最新中国学者有关石墨烯研究高被引文献
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石墨烯及其应用前景作者:高荣伟来源:《少儿科技》2021年第08期2004年,英國科学家在实验室中从石墨上剥离出石墨薄片,并重复操作,最终得到仅由一层碳原子构成的薄片,即石墨烯。
石墨烯是目前世界上最薄、最坚硬的纳米材料,厚度仅0.335纳米,相当于头发丝的二十万分之一,硬度却是同等规格钢材的200倍,被材料学家亲切地称为“黑金”。
不仅如此,石墨烯还抗菌,有优良的透光性能。
石墨烯的这些特性赋予了这种新材料独特的地位,受到了众多科学家的青睐,刚一面世,就引发了全球范围内的研究热潮。
就储藏量来看,中国拥有的石墨烯资源十分丰富。
不仅如此,中国在石墨烯技术研发领域也处于领先地位,不仅开发了许多新用途,而且申请了为数众多的专利。
据统计,当前中国石墨烯专利数量全球领先。
据媒体报道,中国“90后”学者曹原近年来因其在石墨烯领域的科研成果,屡屡登上全球顶尖学术期刊。
2018年3月,《自然》连刊两篇论文,报道石墨烯超导的重大发现,第一作者就是曹原,他也成为该杂志创刊以来年龄最小的来自中国的第一作者。
曹原发现,当两层平行石墨烯堆成约1.1°的微妙角度时,会产生神奇的超导效应。
曹原的发现解决了困扰物理界多年的难题,轰动了国际材料学界,开辟了凝聚态物理的全新领域。
2019年3月,天津大学封伟教授领导的科研团队经过不懈努力,通过含氟自由基切割单壁碳纳米管,在世界范围内首次制备出单层石墨烯纳米带。
从技术角度讲,这是材料学界科研人员首次用一步法获得单层石墨烯纳米带。
值得一提的是,这种制备方法的发现意味着中国科学家突破了西方数十年的技术封锁,意义非凡。
目前,世界上第一条规模化的石墨烯生产线已在中国诞生。
中国石墨烯产业化应用不断取得突破,在世界领跑,产业格局初具雏形。
不过,目前我国石墨烯产业发展面临着产业链上下游之间沟通不畅的问题,关键领域的核心技术有待进一步突破。
石墨烯作为近年来备受关注的新型材料,应用前景十分广阔。
利用石墨烯的特性,半导体产业、光伏产业、航天产业、军工产业等领域都将迎来革命性的技术进步。
石墨烯增强铝基复合材料研究进展孙玮石墨烯是一种二维晶格结构的碳材料,具有优异的导热性、电导性和机械性能。
将石墨烯与金属基材料进行复合,在提高材料性能方面具有广阔的应用前景。
与此铝材料由于其良好的塑性和轻质特性,在航空航天、汽车制造、建筑工程等领域具有广泛的应用。
研究石墨烯增强铝基复合材料在应用中的表现和性能成为了当前研究的热点之一。
孙玮教授作为该领域的专家,在石墨烯增强铝基复合材料方面进行了深入研究,并取得了一系列重要的研究成果。
本文将对孙玮教授的研究工作进行介绍,并阐述石墨烯增强铝基复合材料研究的最新进展。
目前,制备石墨烯增强铝基复合材料的方法主要包括机械混合法、物理混合法和化学气相沉积法。
孙玮教授针对不同的制备方法进行了比较研究,并提出了一种新的制备方法,即电磁搅拌复合法。
该方法利用电磁场对材料进行搅拌,使石墨烯均匀分散在铝基复合材料中,从而提高了复合材料的均一性和稳定性。
二、石墨烯增强铝基复合材料的性能石墨烯增强铝基复合材料具有优异的导热性、强度和硬度,同时还具有良好的耐腐蚀性和耐磨损性。
孙玮教授通过实验对比分析了不同制备方法得到的复合材料的性能差异,发现电磁搅拌复合法得到的复合材料具有更优异的性能表现,这为其在实际应用中的推广奠定了基础。
航空航天领域对材料的轻量化和高性能要求非常高,石墨烯增强铝基复合材料正是符合这一需求的材料。
孙玮教授在石墨烯增强铝基复合材料在航空航天领域的应用方面进行了深入研究,发现该复合材料不仅可以降低飞机的整体重量,还可以提高飞机的耐腐蚀性和疲劳性能,因此具有广阔的应用前景。
随着汽车工业的不断发展,对汽车材料提出了更高的要求,包括轻量化、高强度和高导热性。
石墨烯增强铝基复合材料正是能够满足这些要求的材料。
孙玮教授对该复合材料在汽车制造领域的应用进行了研究,并提出了一种新型的汽车车身材料,该材料不仅重量轻,而且具有更高的安全性能和耐用性,可以大大提高汽车的整体性能。
石墨烯材料专利计量分析及启示作者:董璐陈枢舒郑菲来源:《新材料产业》 2015年第11期文/ 董璐陈枢舒郑菲中国科学院文献情报中心石墨烯[1] (G r a p h e n e)是一种由碳原子以s p2轨域互相键结成六方蜂巢晶格的平面结构,其厚度只有1个碳原子厚,C - C键长约为0.142n m,C - C之间夹角为120°。
石墨烯出现在实验室中是在2004年,英国曼彻斯特大学的科学家安德烈·海姆和康斯坦丁·诺沃肖洛夫成功地在试验中通过微机械剥离的方法从石墨中得到了石墨烯,2人也因此于2010年共同获得了诺贝尔物理学奖[2]。
自2004年被发现以来,因其特殊的纳米结构以及优良的力学、光学、热学、电学和化学性能,石墨烯应用范围非常广泛,在超轻材料、触摸屏、晶体管、电极、传感器、生物医学和海水淡化等众多领域均展现出巨大的应用潜能,其理论科学研究和产业化发展持续升温。
本文拟从专利计量分析的角度,揭示石墨烯领域的专利活动现状和区域布局情况,并对石墨烯材料所涉及的技术领域、核心技术进行初探,对国内外重点研发机构进行分析比较,为科技决策和课题研究提供参考。
本文分析所用专利数据来源于美国汤森路透科技公司TI平台(ThomsonInnovation)的增值专利信息数据库(DWP I和D C P I),共计检索到石墨烯相关专利(族)16 517件(检索式:ABD=graphene or graphenes,数据检索日期为2015年9月20日)。
一、石墨烯专利时间及区域分布在本质上,石墨烯是分离出来的单原子层平面石墨。
早在20世纪初科学家就利用X射线对晶体的散射发现了石墨烯的特色,但一直被认为无法在非绝对零度情况下稳定存在。
直到2004年,才被证实其可以单独存在。
从石墨烯专利的年度变化趋势图(基于最早优先权年,见图1)可以看出,全球石墨烯相关专利的申请在上世纪末就已出现(1991年美国GRAFTECH公司发明了制备低表面酸度插层石墨的方法),但随后发展较为平缓,处于技术萌芽期。
石墨烯对皮肤作用的研究文章
石墨烯在皮肤应用方面引起了广泛的研究兴趣,因为它具有独特的结构和性质,可能对皮肤产生一系列的效应。
以下是一些与石墨烯在皮肤上的作用相关的研究方向:
1.抗菌和抗炎作用:一些研究表明,石墨烯具
有抗菌和抗炎的性质,可能对治疗皮肤感染
和炎症有一定的帮助。
2.促进伤口愈合:有研究指出,石墨烯可能有
助于促进伤口愈合,加速创面愈合过程,可
能与其导电性和生物相容性有关。
3.抗氧化作用:石墨烯被认为具有抗氧化性
质,有助于对抗自由基,可能有助于减缓皮
肤老化的过程。
4.导热性质:石墨烯具有良好的导热性,因此
可能有助于在皮肤上提供一些散热效应,有
助于保持皮肤温度平衡。
5.药物输送:石墨烯的高表面积和可调控的
表面性质使其成为药物输送系统的候选材
料,可能有助于在皮肤上实现定向、控释的
药物输送。
需要注意的是,虽然有很多潜在的应用前景,但
石墨烯在医学和皮肤科领域的具体应用仍在研究中。
此外,石墨烯的安全性也是需要深入研究的一个方面,以确保其在皮肤应用中的长期安全性。
石墨烯材料的研发现状和应用前景石墨烯(graphene)是一种纯碳的二维材料,由于其极高的导电性、导热性和强硬特性,这种材料自从2004年被Nobel Prize获得者Andre Geim教授和 Konstantin Novoselov教授发现以来,引起了全球科学家的高度关注和研究热潮。
自此,石墨烯已经被视为第二个深变革的材料,被认为将改变科技、工业、生物医学、材料科学等领域的发展轨迹。
石墨烯(graphene)的制备方法主要包括机械剥离法、化学剥离法和化学气相沉积法等,其中机械剥离法较为成熟,利用普通铅笔在硅基底上涂一层石墨使其分散后,应用电子显微镜进行选择性剥离,就可以获得薄至单层的石墨烯样品。
然而,方法不够规范和低成本始终是影响石墨烯发展的因素。
近年来,针对石墨烯的制备方法和性质研究取得了实质性的进展,成果涉及其在光电器件、传感器、锂电池、柔性电子设备、生物医学、高性能计算机等领域的应用前景。
据统计,目前全球已有近4万篇的期刊文章,报道石墨烯材料的相关研究。
以下将详细介绍其研发现状和应用前景。
一、石墨烯的应用前景石墨烯拥有优异的性能,其导电性是常规材料的百倍以上,最低电导率约为1.0×10(Mho·m),最高电导率则达到了8.8×107(Mho·m),而且还具有优良的导热性能、极强的机械强度、独特的光学特性和吸附功能。
根据这些特性,石墨烯的应用前景十分广阔。
首先,在光电器件领域,石墨烯薄膜的优异透明性和导电性,可以被用于照明、触摸屏、智能窗户、光伏电池等领域。
其次,在传感器领域,石墨烯的高比表面积和超薄二维结构,可以在气体、生物、化学等领域的传感器中,实现更为精确的感应和测量。
另外,在锂电池及其他能量存储器上,石墨烯的极佳的导电性和锂离子扩散系数,不仅从根本上改善了能量存储器的性能,而且在新型电池领域,如超级电容器、钠离子电池等领域,带来了更为广阔的应用前景。
石墨烯的研究进展作者:杨盛昌来源:《中小企业管理与科技·上旬刊》2017年第03期【摘要】石墨烯是一种二维自由态原子晶体,具有极佳的导电特性、导热特性、光学特性、机械特性,在各个不同的学科领域得到了大量探索和研究。
论文阐述了石墨烯的结构、特性、应用进展以及石墨烯具有的优缺点,并对石墨烯的应用提出了建议。
