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高分子材料工程专业英语课文翻译Polymer Science and Polymer Engineering are closely related andoften used interchangeably. Polymer Science is concerned with the chemistry and physics of polymers, while Polymer Engineering teaches students how to design and manufacture polymer products. No matter which field you choose, there is constant innovation and new developments in the field of Polymer Science and Engineering.高分子科学和高分子工程密切相关，常常互换使用。
高分子科学研究聚合物的化学和物理学，而高分子工程则教授学生如何设计和制造聚合物产品。
无论您选择哪个领域，高分子科学和工程的领域中都不断有创新和新发展。
Polymers are large molecules that are made up of repeating units called monomers. These molecules are characterized by their high molecular weight, which gives them unique properties such as strength, elasticity, and durability. There are many types of polymers, including plastics, rubbers, and fibers.聚合物是由称为单体的重复单位组成的大分子。
Polymer Materials Engineering Professional EnglishText TranslationIntroductionAs an interdisciplinary field incorporating elements of both chemistry and engineering, Polymer Materials Engineering seeks to synthesize, process, and analyze polymers and polymer-based materialsfor a variety of industrial applications. Materials in this field can range from thermoplastics to thermosets, from elastomers to composites, and from gels to liquid crystals. The study of Polymer Materials Engineering is crucial for industries such as manufacturing, automotive, aerospace, healthcare, and electronics.To master Polymer Materials Engineering, one must not only have a solid foundation in engineering, chemistry, and physics, but also be proficient in technical English. Therefore, reading and translating English texts related to Polymer Materials Engineering is a vital skill for students and professionals in this field.In this article, we will provide a translation of an English text related to Polymer Materials Engineering, with the m of improving readers’ understanding and usage of specialized vocabulary in this field.Text TranslationOriginal English text:Rightly or wrongly, a connection often is made between themechanical performance of a polymeric material and its degree of crystallinity. The inference, however, can be incorrect as many other factors affect the mechanical response of polymer materials. Simply stated, crystalline regions are usually stronger and stiffer than amorphous regions. Generally, the degree of crystallinity that yields optimum properties depends on the polymer type and on the application.Translated text:通常我们会认为高分子材料的力学性能与其结晶度相关联，这种推论并不总是正确的。
生产实习（Advanced Practicum）本课程是材料科学与工程本科专业的必修课。
课程内容包括带生到工厂和科研院所了解和实践专业知识在实际生产中的应用。
同时配合仿真实习软件掌握化工生产工艺的操作，为学生进社会工作打好基础。
材料学院开课；预修：PSE3840T，PSE3620T。
橡胶工程高等实验（Rubber Engineering Advanced Experiment）本课程开设研制弹性体高分子材料的综合实验，以完成小型科题的训练为教学目标，培养学生的基本科研素质和创新能力。
教师给出科研课题，学生自行设计方案，完成材料选用、配合点、测试表征方案、结果与讨论等步骤。
最后撰写实验和研究报告。
材料学院开课；预修：PSE3620T，PSE3840PSE3421T。
文献查阅（Literature Searching）本课程的特点：是一门实践课；掌握文献检索的基本知识；工具书的使用方法；熟悉图书馆的检索方法；记住必要的专业术语；掌握相关检索工具的网络检索方法。
材料学院秋季开课预修：MSE2022T，MSE2140T，MSE3440T。
聚合物表征（Techniques for Characterization of Polymers）本课程是材料学专业的核心基础课程系统讲授聚合物结构与性能表征的分析方法，主要内容包括：波谱分析，聚合物分子质量及分子质量分布表征，聚合物微结构分析，聚合物热分析，聚合物流变性能分析，聚合物动态力学分析。
材料学院秋季开课；预修：PSE2150PSE2250T，PSE3620T。
橡胶制品及模具设计（Rubber Products and Mold Design）介绍国内外橡胶工业制品种类及生产，讲述橡胶模压制品设计一般要求和规律，讲述橡胶压模类型对制品的影响、结构设计、模具导向与定位、模具的尺寸与强关系、模具材料、热处理及表面处理的要求及模具的尺寸公差与配合、整体设计。
材料学院秋季开课；预修：M1120T，MEE2250T，MEE1640T。
高分子材料与工程专业词汇大全（包含：一高分子化学二高分子反应三高分子物理四高分子加工技术和应用四大部分的全部词汇~~）一高分子化学新序码汉文名英文名注释1高分子macromolecule, polymer又称“大分子”。
2超高分子supra polymer3天然高分子natural polymer4无机高分子inorganic polymer5有机高分子organic polymer6无机-有机高分子inorganic organic polymer7金属有机聚合物organometallic polymer8元素高分子element polymer9高聚物high polymer10聚合物Polymer11低聚物Oligomer曾用名“齐聚物”。
12二聚体Dimer13三聚体Trimer14调聚物telomer15预聚物prepolymer16均聚物homopolymer17无规聚合物random polymer18无规卷曲聚合物random coiling polymer19头-头聚合物head-to-head polymer20头-尾聚合物head-to-tail polymer21尾-尾聚合物tail-to-tail polymer22反式有规聚合物transtactic polymer23顺式有规聚合物cistactic polymer24规整聚合物regular polymer25非规整聚合物irregular polymer26无规立构聚合物atactic polymer27全同立构聚合物isotactic polymer又称“等规聚合物”。
28间同立构聚合物syndiotactic polymer又称“间规聚合物”。
29杂同立构聚合物heterotactic polymer又称“异规聚合物”。
30有规立构聚合物stereoregular polymer, tactic polymer 又称“有规聚合物”。
