A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
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Product Data SheetAkzoNobel Powder CoatingsInterpon RDX PZALZ66CSProduct Description Interpon RDX PZ is a powder coating primer containing zinc which is designed to give enhanced corrosion protection of mild steel.This duplex system combines cathodic protection and barrier effect. It consists of a two-layersystem with a zinc rich primer Interpon RDX PZ overcoated with a Interpon powder topcoator PU liquid topcoat.Dedicated to steel protection with a surface pre-treatment obtained by grit/shot. InterponRedox PZ is based on a specific epoxy zinc rich formulation that brings conductivity to enablethe cathodic protection. Interpon Redox PZ includes a specific anticorrosive function whichimproves the protection in case of scratch.Powder Properties Chemical type Thermosetting epoxyAppearance SmoothGloss level (60°)40-70%Color Zinc greyRecommended FilmThickness (µm)60 - 120 µmDensity (g/cm3)2,0 g/cm³Application ElectrostaticStorage Under dry, cool (≤ 25°C) conditionsShelf life At least 12 months from production dateCuring schedule See section curing bellowTest Conditions The results shown below are based on mechanical and chemical tests which (unlessotherwise indicated) have been carried out under laboratory conditions and are given forguidance only. Actual product performance will depend upon the circumstances under whichthe product is used.Substrate/Pretreatment Steel; Grit blastingPrimer Thickness 60-80 micronsPrimer Curing 10 minutes at 170°C (Object Temperature)Topcoat Interpon 600 / D1010Topcoat Thickness 60-80 micronsTopcoat Curing 10 minutes at 200°C (Object Temperature)Mechanical Tests Bending test(Cylindrical Mandrel)ISO 1519 Pass 5 mm (Primer)Adhesion ISO 2409(2mm crosshatch) Class 0 (Primer) Class 0 (system)Cupping ISO 1520 Pass 8 mm (Primer) Direct Impact GB 1732-93 Pass 50 kg.cm (Primer)Pass 30 kg.cm (System)Corrosion Tests Mild Steel The results shown are based on tests which (unless otherwise indicated) have been carried out under laboratory conditions and are given for advice only, actual performance depends upon the circumstances under which the product is used.Neutral Salt Spray ISO 9227 Results are detailed in Table1 of AppendixPretreatment Surface preparation depends upon the metal, the type of surface, its conditions and theApplication Interpon RDX PZ can be applied by manual or automatic electrostatic spray equipment. For tribo spray, it should be tested before commencing production.Application settings Fluidizing air pressure: 1.5kg/cm2 initially then 1kg/cm2Transport air pressure: 0.5 to 0.8 kg/cmRecommended voltage: 65 to 70kVCuring limits Primer should be cured using the recommended curingschedules, before application of the topcoat. The objecttemperature must not be below 110°C or above 220°C.Recommended DFT 60-120 µmRecycling Trials, with suitable recycling equipment, must be carriedout before commencing production. Attention should bepaid to the ratio of new powder, a minimum of 80% mustbe used. Gun nozzles must be cleaned every 30 minutes.Note: Failure to comply with the recommended curing conditions may affect the adhesion ofthe topcoat and cause performance degradation. Parts coated with Interpon RDX PZ shouldnot be handled if possible. If unavoidable, clean lint-free gloves must be worn.Curing Interpon RDX PZ shows a wide curing range must allowing application on