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Review on CO2 heat pump water heater for residential use in Japan

Review on CO2 heat pump water heater for residential use in Japan
Review on CO2 heat pump water heater for residential use in Japan

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Review on CO2 heat pump water heater for residential use in Japan

Article in Renewable and Sustainable Energy Reviews · June 2015

DOI: 10.1016/j.rser.2015.05.083

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Review on CO2heat pump water heater for residential use in Japan

Jian-Fei Zhang a,Yan Qin b,Chi-Chuan Wang c,n

a Compressor Technology Department,Panasonic Appliances Compressor(Dalian)Co.,Ltd.,Dalian116033,Liaoning,PR China

b R&D Center,Panasoni

c Appliances Compressor(Dalian)Co.,Ltd.,Dalian116033,Liaoning,PR China

c Department of Mechanical Engineering,National Chiao Tung University,Hsinchu300,Taiwan

a r t i c l e i n f o

Article history:

Received15November2013

Received in revised form

3May2015

Accepted26May2015

Keywords:

Carbon dioxide

Heat pump water heater

Compressor

Water–CO2gas cooler

a b s t r a c t

The present study presents an overview of CO2heat pump water heater for residential use in Japan.The

contents include the general background,current market,and the technology evolvement of the

transcritical CO2system,especially on the key components like compressor and gas cooler.Some

cutting edge technology associated with the high ef?cient compressors and its integration with

expander,such as swing compressor,sub-compressor,two-stage compressor,scroll expander,and

dual-sided scroll-type expander are elaborated in this review.Some ingenious tube designs to promote

the performance of gas cooler are also studied.In practice,the dominant thermal resistance may occur in

the CO2side or water side,thereby implementing twisted tube or dimple tubes may be quite effective.

The placement of enhancement on the water side is especially effective when the operational pressure is

close to the critical pressure whereas heat transfer enhancement is more helpful if the operational

pressure is comparatively high.For augmentation on the CO2side,it would be more bene?cial to place

enhancement a distance away from the pseudo-critical region.

&2015Elsevier Ltd.All rights reserved. Contents

1.Introduction (1383)

1.1.Current market size in Japan (1384)

1.2.Main manufacturers (1384)

1.3.Product trends (1385)

https://www.doczj.com/doc/551772548.html,pressor (1385)

2.1.Current status of the compressors (1385)

2.1.1.Rotary compressor (1385)

2.1.2.Swing compressor (1386)

2.1.3.Scroll compressor (1386)

2.2.Future trends (1386)

2.2.1.Two-stage compressor (1386)

2.2.2.Expander and expander–compressor (1387)

3.Water–CO2heat exchanger (1388)

4.Other heat pump water heater standard for the major countries (1390)

5.Conclusions (1390)

Acknowledgments (1391)

References (1391)

1.Introduction

In Japan,energy demand for hot tap water accounts for about

30%of the total residential energy consumption,but most of this

demand(over90%)is produced by direct combustion of fossil

fuel which may lead to pollution concerns and environmental

Contents lists available at ScienceDirect

journal homepage:https://www.doczj.com/doc/551772548.html,/locate/rser

Renewable and Sustainable Energy Reviews

https://www.doczj.com/doc/551772548.html,/10.1016/j.rser.2015.05.083

1364-0321/&2015Elsevier Ltd.All rights

reserved.

n Correspondence to:EE474,1001University Road,Hsinchu300,Taiwan Depart-

ment of Mechanical Engineering,National Chiao Tung University,Hsinchu300,

Taiwan.

E-mail address:ccwang@https://www.doczj.com/doc/551772548.html,.tw(C.-C.Wang).

Renewable and Sustainable Energy Reviews50(2015)1383–1391

problems.Hence the development of high-performance heat pump water heaters using natural working ?uids had received a lot attention recently as far as energy conservation and green-house gas reduction is concerned [1].Among the existing natural refrigerants,carbon dioxide (CO 2)is especially prominent for its outstanding features like non ?ammable,nontoxic,no known carcinogenic,and free from mutagenic.Moreover,using CO 2in refrigerating systems can be regarded as an alternative form of carbon capture,thereby helping to relief the in ?uence on climate change [2].For the revival of CO 2refrigeration system,the pioneering works of Lorentzen et al.[3–5]had proved that the use of CO 2can meet the simultaneous needs for an ef ?cient air-conditioning and for hot water production.This can be made available by operating the CO 2system in the transcritical region [6].As a consequence,heat pump water heater systems using CO 2as a refrigerant had received a lot of efforts for the past several decades,e.g.[7–13].Numerous heat pump water heaters for the residential sector had been developed in recent years,and gradu-ally gained its popularity in Japan,hence the electrical utilities and the associated water heater manufacturers had granted the name

“Eco Cute ”to the heat pump water heaters that use natural refrigerant CO 2[14].