高分子材料专业英语翻译Polymer materials, also known as macromolecular materials, are a kind of material with high molecular weight composed of repeating structural units. They are widely used in various fields due to their excellent properties such as light weight, high strength, and good corrosion resistance. In recent years, the demand for polymer materials has been increasing, and the study of polymer materials has become a hot topic in the field of materials science. Therefore, it is necessary to have a good understanding of the professional English translation of polymer materials in order to better communicate and exchange ideas with international counterparts.Firstly, let's start with the translation of some basic concepts related to polymer materials. "Polymer" can be translated into "高分子" in Chinese, which refers to the macromolecular compounds formed by the polymerization of monomers. "Polymerization" can be translated as "聚合" or "聚合反应", which specifically refers to the chemical reaction process of monomers forming polymers. "Macromolecule" can be translated as "大分子", which refers to a molecule with a large molecular weight formed by the combination of a large number of atoms. "Monomer" can be translated as "单体", which refers to the small molecules that can polymerize into polymers. "Polymerization degree" can be translated as "聚合度", which refers to the number of monomer units in a polymer molecule.Secondly, it is important to understand the translation of the properties of polymer materials. "Light weight" can be translated as "轻质", which refers to the low density of polymer materials. "High strength" can be translated as "高强度", which refers to the ability of polymer materials to withstand external forces without deformation or fracture. "Corrosion resistance" can be translated as "耐腐蚀性", which refers to the ability of polymer materials to resist chemical or electrochemical corrosion. "Flexibility" can be translated as "柔韧性", which refers to the ability of polymer materials to bend or stretchwithout breaking. "Thermal stability" can be translated as "热稳定性", which refers to the ability of polymer materials to maintain their properties at high temperatures.Furthermore, it is necessary to understand the translation of the processing methods of polymer materials. "Extrusion" can be translated as "挤出", which refers to the process of forcing polymer materials through a die to form continuous shapes. "Injection molding" can be translated as "注塑", which refers to the process of injecting molten polymer materials into a mold to form a desired shape. "Blow molding" can be translated as "吹塑", which refers to the process of inflating molten polymer materials into a mold to form hollow shapes. "Compression molding" can be translated as "压缩成型", which refers to the process of placing polymer materials in a mold and applying pressure and heat to form a desired shape.In conclusion, the professional English translation of polymer materials is essential for researchers, engineers, and professionals in the field of materials science. By mastering the accurate translation of key concepts, properties, and processing methods of polymer materials, we can better communicate and collaborate with international counterparts, promote the exchange of knowledge and technology, and contribute to the development and application of polymer materials on a global scale.。
A 高分子化学和高分子物理UNIT 1 What are Polymer?第一单元什么是高聚物？What are polymers? For one thing, they are complex and giant molecules and are different from low molecular weight compounds like, say, common salt. To contrast the difference, the molecular weight of common salt is only 58.5, while that of a polymer can be as high as several hundred thousand, even more than thousand thousands. These big molecules or ‘macro-molecules’are made up of much smaller molecules, can be of one or more chemical compounds. To illustrate, imagine that a set of rings has the same size and is made of the same material. When these things are interlinked, the chain formed can be considered as representing a polymer from molecules of the same compound. Alternatively, individual rings could be of different sizes and materials, and interlinked to represent a polymer from molecules of different compounds.什么是高聚物？首先，他们是合成物和大分子，而且不同于低分子化合物，譬如说普通的盐。
A 高分子化学和高分子物理UNIT 1 What are Polymer?第一单元什么是高聚物？What are polymers? For one thing, they are complex and giant molecules and are different from low molecular weight compounds like, say, common salt. To contrast the difference, the molecular weight of common salt is only 58.5, while that of a polymer can be as high as several hundred thousand, even more than thousand thousands. These big molecules or ‘macro-molecules’are made up of much smaller molecules, can be of one or more chemical compounds. To illustrate, imagine that a set of rings has the same size and is made of the same material. When these things are interlinked, the chain formed can be considered as representing a polymer from molecules of the same compound. Alternatively, individual rings could be of different sizes and materials, and interlinked to represent a polymer from molecules of different compounds.什么是高聚物？首先，他们是合成物和大分子，而且不同于低分子化合物，譬如说普通的盐。