substrates of different nature and thicknesses.Green curing Full semi-curingObject temperature Min Max Min Max110°C 15’ 40’130°C 12’ 30’160°C 12’ 23’170°C 8’ 17’180°C 6’13’200°C 2’ 8’220°C 1’30’’ 5’30’’The Interpon RDX PZ system provides excellent protection against corrosion on the surface to which it is applied. However, the efficiency of this protection depends on the surface, its preparation before coating and the topcoat applied.If there is penetrating damage through the coating system to the substrate, there may be localized signs of corrosion where damage has occurred but this will not affect the adhesion of the film to the adjacent surface. Interpon RDX PZ considerably limits the extent of spread of corrosion in the event of coating damage.Topcoat Application Primer should be over-coated on the same site within 12 hours of applying the primer. If the delay exceeds 12 hours the parts should be heated for 12 minutes at 160°C. (object temperature). The delay must not exceed 24 hours.Refer to the Product Data Sheet for the powder topcoat for application parameters.To ensure the integrity of the system, as well as optimum performance, the whole system must be cured in accordance with the recommended curing conditions for the topcoat. Curing should be carried out in a convection oven, optionally with infra-red heaters. There must be a uniform heat distribution inside the oven.Note: Failure to comply with the recommended final curing conditions may cause variations in color and gloss and cause performance degradation of the system. A detailed protocol for applying Interpon RDX PZ system is available on request.Damage repair Any damage of the Interpon RDX PZ coating system must be repaired as soon as possible.Surface preparationDamaged areas must be clean and free of grease or rust. Dry-sand the area with 600grade paper down to the substrate. The area must be completely free of dust and cleanedwith a non-aggressive solvent before proceeding.ApplicationFor repairs the following two-coat liquid paint system from International Protective Coatingsis recommended:1st Coat: two-pack zinc-rich epoxy primer, Interzinc 722nd Coat: two-pack polyurethane topcoat, Interthane 990Safety Precautions This product is intended for use only by professional applicators in industrial environments and should not be used without reference to the relevant health and safety data sheetwhich Akzo Nobel has provided to its customers.Disclaimer IMPORTANT NOTE: The information in this data sheet is not intended to be exhaustive and is based on the present state of our knowledge and on current laws: any person using the product for any purpose other than that specificallyrecommended in the technical data sheet without first obtaining written confirmation from us as to the suitability ofthe product for the intended purpose does so at his own risk. It is always the responsibility of the user to take allnecessary steps to fulfil the demands set out in the local rules and legislation. Always read the Material Data Sheetand the Technical Data Sheet for this product if available. All advice we give or any statement made about theproduct by us (whether in this data sheet or otherwise) is correct to the best of our knowledge but we have no controlover the quality or the condition of the substrate or the many factors affecting the use and application of the product.Therefore, unless we specifically agree in writing otherwise, we do not accept