【Abstract】The graphene is a kind of two-dimensional free atom crystal with excellent conductivity, thermal conductivity, optical and mechanical properties. It has been explored and researched much in various subjects areas. In this paper, the structure, properties and application of graphene and its advantages and disadvantages are discussed. Paper puts forward the proposal for the graphene application.【关键词】石墨烯;结构;性质;应用【Keywords】graphene; structure; character; application【中图分类号】TB332 【文献标志码】A 【文章编号】1673-1069(2017)03-0086-021 引言石墨烯(Graphene)是一种由碳原子以sp2杂化方式形成的蜂窝状平面薄膜,是当前发现的唯一一种二维自由态原子晶体,是除金刚石以外其他碳晶体的基本结构单元,具有许多极佳的电子及机械性能,是当前使用的材料中最薄、强度最大、导电和导热性能最好的一种纳米材料[1]。
石墨烯玩出来的诺贝尔奖全文共四篇示例,供读者参考第一篇示例:石墨烯是一种新型的碳材料,由于其独特的结构和性质,被誉为“21世纪的黑金”,并且在2010年荣获了诺贝尔物理学奖。
石墨烯的发现者包括安德烈·海姆和康斯坦丁·诺沃肖洛夫,以及诺沃肖洛夫的学生谢尔盖·德罗诺夫。
他们的发现证明了石墨烯具有优异的电学和热学性质,使其在半导体、电子器件、光电器件等领域有着重要的应用前景。
下面我们就来盘点一下石墨烯玩出来的诺贝尔奖。
石墨烯表现出了惊人的导电性能。
石墨烯的电子输运性质超越了传统半导体,电子在石墨烯中的速度达到了每秒2000公里,因此被誉为最好的导电材料。
石墨烯的高导电性能使其在电子器件领域具有巨大的应用潜力,比如可用于制造更薄更快的电子产品,提高电子产品的性能和稳定性。
石墨烯还表现出了出色的热导性能。
石墨烯的热传导性能是铜的两倍,是金的五倍,这意味着石墨烯可以高效地转移热能。
这种独特的性质使得石墨烯在热管理领域有着广泛的应用前景,比如用于制造更高效的散热材料,提高电子设备的散热效果。
石墨烯还表现出了优异的机械性能。
石墨烯的强度是钢的200倍,同时又具有很好的柔韧性,这使得石墨烯成为一种理想的结构材料。
石墨烯可以被用于制备超强韧、超轻的材料,用于航空航天领域、汽车制造领域等。
石墨烯还表现出了惊人的光学性能。
石墨烯可以吸收所有波长的光线,包括可见光和红外线,因此有望在光学器件领域有着广泛的应用。
比如用于制备更高性能的光学镜片、光纤、激光器等。
第二篇示例:石墨烯是由一层厚度的碳原子构成的二维材料,其结构独特,具有许多惊人的性质。
石墨烯具有非常高的导电性、热导性和强度,同时又非常轻薄和柔韧。
这些极具特色的性质使得石墨烯在电子学、光学等领域具有巨大的应用潜力。
石墨烯的发现,彻底改变了人们对碳材料的认识,也开启了一系列的材料科学研究,在能源、电子、医疗等领域的应用前景广阔。
2004年,安德烈•海姆和康斯坦丁•诺沃肖洛夫以及诺维格拉德夫(Novoselov)三位科学家通过实验室微操工具将石墨层层剥离,最终获得了单层厚度的石墨烯。
石墨烯相关研究文献汇总1.取少量鳞片石墨溶于芘-1-磺酸钠盐(Py-1-SO3)溶液,然后对溶液进行超声分散、离心洗涤,然后取上层溶液,进行表征。
经AFM 测试可知石墨片大小在0.2~0.4um,厚度在1~4nm。
从拉曼光谱得知,提高超声的处理时间可以减小石墨片的大小,并能得到较高的D 峰。
具体实验:取1mg芘-1-磺酸钠盐溶于10ml 蒸馏水中,并向其中加入30mg 鳞片石墨,超声80min后,离心(1000rpm,20min)去除大块未剥离的石墨,然后对上层液再离心(12000rpm,20min)收集上层液,向离心管下层加蒸馏水超声后再次离心收集上层液,如此重复三次。
将四次收集的上层液再次离心,去除石墨微粒,即为石墨烯分散液。
本文献还采用芘的其他磺酸盐和NMP进行分散作为对比研究。
文献:A simple method for graphene production based on exfoliation of graphite in water using 1-pyrenesulfonic acid sodium salt. Carbon,53 (2013) 357 –365.2.将天然石墨溶于IPA(2-丙醇)或DMF(二甲基甲酰胺)有机溶剂中,然后对溶液进行超声分散、离心后取400ul上层液,进行表征。
具体实验:取适量天然石墨分散在2-丙醇或者DMF中(1mg/mL),然后对溶液进行长时间超声,离心取上层溶液(400ul),滴于多孔无定形碳上(400目)进行TEM测试,另取400ul滴于氧化硅基底或者玻璃基底上,进行SEM及拉曼测试。
本文对不同的超声时间、有机溶剂以及超声时水的温度做了系统的探究,得出以下结论:随着超声时间的增加,石墨的碎片化显著增加(通过拉曼光谱ID /IG=C(λ)/La,La石墨碎片的平均尺寸);石墨分散在一些与其表面自由能相近的溶剂中,其混合后的晗变接近于零,这样剥离石墨烯所需的能量较小(这样溶剂-石墨的相互作用是范德华力而不是共价键)。
《文献检索与科技论文写作》作业学生姓名年级专业班级学号指导教师职称目录第一部分文献查阅练习 (1)第二部分文献总结练习 (7)第三部分科技论文图表练习 (8)第四部分心得体会 (11)第一部分文献查阅练习1、黄毅,陈永胜.石墨烯的功能化及其相关应用.中国科学B辑:化学2009年第39卷第9期:887-896摘要:石墨烯是2004年才被发现的一种新型二维平面纳米材料,其特殊的单原子层结构决定了它具有丰富而新奇的物理性质.过去几年中,石墨烯已经成为了备受瞩目的国际前沿和热点.在石墨烯的研究和应用中,为了充分发挥其优良性质,并改善其成型加工性(如分散性和溶解性等),必须对石墨烯进行功能化,研究人员也在这方面开展了积极而有效的工作.但是,关于石墨烯的功能化方面的研究还处在探索阶段,对各种功能化的方法和效果还缺乏系统的认识.如何根据实际需求对石墨烯进行预期和可控的功能化是我们所面临的机遇和挑战.本文重点阐述了石墨烯的共价键和非共价键功能化领域的最新进展,并对功能化石墨烯的应用作了介绍,最后对相关领域的发展趋势作了展望.关键词:功能化应用2、胡耀娟,金娟.石墨烯的制备、功能化及在化学中的应用.物理化学学报(Wuli Huaxue Xuebao)Acta Phys.-Chim.Sin.,2010,26(8):2073-2086摘要:石墨烯是最近发现的一种具有二维平面结构的碳纳米材料,它的特殊单原子层结构使其具有许多独特的物理化学性质.有关石墨烯的基础和应用研究已成为当前的前沿和热点课题之一.本文仅就目前石墨烯的制备方法、功能化方法以及在化学领域中的应用作一综述,重点阐述石墨烯应用于化学修饰电极、化学电源、催化剂和药物载体以及气体传感器等方面的研究进展,并对石墨烯在相关领域的应用前景作了展望。
关键词:制备功能化应用.3、杨永岗,陈成猛,温月芳.新型炭材料.第23卷第3期2008年9月:193-200摘要:石墨烯是单原子厚度的二维碳原子晶体,也是性能优异的新型纳米复合填料。
陈徐博士Carbon发表关于石墨烯太赫兹超材料器件
的最新研究成果
近日,中国科学院西安光学精密机械研究所瞬态光学与光子技术国家重点实验室研究员范文慧课题组,在太赫兹超材料功能器件方面的最新研究成果,以Multiple plasmonic resonance excitations on graphene metamaterials for ultrasensitive terahertz sensing为题,在线发表在Carbon上,论文第一作者为博士研究生陈徐。
论文提出并研究了一种利用石墨烯构建的三维太赫兹超材料结构,通过与太赫兹波的相互作用,可以实现多个等离子体共振模式激发;论文首次提出将这种具有多个等离子体共振模式的三维超材料结构应用于太赫兹传感,具有很高的传感灵敏度,可实现多频段太赫兹波超灵敏主动传感和多频带完美吸收功能,为太赫兹传感研究提供了一种创新方法。
太赫兹波主要指频率在0.1THz~10THz的电磁波,位于红外波与微波之间,处于宏观电子学与微观
光子学的过渡区域,具有很多独特特性,例如光子能量低、穿透性强、频谱覆盖有机分子和生物大分子的分子振动和转动能级等,有助于开发全新的光谱分析和无损检测技术,实现在材料特性检测、微电子测试、医学诊断、环境监控、化工和生物识别、军事国防等方面的应用。
然而,自然界的常规材料很难在太赫兹频段产生有效的电磁响应,在。