1.1.Current market size in Japan

Since the advent of Eco Cute products in 2001as the innovative heat pump technology capable of reducing the energy for heating water,the Eco Cute market has continued to grow.In 2011,the cumulative number of the installed units surpassed 3million,and the product has steadily penetrated into the housing market.As shown in Fig.1,with some 560,000units sold at its peak in 2010,the market size decreased moderately in 2011and 2012.In 2012,it is estimated at about 440,000units.The main reason for expecting the market to recover in 2013lies in a likely increase in the number of new housing constructions with respect to the rise of consumption tax which will be in effect at April 2014.Moreover,Eco Cute also accompanies with some special features during an emergency,such as its ability to supply hot water even during a power outage period [15].1.2.Main manufacturers

Denso is the ?rst CO 2heat pump water heater supplier on the market.Since then many Japanese manufacturers had set up the production line for Eco Cute product,including the major players such as Sanyo,Panasonic,Daikin,Hitachi,Mitsubishi Electric,Sanden,Corona,Toshiba Carrier and Matsushita Electric.The Eco Cute is mainly for residential use with a variety of models,ranging from single family homes and condominiums to those serving not only mild and cold climates,but also regions where it is necessary to withstand corrosion from salt spray.There are also multi-function Eco Cute models that can be combined with ?oor heating or a bathroom heater with a humidi ?er function.The unit capacity and water tank volume normally falls in the range of 4.5/6kW

and

Fig.1.Market size of Eco-cute units in

Japan.

Fig.2.Schematic for a typical residential Eco-cute unit.

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews 50(2015)1383–1391

1384

370/460L,respectively,for residential use as seen in Fig.2.The corresponding speci?cation is tabulated in Table1(4.5kW capa-city,370L water tank,hot water supply model).

1.3.Product trends

Many Japanese manufacturers are striving to improve the overall energy ef?ciency of Eco Cute system by enhancing the performance of key components such as compressor and heat exchanger.The related technologies to tailor this problem are described in more details in the https://www.doczj.com/doc/551772548.html,pressor

At a very low critical temperature,the CO2transcritical cycles normally operate at a very high pressure level which is normally much higher than its counterpart refrigerants like R-410A or R-134a.The appreciably high pressure for CO2system requires special treatments of the key components,especially for the compressors.A detailed general comparison of CO2and R-410A/ R-134a compressor is shown in Table2

2.1.Current status of the compressors

As shown in Fig.3,rotary,swing and scroll are the three main types of compressors applicable to the current CO2water heat pump.The corresponding speci?cations from different manufacturers are tabu-lated in Table3.The typical displacement for the CO2compressors ranges from3.3to4.5cm3[17–20]with revolutions being1800–7200minà1[21]mostly.Typical rating condition may be designed at 4–4.5MPa for the suction pressure,9–10MPa for the discharge pressure and221C for the outlet temperature of the gas cooler.

2.1.1.Rotary compressor

Rotary compressor had been used in the traditional air con-ditioning and heat pump water heater system for a long time,and accordingly it was adopted for CO2refrigerant after certain modi?cations.Hideaki and Shinichi[18]improved the conven-tional R-410A refrigerant compressor using some newly developed technologies,such as the?exible structure for the cylinder vane slot and vane coating method.As a result,the developed CO2 compressor reveals a suf?ciently high performance,good oil circulation and reliability.Hideto and Naotaka[22]developed a single rotary compressor,featuring a so-called DLC-Si technology to reduce wear of the vane.They demonstrated that the wear at the vane with DLC-Si coating is at least two times slower than that with nitrided vane.Yokoyama et al.[23]performed a CFD simula-tion to improve the oil separation and to reduce the shell size inside the CO2rotary compressor using two measures,including ?attening a lower weight of the rotor and to set up a rotating discover a protruding balance weight.Okuda et al.[24]developed

Table1

Basic speci?cations for Eco cute.

