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第一部分：化学品名称化学品中文名称：硫酸钡化学品英文名称：barium sulfate中文名称2：英文名称2：baryta white技术说明书编码：1529CAS No.：7727-43-7分子式：BaSO4分子量：233.39第二部分：成分/组成信息有害物成分含量CAS No.硫酸钡7727-43-7第三部分：危险性概述危险性类别：侵入途径：健康危害：纯硫酸钡不溶于水，无毒。
吸入后可引起胸部紧束感、胸痛、咳嗽等。
对眼睛有刺激性。
长期吸入可致钡尘肺。
环境危害：对环境有危害，对大气可造成污染。
燃爆危险：本品不燃。
第四部分：急救措施皮肤接触：脱去污染的衣着，用流动清水冲洗。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
就医。
吸入：脱离现场至空气新鲜处。
如呼吸困难，给输氧。
就医。
食入：饮足量温水，催吐。
就医。
第五部分：消防措施危险特性：受高热分解产生有毒的硫化物烟气。
有害燃烧产物：氧化硫。
灭火方法：消防人员必须穿全身防火防毒服，在上风向灭火。
灭火时尽可能将容器从火场移至空旷处。
第六部分：泄漏应急处理应急处理：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿一般作业工作服。
用砂土、干燥石灰或苏打灰混合。
收集于干燥、洁净、有盖的容器中，转移至安全场所。
若大量泄漏，收集回收或运至废物处理场所处置。
第七部分：操作处置与储存操作注意事项：密闭操作，局部排风。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩。
避免产生粉尘。
避免与还原剂接触。
搬运时要轻装轻卸，防止包装及容器损坏。
配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、通风的库房。
远离火种、热源。
应与易（可）燃物、还原剂分开存放，切忌混储。
储区应备有合适的材料收容泄漏物。
第八部分：接触控制/个体防护职业接触限值中国MAC(mg/m3)：未制定标准前苏联MAC(mg/m3)：未制定标准TLVTN：ACGIH 10mg/m3TLVWN：未制订标准监测方法：工程控制：密闭操作，局部排风。
天然硫酸钡制品安全技术说明书Material Safety Data Sheet ofBarite Products说明书目录Catalog第一部分The1st 化学品名称Name of Product第九部分The9th理化特性Physicochemical Properties第二部分The2nd 成分/组成信息Ingredients第十部分The10th稳定性和反应活性Stability and Reactivity第三部分The3rd 危险性概述Overview of fatalness第十一部分The11th毒理学资料Toxicological Information第四部分The4th 急救措施First Aid第十二部分The12th生态学资料Ecological Information第五部分The5th 消防措施Measures of Fire-fighting第十三部分The13th废弃处置Waste Management第六部分The6th 泄漏应急处理Emergency Processing of Leaking第十四部分The14th运输信息Transport Information第七部分The7th 操作处置与储存Operating and Storing第十五部分The15th法规信息Regulations and Laws第八部分The8th 接触控制/个体防护Manage touchingandIndividualProtection第十六部分The16th其他信息Others天然硫酸钡制品安全技术说明书Material Safety Data Sheet ofBarite Products 第一部分：化学品名称The1st:Name of Product化学品中文名称Chinese Name 天然硫酸钡化学品俗名Other Names in Chinese天然硫酸钡制品、重晶石粉化学品英文名称English Name Natural BariumSulfate英文名称In EnglishNaturalBariumSulfate,BariteProducts产品型号ZJ-031,ZJ-051,ZJ-101,ZJ-151,ZJ-201,ZJ-451,ZJ-241;ZJ-05C1,ZJ-10C1,ZJ-20C1,ZJ-45C1;ZJ-03D,ZJ-05D,ZJ-10D,ZJ-20D技术说明书编码Code of MSDS111202CAS No13462-86-7生产企业名称Company Name 扬州天力非金属材料有限公司YANGZHOU TIANLI NONMETAL MATERIAL CO.LTD地址Address 中国江苏省扬州市广陵区泰安镇工业园区(邮编：225113)Tai’an Industry Park,Guangling District,Yangzhou,Jiangsu,China225000生效日期Date of Entry into Force 2011-12-26修订日期Date of Revision2018-12-25第二部分：成分/组成信息The2nd:Ingredients有害物成分Hazardous Components含量ContentsCAS No.硫酸钡Barium Sulfate≥80%~99%13462-86-7第三部分：危险性概述The3rd:Overview of fatalness危险性类别Hazard Categories 根据中国劳动保护安全标准不属危险品No Hazard,According to China’s Labor Protection Safety Standards侵入途径Invasion Pathway健康危害Hazard to health 从事开采、加工的工人常出现上呼吸道炎症、支气管炎，可伴有肺气肿。
MSDS-天然重晶石(硫酸钡)——产品安全数据表ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-20071. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONTrade Name: BariteChemical Family: MineralProduct Use: Barite is used as the chief source of barium and its chemical compounds. Ground barite is used as filler in the manufacture of linoleum, oilcloth, paper and textilemanufacturing, rubber, and plastics. Ground barite is used in the oil industry, e.g., as filtering and deodorizing agents in the refining of petroleum and, mixed with other materials, as drilling mud to protect the cutting bit while drilling. White barite is used in making paint as a white pigment.Supplied by:Zhanjiang New Orient Minerals Co., LtdInside of Zhanjiang Seaport District No.4,1# Youyi Road, Xiashan, Zhanjiang,Guangdong, ChinaTel: (86)759-2254830 Fax:(86)759-22535322. COMPOSITION/INFORMATION ON INGREDIENTSSUBSTANCE CAS Number PERCENTACGIHTLV-TWAOSHAPEL-TWABarium sulfate7727-43-792 - 99%10 mg/m315 mg/m33. HAZARDS IDENTIFICATIONPhysical State: Powder. Odor: Odorless Color: White to greyPotential Health Effects:Acute Effects:Eye Contact: May