第一单元什么是高聚物？什么是高聚物？首先，他们是合成物和大分子，而且不同于低分子化合物，譬如说普通的盐。
与低分子化合物不同的是，普通盐的分子量仅仅是58.5，而高聚物的分子量高于105，甚至大于106。
这些大分子或“高分子〞由许多小分子组成。
小分子互相结合形成大分子，大分子可以是一种或多种化合物。
举例说明，想象一组大小一样并由一样的材料制成的环。
当这些环互相连接起来，可以把形成的链看成是具有同种分子量化合物组成的高聚物。
另一方面，独特的环可以大小不同、材料不同，相连接后形成具有不同分子量化合物组成的聚合物。
许多单元相连接给予了聚合物一个名称，poly意味着“多、聚、重复〞，mer意味着“链节、基体〞〔希腊语中〕。
例如：称为丁二烯的气态化合物，分子量为54，化合将近4000次，得到分子量大约为200000被称作聚丁二烯〔合成橡胶〕的高聚物。
形成高聚物的低分子化合物称为单体。
下面简单地描绘一下形成过程：丁二烯＋丁二烯＋…＋丁二烯——→聚丁二烯〔4000次〕因此可以看到分子量仅为54的小分子物质〔单体〕如何逐渐形成分子量为200000的大分子〔高聚物〕。
本质上，正是由于聚合物的宏大的分子尺寸才使其性能不同于象苯这样的一般化合物。
例如，固态苯，在5.5℃熔融成液态苯，进一步加热，煮沸成气态苯。
与这类简单化合物明确的行为相比，像聚乙烯这样的聚合物不能在某一特定的温度快速地熔融成纯洁的液体。
而聚合物变得越来越软，最终，变成非常粘稠的聚合物熔融体。
将这种热而粘稠的聚合物熔融体进一步加热，不会转变成各种气体，但它不再是聚乙烯〔如图1.1〕。
固态苯——→液态苯——→气态苯加热，5.5℃加热，80℃固体聚乙烯——→熔化的聚乙烯——→各种分解产物-但不是聚乙烯加热加热图1.1 低分子量化合物〔苯〕和聚合物〔聚乙烯〕受热后的不同行为发现另一种不同的聚合物行为和低分子量化合物行为是关于溶解过程。
例如，让我们研究一下，将氯化钠渐渐地添加到固定量的水中。
高分子材料工程专业英语翻译UNIT 1 What are Polymer 第一单元什么是高聚物What are polymers For one thing they are complex and giant molecules and are different from low molecular weight compounds like say common salt. To contrast the difference the molecular weight of common salt is only 58.5 while that of a polymer can be as high as several hundred thousand even more than thousand thousands. These big molecules or‘macro-molecules’ are made up of much smaller molecules can be of one or more chemical compounds. To illustrate imagine that a set of rings has the same size and is made of the same material. When these things are interlinked the chain formed can be considered as representing a polymer from molecules of the same compound. Alternatively individual rings could be of different sizes and materials and interlinked to represent a polymer from molecules of different compounds. 什么是高聚物首先他们是合成物和大分子而且不同于低分子化合物譬如说普通的盐。
专业英语词汇accordion手风琴activation活化（作用）additionpolymer加成聚合物，加聚物aggravate加重，恶化agitation搅拌agrochemical农药，化肥Alfincatalyst醇（碱金属）烯催化剂align排列成行aliphatic脂肪（族）的alkalimetal碱金属allyl烯丙基aluminumalkyl烷基铝amidation酰胺化（作用）amino氨基，氨基的amorphous无定型的，非晶体的anionic阴（负）离子的antioxidant抗氧剂antistaticagent抗静电剂aromatic芳香（族）的arrangement（空间）排布，排列atactic无规立构的attraction引力，吸引backbone 主链，骨干behavior性能，行为biological生物（学）的biomedical生物医学的bonddissociationenergy键断裂能boundary界限，范围brittle脆的，易碎的butadiene丁二烯butyllithium丁基锂calendering压延成型calendering压延carboxyl羧基carrier载体catalyst催化剂，触媒categorization分类（法）category种类，类型cation正[阳]离子cationic阳（正）离子的centrifuge离心chainreaction连锁反应chaintermination链终止char 炭characterize表征成为…的特征chilledwater冷冻水chlorine氯（气）coating涂覆cocatalyst 助催化剂coil线团coiling线团状的colligative依数性colloid胶体commence开始，着手commonsalt食盐complex络合物compliance柔量condensationpolymer缩合聚合物，缩聚物conductivematerial导电材料conformation构象consistency稠度，粘稠度contaminant污物contour外形，轮廓controlledrelease控制释放controversy争论，争议conversion转化率conversion转化copolymer 共聚物copolymerization共聚（合）corrosioninhibitor缓释剂countercurrent逆流crosslinking 交联crystal基体，结晶crystalline晶体，晶态，结晶的，晶态的crystalline结晶的crystallinity结晶性，结晶度crystallite微晶decomposition分解defect缺陷deformability变形性，变形能力deformation形变deformation变形degreeofpolymerization聚合度dehydrogenate使脱氢density密度depolymerization解聚deposit堆积物，沉积depropagation降解dewater脱水diacid二（元）酸diamine二（元）胺dibasic二元的dieforming口模成型diffraction衍射diffuse 扩散dimension尺寸dimensionalstability尺寸稳定性dimer二聚物（体）diol二（元）醇diolefin 二烯烃disintegrate分解，分散，分离dislocation错位，位错dispersant分散剂dissociate离解dissolution溶解dissolve使…溶解distort使…变形，扭曲doublebond双键dough（生）面团，揉好的面drug药品，药物elasticmodulus弹性模量elastomer弹性体eliminate消除，打开，除去elongation伸长率，延伸率entanglement缠结，纠缠entropy熵equilibrium平衡esterification酯化（作用）evacuate 撤出extrusion注射成型extrusion挤出fiber纤维flameretardant阻燃剂flexible柔软的flocculatingagent絮凝剂folded-chainlamellatheory折叠链片晶理论formulation配方fractionation分级fragment碎屑，碎片fringed-micelletheory缨状微束理论functionalgroup官能团functionalpolymer功能聚合物functionalizedpolymer功能聚合物gel凝胶glasstransitiontemperature玻璃化温度glassy玻璃（态）的glassy玻璃态的glassystate玻璃态globule小球，液滴，颗粒growingchain生长链，活性链gyration旋转，回旋hardness硬度heattransfer热传递heterogeneous不均匀的，非均匀的hydocyacid羧基酸hydrogen氢（气）hydrogenbonding氢键hydrostatic流体静力学hydroxyl烃基hypothetical假定的，理想的，有前提的ideal理想的，概念的imagine想象，推测imbed嵌入，埋入，包埋imperfect不完全的improve增进，改善impurity杂质indispensable 不了或缺的infraredspectroscopy红外光谱法ingredient成分initiation（链）引发initiator引发剂inorganicpolymer无机聚合物interaction相互作用interchain链间的interlink把…相互连接起来连接intermittent间歇式的intermolecular(作用于)分子间的intrinsic固有的ion离子ionexchangeresin离子交换树脂ionic离子的ionicpolymerization离子型聚合irradiation照射，辐射irregularity不规则性，不均匀的isobutylene异丁烯isocyanate异氰酸酯isopropylate异丙醇金属，异丙氧化金属isotactic等规立构的isotropic各项同性的kineticchainlength动力学链长kinetics动力学latent 