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化学选5试题及答案

化学选5试题及答案
化学选5试题及答案

高二人教版化学第三章有机化学测试题

一. 单选题1. 在农业上常用稀释的福尔马林来浸种,给种子消毒。该溶液中含有( )A. 甲醇 B. 甲醛C. 甲酸 D. 乙醇 2. 常温常压下为无色液体,而且密度大于水的是( )① 苯② 硝基苯③ 溴苯④ 四氯化碳 ⑤ 溴乙烷⑥ 乙酸乙酯 A. ①⑥ B. ②③④⑥ C. ②③④⑤ D. ③④⑤⑥

3. 常温常压下为气体的有机物是( )① 一氯甲烷 ② 二氯甲烷 ③ 甲醇 ④ 甲醛 ⑤ 甲酸 ⑥ 甲酸甲酯 A. ①②B. ②④⑤C. ③⑤⑥D. ①④

4. 结构简式是 CHO CHCH CH 22= 的物质不能发生( )A. 加成反应 B. 还原反应C. 水解反应D. 氧化反应

5. 下列有机物命名正确的是( )

A. 2,2,3-三甲基丁烷

B. 2-乙基戊烷

C. 2-甲基-1-丁炔

D. 2,2-甲基-1-丁烯 6. 下列各化学式中,只表示一种纯净物的是( )A. C 2H 4O B. C 3H 6 C. C 2H 3Br D. C

7. 下列有机物能使酸性KMnO 4溶液褪色,而不能因化学反应而使溴水褪色的是( )A. 苯B. 甲苯C. 乙烯D. 丙炔8. 2001年9月1日将执行国家食品卫生标准规定,酱油中3-氯丙醇(ClCH 2CH 2CH 2OH)含量不超过1ppm 。相对分子质量为94.5的氯丙醇(不含

Cl

OH C --结构)共有( )A. 5种B. 4种C. 3种D. 2种

9. 苯的同系物C 8H 10,在铁催化剂下与液溴反应,其中只能生成一种一溴化物的是( )

A.

C 2H 5

B.

CH 3

CH 3

C.

CH 3

CH 3

D.

10. 检验酒精中是否含有水,可选用的试剂是( )

A. 金属钠

B. 浓H 2SO 4

C. 无水CuSO 4

D. 胆矾11. 下列过程中,不涉及化学变化的是( )A. 用明矾净化水B. 甘油加水作护肤剂C. 烹鱼时,加入少量的料酒和食醋可减少腥味,增加香味D. 烧菜用过的铁锅,经放置常出现红棕色斑迹 12. 等质量的铜片在酒精灯上热后分别插入下列液体,片刻取出,铜片质量不变的是( )A. 盐酸 B. 无水乙醇 C. 冰醋酸 D. 乙醛 13. 结构简式为的有机物, 不能发生的反应是( )A. 消去反应B. 加成反应C. 酯化反应 D. 银镜反应

14. L —多巴是一种有机物,它可用于帕金森综合症的治疗,其结构简式如下:( )

下列关于L —多巴酸碱性的叙述正确的是( )

A. 既没有酸性,又没有碱性

B. 既具有酸性,又具有碱性

C. 只有酸性,没有碱性

D. 只有碱性,没有酸性 15. 欲除去下列物质中混入的少量杂质(括号内物质为杂质),不能达到目的的是( ) A. 乙酸乙酯(乙酸):加饱和Na 2CO 3溶液,充分振荡静置后,分液B. 乙醇(水):加入新制生石灰,蒸馏C. 溴苯(溴):加入NaOH 溶液,充分振荡静置后,分液D. 乙酸(乙醇):加入金属钠,蒸馏 16. 已知甲、乙两种烃的含碳的质量分数相同,下列判断正确的是( )A. 甲和乙一定是同分异构体B. 甲和乙的实验式一定相同C. 甲和乙不可能是同系物D. 等质量的甲和乙完全燃烧生成水的质量一定相等 17. 下列各组物质之间,一定是互为同系物的是()A. HCHO 与HCOOCH 3B. HOCH 2CH 3 与CH 3COOH C. HCOOH 与 C 17H 35COOHD. C 2H 4 与 C 3H 6 18. 具有单双键交替长链(如:—CH =CH —CH =CH —CH =CH —……)的高分子有可能成为导电塑料,获得2000年诺贝尔化学奖。下列分子中可能成为导电塑料的是( )A. 聚乙炔 B. 聚乙烯 C. 聚苯乙烯 D. 聚丁二烯