cause mechanical irritationSkin Contact: May cause mechanical irritation.Inhalation: May cause mechanical irritation.Ingestion: May cause gastric distress, nausea and vomiting if ingested. Carcinogenicity & Chronic Effects: See Section 11 - Toxicological Information.4. FIRST AID MEASURESEye Contact: Promptly wash eyes with lots of water while lifting eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.Skin Contact: Wash skin thoroughly with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if any discomfort continues.Inhalation: Move person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-2007Ingestion: Dilute with 2 - 3 glasses of water or milk, if conscious. Never give anything by mouth to an unconscious person. If signs of irritation or toxicity occur seek medical attention. General notes: Persons seeking medical attention should carry a copy of this MSDS with them.5. FIRE FIGHTING MEASURESFlammable PropertiesFlash Point: F (C): NAFlammable Limits in Air - Lower (%): NDFlammable Limits in Air - Upper (%): NDAutoignition Temperature: F (C): NDFlammability Class: NAOther Flammable Properties: NDExtinguishing Media: This material is not combustible. Useextinguishing media appropriate for surrounding fire.Protection Of Fire-Fighters:Special Fire-Fighting Procedures: Do not enter fire area without proper personal protective equipment, including NIOSH/MSHA approved self-contained breathing apparatus. Evacuate area and fight fire from a safe distance. Water spray may be used to keepfire-exposed containers cool. Keep water run off out of sewers and waterways. Hazardous Combustion Products: Not determined.NFPA Ratings: Health 1, Flammability 0, Reactivity 0HMIS Ratings: Flammability 0, Reactivity 0, Health 1*HMIS Key: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Hazard.*Chronic effects - See Section 11. See Section 8 for Personal Protective Equipment recommendations.6. ACCIDENTAL RELEASE MEASURESPersonal Precautions: Use personal protective equipment identified in Section 8.Spill Procedures: Evacuate surrounding area, if necessary. Contain spilled material. Avoid the generation of dust. Sweep, vacuum, or shovel and place into closable container fordisposal.Environmental Precautions: Do not allow to enter sewer or surface and subsurface waters. Waste must be disposed of in accordance with federal, state and local laws.7. HANDLING AND STORAGEHandling: Put on appropriate personal protective equipment. Avoid contact with skin and eyes. Avoid generating or breathing dust. Use only in a well ventilated area. Wash thoroughly after handling.ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-2007Storage: Store in dry, well-ventilated area. Keep container closed. Store away from incompatibles. Follow safe warehousing practices regarding palletizing, banding, shrink-wrapping and/or stacking.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering Controls: Use appropriate engineering controls such as, exhaust ventilation and process enclosure, to ensure air contamination and keep workers exposure below the applicable limits.Personal Protection Equipment:All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazards present and the risk of exposure to those hazards. The PPE recommendations below are based on our assessment of the chemical hazards associated with this product. The risk of exposure and need for respiratory protection will vary from workplace to workplace and should be assessed by the user.Eye/Face Protection: Dust resistant safety goggles.Skin Protection: Wear appropriate clothing to prevent repeated or prolonged skin contact. Chemical resistant gloves recommended for prolonged or repeated contact. Use protective gloves made of: Neoprene. Nitrile.Respiratory Protection: Wear a NIOSH certified respirator if dust over TLV.General Hygiene Considerations: Work clothes should be washed separately at the end of each work day. Disposable clothing should be discarded, if contaminated with product.