learning model with a large dataset of coherent signals, the algorithm can learn to better identify and extract relevant features from the signals. This can lead to improved accuracy and robustness in detecting and classifying coherent signals.Another improvement could be the integration of deep learning algorithms. Deep learning models, such asconvolutional neural networks (CNNs) or recurrent neural networks (RNNs), have shown great success in various signal processing tasks. By incorporating deep learning into the music algorithm, it can potentially improve the algorithm's ability to handle complex and non-linear coherent signals.Furthermore, optimizing the parameter selection process can also enhance the music algorithm's performance. The music algorithm relies on selecting the number of signal sources and the signal subspace dimension. By developing more efficient and accurate methods for determining these parameters, the algorithm can better adapt to different signal scenarios and improve its overall performance.To illustrate the potential improvements, let's consider the example of music source separation. Currently, the music algorithm is used to separate different sourcesin an audio signal. However, it may struggle when the sources are highly correlated or when there are overlapping sources. By incorporating machine learning techniques, the algorithm can learn to better distinguish between different sources and separate them more accurately.For instance, let's say we have a music recording with vocals and instruments playing simultaneously. The current music algorithm may have difficulty separating the vocals from the instruments if they are highly correlated. However, by training a machine learning model with a large datasetof vocal and instrumental tracks, the algorithm can learnto differentiate between the two and successfully separate them in the given recording.中文回答:改进相干信号的music算法是一个有趣的挑战。
电感耦合等离子体原子发射光谱法的英文Inductively coupled plasma atomic emission spectroscopy (ICP-AES) is a powerful analytical technique that is widely used for the determination of trace elements in various samples. It is based on the principle of inductively coupled plasma, in which a high-frequency electromagnetic field is used to create a plasma from a sample gas. This plasma is then used to excite the atoms of the elements in the sample, causing them to emit characteristic light that can be detected and quantified.ICP-AES offers several advantages over other analytical techniques, such as high sensitivity, multi-element analysis capability, and the ability to analyze a wide range of sample types. It is commonly used in environmental, pharmaceutical, food, and materials analysis, as well as in research and industrial applications.The instrumentation for ICP-AES consists of a sample introduction system, an inductively coupled plasma source, a spectrometer, and a detector. The sample is typically introduced into the plasma using a nebulizer or an ICP torch, where it is atomized and excited by the plasma. The light emitted by the excited atoms is then dispersed by the spectrometer and detected by the detector.One of the key advantages of ICP-AES is its high sensitivity, which allows for the detection of trace elements at levels as low as parts per billion. This makes it an ideal technique for the analysis of samples with low concentrations of elements, such as environmental samples or biological fluids.In addition to its high sensitivity, ICP-AES also offers a high level of precision and accuracy in elemental analysis. The technique is capable of analyzing multiple elements simultaneously, which reduces the time and cost associated with analysis compared to traditional methods that require separate analyses for each element.ICP-AES is also a versatile technique that can be used to analyze a wide range of sample types, including liquids, solids, and gases. It is commonly used in conjunction with sample preparation techniques such as digestion, extraction, and dilution to analyze complex samples.Overall, ICP-AES is a powerful and versatile analytical technique that is widely used for the determination of trace elements in various samples. Its high sensitivity, precision, and multi-element analysis capability make it an indispensable tool for researchers and analysts in a wide range of fields.。
26CyclodextrinsKatia Martina and Giancarlo CravottoCONTENTS26.1 Introduction (593)26.2 Inclusion Complex Formation (595)26.3 Applications of CD in Food (596)26.4 Analysis of CD (597)26.4.1 Characterization of CD-Inclusion Complex (597)26.4.2 Determination of CD Content (598)26.4.2.1 The Colorimetric Method (598)26.4.2.2 Chromatography (599)26.4.2.3 Affinity Capillary Electrophoresis (600)26.5 Conclusion (600)References (601)26.1 I ntroductionCyclodextrins (CDs) are unique molecular complexation agents. They possess a cage-like supramolecular structure, which involves intra- and intermolecular interactions where no covalent bonds are formed between interacting molecules, ions, or radicals. It is mainly a “host–guest” type phenomenon. CDs are definitively the most important supramolecular hosts found in the literature. As a result of molecular complexation, CDs are widely used in many industrial fields (cosmetics, pharmaceutics, bioremediation, etc.) and in analytical chemistry. Their high biocompatibility and negligible cytotoxicity have opened the doors to their uses such as drug excipients and agents for drug-controlled release (Stella and Rajewski 1997, Matsuda and Arima 1999), in food and flavors (Mabuchi and Ngoa 2001), cosmetics (Buschmann and Schollmeyer 2002), textiles (Buschmann et al. 2001), environment protection (Baudin et al. 2000), and fermentation and catalysis (Koukiekolo et al. 2001, Kumar et al. 2001).CDs are cyclic oligosaccharides consisting of at least six glucopyranose units which are joined together by a (1 → 4) linkage. CDs are known as cycloamyloses, cyclomaltoses, and historically as Schardinger dextrins. They are produced as a result of an intramolecular transglycosylation reaction from the degra-dation of starch which is performed by the CD glucanotransferase enzyme (CGTase) (Szetjli 1998). The first reference to the molecule, which later proved to be CD, was published by Villiers in 1891. Digesting starch with Bacillus amylobacter, he isolated two crystalline products, probably α- and β-CDs. In 1903, Schardinger reported the isolation of two crystalline products that he called α- and β-dextrin, in which the helix of amylose was conserved in fixed-ring structures.From the x-ray structures, it appears that the secondary hydroxyl groups (C2 and C3) are located on the wider edge of the ring and the primary hydroxyl groups (C6) on the other edge. The apolar –CH (C3 and C5) and ether-like oxygens are on the inside of the truncated cone-shaped molecules (Figure 26.1). This results in a hydrophilic structure with an apolar cavity, which provides a hydrophobic matrix, often described as a “microheterogeneous environment.” As a result of this cavity, CDs are able to form inclu-sion complexes with a wide variety of hydrophobic guest molecules. One or two guest molecules can be entrapped by one, two, or three CDs.593594 Handbook of Analysis of Active Compounds in Functional FoodsAlthough CDs with up to 12 glucose units are known, only the first three homologues (α-, β-, and γ-CD) have been extensively studied and used. β-CD is the most accessible due to its low price and high versatility. The main properties of the aforementioned CDs are given in Table 26.1.The safety profiles of the three most common natural CDs and some of their derivatives have recently been reviewed (Irie and Uekama 1997, Thompson 1997). All toxicity studies have demonstrated that orally administered CDs are practically nontoxic due to the fact that they are not absorbed by the gastro-intestinal tract.Pioneer country in the industrial applications of CDs was Japan, since 1990 it become the largest con-sumer in the world. Eighty percent of the annual consumption was used in the food industry and over 10% in cosmetics, <5% was used in the pharmaceutical and the agrochemical industries. The industrial usage of CDs progresses somewhat slower in Europe and America. The constant annual growth of the number of scientific papers and patents indicates the scale of research and industrial interest in this field. From a regulatory standpoint, a monograph for β-CD is available in both the US Pharmacopoeia/National Formulary (USP 23/NF 18, 1995) and the European Pharmacopoeia (3rd ed., 1997). All native CDs are listed in the generally regarded and/or recognized as safe (GRAS) list of the US-FDA for use as a food additive. β-CD was recently approved in Europe as a food additive (up to 1 g/kg food). In Japan, the native CDs were declared to be enzymatically modified starch and, therefore, their use in food prod-ucts has been permitted since 1978.FIGURE 26.1 Chemical structure of α, β, and γ-CD.Cyclodextrins 595Apart from these naturally occurring CDs, many derivatives have been synthesized so as to improve solubility, stability to light or oxygen and control over the chemical activity of guest molecules (Eastburnand and Tao 1994, Szente and Szejtli 1999). Through partial functionalization, the applications of CDs are expanded. CDs are modified through substituting various functional compounds on the pri-mary and/or secondary face of the molecule.26.2 I nclusion Complex FormationThe most notable feature of CDs is their ability to form solid inclusion complexes (host–guest complexes) with a very wide range of solid, liquid, and gaseous compounds by molecular complexation (Szejtli 1982).Since the exterior of the CDs is hydrophilic, they can include guest molecules in water solution. As depicted in Figure 26.2, the guest can be either completely or partially surrounded by the host molecule. The driving force in complex formation is the substitution of the high enthalpy water molecules by an appropriate guest (Muñoz-Botella et al. 1995). One, two, or more CDs can entrap one or more guest molecules. More frequently the host–guest ratio is 1:1; however, 2:1, 1:2, 2:2 or even more complicated associations and higher-order equilibria have been described. The packing of the CD adducts is related to the dimensions of the guest and cavity. Several factors play a role in inclusion complex formation and several interactions have been found:a. Hydrophobic effects, which cause the apolar group of a molecule to fit into the cavity.b. Van der Waals interactions between permanent and induced dipoles.c. Hydrogen bonds between guest molecules and secondary hydroxyl groups at the rim of the cavity.d. Solvent effects.TABLE 26.1Physical Properties of α-, β-, and γ-CDsPropertyα-CD β-CD γ-CD Number of glucose units678Mol wt. (anhydrous)97211351297V olume of cavity (Å3 in 1 mol CD)174262427Solubility in water (g 100 mL −1 r.t.)14.5 1.8523.2Outer diameter (Å)14.615.417.5Cavity diameter (Å) 4.7–5.3 6.0–6.57.5–8.3′R ″CD derivatives R R ′ R ″Native CD R R ′ R ″ = H1:1 and 1:2 inclusion complexes with a naphthalene derivativeFIGURE 26.2 1:1 and 1:2 host–guest CD complexes.596Handbook of Analysis of Active Compounds in Functional Foods Regardless of what kind of stabilizing forces are involved, the geometric characteristics and the polar-ity of guest molecules, the medium and temperature are the most important factors for determining the stability of the inclusion complex. Geometric rather than the chemical factors are decisive in determin-ing the kind of guest molecules which can penetrate the cavity. If the guest is too small, it will easily pass in and out of the cavity with little or no bonding at all. Complex formation with guest molecules signifi-cantly larger than the cavity may also be possible, but the complex is formed in such a way that only certain groups or side chains penetrate the CD cavity.Complexes can be formed either in solution or in the crystalline state and water is typically the solvent of choice. Inclusion complexation can be accomplished in cosolvent systems, also in the presence of any nonaqueous solvent. Inclusion in CDs exerts a strong effect on the physicochemical properties of guest molecules as they are temporarily locked or caged within the host cavity giving rise to beneficial modi-fications which are not achievable otherwise (Dodziuk 2006).Molecular encapsulation can be responsible for the solubility enhancement of highly insoluble guests, the stabilization of labile guests against degradation and greater control over volatility and sublimation. It can also modify taste through the masking of flavors, unpleasant odors, and the controlled release of drugs and flavors. Therefore, CDs are widely used in food industry (Shaw 1990), in food packaging (Fenyvesi et al. 2007), in pharmaceuticals (Loftsson and Duchene 2007, Laze-Knoerr et al. 2010), and above all in cosmetics and toiletries (Szejtli 2006).26.3 A pplications of CD in FoodToday the nontoxicity of β-CD is well proven, the same tenet is generally accepted for the other CDs. The regulatory statuses of CDs differ in Europe, the United States, and Japan, because official processes for food approval are different. In the United States α-, β-, and γ-CD have obtained the GRAS status and can be commercialized as such. In Europe, the approval process for α-CD as Novel Food has just started and is expected to legalize the widespread application of α-CD to dietary products, including soluble fiber. In Japan, α-, β-, and γ-CDs are recognized as natural products and their commercialization in the food sector is restricted only by purity considerations. In Australia and New Zealand, α- and γ-CD have been classified as Novel Foods since 2004 and 2003, respectively.Nowadays the application of CD-assisted molecular encapsulation in foods offers many advantages (Cravotto et al. 2006):• Improvement in the solubility of substances.