中国学者有关石墨烯研究高被引文献中国学者有关石墨烯研究高被引文献(被引次数超过80,检索时间2010年)显示 1 条,共 20 条作者: Zhang, J; Zou, HL; Qing, Q; Yang, YL; Li, QW; Liu, ZF; Guo, XY; Du, ZL标题: Effect of chemical oxidation on the structure of single-walled carbon nanotubes来源出版物: JOURNAL OF PHYSICAL CHEMISTRY B, 107 (16): 3712-3718 APR 24 2003摘要: In the present study, we report the systematic investigation of the effect of chemical oxidation on the structure of single-walled carbon nanotubes (SWNTs) by using different oxidants. The oxidation procedure was characterized by using infrared spectroscopy and transmission electron microscopy (TEM). The SWNTs were produced by chemical vapor deposition (CVD) and oxidized with three kinds of oxidants: (1) nitric acid (2.6 M), (2) a mixture of concentrated sulfuric acid (98 wt %) and concentrated nitric acid (16 M) (v/v = 3/1) and (3) KMnO4. The results reveal that the different functional groups can be introduced when the SWNTs are treated with different oxidants. Refluxing in dilute nitric acid can be considered as a mild oxidation for SWNTs, introducing the carboxylic acid groups only at those initial defects that already exist. The abundance of the carboxylic acid groups generated with this oxidant remained constant along with the treating time. In contrast, sonication of SWNTs in H2SO4/HNO3 increased the incidence of carboxylic acid groups not only at initial defect sites but also at newly created defect sites along the walls of SWNTs. Compared to the two oxidants above, when KMnO4 in alkali was used as the oxidant, which is relatively mild, different amounts of -OH, -C=O, and -COOH groups were introduced. The oxidation processes begin mainly with the oxidation of the initial defects that arise during the CVD growth of the SWNTs and are accompanied by processes that can be roughly divided into two steps: (1) the defect-generating step and (2) the defect-consuming step. Specifically, during the defect-generating step, the oxidants attack the graphene structure by electrophilic reactions and generate active sites such as -OH and -C=O. This step depends on the oxidant's ability to generate -C-OH groups and to transform them into -C=O groups. During the defect-consuming step, the graphene structure of the tube was destroyed by the oxidation of the generated active sites in step 1. The defect-consuming step mostly counts on the ability of the oxidant to etch/destroy the graphite-like structure around the already generated -C=O and their neighborhood groups.ISSN: 1520-6106DOI: 10.1021/jp027500u显示 2 条,共 20 条作者: Becerril, HA (Becerril, Hdctor A.); Mao, J (Mao, Jie); Liu, Z (Liu, Zunfeng); Stoltenberg, RM (Stoltenberg, Randall M.); Bao, Z (Bao, Zhenan); Chen, Y (Chen, Yongsheng)标题: Evaluation of solution-processed reduced graphene oxide films as transparent conductors来源出版物: ACS NANO, 2 (3): 463-470 MAR 2008摘要: Processable, single-layered graphene oxide (GO) is an intriguing nanomaterial with tremendous potential for electronic applications. We spin-coated GO thin-films on quartz and characterized their sheet resistance and optical transparency using different reduction treatments. A thermal graphitization procedure was most effective, producing films with sheet resistances as low as 10(2) - 10(3) Omega/square with 80% transmittance for 550 nm light. Our experiments demonstrate solution-processed GO films have potential as transparent electrodes.ISSN: 1936-0851DOI: 10.1021/nn700375n显示 3 条,共 20 条作者: Li, XL (Li, Xiaolin); Zhang, GY (Zhang, Guangyu); Bai, XD (Bai, Xuedong); Sun, XM (Sun, Xiaoming); Wang, XR (Wang, Xinran); Wang, E (Wang, Enge); Dai, HJ (Dai, Hongjie)标题: Highly conducting graphene sheets and Langmuir-Blodgett films来源出版物: NATURE NANOTECHNOLOGY, 3 (9): 538-542 SEP 2008摘要: Graphene is an intriguing material with properties that are distinct from those of other graphitic systems(1-5). The first samples of pristine graphene were obtained by 'peelingoff'(2,6) and epitaxial growth(5,7). Recently, the chemical reduction of graphite oxide was used to produce covalently functionalized single-layer graphene oxide(8-15). However, chemical approaches for the large-scale production of highly conducting graphene sheets remain elusive. Here, we