(推荐)叔丁胺安全数据表

叔丁胺安全资料表MSDS标识中文名：叔丁胺1,1-二甲基乙胺英文名：t-butyiamine；1,1-dimethylethylamine 分子式：C4H11N分子量：73.14CAS号：75－64－9危规号：32172理化性质性状：无色液体，有氨味。

溶解性：溶于水，溶于无水乙醇、苯、氯仿、乙醚等多数有机溶剂。

熔点（℃）：－72.6沸点（℃）：44.5相对密度（水＝1）：0.69临界温度（℃）：210.8临界压力（MPa）：3.84相对密度（空气＝1）：2.5燃烧热（KJ/mol）：2992.9最小点火能（mJ）：无资料饱和蒸汽压（KPa）：45.32（25℃）燃烧爆炸危险性燃烧性：易燃燃烧分解产物：一氧化碳、二氧化碳、氧化氮。

闪点（℃）：－8.8聚合危害：不聚合爆炸下限（％）：1.7稳定性：稳定爆炸上限（％）：8.9最大爆炸压力（MPa）：无资料引燃温度（℃）：380禁忌物：强氧化剂、强酸、酸类。

危险特性：易燃，其蒸汽与空气可形成爆炸性混合物。

遇明火、高热能引起燃烧爆炸。

与氧化剂能发生强烈反应。

其蒸汽比空气重，能在较低处扩散到相当远的地方，遇明火会引起回燃，具有腐蚀性。

灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。

灭火剂：抗溶性泡沫、干粉、二氧化碳、砂土。

毒性LD5078mg/kg（大鼠经口）LC50对人体危害侵入途径：吸入、食入、经皮肤吸收。

健康危害：吸入、口服或经皮肤吸收可能至死。

对眼睛、皮肤、粘膜和呼吸道有强烈刺激作用。

吸入后可引起喉、支气管的痉挛、水肿，化学性肺炎、肺水肿而至死。

中毒表现有烧灼感、咳嗽、喘息、喉炎、气短、头痛、恶心和呕吐。

急救皮肤接触：立即脱去被污染的衣着，用大量流动清水冲洗，至少15分钟。

就医。

眼睛接触：立即提起眼睑，用大量流动清水或生理盐水冲洗彻底冲洗至少15分钟。

就医。

吸入：迅速脱离现场至空气新鲜处，保持呼吸道通畅。

如呼吸困难，给输氧。

如呼吸停止，立即进行人工呼吸。

第一部分化学品及企业标识化学品中文名：叔丁胺化学品英文名：tert-butylamine；2-amino-2-methylpropane化学品别名：2-氨基-2-甲基丙烷；特丁胺CAS No.：75-64-9EC No.：200-888-1分子式：C4H11N产品推荐及限制用途：主要用作橡胶添加剂、杀虫剂、杀菌剂、染料、医药等的中间体。

第二部分危险性概述紧急情况概述：液体。

高度易燃,其蒸气与空气混合，能形成爆炸性混合物。

吞食后有毒。

有严重损害眼睛的危险。

吸入有毒。

对水生环境可能会引起长期有害作用。

GHS危险性类别：根据GB30000-2013化学品分类和标签规范系列标准（参阅第十六部分），该产品分类如下：易燃液体，类别2；急毒性-口服，类别3；皮肤腐蚀/刺激，类别1；眼损伤/眼刺激，类别1；急毒性-吸入，类别3；危害水生环境-慢性毒性，类别3。