潜在的lightscattering光散射line衬里，贴面liquidcrystal液晶macromelecule大分子，高分子matrix基体，母体，基质，矩阵mean-aquareend-to-enddistance 均方末端距mechanicalproperty力学性能，机械性能mechanism机理medium介质中等的，中间的minimise最小化minimum最小值，最小的mo(u)lding模型mobility流动性mobilize运动，流动model模型modify改性molecularweight分子量molecularweightdistribution分子量分布molten熔化的monofunctional单官能度的monomer单体morphology形态（学）moulding模塑成型neutral 中性的nonelastic非弹性的nuclearmagneticresonance核磁共振nucleartrackdetector核径迹探测器numberaveragemolecularweight数均分子量occluded夹杂（带）的olefinic烯烃的optimum最佳的，最佳值[点，状态]orient定向，取向orientation定向oxonium氧鎓羊packing 堆砌parameter参数parison型柸pattern花纹，图样式样peculiarity特性pendantgroup侧基performance性能，特征permeability 渗透性pharmaceutical药品，药物，药物的，医药的phenylsodium苯基钠phenyllithium苯基锂phosgene光气，碳酰氯photosensitizer光敏剂plastics塑料platelet片晶polyamide聚酰胺polybutene聚丁烯polycondensation缩（合）聚（合）polydisperse多分散的polydispersity多分散性polyesterification聚酯化（作用）polyethylene聚乙烯polyfunctional多官能度的polymer聚合物【体】，高聚物polymeric聚合（物）的polypropylene聚苯烯polystyrene聚苯乙烯polyvinylalcohol聚乙烯醇polyvinylchloride聚氯乙烯porosity多孔性，孔隙率positive正的，阳（性）的powdery粉状的processing加工，成型purity纯度pyrolysis热解radical自由基radicalpolymerization自由基聚合radius半径randomcoil无规线团randomdecomposition无规降解reactent反应物，试剂reactive反应性的，活性的reactivity反应性，活性reactivityratio竞聚率real真是的release 解除，松开repeatingunit重复单元retract收缩rubber橡胶rubbery橡胶态的rupture断裂saturation饱和scalp筛子，筛分seal密封secondaryshapingoperation二次成型sedimentation沉降（法）segment链段segment链段semicrystalline半晶settle沉淀，澄清shaping成型sidereaction副作用simultaneously同时，同步singlebond单键slasticparameter弹性指数slurry淤浆solarenergy太阳能solubility溶解度solvent溶剂spacergroup隔离基团sprinkle喷洒squeeze挤压srereoregularity立构规整性【度】stability稳定性stabilizer稳定剂statistical统计的step-growthpolymerization逐步聚合stereoregular有规立构的，立构规整性的stoichiometric当量的，化学计算量的strength强度stretch拉直，拉长strippingtower脱单塔subdivide细分区分substitution取代，代替surfactant 表面活性剂swell溶胀swollen溶胀的synthesis合成synthesize合成synthetic合成的tacky（表面）发粘的,粘连性tanker油轮，槽车tensilestrength抗张强度terminate（链）终止tertiary三元的，叔（特）的tetrahydrofuran四氢呋喃texture结构，组织thermoforming热成型thermondynamically热力学地thermoplastic热塑性的thermoset热固性的three-dimensionallyordered三维有序的titaniumtetrachloride四氯化钛titaniumtrichloride三氯化铁torsion转矩transfer（链）转移，（热）传递triethyloxonium-borofluoride三乙基硼氟酸羊trimer三聚物（体）triphenylenthylpotassium三苯甲基钾ultracentrifugation超速离心（分离）ultrasonic超声波uncross-linked非交联的uniaxial单轴的unsaturated不饱和的unzippering开链urethane氨基甲酸酯variation变化，改变vinyl乙烯基（的）vinylchloride氯乙烯vinylether乙烯基醚viscoelastic黏弹性的viscoelasticstate黏弹态viscofluidstate黏流态viscosity黏度viscosityaveragemolecularweight黏均分子量viscous粘稠的vulcanization硫化weightaveragemolecularweight重均分子量X-rayx射线x光yield产率Young'smodulus杨氏模量课文翻译第一单元什么是高聚物什么是高聚物首先，他们是合成物和大分子，而且不同于低分子化合物，譬如说普通的盐。
05. 高分子化学05.1高分子物质05.2coiling type polymer05.2 聚合与高分子化学反应3 平均官能度average functionality4 双官能［基］单体bifunctional monomer5 三官能［基］单体trifunctional monomer6 乙烯基单体vinyl monomer1,1-亚乙烯基单体，vinylidene monomer7偏［二］取代乙烯单体1,2-亚乙烯基单体，vinylene monomer81,2-二取代乙烯单体9 双烯单体，二烯单体diene monomer10 极性单体polar monomer11 非极性单体non polar monomer12 共轭单体conjugated monomer13 非共轭单体non conjugated monomer14 活化单体activated monomer15 官能单体functional monomer16 大分子单体macromer, macromonomer17 环状单体cyclic monomer18 共聚单体comonomer19 聚合［反应］polymerization20 均聚反应homopolymerization低聚反应，oligomerization21齐聚反应(曾用名)22 调聚反应telomerization23 自发聚合spontaneous polymerization24 预聚合prepolymerization25 后聚合post polymerization26 再聚合repolymerization27 铸塑聚合, 浇铸聚合cast polymerization28 链［式］聚合chain polymerization29 烯类聚合，乙烯基聚合vinyl polymerization30 双烯［类］聚合diene polymerization31 加［成］聚［合］addition polymerization32自由基聚合，游离基聚合(曾用名) free radical polymerization, radical polymerization33控制自由基聚合，可控自由基聚合controlled radical polymerization，CRP34 活性自由基聚合living radical polymerization35 原子转移自由基聚合atom transfer radical polymerization，ATRP36 反向原子转移自由基聚合reverse atom transfer radical polymerization，RATRP37可逆加成断裂链转移reversible addition fragmentation chaintransfer，RAFT38 氮氧[自由基]调控聚合nitroxide mediated polymerization39 稳定自由基聚合stable free radical polymerization，FRP40 自由基异构化聚合free radical isomerization polymerization41 自由基开环聚合radical ring opening polymerization42 氧化还原聚合redox polymerization43无活性端聚合，死端聚合(曾用名)dead end polymerization44 光［致］聚合photo polymerization45 光引发聚合light initiated polymerization46 光敏聚合photosensitized polymerization47 四中心聚合four center polymerization48 电荷转移聚合charge transfer polymerization49 辐射引发聚合radiation initiated polymerization50 热聚合thermal polymerization51 电解聚合electrolytic polymerization52 等离子体聚合plasma polymerization53 易位聚合metathesis polymerization54 开环易位聚合ring opening metathesis polymerization，ROMP55 精密聚合precision polymerization56 环化聚合cyclopolymerization57 拓扑化学聚合topochemical