any liability whatsoever for theperformance of the product or for any loss or damage arising out of the use of the product. All products supplied andtechnical advices given are subject to our standard terms and conditions of sale. You should request a copy of thisdocument and review it carefully. The information contained in this data sheet is subject to modification from time totime in the light of experience and our policy of continuous development. It is the user's responsibility to verify thatthis data sheet is current prior to using the product.Brand names mentioned in this data sheet are trademarks of or are licensed to AkzoNobel.Appendix 1: Performance tables Neutral Salt SprayCoating System Interpon RDX PZ / ALZ66CS + Interpon D1010 Conditions Substrate Steel 2mmPretreatment Grit blastingSA 2.5 – Ra 6-12µmPrimer thickness 60 - 80 µmTopcoat thickness 80 - 100 µmAdhesion on surface before test Class 0Neutral Salt Spray ISO 9227 Time Quotation Average corrosion creep (mm) 1 440 hours Scribe 1,74 mm ± 0,36Coating System Interpon RDX PZ / ALZ66CS + Interpon D1010 Conditions Substrate Steel 2mmPretreatment Grit blastingSA 2.5 – Ra 6-12µmPrimer thickness 60 - 80 µmTopcoat thickness 80 - 100 µmAdhesion on surface before test Class 0Cyclic corrosion test ISO 20340 Time Quotation Average corrosion creep (mm) 25 weeklycyclesScribe 6,13 mm ± 1,32/contact-us/Copyright © 2020 Akzo Nobel Powder Coatings Ltd. Interpon is a registered trademark of AkzoNobel Interpon RDX PZ - Issue #1Last Revision Date: 20.11.2020 Author: Lab Songjiang Shanghai。
有机化学方面的专业英语Angular methyl group 角甲基Alkylidene group 亚烷基Allyl group 烯丙基Allylic 烯丙型[的]Phenyl group 苯基Aryl group 芳基Benzyl group 苄基Benzylic 苄型[的]Activating group 活化基团Chromophore 生色团Auxochrome 助色团Magnetically anisotropic group 磁各向异性基团Smally ring 小环Common ring 普通环Medium ring 中环Large ring 大环Bridged-ring system 桥环体系Spiro compound 螺环化合物Helical molecule 螺旋型分子Octahedral compound 八面体化合物Conjugation 共轭Conjugated-system 共轭体系Acyl cation 酰[基]正离子Benzylic cation 苄[基]正离子Arenirm ion 芳[基]正离子Ketyl radical 羰自由基Radical ion 自由基离子Radical cation 自由基正离子Radical anion 自由基负离子Isomerism 异构[现象] Acid form 酸式Fluxional structure 循变结构Stereochemistry 立体化学Optical activity 光学活性Dextro isomer 右旋异构体Laevo isomer 左旋异构体Tetrahedral configuration 四面体构型Stereoisomerism 立体异构[现象] Asymmetric atom 不对称原子Asymmetric carbon 不对称碳Pseudoasymmetric carbon 假不对称碳Phantom atom 虚拟原子Homotopic 等位[的]Heterotopic 异位[的] Enantiotopic 对映异位[腯Diastereotopic 非对映异位[的] Configuration 构型Absolute configuration 绝对构型Chiral 手性[的] Chiral center 手性中心Chiral molecule 手性分子Achiral 非手性[的]Fischer projection 费歇尔投影式Neoman projection 纽曼投影式D-L system of nomenclature D-L命名体系R-S syytem of nomenclature R-S命名体系Cahn-Ingold-Prelon sequence 顺序规则Symmetry factor 对称因素Plane of symmetry 对称面Mirror symmetry 镜面对称Enantiomer 对映[异构]体Diastereomer 非对映[异构]体Epimer 差向异构体Anomer 端基[差向]异构体Erythro configuration 赤型构型Erythro isomer 赤型异构体Threo configuration 苏型构型Threo isomer 苏型异构体Trigonal carbon 三角型碳Cis-trans isomerism 顺反异构 E isomer E异构体Z isomer Z异构体Endo isomer 内型异构体Exo isomer 外型异构体Prochirality 前手性Pro-R group 前R基团Pro-S proup 前S基团Re face Re面Si face Si面Racemic mixture 外消旋混合物Racemic compound 外消旋化合物Racemic solid solution 外消旋固体溶液Meso compound 内消旋化合物Quasi racemate 准外消旋体Conformation 构象Conformational 构象分析Torsion angle 扭转角Rotamer 旋转异构体Anti conformation 反式构象Bisecting conformation 等分构象Eclipsed conformation 重叠构象Gauche conformation, skew con-formation 邻位交叉构象Staggered conformation 对位交叉构象Steric effect 