report that the exfoliation reintercalation- expansion of graphite can produce high-quality single-layer graphene sheets stably suspended in organic solvents. The graphene sheets exhibit high electrical conductance at room and cryogenic temperatures. Large amounts of graphene sheets in organic solvents are made into large transparent conducting films by Langmuir-Blodgett assembly in a layer-by-layer manner. The chemically derived, high-quality graphene sheets could lead to future scalable graphene devices. ISSN: 1748-3387DOI: 10.1038/nnano.2008.210显示 4 条,共 20 条作者: Xu, YX (Xu, Yuxi); Bai, H (Bai, Hua); Lu, GW (Lu, Gewu); Li, C (Li, Chun); Shi, GQ (Shi, Gaoquan)标题: Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets来源出版物: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130 (18): 5856-+ MAY 7 2008摘要: Flexible graphene films were prepared by the filtration of water-soluble noncovalently functionalized graphene sheets with pyrenebutyrate. The work presented here will not only open a new way for preparing water-soluble graphene dispersions but also provide a general route for fabricating conducting films based on graphene.ISSN: 0002-7863DOI: 10.1021/ja800745y显示 5 条,共 20 条作者: Yi, W; Lu, L; Zhang, DL; Pan, ZW; Xie, SS标题: Linear specific heat of carbon nanotubes来源出版物: PHYSICAL REVIEW B, 59 (14): R9015-R9018 APR 1 1999摘要: The specific heat and thermal conductivity of millimeter-long aligned carbon multiwall nanotubes (MWNT's) have been measured. As a rolled-up version of graphene sheets, a MWNT of a few tens nm diameter is found to demonstrate a strikingly linear temperature-dependent specific heat over the entire temperature range measured (10-390 K). The results indicate that interwall coupling in MWNT's is rather weak compared with its parentform,graphite, so that one can treat a MWNT as a few decoupled two-dimensional single wall tubules. The thermal conductivity is found to be low, indicating the existence of substantial amounts of defects in the MWNT's prepared by a chemical-vapor-deposition method. [S0163-1829(99)50714-5].ISSN: 0163-1829显示 6 条,共 20 条作者: Wang, Q; Li, H; Chen, LQ; Huang, XJ标题: Monodispersed hard carbon spherules with uniform nanopores来源出版物: CARBON, 39 (14): 2211-2214 2001摘要: Hard carbon with perfect spherical morphology was prepared for the first time by a hydrothermal method. It has controllable monodispersed particle size and a smooth surface. Transmission electron microscopy shows that there are a large quantity of uniform nanopores of about 0.4 nm in diameter and only very few parallel graphene, sheets exist within the spherules. This hard carbon material has a specific BET surface area of 400 m(2)/g for N-2 as adsorbate, and can reversibly store lithium up to 430 mAh/g. This shows convincingly that carbon nanopores can store a large quantity of lithium. (C) 2001 Published by Elsevier Science Ltd.ISSN: 0008-6223显示 7 条,共 20 条作者: Zhang, XF; Cao, AY; Wei, BQ; Li, YH; Wei, JQ; Xu, CL; Wu, DH标题: Rapid growth of well-aligned carbon nanotube arrays来源出版物: CHEMICAL PHYSICS LETTERS, 362 (3-4): 285-290 AUG 19 2002摘要: Vertically aligned carbon nanotube (CNT) arrays with high density were synthesized on quartz substrates in large areas (100 x 40 mm(2)) by catalytic decomposition of a ferrocene-xylene mixture at 850 degreesC in a quartz tube reactor. The nanotubes grow at a high growth rate of similar to50 mun/min, and reach 1.5 mm. in length in 30 min. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) investigations reveal that the nanotubes are high-purity multi-wall CNTs with well-ordered graphene sheets, and about 30-60 nm in diameter. This provides a simple way to synthesize well-aligned CNTs in large areas. A continuous rapid growth model is suggested for the CNTs in high growth rate under our experimental conditions. (C) 2002 Elsevier Science B.V. All rights reserved.ISSN: 0009-2614显示 8 条,共 20 条作者: Yan, QM (Yan, Qimin); Huang, B (Huang, Bing); Yu, J (Yu, Jie); Zheng, FW (Zheng, Fawei); Zang, J (Zang, Ji); Wu, J (Wu, Jian); Gu, BL (Gu, Bing-Lin); Liu, F (Liu, Feng); Duan, WH (Duan, Wenhui)标题: Intrinsic current-voltage characteristics of graphene nanoribbon transistors and effect of edge doping来源出版物: NANO LETTERS, 7 (6): 1469-1473 JUN 2007摘要: We demonstrate that the electronic devices built on patterned graphene nanoribbons (GNRs) can be made with atomic-perfect-interface junctions and controlled doping via manipulation of edge terminations. Using first-principles transport calculations, we show that the GNR field effect transistors can achieve high performance levels similar to those made from single-walled carbon nanotubes, with ON/OFF ratios on the order of 10(3)-10(4), subthreshold swing of 60 meV per decade, and transconductance of 9.5 x 10(3) Sm-1. ISSN: 1530-6984DOI: 10.1021/nl070133j显示 9 条,共 20 条作者: Huang, Y (Huang, Y.); Wu, J (Wu, J.); Hwang, KC (Hwang, K. C.)标题: Thickness of graphene and single-wall carbon nanotubes来源出版物: PHYSICAL REVIEW B, 74 (24): Art. No. 245413 DEC 2006摘要: Young's modulus and the thickness of single wall carbon nanotubes (CNTs) obtained from prior atomistic studies are largely scattered. In this paper we establish an analytic approach to bypass atomistic simulations and determine the tension and bending rigidities of graphene and CNTs directly from the interatomic potential. The thickness and elastic properties of graphene and CNTs can also be obtained from the interatomic potential. But the thickness, and therefore elastic moduli, also depend on type of loading (e.g., uniaxial tension, uniaxial stretching, equibiaxial stretching), as well as the nanotube radius R and chirality when R < 1 nm. This explains why the thickness obtained from prior atomistic simulations is scattered. This analytic approach is particularly useful in the study of multiwall CNTs since their stress state may be complex even under simple loading (e.g., uniaxial tension) due to the van der Waals interactions between nanotube walls. The present analysis also provides an explanation of Yakobson's paradox that the very high Young's modulus reported from the atomistic simulations together with the shell model may be due to the not-well-defined CNT thickness.ISSN: 1098-0121文献编号: 245413DOI: 10.1103/PhysRevB.74.245413显示 10 条,共 20 条作者: Dai, LM; Patil, A; Gong, XY; Guo, ZX; Liu, LQ; Liu, Y; Zhu, DB标题: Aligned nanotubes来源出版物: CHEMPHYSCHEM, 4 (11): 1150-1169 NOV 14 2003摘要: Since the discovery of carbon nanotubes by Iijima in 1991, various carbon nanotubes with either a single- or multilayered graphene cylinder(s) have been produced, along with their noncarbon counterparts (for example, inorganic and polymer nanotubes). These nanostructured materials often possess size-dependent properties and show new phenomena related to the nanosize confinement of the charge carriers inside, which leads to the possibility of developing new materials with useful properties and advanced devices with desirable features for a wide range of applications. In particular, carbon nanotubes have been shown to exhibit superior properties attractive for various potential applications, ranging from their use as novel electron emitters in flat-panel displays to electrodes in electrochemical sensors. For many of the applications, it is highly desirable to have aligned/patterned forms of carbon nanotubes so that their structure/property can be easily assessed and so that they can be effectively incorporated into devices. In this Review, we present an overview on the development of aligned and micropatterened nanotubes, with an emphasis on carbon nanotubes.ISSN: 1439-4235DOI: 10.1002/cphc.200300770显示 11 条,共 20 条作者: Shan, CS (Shan, Changsheng); Yang, HF (Yang, Huafeng); Song, JF (Song, Jiangfeng); Han, DX (Han, Dongxue); Ivaska, A (Ivaska, Ari); Niu, L (Niu, Li)标题: Direct Electrochemistry of Glucose Oxidase and Biosensing for Glucose Based on Graphene来源出版物: ANALYTICAL CHEMISTRY, 81 (6): 2378-2382 MAR 15 2009摘要: We first reported that polyvinylpyrrolidone-protected graphene was dispersed well in water and had good electrochemical reduction