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Strengthening and toughening of a 2800-MPa grade maraging steel

Strengthening and toughening of a 2800-MPa grade maraging steel
Strengthening and toughening of a 2800-MPa grade maraging steel

Strengthening and toughening of a 2800-MPa grade maraging steel

Yi He *,Ke Yang,Wenshen Qu,Fanya Kong,Guoyue Su

Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,People’s Republic of China

Received 9October 2001;accepted 23January 2002

Abstract

A new high Ni,Ti and low Mo maraging steel based on 13Ni(400)maraging steel has been developed.The optimum heat treatment was found to be cryogenic treatment (CT)at 200K followed by aging treatment at 773K for 4h in as-forged or solution condition.Optical and transmission electron microscopy (TEM)revealed that the precipitates,such as Ni 3(Mo,Ti),were well developed in lath martensite.It achieved strength of 2700MPa and fracture toughness of above 30MPa m 1/2.The balance among alloy elements and the removal of undissolved coarse particles ensured the good combination of strength and toughness by a normal thermomechanical treatment condition.D 2002Elsevier Science B.V .All rights reserved.

Keywords:Maraging steel;Strengthen;Fracture toughness;Precipitation hardening

1.Introduction

Maraging steels represent one class of ultra-high strength steels that attain their strength by precip-itation hardening.During the past four decades,many kinds of maraging steels have been developed.18%Ni maraging steels containing cobalt are typical category,which result in practical applications of various grade steels with strength up to 2400MPa,designated as 18Ni(350).In order to meet the demands of special project,2800MPa grade marag-ing steel,a higher strength maraging steel than 18Ni type,such as 13%Ni –15Co –10Mo –0.2Ti alloy (designated as 13Ni(400)),which was first invented

by Mihalisin and Bieber [1],has been a subject of many investigations [2–10].In 13Ni(400)maraging steel,as a main alloying element,nickel is obviously lower in content,whereas both cobalt and molybde-num contents are markedly increased in order to get a higher strength,and the titanium is abandoned for maintaining the toughness.However,in most cases,the strength of 13Ni(400)has difficulty reaching the designed strength,i.e.,2800MPa,because of undis-solved Fe 2Mo laves phase in the matrix,and its ductility and fracture toughness (K IC )are lower than what was expected in the forged state [2–10].In order to further strengthen and toughen the 2800MPa grade maraging steel,some other types of maraging steels,such as 15Ni–25Co –7Mo [8],16Ni –15Co –(5f 7)Mo –2.5Ti [9],17Ni –15Co –6Mo–1Ti [11],etc.,have been developed,but they still had bad toughness and ductility with designed

0167-577X/02/$-see front matter D 2002Elsevier Science B.V .All rights reserved.PII:S 0167-577X (02)00610-9

*

Corresponding author.Fax:+86-24-23891320.E-mail address:yihe@https://www.doczj.com/doc/d88104955.html, (Y .He).

https://www.doczj.com/doc/d88104955.html,/locate/matlet

November 2002

Materials Letters 56(2002)763–

769

strength.Although after a special complicated ther-momechanical treatment the ductility of these alloys could have gotten some improvement and its K IC were close to 30MPa m 1/2[7–11],it is necessary to enhance and stabilize the mechanical properties for practical application.

In the present work,an attempt to improve both ductility and toughness without deterioration of strength was made for a 2800-MPa grade maraging steel through a proper adjustment of Ni,Mo and Ti contents,which can result in an enhancement of toughness for the martensite matrix and a modifica-tion of the precipitate phase.

2.Experimental procedure

An 18Ni maraging steel,whose chemical compo-sition is given in Table 1,was melted in a 25-kg vacuum induction melting furnace and then remelted in a vacuum arc melting furnace fitted with a 100-mm diameter mould.The steel was homogenized at 1473K for 24h and then forged into plates with 15mm in thickness and rods with 30mm in diameter,followed by air-cooling.

Mechanical behaviors were measured on longitu-dinal direction for the experimental steel under different solution and aging treatments.Hardness measurements were made to investigate the age-hardening behavior of the steel.The transformation temperatures of the heat were established by dila-tometry.Tensile testing were performed on an AG-5000A MTS machine at a displacement rate of 0.2mm/min.The plane strain fracture toughness (K IC )was also evaluated using three-point bending method in accord with ASTM specification.All the tests were conducted at room temperature.Microstructure observation was made on optical microscopy,scan-ning electron microscopy (SEM)and transmission electron microscopy (TEM).Quantitative X-ray dif-fraction method was employed to check the amount of retained austenite.