空间效应Steric hindrance 位阻Atropisomer 阻转异构体Puckered ring 折叠环Conformational inversion 构象反转Chair conformation 椅型构象Boat conformation 船型构象Twist conformation 扭型构象Skew boat conformation 扭船型构象Half-chair conformation 半椅型构象Pseudorotation 假旋转Envelope conformation 信封[型]构象Axial bond 直[立]键Equatorial bond 平[伏]键Cisoid conformation 顺向构象Transoid conformation 反向构象Retention of configuration 构型保持Regioselectivity 区域选择性Regiospecificity 区域专一性Stereoselectivity 立体选择性Stereospecificty 立体专一性Conformer 构象异构体Conformational effect 构象效应Stereochemical orientation 立体[化学]取向Conformational transmission 构象传递Homolog 同系物Ipso position 本位Ortho position 邻位Meta position 间位Para position 对位Trigonal hybridization 三角杂化Molecular orbiral method 分子轨道法Valence bond method 价键法Delocalezed bond 离域键Cross conjugation 交叉共轭Vinylog 插烯物Mesomeric effect 中介效应Resonance 共振Resonance effect 共振效应Hyperconjugation 超共轭Isovalent hyperconjugation 等价超共轭No-bond resonance 无键共振Aromaticity 芳香性Aromatic sexter 芳香六隅Huckel’rule休克尔规则Paramagnetic ring current 顺磁环电流Diamagnetic ring cruuent 抗磁环电流Homoaromaticity 同芳香性Antiaromaticity 反芳香性Alternant hydrocarbon 交替烃Non-alternant hydrocarbon 非交替烷Pericyclic reaction 周环反应Electrocyclic rearrangement 电环[化]重排Conrotatory 顺旋Disroatatory 对旋Cycloaddition 环加成Symmetry forbidden-reaction 对称禁阻反应Synfacial reaction 同面反应Antarafacial reaction 异面反应Lewis structure 路易斯结构Coordinate-covalent bond 配位共价键Banana bond 香蕉键Pauling electronegativity scale 鲍林电负性标度Polarizability 可极化性Inductive effect 诱导效应Field effect 场效应Electrical effect 电场效应tautomerism 互变异构Tautomerization 互变异构化Keto-enol tautomerism 酮-烯醇互变异构Phenol-keto tautomerism 酚-酮互变异构Imine-enamine atutomerism 亚胺-烯胺互变异构Ring-chain tautomerism 环-链互变异构Valence tautomerism 价互变异构Solvent effect 溶剂Ambident 两可[的]效应Acid-base catalyzed reaction 酸-碱催化反应Basic solvent 碱性溶剂Dielectric constant 介电常数Solvated electron 溶剂化电子Acid-base catalyzed reaction 酸碱催化反应Conjugated acid 共轭酸Conjugated base 共轭碱Thermodynamic acidity 热力学酸度Kinetic acidity 动力学酸度Electron donator-acceptor complex, EDA complex 电子给[体]受体络合物Host 主体Guest 客体Primary isotope effect 一级同位素效应Secondary isotope effect 二级同位数效应Inverse isotope effect 逆同位素效应Kinetic control 动力学控制Thermodynamic control 热力学控制Substrate 底物Intermediate 中间体Reactive intermediate 活泼中间体Microscopic reversibility 微观可逆性Hammond postulate 哈蒙德假说Linear free energy 线性自由能Non-bonded interaction 非键相互作用Torsional effect 扭转效应Restricted rotation 阻碍旋转Eclipsing effect 重叠效应Eclipsing strain 重叠张力Small-angle strain 小角张力Large angle strain 大角张力Transannular interaction 跨环相互作用Transannular strain 跨环张力Anomeric effect 端基异构效应Walden inversion 瓦尔登反转Racemization 外消旋化Isoinversion 等反转Isoracemization 等消旋Homochiral 纯手性[的] Mechanism 机理Unimolecular nucleophilic substitution单分子亲核取代分子亲核取代(含烯丙型重排)Internal nucleophilic substitution 分子内亲核取代Aromatic nucleophilic substitution 芳香亲核取代Unimolecular electrophilic substitution 单分子亲电取代Bimolecular electrophilic substitution 双分子亲电取代Nucleophile-assisted unimolecular electrophilic substitution 亲核体协助单分子亲电取代Unimolecular elimination 单分子消除Bimolecular elimination 双分子消除Unimolecular elimination through the conjugated base 单分子共轭碱消除Bimolecular elimination through the conjugated base 双分子共轭碱消除Bimolecular elimination with formation of a carbonyl group 双分子消除形成羰基Unimolecular acid-catalyzed acyl-oxygen cleavage 单分子酸催化酰氧断裂Bimolecular base-catalyzed acyl-oxygen cleavage 双分子碱催化酰氧断裂Unimolecular acid-catalyzed alkyl-oxygen cleavage 单分子酸催化烷氧断裂Bimolecular base-catalyzed alkyl-oxygen cleavage 双分子碱催化烷氧断裂π-allyl complex mechanism π烯丙型络合机理Borderline mechanism 