Components Data S-

company P-

Company

D-

Company

H-

Company

M-

Company

Outdoor

unit Catalog

year

20092013201220122012

Capacity

(kW)

4.5

Power

(kW)

0.9150.980.9450.970.96

COP 4.9 4.6 4.8 4.6 4.7 CO2

Weight

(kg)

0.860.590.910.82

Unit

weight

(kg)

6143555549

Sound

(dB)

3838383838 Design

pressure

(MPa)

14/814/913.7/9.513.3/814/8.5

Water tank Volume

(L)

370

Weight

(kg)

7061675465

Test condition:dry/wet bubble temperature?16/121C,inlet/outlet water temperature?17/651C([16]).

Table2

Basic speci?cations for compressor in different refrigerants.

Refrigerant CO2R410A R134a

Global warming potential[2]120001300 Volume capacity ratio310.45 Design pressure(MPa)14\8 4.5\2.5 2.5\1.1 High side\low side

Max pressure difference(ratio)10 3.5 2.5Table3

Basic speci?cations for CO2compressors in Japan.

Manufacture Sanyo Mitsubishi E Daikin Denso

Reference[17][18][19][20] Compressor type Two-stage rotary Single rotary Swing Scroll Motor type DC motor

Size(mm)?118?217––?137?285 Displacement(cm3)1st stage:3.33

2nd stage:2.33 4.5 4.2

3.3

Fig.3.Schematic of the compressor layout for various companies.

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews50(2015)1383–13911385

a high ef ?ciency rotary compressor based on inverter design for their ECO CUTE production.

2.1.2.Swing compressor

Owing to the high differential pressure of the CO 2rotary compressor,the internal gas leakage across the vane from the high to low pressure areas increases,leading to a degradation of compressor ef ?ciency.Therefore,Masahide et al.[19]developed a swing compressor which combined a vane and roller together as shown in Fig.4.With the help of swing compressor design,sliding between the vane and roller is eliminated and the wear problem is removed.As a consequence,the gas leakage problem is signi ?-cantly relieved.They therefore concluded that the swing com-pressor is more suitable for the CO 2refrigerant.

2.1.

3.Scroll compressor

Sakakibara et al.[20]developed the ?rst CO 2scroll compressor applicable for CO 2heat pump water heater.The unit worked very effectively since it can reduce as much as 30%energy consumption as compared to the gas combustion system from the level of electrical power generation,yet it also showed a 50%reduction of CO 2emission as compared to the gas combustion system.Based on a mass-production R-410A scroll compressor,Shimoji and Naka-mura [25]developed a prototype of a 10hp CO 2scroll compressor.They also provided a quantitative loss analysis of this compressor using a simpli ?ed model from the basic test,and the results showed that the test results were in line with the analysis.2.2.Future trends

Compressor technology for the CO 2transcritical systems has reached an advanced level after years of development.Recently,researchers are focusing on the two-stage compression and expander technology to boost the compressor ef ?ciency even higher [15].

2.2.1.Two-stage compressor

The pressure difference between discharge-and suction-pressure of CO 2refrigerant is several times larger than that of the conventional HFC (hydro ?uorocarbons)refrigerants.This brings about an increase of gas leakage and mechanical losses.However,by introducing the two-stage compression the pressure difference in each stage is considerably reduced,thereby higher system ef ?ciency and higher reliability can be obtained.Sato et al.[26]compared the compressor performances between single-stage and two-stage compression based on structure difference as depicted in Table 4.From the elaborate comparisons,it appears that the two-stage compression outperforms that of single-stage compression in every aspect.

Suzai et al.[27],Tadano et al.[28],and Yamasaki et al.[29]developed a two-stage rotary compressor as shown in Fig.5to ease the in ?uence of high pressure difference inherited with CO 2.By dividing the compression process into two separate compres-sions,the leakage at the seal is reduced so that high compression ef ?ciency can be attained.In addition,two pistons were placed out of phase (180deg.).With this opposite-side arrangement,the problems of vibration and noise are considerably reduced.From the fundamental CO 2properties,the high volumetric ef ?ciency with small piston size can be achieved.Yet smooth shaft rotation at start up and operation can be made available due to smaller rotational inertia and torque balance for the CO 2.In addition,the internal intermediate pressure design enabled the shell wall thickness to be 35%thinner than that of the high pressure operation.Accordingly this helps to reduce the total weight which is found to be about the same as the conventional R-410A compressor.Moreover,the internal intermediate pressure design makes the pressure difference between on and off period smaller than that of the 1-stage design.This eventually raises high reliability to prevent fatigue of the shell material through periodi-cally high/low pressures cycle.