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical State: PowderColor: White to yellowOdor: OdorlesspH: Not availableVapor Pressure: Not applicable.Viscosity: Not applicable.Boiling Point: Not applicable.Freezing/Melting Point: 2876 deg F ( 1,580.00C)Autoignition Temperature: Not applicableFlash Point: Not applicable.Explosion Limits: Lower/ Upper:: Not availableDecomposition Temperature: Not availableSolubility in water: InsolubleSpecific Gravity/Density: 4.4 (Water=1)Molecular Formula: BaSO4Molecular Weight: 233.4ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-200710. STABILITY AND REACTIVITYChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: None anticipated.Incompatibilities with Other Materials: Not available.Hazardous Decomposition Products: Oxides of sulfur, barium fume.Hazardous Polymerization: Will Not OccurSection 11 - Toxicological InformationRoutes of Exposure: Eyes. Dermal (skin) contact. Inhalation.Target Organs/Medical Conditions Aggravated by Overexposure: Eyes. Skin. Respiratory System.Product Toxicological Information:Long term inhalation of particulate can cause irritation, inflammation and/or permanent injury to the lungs. Illnesses such as pneumoconiosis ("baritosis "), pulmonary fibrosis, chronic bronchitis, emphysema and bronchial asthma may develop.Carcinogenicity: No listed as carcinogen by NTP, IARC,OSHA.12. ECOLOGICAL INFORMATIONMobility (Water/Soil/Air) Not determinedPersistence/Degradability Not applicableBio-accumulation Not DeterminedEcotoxicological InformationAcute Fish T oxicity: TLM96: 7500 ppm (Oncorhynchus mykiss)Acute Crustaceans Toxicity: Not determinedAcute Algae Toxicity: Not determinedChemical Fate Information Not determinedOther Information Not applicableSection 13 - Disposal ConsiderationsAppropriate method of disposal of substance or preparation:Bury in a landfill site approved for the disposal of chemical and hazardous wastes. Observe all federal, state, and local environmental regulations.Section 14 - Transport InformationDOTProper Shipping Name: NoneNon-Hazardous for Transport: This substance is considered to be non-hazardous forZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-2007transport.IATANon-Hazardous for Air Transport: Non-hazardous for air transport.Section 15 - Regulatory InformationEU ADDITIONAL CLASSIFICATIONS: 22-24/25Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.US CLASSIFICATION AND LABEL TEXTUS Statements: Caution: Avoid contact and inhalation.UNITED STATES REGULATORY INFORMATIONSARA LISTED: NoNOTES: This product is subject to SARA section 313 reporting requirements. This product is subject to SARA section 313 reporting requirements.TSCA INVENTORY ITEM: YesCANADA REGULATORY INFORMATIONWHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR.DSL: YesNDSL: No16. OTHER INFORMATIONAdditional Information:For additional information on the use of this product, contact us at 0086-759-2254730. Disclaimer Statement: This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.。
ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-20071. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONTrade Name: BariteChemical Family: MineralProduct Use: Barite is used as the chief source of barium and its chemical compounds. Ground barite is used as filler in the manufacture of linoleum, oilcloth, paper and textile manufacturing, rubber, and plastics. Ground barite is used in the oil industry, e.g., as filtering and deodorizing agents in the refining of petroleum and, mixed with other materials, as drilling mud to protect the cutting bit while drilling. White barite is used in making paint as a white pigment.Supplied by:Zhanjiang New Orient Minerals Co., LtdInside of Zhanjiang Seaport District No.4,1# Youyi Road, Xiashan, Zhanjiang,Guangdong, ChinaTel: (86)759-2254830 Fax:(86)759-22535322. COMPOSITION/INFORMATION ON INGREDIENTSSUBSTANCE CAS Number PERCENTACGIHTLV-TWAOSHAPEL-TWABarium sulfate7727-43-792 - 99%10 mg/m315 mg/m33. HAZARDS IDENTIFICATIONPhysical State: Powder. Odor: Odorless Color: White to greyPotential Health Effects:Acute Effects:Eye Contact: May cause mechanical irritationSkin Contact: May cause mechanical irritation.Inhalation: May cause mechanical irritation.Ingestion: May cause gastric distress, nausea and vomiting if ingested. Carcinogenicity & Chronic Effects: See Section 11 - Toxicological Information.4. FIRST AID MEASURESEye Contact: Promptly wash eyes with lots of water while lifting eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.Skin Contact: Wash skin thoroughly with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if any discomfort continues.Inhalation: Move person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-2007Ingestion: Dilute with 2 - 3 glasses of water or milk, if conscious. Never give anything by mouth to an unconscious person. If signs of irritation or toxicity occur seek medical attention. General notes: Persons seeking medical attention should carry a copy of this MSDS with them.5. FIRE FIGHTING MEASURESFlammable PropertiesFlash Point: F (C): NAFlammable Limits in Air - Lower (%): NDFlammable Limits in Air - Upper (%): NDAutoignition Temperature: F (C): NDFlammability Class: NAOther Flammable Properties: NDExtinguishing Media: This material is not combustible. Use extinguishing media appropriate for surrounding fire.Protection Of Fire-Fighters:Special Fire-Fighting Procedures: Do not enter fire area without proper personal protective equipment, including NIOSH/MSHA approved self-contained breathing apparatus. Evacuate area and fight fire from a safe distance. Water spray may be used to keepfire-exposed containers cool. Keep water run off out of sewers and waterways. Hazardous Combustion Products: Not determined.NFPA Ratings: Health 1, Flammability 0, Reactivity 0HMIS Ratings: Flammability 0, Reactivity 0, Health 1*HMIS Key: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Hazard.*Chronic effects - See Section 11. See Section 8 for Personal Protective Equipment recommendations.6. ACCIDENTAL RELEASE MEASURESPersonal Precautions: Use personal protective equipment identified in Section 8.Spill Procedures: Evacuate surrounding area, if necessary. Contain spilled material. Avoid the generation of dust. Sweep, vacuum, or shovel and place into closable container for disposal.Environmental Precautions: Do not allow to enter sewer or surface and subsurface waters. Waste must be disposed of in accordance with federal, state and local laws.7. HANDLING AND STORAGEHandling: Put on appropriate personal protective equipment. Avoid contact with skin and eyes. Avoid generating or breathing dust. Use only in a well ventilated area. Wash thoroughly after handling.ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-2007Storage: Store in dry, well-ventilated area. Keep container closed. Store away from incompatibles. Follow safe warehousing practices regarding palletizing, banding,shrink-wrapping and/or stacking.