边理机理Homolysis 均裂Heterolysis 异裂Heterolytic mechanism 异裂机理Counter ion 反荷离子Ion pair 离子对Carbocation 碳正离子Nonclassical carbocation 非经典碳正离子Carbanion 碳负离子Masked carbanion 掩蔽碳负离子Carbenoid 卡宾体Carbene 卡宾Nitrene 氮宾Carbine 碳炔Electrophilic addition 亲电加成Electrophile 亲电体Diaxial addition 双直键加成Ma rkovnikov’s rule 马尔科夫尼科规则Anti-Markovnikov addition 反马氏加成Michael addition 迈克尔加成Substitution 取代Electrophilic substitution 亲电取代Addition-elimination mechanism 加成消除机理Electrophilic aromatic substitution 亲电芳香取代Electron transfer 电子转移Electron-donating group 给电子基团Electron-withdrawing group 吸电子基团Deactivating group 钝化基团Orinentation 取向Ortho-para directing group 邻对位定位基Meta directing group 间位定位基Ortho effect 邻位效应Partial rate factor 分速度系数Nucleophilic reaction 亲核反应Internal return 内返Nucleophilicitor亲核体Nucleophilicity 亲核性α-effect α-效应Backside attack 背面进攻Inversion 反转Umbrella effect 伞效应Push-pull effect 推拉效应Leaving group 离去基团Electrofuge 离电体Nucleofuge 离核体Phase-transfer catalysis 相转移催化Neighboring group participation 邻基参与Neighboring group assistance, anchimeric assistance 邻助作用Neighboring group effect 邻基效应Apofacial reaction 反面反应Bridgehead displacement 桥头取代Aryl cation 芳正离子Benzyne 苯炔Zaitsev rule 札依采夫规则Anti-Zaitsev orientation 反札依采夫定向Hofmann’s rule 霍夫曼规则Bredt rule 布雷特规则Initiation 引发Anionic cleavage 负离子裂解Partial bond fixation 键[的]部分固定化02.3有机化学反应Alkylation 烷基化C- alkylation C-烷基化O- alkylation O-烷基化N-alkylation N-烷基化Silylation 硅烷[基]化Exhaustive methylation 彻底甲基化Seco alkylation 断裂烷基化Demethylation 脱甲基化Ethylation 乙基化Arylation 芳基化Acylation 酰化Formylation 甲酰化Carbalkoxylation 烷氧羰基化。
2013—2014学年度第一学期应用化学专业专业英语课程试卷A注意事项:1. 考生务必将自己姓名、学号、专业名称写在指定位置;2. 密封线和装订线内不准答题;一、词汇填空 写出下列每个词汇对应的英汉单词共20小题,每空1分,共20分 1、 分子 molecule2、 物理性质 physical property3、 硬度 hardness4、 电解质 electrolyte5、 熔点 melting point6、 沸点 boiling point7、 离子键 ionic bond or electrovalent bond8、 晶体 crystal9、 硅 silicon10、钾 potassium11、溶解度 solubility12、构型 configuration13、挥发性 volitility14、正电荷 positive charge15、phosphorus 磷16、alcohol 乙醇17、acetone 丙酮18、base 碱19、acid 酸20、ether 乙醚二、给下列无机化合物的英语名称共10小题, 每小题2分,共20分1、 NaCN Sodium cyanide2、 BaOH 2 Barium hydroxide3、 KMnO 4 Potassium permanganate4、 H 2SO 4 Sulfuric acid5、 ZnSO 4 zinc sulfate or zinc sulphate6、 FeS Iron II sulfide or Ferrous sulfide7、 H 3PO 4 phosphoric acid8、 H 2SO 3 Sulfurous acid9、 HClO 4 Perchloric acid10、FeCl 3 iron III chloride or ferric chloride二、给下列有机化合物的英语名称共5小题, 每小题4分,共20分1. 甲乙醚 ethyl methyl ether2.对甲基苯酚 4-methyl phenol3.苯乙烯 styrene4.CH3CH=CCH2CH3 CH2 OH 2-ethyl-2-buten-1-ol5.CH33CCH2CH2OH 4,4-dimethyl-1-butanol or 4,4-dimethyl butanol三、英译汉共10小题, 每小题4分,共40分1、Carbon-sodium and carbon-potassium bonds are largely ionic incarbon-lead, carbon-tin, carbon-thallium and carbon-mercury bonds are essentially covalent.碳-钠键和碳-钾键有较大的离子性,碳-铅键,碳-锡键,碳-铊键和碳-汞键基本上属于共价键;2、The reactivity of organometallic compounds increases with the percent ionic character ofthe carbon-metal bond.金属有机化合物的反应活性随着碳金属键中离子性所占的百分数的增大而增强;3、Organometallic compounds of lithium and magnesium are of great importance in organicsynthesis.锂和镁的金属有机化合物在有机合成上有重大的意义;4、Unlike absorption, in which solute molecules diffuse from the bulk of a gas phase to thebulk of a liquid phase, in adsorption molecules diffuse from the bulk of the fluid to the surface of the solid adsorbent, forming a distinct adsorbed phase.在吸收过程中,溶质分子从气相主体中扩散的液相主体中;但是在吸附过程中,分子从流体主体中扩散到固体吸附剂的表面,形成一个独立的吸附相;5、Equipment for extraction must be capable of providing intimate contact between two phasesso as to affect transfer of solute between them and also of ultimate effecting a complete separation of the phases.