3.Results 3.1.Hardness

Variation of hardness as a function of aging time at different temperature for the experimental steel is shown in Fig.1.It can be found that the aging response is fairly rapid at 773and 803K,and almost 90%of total increase of hardness is attained within the first 15min of aging.Maximum hardness of HRC61.9is obtained at 773K within about 180min and slight overaging occurs after about 20h.However,at temperature of 803K,the hardness begins to decline at about 120min,which is relatively earlier for the steel.Aging at 743K gives a continuous increase of hardness with aging time until about 16h at the peak-aging value.It is also clearly shown that the aging hardness of the steel subjected to a cryogenic treat-ment (CT)at 200K is much higher than that of as-forged samples without CT.3.2.Dilatometry curve

The transformation temperatures for the experi-mental alloy were estimated using dilatometry.Fig.2shows the dilatometry curve together with the various transformation temperatures for this alloy.The A s (873K)and A f (1058K)of the reverse transformation were almost the same as the values of other corresponding grade maraging steel [9],while the M s declined to about 323K,and the M f was below the room temperature.According to the measurement of retained austenite amount by quantitative X-ray diffraction,it was estimated that transformation of austinite to martensite finished at about 200K.3.3.Microstructures

Fig.3shows optical micrographs of the experi-mental steel under two different conditions,with and without CT after forging.It was found that the trans-formation from austenite to martensite is not com-

Table 1

Chemical composition of experimental 18Ni maraging steel (wt.%)Ni Co Mo Ti Al C S P Si Mn O N Fe 17.88

14.75

6.69

1.10

0.08

0.0037

0.002

0.001

0.02

0.007

0.0025

0.0015

Bal

Y.He et al./Materials Letters 56(2002)763–769

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pleted under air cooling or water quenching to room temperature after forging because of more Ni,an austenite-stabilizing element,in the experimental steel compared with that in 13Ni(400)maraging steel.The amount of retained austenite in the steel without CT is about 30%,as shown in Fig.3a .However,with a cryogenic treatment at 200K,the steel has got full of low-carbon martensite structure without retained aus-tenite,as shown in Fig.3b .A complete transformation to martensite also makes the steel an obvious increase of hardness for the as-forged specimens,as shown in Fig.1.

Fig.4represents TEM images of the heat taken after aging for 4h at 773K followed by solution treatment at 1133K and CT in the as-forged con-dition.From the bright field image (Fig.4a),it can be seen that the microstructure of the sample consists of lath martensite with high density of dislocations.The dark field image (Fig.4b)shows that great deals of needle-like precipitates in nanometer size are well developed in the lath martensite.It can be indexed from the SAD pattern shown in Fig.4c that the precipitate should be a Ni 3(Mo,Ti)type phase.The undissolved coarse particles reported in literature [15,21]were not found in this

experiment.

Fig.3.Optical micrographs of the experimental 18Ni maraging steel.(a)As-forged;(b)as-forged +

CT.

Fig.1.Effect of aging time on hardness of as-forged experimental 18Ni maraging

steel.

Fig.2.Dilatometry curve for the alloy showing transformation temperatures.

Y.He et al./Materials Letters 56(2002)763–769765

3.4.Mechanical properties and fractography Table 2lists the results of tensile and plane strain fracture toughness (K IC )tests for both as-forged bars and plates of the 18Ni maraging steel.It can be seen that UTS,YS,and K IC of the experimental steel without CT either as-forged or subjected to a solution treatment are the same as those of 18Ni(350)steel.Strength of the steel is much lower than the designed value because of the retained austenite in microstruc-ture.However,the strength could reach up to 2700MPa due to the removal of the retained austenite by CT before aging.On the other hand,fracture tough-ness,K IC ,does not fall down sharply and still remains at a relatively high level,above 30MPa m 1/2.It is worth noticing that a solution treatment at 1133K for 1h has almost little influence on strength and fracture toughness of the steel.

The maximum strength and optimum toughness of some other the same grade maraging steels are

also

Fig.4.TEM image and corresponding diffraction pattern of the alloy with solution treatment of 1073K/1h followed by CT and aging at 773K for 4h.(a)Bright field image,showing the martensite lath morphology;(b)dark field image taken from the Ni 3(Mo,Ti)spot indicated by the arrow in (c),showing precipitates equally embedded in the lath;(c)[001]M SAD pattern.