Moreover,the two-stage compressor is suitable for economizer cycle,Kobayashi [17]implemented a CO 2heat pump and water heater system with an economic cycle for cold climate region using the compressor shown in Fig.5.Through this design,some 8kW heating capacity and the 4.5kW water heating performance at an outdoor air temperature of à201C were achieved,the capacity and COP is increased as much as 17%when compared to that with no economizer cycle.

Yokoyama et al.[30]developed a two-stage rotary compressor for CO 2heat pump systems with refrigerant injection.Fig.6shows the performance at various rotational speeds in association with the single-stage type having the same speci ?cations.They found that the compressor ef ?ciency of the two-stage type is superior to the single-stage type in the low rotational speed or high pressure-ratio.

Table 4

Comparison of compressor performance according to structure.Number of compression stages Shell pressure

Compression mechanism Shell thickness Gas injection Reliability Ef ?ciency

First stage Second stage

First stage Second stage First stage Second stage

Single stage Discharge pressure ààSuction pressure tàTwo stages

Discharge pressure

àta Intermediate pressure Scroll

Scroll ttttb tb tttScroll Rotary tttttàttRotary Scroll tttttttttttRotary

Rotary tttttàtttSuction pressure Scroll

Scroll tta tb tb tttScroll Rotary tta ttàttRotary Scroll tta àttttttRotary

Rotary

t

ta

ààttt

a Connection piping between ?rst and second stages is required.b

An oil pump must be placed in the middle of the

shaft.

Fig.4.Rotary compressor vs.swing compressor —a schematic.

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews 50(2015)1383–1391

1386

Apparently,this is associated with the inherited lower compression ratio for each stage of the two-phase compression,thereby leading to a much lower gas leaking during compression.The two-stage type is also superior to the single-stage type in compressor ef?ciency and heating capacity because it has the ability to improve these performances with refrigerant injection during high pressure-ratio operation.

Sato et al.[26]developed a novel compressor for commercial CO2 heat-pump water heaters as shown in Fig.7.The developed com-pressor employs rotary and scroll mechanisms in the?rst and second stage respectively to minimize the leakage and mechanical losses.In addition,by employing an intermediate gas injection,the new compressor has attained a high heating capacity and a high ef?ciency under a wide range of conditions.Their test results showed a15% improvement at the rated condition and more than30%improvement emerges at a higher pressure ratio condition which is conversed to the conventional prototype single-stage scroll compressor.

2.2.2.Expander and expander–compressor

One of the major challenges with CO2in air-conditioning applications is the low system energy ef?ciency at higher operat-ing heat sink temperatures.The major loss in CO2cycles is the throttling loss associated with the expansion process.The avail-ability lost during the expansion process can be recovered with a work-producing expansion device,so called an expander[31].Ma et al.[32]calculated and compared the system performance using CO2and R-134a as the working?uids.Their results showed that the performance of CO2system can be improved by using a low cost displacement expander.The expander is easily connected to the compressor coaxially,which contributes to the improvement of recovery work.Their highest ef?ciency recovery ratio can reach up to14.5%of the input power of compressor.

Matsui et al.[33]developed a two-stage rotary expander (Fig.8)which has been designed to connect its shaft to the shaft of a commercial scroll compressor,and is designed to provide an expansion chamber surrounded by the piston and the cylinder in the second stage which is larger than that in the?rst stage.After examining the impact of each design parameter on the perfor-mance through the simulation,an optimized design had

been https://www.doczj.com/doc/551772548.html,parison of the two-stage and single-stage CO2compressors at P d/P s?2.53,taken from[30]

.

Fig.7.Two-stage compressor employs rotary and scroll mechanisms in the?rst and second stage[26]

.

Fig.5.Schematic for a hermetic two-stage CO2compressor.

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews50(2015)1383–13911387

devised and the expander ef ?ciency is increased as much as 60%which is equivalent to a 6%rise of system COP.Hiwata et al.[34]designed a scroll pro ?le of the scroll expander applicable for CO 2refrigerant.Their design makes use of overexpansion and to control the axial force on the thrust bearing.Through this design,they had demonstrated an exceptionally high volumetric ef ?-ciency of 96%.

As shown in Fig.9,Kohsokabe et al.[35]developed a prototype of a scroll expander for CO 2refrigeration cycles.The test results show that their scroll expander revealed a maximum isentropic ef ?ciency of 70%.