提取的设备必须能够让两相有紧密的接触,使得两相中溶质的转移得以实现; 同时这个设备还要让两相的分离得以实现;6、Any potential application of adsorption has to be considered along with alternatives, notablydistillation, absorption and liquid extraction.任何可能的对于吸附的应用必须和其他的分离手段一起考虑来比较优劣,例如蒸馏,吸收和液相萃取;7、Leaching refers to the extraction of a soluble constituent from a solid by means of a solvent.浸提指的是通过使用一种溶剂把一种可溶性组分从固体中分离出来的提取办法;8、Separation of the compounds of a mixture by distillation takes advantages of the fact thatdifferent substances can differ in the degree to which they can be vaporized under the conditions of the experiment.通过蒸馏来分离混合物中的组分利用的是这样一个原理:不同的物质在同一个实验条件下气化的程度有区别;9、In a mixture of two completely immiscible liquids, each exerts its own vapor pressureindependently of the other.在一个由两个完全不互溶的液体所形成的混合物中,每一种液体都形成各自独立的蒸气压,相互不影响;10、On both large and small scale crystallization is the most important method for thepurification of solid organic compounds无论是在大规模还是小规模上,结晶都是一种非常重要的提纯固体有机物的方法;。
Nickel electrolysis process at OutokumpuHarjavalta Metals Oy奥托昆普哈贾瓦尔塔金属公司镍电解工艺AbstractThis paper deals with the electrolysis of nickel from sulphate solution and its electrochemical principles. As an example, the nickel electrolysis process at Outokumpu Harjavalta Metals Oy is discussed in more detail. The leaching of nickel matte and the purification of the nickel sulphate solution prior to electrolysis is also discussed. In addition, a short review of other hydrometallurgical nickel matte treatment processes and nickel electrolysis technologies is given.摘要:本论文主要研究了硫酸镍溶液的电解过程及其电化学原理。
作为例子,本论文主要在细节方面讨论了奥托昆普哈贾瓦尔塔金属公司的镍电解过程。
同时也讨论了电解过程之前的镍浸出及净化过程。
除此之外,其它镍湿法冶金处理过程及电解技术也在文中涉及到。
Outokumpu has produced electrolytic nickel at Harjavaita works since 1960. Nickel is electrowon from a nickel sulphate solution using diaphragm cells where a diaphragm cloth is used to prevent the catholyte solution and the acidic anolyte frommixing. Nickel is deposited on thin nickel starter sheets and the anodes are of unalloyed lead. The current density is 200 A/m2 and the deposition time is seven days. The ready cathodes weigh about 65 kg and they are harvested, washed and cut into squares and strips and finally packed for delivery. Electrolytic nickel is supplied to the electroplating, melting and superalloying industry.早在1960年开始,奥托昆普便在哈贾瓦尔塔工厂开始生产电解镍。
2014~2015学年秋季学期化工专业英语期末考试一、简单词汇翻译(每题1分,共20分)1、Alkali ( )2、sulphuric ( )3、ammonia ( )4、polymer ( )5、polyethylene( )6、polyurethane ( )7、cyclohexane ( ) 8、hydrogen( )9、nitric ( ) 10、profitability( )11、Seale-up ( ) 12、leaching( )13、corriosion ( ) 14、distillation( )15、gradient ( ) 16、exothermic( ) 17、polycarbonate( )18、isothermal( )19、cybernetics ( ) 20、filtration( )二、句子翻译(每题5分,共30分)1、Once the pilot plant is operational,performance and optimization data can be obtained in order to evaluate the process from an economic point of view.___________________________________________________________2、By contrast,the chemical engineer typically works with much larger quantities of material and with very large equipment.___________________________________________________________3、pressure drives the equilibrium forward ,as four molecules of gas are being transformed into two.___________________________________________________________4、What industry needs to achieve in the process is an acceptable combination of reaction speed and reaction yield.