Table 2

Properties of experimental 18Ni maraging steel in different conditions

Condition

U.T.S.(MPa)Y .S.(MPa)Elong.(%)R.A.(%)Hardness (HRC)K IC

(MPa m 1/2)Bar

1133K/1h +773K/4h 2313219713.032.35837.0773K/4h

2270221513.535.55841.41133K/1h +CT +773K/4h 26702593 5.824.561.832.6CT +773K/4h

26932617 6.026.06231.6Plate 1133K/1h +CT +773K/4h 27092617 6.038.16231.5CT +773K/4h 27222678 4.730.06230.2Bar

13Ni (400)[3]

25422498 5.2 1.5–27.525692530 1.8 6.4–60.413Ni (400)[12]

2500–5f 725–3317Ni–15Co–6Mo –1Ti [11]2609257510.637.160.829.315Ni–25Co–7Mo [8]

2700––30–1416Ni–15Co–5f 7Mo –2.5Ti [9]

2891

30

25

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given in Table 2.It is clearly shown that the maximum UTS of 13Ni(400)maraging steel is only 2570MPa,which is much lower than the designed value.Although the strength of other steels got some improvements by special complicated thermomechan-ical and cold-rolling treatment [7–12],their fracture toughness is lower than that of expected.

Fig.5shows the fracture surface of the exper-imental 18Ni maraging steel in the peak-aging steel condition.Macro-fracture morphology of the tensile specimen presents a ductile fracture,as shown in Fig.5a .The micro-morphology (see Fig.5b )also shows a transgranular rupture with uniform dimples due to the ductile nucleation,growth and coales-cence of microvoids.All these are consistent with high reduction in area of the steel.Fracture surface of K IC sample,as shown in Fig.5c ,gives an essentially ductile behavior,though it seems to tend to be a little bit brittle,which is also accorded with high fracture toughness of the steel with ultra-high strength.

4.Discussion

As a main alloying element,nickel plays a very important role in maraging steels.Speich and Swann [13]investigated the Fe–Ni alloy and found that yield strength of the quenched alloy increases with increasing nickel content,which is attributed to the increase of dislocation density.It was found [13]that from pure iron to Fe–4%Ni,the transformation substructure only consists of randomly arranged dislocations,and inversely,when the nickel content is above 25%,internally twinned martensite plates with bad toughness are formed.Therefore,nickel content in maraging steels is one of the important factors for maintaining both high strength and good toughness.In 13Ni(400)maraging steel,although the lower nickel content,compared with that in 18Ni maraging steel,is beneficial to the martensite transformation at room temperature [14],ductility and toughness of the steel is essentially reduced,which has been verified by many investigators [2–10].Inversely,increasing the nickel content up to 18%in the present experimental 18Ni steel could effectively improve mechanical properties of the steel,especially for ductility and toughness

by

Fig.5.SEM photographs of fracture surface of the experimental 18Ni maraging steel.(a)Macro-fracture morphology of tensile specimen;(b)micro-fracture morphology of tensile specimen;(c)fracture morphology of K IC sample.

Y.He et al./Materials Letters 56(2002)763–769767

preventing coalescence of voids and propagation of cracks between voids[15].In practice,it has been verified that maraging steels with18%Ni possess good combinations of strength and toughness in the development in the last decades[16].

In order to obtain the designed ultra-high strength, increasing the cobalt content based on18Ni(350) maraging steel is necessary for the present18Ni steel. On the one hand,cobalt can raise the M s temperature of the steel.On the other more important hand,cobalt will lower the solubility of molybdenum in the mar-tensite matrix[15,17,18]and then there will be more molybdenum taking part in aging reaction to strengthen the steel,which is the so-called synergistic effect of cobalt and molybdenum[19].

As a main strengthening alloying element in maraging steels,molybdenum is always aged with nickel to form metastable Ni3Mo precipitates[15] that have a good lattice fit with the b.c.c.structure of martensite matrix[20].However,the steels with higher molybdenum and/or lower nickel levels tend to have Fe2Mo laves phase formation that is detri-mental for reduction of area and fracture toughness of the steels[15,21].In13Ni(400)maraging steel, the molybdenum content is so high up to10wt.% that the superfluous Mo produces undissolved coarse Fe2Mo particles that are harmful to both strength and fracture toughness of the steel[2,3,6,15,21].In fact,data of the present18Ni steel demonstrate that a proper reduction of molybdenum from10%down to7%would not cut down the strength,but improve the properties.