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering Controls: Use appropriate engineering controls such as, exhaust ventilation and process enclosure, to ensure air contamination and keep workers exposure below the applicable limits.Personal Protection Equipment:All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazards present and the risk of exposure to those hazards. The PPE recommendations below are based on our assessment of the chemical hazards associated with this product. The risk of exposure and need for respiratory protection will vary from workplace to workplace and should be assessed by the user.Eye/Face Protection: Dust resistant safety goggles.Skin Protection: Wear appropriate clothing to prevent repeated or prolonged skin contact. Chemical resistant gloves recommended for prolonged or repeated contact. Use protective gloves made of: Neoprene. Nitrile.Respiratory Protection: Wear a NIOSH certified respirator if dust over TLV.General Hygiene Considerations: Work clothes should be washed separately at the end of each work day. Disposable clothing should be discarded, if contaminated with product.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical State: PowderColor: White to yellowOdor: OdorlesspH: Not availableVapor Pressure: Not applicable.Viscosity: Not applicable.Boiling Point: Not applicable.Freezing/Melting Point: 2876 deg F ( 1,580.00C)Autoignition Temperature: Not applicableFlash Point: Not applicable.Explosion Limits: Lower/ Upper:: Not availableDecomposition Temperature: Not availableSolubility in water: InsolubleSpecific Gravity/Density: 4.4 (Water=1)Molecular Formula: BaSO4Molecular Weight: 233.4ZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-200710. STABILITY AND REACTIVITYChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: None anticipated.Incompatibilities with Other Materials: Not available.Hazardous Decomposition Products: Oxides of sulfur, barium fume.Hazardous Polymerization: Will Not OccurSection 11 - Toxicological InformationRoutes of Exposure: Eyes. Dermal (skin) contact. Inhalation.Target Organs/Medical Conditions Aggravated by Overexposure: Eyes. Skin. Respiratory System.Product Toxicological Information:Long term inhalation of particulate can cause irritation, inflammation and/or permanent injury to the lungs. Illnesses such as pneumoconiosis ("baritosis "), pulmonary fibrosis, chronic bronchitis, emphysema and bronchial asthma may develop.Carcinogenicity: No listed as carcinogen by NTP, IARC,OSHA.12. ECOLOGICAL INFORMATIONMobility (Water/Soil/Air) Not determinedPersistence/Degradability Not applicableBio-accumulation Not DeterminedEcotoxicological InformationAcute Fish Toxicity: TLM96: 7500 ppm (Oncorhynchus mykiss)Acute Crustaceans Toxicity: Not determinedAcute Algae Toxicity: Not determinedChemical Fate Information Not determinedOther Information Not applicableSection 13 - Disposal ConsiderationsAppropriate method of disposal of substance or preparation:Bury in a landfill site approved for the disposal of chemical and hazardous wastes. Observe all federal, state, and local environmental regulations.Section 14 - Transport InformationDOTProper Shipping Name: NoneNon-Hazardous for Transport: This substance is considered to be non-hazardous forZHANJIANG NEW ORIENT MINERALS CO., LTD.MA TERIAL SAFETY DA TA SHEETProduct Name: Barite Revision Date: 14-Nov-2007transport.IATANon-Hazardous for Air Transport: Non-hazardous for air transport.Section 15 - Regulatory InformationEU ADDITIONAL CLASSIFICATIONS: 22-24/25Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.US CLASSIFICATION AND LABEL TEXTUS Statements: Caution: Avoid contact and inhalation.UNITED STATES REGULATORY INFORMATIONSARA LISTED: NoNOTES: This product is subject to SARA section 313 reporting requirements. This product is subject to SARA section 313 reporting requirements.TSCA INVENTORY ITEM: YesCANADA REGULATORY INFORMATIONWHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR.DSL: YesNDSL: No16. OTHER INFORMATIONAdditional Information:For additional information on the use of this product, contact us at 0086-759-2254730. Disclaimer Statement:This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user.。