标签要素象形图：警示词：危险危险信息：高度易燃液体和蒸气，吞咽会中毒，造成严重皮肤灼伤和眼损伤，造成严重眼损伤，吸入会中毒，对水生生物有害并具有长期持续影响。

预防措施：远离热源、热表面、火花、明火以及其它点火源。

禁止吸烟。

保持容器密闭。

容器和接收设备接地和等势联接。

使用不产生火花的工具。

采取措施，防止静电放电。

不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。

作业后彻底清洗。

使用本产品时不要进食、饮水或吸烟。

只能在室外或通风良好之处使用。

避免释放到环境中。

戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

事故响应：呼叫中毒急救中心/医生。

漱口。

沾染的衣服清洗后方可重新使用。

如误吞咽：立即呼叫中毒急救中心/医生。

如误吸入：将受人转移到空气新鲜处，保持呼吸舒适的体位。

如误吞咽：漱口。

不要诱导呕吐。

如皮肤（或头发）沾染：立即去除/脱掉所有沾染的衣服。

用水清洗皮肤或淋浴。

如进入眼睛：用水小心冲洗几分钟。

如戴隐形眼镜并可方便地取出，取出隐形眼镜。

继续冲洗。

安全储存：存放处须加锁。

SAFETY DATA SHEETEMERGENCY CALL: 1-800-424-9300 (CHEMTREC)PRODUCT NAME: Hi-Yield® 2,4-D AmineDESCRIPTION: A liquid herbicide.EPA Reg. No.: 81927-38-7401COMPANY IDENTIFICATION:Voluntary Purchasing Groups, Inc.230 FM 87Bonham, TX 75418DANGERCauses serious eye damage Harmful to aquatic lifeHarmful if swallowedHarmful if inhaledCommon Name Chemical Name CAS # Composition 2,4-D Amine Dimethylamine Salt of 2,4-Dichlorophenoxyacetic Acid 2008-39-1 47.2%Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact CHEMTREC at 1-800-424-9300 for emergency medical treatment information.IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Immediately call a doctor or poison control center.IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a doctor or poison control center if you feel unwell.IF SWALLOWED: Immediately call a poison control center or doctor. Rinse mouth out and have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.Flash point (PMA-4): N/AFlammable Limits (LFL-UFL): N/AFire and Explosion Hazards: Not a fire or explosion hazard.Extinguishing Medium: Water spray, foam, dry chemical or carbon dioxide (CO2).Fire Fighting Equipment:Firefighters should be equipped with self-contained positive pressure breathing apparatus and full bunker gear.Fire Fighting Instructions: Evacuate nonessential personnel to prevent exposure to fire, smoke, fumes or products of combustion. Prevent use of contaminated buildings, area and equipment until decontaminated. Dike and collect any runoff to prevent entry to drains or water bodies.Hazardous Combustion Products: Thermal decomposition may produce toxic gasses such as hydrogen chloride and oxides of carbon and nitrogen.NFPA Ratings: Health – 3 / Flammability – 1 / Reactivity - 0Clean up spills immediately observing the precautions in Section 8 of this SDS. Control spill at the source and prevent material from entering soil, sewers, waterways or low areas. If necessary, dike spill using absorbent or impervious materials such as clay or sand. Recover materials for reuse or disposal by pumping any free liquid into appropriate closed containers, do not flush to drain.Large spills to soil may require removal of topsoil with the affected area removed and placed into appropriate containers for disposal. Large spills may be reportable to the National Response Center (800-424-8802) and to state and/or local agencies.Keep out of reach of children. Do not get in eyes or on clothing, avoid contact with skin and avoid inhaling vapor or spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum using tobacco, or using the toilet. Remove and wash contaminated clothing before reuse.Always store pesticides in a secured warehouse or storage building. Store at temperatures above 32°F. Open containers in well-ventilated areas. Keep container tightly sealed when not in use. Do not stack cardboard boxes more than two pallets high. Do not store near open containers of fertilizer, seed or other pesticides.Engineering Controls: Handle only with adequate ventilation. Facilities storing or utilizing this material should be equipped with an eyewash station and a safety shower.Protective Clothing: Wear long sleeved shirt, long pants, shoes, socks, and chemical resistant gloves and a face shield or goggles. When mixing, loading or cleaning up spills or equipment or otherwise exposed to concentrate, wear a chemical-resistant apron.General: Wash clothing and other absorbent materials that have been exposed to this product. Follow the manufacturer’s instructions for cleaning and maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry.Physical State: Clear pale yellow liquidOdor: Phenolic-aminepH: 8.9 – 9.1Density: 9.7 lbs/galSolubility: SolubleCONDITIONS TO AVOID: Excessive heat. Do not store near heat or flame.CHEMICAL STABILITY: Stable under all normal use and storage conditions.HAZARDOUS DECOMPOSITION PRODUCTS: May release toxic gasses when thermally decomposed. INCOMPATIBILITY WITH OTHER MATERIALS: Strong oxidizing agents, bases and acids. POLYMERIZATION: Will not occur.ORAL TOXICITY (rat LD50): 1,161 mg/kgDERMAL TOXICITY (rat LD50): > 5,000 mg/kgINHALATION TOXICITY (rat LC50): > 3.5 mg/L (4-hour)EYE IRRITATION: Rabbit – Severely irritating / corrosiveSKIN IRRITATION: Rabbit – Slightly irritatingSKIN SENSITIZATION: Not sensitizingCARCINOGENICITY:EPA:Not ListedACGIH: Not Listed NTP:Not ListedIARC:Class 2B (chlorophenoxy herbicides) OSHA: Not ListedMUTAGENIC TOXICITY: No evidence of mutagenic effects during in vivo and in vitro assays. REPRODUCTIVE TOXICITY: No evidence in animal studies.This pesticide may be toxic to fish and aquatic invertebrates and may adversely affect non-target plants. This chemical has properties and characteristics associated with chemicals detected in groundwater. The use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in groundwater contamination.The following is for the active ingredient, 2,4-D Amine:AQUATIC TOXICITYBluegill (96-hr LC50): 524 mg/LRainbow Trout (96-hr LC50): 250 mg/LDaphnia (48-hr EC50): 184 mg/LAVIAN TOXICITYBobwhite Quail (Oral LD50): 500 mg/kgMallard Duck (8-day Dietary LC50): > 5,620 ppmPESTICIDE DISPOSAL: Pesticide wastes are toxic. If container is damaged or if pesticide has leaked, contain all spillage. Absorb and clean up all spilled material with granules or sand. Place in a closed, labeled container for proper disposal. Improper disposal of excess pesticide, spray mixtures, or rinsate is a violation of Federal law and may contaminate ground water. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA regional office for guidance.CONTAINER DISPOSAL:Nonrefillable container. Do not reuse or refill this container. Refer to the product label for specific container handling instructions.US DOT:Containers < 21 Gallons:Not regulated by DOT.Containers > 21 Gallons:DOT Shipping Name: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S.(2,4-Dichlorophenoxyacetic Acid), 9, PG IIIReportable Quantity (RQ): 100 lbs. (26.3 gallons of product)DOT Emergency Response Guide: 171Marine Pollutant: YesFIFRA –This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. The following is the hazard information as required on the pesticide label: PRECAUTIONARY STATEMENTSHAZARDS TO HUMANS AND DOMESTIC ANIMALSDANGER: Corrosive. Causes irreversible eye damage. Harmful if swallowed. Harmful ifabsorbed through skin. Do not get in eyes or on clothing. Avoid contact with skin. Wearprotective eyewear (goggles, face shield, safety glasses), long-sleeved shirt and long pants,shoes and socks, chemical resistant gloves (such as those listed in selection A on the EPAchemical-resistance category selection chart).See inside label booklet for additional Precautionary Statements and Directions for Useincluding Storage and Disposal instructions.ENVIRONMENTAL HAZARDSThis pesticide may be toxic to fish and aquatic invertebrates and may adversely affect non-target plants. Do not apply directly to water, or to areas where surface water is present, or tointertidal areas below the mean high water mark except as noted on appropriate labels. Driftand runoff may be hazardous to aquatic organisms in water adjacent to treated areas. Do notcontaminate water when disposing of equipment wash water or rinsate.This chemical has properties and characteristics associated with chemicals detected ingroundwater. The use of this chemical in areas where soils are permeable, particularly wherethe water table is shallow, may result in groundwater contamination. Application around acistern or well may result in contamination of drinking water or groundwater.All pesticides are governed under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA). The regulatory information presented below is pertinent only when this product is handled outside of the normal use and application as a pesticide. This product is excluded from listing requirements under EPA/TSCA.SARA Title III – Section 302 Extremely Hazardous SubstancesNot listedSARA Title III – Section 311/312 Hazard CategoriesImmediate, DelayedSARA Title III – Section 312 Threshold Planning QuantityN/ASARA Title III – Section 313 Reportable Ingredients2,4-Dichlorophenoxyacetic Acetic Acid (CAS No. 94-75-7): 47.2%CERCLA –2,4-Dichlorophenoxyacetic Acetic Acid (CAS No. 94-75-7): 100 lbs. (26.3 gallons of product) CALIFORNIA PROP 65 STATUS –This product does not contain any chemicals known to the state of California to cause cancer or reproductive toxicity.CANADA –This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.This Safety Data Sheet (SDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA APPROVED PRODUCT LABELING (attached to and accompanying the product container). This SDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use, while the labeling provides that information specifically for product use in the ordinary course.Use, storage and disposal of pesticide products are regulated by the EPA under the authority of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) through the product labeling, and all necessary and appropriate precautionary, use, storage, and disposal information is set forth on that labeling. It is a violation of Federal law to use a pesticide product in any manner not prescribed on the EPA-accepted label.Although information and recommendations set forth herein (hereinafter “Information”) are presented in good faith and believed to be correct as of the date hereof, Voluntary Purchasing Groups, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposed prior to use. In no event will Voluntary Purchasing Groups, Inc. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILTY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.Hi-Yield is a registered trademark of Voluntary Purchasing Groups, Inc.SDS Version: 1.0 Effective Date: 01/25/2016。