toward O-2 and H2O2. With glucose oxidase (GOD) as an enzyme model, we constructed a novel polyvinylpyrrolidone-proteeted graphene/polyethylenimine-ftmctionalized ionic liquid/GOD electrochemical biosensor, which achieved the direct electron transfer of GOD, maintained its bioactivity and showed potential application for the fabrication of novel glucose biosensors with linear glucose response up to14 mM.ISSN: 0003-2700DOI: 10.1021/ac802193c显示 12 条,共 20 条作者: Zhou, X; Zhou, JJ; Ou-Yang, ZC标题: Strain energy and Young's modulus of single-wall carbon nanotubes calculated from electronic energy-band theory来源出版物: PHYSICAL REVIEW B, 62 (20): 13692-13696 NOV 15 2000摘要: The strain energies in straight and bent single-walled carbon nanotubes (SWNT's) are calculated by taking account of the total energy of all the occupied band electrons. The obtained results are in good agreement with previous theoretical studies and experimental observations. Young's modulus and the effective wall thickness of SWNT's are obtained from the bending strain energies of SWNT's with various cross-sectional radii. The repulsion potential between ions contributes the main part of Young's modulus of SWNT's. The wall thickness of the SWNT comes completely from the overlap of electronic orbits and is approximately of the extension of the pi orbit of carbon atom. Both Young's modulus and the wall thickness are independent of the radius and the helicity of SWNT, and insensitive to the fitting parameters. The results show that continuum elasticity theory can serve well to describe the mechanical properties of SWNT's.ISSN: 1098-0121显示 13 条,共 20 条作者: Kan, EJ (Kan, Er-Jun); Li, ZY (Li, Zhenyu); Yang, JL (Yang, Jinlong); Hou, JG (Hou, J.G.)标题: Half-metallicity in edge-modified zigzag graphene nanoribbons来源出版物: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130 (13): 4224-+ APR 2 2008摘要: Graphene is an important material with potential application in spintronics. Edge-modified zigzag graphene nanoribbons (ZGNR) are investigated with density functional theory. The modifications are realized by saturating the dangling edge bonds by different terminal groups, such as H, NH2, NO2, and CH3. Such modification has a significant impact on the ZGNR electronic structure. Half-metallicity is observed when ZGNR is terminated by NO2 groups at one edge and by CH3 groups on the other side. Free energy analysis suggests that edge-modification is a practical way in experiment to realize half-metallicity. ISSN: 0002-7863DOI: 10.1021/ja710407t显示 14 条,共 20 条作者: Peng, LM; Zhang, ZL; Xue, ZQ; Wu, QD; Gu, ZN; Pettifor, DG标题: Stability of carbon nanotubes: How small can they be?来源出版物: PHYSICAL REVIEW LETTERS, 85 (15): 3249-3252 OCT 9 2000摘要: Experimental evidence has been found for the existence of small single wall carbon nanotubes with diameters of 0.5 and 0.33 nn? by high resolution transmission electron microscopy, and their mechanical stability was investigated using tight-binding molecular dynamics simulations. It is shown that, while the carbon tubes with diameters smaller than 0.4 nm are energetically less favorable than a graphene sheet, some of them are indeed mechanically stable at temperatures as high as 1100 degrees C. The 0.33 nm carbon tube observed is likely a (4, 0) tube and is indeed part of a compound nanotube system that forms perhaps the smallest metal-semiconductor-metal tubular junction yet synthesized.ISSN: 0031-9007显示 15 条,共 20 条作者: Wei, BQ; Spolenak, R; Kohler-Redlich, P; Ruhle, M; Arzt, E标题: Electrical transport in pure and boron-doped carbon nanotubes来源出版物: APPLIED PHYSICS LETTERS, 74 (21): 3149-3151 MAY 24 1999摘要: The resistivities of individual multiwalled pure and boron-doped carbon nanotubes have been measured in the temperature range from 25 to 300 degrees C. The connection patterns were formed by depositing two-terminal tungsten wires on a nanotube using focused-ion-beam lithography. A decrease of the resistivity with increasing temperature, i.e., a semiconductor-like behavior, was found