• Protection of the active ingredients against oxidation, light-induced reactions, heat-promoted decomposition, loss by volatility, and sublimation.• Elimination (or reduction) of undesired tastes/odors, microbiological contamination, hygro-scopicity, and so on.Typical technological advantages include, for example, stability, standardized compositions, simple dosing and handling of dry powders, reduced packing and storage costs, more economical, and man-power savings. CDs are mainly used, in food processing, as carriers for the molecular encapsulation of flavors and other sensitive ingredients. As CDs are not altered by moderate heat, they protect flavors throughout many rigorous food-processing methods such as freezing, thawing, and microwaving. β-CD preserves flavor quality and quantity to a greater extent and for a longer time compared to other encap-sulants (Hirayama and Uekama 1987).CDs can improve the chemical stability of foods by complete or partial inclusion of oxygen-sensitive components. They can be used to stabilize flavors against heat that can induce degradation and they can also be employed to prolong shelf-life by acting as stabilizers.CDs are used for the removal or masking of undesirable components; for example, trimethylamine can be deodorized by the inclusion of a mixture of α-, β-, and γ-CDs. CDs are also used to free soybean products from their fatty smell and astringent taste. Even the debittering of citrus juices with β-CD is a long pursued goal.Cyclodextrins 597 CDs have an important use in the removal of cholesterol from animal products such as milk, butter, and egg yolks and have recently been studied as neutraceutics carriers to disperse and protect natural lipophylic molecules such as polyunsaturated fatty acids, Coenzyme Q10 (ubiquinone) and Vitamin K3.26.4 A nalysis of CD26.4.1 C haracterization of CD-Inclusion ComplexWhen molecules are inserted within the hydrophobic interior of the CDs, several weak forces between the host and guest are involved, that is, dipole–dipole interaction, electrostatic interactions, van der Waals forces, and hydrophobic and hydrogen bonding interactions. An equilibrium exists between the free and complexed guest molecules. The equilibrium constant depends on the nature of the CD and guest molecule, as well as temperature, moisture level, and so on. The inclusion complexes formed in this way can be isolated as stable crystalline substances, and precise information on their topology can be obtained from the structural x-ray analysis of single crystals (Song et al. 2009). The topology of the inclusion complex can also be determined in solution. The interactions between host and guest may lead to characteristic shifts in the 1H and 13C NMR spectra (Dodziuk et al. 2004, Chierotti and Gobetto 2008). Nuclear Overhauser effects (NOE) provide more precise information since their magnitudes are a mea-sure of the distance between host and guest protons. Circular dichroism spectra give information on the topology of the adduct, when achiral guests are inserted into the chiral cavity (Silva et al. 2007). Potentiometry, calorimetry, and spectroscopic methods including fluorescence, infrared, Raman, and mass spectrometry have also been used to study inclusion complexes (Daniel et al. 2002).The molecular encapsulation of natural essential oils, spices, and flavors such as cheese, cocoa, meat, and coffee aromas with β-CD has been known since several years. The literature has dealt with the improved physical and chemical stability of these air-, light-, and heat-sensitive flavors (Szente et al. 1988; Qi and Hedges 1995) and investigated the interaction of these compounds with CDs.UV absorbance spectroscopy was applied to investigate hyperchromic effects induced by the addition of β-CD to a water solution of caffeine (Mejri et al. 2009). The spectroscopic and photochemical behav-ior of β-CD inclusion complexes with l-tyrosine were investigated by Shanmugam et al. (2008). UV–vis, fluorimetry, FT-IR, scanning electron microscope techniques, and thermodynamic parameters have been used to examine β-CD/l-tyrosine complexation.Nishijo and Tsuchitani (2001) studied the formation of an inclusion complex between α-CD and l-tryp-tophan using nuclear magnetic resonance (NMR). Linde et al. (2010) investigated the complexation of amino acids by β-CD using different NMR experiments such as diffusion-ordered spectroscopy (DOSY) and rotating frame Overhauser effect spectroscopy (ROESY). This study provided molecular level infor-mation on complex structure and association-binding constants and advanced the sensorial knowledge and the development of new technologies for masking the bitter taste of peptides in functional food products. The preparation of stable, host–guest complexes of β-CD with thymol, carvacrol, and oil of origanum has been described by LeBlanc et al. (2008). The complex was characterized by NMR and the inclusion constant was measured by fluorescence spectroscopy where 6-p-toluidinylnaphthalene-2-sulfonate was in competitive binding and acted as a fluorescent probe.Caccia et al. (1998) provide the evidence of the inclusion complex between neohesperidin dihydrochalcone/β-CD by x-ray, high resolution NMR and MS spectroscopy. The association constant was determined by NMR via an iterative nonlinear fitting of the chemical shift variation of H3 in β-CD. The geometry of the binding was studied by nuclear NOEs between the proton directly involved in the host/guest interaction as well as by ROESY. The use of fast atom bombardment (FAB) gave comple-mentary information on specific host–guest interaction, while x-ray diffractometry patterns could define the complex in solid state.Differential scanning calorimetry (DSC), thermogravimetry analysis (TGA), or nuclear magnetic resonance (1H-NMR) were employed by Marcolino et al. (2011) to study the stability of the β-CD com-plexes with bixin and curcumin. Owing to the huge industrial applications of natural colorants, this study aimed to compare different methods of complexes formation and evaluate their stability.598Handbook of Analysis of Active Compounds in Functional Foods Natural and synthetic coffee flavors were included in β-CD and the complexes were analyzed by x-ray diffraction by Szente and Szejtli (1986). By thermofractometry and the loss of a volatile constitu-ent, it was demonstrated that the volatility of these complexed flavors diminished in such a way that they could be stored for longer periods. Various spectroscopic methods have been compared, by Goubet et al. (1998, 2000), to study the competition for specific binding to β-CD. The substrates were a group of flavors which show different physicochemical properties, such as vapor pressure, water solubility, and log P.Inverse gas chromatography was recently used for the direct assessment of the retention of several aroma compounds of varying chemical functionalities by high amylose corn starch, wheat starch, and β-CD (Delarue and Giampaoli 2000). The inclusion selectivity of several monoterpene alcohols with β-CD in water/alcohol mixtures was studied by Chatjigakis et al. (1999) using reverse-phase HPLC. Flavor r etention in α-, β-, and γ-CDs was compared, by Reineccius et al. (2002), by the GC analysis of the released flavor compounds; quantification was accomplished using standard internal protocols.GC-MS was used for the identification of the volatile constituents of cinnamon leaf and garlic oils before and after the microencapsulation process with β-CD (Ayala-Zavala et al. 2008). The profile of volatile substances in the β-CD microcapsules was used to evaluate the competitive equilibrium between β-CD and all volatile substances. The eugenol and allyl disulfide content of cinnamon leaf and garlic oils were used as a pattern to evaluate the efficiency in the microencapsulation process. The IR spectra of the microcapsules was employed to demonstrate the formation of intramolecular hydrogen bonds between the guest and host molecules.Samperio et al. (2010) investigated the solubility in water and in apple juice of 23 different essential oils and 4 parabens. The study was focused on the β-CD complexes of few essential oil components (o-methoxycinnamaldehyde,trans, trans-2,4-decadienal, and citronellol), evaluating the increase of solubility in water and the storage stability. UV absorption spectrophotometry was performed to quan-tify the compound in solution. Linear regression analysis was used to calculate the concentration of test compounds in solution from day 0 to day 7.26.4.2 D etermination of CD ContentTraditionally, a variety of techniques have been developed to analyze CDs and their derivatives.Few analytical methods for the quantification of β-CD are described in the literature. Among them are colorimetric methods, LC methods based on the use of indirect photometric detection, pulse ampero-metry, or refractive index experiments, affinity capillary electrophoresis, and mass spectrometry are able to provide qualitative and quantitative data when analyzing the complex CD mixtures.26.4.2.1 T he Colorimetric MethodThe colorimetric method may be used as an alternative to chromatography especially at low CD concen-trations, this also works in the presence of linear oligosaccharides. The colorimetric method, based on the complexation of phenolphthalein, was employed by Higuti et al. (2004) to carry out sensitive and relatively specific quantification of β-CD. A decrease in absorbance at 550 nm, due to phenolphthalein–CD complex formation, was exploited to study the optimization of the CGTase production in Bacillus firmus. A highly reproducible and selective α-CD determination method had already been described by Lejeune et al. (1989). This involves the formation of an inclusion complex between the α-CD and methyl orange under conditions of low pH and low temperature. The metal indicator calmagite (1-(1-hydrohy-4-methyl-phenylazo)-2-naphthol-4-sulfonic acid) interacts selectively with γ-CD and was described by Hokse (1983) to quantify a standard solution of γ-CD.Kobayashi et al. (2008) observed that various kinds of hydrophobic food polyphenols and fatty acids could be dispersed in water containing starch by the action of GTAse (CD-producing enzyme). NMR and spectrophotometric methods were used to confirm the presence of CDs as solubilizing agents. The for-mation of inclusion complexes was demonstrated by using Congo Red as a model molecule in the pres-ence of GTAse or α-, β-, and γ-CD, respectively. Major changes in the 1H NMR profile of Congo Red were observed in the presence of γ- and β-CD.Cyclodextrins 599On the other hand, a spectrophotometric and infrared spectroscopic study of the interaction between Orange G, a valuable clastogenic and genotoxic acid dye used as a food colorant, and β-CD has been described by Wang et al. (2007) as a method for the quantitative determination of this dye. Based on the enhancement of the absorbance of Orange G when complexed by β-CD, the authors proposed a ratiomet-ric method, carried out spectrophotometrically, for the quantitative determination of Orange G in bulk aqueous solution. The absorbance ratio of the complex at 479 and 329 nm in a buffer solution at pH 7.0 showed a linear relationship in the range of 1.0 × 10−5 to 4.0 × 10−5 mol L−1. IR spectroscopy of the com-plex was described to confirm the inclusion complex formation.26.4.2.2 C hromatography26.4.2.2.1 T hin-Layer ChromatographyOne reference in the literature refers to the use of thin-layer