19. 甲酸甲酯、乙酸丁酯、丙酸甲酯组成的混合脂中,若氧元素的质量分数为30%,那么氢元素的质量分

数为( )A. 10% B. 15% C. 20% D. 无法确定

20. 已知化合物B 3N 3H 6(硼氮苯)与C 6H 6(苯)的分子结构相似,如下图。 则硼氮苯的二氯取代物B 3N 3H 4Cl 2的同分异构体的数目为( )

A. 6

B. 4

C. 3

D. 2 21. 将一定量有机物充分燃烧后的产物通入足量石灰水中完全吸收,经过滤得到20g 白色沉淀,滤液质量比原石灰水减少5.8g ,该有机物是( )A. 甲烷 B. 乙烯 C. 乙醇 D. 甲酸甲酯

24. 下列选项中说明乙醇作为燃料的优点的是( )① 燃烧时发生氧化反应② 充分燃烧的产物不污染环境③ 乙醇是一种再生能源④ 燃烧时放出大量热量A. ①②③B. ①②④C. ①③④D. ②③④

二. 填空题25. 化学式为C 6H 12的某烯烃的所有碳原子都在同一平面上,则该烯烃的结构简式是______。

26. 某烯烃,经与氢气加成反应可得到结构简式为 3

CH

3

CH 2Cl

CH 2CH C 2OH

CH 2CHO

OH

NH 2CH 2CHCOOH HO

H

H

H H H H

H N

B H N

B H

N B H H 3

3

333|

|

||CH CH C CH CH CH CH CH ----

的烷烃,则此烯烃可能的结构简式是:___________、___________、___________。

30. 有以下一系列反应,最终产物为草酸。

A

光?

?→

?

2

Br B ???

?

?→

?醇

,

NaOH

C ?

?→

?水2Br D ?

?

?

?→

?O

H

NaOH

2

, E ??

?

?

?→

?催化剂

,

2

O

F ??

?

?

?→

?催化剂

,

2

O

COOH

COOH

|

已知B的相对分子质量比A的大79,请推测用字母代表的化合物的结构式:

C是_____________,F是______________。

31. 实验室进行实验①制乙烯②制乙炔③石油分馏④苯的硝化⑤制溴苯⑥制乙酸乙

34.

(C 6H 10O 8),B 和C A 、B 、C B RCHO 最易,R —请在下列空格中填写A A :_________ B E :_________ F 三. 计算题

35. 将某烷烃0.88g 量增加4.08g

36. 已知由某一元羧酸与甲醇生成的酯。取0.68g 该酯与40mL 0.2mol/L 的NaOH 溶液混合加热,使其完全水解后,再用0.2mol/L 的盐酸中和剩余的碱,耗去15mL 盐酸。另取27.2g 该酯,完全燃烧后得到70.4g CO 2和14.4g 水。求:(1)该酯的最简式;(2)该酯的相对分子质量;(3)该酯的结构简式的名称。

37含有一元饱和醛的水溶液84克,其中含醛A 为22.4克,加入另一饱和一元醛B 16克后,

从混合液中取出2.5克,在足量的银氨溶液中加入2.5克混合液,加热后得到4.32克银。已知醛A 比醛B 少一个碳原子。求A 、B 各是什么醛,并写出它们的结构简式。

25. CH

CH 3

3

CH

CH 3

CH 3

26.