for both B-doped and pure carbon nanotubes. B-doped nanotubes have a reduced room-temperature resistivity (7.4 X 10(-7) - 7.7 X 10(-6) Ohm m) as compared to pure nanotubes (5.3 X 10(-6) - 1.9 X 10(-5) Ohm m), making the resistivity of the doped tubes comparable to those along the basal plane of graphite. The activation energy derived from the resistivity versus temperature Arrhenius plots was found to be smaller for the B-doped (55-70 meV) than for the pure multiwalled nanotubes (190-290 meV). (C) 1999 American Institute of Physics. [S0003-6951(99)03021-1].ISSN: 0003-6951显示 16 条,共 20 条作者: Liu, ZF (Liu, Zunfeng); Liu, Q (Liu, Qian); Huang, Y (Huang, Yi); Ma, YF (Ma, Yanfeng); Yin, SG (Yin, Shougen); Zhang, XY (Zhang, Xiaoyan); Sun, W (Sun, Wei); Chen, YS (Chen, Yongsheng)标题: Organic Photovoltaic Devices Based on a Novel Acceptor Material: Graphene来源出版物: ADVANCED MATERIALS, 20 (20): 3924-+ OCT 17 2008摘要: Solution-processable functionalized graphene (SPFGraphene, see figure) is used as the electron-accepting material in organic photovoltaic (OPV) devices for the first time, showing that it is a competitive alternative. The fabrication and performance of bulk heterojunction OPV devices with SPFGraphene and different donor materials is presented, together with the impact of post-fabrication annealing.ISSN: 0935-9648DOI: 10.1002/adma.200800366显示 17 条,共 20 条作者: Fan, XB (Fan, Xiaobin); Peng, WC (Peng, Wenchao); Li, Y (Li, Yang); Li, XY (Li, Xianyu); Wang, SL (Wang, Shulan); Zhang, GL (Zhang, Guoliang); Zhang, FB (Zhang, Fengbao)标题: Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation来源出版物: ADVANCED MATERIALS, 20 (23): 4490-4493 DEC 2 2008摘要: Stable graphene suspensions are prepared using a new, green, and intriguing synthetic route. Graphene can be directly prepared by the fast deoxygenation of exfoliated graphite oxide in strong alkaline solutions at low temperatures (50-90 degrees C), in the absence of reducing agents. This study opens an opportunity towards the production of processable graphene on an industrial scale.ISSN: 0935-9648DOI: 10.1002/adma.200801306显示 18 条,共 20 条作者: Cai, WW (Cai, Weiwei); Piner, RD (Piner, Richard D.); Stadermann, FJ (Stadermann, Frank J.); Park, S (Park, Sungjin); Shaibat, MA (Shaibat, Medhat A.); Ishii, Y (Ishii, Yoshitaka); Yang, DX (Yang, Dongxing); Velamakanni, A (Velamakanni, Aruna); An, SJ (An, Sung Jin); Stoller, M (Stoller, Meryl); An, JH (An, Jinho); Chen, DM (Chen, Dongmin); Ruoff, RS (Ruoff, Rodney S.)标题: Synthesis and solid-state NMR structural characterization of C-13-labeled graphite oxide来源出版物: SCIENCE, 321 (5897): 1815-1817 SEP 26 2008摘要: The detailed chemical structure of graphite oxide ( GO), a layered material prepared from graphite almost 150 years ago and a precursor to chemically modified graphenes, has not been previously resolved because of the pseudo- random chemical functionalization of each layer, as well as variations in exact composition. Carbon-13 (C-13) solid- state nuclear magnetic resonance ( SSNMR) spectra of GO for natural abundance C-13 have poor signal- to- noise ratios. Approximately 100% C-13- labeled graphite was made and converted to C-13- labeled GO, and C-13 SSNMR was used to reveal details of the chemical bonding network, including the chemical groups and their connections. Carbon-13-labeled graphite can be used to prepare chemically modified graphenes for C-13 SSNMR analysis with enhanced sensitivity and for fundamental studies of C-13-labeled graphite and graphene. ISSN: 0036-8075DOI: 10.1126/science.1162369显示 19 条,共 20 条作者: Guo, GY; Chu, KC; Wang, DS; Duan, CG标题: Linear and nonlinear optical properties of carbon nanotubes from first-principles calculations来源出版物: PHYSICAL REVIEW B, 69 (20): Art. No. 205416 MAY 2004摘要: A systematic ab initio study of the optical as well as structural and electronic properties of the carbon nanotubes within density-functional theory in the local-density approximation has been performed. Highly accurate full-potential projected augmented wave method was