chromatography (TLC) technique as an inexpensive, simple, and very informative method for the analysis and separation of CD inclusion com-plex food components. Prosek et al. (2004) isolated the inclusion complex between coenzyme Q10 (CoQ10) and β-CD and described its analysis and separation by one-dimensional, two-dimensional, and multidimensional TLC. The article described different TLC supports, mobile phases, and visualization methods in detail and the authors evaluated that 70% of the complex remained unchanged during the first semipreparative chromatography run and only a small amount of CoQ10 was lost from the complex dur-ing the TLC procedure. The results were confirmed by the use of other separation techniques such as HPLC, HPLC-MS, and NMR.26.4.2.2.2 L iquid Chromatography, LC-MS, HPLC-MSLiquid chromatography (LC) methods are employed for the analysis and separation of CDs and their derivatives. The separation of the complex samples containing CDs in mixture with linear oligosaccha-ride residual starch as well as protein salts and other substances may suffer from poor sensitivity, resolu-tion, and long separation times. Good results can be achieved where differences in mass or polarity are found or, otherwise, will require extensive sample preparation.Several stationary phases have been described, for example, resins modified with specific adsorbents and reverse-phase media used in combination with either refractive index detection (Berthod et al. 1998), evaporative light scattering (Caron et al. 1997, Agüeros et al. 2005), indirect photometric detection (Takeuchi et al. 1990), postcolumn complexation with phenolphthalein (Frijlink et al. 1987, Bassappa et al. 1998), polarimetric detection (Goodall 1993), or pulsed amperometric detection (Kubota et al. 1992).López et al. (2009) described the application of LC and refractive index detection to estimate the amount of residual β-CD (>20 mg per 100 g of product) present in milk, cream, and butter after treat-ment with β-CD. The analyses were performed with a C18 reversed-phase silica-based LC column, α-CD was defined as an internal standard. The repeatability of the analytical method for β-CD was tested on commercial milk, cream, and butter spiked with known amounts of β-CD.The detection limit in milk was determined to be >0.03 mg mL−1 of β-CD which is similar to that found by LC using amperometric detection (Kubota et al. 1992) and its reproducibility was comparable to that found in a colorimetric method for the estimation of β-CD using phenolphthalein (Basappa et al. 1998, Frijlink et al. 1987).LC-MS coupling has led to the development of new interfaces, extending the automation of various procedures and increasing the sensitivity for high-polar and high-molecular mass compounds. New ion-ization techniques such as electron spray (ESI) and matrix-assisted laser desorption ionization (MALDI) (Bartsch et al. 1996, Sporn and Wang 1998) on quadrupole, magnetic sector, or time-of-flight (TOF) instruments or coupled with instruments with tandem MS (MS-MS) capabilities have also been funda-mental in food applications. By coupling HPLC to isotope-ratio, MS has been proven valuable in provid-ing precise isotopic measurements for nonvolatile species such as carbohydrates. For these reasons, the number of reported applications of LC-MS in the analysis of CD in food is rapidly increasing.HPLC/MS analyses for the detection of minute amounts of CDs in enzyme and heat-treated, s tarch-containing food products were proposed by Szente et al. (2006). A suitable sensitive and selective600Handbook of Analysis of Active Compounds in Functional Foods analytical method was studied with the aim of verifying the presence of parent β- and γ-CDs and all the three, α-, β-, and γ-branched CDs with different degrees of glycosylation in appropriately preconcen-trated and purified food samples (beer samples, corn syrups, and bread). Both the HPLC-retention times and mass-spectral data were used for the identification of CDs. As the expected concentrations of CDs were very low, selected ion monitoring (SIM) was preferred to the routinely used refractive index and evaporative light scattering detection techniques as the only reliable detection method. The malto-oli-gomer mixture was analyzed with a detection window opened at the masses of CD sodium salts in order to enable the detection of any malto-oligomer side products.Wang et al. (1999) proposed the efficient qualitative and quantitative analysis of food oligosaccharides by MALDI-TOF-MS. In order to optimize the method, matrices, alkali–metal adducts, response inten-sity, and sample preparation were all examined individually. A series of experiments were carried out by the authors to study analyte incorporation in the matrix. In a first phase of experiments, maltohexanose and γ-CD were used as reference samples to verify the suitability of 2,5-dihydroxybenzoic acid (DHB), 3-aminoquinoline (3-AQ), 4-hydroxy-a-cyanocinnamic acid (HCCA), and 2,5-dihydroxybenzoic acid (DHB), 1-hydroxy-isoquinoline (HIC), (1:1) as the matrix material. Spot-to-spot or sample-to-sample repeatability tests and the ability to achieve a good quality spectrum with a reasonable signal-to-noise ratio and the best resolution were compared. Good quality spectra and acceptable repeatability were achieved with DHB but many interfering matrix peaks were observed in the low mass region. The best results were achieved using a 2,4,6-trihydroxy-acetophenone monohydrate (THAP) matrix. The authors exploited the high solubility of THAP in acetone, its fast evaporation to fine crystals, and the homo-geneous incorporation of the sample to avoid low-quality results which may be due to irregular crystal-lization when the substance is used directly in water.26.4.2.3 A ffinity Capillary ElectrophoresisAffinity capillary electrophoresis (ACE) techniques have been introduced more recently and are currently in rapid development. CDs have played a central role in the development of a wide variety of analytical methods based on ACE in the separation of chiral molecules. ACE also provides a powerful analytical tool for the analysis of CDs and their derivatives.The electrophoretic separation and analysis of α-, β-, and γ-CDs have been carried out recently without modification. CDs that are charged at very high pH can be separated by the formation of inclu-sion complexes. Their complexes, with a large range of aromatic ions, facilitate detection by indirect UV absorbance (Larsen and Zimmermann 1998, 1999). In addition, fluorescent molecules such as 2-anilinonaphthalene-6-sulfonic have been used for the separation and detection of CDs in a ACE system (Penn et al. 1994).Furthermore, the indirect electrophoretic determination of CD content has recently been described using periodate oxidation. The amount of produced iodate was monitored by ACE and reproducible quantitative results were obtained for α-, β-, and γ-CDs (Pumera et al. 2000). Nevertheless, ACE has not been yet exploited for the analysis of CDs in food. The major advantages of ACE compared to other analysis methods are their short analysis times and high versatility. An exhaustive review of this topic was published in 1999 (Larsen and Zimmermann 1998, 1999).26.5 C onclusionThe use of native CDs for human consumption is growing dramatically due to their well-established safety. CDs are effective in protecting lipophilic food components from degradation during cooking and storage. In this context, several methodologies have been developed to detect, identify, and quantify CDs in food extracts and to study molecular inclusion complexes. X-ray and NMR spectroscopy afford valuable and detailed insight into the structure and the dynamics of a wide range of complexes which are not amenable to study by other analytical techniques. HPLC coupled with refractive index and evaporative light scattering detection technique is routinely used in CD food analysis and LC-MS data in this respect are particularly useful in detecting minute amounts of CDs in complex food samples.。
比赛英文演讲稿英文Good day, dear friends! Today, I want to talk to you about the art of crafting an English speech for a competitionFirst and foremost, a great competition speech should have a clear and compelling topic It's like the foundation of a building – if it's not strong, the whole structure could crumble You need to pick something that you are passionate about, something that makes your heart race and your mind buzz with ideas It could be a social issue that you care deeply about, a personal experience that has shaped you, or a vision for the future that you believe inWhen you have your topic, it's time to do some research This is not just about looking up facts and figures on the internet; it's about digging deep, understanding different perspectives, and gathering reallife stories and examples to support your points Remember, the more you know about your topic, the more confident and authoritative you will sound on stageThe structure of your speech is also crucial It should have a beginning that grabs the audience's attention, a middle that presents your main ideas and arguments in a logical and coherent way, and an ending that leaves a lasting impression A common structure is to start with a powerful opening, such as a rhetorical question, a shocking fact, or a personal anecdote Then, in the middle, break your main points into clear paragraphs, each with its own subheading or transition sentence to make the flow smooth And for the ending, summarize your key points, call for action, or leave the audience with a thoughtprovoking statementNow, let's talk about the language Keep it simple and straightforward Avoid using overly complex words and sentences that might confuse your listeners But at the same time, don't be too casual – this is a competition, after all Use vivid and descriptive language to paint a picture in the audience's minds Use metaphors, similes, and anecdotes to make your speech more engaging and memorableDelivery is just as important as the content of your speech Stand tall, make eye contact with your audience, and speak clearly and loudly Use gestures and body language to emphasize your points and convey your emotions And don't forget to pace yourself – don't rush through your speech or speak too slowly and lose the audience's interestOne thing that many people overlook is the importance of rehearsing Practice your speech over and over again, in front of a mirror, to your family and friends, or even record yourself and listen back to it This will help you iron out any kinks, get the timing right, and build up your confidenceAlso, be prepared for unexpected situations What if you forget your lines? Don't panic! Take a deep breath, pause for a moment, and then smoothly move on The audience is usually more forgiving than you thinkIn conclusion, writing and delivering an English speech for a competition is no easy task, but with the right topic, wellresearched content, a clear structure, engaging language, confident delivery, and plenty of practice, you can stand out on that stage and make your voice heard So go ahead, take the plunge, and let your words shine!Thank you for listening!。