In Fig.10,Nagata et al.[36]designed a dual-sided scroll-type expander and is combined with a sub-compressor.The associated installation and operation of this design is schematically shown in Fig.11.According to the experimental results of the prototype device,the sub-compressor increased the pressure by 1.30MPa,while the pressure drop between the inlet and outlet of the expander was 3.19MPa.They also demonstrated that the power consumption of the main-compressor can be reduced using the prototype of an expander originally designed for a CO 2refrigera-tion cycle with an intercooler.

3.Water –CO 2heat exchanger

There are two important challenges for water –CO 2heat exchanger applicable for the heat pump water heater.The ?rst is to provide a reliable leak detection of the heat exchanger during operation.The second is that the heat exchanger must withstand high pressures —at least 13MPa in the CO 2side.As far as a product is concerned,low cost,compact,and high ef ?ciency must also be taken into account.Apparently,the concerns are often against the challenges.

Taira [37]compared three types of the water –CO 2heat exchangers (double tube,smooth tube and dimple tube)as shown in Fig.12.The ?rst type is the double tube heat exchanger with leakage detection ditch,this leakage detectable tube was manu-factured from the insertion of another tube in the inner groove tube and was put together later on.However,the double tube design has the drawbacks of being heavy,expensive,and dif ?culty in reducing size because the bending ratio cannot be reduced.He then developed a new type (smooth tube)heat exchanger which combined water tube and CO 2tube with a counter ?ow con ?g-uration.The weight and volume of the new heat exchanger is about 10to 30%lower than those of a double-tube exchanger.Taira [37]further improved the water –CO 2heat exchanger using a dimple tube as appeared in Fig.12.Note that the superimposed dimple/cavity structure onto the surface structure reinforces the heat transfer augmentations as demonstrated by Wang et al.[38].This is because near wall vortices is generated in the cavity structure in fully developed ?ow region which augments heat transfer considerably.The design is especially useful when the thermal resistance is on the water side.In practice,the dominant thermal resistance is primarily on the water side as depicted by Yu et al.[39]and Lin.et al.[40].Note that it is often quite imperative to place enhancement in the dominant resistance side.For CO 2transcritical cycle,it is evitable that the CO 2will pass through

the

Fig.9.A prototype of a scroll expander for CO 2refrigeration cycles (Kohsokabe et al.[35]

).

Fig.10.A dual-sided scroll-type expander and is combined with a sub-compressor (Nagata et al.[36]

).

Fig.11.Schematic of the operation of a dual-sided scroll-type expander and is combined with a sub-compressor (Nagata et al.[36]

).

Fig.8.Schematic of the developed a two-stage rotary expander (from Matsui et al.[33]).

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews 50(2015)1383–1391

1388

pseudo-critical point where property like heat capacity may show a surge rise,thereby leading to a signi ?cant rise of heat transfer coef ?cient,hence the major thermal resistance may occur in the water side.Notice that the surges of heat capacity and heat transfer coef ?cient at the pseudo-critical point become even pronounced if the system pressures are close the critical pressure.This phenomenon had been elaborated in some previous studies [39–41].However,it should be mentioned that if the operational pressure of CO 2is suf ?ciently high,say 10or 12MPa,the surge of heat capacity near the pseudo-critical point is rather small and the thermal resistance may switched from water side to CO 2side.In this regard,the enhancement can be simply placed at the front or rear part of the gas cooler for effective reduction of total thermal resistance and for lowering the pressure drop.Okada [42]introduced a newly developed “twist &spiral gas cooler ”as depicted in Fig.13.The heat exchanger features a twisted pipe with three lines of spiral grooves for a water pipe,which are prepared by a twisting method.A refrigerant pipe (thin pipe)is wound around the twisted pipe and connected to each other by zinc-free soldering.This arrangement increases the contact surfaces on both pipes,thus increasing the heat transfer area,and the continuous spiral grooves in the twisted pipe accentuates the turbulence effect in the water and is also bene-?cial in reducing pressure loss in the heat exchanger.Furthermore,three pipes are wound around the three spiral grooves in parallel to reduce the pressure loss in the refrigerant.Sakakibara et al.[20]developed a capillary tube heat exchanger as shown in Fig.14,their calculation showed that the set mode of the water tube

and

Fig.12.Typical water –CO 2heat exchangers used in tube-in-tube type heat exchangers (double tube,smooth tube and dimple tube;Taira [37]

).

