ZnO单晶纳米棒阵列的水热法合成及光催化性能
顾修全;霍开富;赵宇龙;强颖怀
【期刊名称】《材料导报》
【年(卷),期】2011(025)020
【摘要】Highly ordered ZnO single-crystal nanorod(NR) arrays have been grown directly on a great number of substrates( including Si, ITO, Cu, brass and polymer materials) by a simple hydrothermal method. When Si wafers, ITO coated glass, Cu foils or PET sheets were used as the substrates, it was necessay to deposit a thin seed layer of ZnO on them prior to the growth of NR arrays. However, when a brass(CuZn alloy) foil was used as the substrate, ZnO NR arrays could be prepared on it without any seed layer. The structure, morphology and optical property were characterized by XRD, SEM and the UV-visible absorption spectra. It was also found that the as-prepared ZnO NR arrays had a good photocatalytic activity, which could degrad ~53% of organic dye(methyl orange aqueous solution) after 3h of ultraviolet(UV) light irradiation. Although the absorption coefficient over the visible band was significantly enhanced after modifying with CdSe, the photocatalytic capabilities of NR arrays were reduced a little. The possible mechanism will be elucidated in this study.%采用水热法在各种衬底上低温、一步合成出一维有序ZnO单晶纳米棒阵列.以透明导电玻璃(ITO)、聚对苯二甲酸乙二醇酯(PET)以及铜作为衬底时,必须预先沉积一层ZnO薄膜作