钙钛矿太阳能电池简介

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advantage
Widely used; mature
technology
Tolerate higher defect density
weakness
High cost; high energy consumption
High cost; heavily polluted; lack of rare
solid solid solid solid solid solid solid
Workpiece ratio(%) 3.8
6.5
9.7 10.9 15 15.4 12.1 19.3 20.2
LOGO
The structure of perovskite solar cell
Perovskite solar cells generally includes anode(FTO), N-type electron transfer layer, Perovskite absorption layer, P-type hole transporting layer and cathode(Au)
LOGO
LOGO
The structure or perovskite
Perovskites are materials described by the formula ABX3
1. Light extinction coefficiency 10 times higher than Dyes 2. Stability 3. Bandgap controllable
Perovskite can produce electrons and holes, electronic passes through electronic transport layer to the anode and to the cathode through the external circuit. meanwhile, hole can go to the cathode by hole transport layer, and combined with electron to complete a loop here.
LOGO
The type of perovskite solar cell
Mesoscopic ultra structure perovskite solar cell Structure:similar to Dye-sensitized solar cell Characteristics:a low energy loss and a hபைடு நூலகம்gh photoelectric conversion efficiencies but much interfacial defects has been existed in the solar cell.
LOGO
The type of perovskite solar cell
Planar perovskite solar cell Structure:don't need a three-dimensional skeleton for supporting materials, mainly consist with conductive glass substitute(FTO), composite oxide layer, perovskite layer, MTL, and metal electrode. Characteristics:simplified the structure of solar cell and the inter defects has been controlled.
element
dye-sensitized solar cell The third generation organic solar cell
Low cost;
abundant raw materials
Poor stability; mechanism complex ; hard to mass production
LOGO
The type of perovskite solar cell
Dye-sensitised perovskite type solar cells Structure:similar to Dye-sensitized solar cell,consist with photo-anode, photoabsortion material,HTM,counter electrode. Characteristics:a stable structure and easy to product,but it can't exist without the mesoporous nano oxide layer and much interfacial defects has been existed in the solar cell.
2013.9
UK
perovskite gas phase precipitation
2013.12 USA
gas phase auxiliary solution precipitation
2014 2015
USA Korea
modify TiO2 layer by doping Y /
Phase
liquid liquid
2012.08 Korea
2012
UK
2013.6 Switzerland
optimize synthesis technology of CH3NH3PbI3
the use of efficient solid electrolyte MSSC structure
perovskite continuous precipitation
LOGO
Perovskite Solar Cell
LOGO
developmental stage of solar cell
generation
solar cell
The first generation
silicon solar cell
The second generation
thin film solar cell
A—CH3NH3 B—Pb X--I
Layer structure
LOGO
The important stage of perovskite solar cell
Data
Nation
Method
2009
Japan
optimization of solar cell technology
2011
Korea