Getting Started GuideAS and A Level Design and TechnologyPearson Edexcel Level 3 Advanced Subsidiary GCE in Design and Technology (Product Design) (8DT0)Pearson Edexcel Level 3 Advanced GCE in Design and Technology (Product Design) (9DT0)GCE Design & Technology 2017Getting Started GuideIntroduction 2 What's changed 3 Qualification at a glance 4 Planning 8 Assessment guidance 9GCE Design & Technology 2017 Getting Started Guide IntroductionThe subject content sets out the knowledge, understanding and skills relevant to AS and A level Design & Technology.The key aim of this new qualification is to enable students to:●Use creativity and imagination when applying iterative design processes todevelop and modify designs, and to design and make prototypes that solve realworld problems, considering their own and others’ needs, wants, aspirationsand values.Students will be able to integrate and apply their understanding and knowledgefrom Key Stage 4, with a focus on mathematics and science for analysis andinforming decisions in design, whilst being open to taking design risks which show innovation and enterprise.Within the Independent Design and Make Project, students will undertake asubstantial design, make and evaluate project. At A level, this will be of theirchoice. At AS they will respond to one of the contextual challenges. They will createa prototype, by which is meant an appropriate working solution to a need or wantthat is sufficiently developed to be tested and evaluated; this could be a full-sized product or a scaled working model or functioning system.This project will require students to follow the iterative design processes ofexploring, creating and evaluating.This Getting Started guide provides an overview of the new GCE specification, tohelp you understand the changes to content and assessment, and what these mean for you and your students.We will be providing a full package of support to help you plan and implement the new specification.●Plan: In addition to the section in this guide, there is a Course Planner andSchemes of Work for a co-teachable AS and A level course, as well as a fulllinear two-year course. These are not meant to be prescriptive, therefore theyare available as a Word document so that you can adapt to suit yourdepartment, specialisms and resources.●Teach: There will be exemplar materials that you will be able to use with yourstudents.●Track and Assess: In addition to the Sample Assessment Materials, there will bean additional set of exemplar papers created that you will be able to use for aMock examination.●Develop: There will be Getting Ready to Teach events, both face to face andonline training. In addition, there will be specific events targeting the NEA interms of delivery and assessment, as well as Feedback events after the firstassessment in 2019.These support documents will be available on the GCE 2017 Design and Technology pages.GCE Design & Technology 2017 Getting Started GuideWhat’s changed?What are the changes to the GCE qualification?There is no longer such a range of pathways that awarding organisations can offer.There are now only three possible endorsements that can be offered:●Product Design●Fashion and Textiles●Design Engineering.Pearson has made the decision to offer one title: Product Design.The new course is made up of two components; a single paper and a single non-examined assessment (NEA) task.The weighting of the NEA has been reduced from the current 60% to 50% at both AS and A level, which gives an equal split between the examined component and the NEA.Maths skills now contribute to the overall qualification and, since Maths cannot be assessed in the NEA, it will be sited in the examination paper, representing 15% of the total paper marks.There are now four Assessment Objectives, rather than the current two. This is to provide an increased focus on analysis and evaluation.The AS is now a stand-alone qualification, the results of which will no longercontribute to the overall A level grade.Changes to Design and Technology content requirementsThe content requirements for GCE Design and Technology have been revised. To gain accreditation, all awarding organisations’ specifications must meet thesecriteria.The new subject content has been split into three sections: Core technicalprinciples, Core Design and Making principles and Specialist knowledge. Students must study a range of material areas; develop an understanding of contemporary industrial and commercial practices; have a good working knowledge of health and safety procedures, as well a sound working knowledge in the use of ICT.Changes to Assessment ObjectivesThe GCE Design & Technology assessment objectives have been revised as shown below.GCE Design & Technology 2017 Getting Started GuideChanges to specification contentChanges have been made as a result of feedback from all parts of the design and technology subject community, including teachers, subject associations,professional bodies and higher education. We have used this opportunity toredesign a qualification that equips students with design skills for the future andencourages creativity and innovation.There is some overlap between the new specification and the legacy specifications.Details of the overlap can be found in the mapping documents available on the GCE 2017 Design and Technology pages.Qualification at a glanceAS LevelContent and assessment overviewThe Pearson Edexcel Level 3 Advanced Subsidiary GCE in Design and Technology (Product Design) consists of one externally-examined paper and one non-examined assessment component.Students must complete all assessment in May/June in any single year.GCE Design & Technology 2017 Getting Started GuideGCE Design & Technology 2017 Getting Started GuideA LevelContent and assessment overviewThe Pearson Edexcel Level 3 Advanced GCE in Design and Technology (ProductDesign) consists of one externally-examined paper and one non-examinedassessment component.Students must complete all assessment in May/June in any single year.GCE Design & Technology 2017 Getting Started GuideGCE Design & Technology 2017 Getting Started GuidePlanningConstructing a coherent courseTime in Year 12 can be spent teaching much of the content, especially topics 1–7 if both AS and A level classes are being taught together.It is quite likely that, if centres are offering a one year AS course, it could be taught concurrently with the A level course. If this is the case, time will need to be given over to the AS group for them to complete the NEA task in response to theContextual Challenge.Alongside the teaching of the content in Year 12, a start can be made on the NEA: The Independent Design and Make Project.The remaining context, topics 8–12, can be taught in Year 13 as the NEA taskprogresses.It is essential that pupils are exposed to Mathematical skills in a variety of contexts at every opportunity over the two- year course.Delivery modelsAs the AS qualification will no longer contribute towards the A level, centres willneed to decide whether they wish to continue to offer the AS qualification. It shouldGCE Design & Technology 2017 Getting Started Guidebe noted that the subject content at AS is identical to work that has to be covered at A level.There is a course planner and detailed schemes of work available on the GCEDesign & Technology 2017 webpage which take account of a delivery approach for both AS and A level. These are word documents and are not prescriptive. Centres may amend and adapt these to suit their students and resources.Co-teachability exampleAssessment guidanceImplications of linear assessmentAll assessment is to take place in the final year as a terminal examination.Therefore, it is essential, if AS is being sat, that the correct Contextual Challenge is used for students. The Contextual Challenges are issued annually, thereforestudents should use the Contextual Challenge valid for the series in which they are entered for the examination.Contextual challengesOur contextual challenges at AS will give students the freedom to take design risks and innovate in a situation where it is safe to test and refine ideas, giving them the confidence at A level to further develop these skills in their own design brief with a client/end user.It is important to note that candidates will be able choose the route they want to work within, so that they can explore design problems in a field of their owninterest or in an area they want to develop skills.AOs and skills targeted at AS levelGCE Design & Technology 2017 Getting Started GuideBreakdown of assessment objectivesAOs and skills targeted at A levelBreakdown of assessment objectivesNEA AdministrationCoursework submissionsAll paper submission should be made on A3 paper; the work should be well bound and easy to access. The work needs to be clearly labelled with name andcentre/candidate number.Electronic submissions are permitted but should be as PowerPoints or PDF. It isimportant that the work on electronic submissions can be read easily in full screen format without the need to zoom in on parts of the page.GCE Design & Technology 2017 Getting Started GuideGuidance in applying the assessment criteriaThe following points may help when establishing a final mark for the student’swork:• read through the student’s work to form an overall impr ession of the level ofresponse achieved• study the evidence presented by the student for each assessment criterion• read the level of response descriptors for each assessment criterion and identify the group of statements that offer the ‘best fit’ for a student’s work• match the evidence presented and the individual statements available to further refine the range of marks, e.g. 10-14, to establish a final score within that range.Where ‘best fit’ bridges two levels of response, e.g. medium and high, and where perhaps two level statements from the high level are met and the rest firmly within the medium level, it would be acceptable to place the overall level of responsewithin the bottom one or two marks of the high level of response category. More statements met from the high level category would earn further credit in thatsection. Similarly, if most of the statements in the medium level of responsecategory were met, but one or two were in the low level of response category, the likely overall mark would be at the low end of the medium level category. Morestatements judged to be in the low level of response category would lower theoverall mark accordingly. This type of refinement is more likely to be necessarywhere a more substantial range of marks is available at each level of response. The maximum mark range in any group of level descriptors is five.Internal standardisationInternally assessed work must be marked in accordance with the assessmentcriteria stated in the specification and any guidance in subject-specific instructions for the conduct of examinations. Where more than one teacher has been involved in the assessment of the candidate’s work, then the work should be internallystandardised. This involves a comparison of marking between the submittingteachers and an agreement to adjust marking where it is agreed to be lenient orsevere. The final marks should then be sent Edexcel after adjustments have been made. It is important that conversations between colleagues are honest and open, allowing colleagues to air concerns if they have them. Where significantdiscrepancies are found between teachers in a sample during moderation, it cancause serious consequences for candidates during the moderation process.Coursework assessment booklets (CAB)The CAB is completed for every candidate in the centre. The candidates and teacher need to sign the relevant section in the CAB to confirm the work is the candidate’s own. The teacher records the marks in the CAB and annotates the booklet toconfirm how the marks awarded relate to the marking criteria.The indication as to how marks have been awarded should:●be clear and unambiguous●be appropriate to the nature and form of the courseworkGCE Design & Technology 2017 Getting Started Guide●facilitate the standardisation of marking within your centre●enable the moderator to check that the assessment criteria have been appliedin the marking.Photographic evidence is also included in the CAB of the practical outcome. The photographs should:●be limited to a maximum of three (any extras can be added to the portfolioitself)●be clear and easily to read●not be enhanced or adjusted in any way prior to processing.It is the responsibility of the centre to make sure that the photographs evidence the detail needed to justify the marks asked. A failure to submit photographic evidence will result in marks not being upheld if it is not clear to the moderator.<header>。