___________________________________________________________5、The ammonia and air mixture can be oxidized to dinitrogen and water.___________________________________________________________6、The important point to keep in mind is that all energy of all kinds must be included,although it may be converted to a single equivalent.___________________________________________________________三、化工专业名词书写(每题一分,共24分)1、加热()2、焙烧()3、吸收()4、冷凝()5、沉降()6、结晶()7、粉碎()8、电解()9、搅动()10、离心()11、平衡()12、体积()13、催化剂()14、一()15、二()16、三()17、四()18、五()19、六()20、七()21、八()22、九、()23、十()24、氮基化合物()四、表达方式运用,用括号里的单词翻译下列句子(每题5分,共20分)1、化学工程师经典的角色是把化学家在实验室里的发现拿来并发展成为能赚钱的、商业规模的化学过程。
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Equipment氢氧化铝aluminum hydrate氢氧化铝Hydrogen alumina清洗cleaning清洗设备cleaning equipment去磁器demagnetizer去离子作用deionization去氧化物处理deoxidizing热轧设备Heat-rolled Equipment熔剂油flux oil熔炼焊剂smelting flux 熔铸设备Founding Equipment乳烛液脱脂emulsion degreasing软铝棉aluminum soft wool软轮抛光buffing散热器Radiator伸缩铝管extension Aluminum tube渗铝aluminizing石灰石limestone刷光brushing双开式弹簧铝门aluminum swing door 水洗rinsing酸洗pickling添加剂additive铁分离器iron separator涂层设备Coating equipment涂料coating推拉式铝门aluminum sliding door脱膜stripping脱脂degreasing无缝铝管seamless Aluminum pipe稀土tombar thite/ rare-earth(RE)硝酸铝aluminum nitrate锌铝aluminum zinc型材拉弯设备Profiles Bending Equipment絮凝flocculate絮凝剂flocculating agent/ admixture压延设备Plain Rolled Equipment压铸铝aluminum die casting亚光处理matte finnishing阳极anode阳极效率anode efficiency阳极氧化anodic oxidation阳极氧化复合膜combined anodic coating阳极氧化膜anodic oxide coating阳极氧化膜再活化reactivation (of an anodic oxide coating)氧化铝alumina ,aluminum oxide氧化铝板alumite tile氧化锌zinc oxide液碱液压油hydraulic liquid/medium阴极cathode银粉漆涂层aluminum paint coating银灰漆aluminum paste 硬铝板duralumin sheet硬脂酸铝aluminum stearate有机聚合物喷涂膜spraying coating有机溶剂脱脂organic solvent degreasing 有效面significant surface原辅材料Raw Materials原铝virgin Aluminum增光brightening振动筛vibration sieve整型机integer machine纸板paperboard纸管paper tube纸制品paper products铸铝aluminum casting铸铝合金aluminum casting alloy铸扎设备Founding Equipment自然氧化natural oxidation香槟Champagne银白silvery white不锈钢色the color of stainless steel古铜色bronze金黄色golden yellow铝材aluminum profile氧化电泳铝材anodizing & electrophoresis profiles佛山耀银山铝业有限公司:FOSHAN YAOYINSHAN ALUMINIUM CO., LTD.铝合金建筑型材:wrought aluminium alloy extrude profiles for architecture阳极氧化型材:anodized colored profiles中国有色金属协会:CHINA NONFORROUS METALS ASSOCIATION电泳涂漆型材:electrophoretic coating profiles粉末喷漆型材:powder coating profiles Domicile:BaShi Industrial Area,Genghe Town Gaoming District,FoshanCity,Guangdong.P.R, China仅供个人用于学习、研究;不得用于商业用途。
SUPPLEMENTARY INFORMATION FORA new class of Solvent-in-Salt electrolyte for high-energyrechargeable metallic lithium batteriesAuthors: Liumin Suo, Yong-Sheng Hu*, Hong Li, Michel Armand and Liquan ChenAffiliations:Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China*Corresponding author’ email: yshu@Supplementary Figures:Supplementary Figure S1: Vogel-Tammann-Fulcher (VTF) plots of the ionic conductivity as a function of 1000/(T-T O) for the electrolytes with different ratios of LiTFSI to solvent.different electrolytes at room temperature.Supplementary Figure S3: The lithium-ion transference numbers. (a) the Li ion transference numbers of 2#, 4# and SIS-7# electrolytes and (b) the Li ion transference numbers of SIS-7# electrolytefor different constant DC voltages V DC (10-80mV).Supplementary Figure S4: DSC traces of DME and DOL:DME (1:1 by volume).was fabricated by mixing CMK-3/S, CNT and PVdF in a weight ratio of 90: 5: 5.electrolyte at a current rate of 0.2 C.Supplementary Figure S7Electrochemical performance of lithium-sulphur batteries. The cathode is Ketjenblack®/sulphur composite with 60wt.