used. Specifically, the optical dielectric function epsilon and second-order optical susceptibility chi((2)) as well as the band structure of a number of the armchair[(3,3),(5,5),(10,10),(15,15),(20,20)], zigzag [(5,0),(10,0),(15,0),(20,0)] and chiral[(4,2),(6,2),(6,4),(8,4),(10,5)] carbon nanotubes have been calculated. The underlying atomic structure of the carbon nanotubes was determined theoretically. It is found that for the electric field parallel to the nanotube axis (Eparallel to(z) over cap), the absorptive part epsilon(') of the optical dielectric function for the small nanotubes (the diameter being smaller than, say, 25 Angstrom) in the low-energy range (0-8 eV) consists of a few distinct peaks. Furthermore, the energy position, the shape, and the number of the peaks depend rather strongly on the diameter and chirality. This suggests that one could use these distinct optical features to characterize the chirality and diameter of the grown nanotubes. In contrast, for the electric field perpendicular to the nanotube axis (Eperpendicular toz), the epsilon(') spectrum of all the nanotubes studied except the three 4 Angstrom nanotubes in the low-energy region is made up of a broad hump. The bandwidth of the hump increases with the nanotube diameter and the magnitude of the hump is in general about half of that of the epsilon(') for Eparallel to(z) over cap. Surprisingly, given their one-dimensional character, the optical anisotropy of the nanotubes is smaller than that of graphite. For the nanotubes with a moderate diameter (say, 30 Angstrom) such as the (20,20) nanotube, the optical anisotropy is not large and the epsilon(') spectrum for both electric-field polarizations becomes rather similar to that of graphite with electric-field parallel to the graphene layers (Eperpendicular toc). The calculated static polarizability alpha(0) for the semiconducting nanotubes is rather anisotropic withalpha(0) for Eparallel to(z) over cap being several times larger than that for Eperpendicular toz. For both electric-field polarizations, alpha(0) is nearly proportional to the square of the tube diameter. The calculated electron energy loss spectra of all the nanotubes studied here for both electric field polarizations are similar to that of Eperpendicular toc of graphite, being dominated by a broad (pi+sigma)-electron plasmon peak at near 27 eV and a small pi-electron plasmon peak at 5-7 eV. Only the chiral nanotubes would exhibit second-order nonlinear optical behavior. Furthermore, only two tensor elements chi(xyz)((2)) andchi(yzx)((2)) are possibly nonzero with chi(xyz)((2))=-chi(yzx)((2)). For all the chiral nanotubes studied here, both the real and imaginary parts of chi(xyz)((2))(-2omega,omega,omega) show an oscillatory behavior. The absolute value of chi(xyz)((2))(-2omega,omega,omega) of all the chiral nanotubes in the photon energy range of 0.1-3.0 eV is huge, being up to ten times larger than that of GaAs, suggesting that chiral nanotubes have potential applications in nonlinear optics, e.g., second-harmonic generation and sum-frequency generation. Nevertheless, the static value of both chi(xyz)((2)) and chi(yzx)((2)) is zero.ISSN: 1098-0121文献编号: 205416DOI: 10.1103/PhysRevB.69.205416显示 20 条,共 20 条作者: Chen, H (Chen, Haiqun); Muller, MB (Mueller, Marc B.); Gilmore, KJ (Gilmore, Kerry J.); Wallace, GG (Wallace, Gordon G.); Li, D (Li, Dan)标题: Mechanically strong, electrically conductive, and biocompatible graphene paper来源出版物: ADVANCED MATERIALS, 20 (18): 3557-+ SEP 17 2008摘要: Ultrastrong, smooth, and shiny graphene paper with a layered structure (see figure) is prepared by vacuum filtration of a well-dispersed graphene dispersion. Moderate thermal annealing further enhances its mechanical properties and electrical conductivity. A combination of exceptional mechanical strength, thermal stability, high electrical conductivity, and biocompability makes this unique material promising for many technological applications. ISSN: 0935-9648DOI: 10.1002/adma.200800757。