Titanium has been proven to be desirable supple-mental hardener for maraging steels.Its role during aging of the steels is to form Ni3Ti precipitate in the lath martensite matrix[15,22,23].As titanium is increased from0.2%in18Ni(200)to 1.6%in 18Ni(350)maraging steel,the yield strength is increased from1400to2400MPa[16].This is about 700MPa increase for each percent of titanium.How-ever,the fracture toughness is sharply dropped from above150MPa m1/2to below50MPa m1/2[24]. Regardless of a moderate titanium content that pro-vides a good combination of strength and toughness, titanium in13Ni(400)maraging steel is cut down to below0.2%,which results in an adequate strength for the steel,but its ductility and fracture toughness are not improved obviously.In fact,increase of titanium content is feasible to get the designed strength for the present18Ni steel.Furthermore,a balance between titanium and trace elements such as carbon,nitrogen and sulfur in the matrix should also be considered to achieve a better fracture toughness.

5.Conclusion

Improvement on both strength and fracture tough-ness for2800MPa grade maraging steel can be made by modification of main alloying elements content and proper heat treatment.A strength of2700MPa with fracture toughness above30MPa m1/2were obtained for the presently designed2800MPa grade maraging steel by modification of Ni,Co,Mo and Ti contents based on13Ni(400),as well as a cryogenic treatment before aging.

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[19]R.F.Decher,J.R.Eash,A.J.Goldman,Transactions of the

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[24]R.C.Hall,Metal Progress105(6)(1974)41–42.

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新视野大学英语3第三版课文翻译 Unit 1 The Way to Success 课文A Never, ever give up! 永不言弃! As a young boy, Britain's great Prime Minister, Sir Winston Churchill, attended a public school called Harrow. He was not a good student, and had he not been from a famous family, he probably would have been removed from the school for deviating from the rules. Thankfully, he did finish at Harrow and his errors there did not preclude him from going on to the university. He eventually had a premier army career whereby he was later elected prime minister. He achieved fame for his wit, wisdom, civic duty, and abundant courage in his refusal to surrender during the miserable dark days of World War II. His amazing determination helped motivate his entire nation and was an inspiration worldwide. Toward the end of his period as prime minister, he was invited to address the patriotic young boys at his old school, Harrow. The headmaster said, "Young gentlemen, the greatest speaker of our time, will be here in a few days to address you, and you should obey whatever sound advice he may give you." The great day arrived. Sir Winston stood up, all five feet, five inches and 107 kilos of him, and gave this short, clear-cut speech: "Young men, never give up. Never give up! Never give up! Never, never, never, never!" 英国的伟大首相温斯顿·丘吉尔爵士,小时候在哈罗公学上学。当时他可不是个好学生,要不是出身名门,他可能早就因为违反纪律被开除了。谢天谢地,他总算从哈罗毕业了,在那里犯下的错误并没影响到他上大学。后来,他凭着军旅生涯中的杰出表现当选为英国首相。他的才思、智慧、公民责任感以及在二战痛苦而黑暗的时期拒绝投降的无畏勇气,为他赢得了美名。他非凡的决心,不仅激励了整个民族,还鼓舞了全世界。 在他首相任期即将结束时,他应邀前往母校哈罗公学,为满怀报国之志的同学们作演讲。校长说:“年轻的先生们,当代最伟大的演说家过几天就会来为你们演讲,他提出的任何中肯的建议,你们都要听从。”那个激动人心的日子终于到了。温斯顿爵士站了起来——他只有5 英尺5 英寸高,体重却有107 公斤。他作了言简意赅的讲话:“年轻人,要永不放弃。永不放弃!永不放弃!永不,永不,永不,永不!” Personal history, educational opportunity, individual dilemmas - none of these can inhibit a strong spirit committed to success. No task is too hard. No amount of preparation is too long or too difficult. Take the example of two of the most scholarly scientists of our age, Albert Einstein and Thomas Edison. Both faced immense obstacles and extreme criticism. Both were called "slow to learn" and written off as idiots by their teachers. Thomas Edison ran away from school because his teacher whipped him repeatedly for asking too many questions. Einstein didn't speak fluently until he was almost nine years old and was such a poor student that some thought he was unable to learn. Yet both boys' parents believed in them. They worked intensely each day with their sons, and the boys learned to never bypass the long hours of hard work that they needed to succeed. In the end, both Einstein and Edison overcame their childhood persecution and went on to achieve magnificent discoveries that benefit the entire world today. Consider also the heroic example of Abraham Lincoln, who faced substantial hardships, failures and repeated misfortunes in his lifetime. His background was certainly not glamorous. He was raised in a very poor family with only one year of formal education. He failed in business twice, suffered a nervous breakdown when his first love died suddenly and lost eight political

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