NEA Exemplar 4: An investigation into scree characteristics in the Lake District National Park Part 2: Examiner commentary - Version 1.1A Level GeographyPearson Edexcel Level 3 Advanced GCE in Geography (9GE0)An investigation into scree characteristics in the Lake District National Park Introduction (maximum 12 marks)Route to enquiry guidanceIt was thought that this project was secure in level 3. This was because it demonstrates accurate and relevant geographical knowledge and understanding of location, geographical theory and comparative context throughout (AO1).It is important to realise that this criterion is encouraging the students to demonstrate their relevant geographical knowledge throughout the project and not just in the introduction. The student has demonstrated this throughout the project such as p3-6 and p13 in the analysis section and p28 in the conclusion section. There is clear understanding shown in the explanations of the factors that might affect scree slopes.Applies understanding to find coherent and relevant links between the investigation’s context and a broader geographical context (AO2). This was shown by linking the screes of the cirques of the Lake District to those at Wast Water as well as to those in Canada on p2 in the Introduction and p32 in the conclusion.Investigates a wide range of relevant geographical sources in order to identify/obtain accurate geographical information and data that support the investigation; research information is used to construct a justified aim, question or hypothesis that provides an appropriate framework for investigation at a manageable scale; planned enquiry process is logically structured and comprehensive (AO3). There was a very broad range that was used throughout the project. There were easily accessible sources from the internet ((ndforms.eu, n.d.) as well as textbooks including Collard (1995) and Small (1989). There were also academic papers such as Andrews 2017 as well as classic older text books such as Sugden & John, 1976. It is important to note that these sources are readily availablefor a topic such a s this but such ‘university style’ references (such as Andrews, 2017) are not necessary other investigations. It was, however, pleasing to see these references used throughout the project.The Investigation might have been improved by using some higher definition maps – the student suggests using an OS map on p8 and it is recommended that the Introduction would have been better with an OS map and a photograph of the sites to be visited. The maps might also have been better if they had been integrated into the text.Fieldwork (maximum 10 marks)Route to enquiry guidanceIt was thought that this project was secure in level 3. This was because the student chooses appropriate methods to collect a range of data and information relevant to the geographical topic (A03). The student used appropriate methods such as Callieux roundness p9 slope angle p9 sediment size p11.Designs a valid sampling framework explicitly linked and appropriate to the geographical focus being investigated (AO3).Considers both frequency and timing of observations (AO3). Spatial sampling was discussed on p8 and p9 and the reasons for different sampling techniques such as systematic and random were explained.Research planning shows appropriate and relevant understanding of the ethical dimensions of field research methods (AO3). The student considers the ethical dimension of their work p11 and 12.Obtains reliable data and information as a result of consistent use of methods with high levels of accuracy/precision (AO3). The use of the Suunto clinometer p9 was one element of the student’s data being precise as it gives a more precise reading than a plastic gun clinometer. In addition the use of callipers was also thought that the data would be collected with a high degree of accuracy.Although there is no compulsory structure many students might find it easier to tabulate this section. Although the data has been collected as a group it is only this student who was investigating the influences on slope angle and so satisfies the criteria for an independentinvestigation. The investigation could also have been improved if the student had explained how they had collected the scree material using the quadrat such as ‘I turned my back and reached behind me for a piece of scree to ensure that I wasn’t bein g selective, even unconsciously’Data representation analysis interpretation evaluation of interpretation evaluation of techniques and methodologies (maximum mark 24)Route to enquiry guidanceIt was thought that this project was level 4. This was because the student uses appropriate geographical skills to deconstruct data in order to show evidenced connections and accurate statistical/geographical significance of data (AO3.)There was a range of geographical skills such as box and whisker p14, line graphs p19 scatter plots p16 and a vane graph p26. There was also the use of statistical techniques such as Spearman’s rank p17 and Chi squared p19 and the use of table to assess the significance of the data p17 and 20.Provides detailed and balanced appraisal of techniques and methodologies used including: o ethical dimensions of field researcho utility and validity of chosen methodologies (AO3).In this case it is probably better to consider that appraisal is a form of evaluation. As with all the criteria evidence can be found throughout the project – in this case there is an appraisal on p 11-12 and again in the evaluation section p31.Synthesises research findings coherently to form rational evidence based conclusions (AO3). Communicates convincing conclusions that are supported by the clear and technically accurate presentation of relevant fieldwork data or information (AO3). The student has a good discussion of the results on p17 and 18 with good links to theory and particularly technical language.The student could have developed how geology might have influenced their results further by detailing secondary information on weathering rates that is widely available in both text books as well as published work.Conclusions and critical evaluations of the overall investigation (maximum mark 24) Route to enquiry guidanceIt was thought that this project was secure in level 4. This was because the student demonstrates accurate and relevant geographical knowledge and understanding of location, geographical theory and comparative context throughout (AO1). Again the key word is throughout and not just in a section titled conclusion. This was shown throughout the project as explained in the Introduction section.Applies understanding to find coherent and relevant links between the investigation’s conclusions and a broader geographical context (AO2). The broader geographical context was comparing the results to a paper published on screes in Canada p32.Synthesises research findings coherently and comprehensively (AO3). Provides a balanced appraisal of the reliability of evidence and validity of conclusions (AO3). A balanced and concise, well-developed argument is expressed through sustained logical lines of reasoning that demonstrates use of a structured and comprehensive enquiry process. Uses accurate geographical terminology (AO3). There is a sound developed argument through the explanation of results as well as the evaluation of the project p30-32. There is good use of accurate geographical terminology.Convincing conclusions are supported by drawing together a selection of relevant evidence and concepts linked to the entire purpose of the investigation (AO3). The student does make evidenced evaluated conclusions p28 as well as an overall appraisal of the aim p33.Although not all aspects of the enquiry have been evaluated (such as the site(s)) there is an evaluation of the methodology, as well as the results and conclusion and as a result it is thought that this is sufficient to place the answer in level 4. It is important to note that the investigation is overlong mainly as a result of the choice of five cirques – although this was clearly driven by the nature of the group work that was undertaken during the fieldwork investigation. It is felt that comparing one cirque with another would have generated sufficient data for a meaningful investigation.Even if the student had put the sub questions and fieldwork into a table the project is 5000 words notwithstanding words in tables and graphs and so is outside the +/- 10% of the recommended word guide of 3000-4000. Although there is no penalty for this, the extra time spent on analysing five instead of one cirque does not really gain the student any extra marks.It is important to note that the fieldwork was carried out in a group with expert supervision provided by both the student’s teach er as well as a third party organisation that provides fieldwork expertise to ensure that all risk assessments have been carried out and are applied. In this case the teacher advised the student not to ascend above 600m. It is therefore not recommended that this type of project is suitable to be replicated by an individual working without such supervision.Overall, although there are areas where the investigation could be improved, it was felt that this was still a top level write up.。
Advances in Applied Mathematics 应用数学进展, 2023, 12(3), 1054-1067 Published Online March 2023 in Hans. https:///journal/aam https:///10.12677/aam.2023.123107Legendre 谱方法求解第二类Fredholm 积分方程董帅鑫1,陈 冲2*1西华师范大学数学与信息学院,四川 南充 2西华师范大学公共数学学院,四川 南充收稿日期:2023年2月15日;录用日期:2023年3月11日;发布日期:2023年3月20日摘要本文提出了非奇异的第二类Fredholm 积分方程求解的Legendre 谱方法。
首先作积分变换,然后应用Legendre-Gauss 求积公式与级数展开法分别对积分项与未知函数做近似,再对变换后的积分方程求近似解,并进行误差分析,最后通过数值算例,验证了该方法的可行性与有效性。
关键词第二类Fredholm 积分方程,Legendre-Gauss 求积公式,级数展开法The Legendre Spectral Method for Numerical Solution of the Second Fredholm Integral EquationShuaixin Dong 1, Chong Chen 2*1College of Mathematics and Information, China West Normal University, Nanchong Sichuan 2College of Mathematics Education, China West Normal University, Nanchong SichuanReceived: Feb. 15th , 2023; accepted: Mar. 11th , 2023; published: Mar. 20th , 2023AbstractIn this paper, a Legendre spectral method for solving the second Fredholm integral equation is presented. Firstly, the integral transformation is performed, and then the Legendre-Gauss qua-*通讯作者。
coh-metrix英文介绍Coh-Metrix: A Comprehensive Analytical Tool for Evaluating Text CoherenceCoh-Metrix is a powerful software tool that has revolutionized the way we analyze and assess the coherence of written texts. Developed by a team of researchers at the University of Memphis, Coh-Metrix provides a comprehensive and in-depth evaluation of the linguistic and cognitive properties of text, enabling researchers, educators, and writers to gain a deeper understanding of the factors that contribute to effective communication.At its core, Coh-Metrix is a computational linguistics-based system that measures various aspects of text cohesion and coherence. It analyzes a wide range of linguistic features, including lexical diversity, syntactic complexity, semantic relationships, and discourse-level organization. By leveraging sophisticated algorithms and natural language processing techniques, Coh-Metrix generates a detailed report that sheds light on the overall coherence of a given text, as well as the specific areas where coherence may be lacking or could be improved.One of the key advantages of Coh-Metrix is its ability to provide a multifaceted analysis of a text. Unlike traditional readability formulas that focus solely on surface-level features such as word length and sentence complexity, Coh-Metrix delves deeper into the cognitive and linguistic processes that underlie text comprehension. It examines the relationships between words, the flow of ideas, the use of referential and causal connections, and the overall cohesion of the text.The Coh-Metrix system is particularly useful in a variety of applications, including educational assessment, content analysis, and text generation. In the educational domain, teachers and researchers can use Coh-Metrix to evaluate the coherence of student writing, identify areas for improvement, and provide targeted feedback to help students develop stronger writing skills. Additionally, Coh-Metrix can be employed in the assessment of textbooks, instructional materials, and other educational resources to ensure that the content is well-structured and accessible to students.In the realm of content analysis, Coh-Metrix has proven invaluable for researchers and professionals who need to analyze large volumes of text data. By automating the process of evaluating text coherence, Coh-Metrix enables researchers to quickly and consistently assess the quality and effectiveness of written materials, such as news articles, marketing content, or policy documents. This, in turn, allowsfor more informed decision-making and the development of more effective communication strategies.Furthermore, Coh-Metrix has applications in the field of text generation, where it can be used to assess the coherence of automatically generated texts. This is particularly relevant in the development of intelligent writing assistants, chatbots, and other natural language generation systems, where ensuring the coherence and readability of the output is crucial for effective communication.One of the key strengths of Coh-Metrix is its ability to adapt to different genres and writing styles. Whether analyzing academic essays, scientific reports, or creative fiction, the tool provides a comprehensive and nuanced evaluation of the text's coherence. This flexibility is crucial in a world where written communication takes on many forms and serves diverse purposes.In addition to its analytical capabilities, Coh-Metrix also offers valuable insights into the cognitive processes involved in text comprehension. By examining the linguistic and discourse-level features of a text, the tool helps researchers and educators better understand how readers interact with and make sense of written information. This knowledge can then be used to inform the development of more effective instructional strategies, writing interventions, and reading support tools.As the field of natural language processing and computational linguistics continues to advance, the importance of tools like Coh-Metrix is only likely to grow. With its ability to provide detailed and objective assessments of text coherence, Coh-Metrix has become an indispensable resource for researchers, educators, and writers who are committed to improving the quality and effectiveness of written communication.In conclusion, Coh-Metrix is a groundbreaking tool that has transformed the way we analyze and understand the coherence of written texts. By leveraging sophisticated computational techniques, Coh-Metrix offers a comprehensive and multifaceted evaluation of the linguistic and cognitive factors that contribute to effective communication. As we continue to navigate the ever-evolving landscape of written expression, tools like Coh-Metrix will undoubtedly play a crucial role in shaping the future of text analysis and enhancing the quality of our written communication.。