polymerization58 平衡聚合equilibrium polymerization59 离子［型］聚合ionic polymerization60 辐射离子聚合radiation ion polymerization61 离子对聚合ion pair polymerization62正离子聚合，阳离子聚合cationic polymerization63 碳正离子聚合carbenium ion polymerization,carbocationicpolymerization64 假正离子聚合pseudo cationic polymerization65 假正离子活［性］聚合pseudo cationic living polymerization66 活性正离子聚合living cationic polymerization67负离子聚合，阴离子聚合anionic polymerization68 碳负离子聚合carbanionic polymerization69 活性负离子聚合living anionic polymerization70 负离子环化聚合anionic cyclopolymerization71 负离子电化学聚合anionic electrochemical polymerization72 负离子异构化聚合anionic isomerization polymerization73 烯丙基聚合allylic polymerization74 活［性］聚合living polymerization75 两性离子聚合zwitterion polymerization76 齐格勒-纳塔聚合Ziegler Natta polymerization77 配位聚合coordination polymerization78 配位离子聚合coordinated ionic polymerization79 配位负离子聚合coordinated anionic polymerization80 配位正离子聚合coordinated cationic polymerization81 插入聚合insertion polymerization82定向聚合，立构规整聚合stereoregular polymerization, stereospecific polymerization83 有规立构聚合tactic polymerization84 全同立构聚合isospecific polymerization85 不对称诱导聚合asymmetric induction polymerization86 不对称选择性聚合asymmetric selective polymerization87 不对称立体选择性聚合asymmetric stereoselective polymerization88 对映［体］不对称聚合enantioasymmetric polymerization89 对映［体］对称聚合enantiosymmetric polymerization90 异构化聚合isomerization polymerization91 氢转移聚合hydrogen transfer polymerization92 基团转移聚合group transfer polymerization，GTP93 消除聚合elimination polymerization94 模板聚合matrix polymerization,templatepolymerization95 插层聚合intercalation polymerization96 无催化聚合uncatalyzed polymerization97 开环聚合ring opening polymerization98 活性开环聚合living ring opening polymerization99 不死的聚合immortal polymerization100 酶聚合作用enzymatic polymerization聚加成反应，polyaddition101逐步加成聚合(曾用名)102 偶联聚合coupling polymerization103 序列聚合sequential polymerization104 闪发聚合，俗称暴聚flash polymerization105 氧化聚合oxidative polymerization106 氧化偶联聚合oxidative coupling polymerization107 逐步［增长］聚合step growth polymerization缩聚反应condensation polymerization，108polycondensation酯交换型聚合transesterification type polymerization, 109ester exchange polycondensation110 自催化缩聚autocatalytic polycondensation111 均相聚合homogeneous polymerization112 非均相聚合heterogeneous polymerization113 相转化聚合phase inversion polymerization114 本体聚合bulk polymerization, mass polymerization 115 固相聚合solid phase polymerization气相聚合gaseous polymerization,116gas phase polymerization117 吸附聚合adsorption polymerization118 溶液聚合solution polymerization119 沉淀聚合precipitation polymerization120 淤浆聚合slurry polymerization121 悬浮聚合suspension polymerization122 反相悬浮聚合reversed phase suspension polymerization 123 珠状聚合bead polymerization, pearl polymerization 124 分散聚合dispersion polymerization125 反相分散聚合inverse dispersion polymerization126 种子聚合seeding polymerization127 乳液聚合emulsion polymerization128 无乳化剂乳液聚合emulsifier free emulsion polymerization 129 反相乳液聚合inverse emulsion polymerization130 微乳液聚合micro emulsion polymerization131 连续聚合continuous polymerization132 半连续聚合semicontinuous polymerization133 分批聚合，间歇聚合batch polymerization134 原位聚合in situ polymerization135 均相缩聚homopolycondensation136 活化缩聚activated polycondensation137 熔融缩聚melt phase polycondensation138 固相缩聚solid phase polycondensation139 体型缩聚three dimensional polycondensation140 界面聚合interfacial polymerization141 界面缩聚interfacial polycondensation142 环加成聚合cycloaddition polymerization143 环烯聚合cycloalkene polymerization144 环硅氧烷聚合cyclosiloxane polymerization145 引发剂initiator146 引发剂活性activity of initiator147 聚合催化剂polymerization catalyst148 自由基引发剂radical initiator149 偶氮［类］引发剂azo type initiator150 2,2′偶氮二异丁腈2,2'- azobisisobutyronitrile, AIBN151 过氧化苯甲酰benzoyl peroxide, BPO152 过硫酸盐引发剂persulphate initiator153 复合引发体系complex initiation system154 氧化还原引发剂redox initiator电荷转移复合物，charge transfer complex, CTC155电荷转移络合物156 聚合加速剂，聚合促进剂polymerization accelerator157 光敏引发剂photoinitiator158 双官能引发剂bifunctional initiator，difunctional initiator 159 三官能引发剂trifunctional initiator160 大分子引发剂macroinitiator161 引发-转移剂initiator transfer agent, inifer162 引发-转移-终止剂initiator transfer agent terminator, iniferter 163 光引发转移终止剂photoiniferter164 热引发转移终止剂thermoiniferter165 正离子催化剂cationic catalyst166 正离子引发剂cationic initiator167 负离子引发剂ionioic initiator168 共引发剂coinitiator169 烷基锂引发剂alkyllithium initiator170 负离子自由基引发剂anion radical initiator171 烯醇钠引发剂alfin initiator172 齐格勒-纳塔催化剂Ziegler Natta catalyst173 过渡金属催化剂transition metal catalyst174 双组分催化剂bicomponent catalyst175 后过渡金属催化剂late transition metal catalyst 176 金属络合物催化剂metal complex catalyst 177 ［二］茂金属催化剂metallocene catalyst178 甲基铝氧烷methylaluminoxane, MAO179μ氧桥双金属烷氧化物催化剂bimetallic μ-oxo alkoxides catalyst180 双金属催化剂bimetallic catalyst 181 桥基茂金属bridged