Fig.13.Con ?guration of “Twist &spiral developed by Okada [42]

.

Fig.14.Developed a capillary tube heat exchanger developed by Sakakibara et al.[20].

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews 50(2015)1383–13911389

the CO 2tube inner diameter were the most important factors affecting the ef ?ciency.Andou et al.[43]focused on the tube in tube heat exchanger (Fig.15).In their test clearly revealed that the thermal resistance of water side is much higher than that of the CO 2side,therefore by use of the design of dimple heat exchanger,the water side heat transfer coef ?cient can be improved more than twice and accordingly a better overall heat transfer performance of the gas cooler is observed.

4.Other heat pump water heater standard for the major countries

Table 5depicts comparisons between the basic standards [16,44–46]applicable for heat pump water heater in major countries (Japan,EU,USA,and China).The JIS standard is generally associated with CO 2whereas other standards for the major countries are primarily for R-22/R-410A/R-134a.Hence cost ratio,evaluated relative to China,is generally highest for the CO 2system and a higher water temperature can be achieved for the CO 2heat pump.5.Conclusions

CO 2is a potential substitute for HFC refrigerants with favorable environmental properties when compared to other HFC

alternatives.In this paper,the CO 2heat pump water heater for residential use in Japan has been reviewed,especially for the technologies associated with the compressor and the water –CO 2heat exchanger.Currently rotary,swing and scroll are the three main types of compressors applicable to the current CO 2water heat pump.With typical displacement of the CO 2compressors ranging from 3.3to 4.5cm 3and with revolutions being 1800–7200min à1,the typical rating condition for the CO 2water heaters are designed at 4–4.5MPa for the suction pressure,9–10MPa for the discharge pressure and 221C for the outlet temperature of the gas cooler.For improving the high throttling loss from the high pressure-difference of CO 2,two-stage compressor and expander technology are proved to be quite effective to resolve this problem.In the meantime,normally the thermal resistance can be either at the water side or CO 2side,hence it is essential to improve the heat transfer coef ?cient of the water side or CO 2.Normally the surge of heat transfer performance of CO 2becomes more and more pro-nounced when the operational pressure is close to the critical point,leading to a dramatic rise of heat transfer coef ?cient and the dominant resistance may be on the water side.On the contrary,if the operational pressure is high,say over 10MPa,the detrimental thermal resistance may be switched to CO 2side.As a consequence,it is imperative to understand the thermal resistance distribution before employing the effective augmentation to the gas cooler tube.For practical application,the operational pressure is normally below 10MPa,hence current technology has introduced the

twisted

Fig.15.Various tube-in-tube heat exchanger developed by Andou et al.[43].

Table 5

Basic speci ?cations for heat pump water heater in different countries.Country Japan EU

USA China

Standard

JIS C-9220EN 16147AHRI 1301GB/T 23137[16][44]

[45][46]

Refrigerants

CO 2

R410A \R134a R22\R410A \R134a Hot water temperature 65à9055à65Ef ?ciency (COP) 4.6à4.9–

3.7à

4.6Cost ratio

3à4

1.5à2

$1

(relative to China)

J.-F.Zhang et al./Renewable and Sustainable Energy Reviews 50(2015)1383–1391

1390

design and dimple tubes to reduce the thermal resistance on the water side.

Acknowledgments

The last author,Dr.Chi-Chuan Wang,would like to thank for the support from the Ministry of Science and Technology of Taiwan,under contract104-3113-E-009-004.

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End???结束 Band ?乐队 Practice??练习 Together 一起 Market?市场 Guitar?吉它 Grade??年级 junior high school?初中 on foot??步行 takepart in??参加 have a good time 玩得开心 go to bed??上床睡觉 get up???起床 Module 2 The Natural WorldUnit3& Unit4Unit3The Earth Earth???地球 Quiz????测试 Pattern??模式 Protect ?保护 Report??报告 Part?部分 Land???陆地 Field?田野、田地 Large??大的 Provide 提供 Pollution污染 Burn???燃烧 Energy ?能量 Pollute??污染 Into ??进入 Ground ?地面 Kill ?杀死 Must?必须 Important ??重要的 Fact???事实 Kilometer??千米 Own?自己的 Catch???抓住 Few????很少 Away ?离开 Problem 问题 provide with ?提供。。。

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关于公司节约成本的具 体方案 Pleasure Group Office【T985AB-B866SYT-B182C-BS682T-STT18】

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unit2广州版八年级下册(最新整理)

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