This article was downloaded by: [112.83.53.115]On: 08 May 2014, At: 17:21Publisher: Taylor & FrancisInforma Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer House,37-41 Mortimer Street, London W1T 3JH, UKMaterials Research LettersPublication details, including instructions for authors and subscription information:http://www.tandfonline.com/loi/tmrl20High-Entropy Alloys: A Critical ReviewMing-Hung Tsaia & Jien-Wei Yehba Department of Materials Science and Engineering, National Chung Hsing University,Taichung 40227, Taiwanb Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu30013, TaiwanPublished online: 30 Apr 2014.To cite this article: Ming-Hung Tsai & Jien-Wei Yeh (2014): High-Entropy Alloys: A Critical Review, Materials Research Letters,DOI: 10.1080/21663831.2014.912690To link to this article: http://dx.doi.org/10.1080/21663831.2014.912690PLEASE SCROLL DOWN FOR ARTICLETaylor & Francis makes every effort to ensure the accuracy of all the information (the “Content”) contained inthe publications on our platform. 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It is essential that you check the license status of any given Open and Open Select article to confirmconditions of access and use.Mater.Res.Lett.,2014http://dx.doi.org/10.1080/21663831.2014.912690www.tandfonline.com/toc/tmrl20/currentHigh-EntropyAlloys:ACriticalReviewMing-HungTsaia∗andJien-WeiYehb∗aDepartmentofMaterialsScienceandEngineering,NationalChungHsingUniversity,Taichung40227,Taiwan;bDepartmentofMaterialsScienceandEngineering,NationalTsingHuaUniversity,Hsinchu30013,Taiwan(Received10February2014;finalform2April2014)SupplementaryMaterialAvailableOnlineHigh-entropyalloys(HEAs)arealloyswithfiveormoreprincipalelements.Duetothedistinctdesignconcept,thesealloysoftenexhibitunusualproperties.Thus,therehasbeensignificantinterestinthesematerials,leadingtoanemergingyetexcitingnewfield.ThispaperbrieflyreviewssomecriticalaspectsofHEAs,includingcoreeffects,phasesandcrystalstructures,mechanicalproperties,high-temperatureproperties,structuralstabilities,andcorrosionbehaviors.Currentchallengesandimportantfuturedirectionsarealsopointedout.Keywords:High-EntropyAlloys,High-EntropyMaterials,AlloyDesign,MechanicalProperties,CorrosionResistance1.IntroductionMostconventionalalloysarebasedononeprincipalelement.Differentkindsofalloyingele-mentsareaddedtotheprincipalelementtoimproveitsproperties,forminganalloyfamilybasedontheprincipalelement.Forexample,steelisbasedonFe,andaluminumalloysarebasedonAl.However,thenumberofelementsintheperiodictableislimited,thusthealloyfamilieswecandeveloparealsolimited.Ifwethinkoutsidetheconventionalboxanddesignalloysnotfromoneortwo‘base’elements,butfrommultipleelementsaltogether,whatwillweget?Thisnewconcept,firstproposedin1995,[1]hasbeennamedahigh-entropyalloy(HEA).[2]HEAsaredefinedasalloyswithfiveormoreprinci-palelements.Eachprincipalelementshouldhaveacon-centrationbetween5and35at.%.[2,3]Besidesprincipalelements,HEAscancontainminorelements,eachbelow5at.%.Thesealloysarenamed‘HEAs’becausetheirliquidorrandomsolidsolutionstateshavesignificantlyhighermixingentropiesthanthoseinconventionalalloys.Thus,theeffectofentropyismuchmorepronouncedinHEAs.Existingphysicalmetallurgyknowledgeandbinary/ternaryphasediagramssuggestthatsuchmulti-elementalloysmaydevelopseveraldozenkindsofphasesandintermetalliccompounds,resultingincomplexandbrittlemicrostructuresthataredifficulttoanalyzeandengineer,andprobablyhaveverylimitedpracticalvalue.∗Correspondingauthor.Emails:mhtsai@nchu.edu.tw;jwyeh@mx.nthu.edu.twOppositetotheseexpectations,however,experimentalresultsshowthatthehighermixingentropyinthesealloysfacilitatestheformationofsolidsolutionphaseswithsimplestructuresandthusreducesthenumberofphases.Suchcharacters,madeavailablebythehigherentropy,areofparamountimportancetothedevelopmentandappli-cationofthesealloys.Therefore,thesealloyswerenamedas‘high-entropy’alloys.Becauseoftheuniquemultiprincipalelementcom-position,HEAscanpossessspecialproperties.Theseincludehighstrength/hardness,outstandingwearresis-tance,exceptionalhigh-temperaturestrength,goodstruc-turalstability,goodcorrosionandoxidationresistance.Someofthesepropertiesarenotseeninconventionalalloys,makingHEAsattractiveinmanyfields.Thefactthatitcanbeusedathightemperaturesbroadensitsspectrumofapplicationsevenfurther.Moreover,thefab-ricationofHEAsdoesnotrequirespecialprocessingtechniquesorequipment,whichindicatesthatthemassproductionofHEAscanbeeasilyimplementedwithexistingequipmentandtechnologies.Morethan30ele-mentshavebeenusedtopreparemorethan300reportedHEAs,forminganexcitingnewfieldofmetallicmate-rials.Thispaperreviewssomecrucialaspectsofthefield,includingcoreeffects,phaseformation,mechani-calproperties,high-temperatureproperties,andcorrosion©2014TheAuthor(s).PublishedbyTaylor&Francis.ThisisanOpenAccessarticledistributedunderthetermsoftheCreativeCommonsAttributionLicense(http://creativecommons.org/licenses/by/3.0),whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited.Themoralrightsofthenamedauthor(s)havebeenasserted.Downloaded by [112.83.53.115] at 17:21 08 May 2014