metallocene182限定几何构型茂金属催化剂constrained geometry metallocene catalyst183 均相茂金属催化剂homogeneous metallocene catalyst 184 链引发chain initiation185 热引发thermal initiation186 染料敏化光引发dye sensitized phtoinitiation187 电荷转移引发charge transfer initiation188 诱导期induction period189 引发剂效率initiator efficiency190 诱导分解induced decomposition191 再引发reinitiation192 链增长chain growth, chain propagation193 增长链端propagating chain end194 活性种reactive species195 活性中心active center196 持续自由基persistent radical197 聚合最高温度ceilling temperature of polymerization 198 链终止chain termination199 双分子终止bimolecular termination200 初级自由基终止primary radical termination201 扩散控制终止diffusion controlled termination202 歧化终止disproportionation termination203 偶合终止coupling termination204 单分子终止unimolecular termination205 自发终止spontaneous termination206 终止剂terminator207 链终止剂chain terminating agent208 假终止pseudotermination209 自发终止self termination210 自由基捕获剂radical scavenger211 旋转光闸法rotating sector method212 自由基寿命free radical lifetime213 凝胶效应gel effect214 自动加速效应autoacceleration effect215 链转移chain transfer216 链转移剂chain transfer agent217 尾咬转移backbitting transfer218 退化链转移degradation (degradative) chain transfer 219 加成断裂链转移［反应］addition fragmentation chain transfer 220 链转移常数chain transfer constant①缓聚作用retardation221②延迟作用222 阻聚作用inhibition223 缓聚剂retarder224 缓聚剂，阻滞剂retarding agent225 阻聚剂inhibitor226 封端［反应］end capping227 端基terminal group228 聚合动力学polymerization kinetics229 聚合热力学polymerization thermodynamics 230 聚合热heat of polymerization231 共聚合［反应］copolymerization232 二元共聚合binary copolymerization233 三元共聚合ternary copolymerization234 竞聚率reactivity ratio235 自由基共聚合radical copolymerization236 离子共聚合ionic copolymerization237 无规共聚合random copolymerization238 理想共聚合ideal copolymerization239 交替共聚合alternating copolymerization 240 恒［组］分共聚合azeotropic copolymerization 241 接枝共聚合graft copolymerization242 嵌段共聚合block copolymerization243 开环共聚合ring opening copolymerization 244 共聚合方程copolymerization equation245 共缩聚copolycondensation246 逐步共聚合step copolymerization247 同种增长homopropagation248 自增长self propagation249 交叉增长cross propagation250 前末端基效应penultimate effect251 交叉终止cross termination252 Q值Q value253 e值e value254 Q,e概念Q, e scheme255 序列长度分布sequence length distribution 256 侧基反应reaction of pendant group257 扩链剂，链增长剂chain extender258 交联crosslinking259 化学交联chemical crosslinking260 自交联self crosslinking261 光交联photocrosslinking262 交联度degree of crosslinking263 硫化vulcanization264 固化curing265 硫［黄］硫化sulfur vulcanization266 促进硫化accelerated sulfur vulcanization 267 过氧化物交联peroxide crosslinking268 无规交联random crosslinking269 交联密度crosslinking density270 交联指数crosslinking index271 解聚depolymerization272 ①降解②退化degradation273 链断裂chain breaking274 解聚酶depolymerase275 细菌降解bacterial degradation276 生物降解biodegradation277 化学降解chemical degradation278 辐射降解radiation degradation05.3 高分子物理化学与高分子物理17三单元组triad18四单元组tetrad19五单元组pentad20无规线团random coil21自由连接链freely-jointed chain22自由旋转链freely-rotating chain23蠕虫状链worm-like chain24柔性链flexible chain25链柔性chain flexibility26刚性链rigid chain27棒状链rodlike chain28链刚性chain rigidity29聚集aggregation30聚集体aggregate31凝聚、聚集coalescence32链缠结chain entanglement33凝聚缠结cohesional entanglement34物理缠结physical entanglement35拓扑缠结topological entanglement36凝聚相condensed phase37凝聚态condensed state38凝聚过程condensing process39临界聚集浓度critical aggregation concentration 40线团-球粒转换coil-globule transition41受限链confined chain42受限态confined state43物理交联physical crosslinking44统计线团statistical coil45等效链equivalent chain46统计链段statistical segment47链段chain segment48链构象chain conformation49无规线团模型random coil model50无规行走模型random walk model51自避随机行走模型self avoiding walk model52卷曲构象coiled conformation53高斯链Gaussian chain54无扰尺寸unperturbed dimension55扰动尺寸perturbed dimension56热力学等效球thermodynamically equivalent sphere 57近程分子内相互作用short-range intramolecular interaction 58远程分子内相互作用long-range intramolecular interaction 59链间相互作用interchain interaction60链间距interchain spacing61长程有序long range order62近程有序short range order63回转半径radius of gyration64末端间矢量end-to-end vector65链末端chain end66末端距end-to-end distance67无扰末端距unperturbed end-to-end distance68均方根末端距root-mean-square end-to-end distance 69伸直长度contour length70相关长度persistence length71主链；链骨架chain backbone72支链branch chain73链支化chain branching74短支链short-chain branch75长支链long-chain branch76支化系数branching index77支化密度branching density78支化度degree of branching79交联度degree of crosslinking80网络network81网络密度network density82溶胀swelling83平衡溶胀equilibrium swelling84分子组装，分子组合molecular assembly85自组装self assembly86微凝胶microgel87凝胶点gel point88可逆[性]凝胶reversible gel89溶胶-凝胶转化sol-gel transformation90临界胶束浓度critical micelle concentration，CMC91组成非均一性constitutional heterogenity, compositionalheterogenity92摩尔质量平均molar