a r X i v :n l i n /0012025v 3 [n l i n .S I ] 10 M a y 2001On the Asymptotic Expansion of the Solutions of the Separated Nonlinear Schr¨o dinger EquationA.A.Kapaev,St Petersburg Department of Steklov Mathematical Institute,Fontanka 27,St Petersburg 191011,Russia,V.E.Korepin,C.N.Yang Institute for Theoretical Physics,State University of New York at Stony Brook,Stony Brook,NY 11794-3840,USAAbstractNonlinear Schr¨o dinger equation with the Schwarzian initial data is important in nonlinear optics,Bose condensation and in the theory of strongly correlated electrons.The asymptotic solutions in the region x/t =O (1),t →∞,can be represented as a double series in t −1and ln t .Our current purpose is the description of the asymptotics of the coefficients of the series.MSC 35A20,35C20,35G20Keywords:integrable PDE,long time asymptotics,asymptotic expansion1IntroductionA coupled nonlinear dispersive partial differential equation in (1+1)dimension for the functions g +and g −,−i∂t g +=12∂2x g −+4g 2−g +,(1)called the separated Nonlinear Schr¨o dinger equation (sNLS),contains the con-ventional NLS equation in both the focusing and defocusing forms as g +=¯g −or g +=−¯g −,respectively.For certain physical applications,e.g.in nonlin-ear optics,Bose condensation,theory of strongly correlated electrons,see [1]–[9],the detailed information on the long time asymptotics of solutions with initial conditions rapidly decaying as x →±∞is quite useful for qualitative explanation of the experimental phenomena.Our interest to the long time asymptotics for the sNLS equation is inspired by its application to the Hubbard model for one-dimensional gas of strongly correlated electrons.The model explains a remarkable effect of charge and spin separation,discovered experimentally by C.Kim,Z.-X.M.Shen,N.Motoyama,H.Eisaki,hida,T.Tohyama and S.Maekawa [19].Theoretical justification1of the charge and spin separation include the study of temperature dependent correlation functions in the Hubbard model.In the papers[1]–[3],it was proven that time and temperature dependent correlations in Hubbard model can be described by the sNLS equation(1).For the systems completely integrable in the sense of the Lax representa-tion[10,11],the necessary asymptotic information can be extracted from the Riemann-Hilbert problem analysis[12].Often,the fact of integrability implies the existence of a long time expansion of the generic solution in a formal series, the successive terms of which satisfy some recurrence relation,and the leading order coefficients can be expressed in terms of the spectral data for the associ-ated linear system.For equation(1),the Lax pair was discovered in[13],while the formulation of the Riemann-Hilbert problem can be found in[8].As t→∞for x/t bounded,system(1)admits the formal solution given byg+=e i x22+iν)ln4t u0+∞ n=12n k=0(ln4t)k2t −(1t nv nk ,(2)where the quantitiesν,u0,v0,u nk and v nk are some functions ofλ0=−x/2t.For the NLS equation(g+=±¯g−),the asymptotic expansion was suggested by M.Ablowitz and H.Segur[6].For the defocusing NLS(g+=−¯g−),the existence of the asymptotic series(2)is proven by P.Deift and X.Zhou[9] using the Riemann-Hilbert problem analysis,and there is no principal obstacle to extend their approach for the case of the separated NLS equation.Thus we refer to(2)as the Ablowitz-Segur-Deift-Zhou expansion.Expressions for the leading coefficients for the asymptotic expansion of the conventional NLS equation in terms of the spectral data were found by S.Manakov,V.Zakharov, H.Segur and M.Ablowitz,see[14]–[16].The general sNLS case was studied by A.Its,A.Izergin,V.Korepin and G.Varzugin[17],who have expressed the leading order coefficients u0,v0andν=−u0v0in(2)in terms of the spectral data.The generic solution of the focusing NLS equation contains solitons and radiation.The interaction of the single soliton with the radiation was described by Segur[18].It can be shown that,for the generic Schwarzian initial data and generic bounded ratio x/t,|c−xthese coefficients as well as for u n,2n−1,v n,2n−1,wefind simple exact formulaeu n,2n=u0i n(ν′)2n8n n!,(3)and(20)below.We describe coefficients at other powers of ln t using the gener-ating functions which can be reduced to a system of polynomials satisfying the recursion relations,see(24),(23).As a by-product,we modify the Ablowitz-Segur-Deift-Zhou expansion(2),g+=exp i x22+iν)ln4t+i(ν′)2ln24t2] k=0(ln4t)k2t −(18t∞n=02n−[n+1t n˜v n,k.(4)2Recurrence relations and generating functions Substituting(2)into(1),and equating coefficients of t−1,wefindν=−u0v0.(5) In the order t−n,n≥2,equating coefficients of ln j4t,0≤j≤2n,we obtain the recursion−i(j+1)u n,j+1+inu n,j=νu n,j−iν′′8u n−1,j−2−−iν′8u′′n−1,j+nl,k,m=0l+k+m=nα=0, (2)β=0, (2)γ=0, (2)α+β+γ=ju l,αu k,βv m,γ,(6) i(j+1)v n,j+1−inv n,j=νv n,j+iν′′8v n−1,j−2++iν′8v′′n−1,j+nl,k,m=0l+k+m=nα=0, (2)β=0, (2)γ=0, (2)α+β+γ=ju l,αv k,βv m,γ,(7)where the prime means differentiation with respect toλ0=−x/(2t).Master generating functions F(z,ζ),G(z,ζ)for the coefficients u n,k,v n,k are defined by the formal seriesF(z,ζ)= n,k u n,k z nζk,G(z,ζ)= n,k v n,k z nζk,(8)3where the coefficients u n,k,v n,k vanish for n<0,k<0and k>2n.It is straightforward to check that the master generating functions satisfy the nonstationary separated Nonlinear Schr¨o dinger equation in(1+2)dimensions,−iFζ+izF z= ν−iν′′8zζ2 F−iν′8zF′′+F2G,iGζ−izG z= ν+iν′′8zζ2 G+iν′8zG′′+F G2.(9) We also consider the sectional generating functions f j(z),g j(z),j≥0,f j(z)=∞n=0u n,2n−j z n,g j(z)=∞n=0v n,2n−j z n.(10)Note,f j(z)≡g j(z)≡0for j<0because u n,k=v n,k=0for k>2n.The master generating functions F,G and the sectional generating functions f j,g j are related by the equationsF(zζ−2,ζ)=∞j=0ζ−j f j(z),G(zζ−2,ζ)=∞j=0ζ−j g j(z).(11)Using(11)in(9)and equating coefficients ofζ−j,we obtain the differential system for the sectional generating functions f j(z),g j(z),−2iz∂z f j−1+i(j−1)f j−1+iz∂z f j==νf j−z iν′′8f j−ziν′8f′′j−2+jk,l,m=0k+l+m=jf k f lg m,2iz∂z g j−1−i(j−1)g j−1−iz∂z g j=(12)=νg j+z iν′′8g j+ziν′8g′′j−2+jk,l,m=0k+l+m=jf kg l g m.Thus,the generating functions f0(z),g0(z)for u n,2n,v n,2n solve the systemiz∂z f0=νf0−z (ν′)28g0+f0g20.(13)The system implies that the product f0(z)g0(z)≡const.Since f0(0)=u0and g0(0)=v0,we obtain the identityf0g0(z)=−ν.(14) Using(14)in(13),we easilyfindf0(z)=u0e i(ν′)28n n!z n,4g0(z)=v0e−i(ν′)28n n!z n,(15)which yield the explicit expressions(3)for the coefficients u n,2n,v n,2n.Generating functions f1(z),g1(z)for u n,2n−1,v n,2n−1,satisfy the differential system−2iz∂z f0+iz∂z f1=νf1−z iν′′8f1−ziν′8g0−z(ν′)24g′0+f1g20+2f0g0g1.(16)We will show that the differential system(16)for f1(z)and g1(z)is solvable in terms of elementary functions.First,let us introduce the auxiliary functionsp1(z)=f1(z)g0(z).These functions satisfy the non-homogeneous system of linear ODEs∂z p1=iν4−ν′′4f′0z(p1+q1)−i(ν′)28−ν′g0,(17)so that∂z(q1+p1)=−(ν2)′′8z,p1(z)= −iνν′′8−ν′u′032z2,g1(z)=q1(z)g0(z),g0(z)=v0e−i(ν′)24−ν′′4v0 z+i(ν′)2ν′′4−ν′′4u0 ,v1,1=v0 iνν′′8−ν′v′0u n,2n −1=−2u 0i n −1(ν′)2(n −1)n −1ν′′u 0,n ≥2,v n,2n −1=−2v 0(−i )n −1(ν′)2(n −1)n −1ν′′v 0,n ≥2.Generating functions f j (z ),g j (z )for u n,2n −j ,v n,2n −j ,j ≥2,satisfy the differential system (12).Similarly to the case j =1above,let us introduce the auxiliary functions p j and q j ,p j =f jg 0.(21)In the terms of these functions,the system (12)reads,∂z p j =iνz(p j +q j )+b j ,(22)wherea j =2∂z p j −1+i (ν′)28−j −14(p j −1f 0)′8f 0+iν4−ν′′zq j −1−−ν′g 0+i(q j −2g 0)′′zj −1 k,l,m =0k +l +m =jp k q l q m .(23)With the initial condition p j (0)=q j (0)=0,the system is easily integrated and uniquely determines the functions p j (z ),q j (z ),p j (z )= z 0a j (ζ)dζ+iνzdζζζdξ(a j (ξ)+b j (ξ)).(24)These equations with expressions (23)together establish the recursion relationfor the functions p j (z ),q j (z ).In terms of p j (z )and q j (z ),expansion (2)readsg +=ei x22+iν)ln 4t +i(ν′)2ln 24tt2t−(18tv 0∞ j =0q j ln 24tln j 4t.(25)6Let a j (z )and b j (z )be polynomials of degree M with the zero z =0of multiplicity m ,a j (z )=M k =ma jk z k,b j (z )=Mk =mb jk z k .Then the functions p j (z )and q j (z )(24)arepolynomials of degree M +1witha zero at z =0of multiplicity m +1,p j (z )=M +1k =m +11k(a j,k −1+b j,k −1)z k ,q j (z )=M +1k =m +11k(a j,k −1+b j,k −1) z k.(26)On the other hand,a j (z )and b j (z )are described in (23)as the actions of the differential operators applied to the functions p j ′,q j ′with j ′<j .Because p 0(z )=q 0(z )≡1and p 1(z ),q 1(z )are polynomials of the second degree and a single zero at z =0,cf.(19),it easy to check that a 2(z )and b 2(z )are non-homogeneous polynomials of the third degree such thata 2,3=−(ν′)4(ν′′)2210(2+iν),(27)a 2,0=−iνν′′8−ν′u ′08u 0,b 2,0=iνν′′8−ν′v ′08v 0.Thus p 2(z )and q 2(z )are polynomials of the fourth degree with a single zero at z =0.Some of their coefficients arep 2,4=q 2,4=−(ν′)4(ν′′)24−(1+2iν)ν′′8u 0−ν(u ′0)24−(1−2iν)ν′′8v 0−ν(v ′0)22.Proof .The assertion holds true for j =0,1,2.Let it be correct for ∀j <j ′.Then a j ′(z )and b j ′(z )are defined as the sum of polynomials.The maximal de-grees of such polynomials are deg (p j ′−1f 0)′/f 0 =2j ′−1,deg (q j ′−1g 0)′/g 0 =72j′−1,anddeg 1z j′−1 α,β,γ=0α+β+γ=j′pαqβqγ =2j′−1. Thus deg a j′(z)=deg b j′(z)≤2j′−1,and deg p j′(z)=deg q j′(z)≤2j′.Multiplicity of the zero at z=0of a j′(z)and b j′(z)is no less than the min-imal multiplicity of the summed polynomials in(23),but the minor coefficients of the polynomials2∂z p j′−1and−(j−1)p j′−1/z,as well as of2∂z q j′−1and −(j−1)q j′−1/z may cancel each other.Let j′=2k be even.Thenm j′=min m j′−1;m j′−2+1;minα,β,γ=0,...,j′−1α+β+γ=j′mα+mβ+mγ =j′2 . Let j′=2k−1be odd.Then2m j′−1−(j′−1)=0,andm j′=min m j′−1+1;m j′−2+1;minα,β,γ=0,...,j′−1α+β+γ=j′mα+mβ+mγ =j′+12]p j,k z k,q j(z)=2jk=[j+12]z nn−[j+18k k!,g j(z)=v0∞n=[j+12]k=max{0;n−2j}q j,n−k(−i)k(ν′)2k2]k=max{0;n−2j}p j,n−ki k(ν′)2k2]k=max{0;n−2j}q j,n−k(−i)k(ν′)2kIn particular,the leading asymptotic term of these coefficients as n→∞and j fixed is given byu n,2n−j=u0p j,2j i n−2j(ν′)2(n−2j)n) ,v n,2n−j=v0q j,2j (−i)n−2j(ν′)2(n−2j)n) .(32)Thus we have reduced the problem of the evaluation of the asymptotics of the coefficients u n,2n−j v n,2n−j for large n to the computation of the leading coefficients of the polynomials p j(z),q j(z).In fact,using(24)or(26)and(23), it can be shown that the coefficients p j,2j,q j,2j satisfy the recurrence relationsp j,2j=−i (ν′)2ν′′2jj−1k,l,m=0k+l+m=jp k,2k p l,2l q m,2m++ν(ν′)2ν′′4j2j−1k,l,m=0k+l+m=jp k,2k(p l,2l−q l,2l)q m,2m,q j,2j=i (ν′)2ν′′2jj−1k,l,m=0k+l+m=jp k,2k q l,2l q m,2m−(33)−ν(ν′)2ν′′4j2j−1k,l,m=0k+l+m=jp k,2k(p l,2l−q l,2l)q m,2m.Similarly,the coefficients u n,0,v n,0for the non-logarithmic terms appears from(31)for j=2n,and are given simply byu n,0=u0p2n,n,v n,0=v0q2n,n.(34) Thus the problem of evaluation of the asymptotics of the coefficients u n,0,v n,0 for n large is equivalent to computation of the asymptotics of the minor coeffi-cients in the polynomials p j(z),q j(z).However,the last problem does not allow a straightforward solution because,according to(8),the sectional generating functions for the coefficients u n,0,v n,0are given byF(z,0)=∞n=0u n,0z n,G(z,0)=∞n=0v n,0z n,and solve the separated Nonlinear Schr¨o dinger equation−iFζ+izF z=νF+18zG′′+F G2.(35)93DiscussionOur consideration based on the use of generating functions of different types reveals the asymptotic behavior of the coefficients u n,2n−j,v n,2n−j as n→∞and jfixed for the long time asymptotic expansion(2)of the generic solution of the sNLS equation(1).The leading order dependence of these coefficients on n is described by the ratio a n2+d).The investigation of theRiemann-Hilbert problem for the sNLS equation yielding this estimate will be published elsewhere.Acknowledgments.We are grateful to the support of NSF Grant PHY-9988566.We also express our gratitude to P.Deift,A.Its and X.Zhou for discussions.A.K.was partially supported by the Russian Foundation for Basic Research under grant99-01-00687.He is also grateful to the staffof C.N.Yang Institute for Theoretical Physics of the State University of New York at Stony Brook for hospitality during his visit when this work was done. References[1]F.G¨o hmann,V.E.Korepin,Phys.Lett.A260(1999)516.[2]F.G¨o hmann,A.R.Its,V.E.Korepin,Phys.Lett.A249(1998)117.[3]F.G¨o hmann,A.G.Izergin,V.E.Korepin,A.G.Pronko,Int.J.Modern Phys.B12no.23(1998)2409.[4]V.E.Zakharov,S.V.Manakov,S.P.Novikov,L.P.Pitaevskiy,Soli-ton theory.Inverse scattering transform method,Moscow,Nauka,1980.[5]F.Calogero,A.Degasperis,Spectral transforms and solitons:toolsto solve and investigate nonlinear evolution equations,Amsterdam-New York-Oxford,1980.[6]M.J.Ablowitz,H.Segur,Solitons and the inverse scattering trans-form,SIAM,Philadelphia,1981.10[7]R.K.Dodd,J.C.Eilbeck,J.D.Gibbon,H.C.Morris,Solitons andnonlinear wave equations,Academic Press,London-Orlando-San Diego-New York-Toronto-Montreal-Sydney-Tokyo,1982.[8]L.D.Faddeev,L.A.Takhtajan,Hamiltonian Approach to the Soli-ton Theory,Nauka,Moscow,1986.[9]P.Deift,X.Zhou,Comm.Math.Phys.165(1995)175.[10]C.S.Gardner,J.M.Greene,M.D.Kruskal,R.M.Miura,Phys.Rev.Lett.19(1967)1095.[11]x,Comm.Pure Appl.Math.21(1968)467.[12]V.E.Zakharov,A.B.Shabat,Funkts.Analiz Prilozh.13(1979)13.[13]V.E.Zakharov,A.B.Shabat,JETP61(1971)118.[14]S.V.Manakov,JETP65(1973)505.[15]V.E.Zakharov,S.V.Manakov,JETP71(1973)203.[16]H.Segur,M.J.Ablowitz,J.Math.Phys.17(1976)710.[17]A.R.Its,A.G.Izergin,V.E.Korepin,G.G.Varzugin,Physica D54(1992)351.[18]H.Segur,J.Math.Phys.17(1976)714.[19]C.Kim,Z.-X.M.Shen,N.Motoyama,H.Eisaki,hida,T.To-hyama and S.Maekawa Phys Rev Lett.82(1999)802[20]A.R.Its,SR Izvestiya26(1986)497.11。