CH 2

CH

CH 3CH 3C CH 3CH 3

CH 3

、CH 3

C

CH 3C

CH 3C CH 3

3

CH 3

、CH 3

C

CH 3CH 2C CH 3CH 3

CH 3

27. (1)③④(2)①④(3)②(4)①②④28. A :乙酸乙酯 B :乙酸钠 C :乙醇 D :乙醛 E :乙酸 F :乙烯 G :甲烷 H :1,2—二溴乙烷29. ① 硝化② 氯化③ 氧化 ④ 酯化⑤ 还原 30. C :22CH CH

F :HO C CHO |

31.(1)②⑤

(2)④ (3)①③④,①(4)①③(5)①④⑥

33.(1)B 和C (2)E CH 2CH 2COOH

(3)还原(或加成、加氢、催化加氢等) 34. A. CHO CHOH HOCH 42)(

B. COOH CHOH HOCH 42)(

C. COOH CHOH HOOC 4)(

D. OH CH CHOH HOCH 242)(

E. HO HO

O CH

CH 2OH

O

HO HO

CH CH

C

O O

CH CH

CH 2OH F.

HO

O

HO O CH 2OH 或

HO

CH CH

C

O

O CH

CH 2OH

HO

CH

三. 计算题

35. 解:g

n O

H n CO n O n H C g

n n n )214()1(2

1

3)1862(22222+++→++

++

g 88.0 g 08.4 3=n 一氯化物为Cl CH CH CH 223,33CHClCH CH 答:略 36. 解(1)有机物中

mol

mol g g

C n 6.1444.70)(=?=

g C m 2.19)(=

mol

mol g g H n 6.1182

4.14)(=??=

g H m 6.1)(=

mol

mol

g g

g g O n 4.0166.12.192.27)(=?--=

1:4:4)(:)(:)(=O n H n C n 最简式为

O H C 44式量为68 (2)酯与NaOH 溶液反应中消耗)(NaOH n

mol L L L mol NaOH n 005.0)015.004.0(/2.0)(=-?=

OH CH RCOONa NaOH RCOOCH 33+→+

1 1

mol 005.0 mol 005.0

1

3136005.068.0)(-?==

mol g mol g

RCOOCH M 相对分子质量为136 (3)设分子式为x O H C )(44

2681361

1

=??=--mol g mol g X 分子式为288O H C 结构简式为

O

C

O

CH 3

名称为苯甲酸甲酯

37原溶液中含A 醛84*26.67%=22.4 g,加入B 醛后,溶液总质量为100g,从混合液中取出 2.5克,实际取出A 醛22.4*2.5%=0.56g,B 醛16*2.5%=0.4g,一共是0.96g 饱和一元醛;得到4.32克银,合0.04mol,说明醛一共是0.02mol ;这样一来,混合醛的平均摩尔质量就是0.96/0.02=48,已知A 比B 少一个碳,所以它们是乙醛(44)和丙醛(58).

2014--2018全国卷七选五真题

【题文】根据短文内容,从短文后的选项中选出能填入空白处的最佳选项。选项中有两项为多余选项。 Tips for Cooking on a Tight Schedule From my experience , there are three main reasons why people don’t cook more often :ability , money , and time 36 .Money is a topic I’ll save for another day .So today I want to give you some wisdom about how to make the most of the time you spen t in the kitchen .Here are three tips for great cooking on a tight schedule : 1.Think ahead .The moments when I think cooking is a pain are when I’m already hungry and there’s nothing ready to eat .So think ahead of the coming week .When will you have time to cook ?Do you have the right materials already ? 37 . 2.Make your time worth it .When you do find time to cook a meal , make the most of it and save yourself time later on .Are you making one loaf of bread ? 38 .It takes around the same amount of time to make more of something .So save yourself the effort for future meal . 3.39 This may surprise you , but one of the best tools for making cooking worth your time is experimentation .It gives you the chance to hit upon new ideas and recipes that can work well with your appetite and schedule. The more you learn and the more you try, the more ability you have to take control of your food and your schedule. Hopefully that gives you a good start. 40_______ And don’t let a busy schedule discourage you from making some great changes in the way you eat and live! A. Try new things. B. Ability is easily improved. C. Make three or four instead. D. Understand your food better. E. Cooking is a burden for many people. F. Let cooking and living simply be a joy rather than a burden. G. A little time planning ahead can save a lot of work later on. BGCAF