mass average 又称“分子量平均”93数均分子量number-average molecular weight,number-average molar mass94重均分子量weight-average molecular weight,weight-average molar mass95Z均分子量Z(Zaverage)-average molecular weight,Z-molar mass96黏均分子量viscosity-average molecular weight，viscosity-average molar mass97表观摩尔质量apparent molar mass98表观分子量apparent molecular weight99聚合度degree of polymerization100动力学链长kinetic chain length101单分散性monodispersity102临界分子量critical molecular weight103分子量分布molecular weight distribution，MWD104多分散性指数polydispersity index，PID105平均聚合度average degree of polymerization106质量分布函数mass distribution function107数量分布函数number distribution function108重量分布函数weight distribution function109舒尔茨-齐姆分布Schulz-Zimm distribution110最概然分布most probable distribution 曾用名“最可几分布”111对数正态分布logarithmic normal distribution 又称“对数正则分布”112聚合物溶液polymer solution113聚合物-溶剂相互作用polymer-solvent interaction114溶剂热力学性质thermodynamic quality of solvent115均方末端距mean square end to end distance116均方旋转半径mean square radius of gyration117θ温度theta temperature118θ态theta state119θ溶剂theta solvent120良溶剂good solvent121不良溶剂poor solvent122位力系数Virial coefficient 曾用名“维里系数”123排除体积excluded volume124溶胀因子expansion factor125溶胀度degree of swelling126弗洛里-哈金斯理论Flory-Huggins theory127哈金斯公式Huggins equation128哈金斯系数Huggins coefficient129χ(相互作用)参数χ-parameter130溶度参数solubility parameter131摩擦系数frictional coefficient132流体力学等效球hydrodynamically equivalent sphere133流体力学体积hydrodynamic volume134珠-棒模型bead-rod model135球-簧链模型ball-spring [chain] model136流动双折射flow birefringence, streaming birefringence 137动态光散射dynamic light scattering138小角激光光散射low angle laser light scattering139沉降平衡sedimentation equilibrium140沉降系数sedimentation coefficient141沉降速度法sedimentation velocity method142沉降平衡法sedimentation equilibrium method143相对黏度relative viscosity144相对黏度增量relative viscosity increment145黏度比viscosity ratio146黏数viscosity number147[乌氏]稀释黏度计[Ubbelohde] dilution viscometer148毛细管黏度计capillary viscometer149落球黏度计ball viscometer150落球黏度ball viscosity151本体黏度bulk viscosity152比浓黏度reduced viscosity153比浓对数黏度inherent viscosity, logarithmic viscositynumber154特性黏数intrinsic viscosity, limiting viscosity number 155黏度函数viscosity function156零切变速率黏度zero shear viscosity157端基分析analysis of end group158蒸气压渗透法vapor pressure osmometry, VPO159辐射的相干弹性散射coherent elastic scattering of radiation160折光指数增量refractive index increment161瑞利比Rayleigh ratio162超瑞利比excess Rayleigh ratio163粒子散射函数particle scattering function164粒子散射因子particle scattering factor165齐姆图Zimm plot166散射的非对称性dissymmetry of scattering167解偏振作用depolarization168分级fractionation169沉淀分级precipitation fractionation170萃取分级extraction fractionation171色谱分级chromatographic fractionation172柱分级column fractionation173洗脱分级，淋洗分级elution fractionation174热分级thermal fractionation175凝胶色谱法gel chromatography176摩尔质量排除极限molar mass exclusion limit177溶剂梯度洗脱色谱法solvent gradient [elution] chromatography 178分子量排除极限molecular weight exclusion limit179洗脱体积elution volume180普适标定universal calibration181加宽函数spreading function182链轴chain axis183等同周期identity period184链重复距离chain repeating distance185晶体折叠周期crystalline fold period186构象重复单元conformational repeating unit187几何等效geometrical equivalence188螺旋链helix chain189构型无序configurational disorder190链取向无序chain orientational disorder191构象无序conformational disorder192锯齿链zigzag chain193双[股]螺旋double stranded helix194[分子]链大尺度取向global chain orientation195结晶聚合物crystalline polymer196半结晶聚合物semi-crystalline polymer197高分子晶体polymer crystal198高分子微晶polymer crystallite199结晶度degree of crystallinity, crystallinity200高分子[异质]同晶现象macromolecular isomorphism201聚合物形态学morphology of polymer202片晶lamella, lamellar crystal203轴晶axialite204树枝[状]晶体dendrite205纤维晶fibrous crystal206串晶结构shish-kebab structure 207球晶spherulite208折叠链folded chain209链折叠chain folding210折叠表面fold surface211折叠面fold plane212折叠微区fold domain213相邻再入模型adjacent re-entry model 214接线板模型switchboard model215缨状微束模型fringed-micelle model 216折叠链晶体folded-chain crystal 217平行链晶体parallel-chain crystal 218伸展链晶体extended-chain crystal 219球状链晶体globular-chain crystal 220长周期long period221近程结构short-range structure 222远程结构long-range structure 223成核作用nucleation224分子成核作用molecular nucleation 225阿夫拉米方程Avrami equation226主结晶primary crystallization 227后期结晶secondary crystallization 228外延结晶，附生结晶epitaxial crystallizationepitaxial growth229外延晶体生长，附生晶体生长230织构texture231液晶态liquid crystal state232溶致性液晶lyotopic liquid crystal233热致性液晶thermotropic liquid crystal234热致性介晶thermotropic mesomorphism235近晶相液晶smectic liquid crystal236近晶中介相smectic mesophase237近晶相smectic phase238条带织构banded texture239环带球晶ringed spherulite240向列相nematic phase241盘状相discotic phase242解取向disorientation243分聚segregation244非晶相amorphous phase 曾用名“无定形相”245非晶区amorphous