a r X i v :a s t r o -p h /0506419v 1 17 J u n 2005To appear in ApJLPreprint typeset using L A T E X style emulateapj v.6/22/04A COHERENT TIMING SOLUTION FOR THE NEARBY ISOLATED NEUTRON STAR RX J0720.4−3125D.L.Kaplan 1,2and M.H.van Kerkwijk 3To appear in ApJLABSTRACTWe present the results of a dedicated effort to measure the spin-down rate of the nearby isolated neutron star RX J0720.4−paring arrival times of the 8.39-sec pulsations for data from Chandra we derive an unambiguous timing solution for RX J0720.4−3125that is accurate to <0.1cycles over >5years.Adding data from XMM and ROSAT ,the final solution yields ˙P=(6.98±0.02)×10−14s s −1;for dipole spin-down,this implies a characteristic age of 2Myr and a magnetic field strength of 2.4×1013G.The phase residuals are somewhat larger than those for purely regular spin-down,but do not show conclusive evidence for higher-order terms or a glitch.From our timing solution as well as recent X-ray spectroscopy,we concur with recent suggestions that RX J0720.4−3125is most likely an off-beam radio pulsar with a moderately high magnetic field.Subject headings:pulsars:individual (RX J0720.4−3125)—stars:neutron —X-rays:stars1.INTRODUCTIONOne of the interesting results from ROSAT All-Sky Survey (Voges et al.1996)was the discovery of seven ob-jects that appear to be nearby,thermally-emitting neu-tron stars that have little if any magnetospheric emis-sion (see Haberl 2004for a review).These objects,known most commonly as “isolated neutron stars,”are distinguished by their long periods ( 3s,when mea-sured),largely thermal spectra with cool temperatures (kT 100eV),faint optical counterparts (when de-tected),and lack of radio emission.It is not yet clear what sets the isolated neutron stars apart from the nearby,relatively young rotation-powered pulsars that also have cool thermal emission —sources like PSR B0656+14and PSR B1055−52—which tend to have short (<1s)spin periods,∼1012-G magnetic fields,non-thermal (i.e.power-law)components in their X-ray spectra,and radio pulsations (e.g.,Pavlov &Zavlin 2003;Kaplan 2004).The isolated neutron stars are known to have longer periods,but their spin-down rates (and hence magnetic fields )are unknown,largely be-cause it has not yet been possible to determine a reliable,coherent timing solution (Kaplan et al.2002,hereafter Paper I;Zane et al.2002).In this Letter we report a new analysis of the varia-tions of the 8.39-s period of the second brightest source of the group,RX J0720.4−3125(Haberl et al.1997).We describe our analysis of Chandra data obtained specifically for timing purposes,as well as archival ROSAT ,Chandra ,and XMM data,in §2.In §3,we show that with the new data,we can avoid the pitfalls of the previous phase-coherent timing analyses and obtain a reliable timing solution.We discuss possible timing noise in §4and the implications of our result in §5.1Pappalardo Fellow2Center for Space Research,Massachusetts Institute of Technol-ogy,77Massachusetts Avenue,37-664D,Cambridge,MA 02139,USA;dlk@3Department of Astronomy and Astrophysics,University of Toronto,60St.George Street,Toronto,ON M5S 3H8,Canada;mhvk@astro.utoronto.ca2.OBSERVATIONSOur primary data were eight observations with the Advanced CCD Imaging Spectrometer (ACIS;Garmire et al.2003)aboard the Chandra X-ray Observa-tory (CXO ;Weisskopf et al.2000).These were designed for timing accuracy,consisting of two sets of four expo-sures geometrically spaced over a period of about two weeks and separated by about half a year.We combined these with data from other Chandra observations,as well as from observations with XMM-Newton (Jansen et al.2001)and ROSAT (Tr¨u mper 1993).A log of all obser-vations is given in Table 1.For the Chandra data,we processed the level-1event lists to the level-2stage following standard procedures and the latest calibration set (CALDB version 3.0.0).For the ACIS continuous-clocking data,this includes correcting the recorded event times for readout,dither,and spacecraft motion —corrections that used to re-quire additional steps (Zavlin et al.2000).We ex-tracted events within 1′′of the source,and then ap-plied a clock correction of 284.7µs to the arrival times (Davis,Holmes,&Myers 2003);the arrival times should now be accurate to 6µs.For the HRC-S/LETG data,we extracted zeroth-order events from a circle with ra-dius 10pixels (1.′′3),and first-order events using the stan-dard LETG spectral extraction windows,but limited to 10≤λ≤65˚A .Finally,we used the axbary program to barycenter all of the events (using the optical po-sition:αJ2000=07h 20m 24.s 96,δJ2000=−31◦25′50.′′2;Kaplan et al.2003)For the XMM data,we used the standard procedures emchain and epchain (XMMSAS version 6.1.0)to repro-cess the observations.One additional step was necessary for the PN data set 622-U2,for which we found a small number of duplicate events (frames 963685–963719);we removed these before processing.Next,we extracted all single-pixel events within 37.′′5of the source position,and used barycen to convert the arrival times to the solar-system barycenter 4.4Some portions of the 2000and 2002XMM /PN ob-servations were affected by a known processing problem2Kaplan&van KerkwijkTABLE1Log of Observations and Times of ArrivalInstrument a ID b Date Exp.Counts TOA c(ks)(MJD)PSPC......3381993-09-27 3.2580049257.2547031(25)HRI........8841996-11-0333.71266250391.3006530(16)HRI........9441998-04-208.1307450925.6881172(36)HRC........3682000-02-01 5.4347251575.3026910(46)HRC........7452000-02-0226.11514951576.2804856(27)HRC........3692000-02-04 6.1366751578.7722735(65)PN/ff/thin..78-S32000-05-1321.114410451677.2260789(5)MOS2/thin.78-S22000-05-1343.97391551677.4127431(7)PN/ff/med.175-S32000-11-2125.715303751869.8413358(14)MOS1/open175-U22000-11-21 6.81776251869.8433759(14)MOS2/open175-U22000-11-217.22108451869.9571032(6)ACIS-CC...27742001-12-0415.0318*******.7881789(11)ACIS-CC...27732001-12-0510.62284752248.2835843(13)ACIS-CC...27722001-12-06 4.1879052249.6286894(26)PN/ff/thin..533-S32002-11-0628.319984152584.9260561(5)PN/ff/thin..534-S32002-11-0830.221217752587.0013053(4)MOS1/open622-U22003-05-027.61762952761.6222174(14)MOS2/open622-U22003-05-027.51878852761.6226056(12)PN/sw/thick622-U22003-05-0272.821016052761.9950589(5)PN/sw/thin711-S72003-10-2718.111287652939.8228751(9)PN/sw/thick711-S82003-10-2725.013868952939.8228774(8)MOS1/open711-U22003-10-2713.83332352939.8506513(5)MOS2/open711-U22003-10-2713.83563652940.1162720(5)ACIS-CC...46662004-01-0610.11904853010.2635608(14)ACIS-CC...46672004-01-07 4.8893853011.2639869(20)ACIS-CC...46682004-01-11 5.2933453015.5407400(19)ACIS-CC...46692004-01-19 5.2939153023.1274147(23)HRC........53052004-02-2735.72159753062.4142490(27)PN/ff/thin..815-S12004-05-2231.621985553147.6811948(4)ACIS-CC...46702004-08-0310.11743253220.9975987(14)ACIS-CC...46712004-08-05 5.1805153222.2171299(21)ACIS-CC...46722004-08-09 5.1855653226.2443808(25)ACIS-CC...46732004-08-23 5.1713353240.1824669(24)HRC........55812005-01-2367.74480153393.6657119(18)a PSPC:Position Sensitive Proportional Counter(Briel&Pfeffermann1995)aboard ROSAT.HRI:High-Resolution Imager(Zombeck et al.1995)aboardROSAT.HRC:High-Resolution Camera for spectroscopy aboard Chandra(HRC-S;Kraft et al.1997),used with the Low-Energy Transmission Grat-ing.ACIS:Chandra’s Advanced CCD Imaging Spectrometer(Garmire et al.2003),used in continuous clocking mode.EPIC-pn:XMM’s European Pho-ton Imaging Camera with PN detectors(Str¨u der et al.2001),used in full-frame(ff)or small window(sw)mode,with thin,medium,or thickfilter.EPIC-MOS1/2:European Photon Imaging Cameras with MOS detectorsaboard XMM(Turner et al.2001),used in small-window mode with thin orno(open)filter.b Observation identifier(CXO,ROSAT)or revolution number and exposureidentifier(XMM).c The TOA is defined as the time of maximum light closest to the middle ofeach observation,and is given with1-σuncertainties.The reduction of the ROSAT data followed that inPaper I,except that we properly corrected the eventtimes to the Barycentric Dynamical Time(TDB)sys-tem instead of the Coordinated Universal Time(UTC)system returned by the FTOOLS barycentering tasks(seeCropper et al.2004).We used the corrections suppliedin Cox(2000,p.14).that rejected significant portions of the observations;seehttp://xmm.vilspa.esa.es/sas/documentation/watchout/lost_events.shtml. This should not introduce any systematic error,though it meansthat our TOAs for these observations are not as precise as possiblewith all events.However,since the present TOA uncertaintiesare smaller than the timing noise(§4),we decided not to try toremedy this problem.3.TIMING ANALYSISOur goal was to use times-of-arrival(TOAs)to infer a phase-coherent timing solution involving the spin period and its derivative,where each cycle of the source was counted.To measure TOAs we needed an initial refer-ence period,something which we determined using a Z21 test(Rayleigh statistic;Buccheri et al.1983)on the com-bined2004January ACIS and2004February HRC data. Wefind P=8.3911159(10)s(here and below,numbers in parentheses indicate twice the formal1-σuncertain-ties in the last digit unless otherwise indicated),which is consistent with our earlier value(Paper I)but much more accurate because we could coherently connect ob-servations over a much longer(52day)time span. Using this period,we constructed binned light curvesA Timing Solution for RX J0720.4−31253Fig. 1.—Phase residuals for RX J0720.4−3125.The top panelshows the residuals for each TOA compared to a linear(˙ν=0)model.The solid curve gives the best-fit quadratic(˙ν=0,¨ν=0)ephemeris for all data(Tab.2,with a0.27-s systematic uncertaintyadded in quadrature).The vertical dashed line indicates the ref-erence time t0.The bottom panel shows the residuals relative tothe quadratic model.We also show a best-fit cubic model(¨ν=0;dotted line)and a model that includes a glitch in frequency nearMJD52800(∆f≈1×10−9;dashed curve).