% sulphur and the used electrolytes are 2#:LiTFSI/DOL:DME=2 mol/1 L and SIS-7#: 7 mol/1 L, respectively.employing SIS-7# electrolyte at a current rate of 0.1C in the temperature range of -20 o C and 0 o C.Supplementary Figure S9: Metallic lithium anode deposition and dissolution experiment. (a) The first lithium deposition on Cu foil with 2# and SIS-7# electrolytes (10 C cm-2, I = 0.1 mA cm-2), and the first dissolution after deposition (upper cut-off 3V). (b) and (c) are SEM images of Li deposition with 2# electrolyte. (e), (f), (g) and (h) are SEM images of Li dissolution with SIS-7# electrolyte, among them,(g) and (h) are cross-section images.Supplementary Figure S10: XPS spectra (Li1s, F1S, S2P, C1S, N1S and O1S) measured from metallic lithium anodes after 100 cycles at a current rate of 0.2C without Ar+ ion sputtering. (a) Li1s, (c) F1S, (e) S2P, (g) C1S, (i) N1S and (k) O1S belong to 2# electrolyte, and (b) Li1s, (d) F1S, (f) S2P, (h) C1S, (j) N1Sand (l) O1S belong to SIS-7# electrolyte.Supplementary Figure S11: XRD patterns of (a) sulphur, (b) mesoporous (CMK-3) and (c) CMK-3 and sulphur composite with 60wt.% sulphur. Supplementary Figure S11 shows the XRD patterns of sulphur, CMK-3 and CMK-3/Sulphur nanocomposite, indicating the crystalline nature of pure sulphur, amorphous nature of CMK-3 carbon and CMK-3/Sulphur respectively. According to the total pore volume from BET data (Supplementary Table S3), the maximum loading of sulphur in mesoporous CMK-3 carbon is 57.9wt.%. Therefore, the loading sulphur content is fixed in 60wt.%, and the real sulphur content is 57.4wt.% confirmed by TG result(Supplementary Figure S13).(a, b) CMK-3 and (c, d) CMK-3/S with sulphur content 60wt.%.with a heating rate of 20 o C/min.Supplementary Tables:Supplementary Table S1: Estimated energy densities of lithium-ion cathodes and sulphur-cathodesFormula Theoretical capacity(mA h g-1-cathode)Estimated capacity(mA h g-1-cathode)Voltage (V)(vs. Li+/Li)Estimated energy density(Wh kg-1-cathode)Formula(anode)Theoretical capacity(mA h g-1-anode)Voltage (V)Estimated energy density(Wh kg-1-cell)SulphurC/S-60%C/S-50%C/S-40%C/S-30%x Li2MnO3-y LiMO2 LiFePO4LiMn2O4LiCoO216751005837670502250-320170148274—600500400300250-3001601101402.12.12.12.12.13.53.454.03.7351712601050840630875-1050552440518LiLiLiLiLiLi/C6Li/C6Li/C6Li/C6382938293829382938293829/3723829/3723829/3723829/3722.12.12.12.12.13.5/3.43.45/3.354.0/3.93.7/3.624471090929760569712-824/508-565483/378394/331456/366Note: Estimated capacity of sulphur in C/S composite is assumed to be 1000 mA h g-1. If Li metal is used as an anode, the excess Li is needed in a real cell due to the low cycling efficiency of Li anode, thus decreasing the energy density. In addition, if the silicon or tin based material is used as an anode, the estimated energy density of a cell is between lithium anode and graphite anode, please refer to reference 5: Zu, C. X. & Li, H. Thermodynamic analysis on energy densities of batteries. Energy Environ. Sci.4, 2614-2624 (2011)..Supplementary Table S2: Electrochemical performance comparison between SIS-7# and 2#Note: Voltage range: 1-3 V and Cycling number: 100Supplementary Table S3: BET data of CMK-3Carbon BET Surface area(m2 g-1)Average pore Radius(nm)Pore volume(cm-3 g-1)CMK-31057 3.8 1.19。