危险物质安全数据表模板介绍危险物质安全数据表（Safety Data Sheet，SDS）是一份用于提供危险物质信息的文档。

这份文档是安全技术文献的一种形式，也是物资管理和工作场所安全的必需品之一，涉及危险物质详情、危害、安全操作和应急措施等信息。

根据联合国《全球协调制度(GHS)》和欧盟《化学品法规(REACH)》要求，生产和进口危险物质的企业必须根据化学品法规制定SDS，以确保人体健康和环保安全。

SDS模板SDS模板包括以下16个部分：1. 产品和公司标识2. 危险性成分3. 级别标识符号及Signal Words4. 急救措施5. 消防措施6. 意外泄露处置7. 操作处置8. 暴露控制/个人保护9. 物理和化学特性10. 稳定性和反应活性11. 毒理学信息12. 生态学信息13. 处理和储存14. 运输信息15. 法规信息16. 其他信息SDS填写规范为了使用方便，SDS应该尽可能简明扼要，同时全面准确。

以下需要遵循的填写规范：1. 确保产品描述和注意事项一致，包括产品名称、用途、生产厂商、供货商。

2. 列出化学成分、CAS号和含量，进一步标注危险性分类、物质危害、对环境和人体的相关风险等级。

3. 描述紧急情况下的急救措施并提供应急电话。

4. 描述组织和个人安全措施和操作，包括适当的加工、操作和存储条件，以及个人保护装备和管理控制。

5. 描述有关环境方面的信息，包括泄漏处置、防止风险、存储要求和处理。

6. 描述化学性质、物理性质、稳定性和反应特性等危害情况。

7. 描述产品与水、土壤、大气、动植物的相互作用，并评估有关的生态学影响。

8. 描述环境法规和公共安全标准，以及危险物质主管部门的规定。

叔丁胺标准
叔丁胺（又称为N,N-二甲基丙胺或TBA）是一种有机化合物，化学式为 (CH3)3CNH2。

它是一种无色液体，可溶于水和大多数有机溶剂。

叔丁胺的主要用途是作为溶剂、碱催化剂和原料。

它可以用于有机合成反应中的去质子化反应、碱催化的反应和烷基化反应等。

叔丁胺的标准通常包括以下几个方面：
1. 外观和物理性质：叔丁胺应为无色液体，无杂质和悬浮物。

2. 含量测定：可以使用气相色谱（GC）或高效液相色谱（HPLC）等方法来测定叔丁胺的含量。

3. 水含量：水含量是叔丁胺质量的重要指标，通常使用卡尔费伯法（Karl Fischer method）或重量法进行测定。

4. 酸度：酸度指示了叔丁胺的酸碱性质，通常使用酸度滴定法来测定。

5. 不溶性物：叔丁胺在水中的不溶性应低于一定的限度，通常通过过滤或离心过滤等方法进行检验。

6. 其他杂质检验：叔丁胺还应检测其他可能存在的杂质，例如有机溶剂、重金属离子等。

以上是一般情况下叔丁胺的标准要求，具体标准可能会根据产品的用途、厂家要求和相关行业标准有所不同。

在使用叔丁胺时应严格按照产品标准进行操作，并注意相关安全操作规程。

第一部分：化学品名称回目录化学品中文名称：叔丁胺化学品英文名称：tert-butylamine中文名称2：1,1-二甲基乙胺英文名称2：1,1-dimethylethylamine技术说明书编码：353CAS No.：75-64-9分子式：C4H11N分子量：73.14第二部分：成分/组成信息回目录有害物成分含量CAS No.有害物成分含量CAS No. 叔丁胺75-64-9第三部分：危险性概述回目录健康危害：吸入、口服或经皮肤吸收可能致死。