《化学平衡》高考试题分析与复习备考建议

根据以上规律判断,上列结论正确的是 A 反应Ⅰ:△H>0,P2>P1 B 反应Ⅱ:△H<0,T1<T2 C 反应Ⅲ:△H>0,T2>T1;或△H<0,T2<T1 D 反应Ⅳ:△H<0 T2>T1 4、注重整合,适度综合,增大知识覆盖面 在理科综合卷中有一些比较单一的题,图象也多是一幅图,但更多的是涉及多个知识点的试题,为体现学科内综合特点,增大知识覆盖面,往往是在一道题中对化学反应速率和化学平衡进行或简单或程度较高的综合,综合的形式是4个选项涉及4个不同方面、对4个图象进行分析、对表格中的多组数据进行处理、在Ⅱ卷大题中进行综合设问等。 如:06年天津卷第11题:某温度下,体积一定的密闭容器中进行如下可逆反应: X(g)+Y(g)Z(g)+W(s):△H>0 下列叙述正确的是 A 加入少量W,逆反应速率增大 B 当容器中气体压强不变时,反应达到平衡 C 升高温度,平衡逆向移动 D 平衡后加入X,上述反应的△H增大 5、形式新颖,灵活多变,彰显能力立意 试题在题型上似乎没有明显的变化,但创新性仍是非常突出的。给人的感觉是化学反应速率的计算和平衡图象的分析更加灵活多变(如06年四川、江苏题);对化学反应速率的变化、化学平衡移动的起因、过程和结果、多种平衡状态的比较等考查的更加透彻(如06年重庆、广东题);对等效平衡的考查更有深度(如05年江苏题);总有出乎意料的“亮点”(如06年天津卷加入反应物与△H的关系)。这样的题目推陈出新,不落俗套,体现的是能力立意,考查的是灵活运用所学知识解决实际问题的能力。 三、命题预测 1、稳定高考命题的指导思想一直是稳中有变,2007年高考对化学平衡的考 查也会在题型、题量、赋分、取材、命题风格上保持相对稳定。鉴于05、06年的综合题中化学平衡几乎都占1/16,04和06年的湖北卷几乎都未考平衡,所以07年试卷中出一道选择题的可能性是最大的。同时,近年综合卷中难觅大题踪影,因此,以大型填空题或填空、实验、计算相融合的综合题来考查化学平衡的可能性也是存在的。 2、创新创新是试题的灵魂和魅力所在。化学平衡中包含很广阔的创新空间, 如化学反应速率和化学平衡的实验分析和设计、灵活多变的化学平衡图象、小巧新颖的速率和平衡计算等,特别是在情景、取材上创新,在图象上创新,化学平衡的思想和勒夏特列原理在其它平衡体系中的应用等值得关注。

(完整版)2011-2017全国卷七选五高考真题+答案

2011 Money Matters Parents should help their children understand money. 71 so you may start talking about money when your child shows an interest in buying things, candy or toys, for example. 1. The basic function of money Being explaining the basic function of money by showing how people trade money for goods or services. It is important to show your child how money is traded for the thing he wants to have. If he wants to have a toy, give him the money and let him hand the money to the cashier (收银员). 72 When your child grows a bit older and understands the basic function of money, you can start explaining more complex ways of using money. 2. Money lessons Approach money lessons with openness and honesty. 73 If you must say no to a child’s request to spend money, explain, ”You have enough toy trucks for now.”Or, if the request is for many different things, say. “You have to make a choice between this toy and that toy.” 3. 74 Begin at the grocery store. Pick put similar brands of a product—a name brand butter and a generic(无商标产品),for example. You can show your child how to make choices between different brands of a product so that you can save money. 75 If he chooses the cheaper brand, allow him to make another purchase with the money saved. Later, you may explains how the more expensive choice leaves less money for other purchases. A. Wise decision. B. The value of money. C. Permit the child why he can—or cannot—have certain things. D. Talk yourself what things that cost money are most important to you. E. Ask yourself what things that cost money are most important to you. F. Talk about how the money bought the thing after you leave the toy store. G. The best time to teach a child anything about money is when he shows an interest.

高考化学复习 化学平衡常数及其计算习题含解析

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