region246非晶态amorphous state247非晶取向amorphous orientation248链段运动segmental motion249亚稳态metastable state250相分离phase separation251亚稳相分离spinodal decomposition252bimodal decomposition253微相microphase254界面相boundary phase255相容性compatibility256混容性miscibility257不相容性incompatibility258不混容性immiscibility259增容作用compatiibilizationlower critical solution temperature, LCST 260最低临界共溶(溶解)温度upper critical solution temperature , UCST 261最高临界共溶(溶解)温度262浓度猝灭concentration quenching263激基缔合物荧光excimer fluorescence264激基复合物荧光exciplex fluorescence265激光共聚焦荧光显微镜laser confocal fluorescence microscopy 266单轴取向uniaxial orientation267双轴取向biaxial orientation, biorientation268取向度degree of orientation269橡胶态rubber state270玻璃态glassy state271高弹态elastomeric state272黏流态viscous flow state273伸长elongation274高弹形变high elastic deformation275回缩性，弹性复原nerviness276拉伸比draw ratio, extension ratio277泊松比Poisson's ratio278杨氏模量Young's modulus279本体模量bulk modulus280剪切模量shear modulus281法向应力normal stress282剪切应力shear stress283剪切应变shear strain284屈服yielding285颈缩现象necking 又称“细颈现象”286屈服应力yield stress287屈服应变yield strain288脆性断裂brittle fracture289脆性开裂brittle cracking290脆-韧转变brittle ductile transition291脆化温度brittleness(brittle) temperature292延性破裂ductile fracture293冲击强度impact strength294拉伸强度tensile strength 又称“断裂强度,breaking strength”295极限拉伸强度ultimate tensile strength296抗撕强度tearing strength 又称“抗扯强度”297弯曲强度flexural strength, bending strength298弯曲模量bending modulus299弯曲应变bending strain300弯曲应力bending stress301收缩开裂shrinkage crack302剪切强度shear strength303剥离强度peeling strength304疲劳强度fatigue strength, fatigue resistance305挠曲deflection306压缩强度compressive strength307压缩永久变形compression set308压缩变形compressive deformation309压痕硬度indentation hardness310洛氏硬度Rockwell hardness311布氏硬度Brinell hardness312抗刮性scrath resistance313断裂力学fracture mechanics314力学破坏mechanical failure315应力强度因子stress intensity factor316断裂伸长elongation at break317屈服强度yield strength318断裂韧性fracture toughness319弹性形变elastic deformation320弹性滞后elastic hysteresis321弹性elasticity322弹性模量modulus of elasticity323弹性回复elastic recovery324不可回复形变irrecoverable deformation325裂缝crack 俗称“龟裂”326银纹craze327形变；变形deformation328永久变形deformation set329剩余变形residual deformation330剩余伸长residual stretch331回弹，回弹性resilience332延迟形变retarded deformation333延迟弹性retarded elasticity334可逆形变reversible deformation335应力开裂stress cracking336应力-应变曲线stress strain curve337拉伸应变stretching strain338拉伸应力弛豫tensile stress relaxation339热历史thermal history340热收缩thermoshrinking341扭辫分析torsional braid analysis，TBA 342应力致白stress whitening343应变能strain energy344应变张量strain tensor345剩余应力residual stress346应变硬化strain hardening347应变软化strain softening348电流变液electrorheological fluid349假塑性pseudoplastic350拉胀性auxiticity351牛顿流体Newtonian fluid352非牛顿流体non-Newtonian fluid353宾汉姆流体Bingham fluid354冷流cold flow355牛顿剪切黏度Newtonian shear viscosity 356剪切黏度shear viscosity357表观剪切黏度apparent shear viscosity358剪切变稀shear thinning359触变性thixotropy360塑性形变plastic deformation361塑性流动plastic flow362体积弛豫volume relaxation363拉伸黏度extensional viscosity364黏弹性viscoelasticity365线性黏弹性linear viscoelasticity366非线性黏弹性non-linear viscoelasticity367蠕变creep368弛豫[作用] relaxation 又称“松弛”369弛豫模量relaxation modulus370蠕变柔量creep compliance371热畸变温度heat distortion temperature372弛豫谱relaxation spectrum373推迟[时间]谱retardation [time] spectrum374弛豫时间relaxation time375推迟时间retardation time376动态力学行为dynamic mechanical behavior377动态黏弹性dynamic viscoelasticity378热-机械曲线thermo-mechanical curve379动态转变dynamic transition380储能模量storage modulus381损耗模量loss modulus382复数模量complex modulus383复数柔量complex compliance384动态黏度dynamic viscosity385复数黏度complex viscosity386复数介电常数complex dielectric permittivity387介电损耗因子dielectric dissipation factor388介电损耗常数dielectric loss constant389介电弛豫时间dielectric relaxation time390玻璃化转变glass transition391玻璃化转变温度glass-transition temperature05.4 高分子加工技术和应用。
UNIT 1 What are Polymer?什么是高聚物？首先，他们是合成物和大分子，而且不同于低分子化合物，譬如说普通的盐。
与低分子化合物不同的是，普通盐的分子量仅仅是58.5，而高聚物的分子量高于105，甚至大于106。
这些大分子或“高分子”由许多小分子组成。
小分子相互结合形成大分子，大分子能够是一种或多种化合物。
举例说明，想象一组大小相同并由相同的材料制成的环。
当这些环相互连接起来，可以把形成的链看成是具有同种分子量化合物组成的高聚物。
另一方面，独特的环可以大小不同、材料不同，相连接后形成具有不同分子量化合物组成的聚合物。
许多单元相连接给予了聚合物一个名称，poly意味着“多、聚、重复”，mer意味着“链节、基体”（希腊语中）。
例如：称为丁二烯的气态化合物，分子量为54，化合将近4000次，得到分子量大约为200000被称作聚丁二烯（合成橡胶）的高聚物。
形成高聚物的低分子化合物称为单体。
下面简单地描述一下形成过程:因而能够看到分子量仅为54的小分子物质（单体）如何逐渐形成分子量为200000的大分子（高聚物）。
实质上，正是由于聚合物的巨大的分子尺寸才使其性能不同于象苯这样的一般化合物。
例如，固态苯，在5.5℃熔融成液态苯，进一步加热，煮沸成气态苯。
与这类简单化合物明确的行为相比，像聚乙烯这样的聚合物不能在某一特定的温度快速地熔融成纯净的液体。
而聚合物变得越来越软，最终，变成十分粘稠的聚合物熔融体。
将这种热而粘稠的聚合物熔融体进一步加热，不会转变成各种气体，但它不再是聚乙烯（如图1.1）。
发现另一种不同的聚合物行为和低分子量化合物行为是关于溶解过程。
例如，让我们研究一下，将氯化钠慢慢地添加到固定量的水中。
盐，代表一种低分子量化合物，在水中达到点（叫饱和点）溶解，但，此后，进一步添加盐不进入溶液中却沉到底部而保持原有的固体状态。
饱和盐溶液的粘度与水的粘度不是十分不同，但是，如果我们用聚合物替代，譬如说，将聚乙烯醇添加到固定量的水中，聚合物不是马上进入到溶液中。