对眼睛、皮肤、粘膜和呼吸道有强烈刺激作用。

吸入后可引起喉、支气管的痉挛、水肿，化学性肺炎、肺水肿而致死。

中毒表现有烧灼感、咳嗽、喘息、喉炎、气短、头痛、恶心和呕吐。

燃爆危险：本品易燃，高毒，具强刺激性。

第四部分：急救措施回目录皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15分钟。

就医。

眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15分钟。

就医。

吸入：迅速脱离现场至空气新鲜处。

保持呼吸道通畅。

如呼吸困难，给输氧。

如呼吸停止，立即进行人工呼吸。

就医。

食入：用水漱口，给饮牛奶或蛋清。

就医。

第五部分：消防措施回目录危险特性：易燃，其蒸气与空气可形成爆炸性混合物，遇明火、高热能引起燃烧爆炸。

与氧化剂能发生强烈反应。

其蒸气比空气重，能在较低处扩散到相当远的地方，遇火源会着火回燃。

具有腐蚀性。

有害燃烧产物：一氧化碳、二氧化碳、氧化氮。

灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。

灭火剂：抗溶性泡沫、二氧化碳、干粉、砂土。

第六部分：泄漏应急处理回目录应急处理：迅速撤离泄漏污染区人员至安全区，并进行隔离，严格限制出入。

切断火源。

建议应急处理人员戴自给正压式呼吸器，穿防毒服。

不要直接接触泄漏物。

尽可能切断泄漏源。

防止流入下水道、排洪沟等限制性空间。

小量泄漏：用砂土、干燥石灰或苏打灰混合。

也可以用大量水冲洗，洗水稀释后放入废水系统。

大量泄漏：构筑围堤或挖坑收容。

危险化学品安全数据表全集文档(可以直接使用，可编辑实用优质文档，欢迎下载）危险化学品安全数据表危险化学品安全数据表危险化学品安全数据表危险化学品安全数据表危险化学品安全数据表危险化学品安全数据表危险化学品安全数据表D2*******危险化学品安全数据表D2*******危险化学品安全数据表D2*******危险化学品安全数据表D2*******危险化学品安全数据表化学危险品清单和安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）注：危害性：（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂化学物质安全数据表（MSDS清单）（1）爆炸性（2）易燃性（3）可燃性（4）自燃性（5）腐蚀刺激性（6）急性毒性（7）特定毒性（8）破坏臭氧层物质（9）氧化性（10）有机氯溶剂危险化学品台账（原料）危险化学品台账（中间体）危险化学品台账（产品）。