(with16phase bins)and determined the TOAs byfittinga sinusoid(appropriate for the sinusoidal pulsations ofRX J0720.4−3125;Haberl et al.1997);the uncertaintieswere calculated from the uncertainties in the phases ofthefitted sinusoids(we verified that we obtain consistentresults if we change the binning or measure TOAs usingcross-correlation instead).Here,the TOA is defined asthe time of maximum light closest to the middle of theobservation,a choice which minimizes co-variance withsmall changes in period.We present TOAs for all of thedata in Table1.We then determined a timing solution for only theChandra data using an iterative procedure.Wefirst usedthe reference period to determine cycle counts for thefiveabove-mentioned observations,as well as the next obser-vation closest in time.Wefit these cycle counts toφ(t)=φ0+ν(t−t0)+16¨ν(t−t0)3...,(1)whereφ0is the cycle count plus phase at reference time t0,νis the spin-frequency,˙νis its derivative,¨νis the second derivative.We then iterated,using the improved solution to determine the cycle count for the next ob-servation,etc.We started with˙ν=¨ν=0,but left˙νfree once that significantly improved thefit;¨νwas not required(cf.,§4below).Thefinal ephemeris listed in Table2has small,≤0.1cycle,residuals,andfits the Chandra data well:χ2ν≡χ2/N dof=1.06(with N dof=13degrees of free-dom).To test the uniqueness of our ephemeris,we tried changing the cycle counts(adding or subtracting one or more cycles)at the least unambiguous points,but found that the resulting solutions were very poor(e.g.,alter-ing the cycles between the2001ACIS and2000HRC observations gaveχ2ν=89.26).To improve and extend the ephemeris,we added the XMM and ROSAT data into the solution(see Table2). As for the Chandra data alone,the cycle counts are unambiguous and,as can be seen in Fig.1,the resid-TABLE2X-ray Timing Ephemerides for RX J0720.4−3125 Quantity a CXO only All data b Dates(MJD)51575–5339449257–53394t0(MJD)....53010.2635605(18)53010.2635637(24)ν(Hz)......0.11917366926(46)0.11917366908(38)˙ν(Hz s−1)..−9.97(11)×10−16−9.918(30)×10−16 TOA rms(s)0.180.31χ2/DOF....13.8/13=1.0630.7/31=0.99P(s)........8.391115305(32)8.391115532(26)˙P(s s−1)....7.019(80)×10−146.983(22)×10−14˙E(erg s−1)..4.7×10304.7×1030B dip(G)....2.5×10132.4×1013τchar(yr)....1.9×1061.9×106Note.—Uncertainties quoted are twice the formal1-σuncertainties in thefit.a˙E=1045I454π2ν˙νis the spin-down luminosity(with I=1045I45g cm2the moment of inertia);B dip=3.2×10194Kaplan&van Kerkwijkbyfitting the phase residuals with a third-order(¨ν=0) solution like that shown in Fig.1.This does in fact im-prove thefit—givingχ2ν=6.02for N dof=30with an rms of0.32s—though it is still formally unacceptable. Wefind¨ν≈2.4(4)×10−25Hz s−2(this also changes ˙νby3%from the value in Tab.2),giving a timing noise measurement of∆8≡log10(|¨ν|(108)3/6ν)=−0.5. This value is on the high side of,but not outside the range expected from relations between˙P and∆8found for radio pulsars(Arzoumanian et al.1994)and mag-netars(Woods et al.2000;Gavriil&Kaspi2002).We do not believe it is likely that the third-order solution represents a real long-term change in˙ν,since the value of¨νchanges significantly if one uses just the Chan-dra,Chandra+XMM,or all of the data5[8(6),18(4), or2.4(4)×10−25Hz s−2,withχ2ν=0.64,2.81,or6.02 respectively].A second possibility is a sudden change in rota-tion—a glitch,as proposed(and largely rejected)by de Vries et al.(2004)to account for variations in spec-tral shape(differences of10%in the inferred temper-ature)and pulse shape(changes of50–100%in pulsed fraction)observed between2000and2003.The system-atic increase in the residuals after MJD53000in Fig-ure1might indeed indicate a glitch.We triedfitting a simple glitch model,in which we assumed that only the frequency changed,that the recovery time was longer than the span of our observations,and that the glitch occurred on2003July1(MJD52821),in between the two XMM observations that showed the largest spec-tral change(de Vries et al.2004).Wefind a reasonable fit for a glitch with∆f=1.3×10−9Hz and a recov-ery time>3yr,givingχ2ν=7.7(see Fig.1).This would be a small glitch,with∆f/f=1.1×10−8com-pared to values of10−9to10−6for radio pulsars(with smaller values more typical for larger magneticfields; Lyne,Shemar,&Smith2000).It also implies that ener-getically,the putative glitch would be insignificant:the change in kinetic energy of∼1036ergs(van Riper et al. 1991)would only be noticeable if dissipated in<1day given the bolometric luminosity of RX J0720.4−3125of 2×1032d2300ergs s−1(where d=300d300pc is the dis-tance to RX J0720.4−3125;Kaplan et al.2003).In prin-ciple,however,it could still have altered the light curve and spectrum of RX J0720.4−3125through realignment of the magneticfield relative to the spin axis. Finally,a more mundane explanation for the rela-tively poorfit is that the data are from different instru-ments with different energy responses(even among a sin-gle instrument aboard XMM,the changingfilters alter the response).The pulse profile of RX J0720.4−3125 is known to depend on energy(Cropper et al.2001; Paper I;Haberl et al.2004)and to change over time (de Vries et al.2004).While the changes to the shape are small,some systematic offsets are expected between the pulse profiles as measured by different instruments or at different times.We hope to investigate this in more detail in the near future.At present,we cannot distinguish between the various5From Fig.1,it may appear that one could obtain a betterfit by reducing the cycle count for the1998HRI point by one;however, doing that,the other ROSAT points cannot be reproduced any more.possibilities for the relatively poorfits.The predicted future behavior is different,however,and thus further observations of RX J0720.4−3125(some of which are in progress)should be able to distinguish between these models.5.DISCUSSION&CONCLUSIONSFrom our timing solution,we infer a spin-down rate ˙P=6.98(2)×10−14s s−1.This is consistent with the limits derived in Paper I and by Zane et al.(2002),but inconsistent with the tentative solution of Cropper et al. (2004),who found˙P=(1.4±0.6)×10−13s s−1at99% confidence(but who noted that elements of their solution were inconsistent with each other and that their analy-sis was subject to confusing aliases).In Table2,we list derived parameters—rotational energy loss rate,mag-neticfield,and characteristic age(the latter two under the assumption of magnetic dipole spin-down).The values of P and˙P place RX J0720.4−3125well above above most of the radio-pulsar“death-lines”pro-posed so far(e.g.,Young,Manchester,&Johnston1999) and in a region populated by radio pulsars in P-˙P diagrams like that in Paper I(its parameters are ap-proximately between those of PSR J1830−1135,with P=6.2s,˙P=5×10−14s s−1,and PSR J1847−0130, with P=6.7s,˙P=1.3×10−12s s−1).Hence, RX J0720.4−3125may well be a radio pulsar itself,but one whose radio beam(s)do not intersect our line of sight. Its inferred magneticfield,B=2.4×1013G,is not excep-tional;the Parkes Multi-beam Survey(Manchester et al. 2001)in particular has discovered a fair number of ra-dio pulsars with B 1013G(e.g.,Camilo et al.2000; Morris et al.2002;McLaughlin et al.2003),and it is now clear the distribution of magneticfields isflatter than previously assumed(Vranesevic et al.2004).With˙E=4.7×1030ergs s−1,RX J0720.4−3125is not expected to have much non-thermal X-ray emis-sion:from the relation of Becker&Tr¨u mper(1997), one estimates L X,non−th∼10−3˙E≃5×1027ergs s−1, much smaller than the thermal emission,L X,therm≃2×1032d300ergs s−1.This is consistent with lim-its from Chandra and XMM(Paerels et al.2001; Pavlov,Zavlin,&Sanwal2002;Kaplan et al.2003). What is somewhat puzzling is the inferred age of2Myr. Tracing RX J0720.4−3125back to OB associations where it might have been born put it close to the Trumpler10 association∼0.7Myr ago(Motch,Zavlin,&Haberl 2003;Kaplan2004).Similarly,based on its estimated temperature and luminosity,most standard cooling mod-els(modified URCA for1.4M⊙neutron stars)put RX J0720.4−3125at 1Myr(Heyl&Hernquist1998; Paper I;Cropper et al.2004).It is of course possible that RX J0720.4−3125was born with a long period and/or had significantly non-dipole braking,such that the spin-down age is not a good es-timate of its true age.However,no case with as long a birth period as would be required for RX J0720.4−3125 is known among radio pulsars(cf.Kramer et al.2003; Gavriil et al.2004).Another possible explanation is that RX J0720.4−3125 was ejected from a binary system with a massive com-panion∼0.7Myr ago,either when the companion un-derwent a supernova or during a binary exchange inter-A Timing Solution for RX J0720.4−31255action.In this case,a relatively long period is expected: if the neutron star accreted matter from its compan-ion,its spin period would have tended toward the equi-librium period,P eq≈5s(B/1013G)6/7(˙M/˙M Edd)−3/7 (where˙M is the accretion rate and˙M Edd is the Edding-ton rate).A relatively short cooling age would also be consistent with this model:the accretion and accompa-nying steady hydrogen burning could reheat the neutron star(or keep it hot).Of course,it remains to be seen that a suitable evolutionary scenario can be found.In any case,the prediction for the model with two supernovae is that there may well be another 1Myr old neutron star whose proper motion traces back to the same origin as RX J0720.4−3125(cf.Vlemmings et al.2004). Finally,we can compare the magneticfield strength of 2.4×1013G with what is inferred from the broad absorp-tion feature in the spectrum(observed to be at0.3keV, which corresponds to0.39keV at the surface for a grav-itational redshift of0.3;Haberl et al.2004;Vink et al. 2004).If due to a proton cyclotron line,one infers B≃6×1013G(Haberl et al.2004),which is substan-tially larger than inferred from the spin-down.This may simply reflect the inadequacy of the dipole spin-down model,or the presence of higher order multipoles.On the other hand,based on a comparison with other sources, van Kerkwijk et al.(2004)suggested that the absorption feature was due to the transition from the ground state to the second excited tightly bound state of neutral hydro-gen,which would require B≃2×1013G and matches the spin-down value nicely.If that is the case,higher signal-to-noise spectra should reveal the transition to thefirst excited state at∼0.15keV.We thank an anonymous referee for useful comments, and Kaya Mori,George Pavlov,Saul Rappaport,Deepto Chakrabarty,and Peter Woods for helpful discussions. DLK was partially supported by a fellowship from the Fannie and John Hertz Foundation.We acknowledge support through Chandra grant GO4-5082X.REFERENCESArzoumanian,Z.,Nice,D.J.,Taylor,J.H.,&Thorsett,S.E.1994, ApJ,422,671Becker,W.&Tr¨u mper,J.1997,A&A,326,682Briel,U.G.&Pfeffermann,E.1995,Proc.SPIE,2518,120 Buccheri,R.,et al.1983,A&A,128,245Camilo,F.,Kaspi,V.M.,Lyne,A.G.,Manchester,R.N.,Bell, J.F.,D’Amico,N.,McKay,N.P.F.,&Crawford,F.2000,ApJ, 541,367Cox,A.N.2000,Allen’s Astrophysical Quantities,4th edn.(New York:AIP Press/Springer)Cropper,M.,Haberl,F.,Zane,S.,&Zavlin,V.E.2004,MNRAS, 351,1099Cropper,M.,Zane,S.,Ramsay,G.,Haberl,F.,&Motch,C.2001, A&A,365,L302Davis,W.,Holmes,J.,&Myers,R.2003,in The2003Chandra Calibration Workshopde Vries,C.P.,Vink,J.,M´e ndez,M.,&Verbunt,F.2004,A&A, 415,L31Garmire,G.P.,Bautz,M.W.,Ford,P.G.,Nousek,J.A.,&Ricker, G.R.2003,Proc.SPIE,4851,28Gavriil,F.P.&Kaspi,V.M.2002,ApJ,567,1067Gavriil,F.P.,Kaspi,V.M.,&Roberts,M.S.E.2004,Advances in Space Research,33,592Haberl, F.2004,in XMM-Newton EPIC Consortium meeting, Palermo,2003October14-16(astro-ph/0401075)Haberl,F.,Motch,C.,Buckley,D.A.H.,Zickgraf,F.-J.,&Pietsch, W.1997,A&A,326,662Haberl,F.,Zavlin,V.E.,Tr¨u mper,J.,&Burwitz,V.2004,A&A, 419,1077Heyl,J.S.&Hernquist,L.1998,MNRAS,298,L17Jansen,F.,et al.2001,A&A,365,L1Kaplan, D.L.2004,Ph.D.Thesis,California Institute of TechnologyKaplan,D.L.,Kulkarni,S.R.,van Kerkwijk,M.H.,&Marshall, H.L.2002,ApJ,570,L79Kaplan,D.L.,van Kerkwijk,M.H.,Marshall,H.L.,Jacoby,B.A., Kulkarni,S.R.,&Frail,D.A.2003,ApJ,590,1008Kraft,R.P.,et al.1997,Proc.SPIE,3114,53Kramer,M.,Lyne,A.G.,Hobbs,G.,L¨o hmer,O.,Carr,P.,Jordan, C.,&Wolszczan,A.2003,ApJ,593,L31Lyne,A.G.,Shemar,S.L.,&Smith,F.G.2000,MNRAS,315, 534Manchester,R.N.,et al.2001,MNRAS,328,17McLaughlin,M.A.,et al.2003,ApJ,591,L135Morris,D.J.,et al.2002,MNRAS,335,275Motch,C.,Zavlin,V.E.,&Haberl,F.2003,A&A,408,323 Paerels,F.,et al.2001,A&A,365,L298Pavlov,G.G.&Zavlin,V. E.2003,in Texas in Tuscany. XXI Symposium on Relativistic Astrophysics,ed.R.Bandiera, R.Maiolino,& F.Mannucci(Singapore:World Scientific Publishing),319–328(astro-ph/0305435)Pavlov,G.G.,Zavlin,V.E.,&Sanwal,D.2002,in Neutron Stars, Pulsars,and Supernova Remnants,ed.W.Becker,H.Lesch,& J.Tr¨u mper(Garching:MPE Rep.278),273(astro-ph/0206024) Str¨u der,L.,et al.2001,A&A,365,L18Tr¨u mper,J.1993,Science,260,1769Turner,M.J.L.,et al.2001,A&A,365,L27van Kerkwijk,M.H.,Kaplan,D.L.,Durant,M.,Kulkarni,S.R., &Paerels,F.2004,ApJ,608,432van Riper,K.A.,Epstein,R.I.,&Miller,G.S.1991,ApJ,381, L47Vink,J.,de Vries,C.P.,M´e ndez,M.,&Verbunt,F.2004,ApJ, 609,L75Vlemmings,W.H.T.,Cordes,J.M.,&Chatterjee,S.2004,ApJ, 610,402Voges,W.,et al.1996,IAU Circ.,6420,2Vranesevic,N.,et al.2004,ApJ,617,L139Weisskopf,M.C.,Tananbaum,H.D.,Van Speybroeck,L.P.,& O’Dell,S.L.2000,Proc.SPIE,4012,2Woods,P.M.,et al.2000,ApJ,535,L55Young,M.D.,Manchester,R.N.,&Johnston,S.1999,Nature, 400,848Zane,S.,Haberl,F.,Cropper,M.,Zavlin,V.E.,Lumb,D.,Sembay, S.,&Motch,C.2002,MNRAS,334,345Zavlin,V.E.,Pavlov,G.G.,Sanwal,D.,&Tr¨u mper,J.2000,ApJ, 540,L25Zombeck,M.V.,David,L.P.,Harnden,F.R.,&Kearns,K.1995, Proc.SPIE,2518,304。