USA SAFETY DATA SHEET3000000026741. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct name: CHEMLOK 218 Product Use/Class:AdhesiveLORD Corporation 111 LORD DriveCary, NC 27511-7923 USATelephone: 814 868-3180Non-Transportation Emergency: 814 763-2345 Chemtrec 24 Hr Transportation Emergency No.800 424-9300 (Outside Continental U.S. 703 527-3887)EFFECTIVE DATE: 05/05/20172. HAZARDS IDENTIFICATIONGHS CLASSIFICATION:Flammable liquids Category 2Acute toxicity Inhalation - Dust and Mist Category 4 - 21.1% of the mixture consists of ingredient(s) of unknown toxicity.Skin corrosion/irritation Category 2Serious eye damage/eye irritation Category 2A Skin sensitization Category 1Germ cell mutagenicity Category 2 Carcinogenicity Category 1AReproductive toxicity Category 1ASpecific target organ systemic toxicity (single exposure) Category 3Specific target organ systemic toxicity (single exposure) Category 1 Central nervous system, Cardio-vascular system, Respiratory system, Kidney, Nervous system, Body, Systemic toxicitySpecific target organ systemic toxicity (repeated exposure) Category 1 Central nervous system, Kidney,Hematopoietic System, Cardio-vascular system, intestinal tract, Stomach, Digestive organs, Liver, spleen, thymus Specific target organ systemic toxicity (repeated exposure) Category 2 Nervous system, Respiratory system Hazardous to the aquatic environment - acute hazardCategory 2 Hazardous to the aquatic environment - chronic hazardCategory 2GHS LABEL ELEMENTS:Symbol(s)Signal WordD ANGERHazard StatementsHighly flammable liquid and vapor. Harmful if inhaled. Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction. Suspected of causing genetic defects. May cause cancer.May damage fertility or the unborn child. May cause harm to breast-fed children. May cause drowsiness or dizziness.May cause respiratory irritation.Causes damage to organs.(Central nervous system, Cardio-vascular system, Respiratory system, Kidney, Nervous system, Body, Systemic toxicity)Causes damage to organs through prolonged or repeated exposure.(Central nervous system, Kidney, Hematopoietic System, Cardio-vascular system, intestinal tract, Stomach, Digestive organs, Liver, spleen, thymus)May cause damage to organs through prolonged or repeated exposure.(Nervous system, Respiratory system)Toxic to aquatic life.Toxic to aquatic life with long lasting effects.Precautionary StatementsPreventionKeep away from heat/sparks/open flames/hot surfaces. - No smoking.Ground/Bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting equipment.Use only non-sparking tools.Take precautionary measures against static discharge.Obtain special instructions before use.Do not handle until all safety precautions have been read and understood.Wear protective gloves/protective clothing/eye protection/face protection.Use personal protective equipment as required.Do not breathe dust/fume/gas/mist/vapors/spray.Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Use only outdoors or in a well-ventilated area.Contaminated work clothing should not be allowed out of the workplace.Avoid release to the environment.ResponseIn case of fire: refer to section 5 of SDS for extinguishing media.Call a POISON CENTER or doctor/physician if you feel unwell.IF exposed: Call a POISON CENTER or doctor/physician.Specific treatment (see supplemental first aid instructions on this label).IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.If skin irritation or rash occurs: Get medical advice/attention.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Collect spillage.StorageStore in a well-ventilated place. Keep cool.Store in a well-ventilated place. Keep container tightly closed.Store locked up.Disposal:Dispose of contents/container in accordance with waste/disposal laws and regulations of your country or particular locality.Other Hazards:This product contains component(s) which have the following warnings; however based on the GHS classification criteria of your country or locale, the product mixture may be outside the respective category(s).Acute: Vapor harmful; may affect the brain or nervous system causing dizziness, headache or nausea. Possibleirritation of the respiratory system can occur causing a variety of symptoms such as dryness of the throat, tightness of the chest, and shortness of breath. May cause central nervous system depression characterized by the followingprogressive steps: headache, dizziness, staggering gait, confusion, unconsciousness or coma. Harmful if absorbed through skin.May be harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses.Chronic: May cause long-term lung damage. Trichloroethylene has been classified by IARC as a human carcinogen (Group 1) and by NTP as a reasonably anticipated human carcinogen. 1,2 butylene oxide has been classified by IARC as a possible human carcinogen (Group 2B) and reported by NTP to show clear evidence for carcinogenicity inanimals. ACGIH considers Ethyl alcohol to be an A3 carcinogen (confirmed animal carcinogen with unknownrelevance in humans).3. COMPOSITION/INFORMATION ON INGREDIENTSChemical Name CAS Number RangeToluene108-88-325 - 30%Isopropanol67-63-025 - 30%Trichloroethylene79-01-620 - 25%Phenolic resin9003-35-4 5 - 10%Ethyl alcohol64-17-5 5 - 10%Phenol108-95-2 1 - 5%1,2-Butylene oxide106-88-70.1 - 0.9%Any "PROPRIETARY" component(s) in the above table is considered trade secret, thus the specific chemical and its exact concentration is being withheld.4. FIRST AID MEASURESFIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention.FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur.FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult, give oxygen. Get immediate medical attention.FIRST AID - INGESTION: If swallowed, do not induce vomiting. Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing.5. FIRE-FIGHTING MEASURESSUITABLE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water FogUNSUITABLE EXTINGUISHING MEDIA: Not determined for this product.SPECIFIC HAZARDS POSSIBLY ARISING FROM THE CHEMICAL: Flammable liquid and vapor. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion.SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). Water spray may be ineffective. If water is used, fog nozzles are preferable.6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Remove all sources of ignition (flame, hot surfaces, and electrical, static or frictional sparks). Avoid breathing vapors. Avoid contact. Use self-contained breathing equipment.ENVIRONMENTAL PRECAUTIONS: Do not contaminate bodies of water, waterways, or ditches, with chemical or used container.METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP: Keep non-essential personnel a safe distance away from the spill area. Notify appropriate authorities if necessary. Avoid contact. Before attempting cleanup, refer to hazard caution information in other sections of the SDS form. Contain and remove with inert absorbent material and non-sparking tools.7. HANDLING AND STORAGEHANDLING: Keep closure tight and container upright to prevent leakage. Ground and bond containers when transferring material. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not handle until all safety precautions have been read and understood. Empty containers should not be re-used. Avoid using pressurizable equipment which has aluminum or zinc parts; this product contains chlorinated solvents. Use with adequate ventilation. Because empty containers may retain product residue and flammable vapors, keep away from heat, sparks and flame; do not cut, puncture or weld on or near the empty container. Do not smoke where this product is used or stored. STORAGE: Do not store or use near heat, sparks, or open flame. Store only in well-ventilated areas. Do not puncture, drag, or slide container. Keep container closed when not in use. Refer to OSHA 29CFR Part 1910.106 "Flammable and Combustible Liquids" for specific storage requirements.INCOMPATIBILITY: Strong acids, bases, and strong oxidizers.; Aluminum, zinc, caustics, halogens.; Alkalis.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONCOMPONENT EXPOSURE LIMITChemical Name ACGIH TLV-TWA ACGIH TLV-STELOSHA PEL-TWAOSHA PEL-CEILINGSkinToluene20 ppm N.E.200 ppm 300 ppmN.A.Isopropanol200 ppm400 ppm980 mg/m3400 ppmN.E.N.A.Trichloroethylene10 ppm25 ppm100 ppm 200 ppmN.A.Phenolic resin N.E.N.E.N.E. N.E.N.A.Ethyl alcohol N.E.1,000 ppm1,900 mg/m31,000 ppmN.E.N.A.Phenol 5 ppm N.E.19 mg/m35 ppmN.E.S1,2-Butylene oxide N.E.N.E.N.E. N.E.N.A.N.A. - Not Applicable, N.E. - Not Established, S - Skin DesignationEngineering controls: Sufficient ventilation in pattern and volume should be provided in order to maintain air contaminant levels below recommended exposure limits. Caution: Solvent vapors are heavier than air and collect in lower levels of the work area. Sufficient ventilation (using explosion-proof equipment) should be provided to prevent flammable vapor/air mixtures from accumulating.PERSONAL PROTECTION MEASURES/EQUIPMENT:RESPIRATORY PROTECTION: Use a NIOSH approved chemical/mechanical filter respirator designed toremove a combination of particulates and organic vapor if occupational limits are exceeded. For emergencysituations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved air-supplied respirator. For respirator use observe OSHA regulations (29CFR 1910.134) or use in accordance with applicable laws and regulations of your country or particular locality.SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact.EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur.OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse.HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in anychemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling.9. PHYSICAL AND CHEMICAL PROPERTIESTypical values, not to be used for specification purposes.ODOR: Solvent VAPOR PRESSURE: N.D.APPEARANCE: Amber VAPOR DENSITY: Heavier than Air PHYSICAL STATE: Liquid LOWER EXPLOSIVE LIMIT: 1.2 %(V)UPPER EXPLOSIVE LIMIT: 44.8 %(V)FLASH POINT: 36 °F, 2 °C SetaflashClosed CupBOILING RANGE: 78 - 111 °C EVAPORATION RATE: Slower than n-butyl-acetate AUTOIGNITION TEMPERATURE:N.D.DENSITY: 0.98 g/cm3 - 8.13 lb/gal DECOMPOSITION TEMPERATURE:N.D. VISCOSITY, DYNAMIC: ≥750 mPa.s @ 25 °C ODOR THRESHOLD: N.D.VISCOSITY, KINEMATIC: ≥765 mm2/s @ 25 °CSOLUBILITY IN H2O: Insoluble VOLATILE BY WEIGHT: 78.44 %pH: N.A.VOLATILE BY VOLUME: 82.57 %FREEZE POINT: N.D. VOC CALCULATED: 6.37 lb/gal, 764 g/lN.D.COEFFICIENT OF WATER/OILDISTRIBUTION:LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined10. STABILITY AND REACTIVITYHAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. STABILITY: Product is stable under normal storage conditions.CONDITIONS TO AVOID: High temperatures. Sources of ignition.; High humidity.; Aluminum or galvanized parts in a closed system.INCOMPATIBILITY: Strong acids, bases, and strong oxidizers.; Aluminum, zinc, caustics, halogens.; Alkalis.HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, Butyraldehyde, butyric acid, acrolein, crotonaldehyde., Phosgene11. TOXICOLOGICAL INFORMATIONEXPOSURE PATH: Refer to section 2 of this SDS.SYMPTOMS:Refer to section 2 of this SDS.TOXICITY MEASURES:Chemical Name LD50/LC50Toluene Oral LD50: Rat2,600 mg/kgDermal LD50: Rabbit12,000 mg/kgInhalation LC50: Rat12.5 mg/l/4 hIsopropanol Oral LD50: Rat1,870 mg/kgDermal LD50: Rabbit4,059 mg/kgInhalation LC50: Rat72,600 mg/m3/4 hTrichloroethylene Oral LD50: Rat4,920 mg/kgDermal LD50: Rabbit29,000 mg/kgInhalation LC50: Rat26 mg/l/4 hPhenolic resin Oral LD50: Rat> 5 g/kgDermal LD50: Rat> 2 g/kgEthyl alcohol Oral LD50: Rat7,060 mg/kgInhalation LC50: Rat124.7 mg/l/4 hPhenol Oral LD50: Rat340 mg/kgDermal LD50: Rabbit630 mg/kgGHS LC50 (dust and mist): Acute toxicity point estimate0.55 mg/l 1,2-Butylene oxide Oral LD50: Rat900 mg/kgDermal LD50: Rabbit1,255 - 2,546 mg/kgInhalation LC50: Rat> 6,300 mg/m3/4 hGerm cell mutagenicity: Category 2 - Suspected of causing genetic defects.Components contributing to classification: Trichloroethylene. Phenol.Carcinogenicity: Category 1A - May cause cancer.Components contributing to classification: Trichloroethylene. 1,2-Butylene oxide.Reproductive toxicity: Category 1A - May damage fertility or the unborn child. May cause harm to breast-fed children.Components contributing to classification: Toluene. Isopropanol. Trichloroethylene. Phenol. Methanol. 1,2-Butylene oxide.12. ECOLOGICAL INFORMATIONECOTOXICITY:Chemical Name EcotoxicityToluene Fish: Pimephales promelas15.22 - 19.05 mg/l96 h flow-throughPimephales promelas12.6 mg/l96 h StaticOncorhynchus mykiss5.89 - 7.81 mg/l96 h flow-throughOncorhynchus mykiss14.1 - 17.16 mg/l96 h StaticOncorhynchus mykiss5.8 mg/l96 h semi-staticLepomis macrochirus11.0 - 15.0 mg/l96 h StaticOryzias latipes54 mg/l96 h StaticPoecilia reticulata28.2 mg/l96 h semi-staticPoecilia reticulata50.87 - 70.34 mg/l96 h StaticInvertebrates: Daphnia magna5.46 - 9.83 mg/l48 h StaticDaphnia magna11.5 mg/l48 hPlants: Pseudokirchneriella subcapitata> 433 mg/l96 hPseudokirchneriella subcapitata12.5 mg/l72 h StaticIsopropanol Fish: Pimephales promelas9,640 mg/l96 h flow-throughPimephales promelas11,130 mg/l96 h StaticLepomis macrochirus> 1,400,000 µg/l96 hInvertebrates: Daphnia magna13,299 mg/l48 hPlants: Desmodesmus subspicatus> 1,000 mg/l96 hDesmodesmus subspicatus> 1,000 mg/l72 hTrichloroethylene Fish: Pimephales promelas31.4 - 71.8 mg/l96 h flow-throughLepomis macrochirus39 - 54 mg/l96 h StaticInvertebrates: Daphnia magna2.2 mg/l48 hPlants: Desmodesmus subspicatus450 mg/l96 hPseudokirchneriella subcapitata175 mg/l96 hPhenolic resin N.D.Ethyl alcohol Fish: Pimephales promelas> 100 mg/l96 h StaticPimephales promelas13,400 - 15,100 mg/l96 h flow-throughInvertebrates: Daphnia magna9,268 - 14,221 mg/l48 hDaphnia magna2 mg/l48 h StaticPhenol Fish: Pimephales promelas20.5 - 25.6 mg/l96 h StaticPimephales promelas32 mg/l96 hOncorhynchus mykiss5.449 - 6.789 mg/l96 h flow-throughOncorhynchus mykiss7.5 - 14 mg/l96 h StaticOncorhynchus mykiss4.23 - 7.49 mg/l96 h semi-staticOncorhynchus mykiss5.0 - 12.0 mg/l96 hLepomis macrochirus13.5 mg/l96 h StaticLepomis macrochirus11.9 - 25.3 mg/l96 h flow-throughLepomis macrochirus11.5 mg/l96 h semi-staticPoecilia reticulata34.09 - 47.64 mg/l96 h StaticPoecilia reticulata31 mg/l96 h semi-staticBrachydanio rerio27.8 mg/l96 hOryzias latipes33.9 - 43.3 mg/l96 h flow-throughOryzias latipes23.4 - 36.6 mg/l96 h StaticPimephales promelas11.9 - 50.5 mg/l96 h flow-throughInvertebrates: Daphnia magna4.24 - 10.7 mg/l48 h StaticDaphnia magna10.2 - 15.5 mg/l48 hPlants: Pseudokirchneriella subcapitata46.42 mg/l96 hDesmodesmus subspicatus187 - 279 mg/l72 h Static1,2-Butylene oxide Invertebrates: Daphnia magna69.8 mg/l48 hPlants: Desmodesmus subspicatus> 500 mg/l72 hPERSISTENCE AND DEGRADABILITY:Not determined for this product.BIOACCUMULATIVE: Not determined for this product.MOBILITY IN SOIL: Not determined for this product.OTHER ADVERSE EFFECTS: Not determined for this product.13. DISPOSAL CONSIDERATIONSDISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility.14. TRANSPORT INFORMATIONUS DOT RoadDOT Proper Shipping Name: AdhesivesDOT Hazard Class: 3SECONDARY HAZARD: NoneDOT UN/NA Number: 1133Packing Group: IIEmergency Response Guide Number: 128IATA CargoPROPER SHIPPING NAME: AdhesivesDOT Hazard Class: 3HAZARD CLASS: NoneUN-NUMBER: 1133PACKING GROUP: IIEMS: 3LIMDGPROPER SHIPPING NAME: AdhesivesDOT Hazard Class: 3HAZARD CLASS: NoneUN-NUMBER: 1133PACKING GROUP: IIEMS: F-EThe listed transportation classification applies to non-bulk shipments. It does not address regulatory variations due to changes in package size, mode of shipment or other regulatory descriptors. For the most accurate shipping information, refer to your transportation/compliance department.15. REGULATORY INFORMATIONU.S. FEDERAL REGULATIONS: AS FOLLOWS:SARA SECTION 313This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372.:Chemical Name CAS Number Weight % Less ThanToluene108-88-330.0%Isopropanol67-63-030.0%Trichloroethylene79-01-625.0%Phenol108-95-2 5.0%1,2-Butylene oxide106-88-70.9%TOXIC SUBSTANCES CONTROL ACT:INVENTORY STATUSThe chemical substances in this product are on the TSCA Section 8 Inventory.EXPORT NOTIFICATIONThis product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:Chemical Name CAS NumberTrichloroethylene79-01-616. OTHER INFORMATIONUnder HazCom 2012 it is optional to continue using the HMIS rating system. It is important to ensure employees have been trained to recognize the different numeric ratings associated with the HazCom 2012 and HMIS schemes.HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 3 PHYSICAL HAZARD: 0* - Indicates a chronic hazard; see Section 2Revision: Section 3Effective Date: 05/05/2017DISCLAIMERThe information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.。

PHYTON CORPORATIONSAFETY DATA SHEETProduct Identity: Phyton 35Recommended use: Restrictions on Use: Bactericide and FungicideUse only as directed on the product label.Supplier: Phyton CorporationP.O. Box 385370Minneapolis, MN 55438Telephone: +1 (952) 378-1157, 800-356-8733Emergency Phone:For Chemical EmergencySpill, Leak, Fire, or AccidentCall CHEMTREC Day or NightWithin USA and Canada: 1-800-424-9300Outside USA and Canada: +1 703-527-3887 (collect calls accepted)GHS Classification:GHS Label Elements:DANGER!Statements of Hazard ResponseCauses serious eye irritation. Very toxic to aquatic life with long lasting effects.PreventionWash hands thoroughly after handling.Avoid release to the environment.Wear eye protection.DisposalDispose of contents and container in accordance withlocal, regional, and national regulations.IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Collect spillage.Eye: First check victim for contact lenses and remove if present. Flush victim's eyes with large quantities of water for at least 15 minutes, holding the eyelids apart. Get medical attention if irritation persists.Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. If irritation or symptoms develop, get medical attention. Launder clothing before re-use. (Discard contaminated shoes)Ingestion: Do not induce vomiting unless directed by a medical professional. If conscious, rinse mouth with water. Never give anything by mouth to an unconscious or convulsing person. Get medical attention if symptoms occur or if the victim feels unwell.Inhalation: Immediately remove victim to fresh air. Get medical attention if symptoms occur and persist.Most important Symptoms: Causes eye irritation. May Cause skin irritation. Ingestion may cause headache, dizziness, nausea, vomiting, irregular heartbeat, respiratory difficulty, metallic taste, gastrointestinal bleeding, liver and kidney failure.Indication of immediate medical attention/special treatment: Immediate medical attention is not generally required.Suitable (and Unsuitable) Extinguishing Media: Use water spray, carbon dioxide, foam or dry chemical. Specific hazards arising from the chemical: This product is not classified as flammable but may burn under fire conditions. Combustion may produce ammonia, copper fumes and oxides of carbon, sulfur and nitrogen. Special Protective Equipment and Precautions for Fire-Fighters: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire exposed containers with water spray. Do not allow run-off from fire fighting to enter drains or water courses.Personal Precautions, Protective Equipment, and Emergency Procedures: Evacuate spill area and keep unprotected personnel away. Do not breathe vapors or mists.Avoid contact with the eyes, skin and clothing. Wear appropriate protective clothing.Methods and Materials for Containment and Cleaning Up: Contain and collect using inert absorbent materials and place in appropriate containers for disposal. Do not flush to sewer! Report releases as required by local, state and federal authorities. Contact your local pesticide, environmental control agency, or hazardous waste representative for advice.Precautions for Safe Handling: Avoid contact with the eyes, skin and clothing. Avoid breathing vapors or mists. Wear appropriate protective clothing and equipment. Use only with adequate ventilation. Wash thoroughly with soap and water after handling. Keep containers closed when not in use.Do not cut, drill, grind or weld on or near containers, even empty containers. Do not reuse containers. Empty containers retain product residues which can be hazardous. Follow all SDS precautions when handling empty containers.Conditions for Safe Storage, Including Any Incompatibilities: Do not contaminate water, food or feed by storage or disposal. Do not freeze or store below 45°F. Store in original container. Store away from oxidizers and other incompatible materials.Engineering Controls: Use with adequate ventilation to maintain exposures below the occupational exposure limits.Personal Protective Equipment: Refer to the product label for additional requirements for pesticide use. Respiratory Protection: In operations where exposure levels are excessive, an approved respirator withdust/mist cartridges or supplied air respirator should be used. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice. Skin Protection: Wear impervious gloves.Eye Protection: Chemical safety goggles should be worn.Other: Impervious coveralls, apron and boots is recommended to prevent skin contact and contamination of personal clothing. An eye wash should be available in the immediate work area.Appearance and Odor: Opaque brown-green liquid.Reactivity: Not normally reactiveChemical Stability: Stable under normal storage and handling conditions.Possibility of Hazardous Reactions: Reaction with oxidizers may generate heat.Conditions to Avoid: Avoid heat, flames and sources of ignition.Incompatible Materials: Avoid oxidizing agents.Hazardous Decomposition Products: Thermal decomposition yields ammonia and oxides of nitrogen, carbon, copper and sulfur.HEALTH HAZARDS:Eye: Contact may cause irritation with redness, tearing and stinging Moderate irritant in rabbit study.Skin: May causes mild skin irritation. Repeated or prolonged contact may cause defatting of the skin and dermatitis. Slight irritant in rabbits. Low toxicity in rabbits.Ingestion: Ingestion may cause headache, dizziness, nausea, vomiting, diarrhea, irregular heartbeat, respiratory difficulty, metallic taste, gastrointestinal bleeding, liver and kidney failure.Inhalation: Inhalation of vapors or mists may cause mucous membrane and respiratory irritation and effects similar to ingestion.Chronic: None known.Sensitization: Negative in the guinea pig Buehler test.Carcinogenicity: None of the components are listed as a carcinogen or suspected carcinogen by IARC, NTP, ACGIH, OSHA or the EU Substance Directive.Germ Cell Mutagenicity: Components are not germ cell mutagens.Reproductive Toxicity: Components are not reproductive toxins.Numerical Measures of Toxicity:Copper (II) Sulfate: Oral rat LD50 481 mg/kgProduct Test Data: Oral rat LD50 >5000 mg/kg; Dermal rabbit LD50 >5000 mg/kg; Inhalation rat LD50 >2.06 mg/L (no mortalities at highest attainable dose)Ecotoxicity:Copper (II) Sulfate – LC50 Cyprinus carpio – 810 ug/L/96 hr; LC50 freshwater trout – 190-210 ug/L/96 hr; This product is classified as highly toxic to the aquatic environment with long-term effects. Releases to the environment should be avoided.Persistence and Degradability: Not expected to be readily biodegradable.Bioaccumulative Potential: No data available.Mobility in Soil: No data available.Other Adverse Effects: No data availablePesticide wastes are acutely toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Open dumping is prohibited.CONTAINER DISPOSAL: Nonrefillable container. Do not reuse or refill this container. Triple rinse container (orequivalent) promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or, if allowed by State and local authorities, by burning. If burned, stay out of smoke.DOT Hazardous Materials Description: This product is not regulated for transport in containers less than 46 lbs. For containers with more than 46 lbs, the following shipping information applies:Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Copper (II) Sulfate), RQUN Number: UN3082Hazard Class/Packing Group: 9, IIILabels Required: Class 9, Marine PollutantIMDG Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Copper (II) Sulfate)IMDG Hazard Class: 9, IIIUN Number: UN3082IMDG Hazard Labels Required: Class 9, Marine PollutantIATA Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Copper (II) Sulfate)IATA Hazard Class: 9, PG IIIUN Number: UN3082IATA Hazard Labels Required: Class 9, EHS MarkEPA FIFRA INFORMATIONThis chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.WARNING: Causes substantial but temporary eye injury. Harmful if swallowed or absorbed through the skin. Do not get into eyes or on clothing. Avoid contact with skin.CERCLA 103 Reportable Quantity: This product has a Reportable Quantity (RQ) of 46 lbs. (based on the RQ for Copper (II) Sulfate of 10 lbs present at 21.27%). Releases above the RQ must be reported to the National Response Center. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations.Hazard Category for Section311/312: Acute HealthSection313Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements:Copper (II) Sulfate 7758-98-7 21.27%Section302 Extremely Hazardous Substances (TPQ): NoneSDS Date of Preparation: June 1, 2015NOTICEThis above information is believed to be correct but does not propose to be all inclusive and shall be used only as a guide. Phyton Corporation shall not be held liable for any damage resulting from handling or from contact with the above product. This information relates only to the product designated herein and does not relate to its use in combination with any other material or process.。